Academic literature on the topic 'Physisorbed'

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Journal articles on the topic "Physisorbed"

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CAMPLIN, J. P., J. K. EVE, and E. M. McCASH. "RAIRS OF SMALL HYDROCARBONS ON Pd(100)." Surface Review and Letters 04, no. 06 (December 1997): 1371–74. http://dx.doi.org/10.1142/s0218625x97001838.

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Ethyne was seen to physisorb on the Pd(100) surface at temperatures below 210 K and chemisorb at temperatures above. Physisorbed multilayers of propyne were observed above a chemisorbed monolayer in the temperature range of 80–130 K. Both alkynes exhibited chemisorption on the Pd surface with the C ≡ C bond parallel to the surface. This led to substantial rehybridisation of the C ≡ C carbon atoms, causing the C–H and C–CH 3 bonds to tilt well away from the surface plane. Ethene was found to form physisorbed multilayers on the Pd (100) surface at temperatures between 28 and 70 K. The RAIR spect
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Sims, Ruby, Sarah Harmer, and Jamie Quinton. "The Role of Physisorption and Chemisorption in the Oscillatory Adsorption of Organosilanes on Aluminium Oxide." Polymers 11, no. 3 (March 4, 2019): 410. http://dx.doi.org/10.3390/polym11030410.

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The effect of physisorbed and chemisorbed species on the time-dependent self-assembly mechanism of organosilane films has been investigated on aluminium oxide using X-ray Photoelectron Spectroscopy. The role of physisorbed species was determined through their removal using a simple rinsing procedure while monitoring film substrate coverage. Removing physisorbed species from Propyldimethylmethoxysilane films, shown to follow a Langmuir-type adsorption profile, reduces the substrate coverage initially but quickly results in coverages equivalent to films that did not undergo a rinsing procedure.
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Li, Qingbin, та Allan LL East. "Catalyzed β scission of a carbenium ion — Mechanistic differences from varying catalyst basicity". Canadian Journal of Chemistry 83, № 8 (1 серпня 2005): 1146–57. http://dx.doi.org/10.1139/v05-135.

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The β-scission mechanism of physisorbed and chemisorbed pentenium ions, as catalyzed by AlH2(OH)2– and by AlHCl3– anions, was investigated using density functional theory computations and explicit-contact modelling. A thorough search of intermediates was performed for each catalyst. On the aluminum chloride, β scission of an aliphatic, secondary carbenium ion featured chemisorbed and physisorbed ion intermediates, while on the aluminum hydroxide, β scission featured chemisorbed ions but physisorbed neutral species. The importance of this work is its demonstration of a qualitatively different m
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Phan Thanh, Hai, Le Tran Thi Ngoc, Mai Truong Thi Cam, Thanh Huynh Thi Minh, and Trung Huynh Thi Mien. "Dibenzyl viologgen adlayer functionalzed graphitic surraces using electrochemical approach." Vietnam Journal of Catalysis and Adsorption 10, no. 1S (October 15, 2021): 14–17. http://dx.doi.org/10.51316/jca.2021.083.

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In this contribution, the electrochemciacl deposition method is used to synthesize uncharged dibenzyl viologen (DBV0) firm on HOPG surface. Electrochemical property and surface structure of the molecular adlayer are characterized by employing a combination of cyclic voltammetry (CV) and scanning electron microscope (SEM). Consequently, the DBV0 molecules generated from the reduction of the corresponding DBV2+ molecules at the solid/liqid interface by applying suitable electrochemical potentials are able to physisorb and form a physisorbed adlayer on HOPG. The existence of the DBV0 adlayer on H
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Carbonell-Coronado, C., F. de Soto, C. Cazorla, J. Boronat, and M. C. Gordillo. "H2 Physisorbed on Graphane." Journal of Low Temperature Physics 171, no. 5-6 (November 16, 2012): 619–25. http://dx.doi.org/10.1007/s10909-012-0828-8.

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Arnold, Thomas, and Stuart M. Clarke. "Diffraction from physisorbed layers." Current Opinion in Colloid & Interface Science 17, no. 1 (February 2012): 23–32. http://dx.doi.org/10.1016/j.cocis.2011.11.003.

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FRANCHY, R., S. K. SO, and P. GAßMANN. "THE ADSORPTION OF OXYGEN ON Hong NiAl(001) AT 300 K AND 20 K." Surface Review and Letters 03, no. 05n06 (October 1996): 1909–17. http://dx.doi.org/10.1142/s0218625x96002825.

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The adsorption of oxygen on NiAl at 300 K and 20 K has been studied by means of high resolution electron energy loss spectroscopy (EELS), low energy electron diffraction (LEED) and Auger electron spectroscopy (AES). The adsorption of oxygen at 300 K leads to formation of a thin film of amorphous aluminum oxide ( a-Al 2 O 3). After oxygen adsorption at 300 K and annealing of the oxygen-saturated surface to 1200 K, a well-ordered thin θ-Al2O3 film is formed. After annealing of the oxygen-saturated surface to 1400 K, an α-like Al 2O3 oxide is grown. Even at 20 K oxidation of the NiAl (001) surfac
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Kokalj, Anton. "Corrosion inhibitors: physisorbed or chemisorbed?" Corrosion Science 196 (March 2022): 109939. http://dx.doi.org/10.1016/j.corsci.2021.109939.

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Bruch, L. W. "Structure of Thin Physisorbed Layers." Materials Science Forum 4 (January 1985): 1–20. http://dx.doi.org/10.4028/www.scientific.net/msf.4.1.

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Adams, John E. "Dynamics of a physisorbed dimer." Journal of Chemical Physics 89, no. 1 (July 1988): 522–28. http://dx.doi.org/10.1063/1.455496.

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Dissertations / Theses on the topic "Physisorbed"

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Griffiths, Paul Thomas. "Photodissociation of physisorbed molecules." Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.267768.

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Palmer, R. E. "Inelastic electron scattering by physisorbed molecules." Thesis, University of Cambridge, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383837.

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Papadantonakis, Kimberly Marshall Okumura Mitchio Lewis Nathan Saul. "Exploration of physisorbed monolayers for molecular-scale surface patterning /." Diss., Pasadena, Calif. : California Institute of Technology, 2009. http://resolver.caltech.edu/CaltechETD:etd-07222008-144633.

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Srepusharawoot, Pornjuk. "Computational Studies of Hydrogen Storage Materials : Physisorbed and Chemisorbed Systems." Doctoral thesis, Uppsala universitet, Materialteori, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-132875.

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This thesis deals with first-principles calculations based on density functional theory to investigate hydrogen storage related properties in various high-surface area materials and the ground state crystal structures in alkaline earth dicarbide systems. High-surface area materials have been shown to be very promising for hydrogen storage applications owing to them containing numerous hydrogen adsorption sites and good kinetics for adsorption/desorption. However, one disadvantage of these materials is their very weak interaction with adsorbed hydrogen molecules. Hence, for any feasible applica
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Guest, Richard James. "Spectroscopic studies of the structure and dynamics of physisorbed oxygen." Thesis, University of Cambridge, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.307039.

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Kagan, Mark R. "Raman spectroscopy of organic molecules physisorbed onto graphitic carbon surfaces /." The Ohio State University, 1996. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487935958848054.

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Gameson, I. "An X-ray study of gases on solids." Thesis, University of Cambridge, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.233976.

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The work described in this thesis is concerned with the study of ph-ysisorbed phases by x-ray diffraction using a conventional sealed x-ray tube source. Diffraction data has been collected for a number of adsorption systems using graphite, a montmorillonite clay (Gel White) and zeolite rho as the substrate. It is well known that phases of unique two-dimensional character can be formed on the surface of graphite, and the structure of adsorbed benzene and hexaflurobenzene on graphite have been studied in this thesis. Contrary to current theoretical predictions the >/7x T/7R19" commensurate struc
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Phillips, Tamsin Katie. "The influence of the carbonyl group in physisorbed monolayers on graphite." Thesis, University of Cambridge, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.609212.

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Conner, Marilyn W. "Theory of solid physisorbed films within the Potts lattice gas model /." The Ohio State University, 1986. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487266691096888.

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Stocker, Matthias [Verfasser]. "Investigations of the role of physisorbed hydrogen in STM experiments / Matthias Stocker." Ulm : Universität Ulm. Fakultät für Naturwissenschaften, 2015. http://d-nb.info/108056294X/34.

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Book chapters on the topic "Physisorbed"

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Kern, Klaus, and George Comsa. "Physisorbed Rare Gas Adlayers." In Chemistry and Physics of Solid Surfaces VII, 65–108. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73902-6_2.

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Gortel, Z. W., and H. J. Kreuzer. "Nonequilibrium Desorption of Physisorbed Atoms." In Kinetics of Interface Reactions, 44–53. Berlin, Heidelberg: Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-72675-0_4.

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Springuel-Huet, M. A. "129Xe NMR of Physisorbed Xenon." In Physical Adsorption: Experiment, Theory and Applications, 331–48. Dordrecht: Springer Netherlands, 1997. http://dx.doi.org/10.1007/978-94-011-5672-1_13.

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Springuel-Huet, M. A. "129Xe NMR of Physisorbed Xenon." In Physical Adsorption: Experiment, Theory and Applications, 349–68. Dordrecht: Springer Netherlands, 1997. http://dx.doi.org/10.1007/978-94-011-5672-1_14.

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Hess, George B. "Multilayer Physisorbed Films on Graphite." In NATO ASI Series, 357–89. Boston, MA: Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-5970-8_20.

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Wandelt, K. "Photoelectron and Auger Electron Emission from Physisorbed Xenon." In Springer Series in Surface Sciences, 224–36. Berlin, Heidelberg: Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-75066-3_28.

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Kern, K., R. David, P. Zeppenfeld, and G. Comsa. "High Resolution He-Scattering Studies of Physisorbed Films." In Springer Series in Surface Sciences, 502–8. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73343-7_82.

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Comsa, G., K. Kern, and B. Poelsema. "Physisorbed Rare Gas Adlayers Studied with Helium Scattering." In Springer Series in Surface Sciences, 243–64. Berlin, Heidelberg: Springer Berlin Heidelberg, 1992. http://dx.doi.org/10.1007/978-3-662-02774-5_10.

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Palmer, R. E., P. J. Rous, and R. F. Willis. "Negative Ion Resonance Electron Scattering from Oriented, Physisorbed O2." In Electron-Molecule Scattering and Photoionization, 123–30. Boston, MA: Springer US, 1988. http://dx.doi.org/10.1007/978-1-4613-1049-5_9.

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Webb, M. B., and E. R. Moog. "LEED Studies of Physisorbed Noble Gases on Metals and Interadatom Interactions." In The Structure of Surfaces, 397–403. Berlin, Heidelberg: Springer Berlin Heidelberg, 1985. http://dx.doi.org/10.1007/978-3-642-82493-7_63.

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Conference papers on the topic "Physisorbed"

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Ruths, M., S. Lundgren, K. Danerlo¨v, and K. Persson. "Tribological Properties of Physisorbed, Unsaturated Fatty Acids." In STLE/ASME 2008 International Joint Tribology Conference. ASMEDC, 2008. http://dx.doi.org/10.1115/ijtc2008-71164.

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We have measured normal and lateral (friction) forces across films of saturated and unsaturated fatty acids with the Surface Forces Apparatus (SFA). When adsorbed onto mica from n-hexadecane, linoleic acid forms a dimer layer between monolayer-covered surfaces. This dimer layer, which is not observed in stearic or oleic acid, is removed at low loads. The remaining linoleic acid monolayers are thinner than the ones formed by stearic and oleic acid, and show a more complex friction response with two regimes of linear friction, higher stability at very high loads, and a dependence of the friction
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Wang, S. J. "Physisorbed surfaces studied by positron annihilation spectroscopy." In The fifth international workshop on slow positron beam techniques for solids and surfaces. AIP, 1994. http://dx.doi.org/10.1063/1.45501.

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Miyake, K., Y. Hori, T. Ikeda, M. Asakawa, T. Shimizu, and S. Sasaki. "Frictional Properties of Alkyl-Substituted Phthalocyanines Physisorbed on Graphite." In World Tribology Congress III. ASMEDC, 2005. http://dx.doi.org/10.1115/wtc2005-63625.

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The frictional properties of alkyl-substituted phthalocyanines physisorbed on the graphite substrate are investigated by atomic force microscopy in liquid condition. the frictional process of alkyl-substituted phthalocyanines physisorbed on the graphite substrate consists of two regions of “shear” and “wear”. In the “shear” process, friction force varies approximately as power law with exponent of 0.6–0.7 (Region I). On the other hand, friction force is maintained substantially constant in the “wear” process (Region II). The experimental data are qualitatively explained by the simplified model
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Hotzel, A., E. Knoesel, Martin Wolf, and G. Ertl. "Controlled modification of surface state lifetimes by physisorbed adsorbates." In Optoelectronics and High-Power Lasers & Applications, edited by Hai-Lung Dai and Hans-Joachim Freund. SPIE, 1998. http://dx.doi.org/10.1117/12.307125.

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Schoen, P. A. E., D. Poulikakos, J. H. Walther, and P. Koumoutsakos. "Temperature driven transport of gold nanoparticles physisorbed inside carbon nanotubes." In 2006 Sixth IEEE Conference on Nanotechnology. IEEE, 2006. http://dx.doi.org/10.1109/nano.2006.247614.

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McGonigal, G. C., R. H. Bernhardt, Y. H. Yeo, and D. J. Thomson. "STM Imaging of Physisorbed Molecules at the Liquid/Graphite Interface." In Scanned probe microscopy. AIP, 1991. http://dx.doi.org/10.1063/1.41411.

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Varakin, Vladimir N., S. P. Kabanov, and Alexander P. Simonov. "Desorption of physisorbed molecules electronically excited by radiation of excimer lasers." In ICONO '98: Laser Spectroscopy and Optical Diagnostics--Novel Trends and Applications in Laser Chemistry, Biophysics, and Biomedicine, edited by Andrey Y. Chikishev, Victor N. Zadkov, and Alexei M. Zheltikov. SPIE, 1999. http://dx.doi.org/10.1117/12.340024.

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Harris, S. M., and S. Holloway. "Resonant inelastic scattering of electrons from gas-phase and physisorbed N2." In The 54th international meeting of physical chemistry: Fast elementary processes in chemical and biological systems. AIP, 1996. http://dx.doi.org/10.1063/1.50174.

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Krim, Jacqueline. "QCM Studies of Phononic and Electronic Contributions to Sliding Friction in Adsorbed Monolayers." In World Tribology Congress III. ASMEDC, 2005. http://dx.doi.org/10.1115/wtc2005-64097.

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Studies of the fundamental origins of friction have undergone rapid progress in recent years with the development of new experimental and computational techniques for measuring and simulating friction at atomic length and time scales. The increased interest has sparked a variety of discussions and debates concerning the nature of the atomic-scale mechanisms, which dominate the dissipative process by which mechanical energy is transformed into heat. Measurements of the sliding friction of physisorbed monolayers and bilayers provides information on the relative contributions of electronic to pho
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Igarashi, Sin-ichi, Takato Hirayama, Ichiro Arakawa, and Yukio Abe. "Ellipsometric study of rare gas films physisorbed on a surface of a metal single crystal." In International Symposium on Polarization Analysis and Applications to Device Technology, edited by Toru Yoshizawa and Hideshi Yokota. SPIE, 1996. http://dx.doi.org/10.1117/12.246227.

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Reports on the topic "Physisorbed"

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Krim, Jacqueline. Adhesion Measurements of Physisorbed Layers on Metal Surfaces. Fort Belvoir, VA: Defense Technical Information Center, April 1992. http://dx.doi.org/10.21236/ada251428.

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