Academic literature on the topic 'Phthalonitrile'

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Journal articles on the topic "Phthalonitrile"

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Mori, Satoru, Naoya Ogawa, Etsuko Tokunaga, and Norio Shibata. "Synthesis and optical properties of trifluoroethoxy-substituted double-decker phthalocyanines." Journal of Porphyrins and Phthalocyanines 18, no. 10n11 (2014): 1034–41. http://dx.doi.org/10.1142/s1088424614500862.

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The synthesis of trifluoroethoxy-substituted double-decker phthalocyanines was investigated for the first time. Trifluoroethoxy-substituted phthalonitriles reacted with lanthanide acetylacetonate hydrate in n-octanol in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene when refluxed. La and Eu were chosen as central metals. Phthalonitriles, including one trifluoroethoxy substituent at the α- or β-position, were nicely induced to double-decker phthalocyanines. Phthalonitrile having two trifluoroethoxy substituents at α-positions did not react, although we succeeded in leading β-di-substituted
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Crucius, Göran, Michael Hanack та Thomas Ziegler. "Synthesis and characterization of [1,4-bis(α,β-galactopyranos-6-yl)phthalocyaninato]zinc(II)". Journal of Porphyrins and Phthalocyanines 17, № 08n09 (2013): 807–13. http://dx.doi.org/10.1142/s1088424613500387.

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Herein we present the synthesis and full characterization of the water-soluble [1,4-bis(α,β-galactopyranos-6-yl)phthalocyaninato]zinc(II) (8). For a cross-condensation with phthalonitrile in presence of zinc bromide, bisglycosylated phthalonitrile (5) has been synthesized by nucleophilic displacement of triflyl groups or fluorine atoms by acetonide protected galactose in the appropriated phthalonitriles 1 and 2. Furthermore we prepared 3,6-bis(1,2:3,4-di-O-isopropylidene-α-D-galactopyranos-6-yl)phthalonitrile (5) starting from 2,3-dicyanohydroquinone and 1,2:3,4-di-O-isopropylidene-α-D-galacto
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Causey, Patrick W., Igor Dubovyk, and Clifford C. Leznoff. "Syntheses and characterization of phthalonitriles and phthalocyanines substituted with adamantane moieties." Canadian Journal of Chemistry 84, no. 10 (2006): 1380–87. http://dx.doi.org/10.1139/v06-096.

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The reaction of 3,4,5,6-tetrafluorophthalonitrile with 1-adamantanol, 1-adamantylamine, 1-adamantanemethanol, and 1-adamantaneethanol gave 4,5-di-(1-adamantyloxy)-3,6-difluorophthalonitrile, 4,5-di-(1-adamantylamino)-3,6-difluorophthalonitrile, 4-(1-adamantylamino)-3,5,6-trifluorophthalonitrile, 3,4,5,6-tetra-(1-adamantylmethoxy)phthalonitrile, and 3,4,5,6-tetra-(1-adamantylethoxy)phthalonitrile, respectively. The conversion of these tetrasubstituted phthalonitriles to magnesium, nickel, and metal-free phthalocyanines was demonstrated. These highly hindered phthalocyanines exhibited interestin
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Vashurin, Artur, Vladimir Maizlish, Ilya Kuzmin, et al. "Symmetrical and difunctional substituted cobalt phthalocyanines with benzoic acids fragments: Synthesis and catalytic activity." Journal of Porphyrins and Phthalocyanines 21, no. 01 (2017): 37–47. http://dx.doi.org/10.1142/s108842461750002x.

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Difunctional and symmetric phthalonitriles were synthesized by nucleophilic substitution of brome and nitro-group in 4-bromo-5-nitro-phthalonitrile for residues 4-amino-, 4-hydroxyl- and 4-sulfanyl benzoic acid. Symmetrical and difunctional substituted cobalt phthalocyanines were obtained by template synthesis based on mentioned phthalonitriles. Their spectral properties and catalytic activity in aerobic oxidation of sodium [Formula: see text],[Formula: see text]-carbomoditiolate were investigated.
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LEZNOFF, CLIFFORD C., ANNA M. D'ASCANIO, and S. ZEKI YILDIZ. "Phthalocyanine formation using metals in primary alcohols at room temperature." Journal of Porphyrins and Phthalocyanines 04, no. 01 (2000): 103–11. http://dx.doi.org/10.1002/(sici)1099-1409(200001/02)4:1<103::aid-jpp209>3.0.co;2-e.

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Lithium metal added to a solution of 4-neopentoxyphthalonitrile in 1-octanol or other long-chain primary alcohols at room temperature resulted in phthalocyanine formation at a reasonable rate in good yield, while preformed lithium 1-octanolate under the same conditions gave 2,9,16,23-tetraneopentoxyphthalocyanine, but in lower yield at a slower rate. The use of lower-molecular-weight alcohols slowly gave a phthalocyanine in lower yields. Reverse micelle formation when using long-chain alcohols is proposed as a possibility for enhanced phthalocyanine formation at room temperature. 2,9,16,23-Tet
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Znoiko, S. A., M. S. Kuzmina, V. E. Maizlish, G. N. Koshel, and N. V. Lebedeva. "Nucleophilic substitution in 4-bromo-5-nitrophthalodinitrile: XVIII. Synthesis and spectral properties of octasubstituted zinc phthhalocyanines with cyclohexylphenol moieties." Журнал общей химии 93, no. 7 (2023): 1098–107. http://dx.doi.org/10.31857/s0044460x23070144.

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Using 4-bromo-5-nitro- and 4,5-dichlorophthalonitriles, substituted phthalonitriles containing a fragment of 2-cyclohexylphenol and nitro- or 1-benzotriazolyl groups, as well as phthalonitrile containing two 2-cyclohexylphenoxy groups, were synthesized. Tetramerization of these precursors with zinc acetate hexahydrate gave the corresponding octa-substituted zinc phthalocyanines. Their spectral properties were studied.
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Al-Raqa, Shaya Y. "Synthesis, photochemical and photophysical properties of novel unsymmetrically substituted zinc(II) phthalocyanines." Journal of Porphyrins and Phthalocyanines 10, no. 01 (2006): 55–62. http://dx.doi.org/10.1142/s1088424606000077.

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The synthesis of three novel unsymmetrical free base, zinc(II) phthalocyanine derivatives obtained from 3,6-di-(thiophen-3-yl)phthalonitrile and 3,6-didecylphthalonitrile are described. The synthesis of novel 3,6-substituted phthalonitriles bearing heteroaromatic derivatives were achieved through Suzuki-coupling reaction by treatment of 3,6-di(trifluoromethanesulfonyloxy)phthalonitriles and heteroaromatic boronic acids. Two of the newly synthesized complexes showed a high efficiency against a model biological substrate, such as N-acetyl-L-tryptophanamide NATA, and shows a high singlet oxygen q
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Bulgakov, BA, AV Sulimov, AV Babkin, et al. "Phthalonitrile-carbon fiber composites produced by vacuum infusion process." Journal of Composite Materials 51, no. 30 (2017): 4157–64. http://dx.doi.org/10.1177/0021998317699452.

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High-temperature carbon fiber-reinforced plastics based on phthalonitrile resins are obtained for the first time by vacuum infusion process. For this purpose, formulations based on low-melting bis(3-(3,4-dicyanophenoxy)phenyl) phenyl phosphate monomer in combination with 1,3-bis(3,4-dicyanophenoxy)benzene and 4-[3-(prop-2-yn-1-yloxy)phenoxy]benzene-1,2-dicarbonitrile were developed. Resin viscosities η ≤ 600 mPa·s were suitable for VIP and at the same time the thermal and mechanical properties of the cured matrices were in high level featured to phthalonitriles (HDT ≥ 420℃, E ≥ 5.1 GPa). CFRP
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Chen, Xinggang, Jiayu Liu, Zhenjie Xi, et al. "Synthesis and thermal properties of high temperature phthalonitrile resins cured with self-catalytic amino-contanining phthalonitrle compounds." High Performance Polymers 29, no. 10 (2016): 1209–21. http://dx.doi.org/10.1177/0954008316673419.

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A series of self-catalytic phthalonitrile compounds with o-, m-, and p- amino groups, namely, 4-(2-aminophenoxy)phthalonitrile (2-NH2-CN), 4-(3-aminophenoxy)phthalonitrile (3-NH2-CN), and 4-(4-aminophenoxy)phthalonitrile (4-NH2-CN), were synthesized via a facile nucleophilic displacement of a nitro-substituent with 4-nitrophthalonitrile. The phthalonitrile resins were prepared by curing 2-NH2-CN, 3-NH2-CN, and 4-NH2-CN with 1,3-bis(3,4-dicyanophenoxy) benzene ( m-BDB). The structures of these compounds were characterized by Fourier transform infrared spectroscopy, proton nuclear magnetic reson
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Wang, Guangxing, Ying Guo, Yue Han, et al. "Enhanced properties of phthalonitrile resins reinforced by novel phthalonitrile-terminated polyaryl ether nitrile containing fluorene group." High Performance Polymers 32, no. 1 (2019): 3–11. http://dx.doi.org/10.1177/0954008319847259.

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Novel phthalonitrile resins (BPAPNs) were prepared by blending phthalonitrile-terminated oligomeric polyaryl ether nitrile, 4,4′-(1,3-phenylenebis(oxy))diphthalonitrile (PN), and 4-amino-4-(3,4-dicyanophenoxy)phenyl. The curing behavior of the blends was studied by differential scanning calorimetry, Fourier-transform infrared spectroscopy, and rheology measurements. Additionally, quartz fiber-reinforced composites were prepared by hot-pressing process. Thermal stability and mechanical properties of cured phthalonitrile resins and composites were characterized and discussed. Compared with that
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Dissertations / Theses on the topic "Phthalonitrile"

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Hardrict, Shauntrece Nicole. "Novel Novolac-Phthalonitrile and Siloxane-Phthalonitrile Resins cured with low melting Novolac Oligomers for Flame Retardant Structural Thermosets." Thesis, Virginia Tech, 2003. http://hdl.handle.net/10919/9669.

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The chemical modification of low molecular weight novolac oligomers and siloxane/silane-containing monomers has led to novel phthalonitrile derivatives with low glass transition temperatures, ranging from -25 to 75 ºC. Multi-functional, low molecular weight phenol-formaldehyde novolac resins were blended with these novel phthalonitrile derivatives to achieve low viscosity resin blends. Moderate temperatures and rapid curing cycles were employed (200 ºC, 1 h and 225 ºC, 4h) to produce networks with high glass transition temperatures (> 250 ºC). A decrease in the sharp band at 2230 cm⁻¹, attr
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Monzel, William Jacob. "Synthesis, Processing, and Properties of Silicon-Containing Phthalonitrile Resins." Diss., Virginia Tech, 2019. http://hdl.handle.net/10919/87412.

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Hybrid inorganic-organic resins may provide higher temperature performance in oxidizing environments than their organic counterparts. Phthalonitrile (PN) polymers are excellent candidates for hybridization due to their high thermal stability and glass transition temperatures and their need for improved long-term oxidative stability and toughness. In this work phenyl-substituted organosilicon linkages were incorporated into PN monomers to investigate their effect on the processing, thermo-mechanical properties, and thermal and oxidative stability. Three hybrid silicon-containing phthalonitrile
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Chavez, Joshua L. "The Synthesis and Characterization of 1,3-Bis(Arylimino)Isoindoline Using Phthalonitrile Diiminoisoindoline as Starting Material." University of Akron / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=akron1321062562.

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Vadala, Michael Lawrence. "Preparation and Functionalization of Macromolecule-Metal and Metal Oxide Nanocomplexes for Biomedical Applications." Diss., Virginia Tech, 2006. http://hdl.handle.net/10919/27098.

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Copolymer-cobalt complexes have been formed by thermolysis of dicobalt octacarbonyl in solutions of copolysiloxanes. The copolysiloxane-cobalt complexes formed from toluene solutions of PDMS-b-[PMVS-co-PMTMS] block copolymers were annealed at 600-700 °C under nitrogen to form protective siliceous shells around the nanoparticles. Magnetic measurements after aging for several months in both air and in water suggest that the ceramic coatings do protect the cobalt against oxidation. However, after mechanical grinding, oxidation occurs. The specific saturation magnetization of the siliceous-coba
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Sumner, Michael Jameson. "High Performance Materials Containing Nitrile Groups." Diss., Virginia Tech, 2003. http://hdl.handle.net/10919/11261.

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The objective of the research described in this thesis has been to improve the toughness of phenolic networks while maintaining flame resistance. A four step synthetic scheme has been developed to prepare 4,4¡¦-Bis(3,4-dicyanophenoxy)biphenyl(biphenoxyphthalonitrile). A 700 g mol-1 novolac oligomer was cured with relatively low concentrations of this reagent (~20 wt %) into high Tg (~190 ¢XC) networks. The curing reaction was attrubuted to nucleophilic attack of the phenolic hydroxyl on the nitrile groups of the phthalonitrile resulting in the formation of heterocylic rings. TGA and con
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Baranauskas, Victor Vincent. "Cobalt Nanoparticle-Macromolecular Complexes and Their Conversion to Oxidatively Stable Entities." Diss., Virginia Tech, 2005. http://hdl.handle.net/10919/27376.

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The goal of the research presented in this dissertation was to synthesize novel macromolecular materials that would afford oxidative stability to magnetic cobalt nanoparticles under ambient conditions. The cobalt nanoparticles were formed via the thermolysis of Co2(CO)8 in concentrated solutions of toluene containing the macromolecular dispersion stabilizers. The copolymers were designed to encapsulate the nanoparticles with a number of thin protective coatings to prevent their undesirable oxidation under ambient condtions. Cobalt nanoparticles encased with an organic glass were synthesized
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Van, der Walt Mietha Magdalena. "Syntheses of sulfanylphthalimide and xanthine analogues and their evaluation as inhibitors of monoamine oxidase and as antagonists of adenosine receptors / Mietha Magdalena van der Walt." Thesis, North-West University, 2013. http://hdl.handle.net/10394/9537.

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Currently L-DOPA is the drug most commonly used for the treatment of Parkinson’s disease (PD). However, the long-term use of L-DOPA is associated with the development of motor fluctuations and dyskinesias. Treatment mainly addresses the dopaminergic features of the disease and leaves its progressive course unaffected. An optimal treatment would be a combination of both motor and non-motor symptom relief with neuroprotective properties. Two drug targets have attracted the attention for PD treatment, namely monoamine oxidase B (MAOB) and adenosine A2A receptors. MAO-B inhibitors enhance the elev
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Terekhov, Dmitri S. "The synthesis of halogenated phthalonitriles and their use for the synthesis of mononuclear and binuclear phthalocyanines." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/nq22899.pdf.

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Books on the topic "Phthalonitrile"

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Phthalonitrile Resins and Composites. Elsevier, 2018. http://dx.doi.org/10.1016/c2016-0-03991-8.

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Phthalonitrile Resins and Composites: Properties and Applications. Elsevier Science & Technology Books, 2018.

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Jun, Wang, Mehdi Derradji, and Liu Wenbin. Phthalonitrile Resins and Composites: Properties and Applications. Elsevier Science & Technology Books, 2018.

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Chandran, Satheesh, C. P. Reghunadhan Nair, Dhanya Augustine, and Dona Mathew. High Performance Phthalonitrile Resins: Challenges and Engineering Applications. De Gruyter, Inc., 2019.

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Chandran, Satheesh, C. P. Reghunadhan Nair, Dona Mathew, and Augustine Dhanya. High Performance Phthalonitrile Resins: Challenges and Engineering Applications. de Gruyter GmbH, Walter, 2019.

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High Performance Phthalonitrile Resins: Challenges and Engineering Applications. de Gruyter GmbH, Walter, 2019.

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Bremen, Universität, ed. Zur Synthese und Analytik von Phthalocyaninen aus substituierten Phthalonitrilen und Bisphthalonitrilen in Gegenwart organischer Basen. 1988.

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Book chapters on the topic "Phthalonitrile"

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Bershtein, Vladimir A., and Pavel N. Yakushev. "Phthalonitrile/Montmorillonite Nanocomposites." In High-Temperature Polymer Nanocomposites Based on Heterocyclic Networks from Nitrile Monomers. Springer Nature Switzerland, 2023. http://dx.doi.org/10.1007/978-3-031-32943-2_7.

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Bershtein, Vladimir A., and Pavel N. Yakushev. "Phthalonitrile/Metal Oxide Nanocomposites." In High-Temperature Polymer Nanocomposites Based on Heterocyclic Networks from Nitrile Monomers. Springer Nature Switzerland, 2023. http://dx.doi.org/10.1007/978-3-031-32943-2_8.

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Bershtein, Vladimir A., and Pavel N. Yakushev. "Phthalonitrile Composites with POSS Nanoparticles." In High-Temperature Polymer Nanocomposites Based on Heterocyclic Networks from Nitrile Monomers. Springer Nature Switzerland, 2023. http://dx.doi.org/10.1007/978-3-031-32943-2_6.

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Bershtein, Vladimir A., and Pavel N. Yakushev. "Other Types of Phthalonitrile Nanocomposites." In High-Temperature Polymer Nanocomposites Based on Heterocyclic Networks from Nitrile Monomers. Springer Nature Switzerland, 2023. http://dx.doi.org/10.1007/978-3-031-32943-2_9.

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Laskoski, Matthew, Dawn D. Dominguez, and Teddy M. Keller. "Processable Phthalonitrile Resins with High-Thermal and Oxidative Stability." In ACS Symposium Series. American Chemical Society, 2005. http://dx.doi.org/10.1021/bk-2006-0922.ch029.

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McKeown, N. B. "From Phthalonitrile." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-01841.

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Derradji, Mehdi, Jun Wang, and Wenbin Liu. "Phthalonitrile Resins’ Properties." In Phthalonitrile Resins and Composites. Elsevier, 2018. http://dx.doi.org/10.1016/b978-0-12-812966-1.00002-0.

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Wypych, George. "PNR phthalonitrile resin." In Handbook of Polymers. Elsevier, 2016. http://dx.doi.org/10.1016/b978-1-895198-92-8.50153-1.

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Derradji, Mehdi, Jun Wang, and Wenbin Liu. "Fiber-Reinforced Phthalonitrile Composites." In Phthalonitrile Resins and Composites. Elsevier, 2018. http://dx.doi.org/10.1016/b978-0-12-812966-1.00005-6.

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McKeown, N. B. "Dimers from Cyclotetramerization Reactions Containing a Phthalonitrile and a Bis(phthalonitrile)." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-01954.

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Conference papers on the topic "Phthalonitrile"

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Epshteyn, A., B. Dyatkin, B. Chaloux, M. Laskoski, and T. Butler. "High-Char Phthalonitrile Resin Blends." In SAMPE 2020 | Virtual Series. NA SAMPE, 2020. http://dx.doi.org/10.33599/s.20.0373.

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Epshteyn, A., B. Dyatkin, B. Chaloux, M. Laskoski, and T. Butler. "High-Char Phthalonitrile Resin Blends." In SAMPE 2020 | Virtual Series. NA SAMPE, 2020. http://dx.doi.org/10.33599/382/s.20.0373.

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Epshteyn, A., B. Dyatkin, B. Chaloux, M. Laskoski, and T. Butler. "High-Char Phthalonitrile Resin Blends." In SAMPE 2020 | Virtual Series. NA SAMPE, 2020. http://dx.doi.org/10.33599/nasampe/s.20.0373.

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Babkin, A., A. Kepman, V. Avdeev, and B. Bulgakov. "Advanced Phthalonitrile Resin Systems for Vacuum Processing." In SAMPE 2020 | Virtual Series. NA SAMPE, 2020. http://dx.doi.org/10.33599/382/s.20.0238.

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Babkin, A., A. Kepman, V. Avdeev, and B. Bulgakov. "Advanced Phthalonitrile Resin Systems for Vacuum Processing." In SAMPE 2020 | Virtual Series. NA SAMPE, 2020. http://dx.doi.org/10.33599/s.20.0238.

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Babkin, A., A. Kepman, V. Avdeev, and B. Bulgakov. "Advanced Phthalonitrile Resin Systems for Vacuum Processing." In SAMPE 2020 | Virtual Series. NA SAMPE, 2020. http://dx.doi.org/10.33599/nasampe/s.20.0238.

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PHUA, Eric Jian Rong, Ming LIU, Jacob Song Kit LIM, Bokun CHO, and Chee Lip GAN. "Phthalonitrile-Based Electronic Packages for High Temperature Applications." In 2018 IEEE 20th Electronics Packaging Technology Conference (EPTC). IEEE, 2018. http://dx.doi.org/10.1109/eptc.2018.8654340.

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Tay, Yu Shan, Jian Rong Eric Phua, and Chee Lip Gan. "Behavior of Resorcinol based Phthalonitrile as High Temperature Encapsulant." In 2019 IEEE 21st Electronics Packaging Technology Conference (EPTC). IEEE, 2019. http://dx.doi.org/10.1109/eptc47984.2019.9026569.

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Monzel, William, Guo-Quan Lu, Timothy Pruyn, Christopher Houser, and Gordon Yee. "Evaluation of Silicon-containing Phthalonitrile Polymers- Properties, and Degradations." In SAMPE 2019 - Charlotte, NC. SAMPE, 2019. http://dx.doi.org/10.33599/nasampe/s.19.1534.

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Tong, Lifen, Renbo Wei, and Xiaobo Liu. "Novel in-situ nanocomposites of phthalonitrile end-capped polyarylene ether nitrile/copper phthalocyanine." In MATHEMATICAL SCIENCES AND ITS APPLICATIONS. Author(s), 2017. http://dx.doi.org/10.1063/1.4971914.

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