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Journal articles on the topic 'Photothermal polymerization'

Author: Grafiati

Published: 25 May 2024

Last updated: 31 July 2025

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1

Hou, Shi-Chang, Dao-Wei Zhang, Jun Chen, Xiao-Xiao Guo, Abdul Haleem, and Wei-Dong He. "Sulfonated PAM/PPy Cryogels with Lowered Evaporation Enthalpy for Highly Efficient Photothermal Water Evaporation." Polymers 15, no. 9 (2023): 2108. http://dx.doi.org/10.3390/polym15092108.

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Because of the increasing scarcity of water resources, the desalination of seawater by photothermal evaporation with harvested solar energy has gradually become a popular research topic. The interconnected macroporous cryogel prepared from polymerization and crosslinking below the freezing temperature of the reactant solution has an excellent performance in photothermal water evaporation after loading photothermal materials. In this study, polyacrylamide (PAM) cryogels were prepared by cryo-polymerization and sulfonated in an alkaline solution containing formaldehyde and Na2SO3. Importantly, t

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2

Wang, Yanming, Xin Ji, Peng Pang, et al. "Synthesis of Janus Au nanorods/polydivinylbenzene hybrid nanoparticles for chemo-photothermal therapy." Journal of Materials Chemistry B 6, no. 16 (2018): 2481–88. http://dx.doi.org/10.1039/c8tb00233a.

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3

Hou, Liman, Jianyong Fang, Weiqi Wang, Zhigang Xie, Dewen Dong, and Ning Zhang. "Indocyanine green-functionalized bottle brushes of poly(2-oxazoline) on cellulose nanocrystals for photothermal cancer therapy." Journal of Materials Chemistry B 5, no. 18 (2017): 3348–54. http://dx.doi.org/10.1039/c7tb00812k.

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4

Haas, Kaitlin M., and Benjamin J. Lear. "Billion-fold rate enhancement of urethane polymerization via the photothermal effect of plasmonic gold nanoparticles." Chemical Science 6, no. 11 (2015): 6462–67. http://dx.doi.org/10.1039/c5sc02149a.

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5

Ci, Dazheng, Ning Wang, Yunqi Xu, et al. "SiO₂@AuAg/PDA hybrid nanospheres with photo-thermally enhanced synergistic antibacterial and catalytic activity." RSC Advances 14, no. 7 (2024): 4518–32. http://dx.doi.org/10.1039/d3ra07607e.

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SiO2@AuAg/Polydopamine core/shell nanospheres, which possessed synergistic “Ag+-release–photothermal” antibacterial and catalytic behaviors, have been successfully prepared via a simple in situ redox polymerization method.

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6

Qian, Hongyun, Huiping Dang, Changchang Teng, Dalong Yin та Lifeng Yan. "Synthesis of pH-responsive supramolecular polypeptide nanoparticles from α-amino acids for combined chemo-photothermal therapy". JUSTC 53, № 3 (2023): 0305. http://dx.doi.org/10.52396/justc-2022-0154.

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A new smart supramolecular polypeptide copolymer P(Glu-co-Lys) was synthesized by the polymerization of α-amino acids using the N-thiocarboxylic acid anhydride (NTA) method, using the pH dynamic response peptide of L-glutamic acid and L-lysine as a carrier for tumor cells. The drug delivery system activated by external acid can self-assemble (pH 7.4) and disassemble (pH 5.5) under the adjustment of pH to load the drug and control its release. Doxycycline (DOX) and the photothermal reagent hydrophilic quanternary stereo-cyanine (HQS-Cy) were loaded into the peptide copolymer to obtain HQS-Cy/DO

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7

Li, Feng, Yaqin Song, Miao Yao, Jun Nie, and Yong He. "Design and properties of novel photothermal initiators for photoinduced thermal frontal polymerization." Polymer Chemistry 11, no. 24 (2020): 3980–86. http://dx.doi.org/10.1039/d0py00305k.

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Three synthesized photothermal initiators (2959-HDHP, 184-HDHP, 1173-HDHP) exhibited better photoinduced thermal frontal polymerization effect than mixture system due to higher heat transfer efficiency from photopolymerization to thermal initiator.

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8

Dean, Leon M., Amogha Ravindra, Allen X. Guo, Mostafa Yourdkhani, and Nancy R. Sottos. "Photothermal Initiation of Frontal Polymerization Using Carbon Nanoparticles." ACS Applied Polymer Materials 2, no. 11 (2020): 4690–96. http://dx.doi.org/10.1021/acsapm.0c00726.

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9

Yang, Mei, Minfang Zhang, Masao Kunioka, et al. "Photothermal conversion of carbon nanohorns enhancing caprolactone polymerization." Carbon 83 (March 2015): 15–20. http://dx.doi.org/10.1016/j.carbon.2014.11.022.

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10

Bhattarai, Deval Prasad, and Beom Su Kim. "NIR-Triggered Hyperthermal Effect of Polythiophene Nanoparticles Synthesized by Surfactant-Free Oxidative Polymerization Method on Colorectal Carcinoma Cells." Cells 9, no. 9 (2020): 2122. http://dx.doi.org/10.3390/cells9092122.

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In this work, polythiophene nanoparticles (PTh–NPs) were synthesized by a surfactant-free oxidative chemical polymerization method at 60 °C, using ammonium persulphate as an oxidant. Various physicochemical properties were studied in terms of field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Fourier transform infra-red (FT-IR) spectroscopy, and differential scanning calorimetry (DSC)/thermogravimetric analysis (TGA). Photothermal performance of the as-synthesized PTh–NPs was studied by irradiating near infra-red of 808 nm under different concentration of the substra

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11

Xie, Yixin, Ji Xu, Hui Jin, et al. "Polypyrrole Nanosheets Prepared by Rapid In Situ Polymerization for NIR-II Photoacoustic-Guided Photothermal Tumor Therapy." Coatings 13, no. 6 (2023): 1037. http://dx.doi.org/10.3390/coatings13061037.

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Recently, the near-infrared-II (NIR-II, 1000–1350 nm) region has been extensively applied in deep-tissue photothermal therapy (PTT) on account of it having stronger tissue penetration and a higher maximum permissible exposure (MPE) than the near-infrared-I (NIR-I, 650–950 nm) region. In this study, we developed a rapid and convenient in situ polymerization strategy to fabricate polypyrrole nanosheets (PPy NSs) within a few minutes using manganese dioxide nanosheets (MnO2 NSs) as both the oxidant and the self-sacrificed template. The fabricated PPy NSs exhibited excellent NIR-II absorption, whi

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12

Jiang, Xue, Yu Sun, Lihuang Shang, Conglian Yang, Li Kong, and Zhiping Zhang. "Green tea extract-assembled nanoclusters for combinational photothermal and chemotherapy." Journal of Materials Chemistry B 7, no. 39 (2019): 5972–82. http://dx.doi.org/10.1039/c9tb01546a.

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13

Walker, Joan M., Linfeng Gou, Sibaprasad Bhattacharyya, Sarah E. Lindahl, and Jeffrey M. Zaleski. "Photothermal Plasmonic Triggering of Au Nanoparticle Surface Radical Polymerization." Chemistry of Materials 23, no. 23 (2011): 5275–81. http://dx.doi.org/10.1021/cm202741p.

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14

Bonardi, Aude heloise, Fabrice Bonardi, Frédéric Dumur, Didier Gigmes, Jean Pierre Fouassier, and Jacques Lalevée. "Fillers as Heaters for Photothermal Polymerization upon NIR Light." Macromolecular Rapid Communications 40, no. 23 (2019): 1900495. http://dx.doi.org/10.1002/marc.201900495.

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15

Chen, Xu, Feng Gao, and Lihua Yang. "Polymerized small molecular dyes providing nanoparticles with stable photosensitivity for eradicating cancer cells." JUSTC 53, no. 6 (2023): 0607. http://dx.doi.org/10.52396/justc-2023-0056.

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To make small molecular photosensitizer-based nanoparticles photostable, we polymerized such photosensitizers via emulsion polymerization, and the resulting nanoparticles exhibited sustained absorption of the excitation wavelength in the near-infrared region, generated stable photothermal and photodynamic effects upon repeated irradiation with an near-infrared laser, and efficiently eradicated cancerous cells even after prior irradiation exposure.

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16

Yang, Guang-Hui, Shao-Zhen Yi, Shu-Rong Du, Jia-Lin Gao, and Xue-Juan Wan. "Highly temperature-sensitive, photothermal, and robust intelligent hydrogels tailored for the NIR-II biological window." Materials Express 14, no. 8 (2024): 1113–25. https://doi.org/10.1166/mex.2024.2722.

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Combining PNIPAM with a biocompatible NIR-II photothermal agent to prepare near-infrared-responsive hydrogels holds significant importance in the field of biomedical applications. In this study, PNIPAM/Bacterial cellulose (BC)/MXene composite hydrogels were prepared by in-situ polymerization, where Nb2C MXene serving as a near-infrared photothermal agent and BC acting as enhancing filler. The composite hydrogels possess a semi-interpenetrating network structure, where PNIPAM serves as the crosslinking network backbone, and BC act as a semi-interpenetrating network, which significantly enhances

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17

Li, Xiaoting, Xianchun Liu, Xiaoguang Qiao, and Shuangxi Xing. "Confining the polymerization of aniline to generate yolk–shell polyaniline@SiO2 nanostructures." RSC Advances 5, no. 96 (2015): 79172–77. http://dx.doi.org/10.1039/c5ra15065e.

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Yolk–shell nanostructured polyaniline@SiO<sub>2</sub> particles were fabricated by using CeO<sub>2</sub>@SiO<sub>2</sub> particles as reactive and confined templates and the samples were applied in drug loading and photothermal release as a proof of concept.

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18

Jiang, Yu, Xingchen Duan, Junhua Bai, Hongkun Tian, Dan Ding, and Yanhou Geng. "Polymerization-induced photothermy: A non-donor-acceptor approach to highly effective near-infrared photothermal conversion nanoparticles." Biomaterials 255 (October 2020): 120179. http://dx.doi.org/10.1016/j.biomaterials.2020.120179.

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19

Yao, Lan, Haihui Li, Kai Tu, Lifen Zhang, Zhenping Cheng, and Xiulin Zhu. "Construction of NIR Light Controlled Micelles with Photothermal Conversion Property: Poly(poly(ethylene glycol)methyl ether methacrylate) (PPEGMA) as Hydrophilic Block and Ketocyanine Dye as NIR Photothermal Conversion Agent." Polymers 12, no. 5 (2020): 1181. http://dx.doi.org/10.3390/polym12051181.

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Polymeric nanomaterials made from amphiphilic block copolymers are increasingly used in the treatment of tumor tissues. In this work, we firstly synthesized the amphiphilic block copolymer PBnMA-b-P(BAPMA-co-PEGMA) via reversible addition-fragmentation chain transfer (RAFT) polymerization using benzyl methacrylate (BnMA), poly (ethylene glycol) methyl ether methacrylate (PEGMA), and 3-((tert-butoxycarbonyl)amino)propyl methacrylate (BAPMA) as the monomers. Subsequently, PBnMA-b-P(APMA-co-PEGMA)@NIR 800 with photothermal conversion property was obtained by deprotection of the tert-butoxycarbony

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20

Rejeb, Rania, Philibert Lenormand, Gaspard Bichot, et al. "NIR photothermal activation in epoxy/anhydride systems for advanced polymerization." European Polymer Journal 222 (January 2025): 113589. http://dx.doi.org/10.1016/j.eurpolymj.2024.113589.

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21

Kawashima, H., H. Mayama, Y. Nakamura, and S. Fujii. "Hydrophobic polypyrroles synthesized by aqueous chemical oxidative polymerization and their use as light-responsive liquid marble stabilizers." Polymer Chemistry 8, no. 17 (2017): 2609–18. http://dx.doi.org/10.1039/c7py00158d.

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22

Vedanarayanan, V., J. Dilli Srinivasan, K. Arulvendhan, et al. "Synthesis of Modified Phase-Changing Material with Latent Heat and Thermal Conductivity to Store Solar Energy Using a Carbon Nanotube." International Journal of Photoenergy 2022 (April 11, 2022): 1–12. http://dx.doi.org/10.1155/2022/3412817.

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MicroPCMs’ excellent thermal capacity and photothermal translation features benefit solar energy storage applications significantly. A successful in situ polymerization procedure was employed to build microencapsulated phase-change materials using n-hexadecanol as the core and melamine-formaldehyde resin as the outer shell, and the thermal characteristics of the microPCMs were evaluated. In terms of micromorphology, the incorporation of hydroxylated carbon nanotubes into microPCMs with a compact shell has little effect on their spherical structure. MicroPCMs’ melting heat and latent heat are b

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23

Bae, Seo Ryung, Jihye Choi, Hyun-Ouk Kim, et al. "Pseudo metal generation via catalytic oxidative polymerization on the surface of reactive template for redox switched off–on photothermal therapy." Journal of Materials Chemistry B 3, no. 3 (2015): 505–13. http://dx.doi.org/10.1039/c4tb01461h.

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24

Caron, Aurore, Guillaume Noirbent, Didier Gigmes, Frédéric Dumur, and Jacques Lalevée. "Near‐Infrared PhotoInitiating Systems: Photothermal versus Triplet–Triplet Annihilation‐Based Upconversion Polymerization." Macromolecular Rapid Communications 42, no. 11 (2021): 2100047. http://dx.doi.org/10.1002/marc.202100047.

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25

Lee, Hwangjae, Semin Kim, Chiseon Ryu, and Jae Young Lee. "Photothermal Polymerization Using Graphene Oxide for Robust Hydrogelation with Various Light Sources." ACS Biomaterials Science & Engineering 6, no. 4 (2020): 1931–39. http://dx.doi.org/10.1021/acsbiomaterials.0c00161.

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26

Lee, Hwangjae, Solchan Chung, Min-Gon Kim, Luke P. Lee, and Jae Young Lee. "Near-Infrared-Light-Assisted Photothermal Polymerization for Transdermal Hydrogelation and Cell Delivery." Advanced Healthcare Materials 5, no. 13 (2016): 1638–45. http://dx.doi.org/10.1002/adhm.201600048.

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27

Li, Ruiting, Xiaodong Lian, Zhen Wang, and Yapei Wang. "Radical Cation Initiated Surface Polymerization on Photothermal Rubber for Smart Antifouling Coatings." Chemistry – A European Journal 25, no. 1 (2018): 183–88. http://dx.doi.org/10.1002/chem.201804526.

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28

Peñuñuri-Miranda, Omar, Miguel Olivas-Martinez, José Alberto Ibarra-Espinoza, et al. "Spatiotemporal Temperature Distribution of NIR Irradiated Polypyrrole Nanoparticles and Effects of pH." Polymers 14, no. 15 (2022): 3151. http://dx.doi.org/10.3390/polym14153151.

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The spatiotemporal temperature distributions of NIR irradiated polypyrrole nanoparticles (PPN) were evaluated by varying PPN concentrations and the pH of suspensions. The PPN were synthesized by oxidative chemical polymerization, resulting in a hydrodynamic diameter of 98 ± 2 nm, which is maintained in the pH range of 4.2–10; while the zeta potential is significantly affected, decreasing from 20 ± 2 mV to −5 ± 1 mV at the same pH range. The temperature profiles of PPN suspensions were obtained using a NIR laser beam (1.5 W centered at 808 nm). These results were analyzed with a three-dimension

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29

Xu, Kezhu, Qunling Fang, Jing Wang, Ailing Hui, and Shouhu Xuan. "Magnetic-Field-Induced Improvement of Photothermal Sterilization Performance by Fe3O4@SiO2@Au/PDA Nanochains." Materials 16, no. 1 (2022): 387. http://dx.doi.org/10.3390/ma16010387.

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Due to the abuse of antibiotics, the sensitivity of patients to antibiotics is gradually reduced. This work develops a Fe3O4@SiO2@Au/PDA nanochain which shows an interesting magnetic-field-induced improvement of its photothermal antibacterial property. First, SiO2 was wrapped on Fe3O4 nanospheres assembled in a chain to form a Fe3O4@SiO2 nanocomposite with a chain-like nanostructure. Then, the magnetic Fe3O4@SiO2@Au/PDA nanochains were prepared using in situ redox-oxidization polymerization. Under the irradiation of an 808 nm NIR laser, the temperature rise of the Fe3O4@SiO2@Au/PDA nanochain d

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30

Acter, Shahinur, Michele Moreau, Robert Ivkov, Akila Viswanathan, and Wilfred Ngwa. "Polydopamine Nanomaterials for Overcoming Current Challenges in Cancer Treatment." Nanomaterials 13, no. 10 (2023): 1656. http://dx.doi.org/10.3390/nano13101656.

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In efforts to overcome current challenges in cancer treatment, multifunctional nanoparticles are attracting growing interest, including nanoparticles made with polydopamine (PDA). PDA is a nature-inspired polymer with a dark brown color. It has excellent biocompatibility and is biodegradable, offering a range of extraordinary inherent advantages. These include excellent drug loading capability, photothermal conversion efficiency, and adhesive properties. Though the mechanism of dopamine polymerization remains unclear, PDA has demonstrated exceptional flexibility in engineering desired morpholo

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31

Ni, Qingrun, Yating Wang, Shoujuan Wang, Magdi E. Gibril, and Fangong Kong. "Constructing Multifunctional Composite Paper Coated with Polypyrrole@Lignocellulosic Slurry with Humidity Sensing, Conductivity, Antibacterial, and Photothermal Properties." Polymers 17, no. 7 (2025): 898. https://doi.org/10.3390/polym17070898.

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A multifunctional paper-based composite of paper coated with a polypyrrole@lignocellulosic slurry (PPy@LS) and carboxymethyl cellulose (CMC) was developed. PPy@LS was prepared via the polymerization of pyrrole onto a lignocellulosic slurry derived from hemp stalks prepared using deep eutectic solvents. The PPy@LS slurry was mixed with the required amount of CMC and vacuum-filtered onto filter paper to fabricate the composite (PPy@LS/CMC). The resulting composite paper exhibited excellent multifunctional properties, including electrical conductivity, photothermal conversion, and antibacterial p

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32

Ece, Ozelik Zeliha, Tas Buket Alkan, Bor Shin Chee, et al. "Near-Infrared-Induced High-Performance Antimicrobial Active Coating for Medical Textiles Based on Easy-to-Synthesize Natural Catechin with Full End of Life Circularity." ACS Sustainable Chemistry & Engineering 12, no. 49 (2024): 17936–51. https://doi.org/10.1021/acssuschemeng.4c08280.

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The near-infrared (NIR)-induced antimicrobial textile (CTex) exhibits significant antimicrobial and antibiofilm activity over 4log reductions (more than 99.99% killing efficiency) against methicillin-resistant <em>S. aureus</em> (MRSA), <em>S. aureus</em>, <em>E. coli</em>, and <em>C. albicans</em> within seconds under 808 nm NIR-laser irradiation by rapidly reaching almost 180 °C. A simple yet effective preparation method for an intensely active photothermal polymer backbone from the natural compound catechin is presented. The NIR-responsive polymer backbone was synthesized using a step-g

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33

Martínez-Torres, P., A. Mandelis, and J. J. Alvarado-Gil. "Photothermal determination of thermal diffusivity and polymerization depth profiles of polymerized dental resins." Journal of Applied Physics 106, no. 11 (2009): 114906. http://dx.doi.org/10.1063/1.3266007.

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34

Dowaidar, Moataz. "Polydopamine may be easily functionalized with a range of nanomaterials for synergistic cancer therapy, in addition to its exceptional photothermal effects." Journal of Biomedical Engineering 39, no. 6 (2022): 70–94. https://doi.org/10.5281/zenodo.8162024.

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Recent breakthroughs in photothermal treatment coupled with complex therapies such as gene therapy, radiation, and especially immunotherapy were highlighted. Due to their exceptional biocompatibility, degradability, low toxicity and high photothermal conversion efficiency, facile oxidative self-polymerization of dopamine can create PDA and serve as an excellent nanocarrier or photothermal cancer treatment agent. Due to its high adhesive capacity, PDA may be easily functionalized with a range of nanomaterials for synergistic cancer therapy, in addition to its exceptional photothermal effects. A

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35

Wang, Changling, Guiling Zhang, and Xiaosong Zhang. "Experimental and Photothermal Performance Evaluation of Multi-Wall Carbon-Nanotube-Enhanced Microencapsulation Phase Change Slurry for Efficient Photothermal Conversion and Storage." Energies 15, no. 20 (2022): 7627. http://dx.doi.org/10.3390/en15207627.

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Melamine formaldehyde was used as the shell material and n-eicosane as the core material with the method of in situ polymerization to synthesize microencapsulated phase change materials (MPCMs). To enhance the thermophysical characteristics and photothermal conversion performance of the MPCM slurry, multi-wall carbon nanotubes were added, and the microscopic morphology and thermophysical parameters of the MWCNT-MPCM slurry were analyzed. The thermal conductivity, viscosity, and photothermal conversion properties of the slurry were examined. The results indicated that the synthesized MPCMs were

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36

Huang, Jiaxing. "Syntheses and applications of conducting polymer polyaniline nanofibers." Pure and Applied Chemistry 78, no. 1 (2006): 15–27. http://dx.doi.org/10.1351/pac200678010015.

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Nanofibers with diameters of tens of nanometers appear to be an intrinsic morphological unit that was found to "naturally" form in the early stage of the chemical oxidative polymerization of aniline. In conventional polymerization, nanofibers are subject to secondary growth of irregularly shaped particles, which leads to the final granular agglomerates. The key to producing pure nanofibers is to suppress secondary growth. Based on this, two methods - interfacial polymerization and rapidly mixed reactions - have been developed that can readily produce pure nanofibers by slightly modifying the c

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37

González-Ayón, Mirian A., Jacob Licea-Rodriguez, Eugenio R. Méndez, and Angel Licea-Claverie. "NVCL-Based Galacto-Functionalized and Thermosensitive Nanogels with GNRDs for Chemo/Photothermal-Therapy." Pharmaceutics 14, no. 3 (2022): 560. http://dx.doi.org/10.3390/pharmaceutics14030560.

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Dual-function nanogels (particle size from 98 to 224 nm) synthesized via surfactant-free emulsion polymerization (SFEP) were tested as smart carriers toward synergistic chemo- and photothermal therapy. Cisplatin (CDDP) or doxorubicin (DOX) and gold nanorods (GNRDs) were loaded into galacto-functionalized PNVCL-based nanogels, where the encapsulation efficiency for CDDP and DOX was around 64 and 52%, respectively. PNVCL-based nanogels were proven to be an efficient delivery vehicle under conditions that mimic the tumor site in vitro. The release of CDDP or DOX was slower at pH 7.4 and 37 °C tha

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38

Han, Haijie, Shimiao Zhang, Yin Wang, et al. "Biomimetic drug nanocarriers prepared by miniemulsion polymerization for near-infrared imaging and photothermal therapy." Polymer 82 (January 2016): 255–61. http://dx.doi.org/10.1016/j.polymer.2015.11.022.

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39

Bonardi, Aude‐Heloise, Fabien Bonardi, Guillaume Noirbent, et al. "Free‐radical polymerization upon near‐infrared light irradiation, merging photochemical and photothermal initiating methods." Journal of Polymer Science 58, no. 2 (2020): 300–308. http://dx.doi.org/10.1002/pol.20190079.

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40

Li, Hongchuang, Zhou Sha, Yuheng Song, et al. "Developing Wearable Photothermal and Antibacterial Fabrics: In-Situ Polymerization of MoS2-Hybridized PET Fibers." Composites Science and Technology 270 (September 2025): 111291. https://doi.org/10.1016/j.compscitech.2025.111291.

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41

Hou, Guodong, Runhang Wei, Feiyu Zhang, Xuning Wang, Wei Lu, and Xiaoshi Qian. "Biomimetic Photothermal Actuator Exhibits Robust Motion and Omnidirectional Phototropism." Journal of Nanoelectronics and Optoelectronics 19, no. 1 (2024): 29–35. http://dx.doi.org/10.1166/jno.2024.3534.

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Organisms in the natural world receive signals from the external environment and exhibit continuous propulsion. However, creating artificial systems that can rapidly track energy sources in real-time without human intervention and electronic circuit programming poses a significant challenge. Here, we have developed a soft actuator that mimics the phototropism of plants and possesses autonomous sensing and driving capabilities. The soft actuator is based on a thermo responsive PNIPAAM hydrogel, and its uniform incorporation of light-absorbing agents imparts photothermal response characteristics

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42

Yeung, Ka-Wai, Yuqing Dong, Ling Chen, et al. "Printability of photo-sensitive nanocomposites using two-photon polymerization." Nanotechnology Reviews 9, no. 1 (2020): 418–26. http://dx.doi.org/10.1515/ntrev-2020-0031.

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AbstractTwo-photon polymerization direct laser writing (TPP DLW) is an emerging technology for producing advanced functional devices with complex three-dimensional (3D) micro-structures. Tremendous efforts have been devoted to developing two-photon polymerizable photo-sensitive nanocomposites with tailored properties. Light-induced reconfigurable smart materials such as liquid crystalline elastomers (LCEs) are promising materials. However, due to the difficulties in designing two-photon polymerizable liquid crystal monomer (LCM) nanocomposite photoresists, it is challenging to fabricate true 3

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43

Li, Shu, Jia Li, Jun Xing, Ling Li, Long Wang, and Cai Wang. "Development and Characterization of Hyaluronic Acid Graft-Modified Polydopamine Nanoparticles for Antibacterial Studies." Polymers 17, no. 2 (2025): 162. https://doi.org/10.3390/polym17020162.

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The problem of antibiotic abuse and drug resistance is becoming increasingly serious. In recent years, polydopamine (PDA) nanoparticles have been recognized as a potential antimicrobial material for photothermal therapy (PTT) due to their excellent photothermal conversion efficiency and unique antimicrobial ability. PDA is capable of rapidly converting light energy into heat energy under near-infrared (NIR) light irradiation to kill bacteria efficiently. In order to solve the problem of PDA’s tendency to aggregate and precipitate, this study improved its stability by grafting hyaluronic acid (

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44

Gachet, Benoit, Maxime Lecompère, Céline Croutxé-Barghorn, Dominique Burr, Gildas L'Hostis, and Xavier Allonas. "Highly reactive photothermal initiating system based on sulfonium salts for the photoinduced thermal frontal cationic polymerization of epoxides: a way to create carbon-fiber reinforced polymers." RSC Advances 10, no. 68 (2020): 41915–20. http://dx.doi.org/10.1039/d0ra07561b.

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45

Reyes-Mateo, Kevin, Jordi Marquet Cortes, Jordi Hernando, and Rosa-Maria Sebastian. "Photothermal polymerization of benzoxazines." Polymer Chemistry, 2022. http://dx.doi.org/10.1039/d2py00635a.

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Despite the use of catalysts and initiators, high polymerization temperatures are typically required for polybenzoxazines, a severe constraint for their general application as high performance thermosets. In this work we...

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46

Hu, Cunjie, Hui Chen, Jing Zheng, et al. "Interfacial Polymerization Fabricated Polydopamine Capsules as a Step Toward a Photothermal Protocell Model." Advanced Functional Materials, August 25, 2024. http://dx.doi.org/10.1002/adfm.202412408.

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AbstractPhotothermal is a significant solar energy conversion process on Earth, and photothermal‐responsive protocells are a potential model for prebiotic chemistry. Here, polydopamine microcapsules are fabricated via emulsion droplets‐templated interfacial polymerization and investigated their potential as synthetic protocell models for photothermal conversion and utilization. DNAzyme‐mediated dopamine peroxidation and polymerization occur at the water/oil interface of the emulsion droplets, facilitated by a biphasic microfluidic technique, leading to the formation of uniform polydopamine mic

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Yang, Ning, Yuetong Kang, Jiaren Liu, et al. "Photothermal Miniemulsion Polymerization by Amphiphilic Gold Nanoclusters." Chemistry – An Asian Journal, December 23, 2024. https://doi.org/10.1002/asia.202401194.

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Gold nanoclusters (AuNCs), which are approximately 2 nm in size, exhibit distinctive photophysical and catalytic properties, but their performance is often compromised by environmental factors. To mitigate these challenges, attempts have been made to incorporate AuNCs into polymer matrices to enhance their stability. Miniemulsion polymerization has proven to be an effective method for fabricating organic‐inorganic composites. Here, we present a facile photothermal‐assisted method for miniemulsion polymerization utilizing AuNCs, which serve as co‐stabilizers of the emulsion and photothermal con

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Lee, Chaewon, Jin Hyeok Park, Mina Kim, Jong Sik Kim, and Tae Soup Shim. "Fabrication of Tunable Photothermal Actuator via In-Situ Oxidative Polymerization of Polydopamine Nanoparticles in Hydrogel Bilayers." Soft Matter, 2022. http://dx.doi.org/10.1039/d2sm00420h.

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Photothermally triggered actuation enables the remote and local control of a material. The complex actuation can be achieved by controlling the photothermal efficiency of the material, which is crucial for...

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Koizumi, Rin, Yuya Atsuta, Anne‐Laure Fameau, et al. "Stearic Acid as Polymerization Medium, Dopant and Hydrophobizer: Chemical Oxidative Polymerization of Pyrrole." Macromolecular Rapid Communications, October 3, 2024. http://dx.doi.org/10.1002/marc.202400448.

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AbstractIn recent years, fatty acids have garnered significant attention as a natural phase‐change material and a hydrophobizer due to their biocompatibility and biodegradability. In this study, the utilization of fatty acid is proposed as a polymerization medium for the first time. As a specific reaction, chemical oxidative polymerizations of pyrrole is conducted using ferric chloride as an oxidant in a stearic acid medium. The polymerizations resulted in the production of micrometer‐sized polypyrrole (PPy) grains, which are aggregates of atypical primary particles with submicrometer size. Th

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Tian, Liang, Lihua Han, Fang Wang, et al. "Dynamic Water Microskin Induced by Photothermally Responsive Interpenetrating Hydrogel Networks for High‐Performance Light‐Tracking Water Evaporation." Advanced Energy Materials, October 26, 2024. http://dx.doi.org/10.1002/aenm.202404117.

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AbstractSolar‐driven interfacial water evaporation is attracting increasing attention as a promising environmentally‐friendly solution to freshwater scarcity. It has been proven that a thin water layer on photothermal materials can prevent solar energy from invalidly heating the excess water to enhance the evaporation rate. However, the current water layers are usually formed on inelastic materials via confined capillarity, which are static and uncontrollable. Herein, we propose a flexible hydrogel‐based photothermal conversion material with thermal responsiveness by facile frontal polymerizat

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