To see the other types of publications on this topic, follow the link: Phthalate Anions.

Journal articles on the topic 'Phthalate Anions'

Create a spot-on reference in APA, MLA, Chicago, Harvard, and other styles

Select a source type:

Consult the top 50 journal articles for your research on the topic 'Phthalate Anions.'

Next to every source in the list of references, there is an 'Add to bibliography' button. Press on it, and we will generate automatically the bibliographic reference to the chosen work in the citation style you need: APA, MLA, Harvard, Chicago, Vancouver, etc.

You can also download the full text of the academic publication as pdf and read online its abstract whenever available in the metadata.

Browse journal articles on a wide variety of disciplines and organise your bibliography correctly.

1

Poleti, Dejan, and Jelena Rogan. "Dirubidium hexaaquacobalt(II) tetrakis(hydrogen phthalate) tetrahydrate and coordination modes of the hydrogen phthalate anion." Acta Crystallographica Section C Crystal Structure Communications 69, no. 8 (2013): 841–46. http://dx.doi.org/10.1107/s0108270113016788.

Full text
Abstract:
The title compound, Rb2[Co(H2O)6](C8H5O4)4·4H2O, consists of nearly regular octahedral [Co(H2O)6]2+cations with the CoIIcations on the inversion centre (special position 2a), Rb+cations, hydrogen phthalate (Hpht−) anions and disordered water molecules. The Rb+cation is surrounded by nine O atoms from Hpht−anions and water molecules, with a strongly deformed pentagonal–bipyramidal geometry and one apex split into three positions. The crystal packing is governed by numerous hydrogen bonds involving all water molecules and Hpht−anions. In this way, layers parallel to theabplane are formed, with t
APA, Harvard, Vancouver, ISO, and other styles
2

Mirocki, Artur, and Artur Sikorski. "The Influence of Solvent on the Crystal Packing of Ethacridinium Phthalate Solvates." Materials 13, no. 22 (2020): 5073. http://dx.doi.org/10.3390/ma13225073.

Full text
Abstract:
The synthesis, structural characterization and influence of solvents on the crystal packing of solvated complexes of ethacridine with phthalic acid: 6,9-diamino-2-ethoxyacridinium phthalate methanol solvate (1), 6,9-diamino-2-ethoxyacridinium phthalate ethanol solvate (2), 6,9-diamino-2-ethoxyacridinium phthalate isobutanol solvate (3), and 6,9-diamino-2-ethoxyacridinium phthalate tert-butanol solvate monohydrate (4) are described in this article. Single-crystal XRD measurements revealed that the compounds 1–4 crystallized in the triclinic P-1 space group, and the 6,9-diamino-2-ethoxyacridiniu
APA, Harvard, Vancouver, ISO, and other styles
3

Smith, Graham, Urs D. Wermuth, and Jonathan M. White. "2,3-Dimethoxy-10-oxostrychnidinium 2-carboxy-4,5-dichlorobenzoate." Acta Crystallographica Section E Structure Reports Online 63, no. 11 (2007): o4276—o4277. http://dx.doi.org/10.1107/s1600536807047952.

Full text
Abstract:
The structure of the title compound, C23H27N2O4 +·C8H3Cl2O4 −, a 1:1 proton-transfer compound of brucine with 4,5-dichlorophthalic acid, has been determined at 130 K. The brucinium cations and the hydrogen phthalate anions associate through single N—H...Ocarboxylate hydrogen bonds [2.639 (3) Å], giving dimers which are extended via weak head-to-tail C—H...Omethoxy associations into chains forming down the 21 screw axis of the unit cell. The carboxyl proton of the anion gives a short intramolecular O—H...Ocarboxylate hydrogen bond [2.441 (3) Å].
APA, Harvard, Vancouver, ISO, and other styles
4

Skupiński, Sebastian, Marta Kalbarczyk, Daniel Kamiński, and Marek Kosmulski. "Surface Chemistry Aspects of Ion Exchange in Basic Copper Salts." Molecules 30, no. 1 (2024): 21. https://doi.org/10.3390/molecules30010021.

Full text
Abstract:
Brochantite was precipitated using stoichiometric amounts of CuSO4 and NaOH and characterized by scanning electron microscopy, specific surface area, thermogravimetric analysis, and zeta potential. Brochantite can be converted into paratacamite, basic copper bromide, and copper phthalate by shaking the powder with solutions containing excess corresponding anions. By contrast, attempts to convert brochantite into basic iodide, acetate, nitrate, or rhodanide in a similar way failed, that is, the powder after shaking with solutions containing excess corresponding anions still showed the powder X-
APA, Harvard, Vancouver, ISO, and other styles
5

Harvey, Miguel Angel, Sebastián Suarez, Fabio Doctorovich, Fabio D. Cukiernik, and Ricardo Baggio. "The structure of {[Co(pht)(bpy)(H2O)]·3H2O} n (pht is phthalate and bpy is 4,4′-bipyridine) and the role of solvent water clusters in structure stability." Acta Crystallographica Section C Structural Chemistry 70, no. 5 (2014): 440–44. http://dx.doi.org/10.1107/s2053229614006950.

Full text
Abstract:
The CoII cation in poly[[aqua(μ-benzene-1,2-dicarboxylato-κ3 O 1,O 2:O 1)(μ-4,4′-bipyridine-κ2 N:N′)cobalt(II)] trihydrate], {[Co(C8H4O4)(C10H8N2)(H2O)]·3H2O} n , is octahedrally coordinated by two N atoms of two 4,4′-bipyridine ligands, three O atoms from phthalate anions and a fourth O atom from a coordinated water molecule. The packing consists of planes of coordination polymers linked by hydrogen bonds mediated by three solvent water molecules; the linkage is achieved by the water molecules forming intricate oligomeric clusters which also involve the O atoms of the phthalate ligands.
APA, Harvard, Vancouver, ISO, and other styles
6

Khan, Mohd Farhan, Jawed Mustafa, Faez Qahtani, et al. "Inorganic Nitrate Determination Employing Co(II) Complex Potentiometry." Science of Advanced Materials 16, no. 5 (2024): 606–13. http://dx.doi.org/10.1166/sam.2024.4672.

Full text
Abstract:
The research presented here describes the development of membranes made of polymeric materials with unique cobalt(II) complexes to identify nitrate anions in water. The authors of the study precisely coordinated cobalt(II) ions with a neutral tetradentate ligand known as N,N-Ethylene bis(Salicylideneaminato) to develop an efficient anion-binding carrier with nitrate sensitivity. Good nitrate specificity was accomplished by incorporating these Co(II) complexes onto membranes alongside the plasticizer dibutyl phthalate (DBP). The improved Co(II)-based sensors achieved near-Nernstian response slo
APA, Harvard, Vancouver, ISO, and other styles
7

Perrin, Charles L., and Jonathan S. Lau. "Hydrogen-Bond Symmetry in Zwitterionic Phthalate Anions: Symmetry Breaking by Solvation." Journal of the American Chemical Society 128, no. 36 (2006): 11820–24. http://dx.doi.org/10.1021/ja063797o.

Full text
APA, Harvard, Vancouver, ISO, and other styles
8

Bai, Shuqin, Lingling Zhang, Wei Ding, Gaowa Naren, and Takushi Yokoyama. "Accelerating effect of salicylate and phthalate anions on silica particle formation." Colloid and Polymer Science 294, no. 9 (2016): 1431–37. http://dx.doi.org/10.1007/s00396-016-3889-4.

Full text
APA, Harvard, Vancouver, ISO, and other styles
9

Stathakis, Costas, and Richard M. Cassidy. "Control of relative migration of small inorganic and organic anions with cyclodextrins in capillary electrophoresis (CE)." Canadian Journal of Chemistry 76, no. 2 (1998): 194–98. http://dx.doi.org/10.1139/v97-230.

Full text
Abstract:
The capillary electrophoretic separation of iodide, nitrate, perchlorate, thiocyanate, bromate, iodate, and ethane-, butane-, pentane-, and octanesulphonate was examined in sodium chromate or potassium hydrogen phthalate electrolytes and in the presence of α -, γ -, (0-40 mmol/L) and β -cyclodextrin (0-10 mmol/L). Largest decreases in electrophoretic mobility were observed for iodide, perchlorate, and thiocyanate, probably due to inclusion of these anions in the cyclodextrin (CD) cavity. Changes in migration patterns and electroosmotic flow were observed, which depended on cyclodextrin type an
APA, Harvard, Vancouver, ISO, and other styles
10

Song, Ye, Lin Liu, Xufei Zhu, et al. "Physicochemical properties of ionic liquids based on imidazolium/pyrrolidinium cations and maleate/phthalate anions." Solid State Ionics 179, no. 13-14 (2008): 516–21. http://dx.doi.org/10.1016/j.ssi.2008.03.035.

Full text
APA, Harvard, Vancouver, ISO, and other styles
11

Lenik, Joanna, and Cecylia Wardak. "Properties of ibuprofen ion-selective electrodes based on the ion pair complex of tetraoctylammonium cation." Open Chemistry 8, no. 2 (2010): 382–91. http://dx.doi.org/10.2478/s11532-010-0005-3.

Full text
Abstract:
AbstractIbuprofen membrane electrodes based on different plasticizers: diisobutyl phthalate (DIBP), o-nitrophenyloctyl ether (o-NPOE), dioctyl sebacate (DOS) and tetraoctylammonium 2-(4-isobutylphenyl)propionate were prepared. All electrodes show: a near Nernstian slope of characteristic (58.3–60.9 mV decade−1) in the measurement range (10−4–10−1 mol L−1), limit of detection (5.0×10−5 mol L−1), really long lifetime (12 months), dependence of the electrode potential on pH (5.5–9.0), reproducibility of potential (0.6–1.2 mV) and selectivity coefficients in relation to some organic and inorganic
APA, Harvard, Vancouver, ISO, and other styles
12

Smith, Graham, Urs D. Wermuth, and Jonathan M. White. "Zero-, one- and two-dimensional hydrogen-bonded structures in the 1:1 proton-transfer compounds of 4,5-dichlorophthalic acid with the monocyclic heteroaromatic Lewis bases 2-aminopyrimidine, nicotinamide and isonicotinamide." Acta Crystallographica Section C Crystal Structure Communications 65, no. 3 (2009): o103—o107. http://dx.doi.org/10.1107/s0108270109004405.

Full text
Abstract:
The structures of the anhydrous 1:1 proton-transfer compounds of 4,5-dichlorophthalic acid (DCPA) with the monocyclic heteroaromatic Lewis bases 2-aminopyrimidine, 3-(aminocarbonyl)pyridine (nicotinamide) and 4-(aminocarbonyl)pyridine (isonicotinamide), namely 2-aminopyrimidinium 2-carboxy-4,5-dichlorobenzoate, C4H6N3+·C8H3Cl2O4−, (I), 3-(aminocarbonyl)pyridinium 2-carboxy-4,5-dichlorobenzoate, C6H7N2O+·C8H3Cl2O4−, (II), and the unusual salt adduct 4-(aminocarbonyl)pyridinium 2-carboxy-4,5-dichlorobenzoate–methyl 2-carboxy-4,5-dichlorobenzoate (1/1), C6H7N2O+·C8H3Cl2O4−·C9H6Cl2O4, (III), have
APA, Harvard, Vancouver, ISO, and other styles
13

Jeon, Jong Yeob, Seong Chan Eo, Jobi Kodiyan Varghese, and Bun Yeoul Lee. "Copolymerization and terpolymerization of carbon dioxide/propylene oxide/phthalic anhydride using a (salen)Co(III) complex tethering four quaternary ammonium salts." Beilstein Journal of Organic Chemistry 10 (August 5, 2014): 1787–95. http://dx.doi.org/10.3762/bjoc.10.187.

Full text
Abstract:
The (salen)Co(III) complex 1 tethering four quaternary ammonium salts, which is a highly active catalyst in CO2/epoxide copolymerizations, shows high activity for propylene oxide/phthalic anhydride (PO/PA) copolymerizations and PO/CO2/PA terpolymerizations. In the PO/PA copolymerizations, full conversion of PA was achieved within 5 h, and strictly alternating copolymers of poly(1,2-propylene phthalate)s were afforded without any formation of ether linkages. In the PO/CO2/PA terpolymerizations, full conversion of PA was also achieved within 4 h. The resulting polymers were gradient poly(1,2-pro
APA, Harvard, Vancouver, ISO, and other styles
14

Matveichuk, Yulya V. "EFFECT OF NATURE OF PLASTICIZER ON CHARACTERISTICS OF ION-SELECTIVE ELECTRODES REVERSIBLE TO DOUBLY CHARGED INORGANIC ANIONS." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 63, no. 1 (2019): 18–22. http://dx.doi.org/10.6060/ivkkt.20206301.6019.

Full text
Abstract:
A study of the effect of the nature of the plasticizer on the characteristics (lower detection limit and selectivity) of electrodes that are reversible to carbonate, hydrogen phosphate, sulfate, selenate, selenite, sulfite, molybdate, tungstate, and thiosulfate ions was carried out. It was found that the membranes of carbonate and hydrophosphate selective electrodes based on quaternary ammonium salts are preferable to plasticize with o-nitrophenyl decyl ether, membranes of sulfate, selenate, selenite-selective electrodes - 1-bromonaphthalene, sulfite, molybdate, tungstate, and thiosulfate sele
APA, Harvard, Vancouver, ISO, and other styles
15

ZHANG, Mingyu, and Jingwu KANG. "Determination of anions in low molecular weight heparin by capillary electrophoresis with phthalate as the background electrolyte." Chinese Journal of Chromatography 35, no. 1 (2017): 59. http://dx.doi.org/10.3724/sp.j.1123.2016.08034.

Full text
APA, Harvard, Vancouver, ISO, and other styles
16

Perrin, Charles L., and John D. Thoburn. "Evidence for a double-minimum potential for intramolecular hydrogen bonds of aqueous hydrogen maleate and hydrogen phthalate anions." Journal of the American Chemical Society 111, no. 20 (1989): 8010–12. http://dx.doi.org/10.1021/ja00202a050.

Full text
APA, Harvard, Vancouver, ISO, and other styles
17

Ito, Kazuaki. "Separation behavior of inorganic anions on an octadecyl-bonded silica column coated with cetyltrimethylammonium by phthalate and salicylate eluents." Journal of Chromatography A 764, no. 2 (1997): 346–49. http://dx.doi.org/10.1016/s0021-9673(96)00887-4.

Full text
APA, Harvard, Vancouver, ISO, and other styles
18

Panda, Antarjyami, and Nimai C. Naik. "Effect of ion-pairing on the solvolytic aquation of bromopentaamminecobalt(III) ion in the presence of maleate and phthalate anions." Transition Metal Chemistry 14, no. 6 (1989): 439–42. http://dx.doi.org/10.1007/bf01092585.

Full text
APA, Harvard, Vancouver, ISO, and other styles
19

Nagaraju, Rajendra Prasad. "Use of sodium tetraphenyl boron for fabrication of potentiometric membrane sensor for the assay of olanzapine in pharmaceuticals and human urine." Applied Chemical Engineering 3, no. 2 (2020): 1. http://dx.doi.org/10.24294/ace.v3i2.179.

Full text
Abstract:
Olanzapine (OLP), chemically known as 2-Methyl-10-(4-methyl-piperazin-1-yl)-4H-3-thia-4, 9-diaza-benzo[f]azulene, is an atypical antipsychotic drug. It is used for the treatment of schizophrenia and bipolar disorder. A new simple and selective membrane based potentiometric sensor was developed for potentiometric determination of olanzapine. The membrane was constructed using an ion-pair of OLP and sodium tetraphenyl boron in dioctyl phthalate and PVC. The membrane provides good linear Nernstian response covering relatively wide concentration range of 4 × 10-6 - 1 × 10-2 M OLP over pH range of
APA, Harvard, Vancouver, ISO, and other styles
20

Millange, Franck, Richard I. Walton, Lixu Lei, and Dermot O‘Hare. "Efficient Separation of Terephthalate and Phthalate Anions by Selective Ion-Exchange Intercalation in the Layered Double Hydroxide Ca2Al(OH)6·NO3·2H2O." Chemistry of Materials 12, no. 7 (2000): 1990–94. http://dx.doi.org/10.1021/cm0002057.

Full text
APA, Harvard, Vancouver, ISO, and other styles
21

Russell, RA, BA Pilley, RW Irvine, and RN Warrener. "Anthracyclines. XVI. Further Comments Concerning the Phthalide Anion Annelation of Quinone Monoacetals." Australian Journal of Chemistry 40, no. 2 (1987): 311. http://dx.doi.org/10.1071/ch9870311.

Full text
Abstract:
.Yields of tricyclic and tetracyclic quinones prepared by annelation of quinone monoacetals with the anion of 3-phenylsulfonylphthalides are shown to be sensitive to the substituent on both the phthalide and the quinone monoacetal partner. In contrast, reactions with the anions of 3-cyanophthalides afford high yields of condensed products in all cases examined.
APA, Harvard, Vancouver, ISO, and other styles
22

Egestad, Börje, and Per Sjöberg. "Radical molecular anions formed from organic molecules under negative-ion fast-atom bombardment conditions: An unexpected finding during studies on the metabolism of bis(2-ethylhexyl) phthalate." Rapid Communications in Mass Spectrometry 7, no. 9 (1993): 812–14. http://dx.doi.org/10.1002/rcm.1290070906.

Full text
APA, Harvard, Vancouver, ISO, and other styles
23

Lo, I. M. C., H. M. Liljestrand, J. Khim, and Y. Shimizu. "Clay liner materials for land disposal of hazardous non-metal wastes." Water Science and Technology 33, no. 8 (1996): 71–77. http://dx.doi.org/10.2166/wst.1996.0154.

Full text
Abstract:
Simple land disposal systems for hazardous and mixed wastes contain heavy metal cationic species through precipitation and ion exchange mechanisms but typically fail by releasing soluble organic and inorganic anionic species. To enhance the removal of anions from leachate, clays are modified with coatings of iron or aluminium cations to bridge between the anionic surface and the anionic pollutants. A competitive surface ligand exchange model indicates that surface coatings of 10 meq cation/gm montmorillonite under typical leachate conditions increase the inorganic anion sorption capacity by at
APA, Harvard, Vancouver, ISO, and other styles
24

Usubaliev, B. T. "COORDINATION POLYMER OF STRONTIUM (II) BASED ON PHTHALIC ACID AND PYRAZINE ADDUCT." Azerbaijan Chemical Journal, no. 3 (September 22, 2022): 57–62. http://dx.doi.org/10.32737/0005-2531-2022-3-57-62.

Full text
Abstract:
The coordination polymer of Sr (II), with the chemical formula of {SrL1 (L2)0.5·(H2O)0.36}n (L1 = phthalic acid anion and L2 = pyrazine), have been synthesized by the interaction of sodium phthalate with a water-soluble strontium salt and pyrazine in the aqueous medium with further evaporation of an aqueous solution and characterized by IR spectroscopic, elemental, single-crystal X-ray diffraction and thermal analysis. The results of XRD analysis showed that the synthesis product has a single-phase and is well-identified by means: 12.73; 11.41; 9.04 showing that the unit cell parameters of thi
APA, Harvard, Vancouver, ISO, and other styles
25

Shahid, Muhammad, Muhammad Nawaz Tahir, Muhammad Salim, and Munawar Ali Munawar. "Crystal structure of 3,4-dichloroanilinium hydrogen phthalate." Acta Crystallographica Section E Crystallographic Communications 71, no. 7 (2015): o446. http://dx.doi.org/10.1107/s2056989015010300.

Full text
Abstract:
In the title salt, C6H6Cl2N+·C8H5O4−, the carboxylic acid and carboxylate groups of the anion form dihedral angles of 20.79 (19) and 74.76 (14)°, respectively, with the plane of the benzene ring. In the crystal, molecules are assembled into a two-dimensional polymeric network parallel to (100)viaN—H...O and O—H...O hydrogen bonds. In addition, within the layer, there are π–π stacking interactions between the benzene rings of the cation and the anion [centroid–centroid distance = 3.6794 (17) Å]. A weak C—H...O interaction is also observed.
APA, Harvard, Vancouver, ISO, and other styles
26

Mitchell, Anthony S., and Richard A. Russell. "Annulation reactions with stabilized phthalide anions." Tetrahedron 51, no. 18 (1995): 5207–36. http://dx.doi.org/10.1016/0040-4020(95)00247-6.

Full text
APA, Harvard, Vancouver, ISO, and other styles
27

Kraus, George A., and Pengfei Dong. "Phthalide Anions in Organic Synthesis. A Direct Total Synthesis of Furomollugin." Natural Product Communications 10, no. 6 (2015): 1934578X1501000. http://dx.doi.org/10.1177/1934578x1501000657.

Full text
APA, Harvard, Vancouver, ISO, and other styles
28

N. Prabha, P. Parthiban, P. Arjun, and J. Bhuvana. "BIOACTIVE COMPOUNDS IDENTIFICATION IN Abutilon Indicum THROUGH GC-MS ANALYSIS AND MOLECULAR DOCKING STUDY." RASAYAN Journal of Chemistry 18, no. 01 (2025): 641–47. https://doi.org/10.31788/rjc.2025.1819010.

Full text
Abstract:
One of the most important medicinal plants of India, Abutilon Indicum, is used for inflammatory joint diseases, ulcers, and scorpion bites, besides being used as antioxidant, laxative, diuretic, analgesic, and antimicrobial agent. The plant leaves’ ethanol extract was analyzed through GC-MS; the secondary metabolites were identified, and the lead molecules were evaluated by molecular docking with liver protein. From the GC-MS analysis, about 20 compounds were identified. Among them, the highest area of about 65% with a retention time (RT) of 10.082 min is for diethyl phthalate, followed by 18%
APA, Harvard, Vancouver, ISO, and other styles
29

Dong, Feilong, Jiayi Cheng, Yifeng Cheng, and Xiaoyan Ma. "Comparison of UV/PAA and VUV/PAA Processes for Eliminating Diethyl Phthalate in Water." Water 16, no. 23 (2024): 3533. https://doi.org/10.3390/w16233533.

Full text
Abstract:
Diethyl phthalate (DEP) is a commonly utilized plasticizer that has gained significant attention due to its widespread occurrence in the environment and its harmful impact on human health. The primary objective of this study was to evaluate and compare several (ultraviolet) UV-(peracetic acid) PAA advanced oxidation processes based on hydroxyl radicals to degrade DEP. The effect of UV-LEDs incorporating PAA at different UV ranges (UV-A, λ = 365 nm; UV-C, λ = 254 nm and VUV, λ = 254 nm) was evaluated. The results demonstrated that DEP was successfully degraded in both the UVC/PAA (removal rate
APA, Harvard, Vancouver, ISO, and other styles
30

Dybczyński, Rajmund S., and Krzysztof Kulisa. "Observations on Ion Interaction Chromatographic System: Reversed Phase Column—H3BO3/TBAOH Mobile Phase and the Effect of Temperature." Chromatographia 83, no. 12 (2020): 1553–60. http://dx.doi.org/10.1007/s10337-020-03963-3.

Full text
Abstract:
Abstract New ion interaction chromatographic (IIC) system with RP column and boric acid plus tetra-n-butylammonium hydroxide (TBAOH) mobile phase was investigated. In the system: CPhenylHexyl—10 mM H3BO3/4 mM TBAOH, a large group of anions viz. F−,IO3−, Cl−, ClO2−, BrO3−, NO2−, Br−, NO3−, ClO3−, I−, HPO42−, SO42−, CrO42−, S2O32−, benzoate−, SCN−, ClO4− and phthalate2−, could be isocratically resolved. A study on the effect of temperature revealed that some ions added to ion exchange are also held in the stationary phase by the hydrophobic adsorption. The retention loss for all anions with time
APA, Harvard, Vancouver, ISO, and other styles
31

MITCHELL, A. S., and R. A. RUSSELL. "ChemInform Abstract: Annulation Reaction with Stabilized Phthalide Anions." ChemInform 26, no. 36 (2010): no. http://dx.doi.org/10.1002/chin.199536322.

Full text
APA, Harvard, Vancouver, ISO, and other styles
32

Boileau, L. J. R., E. Nieboer, and D. H. S. Richardson. "Uranium accumulation in the lichen Cladonia rangiferina. Part I. Uptake of cationic, neutral, and anionic forms of the uranyl ion." Canadian Journal of Botany 63, no. 3 (1985): 384–89. http://dx.doi.org/10.1139/b85-045.

Full text
Abstract:
Evidence from published work is first reviewed to show that cationic, neutral, and anionic complexes of the uranyl ion are available to plants growing in uranium-enriched environments. The results of a study on the uptake of uranyl ions by the lichen Cladonia rangiferina L. Wigg. are then presented. Uptake was examined from three different uranyl solutions each predominantly containing a single species: namely, the cation [Formula: see text] (in distilled water), the neutral 1:1 complex with phthalate (UO2L), and the anionic complex of oxalate [Formula: see text]. Uptake decreased along the ch
APA, Harvard, Vancouver, ISO, and other styles
33

Siva, V., M. Suresh, S. Athimoolam, and S. Asath Bahadur. "Crystal structure and Hirshfeld surface analysis of 2-aminopyridinium hydrogen phthalate." Acta Crystallographica Section E Crystallographic Communications 75, no. 11 (2019): 1627–31. http://dx.doi.org/10.1107/s2056989019012957.

Full text
Abstract:
Aminopyridine and phthalic acid are well known synthons for supramolecular architectures for the synthesis of new materials for optical applications. The 2-aminopyridinium hydrogen phthalate title salt, C5H7N2 +·C8H5O4 −, crystallizes in the non-centrosymmetric space group P21. The nitrogen atom of the –NH2 group in the cation deviates from the fitted pyridine plane by 0.035 (7) Å. The plane of the pyridinium ring and phenyl ring of the anion are oriented at an angle of 80.5 (3)° to each other in the asymmetric unit. The anion features a strong intramolecular O—H...O hydrogen bond, forming a s
APA, Harvard, Vancouver, ISO, and other styles
34

Warneke, Jonas, Martin Mayer, Markus Rohdenburg, et al. "Direct functionalization of C−H bonds by electrophilic anions." Proceedings of the National Academy of Sciences 117, no. 38 (2020): 23374–79. http://dx.doi.org/10.1073/pnas.2004432117.

Full text
Abstract:
Alkanes and [B12X12]2−(X = Cl, Br) are both stable compounds which are difficult to functionalize. Here we demonstrate the formation of a boron−carbon bond between these substances in a two-step process. Fragmentation of [B12X12]2−in the gas phase generates highly reactive [B12X11]−ions which spontaneously react with alkanes. The reaction mechanism was investigated using tandem mass spectrometry and gas-phase vibrational spectroscopy combined with electronic structure calculations. [B12X11]−reacts by an electrophilic substitution of a proton in an alkane resulting in a B−C bond formation. The
APA, Harvard, Vancouver, ISO, and other styles
35

Chen, Fangmin, Chichi Zhou, Yan Li, and Xiuqing Zhang. "Syntheses, crystal structures, and fluorescent properties of three coordination polymers with 5-sulfoisophthalic acid anion and 4-phenylpyridine." Journal of Chemical Research 45, no. 11-12 (2021): 1052–58. http://dx.doi.org/10.1177/17475198211055089.

Full text
Abstract:
Three coordination polymers—{[Ag2(SIP)(4-pp)]·[Ag(4-pp)2]·H2O}n, [Pb4(SIP)2( μ3-OH)2(H2O)2]n, and {[Zn2(SIP)2(4-pp)4][Zn(4-pp)2(H2O)4]·4H2O}n (SIP = 5-sulfoisophthalic acid anion, 4-pp = 4-phenylpyridine)—are constructed under hydrothermal or solvothermal conditions using sodium m-phthalate 5-sulfonate (NaH2SIP) and 4-phenylpyridine as ligands. The structures of the three complexes are determined by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analyses, Fourier-transform infrared analysis, and photoluminescence. The fluorescent properties of the complexes in th
APA, Harvard, Vancouver, ISO, and other styles
36

Bahrami, Salar, Leila Dolatyari, Hassan Shayani-Jam, Mohammad Reza Yaftian, and Spas D. Kolev. "On the Potential of a Poly(vinylidenefluoride-co-hexafluoropropylene) Polymer Inclusion Membrane Containing Aliquat® 336 and Dibutyl Phthalate for V(V) Extraction from Sulfate Solutions." Membranes 12, no. 1 (2022): 90. http://dx.doi.org/10.3390/membranes12010090.

Full text
Abstract:
A polymer inclusion membrane (PIM) composed of 50 wt% base polymer poly(vinylidenefluoride-co-hexafluoropropylene), 40 wt% extractant Aliquat® 336, and 10 wt% dibutyl phthalate as plasticizer/modifier provided the efficient extraction of vanadium(V) (initial concentration 50 mg L−1) from 0.1 M sulfate solutions (pH 2.5). The average mass and thickness of the PIMs (diameter 3.5 cm) were 0.057 g and 46 μm, respectively. It was suggested that V(V) was extracted as VO2SO4− via an anion exchange mechanism. The maximum PIM capacity was estimated to be ~56 mg of V(V)/g for the PIM. Quantitative back-
APA, Harvard, Vancouver, ISO, and other styles
37

Xu, Zhengwen, Yunlong Zhao, Jing Shi, Jiangang Lu, Ling Cheng, and Mindong Chen. "Adsorption of Monobutyl Phthalate from Aqueous Phase onto Two Macroporous Anion-Exchange Resins." Journal of Chemistry 2014 (2014): 1–5. http://dx.doi.org/10.1155/2014/689734.

Full text
Abstract:
As new emerging pollutants, phthalic acid monoesters (PAMs) pose potential ecological and human health risks. In the present study, adsorption performance of monobutyl phthalate (MBP) onto two macroporous base anion-exchange resins (D-201 and D-301) was discussed. It was found that the adsorption isotherms were best fitted by the Langmuir equation while the adsorption kinetics were well described by pseudo-first-order model. Analyses of sorption isotherms and thermodynamics proved that the adsorption mechanisms for DBP onto D-201 were ion exchange. However, the obtained enthalpy values indicat
APA, Harvard, Vancouver, ISO, and other styles
38

OHKI, Akira, Masanobu YAMURA, Yuko SUMIYOSHI, Makoto TAKAGI, and Shigeru MAEDA. "Solvent extraction of phthalate isomer dianions by the use of dicationic anion-exchange extractants." Analytical Sciences 6, no. 2 (1990): 291–94. http://dx.doi.org/10.2116/analsci.6.291.

Full text
APA, Harvard, Vancouver, ISO, and other styles
39

Ma, Qing Zhi, Wan Xi Peng, Dang Quan Zhang, Qi Mei Liu, and Yi Qiang Wu. "Study on Healthful Function of Superheated Water Extractives of Phyllostachys Heterocycla by GC/MS." Materials Science Forum 575-578 (April 2008): 1320–24. http://dx.doi.org/10.4028/www.scientific.net/msf.575-578.1320.

Full text
Abstract:
The chemical components from superheated water extractive of fresh Phyllostachys heterocycla shavings were separated and identified by GC/MS after enriched. Relative content of each component was determined by area normalization. 31 compounds representing 99.99% of the extractives were identified. The main and abundant constituents were as: heptacosane (35.37%), 2,2,4-trimethyl-3- (3,8,12,16-tetramethyl-heptadeca-3,7,11,15-tetraenyl)-cyclohexanol (16.25%), isochiapin B (12.24%), tetradecane, 2,6,10-trimethyl- (cas) (7.59%), dibutyl phthalate (5.66%), etratriacontane (cas) (4.89%), 1,2-benzened
APA, Harvard, Vancouver, ISO, and other styles
40

Janowski, WK, та RH Prager. "The Chemistry of Phthalide-3-carboxylic Acid. III. Decarboxylation of Salts in the Presence of α,Β-Unsaturated Ketones". Australian Journal of Chemistry 38, № 6 (1985): 921. http://dx.doi.org/10.1071/ch9850921.

Full text
Abstract:
Potassium phthalide-3-carboxylate (3-oxo-1,3-dihydroisobenzofuran-1- carboxylate ) decarboxylates readily in dimethyl sulfoxide at 145°, and the intermediate phthalidyl anion is efficiently trapped by α,β - unsaturated ketones. The major 1,4-addition product is accompanied by smaller amounts of an isomeric product formed by subsequent cyclization and rearrangement, and sometimes traces of a 1 : 2 1,4-addition product. The caesium salt gives slightly more cyclized product, and the lithium salt undergoes very slow decarboxylation. The synthetic usefulness of the salt decarboxylation is compared
APA, Harvard, Vancouver, ISO, and other styles
41

Garcia-Viloca, Mireia, Àngels González-Lafont, and José M. Lluch. "Asymmetry of the Hydrogen Bond of Hydrogen Phthalate Anion in Solution. A QM/MM Study." Journal of the American Chemical Society 121, no. 39 (1999): 9198–207. http://dx.doi.org/10.1021/ja9918831.

Full text
APA, Harvard, Vancouver, ISO, and other styles
42

Brimble, Margaret, and Kris Rathwell. "Use of Stabilized Phthalide Anion Annulation Reactions in Synthesis: An Update." Synthesis 2007, no. 5 (2007): 643–62. http://dx.doi.org/10.1055/s-2007-965915.

Full text
APA, Harvard, Vancouver, ISO, and other styles
43

Volnyanska, O. V., M. O. Mironyak, O. V. Labyak, and M. V. Nikolenko. "Ionometric sensor for express determination of hexamethylenetetramine." Voprosy Khimii i Khimicheskoi Tekhnologii, no. 5 (October 2022): 33–37. http://dx.doi.org/10.32434/0321-4095-2022-144-5-33-37.

Full text
Abstract:
The article is devoted to the development of an ionometric sensor for the determination of hexamethylenetetramine (HMTA). It was found that poorly soluble complex compounds with the composition (HMTA)3(PMo12O40)2 and (HMTA)3(PW12O40)2 are formed as a result of the interaction of the cation of the test substance with the anions of heteropoly acids. The obtained compounds were used as electrode active substances for polyvinyl chloride membranes of ionometric sensors. Phthalic acid derivatives (dibutyl and dioctyl phthalates) were used as solvents for plasticized membranes. The optimal compositio
APA, Harvard, Vancouver, ISO, and other styles
44

Park, Jong-Hyeok, and Jin-Soo Park. "KOH-doped Porous Polybenzimidazole Membranes for Solid Alkaline Fuel Cells." Energies 13, no. 3 (2020): 525. http://dx.doi.org/10.3390/en13030525.

Full text
Abstract:
In this study the preparation and properties of potassium hydroxide-doped meta-polybenzimidazole membranes with 20–30 μm thickness are reported as anion conducting polymer electrolyte for application in fuel cells. Dibutyl phthalate as porogen forms an asymmetrically porous structure of membranes along thickness direction. One side of the membranes has a dense skin layer surface with 1.5–15 μm and the other side of the membranes has a porous one. It demonstrated that ion conductivity of the potassium hydroxide-doped porous membrane with the porogen content of 47 wt.% (0.090 S cm−1), is 1.4 tim
APA, Harvard, Vancouver, ISO, and other styles
45

Ma, Tingting, Linwei Liu, Wei Zhou, Like Chen, and Peter Christie. "Effects of Phthalate Esters on Ipomoea aquatica Forsk. Seedlings and the Soil Microbial Community Structure under Different Soil Conditions." International Journal of Environmental Research and Public Health 16, no. 18 (2019): 3489. http://dx.doi.org/10.3390/ijerph16183489.

Full text
Abstract:
Phthalate acid esters (PAEs) are the most frequently utilized synthetic chemical compounds worldwide. They are typical emergent contaminants and are currently attracting considerable concern due to their risks to plants, animals, and public health. Determining the vital environmental factors that affect the toxicity of target pollutants in soil is important for vegetable production and the maintenance and control of soil productivity. We investigated the influence of di-n-butyl phthalate (DBP) and bis(2-ethylhexyl) phthalate (DEHP) under different soil conditions on physiological changes in wa
APA, Harvard, Vancouver, ISO, and other styles
46

Yoshida, Hisao, Jun-ichi Nishimoto, Yoshinori Miyashita, et al. "Support Effect of Silica on Photocatalytic Degradation of Dibutyl Phthalate by TiO2Nanoparticles in Water Containing Chloride Anion." Chemistry Letters 32, no. 11 (2003): 1030–31. http://dx.doi.org/10.1246/cl.2003.1030.

Full text
APA, Harvard, Vancouver, ISO, and other styles
47

Henderson, Gary B., and Edward M. Zevely. "Properties of an anion/H+ contransport system in L1210 cells that utilizes phthalate as a nonphysiological substrate." Journal of Membrane Biology 89, no. 1 (1986): 99–106. http://dx.doi.org/10.1007/bf01870899.

Full text
APA, Harvard, Vancouver, ISO, and other styles
48

Xu, Zhengwen, Ling Cheng, Jing Shi, et al. "Kinetic study of the removal of dimethyl phthalate from an aqueous solution using an anion exchange resin." Environmental Science and Pollution Research 21, no. 10 (2014): 6571–77. http://dx.doi.org/10.1007/s11356-014-2556-x.

Full text
APA, Harvard, Vancouver, ISO, and other styles
49

Mironyak, Maria, Olena Volnyanska, Oksana Labyak, Vadym Kovalenko, and Valerii Kotok. "DEVELOPMENT OF A POTENTIOMETRIC SENSOR SENSITIVE TO POLYSORBATE 20." EUREKA: Physics and Engineering 4 (July 31, 2019): 3–9. http://dx.doi.org/10.21303/2461-4262.2019.00942.

Full text
Abstract:
Polyoxyethylated sorbitans (polysorbates) are widely used in the chemical, pharmaceutical, and cosmetic industries, but only quantitative determination is used mainly for chromatographic methods. In this paper, the results of the development and testing of a potentiometric sensor sensitive to nonionic surfactant polyoxyethylene sorbitan monolaurate (polysorbate-20) are presented. An anion of the heterogeneous acid of the Keggin structure (12-molybdophosphate heteropolyacid) was used as a counterion to obtain the electrode-active substance for the potentiometric sensor membrane. Polysorbate-20
APA, Harvard, Vancouver, ISO, and other styles
50

Shi, Qianqian, Aimin Li, Qing Zhou, Chendong Shuang, and Yan Li. "Removal of diethyl phthalate from aqueous solution using magnetic iron–carbon composite prepared from waste anion exchange resin." Journal of the Taiwan Institute of Chemical Engineers 45, no. 5 (2014): 2488–93. http://dx.doi.org/10.1016/j.jtice.2014.05.004.

Full text
APA, Harvard, Vancouver, ISO, and other styles
We offer discounts on all premium plans for authors whose works are included in thematic literature selections. Contact us to get a unique promo code!