Academic literature on the topic 'Phthalocyanines – Derivatives'

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Journal articles on the topic "Phthalocyanines – Derivatives"

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BREGADZE, VLADIMIR I., IGOR B. SIVAEV, DETLEF GABEL, and DIETER WÖHRLE. "Polyhedral boron derivatives of porphyrins and phthalocyanines." Journal of Porphyrins and Phthalocyanines 05, no. 11 (2001): 767–81. http://dx.doi.org/10.1002/jpp.544.

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The synthesis of compounds containing polyhedral boron cages and porphyrin or phthalocyanine units connected covalently in one molecule is reviewed. The importance of these compounds arises, on the one hand, from the use of polyhedral boron derivatives in neutron capture therapy for cancer; on the other hand, porphyrins and phthalocyanines are known as photosensitizers in photodynamic tumor therapy. Current interest in the binding of polyhedral boron compounds to porphyrins and phthalocyanines is due to the observation that porphyrins and phthalocyanines show improved uptake and good persisten
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Awaji, Ayoub, Baybars Köksoy, Mahmut Durmuş, Ateyatallah Aljuhani, and Shaya Alraqa. "Novel Hexadeca-Substituted Metal Free and Zinc(II) Phthalocyanines; Design, Synthesis and Photophysicochemical Properties." Molecules 24, no. 1 (2018): 77. http://dx.doi.org/10.3390/molecules24010077.

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The syntheses of a novel 1,4,8,11,15,18,22,25-octahexyloxy-2,3,9,10,16,17,23,24-octa-(4-trifluoromethoxyphenyl) phthalocyanine (3a) and its zinc(II) phthalocyanine derivative (3b) have been described and characterized by elemental analysis,1H NMR, 13C NMR, 19F NMR, mass, UV-Vis and FT-IR. The newly prepared metal-free phthalocyanine and its zinc(II) counterpart are soluble in most organic solvents. The photophysical and photochemical properties such as aggregation, fluorescence, singlet oxygen generation and photodegradation under light irradiation of these phthalocyanines have been investigat
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Dixon, Dabney W., Anila F. Gill, and Brian R. Sook. "Characterization of sulfonated phthalocyanines by mass spectrometry and capillary electrophoresis." Journal of Porphyrins and Phthalocyanines 08, no. 11 (2004): 1300–1310. http://dx.doi.org/10.1142/s1088424604000672.

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We report the characterization of sulfonated phthalocyanines using capillary electrophoresis and mass spectrometry. Derivatives investigated included the copper, cobalt, zinc and metal-free sulfonated phthalocyanines. In general, sulfonated phthalocyanines were found as aggregates in capillary electrophoresis separations, even at low concentration. Separations were much better at pH 9.0 than at pH 2.5. The addition of β-cyclodextrin did not alter the electropherograms significantly. The electropherograms of commercially available copper phthalocyanine-3,4',4″,4‴-tetrasulfonic acid and 4,4',4″,
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Lam, Herman, Sebastian M. Marcuccio, Polina I. Svirskaya, et al. "Binuclear phthalocyanines with aromatic bridges." Canadian Journal of Chemistry 67, no. 6 (1989): 1087–97. http://dx.doi.org/10.1139/v89-164.

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Three different binuclear phthalocyanines were prepared and characterized. Two of the binuclear phthalocyanines are cofacially linked by rigid naphthalene and anthracene spacers, while the third consists of a direct linkage between two phthalocyanine rings. The dicobalt, dicopper, and dizinc derivatives were prepared by inserting the metal into the metal-free species. The synthesis and the physical and spectroscopic properties of the precursor bisphthalonitriles are also included. Keywords: phthalocyanines, cofacial, binuclear, bisphthalonitriles.
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Mori, Satoru, and Norio Shibata. "Synthesis and application of trifluoroethoxy-substituted phthalocyanines and subphthalocyanines." Beilstein Journal of Organic Chemistry 13 (October 27, 2017): 2273–96. http://dx.doi.org/10.3762/bjoc.13.224.

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Phthalocyanines and subphthalocyanines are attracting attention as functional dyes that are applicable to organic solar cells, photodynamic therapy, organic electronic devices, and other applications. However, phthalocyanines are generally difficult to handle due to their strong ability to aggregate, so this property must be controlled for further applications of phthalocyanines. On the other hand, trifluoroethoxy-substituted phthalocyanines are known to suppress aggregation due to repulsion of the trifluoroethoxy group. Furthermore, the electronic characteristics of phthalocyanines are signif
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Burnham, Paul M., Isabelle Chambrier, David L. Hughes, et al. "Synthesis, lead lability and ring deformation of three 1,4,8,11,15,18,22,25-octasubstituted phthalocyaninato lead derivatives." Journal of Porphyrins and Phthalocyanines 10, no. 10 (2006): 1202–11. http://dx.doi.org/10.1142/s1088424606000570.

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The syntheses and attempted syntheses of some non-peripherally (1,4,8,11,15,18,22,25) octasubstituted lead phthalocyanines from their corresponding metal-free derivatives are described. Some compounds exhibited lability of the lead ion during work-up to regenerate the starting material. The results of single crystal X-ray diffraction analyses of 1,4,8,11,15,18,22,25-octahexyl-, 1,4,8,11,15,18,22,25-octa-iso-pentyl- and 1,4,8,11,15,18,22,25-octahexylsulfanyl lead phthalocyanines are reported and cast some light on the greater stability of 1,4,8,11,15,18,22,25-octahexylsulfanyl lead phthalocyani
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Jin, Shan, Gongzhen Cheng, George Z. Chen, and Zhenping Ji. "Tuning the maximum absorption wavelengths of phthalocyanine derivatives." Journal of Porphyrins and Phthalocyanines 09, no. 01 (2005): 32–39. http://dx.doi.org/10.1142/s1088424605000071.

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A new series of low-symmetry octasubstituted metal-free phthalocyanines with the general formula H 2 N x P β4− x ( OBu )8 ( x = 0-4) were synthesized by mixed condensation of two different substituted precursors (4,5-dibutoxy- phthalonitrile and 1,4-dibutoxy-2,3-dicyanonaphthalene). Their electronic absorption spectra and MALDI-TOF-MS were investigated. The regiospecific, nonlinear and linear substituent effects of alkoxyl groups on the positions of the Q-bands of phthalocyanines with different substituent groups at different peripheral positions were systematically investigated. The results c
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Penon, Oriol, Filippo Marsico, Davide Santucci, Laura Rodríguez, David B. Amabilino, and Lluïsa Pérez-García. "Multiply biphenyl substituted zinc(II) porphyrin and phthalocyanine as components for molecular materials." Journal of Porphyrins and Phthalocyanines 16, no. 12 (2012): 1293–302. http://dx.doi.org/10.1142/s1088424612501453.

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The preparation and physico-chemical characteristics of zinc(II) porphyrin and phthalocyanine derivatives with biphenyl units are reported. These compounds have been prepared as components for molecular electronics systems and rotor-based molecular machines, where the biphenyl units can act as paddles because they are oriented quasi-perpendicularly to the plane of the aromatic macrocycles which would be coordianted through the transition metal ion by an axial ligand. The minimalist design along with the absence of solubilizing groups leads to a low solubility of the compounds in organic solven
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Qian, Yuxin, Bo Liu, Wubiao Duan, and Qingdao Zeng. "Assemblies of porphyrin and phthalocyanine derivatives studied by STM." Journal of Porphyrins and Phthalocyanines 22, no. 09n10 (2018): 717–25. http://dx.doi.org/10.1142/s1088424618500803.

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Porphyrins and phthalocyanines are currently a prevalent topic with great potential due to their abundant photonic/electronic properties. The study of porphyrin or phthalocyanine supramolecular architectures on solid surfaces is laying the foundation for the further development of molecular electronics or other structures in applications. Above all, the invention of scanning tunneling microscopy (STM) has opened a new path to explore these concepts on surfaces. Self-assemblies on solid surfaces can be probed with STM at submolecular resolutions to disclose the conformations and arrangements of
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Araújo, Ana R. L., Augusto C. Tomé, Carla I. M. Santos, et al. "Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines." Molecules 25, no. 7 (2020): 1745. http://dx.doi.org/10.3390/molecules25071745.

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The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, carbon nanotubes, silica nanoparticles, gold nanoparticles, and quantum dots. This approach is also being relevant to conjugate phthalocyanines with carbohydrates and to obtain new sophisticated molecules; in such way, new systems with significant potential applications become available. This review h
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Dissertations / Theses on the topic "Phthalocyanines – Derivatives"

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Maqanda, Weziwe Theorine. "Synthesis, photochemical and photophysical properties of phthalocyanine derivatives." Thesis, Rhodes University, 2005. http://hdl.handle.net/10962/d1007472.

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Substituted zinc and magnesium phthalocyanine and porphyrazine derivatives were synthesized according to the reported procedures. The magnesium and zinc phthalocyanine and porphyrazine derivatives were synthesized by ring enlargement of subphthalocyanine and statistical condensation of the two phthalonitrile derivatives. Characterization of the complexes involved the use of infrared spectroscopy, nuclear magnetic resonance spectroscopy, ultraviolet and visible spectroscopy, and Maldi-TOF spectroscopy (for selected compounds) and elemental analysis. Photochemical and photophysical properties of
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Chauke, Vongani Portia. "Synthesis, photochemical and photophysical properties of gallium and indium phthalocyanine derivatives." Thesis, Rhodes University, 2008. http://eprints.ru.ac.za/1135/.

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Ogunsipe, Abimbola Olukayode. "Photophysical and photochemical studies of non-transition metal phthalocyanine derivatives." Thesis, Rhodes University, 2005. http://hdl.handle.net/10962/d1007721.

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A detailed photophysicochemical study of some non-transition metal (AI, Zn, Si, Ge, and Sn) metallophthalocyanine (MPc) derivatives is presented. The effects of substituents, central metal ions and solvents on the photophysical and photochemical properties are investigated and rationalized accordingly. The presence of peripheral substituents on the macrocycle enhances the yield of the triplet state. Near infra-red absorptions of the solvents reveal that solvents which absorb around 1100 nm and around 1270 nm, quench the triplet state of the MPc derivative and singlet oxygen, respectively. Alth
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Matlaba, Pulane Maseleka. "Synthesis of zinc phthalocyanine derivatives for possible use in photodynamic therapy." Thesis, Rhodes University, 2003. http://hdl.handle.net/10962/d1005039.

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The synthesis of symmetrically and unsymmetrically substituted zinc phthalocyanines (ZnPc) derivatives is done according to reported procedures. The unsymmetrical ZnPc derivatives are synthesized by ring expansion of sub-phthalocyanine complexes. Ring substitution is effected with tert-butyl phenol, naphthol, and hydroxybenzoic acid. Comparison of the redox potentials for the complexes substituted with varying numbers of tert-butyl phenol: 1, 2, 3, 6 and 8 show that the complex with the highest number of substituents are more difficult to oxidize and easier to reduce. Water soluble sulphonated
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Omapinyan, Sriwalai Chaisang. "Vibrational spectroscopy of porphyrins, phthalocyanines and tetraphenyl derivatives of group IV-A elements." Thesis, University of East Anglia, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.361416.

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Yavuz, Arzu. "Synthesis And Characterization Of Electrochemically Polymerized Metal-free, Nickel And Zinc Containing Phthalocyanine Derivatives." Phd thesis, METU, 2009. http://etd.lib.metu.edu.tr/upload/3/12610723/index.pdf.

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In the first part of this study, 4-(2,5-di-2-thiophen-2-yl-pyrrol-1-yl)-phthalonitrile (SNS-PN) was synthesized by utilizing 1,4-di(2-thienyl)-1,4- butadione (SOOS) and 4-aminophthalonitrile via Knorr-Paal Reaction. Nuclear magnetic resonance (1H NMR and 13C NMR) and fourier transform infrared (FTIR) spectroscopies were utilized for the characterization of this compound. SNS-PN monomer was then electrochemically polymerized in acetonitrile/0.2 M LiClO4 solvent/electrolyte couple. Characterizations of the resulting polymer P(SNS-PN) were carried out by cyclic voltammetry (CV), UV&ndash<br>vis a
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Lu, Chin-Wei. "Synthesis of Asymmetric Phthalocyanine Derivatives." Diss., The University of Arizona, 2013. http://hdl.handle.net/10150/312651.

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The work in this dissertation describes improved methods of asymmetrically substituted Pc derivative synthesis addressing some currently encountered problems including: (1) the need for facile synthesis of asymmetric Pc/Nc hybrids; (2) a lack of general methods for producing asymmetric Pc materials with structural diversity. Chapter 1 provides a concise review on Pc and Pc/perylenediimide (PDI) derivatives that have been reported as a part of architecture in monochromophoric or multichromophoric molecules for energy and charge transfer studies. In addition, the intrinsic electronic and photop
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Dunn, A. J. "Synthesis and spectroscopic studies of some substituted phthalocyanine derivatives." Thesis, University of East Anglia, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.377695.

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Cao, Yu, and Yu Cao. "Molecular Engineering of Phthalocyanine Derivatives as Materials for Organic Photovoltaics." Diss., The University of Arizona, 2015. http://hdl.handle.net/10150/605113.

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Phthalocyanine (Pc) derivatives are π-conjugated molecules that have been explored as active layer components in organic photovoltaics (OPVs). The structure can be modified through incorporation of metals and installation of substituents which allows modulation of Pc-based materials toward desired solubility, photophysical properties and condensed phase organization. Research efforts in this thesis can be classified as (i) modulation of Pc absorption (Q-band) toward long wavelength to provide materials for near-infrared (NIR) absorbing OPVs, and (ii) development of solution processable Pc deri
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Collazo-Ramos, Aura L., and Aura L. Collazo-Ramos. "Synthesis of Phthalocyanine Derivatives as Materials for Organic Photovoltaic Cells." Diss., The University of Arizona, 2016. http://hdl.handle.net/10150/621741.

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Organic photovoltaics (OPVs) are used to convert sunlight into electricity by using thin films of organic semiconductors. OPVs have the potential to produce low cost, lightweight, flexible devices with an eased manufacturing process. This technology contains the potential to increase the use of clean, sustainable solar energy, helping manage the global energy and environmental crisis that results majorly from the constant use of fossil fuels as an energy source. The ability to modulate the physical properties of organic molecules by tuning their chemical structure is an advantage for OPVs. Pht
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Books on the topic "Phthalocyanines – Derivatives"

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Dunn, Adrian J. Synthesis and spectroscopic studies of some substituted phthalocyanine derivatives. University of East Anglia, 1987.

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Howe, Steven D. A synthetic, spectroscopic and conductometric study of some phthalocyanine derivatives. University ofEast Anglia, 1986.

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Book chapters on the topic "Phthalocyanines – Derivatives"

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Svensen, R., S. Fery-Forgues, A. J. MacRobert, and D. Phillips. "Pulsed Laser Studies of Aluminium Phthalocyanine Derivatives." In Photosensitisation. Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73151-8_64.

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Claessens, Christian G., Gema de la Torre, and Tomás Torres. "From Dipolar to Octupolar Phthalocyanine Derivatives: The Example of Subphthalocyanines." In Challenges and Advances in Computational Chemistry and Physics. Springer Netherlands, 2006. http://dx.doi.org/10.1007/1-4020-4850-5_16.

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Lau, Janet T. F. "A Zinc(II) Phthalocyanine Conjugated with an Oxaliplatin Derivative for Dual Chemo- and Photodynamic Therapy." In Towards Dual and Targeted Cancer Therapy with Novel Phthalocyanine-based Photosensitizers. Springer International Publishing, 2013. http://dx.doi.org/10.1007/978-3-319-00708-3_2.

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Abramczyk, H., and I. Szymczyk. "Photoinduced Redox Processes in Phthalocyanine Derivatives by Resonance Raman Spectroscopy and Time Resolved Techniques." In Novel Approaches to the Structure and Dynamics of Liquids: Experiments, Theories and Simulations. Springer Netherlands, 2004. http://dx.doi.org/10.1007/978-1-4020-2384-2_13.

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Lu, Xiaoquan, and Samrat Devaramani. "Electrochemical Investigation of Porphyrin and Its Derivatives at Various Interfaces." In Phthalocyanines and Some Current Applications. InTech, 2017. http://dx.doi.org/10.5772/67637.

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"2. Phthalocyanines and Related Compounds: 2.1. Synthesis of Phthalocyanines and Annulated Derivatives (I)." In Hetarenes IV, edited by Ernst Schaumann. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-111048.

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"2. Phthalocyanines and Related Compounds: 2.1. Synthesis of Phthalocyanines and Annulated Derivatives (II)." In Hetarenes IV, edited by Ernst Schaumann. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-111049.

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"2. Phthalocyanines and Related Compounds: 2.1. Synthesis of Phthalocyanines and Annulated Derivatives (III)." In Hetarenes IV, edited by Ernst Schaumann. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-111050.

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"2. Phthalocyanines and Related Compounds: 2.1. Synthesis of Phthalocyanines and Annulated Derivatives (IV)." In Hetarenes IV, edited by Ernst Schaumann. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-111051.

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Lo, Pui-Chi, Janet T. F. Lau, and Dennis K. P. Ng. "84 Bioconjugation of Phthalocyanine Derivatives." In Handbook of Porphyrin Science. World Scientific Publishing Company, 2012. http://dx.doi.org/10.1142/9789814335508_0011.

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Conference papers on the topic "Phthalocyanines – Derivatives"

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Riesz, Peter, and C. Murali Krishna. "Phthalocyanines And Their Sulfonated Derivatives As Photosensitizers In Photodynamic Therapy." In 1987 Cambridge Symposium, edited by Douglas C. Neckers. SPIE, 1988. http://dx.doi.org/10.1117/12.942685.

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Svec, Jan, and Petr Zimcik. "New phthalocyanine and azaphthalocyanine derivatives." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_20131014112029.

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Wada, T., M. Q. Tian, Y. Liu, and H. Sasabe. "Nonlinear optical properties of asymmetrical phthalocyanine derivatives." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.836128.

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Meerovich, Gennadii A., Eugeny A. Lukyanets, Olga A. Yuzhakova, et al. "Phosphosubstituted phthalocyanine derivatives as effective photosensitizers for PDT." In BiOS Europe '97, edited by Kristian Berg, Benjamin Ehrenberg, Zvi Malik, Johan Moan, and Abraham Katzir. SPIE, 1997. http://dx.doi.org/10.1117/12.297804.

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Wohrle, Dieter, Andrea Weitemeyer, Abdol K. Sobbi, Ulrike Michelsen, and H. Kliesch. "Monofunctional phthalocyanine derivatives as potential sensitizers for PDT." In BiOS Europe '95, edited by Benjamin Ehrenberg, Giulio Jori, and Johan Moan. SPIE, 1996. http://dx.doi.org/10.1117/12.230956.

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Geng, Yanhou, Shaoqiang Dong, Hongkun Tian, Donghang Yan, and Fosong Wang. "Phthalocyanine derivatives for solution-processed organic thin-film transistors." In SPIE Photonic Devices + Applications, edited by Zhenan Bao and Iain McCulloch. SPIE, 2011. http://dx.doi.org/10.1117/12.894692.

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Kazak, A. V., N. V. Usol'tseva, A. I. Smirnova, I. Yu Lukyanov, and S. G. Yudin. "Optical properties of Langmuir-Blodgett films of tetraphenylporphin derivatives and mix-substituted phthalocyanine derivatives." In 2014 24th International Crimean Conference "Microwave & Telecommunication Technology" (CriMiCo). IEEE, 2014. http://dx.doi.org/10.1109/crmico.2014.6959619.

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Meerovich, Gennadii A., Eugeny A. Lukyanets, Olga A. Yuzhakova, et al. "Photosensitizer for PDT based on phosphonate phthalocyanine derivative." In BiOS Europe '96, edited by Stanley B. Brown, Benjamin Ehrenberg, and Johan Moan. SPIE, 1996. http://dx.doi.org/10.1117/12.260769.

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Pakhomov, L. G., and G. L. Pakhomov. "NO/sub 2/ interaction with thin films of phthalocyanine derivatives." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.836076.

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Suda, Yasumasa, Kiyotaka Shigehara, Akira Yamada, et al. "Reversible phase transition and third-order nonlinearity of phthalocyanine derivatives." In San Diego, '91, San Diego, CA, edited by Kenneth D. Singer. SPIE, 1991. http://dx.doi.org/10.1117/12.50707.

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