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Journal articles on the topic 'Physical chemistry; Chemistry; Analytical chemistry'

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Published: 4 June 2021
Last updated: 10 February 2022

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1

Kolditz, L. "Analytical Chemistry." Zeitschrift für Physikalische Chemie 211, Part_1 (January 1999): 118–19. http://dx.doi.org/10.1524/zpch.1999.211.part_1.118.

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2

Werner, G. "Environmental Analytical Chemistry." Zeitschrift für Physikalische Chemie 209, Part_2 (January 1999): 286–87. http://dx.doi.org/10.1524/zpch.1999.209.part_2.286.

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3

Wójcik, John F. "Physical chemistry source book." Microchemical Journal 42, no. 1 (August 1990): 147. http://dx.doi.org/10.1016/0026-265x(90)90036-5.

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4

Cammann, Karl. "Sensors and analytical chemistry." Physical Chemistry Chemical Physics 5, no. 23 (2003): 5159. http://dx.doi.org/10.1039/b309894j.

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5

Frazier, Richard A. "Physical Chemistry of Foods." Food Chemistry 85, no. 2 (April 2004): 315. http://dx.doi.org/10.1016/s0308-8146(03)00246-2.

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6

Howard, AlanG. "Physical methods of chemistry." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 256, no. 1 (November 1988): 235–36. http://dx.doi.org/10.1016/0022-0728(88)85025-3.

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7

Cassaday, M., H. Diebler, R. Herron, M. Pelavin, D. Svenjak, and D. Vlastelica. "Capsule chemistry technology for high-speed clinical chemistry analyses." Clinical Chemistry 31, no. 9 (September 1, 1985): 1453–56. http://dx.doi.org/10.1093/clinchem/31.9.1453.

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Abstract We describe a new analytical approach--"capsule chemistry"--for high-speed, selective analysis of a wide variety of analytes. Sequential micro-aliquots of sample and reagents are encapsulated within an inert fluorocarbon liquid. The resulting "test capsule" is introduced into a single analytical flow path, composed of a solid fluorocarbon, Teflon, where the sample is incubated, mixed, reacted, and measured as a moving series of individual tests. These randomly selective assays are processed at a rate of 720 per hour. The unique physical interaction between the liquid and solid fluorocarbon carrier materials effectively prevents detectable "carryover" of aqueous constituents between the successive test capsules. Reactions are monitored through the walls of the Teflon analytical channel at nine in-line detector stations for colorimetric and nephelometric measurements.
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8

Bai, Chunli. "Preface." Pure and Applied Chemistry 78, no. 5 (January 1, 2006): iv. http://dx.doi.org/10.1351/pac20067805iv.

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"Creativity is the soul of a nation and an inexhaustible source of a country's prosperity." Original innovation, as the major source of new technologies, will not only bring about technological breakthroughs, but give rise to new industries and new economic structures, offering unlimited opportunities for later starters to overtake the frontrunners. "Innovation in Chemistry" is the specific theme for the 40th International Union of Pure and Applied Chemistry (IUPAC) Congress, which was held on 14-19 August 2005 in Beijing, China. The Congress provided an excellent forum for presenting the latest innovative achievements in the chemical sciences and in the practice of chemistry.A total of 1083 participants from 64 countries attended the Congress. With 412 of the participants from mainland China and 556 from other countries and regions, the Congress helped to build a bridge between Chinese chemists and the world, encouraging cooperation and excellence in fundamental research and industrializations.The high-scientific value of the Congress was evident in the plenary lectures, which were delivered by eight distinguished chemists, including three Nobel Laureates and one Einstein Award Winner. A total of 1145 papers and 622 posters were presented in the eight sessions of the Congress: (1) Environmental Chemistry and Green Chemistry; (2) Chemistry in the Life Sciences and Chemical Biology; (3) Materials Chemistry, Supermolecular Chemistry, and Nanochemistry; (4) Information Technology in Chemistry and Computational Chemistry; (5) Innovation in Physical Chemistry and Biophysical Chemistry: Research Methods and Techniques; (6) Innovation in Methodology, Technique, and Instrumentation and Analytical Chemistry; (7) Innovation in Chemical Education and Teaching Methods; (8) Innovation in the Chemical and Petrochemical Industries and "Responsible Care" for Society.Fourteen papers selected from the plenary and invited lectures from the 40th IUPAC Congress are published in this special issue of Pure and Applied Chemistry (PAC), which cover a spectrum from theoretical chemistry to chemical engineering, from micro/nanoscale studies to industrial-scale process/equipment evaluations. The review on the study of single molecules and their assembly provides a comprehensive, up-to-date summary of the field based on the fundamental research; much of the information presented falls within the special expertise of the group. The paper on the superheavy element describes the latest developments in a field that has shown higher activity in recent years as the predicted "island of stability" comes within the reach of the available hardware. This area is always of special interest to international scientists owing to the special synthesis techniques for superheavy elements employed by the Dubna group. Green chemistry is becoming a characteristic area in China that plays a significant role in motivating the development of new synthetic techniques, such as cross-dehydrogenative coupling. Other papers in this issue address a variety of topics from novel instrumentation for electrochemical impedance spectroscopy to synthesis of oxide nanomaterials; from catalysts to waste water treatment. These papers give a snapshot of the research reported at the 40th IUPAC Congress. I sincerely hope that this special issue of PAC brings some fresh ideas, novel concepts, and useful data to the readers.The International Organizing Committee contributed to the shaping of an important area of emerging science and technology. Thanks and appreciations are due to the Local Organizing Committee for the efficiency and excellence of the local arrangements and for the gracious hospitality. I am grateful to those who contributed their latest research work to this issue, and the support from Dr. John W. Jost, IUPAC Executive Director.Chunli BaiPresident of the 40th IUPAC Congress,President of the Chinese Chemical Society,and Executive Vice President of the Chinese Academy of Sciences
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9

Harvey, David. "Incorporating Analytical Chemistry into an Introductory Course in Chemistry." Spectroscopy Letters 40, no. 3 (May 2007): 381–94. http://dx.doi.org/10.1080/00387010701292924.

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10

Walters, John P. "Role-playing analytical chemistry laboratories. Part II: physical resources." Analytical Chemistry 63, no. 22 (November 15, 1991): 1077A—1087A. http://dx.doi.org/10.1021/ac00022a001.

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11

Williams, Kathryn R. "Capillary Electrophoresis in the Analytical and Physical Chemistry Laboratories." Journal of Chemical Education 75, no. 9 (September 1998): 1079. http://dx.doi.org/10.1021/ed075p1079.

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12

Williams, Kathryn R. "Automatic Titrators in the Analytical and Physical Chemistry Laboratories." Journal of Chemical Education 75, no. 9 (September 1998): 1133. http://dx.doi.org/10.1021/ed075p1133.

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13

Patriarche, G. J. "Electroanalysis V. Reviews on Analytical Chemistry." Bioelectrochemistry and Bioenergetics 21, no. 1 (February 1989): 114–15. http://dx.doi.org/10.1016/0302-4598(89)87021-7.

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14

Burns, D. T. "Physical methods of chemistry, 2nd edn." Analytica Chimica Acta 198 (1987): 330–31. http://dx.doi.org/10.1016/s0003-2670(00)85040-0.

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15

Bartlett, P. N. "Studies in physical and theoretical chemistry." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 256, no. 1 (November 1988): 235. http://dx.doi.org/10.1016/0022-0728(88)85024-1.

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16

Thévenot, Daniel R., Klara Toth, Richard A. Durst, and George S. Wilson. "Electrochemical biosensors: recommended definitions and classification1International Union of Pure and Applied Chemistry: Physical Chemistry Division, Commission I.7 (Biophysical Chemistry); Analytical Chemistry Division, Commission V.5 (Electroanalytical Chemistry).1." Biosensors and Bioelectronics 16, no. 1-2 (January 2001): 121–31. http://dx.doi.org/10.1016/s0956-5663(01)00115-4.

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17

Vasilevskaya, Elena, and Viktor Khvalyuk. "CHEMISTRY IN THE NEW GENERATION OF UNIVERSITY EDUCATION STANDARDS IN BELARUS." GAMTAMOKSLINIS UGDYMAS / NATURAL SCIENCE EDUCATION 6, no. 3 (December 5, 2009): 24–28. http://dx.doi.org/10.48127/gu-nse/09.6.24b.

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The article presents the structure and content of a new generation of post-secondary education standards in Belarus. New educational standards consist of four units: a social science core, a natural science core, a core of professional disciplines, and a selection of special courses. We discuss the place and role of chemistry in new curriculums for students of natural sciences, engineering and humanities. For chemistry students, the natural science core includes such disciplines as Higher Mathemat-ics, Physics, Ecology, Introduction to Information Technology, Information Technology in Chemistry, and Mathematical Modeling of Chemical Processes and others. In the core of professional disciplines there are classical selection of chemistry courses including Inorganic Chemistry, Analytical Chemistry, Organic Chemistry, Physical Chemistry, Chemistry of Polymers and Biopolymers, Chemical Technology, Instru-mental Methods of Chemical Analysis, Physical Methods of Structure Determination, Quantum Chemistry, Crystal chemistry, Structure of Matter, Fundamental Problems of Chemistry, etc. Key words: chemical university education, education standard techniques.
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18

Offroy, Marc, and Ludovic Duponchel. "Topological data analysis: A promising big data exploration tool in biology, analytical chemistry and physical chemistry." Analytica Chimica Acta 910 (March 2016): 1–11. http://dx.doi.org/10.1016/j.aca.2015.12.037.

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19

Portal, Christophe F., and Mark Bradley. "High-Throughput Physical Organic Chemistry Hammett Parameter Evaluation." Analytical Chemistry 78, no. 14 (July 2006): 4931–37. http://dx.doi.org/10.1021/ac060596u.

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20

Asher, Sanford A. "UV Resonance Raman Spectroscopy for Analytical, Physical, and Biophysical Chemistry." Analytical Chemistry 65, no. 2 (January 15, 1993): 59A—66A. http://dx.doi.org/10.1021/ac00050a717.

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21

Asher, Sanford A. "UV Resonance Raman Spectroscopy for Analytical, Physical, and Biophysical Chemistry." Analytical Chemistry 65, no. 4 (February 15, 1993): 201A—210A. http://dx.doi.org/10.1021/ac00052a715.

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22

Lin, Jie, and Chris W. Brown. "Novel applications of near-infrared spectroscopy of water and aqueous solutions from physical chemistry to analytical chemistry." TrAC Trends in Analytical Chemistry 13, no. 8 (September 1994): 320–26. http://dx.doi.org/10.1016/0165-9936(94)87004-7.

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23

A, J. B. "Computational Chemistry: an Emphasis on Practical Calculations (Studies in Physical and Theoretical Chemistry 56)." Journal of Molecular Structure 212 (September 1989): 333. http://dx.doi.org/10.1016/0022-2860(89)85099-9.

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24

Yulina, I. K., A. Permanasari, H. Hernani, and W. Setiawan. "Analytical thinking skill profile and perception of pre service chemistry teachers in analytical chemistry learning." Journal of Physics: Conference Series 1157 (February 2019): 042046. http://dx.doi.org/10.1088/1742-6596/1157/4/042046.

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25

Fukuhara, Gaku. "Analytical supramolecular chemistry: Colorimetric and fluorimetric chemosensors." Journal of Photochemistry and Photobiology C: Photochemistry Reviews 42 (March 2020): 100340. http://dx.doi.org/10.1016/j.jphotochemrev.2020.100340.

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26

Plakatouras, John C. "Preface." Pure and Applied Chemistry 85, no. 2 (January 1, 2013): iv. http://dx.doi.org/10.1351/pac20138502iv.

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It is a privilege to act as the conference editor for this issue of Pure and Applied Chemistry (PAC) dedicated to the 12th Eurasia Conference on Chemical Sciences (EuAsC2S-12). The Eurasia Conferences on Chemical Sciences started in Bangkok in 1988 under the leadership of the founders, Bernd M. Rode (Austria), Hitoshi Ohtaki (Japan), and Ivano Bertini (Italy), together with Salag Dhabandana (Bangkok).During the preparation of the present issue of PAC, on 7 July 2012, Ivano Bertini, leading scientist in chemistry and biology, passed away. We will always remember him for his unselfish leadership and enormous contribution in paramagnetic NMR.The aim of the conferences is to foster friendship and exchange of knowledge between chemists in the Eurasian supercontinent as well as those in the Americas and Australia. While all previous conferences have been held in Asia or the Middle East, EuAsC2S-12 took place at the Hotel Corfu Chandris, on the island of Corfu, Greece, on 16-21 April 2012 with the aim of encouraging and enhancing the participation of European scientists and thus help to make them better known. EuAsC2S-12 was organized by the University of Ioannina on the Greek mainland with Emeritus Prof. Nick Hadjiliadis as Chair of the local organizing committee.The total number of participants was 450, with ca. 400 active delegates from 60 countries. The scientific program comprised 14 sessions, each of which was represented by invited speakers and further oral presentations on the following topics:- bioinorganic chemistry- pharmaceutical chemistry and drug design- organic synthesis and natural products- environmental and green chemistry- physical chemistry and spectroscopy- theoretical and computational chemistry- organometallic chemistry and catalysis- clinical biochemistry and molecular diagnostics- coordination chemistry and inorganic polymers- analytical and solution chemistry- supramolecular chemistry and nanomaterials- food chemistry- chemical education- polymer scienceThe scientific program, which was accompanied by a rich social activities program, included 9 plenary lectures, 214 oral presentations, and 190 poster presentations.The collection of 13 papers in this issue of PAC is a representation of the topics related to inorganic chemistry, covered in the lectures held during EuAsC2S-12. The papers represent a good cross-section of major themes ranging from traditional coordination chemistry, bio inorganic chemistry, supramolecular coordination chemistry, catalysis, and inorganic materials.The 13th Eurasia conference will be held in India in December 2014 with Prof. N. Jayaraman, Bangalore as head of the organizing committee.John C. PlakatourasConference Editor
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27

Thevenot, Daniel R., Klara Toth, Richard A. Durst, and George S. Wilson. "International union of pure and applied chemistry physical chemistry division, steering committee on biophysical chemistry analytical chemistry division, commission V.5 (electroanalytical chemistry) Electrochemical biosensors: proposed definitions and classification synopsis of the report." Sensors and Actuators B: Chemical 30, no. 1 (January 1996): 81. http://dx.doi.org/10.1016/0925-4005(95)01816-6.

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28

Portal, Christophe, Delphine Launay, Andrew Merritt, and Mark Bradley. "High Throughput Physical Organic Chemistry: Analytical Constructs for Monomer Reactivity Profiling." Journal of Combinatorial Chemistry 7, no. 4 (July 2005): 554–60. http://dx.doi.org/10.1021/cc050013e.

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29

Tuckermann, Rudolf. "Acoustic levitation in the field of analytical, physical, and atmospheric chemistry." Journal of the Acoustical Society of America 116, no. 4 (October 2004): 2597. http://dx.doi.org/10.1121/1.4785361.

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30

Cicolani, Renato Salviato, Lilian Rodrigues Rosa Souza, Giovanni Batista de Santana Dias, João Manoel Rocha Gonçalves, Isabella dos Santos Abrahão, Vitória Maximino Silva, and Grégoire Jean-François Demets. "Cucurbiturils for environmental and analytical chemistry." Journal of Inclusion Phenomena and Macrocyclic Chemistry 99, no. 1-2 (May 13, 2020): 1–12. http://dx.doi.org/10.1007/s10847-020-00999-8.

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31

Guo, Jian Zhong, Li Liu, and Yan Long Feng. "Analysis on the Application of Multimedia Technology in Basic Chemistry Teaching." Advanced Materials Research 268-270 (July 2011): 679–81. http://dx.doi.org/10.4028/www.scientific.net/amr.268-270.679.

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Directing at the characteristics of the basic chemistry, the paper discusses the characteristics of the “Inorganic chemistry”, “organic chemistry”, “physical chemistry” and “analytical chemistry”, and points out that application of multimedia in the basic chemistry is in line with student’s learning and cognitive rules. And multimedia teaching can greatly improve the teaching efficiency, extend the class size and optimize the teaching effect, which is an important way to teaching reform of course in the Information Age. Then it analyzes the unique role played in teaching by media. While, if multimedia technology is not rationally used in this field, the results will be counterproductive. We try to display the advantages of multi-media teaching and strive to overcome its fault in the teaching process. We also do some discussion on the effects of improving the teaching continuously.
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32

Serafini, Marta, Ilaria Murgia, Mariateresa Giustiniano, Tracey Pirali, and Gian Cesare Tron. "The 115 Years Old Multicomponent Bargellini Reaction: Perspectives and New Applications." Molecules 26, no. 3 (January 21, 2021): 558. http://dx.doi.org/10.3390/molecules26030558.

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Despite its uniqueness, the Bargellini multicomponent reaction remains barely known by the most part of chemists. This can be ascribed to the fact that this transformation has not been adequately reviewed in the classic books of named reactions in organic chemistry. Nevertheless, several works on this reaction have been carried out over the years, many of them were written in Italian in the period 1929–1966. In this review article we extensively cover, in a chronological order, the most important applications of the Bargellini reaction reported to date, with the hope that this knowledge-sharing will help chemists to properly use this multicomponent transformation and imagine novel reactivities based on it.
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33

Koryta, J. "Physical methods of chemistry. Vol. 2. Electrochemical methods." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 255, no. 1-2 (November 1988): 337–38. http://dx.doi.org/10.1016/0022-0728(88)80028-7.

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34

Łobiński, Ryszard, Dirk Schaumlöffel, and Joanna Szpunar. "Mass spectrometry in bioinorganic analytical chemistry." Mass Spectrometry Reviews 25, no. 2 (March 2006): 255–89. http://dx.doi.org/10.1002/mas.20069.

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35

Pan, Sudip, and Gernot Frenking. "A Critical Look at Linus Pauling’s Influence on the Understanding of Chemical Bonding." Molecules 26, no. 15 (August 3, 2021): 4695. http://dx.doi.org/10.3390/molecules26154695.

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The influence of Linus Pauling on the understanding of chemical bonding is critically examined. Pauling deserves credit for presenting a connection between the quantum theoretical description of chemical bonding and Gilbert Lewis’s classical bonding model of localized electron pair bonds for a wide range of chemistry. Using the concept of resonance that he introduced, he was able to present a consistent description of chemical bonding for molecules, metals, and ionic crystals which was used by many chemists and subsequently found its way into chemistry textbooks. However, his one-sided restriction to the valence bond method and his rejection of the molecular orbital approach hindered further development of chemical bonding theory for a while and his close association of the heuristic Lewis binding model with the quantum chemical VB approach led to misleading ideas until today.
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36

Goś, Piotr, Jarosław Chmielewski, Marta Janczura, Damian Gorczyca, and Ewa Żyfka-Zagrodzińska. "Chemical structure, synthesis, and physical and chemical properties of porous polymers as materials applied in analytical chemistry and environmental protection." Ochrona Srodowiska i Zasobów Naturalnych 27, no. 4 (December 1, 2016): 32–36. http://dx.doi.org/10.1515/oszn-2016-0027.

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Abstract This article is part of a series devoted to discussing strategies for the synthesis of ion-imprinted polymers and molecularly imprinted polymers, their chemical structure and great potential, which may be used in porous material design, analytical chemistry, environmental protection and other areas of science. The presented work constitutes a basis for a better understanding of what porous polymers are, how we can synthesise them and how to foresee their properties, which can be later used in studies of environmental pollution and analytical chemistry.
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37

Mateo, Cesar, and Jose Palomo. "Asymmetric and Selective Biocatalysis." Catalysts 8, no. 12 (November 28, 2018): 588. http://dx.doi.org/10.3390/catal8120588.

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The synthesis of compounds or chiral building-blocks with the desired configuration is one of the greatest challenges of chemistry and is of great interest in different fields such as analytical chemistry and especially in fine and pharmaceutical chemistry. [...]
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38

Shlyapnikov, Yury A. "Physical Chemistry of Disorder in Polymer Chains Arrangement." International Journal of Polymeric Materials 18, no. 3-4 (November 1992): 179–87. http://dx.doi.org/10.1080/00914039208029319.

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39

Zhang, Peiran, Hunter Bachman, Adem Ozcelik, and Tony Jun Huang. "Acoustic Microfluidics." Annual Review of Analytical Chemistry 13, no. 1 (June 12, 2020): 17–43. http://dx.doi.org/10.1146/annurev-anchem-090919-102205.

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Acoustic microfluidic devices are powerful tools that use sound waves to manipulate micro- or nanoscale objects or fluids in analytical chemistry and biomedicine. Their simple device designs, biocompatible and contactless operation, and label-free nature are all characteristics that make acoustic microfluidic devices ideal platforms for fundamental research, diagnostics, and therapeutics. Herein, we summarize the physical principles underlying acoustic microfluidics and review their applications, with particular emphasis on the manipulation of macromolecules, cells, particles, model organisms, and fluidic flows. We also present future goals of this technology in analytical chemistry and biomedical research, as well as challenges and opportunities.
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40

Schmitt-Kopplin, Philippe, Daniel Hemmler, Franco Moritz, Régis D. Gougeon, Marianna Lucio, Markus Meringer, Constanze Müller, Mourad Harir, and Norbert Hertkorn. "Systems chemical analytics: introduction to the challenges of chemical complexity analysis." Faraday Discussions 218 (2019): 9–28. http://dx.doi.org/10.1039/c9fd00078j.

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We present concepts of complexity, and complex chemistry in systems subjected to biotic and abiotic transformations, and introduce analytical possibilities to disentangle chemical complexity into its elementary parts as a global integrated approach termed systems chemical analytics.
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41

Mitkin, Valentin N. "Physical–chemical basis for application of fluoroxidants in noble metal analytical chemistry." Spectrochimica Acta Part B: Atomic Spectroscopy 56, no. 2 (February 2001): 135–75. http://dx.doi.org/10.1016/s0584-8547(00)00303-7.

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42

Asher, Sanford A. "UV resonance Raman spectroscopy for analytical, physical, and biophysical chemistry. Part 1." Analytical Chemistry 65, no. 2 (January 15, 1993): 59A—66A. http://dx.doi.org/10.1021/ac00050a001.

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43

Asher, Sanford A. "UV resonance Raman spectroscopy for analytical, physical, and biophysical chemistry. Part 2." Analytical Chemistry 65, no. 4 (February 15, 1993): 201A—210A. http://dx.doi.org/10.1021/ac00052a001.

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44

Thorburn Burns, D. "Physical Methods of Chemistry 2nd edn., Volume IV Microscopy." Analytica Chimica Acta 262, no. 2 (June 1992): 348. http://dx.doi.org/10.1016/0003-2670(92)80080-q.

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45

Steinfeld, J. I. "Femtosecond chemistry." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 51, no. 14 (December 1995): 2591–92. http://dx.doi.org/10.1016/0584-8539(95)90059-4.

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46

Miller, Tierney C., John N. Richardson, and Jeb S. Kegerreis. "Using Mathematical Software To Introduce Fourier Transforms in Physical Chemistry To Develop Improved Understanding of Their Applications in Analytical Chemistry." Journal of Chemical Education 93, no. 2 (November 24, 2015): 299–303. http://dx.doi.org/10.1021/acs.jchemed.5b00493.

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47

Xie, Feng, Hong Tan, Zhan Bin Li, Hong Bo Yang, Hai Da Sun, and Rong Hua Li. "The Influence of Particle Diameter on Analytical Results." Applied Mechanics and Materials 599-601 (August 2014): 196–200. http://dx.doi.org/10.4028/www.scientific.net/amm.599-601.196.

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In analytical chemistry, particle diameter is very important during the sample preparation. A model is presented describing the effects of particle diameter on the content of analyte determines the size of the particle; and the particle size determines the weight of samples and relative standard deviation in the results. This new methodology for the optimisation of physical sample preparation is applied for the first time. Based on this relationship, we can find an extensive application in analytical chemistry.
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48

Levine, Raphael. "Foreword by the Guest Editor: At the Confluence of Physical and Analytical Chemistry." Israel Journal of Chemistry 47, no. 2 (December 2007): NA. http://dx.doi.org/10.1560/ijc.47.2.i.

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49

Williams, Kathryn R., and Loretta H. Tennant. "Micelles in the Physical/Analytical Chemistry Laboratory. Acid Dissociation of Neutral Red Indicator." Journal of Chemical Education 78, no. 3 (March 2001): 349. http://dx.doi.org/10.1021/ed078p349.

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50

Ganadu, Maria Luisa, Francesco Demartin, Angelo Panzanelli, Ennio Zangrando, Massimiliano Peana, Serenella Medici, and Maria Antonietta Zoroddu. "Gold Clusters: From the Dispute on a Gold Chair to the Golden Future of Nanostructures." Molecules 26, no. 16 (August 19, 2021): 5014. http://dx.doi.org/10.3390/molecules26165014.

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The present work opens with an acknowledgement to the research activity performed by Luciana Naldini while affiliated at the Università degli Studi di Sassari (Italy), in particular towards gold complexes and clusters, as a tribute to her outstanding figure in a time and a society where being a woman in science was rather difficult, hoping her achievements could be of inspiration to young female chemists in pursuing their careers against the many hurdles they may encounter. Naldini’s findings will be a key to introduce the most recent results in this field, showing how the chemistry of gold compounds has changed throughout the years, to reach levels of complexity and elegance that were once unimagined. The study of gold complexes and clusters with various phosphine ligands was Naldini’s main field of research because of the potential application of these species in diverse research areas including electronics, catalysis, and medicine. As the conclusion of a vital period of study, here we report Naldini’s last results on a hexanuclear cationic gold cluster, [(PPh3)6Au6(OH)2]2+, having a chair conformation, and on the assumption, supported by experimental data, that it comprises two hydroxyl groups. This contribution, within the fascinating field of inorganic chemistry, provides the intuition of how a simple electron counting may lead to predictable species of yet unknown molecular architectures and formulation, nowadays suggesting interesting opportunities to tune the electronic structures of similar and higher nuclearity species thanks to new spectroscopic and analytical approaches and software facilities. After several decades since Naldini’s exceptional work, the chemistry of the gold cluster has reached a considerable degree of complexity, dealing with new, single-atom precise, materials possessing interesting physico-chemical properties, such as luminescence, chirality, or paramagnetic behavior. Here we will describe some of the most significant contributions.
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