Dissertations / Theses on the topic 'Pinus patula – Mechanical properties'

Thesis (MScFor (Dept. of Forest and Wood Science)--University of Stellenbosch, 2010.
ENGLISH ABSTRACT: In this study 1345 pieces of 38x114 mm timber sawn from 16-20 year-old Pinus patula trees were obtained from a wide variety of sites along the Mpumalanga escarpment in South Africa. The samples were tested for various mechanical and physical properties. The objectives of this study were (1) to determine the variation in the bending strength, tension strength, and stiffness of the sawn timber, (2) to assess the efficiency of the current visual and mechanical grading rules on this sample, and (3) to evaluate the potential of some indicator properties to be used as structural grading parameters on this resource. A large number of non-destructive measurements were performed on all the samples, including scanning of the boards with a commercial X-ray density scanner, moisture content measurement, growth ring measurements, warp measurement, acoustic frequency measurement and measurement of the stiffness using a mechanical grader. The data from the X-ray density scanner was used to calculate a number of knot-related variables for each board. Visual grading according to the SANS 1783-2 (2005) specifications for structural timber was performed by a certified grader on all the boards. The timber was divided into two groups for destructive testing, one group each for bending and tension tests. Tests were conducted according to the SANS 6122 (1994) method for in-grade testing. Due to the sampling method followed, the destructive tests effectively used a random placement of defects with regard to the load application position. From the destructive tests the modulus of elasticity (MOEedge), bending strength (MOR) and tensile strength were determined. The study showed that the MOEedge of the sawn timber was far below the requirements of the current national standard (SANS 10163-1) for all of the visual and mechanical grades. The mean MOEedge of the visually graded S5 timber was about 30% lower than required. The 5th percentile values for bending strength of all the visual and mechanical grades were above the required values of SANS 10163-1. The 5th percentile values for tensile strength of all the visual and mechanical grades were similar to that required by the SANS 10163-1 standard. Correlations between flatwise measured MOE (MOEflat) and edgewise measured MOE (MOEedge) were smaller than expected, as well as the correlations between both MOEedge and MOEflat with MOR. Dynamic MOE (MOEdyn), calculated from acoustic frequency tests on the timber, was found to be the best single predictor of MOEedge, MOR and tension strength. Multiple regression analysis showed that a combination of MOEdyn, density and knot parameters can be used to improve the predictability of some of the strength and stiffness characteristics of the timber. It is recommended that a comprehensive study on the structural grading of SA Pine be performed which includes (1) an analysis of market requirements in terms of strength and stiffness properties of timber, (2) in-grade testing of a representative sample of structural timber in South Africa, and (3) a review of the standards used in South Africa to regulate the structural grading of timber.
AFRIKAANSE OPSOMMING: In hierdie studie is 1345 stukke 38x114 mm 16-20 jaar-oue Pinus patula planke, afkomstig van ‘n wye verskydenheid groeiplekke teen die Mpumalanga platorand in Suid Afrika, gebruik. Die planke is getoets vir verskeie meganiese sowel as fisiese eienskappe. Die doelwitte van hierdie studie was om (1) die variasie in buigsterkte, treksterkte en styfheid van die gesaagde planke te bepaal, (2) die effektiwiteit van die huidige visuele -en meganiese graderingsreëls op hierdie monster planke vas te stel, en (3) die potensiaal te evalueer van sommige eienskappe wat gebruik kan word as strukturele graderingsparameters. ‘n Groot hoeveelheid nie-destruktiewe toetse is op alle planke uitgevoer, wat ingesluit het skandering van planke met ‘n kommersiële X-straaldigt-heidskandeerder, metings van voginhoud, groeiringwydtes, deformasie, akoestiese frekwensie en die bepaling van styfheid met behulp van ‘n meganiese gradeerder. Die data van die X-straalskandeerder is gebruik om ‘n aantal kwasverwante veranderlikes vir elke plank te bereken. Visuele gradering is op alle planke uitgevoer ooreenkomstig met die SANS 1783-2 (2005) spesifikasies vir strukturele hout deur ‘n gesertifiseerde gradeerder. Die hout is in twee groepe opgedeel vir destruktiewe toetse, een vir buigtoetse en een vir trektoetse, ooreenkomstig met die SANS 6122 (1994) metode vir binnegraadse toetse. As gevolg van die monsternemingsmetodiek wat gevolg is, is daar effektief gebruik gemaak van ‘n lukrake plasing van defekte met betrekking tot die las-aanwendingsposisie. Die modulus van elastisiteit (MOEedge), buigsterkte (MOR) en treksterkte is deur middel van destruktiewe toetsresultate bepaal. Die studie het aangetoon dat die MOEedge van gesaagde hout aansienlik minder as die vereiste van die huidige nasionale standaard (SANS 10163-1) is vir al die visuele en meganiese grade. Die gemiddelde MOEedge van die visueel-gegradeerde S5 planke was omtrent 30% laer as vereis. Die 5de persentiel waardes vir buigsterkte van alle visuele en meganiese grade was hoër as die vereiste waardes soos voorgeskryf deur SANS 10163-1. Die 5de persentiel waardes vir treksterkte van alle visuele en meganiese grade was gelykstaande aan wat vereis word deur SANS 10163-1. Korrelasies tussen MOE, gemeet op die wydte sy (MOEflat), en MOE, gemeet op die diktesy (MOEedge), asook die korrelasies van beide MOEedge en MOEflat met MOR van die planke was laer as verwag. Dinamiese MOE (MOEdyn), wat bereken was vanaf die akoestiese frekwensie resultate, is vasgestel as die beste enkele indikator van MOEedge, MOR en treksterkte. Meervuldige regressie analise het aangetoon dat ‘n kombinasie van MOEdyn, digtheid en kwasparameters gebruik kan word om die voorspelbaarheid van sommige van die sterkte- en styfheids eienskappe van die hout te verbeter. Daar word aanbeveel dat ‘n omvattende studie gedoen word op die strukturele gradering van SA Dennehout, wat insluit (1) ‘n analise van die markbehoeftes in terme van die sterkte- en styfheids eienskappe van hout, (2) binnegraadse toetsing van ‘n verteenwoordigende monster strukturele hout in Suid Afrika, en (3) die hersiening van standaarde in gebruik in Suid Afrika om die strukturele gradering van hout te reguleer.

The study of a methodology to model the mechanical properties of Pinus Radiata takes place from the nanoscopic cell fiber [3] to the board scale level. Gibson and Ashy had generalized wood cells into hexagonal cells, previous work [2] extends the model specifically for Pinus Radiata. Unfortunately, earlier work was done on published data from various sources, not necessary related to Pinus Radiata nor from a common reference piece of characterized Pinus Radiata, making correlation with experimental work [4] difficult. Further work was done by the author on a characterized sample of Pinus Radiata to correlate elastic properties with actual cellular geometry and experimental result. Critical geometrical parameters were studied for a feasible mathematical idealization as necessary parameters to further refine the FEM model. Two approaches were used in evaluating board scale modeling; actual wood cells geometry and idealized hexagonal models. These models are extended to Growth ring model to predict growth ring mechanical properties and validated with experimental results as a preliminary Board scale model. Stol had modeled Wood cells as hexagonal cellular material using Gibson's [1] analytical solution in his work with orthotropic wood wall's properties [2]. Sto1's analytical solution neglects the longitudinal dimension, which in realism is closer to plate than beam. Gibson and Asbhy's work on prediction of cellular properties analytically formed the basis of formulation analytical solution using energy method (Ritz's method) with plate type stiffness function and further extended with shear and longitudinal boundary coupling effect. The plate analytical solution was validated by FEM to be in close agreement, within a 5% error. The model based on real cell geometry and its equivalent regular array of identical cell has broad agreements with experimental values. Further refinements of this model are important steps in the development of a definitive model. Preliminary work on a growth ring FEM model is important as part of the preparation for a board scale model, however further refinements would be necessary for definitive board scale FEM model.

Thesis (PhD(For))--Stellenbosch University, 2014.
ENGLISH ABSTRACT: Pinus patula is the most intensively planted conifer in the tropics and sub‐tropics. In South Africa Pinus patula plantations are the main saw‐log resource for structural lumber production. Improved intensive silvicultural practices and tree breeding have resulted in marked increases in the rate of growth. To reap the financial benefits of the faster growth, plantation managers are more and more inclined to reduce rotation ages, which inevitably results in the production of higher proportions of juvenile wood at final harvest, and lumber which often does not meet the minimum requirements for stiffness for structural lumber. Knowledge of the variation and the accurate prediction of the mechanical properties of the timber of standing trees can have various benefits for growers and processors of trees. It can be used for tree allocation to different processing facilities, for processing production planning, and to assist tree breeders to screen and select for superior breeding material. The objectives of this study were (1), to examine the within‐ and between‐tree variation in wood properties of young South African grown Pinus patula trees known to have important impacts on the suitability of sawn lumber for structural purposes and (2), to develop empirical prediction models for the flexural lumber properties from standing Pinus patula, based on variables that could be assessed non‐destructively from standing trees. Sample material was obtained from 170 trees (16‐20 years old) established in 17 compartments along the Mpumalanga escarpment of South Africa. A large number of variables which could be obtained non‐destructively from the trees while they were still standing, were measured. The trees were subsequently felled and two logs, 2.1 m in length, were extracted from each tree at two height positions. The 340 logs were processed into 1402 pieces of lumber for further measurements and destructive testing. Results showed that the mean modulus of elasticity measured on edge (MOEedge) was far below the limits set for structural grade softwood timber in South Africa. All the desirable properties for structural lumber improved with distance from the pith with the exception of the 5th percentile value for modulus of rupture (MOR), which was higher at the pith than for the boards processed adjacent to the pith. Boards processed from the lower part of the stem were superior in most of the important properties compared to those higher up in the stem. Separate multiple regression models for predicting the average dynamic MOE (MOEdyn) of individual boards, trees and compartments were developed. The models managed to explain 68%, 60% and 95% of the variation in MOEdyn respectively. The models developed for MOR explained 40% and 42% of variability at board and tree level respectively. At compartment level, 80% of the variation in the 5th percentile MOR value could be explained by the model. Sensitivity analyses showed that site index at base age of 10 years, acoustic time‐of‐flight, wood density and ring width were the most influential variables in the MOE models. The models indicated that tree slenderness during early growth seems to play a major role in determining the dynamic MOE and MOR of lumber. This is in agreement with Euler’s buckling theory and the bending stress theory. Microfibril angle (MFA) and density were measured on radial strips taken from a sub‐sample of trees with the Silviscan 3 technology. The mean microfibril angle per year ring in Pinus patula varied between 7o and 29o. In general MFA decreased with distance from the pith and height above ground level. A multiple regression model including microfibril angle, density and ring width explained 71% of the variation in the dynamic MOE of boards. Sensitivity analysis on the model showed that microfibril angle and density had roughly equal influences on predicting the MOEdyn of Pinus patula boards.
AFRIKAANSE OPSOMMING: Pinus patula is die mees aangeplante naaldhoutspesie in die tropiese en sub‐tropiese areas van die wêreld. Dit is die grootste bron van saagblokke vir die produksie van strukturele hout in SA. Intensiewe boskultuurpraktyke en boomteling het gelei tot ‘n merkbare verhoging in die groeitempo van die spesie. Plantasiebestuurders is gevolglik geneig om rotasie‐ouderdomme te verlaag, wat lei tot ‘n groter persentasie jeughout wat nie aan die minimum styfheidvereistes van strukturele hout voldoen nie. Kennis van die variasie en die akkurate voorspelling van die meganiese eienskappe van staande bome kan voordele inhou vir beide die verbouers en verwerkers van bome. Dit kan byvoorbeeld van hulp wees met die toewysing van bome aan verwerkingsfasiliteite, vir produksiebeplanning, en vir ondersteuning met die keuse van teelmateriaal vir boomtelers. Die doelwitte van hierdie studie was (1), om die binne– en tussenboomvariasie in die houteienskappe, wat ‘n bepalende invloed het op die geskiktheid van jong Suid Afrikaanse Pinus patula bome vir strukturele hout produksie, te ondersoek en (2), om empiriese modelle vir die voorspelling van die buigeienskappe van planke te ontwikkel, gebaseer op veranderlikes wat niedestruktief op staande Pinus patula bome ge‐evalueer is. Monsters vir die studie is verkry vanaf 170 bome (16‐20 jaar oud), geplant in 17 vakke op die Mpumalanga platorand van Suid Afrika. ‘n Groot aantal veranderlikes is nie‐destruktief gemeet op die staande bome waarna die bome gevel is en twee saagblokke, 2.1m in lengte, is op twee hoogte posisies uit elke boom verwyder. Die 340 blokke is verwerk tot 1402 planke vir verdere metings en destruktiewe toetse. Resultate het getoon dat die gemiddelde modulus van elastisiteit gemeet op die dwarskant (MOEedge) aansienlik laer was as wat vereis word vir strukturelegraad hout in Suid Afrika. Al die gewenste eienskappe het toegeneem met afstand vanaf die murg behalwe die 5de persentiel breekmodulus (MOR), wat hoër was vir murgplanke as vir aangrensende planke. Planke afkomstig van die laer dele van die stam het oor die algemeen beter eienskappe gehad as planke afkomstig van die hoër dele. Veelvuldige regressiemodelle kon 68%, 60% en 95% van die variasie in die gemiddelde dinamiese MOE (MOEdyn) op die vlak van onderskeidelik individuele planke, bome en vakke verklaar. Die modelle vir MOR kon 40% en 42% van die variasie op onderskeidelik plank‐ en boomvlak verklaar. Die model vir 5de persentiel MOR van vakke kon 80% van die variasie verklaar. ‘n Sensitiwiteitsanalise het aangetoon dat groeiplekindeks op ouderdom 10, akoestiese vlugtyd, digtheid en jaarringwydte die belangrikste veranderlikes was wat MOEdyn beïnvloed het. Die modelle het aangetoon dat die slankheid van bome tydens vroeë groei vermoedelik ‘n belangrike invloed op die MOEdyn en MOR van planke het. Dit is in ooreenstemming met Euler se knikteorie en die buigsterkteteorie. Die mikrofibrilhoek en digtheid van ‘n steekproef van die bome is gemeet met die Silviscan 3 apparaat. Die gemiddelde mikrofibrilhoek per jaarring het tussen 7 o en 29o varieer. Hierdie variasie was hoofsaaklik afhanklik van boomhoogte en aantal jaarringe vanaf die murg. ‘n Veelvuldige regressiemodel wat mikrofibrilhoek, digtheid en jaarringwydte insluit, kon 71% van die variasie in MOEdyn verklaar. ‘n Sensitiwiteitsanalise op die model het aangetoon dat mikrofibrilhoek en digtheid ongeveer ewe belangrik was wat betref hulle invloed op die voorspelde MOEdyn van Pinus patula planke.

The objectives of this study were to study wood property variation in Pinus patula from different physiographic sites, the interrelationship between wood properties and the effects of some forest site factors on wood properties and their within-tree variation. The wood properties considered were density, transverse shrinkage, grain angle and stiffness (modulus of elasticity). Ten trees were taken from each of seventeen sites selected during a previous study of soil ecology and tree growth patterns on the escarpment of Mpumalanga in South Africa. This is a complex physiographic region with several different growth sites within a relatively small geographical area. The key finding of the study was that the effect of radial distance from the pith (i.e. the age of the tree) was highly significant and accounted for most of the variation of the trees sampled. Although the effect of site on the selected wood properties was highly significant, its effect accounted for a relatively small percentage of the total variation in each case. Consequently, solid wood processors must take into account the large variation within a tree when implementing strategies to minimise the downgrade of timber as result of excessive board distortion and/or inferior strength. There were significant correlations between wood density and density slope, radial shrinkage, shrinkage ratio and stiffness and also significant correlations between wood stiffness and density slope and radial shrinkage. Density and grain angle both showed significant correlations with the most important climatic factors. ‘Growth days’ (which is an index reflecting the number of days per year when soil moisture is not a limiting factor for plant growth) was identified as one of the principal growth factors influencing the selected wood properties, because of it’s strong relationships with wood density, density slope, grain angle and stiffness. Regression models were developed to predict wood density and grain angle from growth variables. The results show that those wood properties that correlate with geographic representable site variables can be included in site classification and evaluation systems, to assist in predicting growth in terms of volume yield and wood quality.

A possibilidade de utilização da técnica de colorimetria para obter informações relevantes das peças de Pinus é uma excelente alternativa, uma vez que o colorímetro é um equipamento de fácil manuseio e rápida aquisição de dados, e o uso de madeira de florestas plantadas é crescente no Brasil. O objetivo desta pesquisa foi gerar modelos de regressão para estimativa da densidade aparente e das propriedades mecânicas (resistência e módulo de elasticidade) em função de parâmetros colorimétricos. Nesta pesquisa, 403 amostras de Pinus sp. foram caracterizadas de acordo com o sistema CIE L*a*b*, utilizando um colorímetro Konica Minolta. A densidade aparente, a resistência à compressão paralela às fibras e o módulo de elasticidade na compressão paralela às fibras das 403 amostras também foram determinados, de acordo com as premissas do Anexo B da norma brasileira ABNT NBR 7190 (1997). Foi proposto um modelo de regressão multivariável e testado utilizando análise de variância (ANOVA), ao nível de significância de 5%, para estimar as três propriedades citadas, em função dos parâmetros colorimétricos e do número anéis de crescimento (quantidades de lenho inicial e lenho tardio). Os resultados indicaram que a madeira apresenta coloração branco-amarelada, pois possui valor de luminosidade (L*) superior a 54. A pigmentação amarela (b*) é a principal responsável pela formação das cores no gênero Pinus. A análise de correlação entre cor, número de lenhos (Nle) e densidade revelou que apenas a luminosidade, o número de lenhos e a interação desses fatores afetaram significativamente os valores de densidade. A diminuição da luminosidade e o aumento na quantidade de lenhos implicam um aumento significativo nos valores de densidade da madeira. A análise de correlação entre cor, número de lenhos e módulo de elasticidade revelou que apenas o número de lenhos afetou significativamente os valores do módulo de elasticidade. O aumento no número lenhos implica aumento significativo no módulo de elasticidade na compressão paralela às fibras. A análise de correlação entre cor, número de lenhos e resistência à compressão paralela às fibras mostrou que apenas os fatores L*, a*, b* e as interações L*·b*, a*·b*, afetaram significativamente os valores da resistência. A interação entre os fatores L* e b* implicou na redução dos valores da resistência à compressão paralela às fibras. A técnica de colorimetria mostrou-se adequada para a estimativa de propriedades físico-mecânicas da madeira.
The possibility of using the colorimetric technique to obtain relevant information of Pinus pieces is an excellent alternative, since the colorimeter is an equipment of easy handling and quick data acquisition, and the use of wood from planted forests is growing in Brazil. This research aims to generate regression models to estimate the wood density and mechanical properties (strength and modulus of elasticity) as a function of colorimetric parameters. Here, 403 pieces of Pinus sp. have been characterized according to the CIE L*a*b* system using a Konica Minolta colorimeter. The apparent density, the compression parallel to the grain strength and the modulus of elasticity in the compression parallel to the grain of the 403 samples were also determined, according to the assumptions of Brazilian standard code ABNT NBR 7190 (1997). It was proposed a multivariate regression model and tested using analysis of variance (ANOVA), at 5% significance level, to estimate the density, the compressive strength and the modulus of elasticity as a function of the colorimetric parameters and the number of tree growth rings (earlywood and latewood). Results indicated that the wood has a yellowish-white coloration, with a value of brightness (L*) higher than 54. The yellow pigmentation (b*) is the main responsible for the color formation of the genus Pinus. Correlation analysis among color, number of tree growth rings (Nle) and density showed that only the brightness, the number of tree growth rings and the interaction of these factors affected significantly the values of density. Decreasing in brightness and increasing in the number tree growth rings implies a significant increasing in wood density values. Correlation analysis among color, number of tree growth rings and modulus of elasticity showed that only the number of tree growth rings affected significantly the values of modulus of elasticity. Increasing in the number tree growth rings implies a significant increasing in the modulus of elasticity. Correlation analysis among color, number of tree growth rings and compression parallel to the grain strength showed that only the factors L*, a*, b* and the interactions L* ·b*, a*· b*, affected significantly the values of strength. The interaction between the factors L* and b* implied the reduction of the values of the compression parallel to the grain strength. The colorimetric technique was appropriated for estimative of physico-mechanical properties of wood.

O setor da construção civil é um dos que mais consomem recursos naturais e utilizam energia de forma intensiva, gerando consideráveis impactos ambientais juntamente com grande quantidade de resíduos. A utilização de produtos alternativos como painéis de madeira surge como uma possibilidade de redução de tais impactos. O Oriented Strand Board, desenvolvido para substituir o painel compensado, tem conquistado cada vez mais espaço na construção apesar de sua menor estabilidade dimensional perante o seu antecessor. A adição de resíduos, como o plástico, na matriz constituinte destes painéis representa alternativa de reaproveitamento destes descartes e economia de madeira no processo produtivo destes compósitos, além de proporcionar melhoria nas propriedades físicas dos mesmos. O objetivo deste trabalho foi confirmar a viabilidade técnica da produção de painéis OSB de madeira de Pinus sp. com adição de proporções de 20 e 30% de partículas de polipropileno biorientado em sua matriz constituinte e resina poliuretana à base de óleo de mamona. A avaliação de desempenho foi feita por intermédio das propriedades físicas e mecânicas dos painéis, determinadas atendendo as recomendações da EN 300 (1999). Os painéis foram classificados como OSB 4, de acordo com as propriedades físicas avaliadas, e OSB 1, considerando os módulos de elasticidade e ruptura obtidos em ensaios de flexão estática. A adesão interna, para os painéis produzidos com os parâmetros de processo adotados, não alcançou os valores exigidos pela citada norma. De todas as propriedades avaliadas, apenas inchamento em espessura e absorção de água foram influenciadas pela porcentagem de BOPP. Assim, considera-se comprovada a viabilidade técnica da produção dos painéis OSB deste trabalho, para aplicação na construção civil.
Building construction is one of the sectors that most consuming natural resources and use energy intensively, generating considerable environmental impacts coupled with large amount of waste. Employing alternative product like wood panels comes as a possibility to reduce these impacts. Oriented Strand Board, developed to substitute the plywood panel, has gained more space in the construction spite of its lower dimensional stability against its predecessor. The addition of plastic waste in constitutive matrix of these panels represents an alternative to reuse this kind of waste and wood economy in the productive process of these composites, besides improving their physical properties. The aim of this study was to evaluate the technical feasibility of producing OSB of Pinus sp. wood with the addition of various proportions of particles of bioriented polypropylene in its constitutive matrix and polyurethane resin based on castor oil with evaluation of physical and mechanical properties of these panels. In accordance with EN 300 (1999), the OSB panels have been classified as 4 in accordance with the physical properties assessed and as OSB 1 for the elasticity modules and rupture. Property of internal bond not presented the minimum values required by the same standard. Of all properties evaluated, only thickness swelling and water absorption were influenced by the percentage of BOPP. However, it is considered completely evidenced the technical viability of production of the OSB of this work, and its potential employability in civil construction sector.

O presente trabalho teve como objetivo avaliar o potencial de utilização da madeira do híbrido Pinus elliottii var. elliottii x Pinus caribaea var. hondurensis para a produção de lâminas e manufatura de painéis compensados. Para realização do estudo foram utilizadas 10 toras de 1,30 m de comprimento, provenientes de 5 árvores coletadas aos 7 anos e 10 meses de idade nos plantios da empresa Pinus Brasil, localizada em Buri - SP. O rendimento do processo de laminação das toras e a qualidade das lâminas produzidas foram avaliados. O delineamento para a produção experimental e avaliação dos painéis compensados constituiu-se de 8 tratamentos arranjados em esquema fatorial, através dos quais foram analisados os efeitos de duas posições de retirada da tora no tronco (A e B), duas gramaturas de adesivo (380 e 420g/m²) e dois tempos de prensagem (8 e 12 minutos). Para cada tratamento foram produzidos 3 painéis compensados, cada qual com 5 lâminas coladas entre si com adesivo à base de fenol-formaldeído. O rendimento médio do processo de laminação das toras, sem casca, foi de aproximadamente 53%, podendo ser considerado bom e compatível com outros resultados encontrados na literatura. As toras A, mais próximas da base das árvores, produziram maior número de lâminas, no entanto, de qualidade inferior em relação às lâminas das toras (B). A massa específica aparente dos painéis estudados foi relativamente baixa em comparação a outros compensados de Pinus, cuja propriedade apresentou valor médio estatisticamente superior para os compensados confeccionados com lâminas das toras A. Os painéis apresentaram boa estabilidade dimensional, sendo que o tempo de prensagem de 12 minutos para a produção dos compensados resultou em diminuição estatisticamente significativa do inchamento em espessura. O tempo de prensagem, gramatura de adesivo e posição da tora influenciaram os valores de resistência da colagem dos painéis, sendo que os maiores valores foram observados para os painéis produzidos com lâminas das toras B, tempo de prensagem de 12 minutos e gramatura de 420g/m². Os valores médios do módulo de ruptura (MOR) e do módulo de elasticidade (MOE) à flexão estática dos painéis foram, respectivamente, compatíveis e inferiores quando comparados com os do Catálogo Técnico n°1 Compensados de Pinus (ABIMCI, 2002). Houve efeito do fator posição da tora no MOR paralelo dos painéis e o maior valor médio foi observado para os compensados confeccionados com lâminas das toras da posição A. Houve interação entre os fatores posição da tora e tempo de prensagem para o MOR e MOE perpendiculares, sendo que, de modo geral, os menores valores foram observados para os compensados confeccionados com lâminas das toras B e prensados no tempo de 12 minutos. Conclui-se que a madeira do híbrido estudado apresenta bom potencial para a produção de lâminas e manufatura de compensados. Porém, o emprego desses painéis em produtos que requeiram elevados valores do MOR e do MOE, por exemplo, em formas de concreto, não é aconselhável, porque esses painéis não satisfariam tais requisitos.
The main objective of this work was to evaluate the potential of wood utilization from Pinus elliottii var. elliottii x Pinus caribaea var. hondurensis hybrid for veneer production and plywood manufacturing. This study used 10 logs measuring 1.30m in length, obtained from 05 trees, 07 years and 10 months of age, from plantations located in Buri SP, Brazil. Peeling process yield and quality of veneers produced were evaluated. The experimental design consisted of eight treatments, arranged in a factorial way, being the effects of two log positions (A and B) on the trunk, two adhesive spread rates (380 and 420g/m²) and two press times (8 and 12 minutes). Three plywood panels were produced for each treatment and each panel was constituted of 05 veneers glued with an adhesive based on phenol-formaldehyde. The peeling process yield was approximately 53%, based on logs without bark, and can be considered good and compatible with other results found in the literature. The logs A, closer to the base of the tree, produced a greater number of veneers, but of inferior quality compared to the logs B veneers. The apparent specific mass of the plywood panels was relatively low, compared to other Pines plywood available in the literature, with a superior mean value for the plywood made with veneers of logs A comparing to logs B. The plywood panels showed good dimensional stability. The press time of 12 minutes resulted in significant thickness swelling decrease and the press time, adhesive spread rate and log position, influenced the bonding line strength. The best results of bonding line strength were obtained for the plywood produced with logs B veneers, press time of 12 minutes and spread rate of 420g/m². The static bending properties of the plywood panels studied, modulus of rupture (MOR) and modulus of elasticity (MOE),were compatible and inferior, respectively, compared to other Brazilian-pines plywood. There was an effect of the log position factor on the MOR-parallel-to-grain with best results obtained for plywood panels produced with veneers of logs A. There was interaction between the log position and press time factors on the MOR and MOE, both perpendicular-to-grain, with the lowest values observed for plywood panels produced with log B veneers and press time of 12 minutes. The hybrid pine wood studied has good potential for veneer production and plywood manufacturing. However, the use of these panels in products that require high values of MOR and MOE, for example, in formwork is not advisable, because these panels do not satisfy these requirements.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
O setor madeireiro tem crescido nos últimos anos no Brasil, visto que o país possui vastas áreas com florestas de reflorestamento. Entretanto, com o passar dos anos, tem crescido a consciência de uma melhor utilização das matérias-primas, inclusive da madeira. Neste contexto, surgem os painéis à base de madeira, os quais utilizam melhor as toras, que podem ser de diferentes dimensões. Dentre estes painéis, destaca-se o compensado laminado, que é um painel produzido com um número ímpar de lâminas de madeira, dispostas perpendicularmente umas às outras com relação a direção da grã. Este painel possui ampla utilização, principalmente na indústria moveleira e na construção civil, podendo ser utilizado em construções do tipo wood frame. Além disso, o compensado necessita passar por algum processo de tratamento contra o ataque de fungos, insetos e intempéries. Assim, este estudo teve o objetivo de analisar a influência de tratamentos preservativos nas propriedades físicas e mecânicas do compensado laminado de Pinus taeda. Para isso, foi realizada a termorretificação, com três diferentes temperaturas (160°C, 180°C e 200°C) e o tratamento químico com CCA. Foram realizados os tratamentos das lâminas antes da produção do compensado e os tratamentos dos painéis já produzidos, sem prévio tratamento das lâminas, com o intuito de avaliar qual forma de tratamento é a mais adequada. Foram realizadas as análises de teor de extrativos totais, molhabilidade das lâminas, microscopia eletrônica de varredura e testes físicos e mecânicos. Os resultados obtidos mostraram que os tratamentos de termorretificação e o tratamento com CCA melhoraram a estabilidade dimensional do painel compensado, devido às alterações químicas ocorridas na madeira. Além disso, ambos os tratamentos diminuíram a resistência mecânica à flexão estática e a qualidade de colagem. Entretanto, todos os tratamentos continuaram a atender as especificações mínimas de órgãos normativos. Com base em todas as análises concluiu-se que a termorretificação do painel a 200°C mostrou-se mais adequada.
The forestry sector has grown recently in Brazil, since the country has vast reforestation fields. However, over the years, there has been growing the consciousness of a better use of raw materials, including wood. In this context arise the wood based panels, which make better use of logs, which may be of different dimensions. Among these panels is highlighted the plywood, which is a panel produced with an odd number of wood veneers arranged perpendicularly to each other with respect to the grain direction. This panel has wide application, especially in the furniture industry and in construction and can be used in wood frame type construction. Besides that, the plywood needs to undergo some treatment process against the attack of fungi, insects and weatherproof. Thus, this study aims to analyze the influence of preservative treatments on physical and mechanical properties of Pinus taeda plywood. To this were performed the heat treatment with three different temperatures (160 °, 180 ° C and 200 ° C) and chemical treatment with CCA. It was carried out the veneers treatments before the production of plywood and the panel treatment, without prior veneers treatment, in order to assess which form of treatment is most appropriate. The analyzes of extractive content, veneers wettability, scanning electron microscopy and physical and mechanical tests were performed. The results showed that the heat treatment and CCA treatment improved the dimensional stability of the plywood due to chemical changes in the wood. In addition, both treatments decreased mechanical strength in static bending and bonding quality. However, all treatments continued to meet the minimum specifications of specialized organs. Based on all the analyzes it was concluded that the heat treatment of the panel at 200°C was more adequate.

Os painéis OSB estão disponíveis desde o início da década de 1980, constituindo a segunda geração das chapas waferboard. Trata-se de painel estrutural com a camada interna de partículas de madeira dispostas perpendicular ou aleatoriamente em relação às camadas de partículas externas. No presente trabalho, caracterizou-se a estrutura anatômica do lenho de árvores de Pinus taeda e as propriedades físico-mecânicas dos painéis OSB de partículas da madeira de rolo-resto e de toras integrais. Os resultados das análises laboratoriais permitiram concluir que a estrutura anatômica do lenho e dos anéis de crescimento é característica da espécie, com os anéis de crescimento possibilitando determinar a idade, a taxa de crescimento e a reação das árvores aos desbastes. A variação radial das dimensões das traqueides e da densidade aparente do lenho por densitometria de raios X relaciona-se com a formação da madeira juvenil, de transição e adulta e com as propriedades das partículas de madeira. Essas características da madeira e das partículas de rolo-resto e de tora integral influenciaram nas propriedades dos painéis OSB em relação à densidade média, perfil de densidade aparente por densitometria de raios X, resistência das partículas à tração paralela das traqueídes, propriedades físico-mecânicas, dentre outras. A utilização do rolo-resto, resíduo da laminação de toras de pinus, como partículas de madeira para a confecção de painéis OSB é discutida no presente trabalho.
OSB panels are available since the early 1980\'s and constitutes the second generation of \"waferboard\" plates. It is structural panel with the inner layer of wood particles arranged randomly or perpendicular in relation to the external layers of particles. The present study characterized the wood anatomical structure of Pinus taeda trees and physical-mechanical properties of OSB panels of wood particles of roll-rest (residue of the log lamination) and integral logs. The results of laboratorial analysis concluded that the wood and tree-ring anatomical structure is characteristic of the species, the tree-rings is applied to determine the trees age, growth rate and trees response to the thinning. The radial variation of the tracheid dimensions and wood density - by X-ray densitometry - is related to the formation of juvenile, transition and adult wood and the properties of wood particles. These characteristics of wood and wood particles of roll-rest and integral logs influenced the properties of OSB panels with respect to the mean density, density profile by X-ray densitometry, resistance to the shear strength of the particles of tracheids, physical and mechanical properties, etc. The use of residues of lamination process pine logs to wood particles for the manufacture of OSB panels is discussed.

O presente trabalho foi realizado no âmbito do projecto nacional – Valorização do lenho de acácia produzido em Portugal. Potenciais utilizações (POCTI/42594/AGR/2001), e do projecto GEMINI - Genetic determination of maritime pine pulp and paper properties. Comissão das Comunidades Europeias, Projecto GEMINI – QLK5-CT-1999-00942. Bolsa de doutoramento (SFRH/BD/42073/2007) atribuída pela Fundação para a Ciência e Tecnologia (FCT) co-financiada pelo programa POCI 2010 – Formação Avançada para a Ciência – Medida IV.3 e pelo FSE.

O tratamento térmico da madeira (ou termorretificação) é realizado com o aquecimento da madeira em faixas de temperaturas inferiores à carbonização, até 280ºC. O objetivo desta tecnologia é melhorar as propriedades da madeira e, desta forma, proporcionar a obtenção de produtos com maior valor agregado. Neste trabalho, avaliou-se o comportamento em peças estruturais das espécies Eucalipto citriodora (Corymbia citriodora) e Pinus taeda, tratadas termicamente nas temperaturas de 160, 180, 200, 220 e 240ºC e, para o pínus, até a temperatura de 260ºC. Os ensaios experimentais realizados para a madeira tratada termicamente foram de classificação visual, obtenção de suas propriedades químicas, físicas, mecânicas (resistência e rigidez), entomológicas e com fungos. Quanto à análise química, foi identificado redução nos teores de extrativos e hemiceluloses, após termorretificação das amostras, e aumento no teor de celulose e lignina. A densidade aparente e a propriedade de inchamento das madeiras reduziram com o aumento da temperatura, e a permeabilidade a gás aumentou para o eucalipto. As mudanças nas propriedades colorimétricas das madeiras levaram ao escurecimento, devido à degradação dos seus principais componentes químicos, principalmente as hemiceluloses. De uma maneira geral, as propriedades de resistência (à compressão, à flexão, à tração e ao cisalhamento paralelo às fibras) das madeiras diminuiram e as propriedades de rigidez (módulo de elasticidade na compressão Eco e o MOE) aumentaram ao longo do tratamento com calor. A determinação dos valores característicos de resistência para cálculos estruturais foram adequados quando comparados à norma brasileira ABNT NBR 7190/97. O tratamento térmico proporcionou a proteção da madeira de Eucalipto citriodora quando ela foi exposta ao ataque de cupins subterrâneos Nasutitermes sp., de acordo com os ensaios de alimentação forçada, e das madeiras de E. citriodora e Pinus taeda, quando expostas ao fungo de podridão mole (Paecilomyces variotti).
Heat treatment of wood (or thermal rectification) is performed by heating wood below carbonization temperature, up to 280ºC. The aim of this technology is to improve the wood properties and thus to obtain products with higher added value. In this study, we evaluate the behavior of structural pieces of two species: Eucalyptus citriodora (Corymbia citriodora) and Pinus taeda, thermally treated at temperatures of 160, 180, 200, 220 e 240ºC, and pine up to the temperature of 260ºC. The experimental analyses to thermally treated wood were visual grading, chemical, physical, mechanical (strength and stiffness) and durability. Regarding chemical analysis, there was a reduction in the extractive and hemicellulose contents, while and the cellulose and lignin content increased; density and swelling properties decreased with increasing temperature, and the air permeability increased to eucalyptus. Changes in the colorimetric properties of wood caused the species in the study to become darker due to degradation of chemical components, mainly hemicellulose. In general, the strength properties (compression, bending, tension and shear parallel to the grain) of wood reduced and the stiffness properties (elasticity modulus by compression (Eco) and MOE) improved along thermal treatment. The determination of characteristic values of strength to structural calculations was adequate when compared to the Brazilian norm ABNT NBR 7190/97. It was observed that thermal treatment provided protection of wood of Eucalyptus citriodora from subterranean termites attack Nasutitermes sp., in the force-feeding test and Eucalyptus citriodora and Pinus taeda on soft rot fungi Paecilomyces variotti.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
As preocupações ambientais e o esgotamento dos combustíveis fósseis resultaram em um interesse crescente em materiais ambientalmente amigáveis, à base de polímeros naturais. Esforços estão sendo feitos para introduzir a lignina em compostos plásticos, tais como polipropileno, com o objetivo de produzir materiais com boas características mecânicas e, ao mesmo tempo, ambientalmente amigáveis. A lignina é uma matéria-prima amplamente disponível na natureza, que contém alta densidade de compostos aromáticos, os quais são atualmente, em sua maioria, derivados do petróleo. No entanto, grande parte da lignina é utilizada para geração de energia e pode ser um potencial agente poluidor se não destinada de forma adequada. Desse modo, é importante encontrar uma maneira econômica de converter esse polímero natural em materiais de alto valor agregado, como compósitos com alto desempenho mecânico e térmico. Neste estudo, compósitos de polipropileno e de lignina kraft de pinus (LKI) e de bagaço de cana (LBC) foram submetidos à extrusão, e os corpos de prova foram produzidos pelo processo de injeção. Os materiais produzidos foram analisados quanto às propriedades mecânicas, térmicas (TGA, DSC, HDT), química (FTIR), reológica (índice de fluidez) e morfológica (MEV). Os objetivos desta pesquisa foram desenvolver novos compósitos de polipropileno contendo lignina e proporcionar propriedades mecânicas comparáveis aos polipropilenos comerciais, além de obter compósito com alto grau de afinidade entre a lignina e o polipropileno. Os resultados mostraram que a incorporação de lignina na matriz de polipropileno originou, de maneira geral, compósitos com propriedades adequadas para vários segmentos industriais, especialmente aqueles em que características mecânicas e térmicas são cruciais, tais como a substituição de plásticos de engenharia e polipropileno com cargas minerais.
Environmental concerns and the depletion of fossil fuels resulted in a growing interest in environmentally friendly materials based on natural polymers. Efforts are being made to introduce the lignin in plastic composites such as polypropylene, in order to produce materials with good mechanical characteristics and at the same time environmentally friendly. Lignin is a biopolymer widely available which contains high density of aromatic compounds. Nowadays, the aromatic compounds are almost exclusively derived from petroleum. However, the lignin is used mainly to generate energy and can be a pollution potential if not properly treated. Lignin, however, can improve the performance of composites. Moreover, it is important to find an economical way to convert lignin into high value-added materials. In this study, blends of polypropylene, pine kraft lignin (LKI) and sugar cane bagasse lignin (LBC) were subjected to extrusion and the specimens were produced by injection process. The materials produced were analyzed for their mechanical, thermal (TGA, DSC, HDT), chemical (FTIR), rheological (melt flow index) and morphological (SEM) properties. The objective of this research was to develop new lignin-based polypropylene composite with mechanical properties comparable to commercial polypropylene. The results showed that the incorporation of lignin in polypropylene matrix resulted in composites, in general, with properties suitable for various industrial segments, especially those in which mechanical and thermal properties are crucial, such as the replacement of engineering plastics and polypropylene mineral filled.

Temas relacionados ao desenvolvimento de novos materiais têm sido cada vez mais abordados e discutidos, num contexto em que questões como meio ambiente, sociedade, economia de energia e aproveitamento de resíduos, vêm se tornando relevantes. Neste cenário, faz-se necessário estudar aplicações de insumos alternativos na produção de pisos de madeira, tanto para reduzir o consumo de essências tropicais quanto para suprir o aumento da demanda de madeira nas indústrias deste segmento. O objetivo deste estudo foi produzir painéis de partículas homogêneos de alta densidade, com resíduos de madeira de Pinus elliottii e casca de aveia (Avena sativa), aderidos sob pressão com dois tipos de adesivo, poliuretano à base de óleo de mamona e melamina formaldeído, nos percentuais de 11 e 13%, e avaliar o desempenho físico-mecânico de tais painéis para aplicação em pisos. O desempenho físico-mecânico dos painéis (Planejamento I - 20 tratamentos) foi avaliado com base nas normas ABNT NBR 14810 (2006 e 2013). Realizou-se análise de variância (ANOVA) para testar a influência dos fatores individuais (percentual de casca de aveia, percentual de adesivo e tipo de adesivo), além das interações entre tais fatores (dois a dois e três a três) nas propriedades físico-mecânicas dos painéis. Também foi avaliado o desempenho para pisos, tanto dos painéis (Planejamento II - 12 tratamentos) quanto de três espécies de madeira tropical (Angelim Vermelho, Dinizia excelsa; Cumaru, Dipteryx odorata e Jatobá, Hymenaea sp.), segundo diversas normas relacionadas a pisos de madeira. Os resultados apontaram propriedades físico-mecânicas dos painéis, em alguns tratamentos superiores aos requisitos estipulados por normas nacionais e internacionais. Quanto ao desempenho para pisos, os painéis apresentaram desempenho semelhante as três espécies de madeira, na maioria das propriedades avaliadas. A análise de porosimetria por intrusão de mercúrio confirmou a similaridade entre os painéis (do Planejamento II) e as três espécies de madeira avaliadas, evidenciando a potencialidade dos painéis produzidos para aplicação na indústria de pisos engenheirados.
Matters related to the development of new materials have been increasingly addressed and discussed in a context where issues such as the environment, society, energy and waste recovery economy, is becoming relevant. In this scenario, it is necessary to study alternative inputs for applications in the production of wood floors, both to reduce the consumption of tropical essences as to meet the increasing demand for wood in industries in this segment. The aim this study was to produce high density homogeneous particleboard with waste wood of Pinus elliottii and oat hulls (Avena sativa), adhered under pressure with two types of adhesive, castor oil-based polyurethane and melamine formaldehyde, the percentage of 11 and 13%, and evaluate the physical and mechanical performance of such panels for use in floors. The physical-mechanical performance of the panels (Planning I - 20 treatments) was evaluated based on the NBR 14810 (2006 and 2013) standards. We conducted an analysis of variance (ANOVA) to evaluate the influence of individual factors (oat hulls percentage, adhesive percentage and type of adhesive), and the interactions between these factors (two by two and three by three) on the physical properties-mechanical panels. It was also evaluated the performance for floors, both panels (Planning II - 12 treatments) as three species of tropical wood (Angelim Vermelho, Dinizia excelsa; Cumaru, Dipteryx odorata e Jatobá, Hymenaea sp.), according to various standards related to wood floors. The results indicated physical and mechanical properties of the panels, in some treatments superior to the requirements stipulated by national and international standards. As for performance flooring, panels statistically equivalent to the three species of wood, most of the evaluated properties. Porosimetry analysis by mercury intrusion confirmed the similarity between the panels (from Planning II) and the three wood species evaluated, demonstrating the potential of the panels produced for use in the flooring industry engineered.

A utilização de produtos provenientes de fontes renováveis e livres de substâncias tóxicas é tendência global, prova disso é o constante aumento da demanda por produtos à base de madeira. Segundo o Forest Products Statistics (2015), a produção mundial de painéis de madeira reconstituída, em 2014, foi de 388 milhões de m³, um aumento de 5,5% em comparação com o ano anterior e um aumento de 34% quando comparado com 2010. No entanto, o setor industrial de painéis de madeira há décadas enfrenta um grande desafio com relação às emissões tóxicas vindas dos adesivos convencionais. Diante destes problemas, a proposta do presente trabalho foi testar a viabilidade da produção de painéis aglomerados e painéis OSB, com significativa redução da emissão de formaldeído, a partir de resíduos de madeira de Pinus sp. e Tectona grandis (Teca). Neste sentido, buscou-se contribuir para o aumento do conhecimento científico sobre a utilização do polímero natural polihidroxibutirato (PHB) e do resíduo de tinta à base de resina epóxi como adesivos alternativos. Os painéis foram fabricados variando-se os parâmetros de produção para obtenção de melhores condições de processo, sendo estes: densidade baixa, média e alta; teor de adesivo de 20, 30 e 40%; adição de partículas de Teca nas proporções de 0, 25, 50, 75, 100%. O desempenho físico-mecânico dos painéis foi avaliado com base nas normas ABNT NBR 14810 (2013) e ANSI A208.1 (2009). Realizou-se análise de variância (ANOVA) para testar a influência dos fatores individuais (densidade, percentual de adesivo e fração de Teca), além das interações entre tais fatores nas propriedades físico-mecânicas dos painéis. Os resultados apontaram para excelentes propriedades físicas e mecânicas dos painéis aglomerados de média e alta densidade, tendo resíduo de tinta, principalmente, nas proporções de 30 e 40%. Na maioria dos casos as propriedades de tais painéis foram superiores aos requisitos estipulados pela norma brasileira e pelas internacionais. Assim, ficou confirmada a viabilidade de produção dos aglomerados com pelo menos um dos insumos estudados bem como seu potencial de emprego para as finalidades compatíveis com produtos desta natureza.
The use of products from renewable sources and free of toxic substances is a global trend, the proof is the steady increase in demand for wood-based products. According to the Forest Products Statistics (2015), world production of reconstituted wood panels in 2014 was 388 million cubic meters, an increase of 5.5% compared to the previous year and an increase of 34% compared to 2010. However, the industrial sector of wood panels for decades faces a major challenge with regard to toxic emissions coming from conventional adhesives. Faced with these problems, the purpose of this study was to test the feasibility of production of panels and OSB panels, with significant reduction of formaldehyde emissions from wood waste Pinus sp. and teak (Teak). In this sense, we sought to contribute to the increase of scientific knowledge on the use of natural polymer polyhydroxybutyrate (PHB) and residual ink resin-based epoxy as alternative adhesives. The panels were manufactured by varying the production parameters to obtain the best processing conditions, namely: low density, medium and high; resin content of 20, 30 and 40%; adding particles of Teak in proportions of 0, 25, 50, 75, 100%. The physical-mechanical performance of the panels was evaluated based on the standards NBR 14810 (2013) and ANSI A208.1 (2009). Held analysis of variance (ANOVA) to test the influence of individual factors (density, adhesive percentage and fraction Teak), and the interactions among these factors in the physical-mechanical properties of the panels. The results showed excellent physical and mechanical properties of the panels average clusters and high density, and ink residue, mainly in the proportions of 30 and 40%. In most cases the properties of these boards were superior to the requirements set by the Brazilian and international standards. Thus, it was confirmed production of agglomerates with at least one viability of inputs studied as well as their potential for employment for purposes compatible with products of this nature.

Due to the opportunity for afforestation in South Africa being severely limited, extensive research is being carried out on obtaining more wood per given area, improving the quality and value of the wood and on gaining a better understanding of how wood properties influence the characteristics of the pulp it produces. The last mentioned is the main focus of this study. If the variations in pulp, due to variations in wood properties, are better understood, then the existing fibre resource could be more efficiently managed and utilised to maximise its value. The main objective of this study was to determine how variation in physical and chemical properties, from the existing P.patula resource drives variation in pulp strength properties. It is well known that differences in tree age and site index lead to major sources of variation of various wood properties. These two easily measured variables were used in this study to capture a significant amount of variation in the wood of the aforementioned genus that enters a mill. Samples were obtained from two extremes in site quality, as measured by site index, (viz. good and poor sites) and three age ranges (viz. 9-10 years, 13-14 years and 20-21 years) from the KwaZulu-Natal Midlands. Wood chips from each of the six sites were pulped for various lengths of time, using the Kraft pulping method and under the same pulping conditions. A wide range of anatomical and chemical properties of wood and pulp were measured to characterise these samples as extensively as possible. All pulp samples were beaten in a PFI mill, at four different levels. The freeness values of the beaten samples were measured. The physical properties measured on handsheets made from the pulp included sheet density, burst index, tear index, tensile index, tensile energy absorbed, stretch and zero-span tensile strength. Regression models were developed to quantify the impact of the measured variables on each of the strength properties. Principal component analysis was performed on the wood characteristics measured and indicated that tree age is a more critical source of variation in wood properties than site index. The predictions of whole tree wood properties from the properties measured at breast height were excellent. Pulping studies showed that pulp yield, at kappa 20-30, increased with tree age. Wood cellulose proved to be a very good predictor of pulp yield. Xylose and mannose appeared to be most resistant to degradation during pulping. The low yield pulps were easier to refine than those with high yield. This has important implications when considering high yield pulping processes. With regard to pulp strength, the younger material could not achieve the high tear strengths obtained by the older material. However, the tear strengths achieved by these younger sites were comparable with, if not higher than, that obtained by hardwood species. The implications of this is that younger P. patula trees could be used for grades of paper where very high tear strength is not essential, but tensile is (e.g. tissue paper) and that older material can be better used for the purpose of providing the high tear strength needed by certain paper grades (e.g. linerboard and sackkraft). The maximum tensile strength achieved by the younger material was higher than that of the older material. When compared at constant freeness or sheet density, longer cooking times had a deleterious effect on strength properties. Strong predictions of pulp strength from basic wood properties were obtained when strength results were compared at constant freeness and sheet density. Because of the great influence of fibre morphology and chemistry on refining rates and on the resultant strength properties, the results of the study suggest that fibres of greatly different chemical and anatomical characteristics should not be refined together, if beating energy and pulp strength are to be optimised. However, further work is required to evaluate if the separation of fibre resources, to improve pulp quality, would be economically viable.
Thesis (M.Sc.Eng.)-University of KwaZulu-Natal, Durban, 2005.

Este trabalho foi expressamente elaborado com vista à obtenção do grau de Doutor em Ciências Agronómicas e Florestais - Tese apresentada à Universidade de Trás-os-Montes e Alto Douro
Pinus nigra Arnold is a relict pine species from the Tertiary period, with a complex botanical classification. Its natural distribution is wide, fragmented and ranges from the Northern Mediterranean, North Africa and Eastwards to the Black Sea, Corsica and Sicily islands. In Portugal, P. nigra populations are allochthonous, were planted 50 to 90 years ago with plant material of unknown origin and, until the beginning of this work, were just characterized morphologically by Louro in 1982. This work intended to evaluate the P. nigra stands planted in the North and Centre of Portugal, their wood density, growth and quality traits, and to characterise molecularly their genetic structure, variability and relationships in order to infer about their origin and/or infraspecific taxonomy by comparison with P. nigra samples from different provenances and with known taxonomic classification. For this work, six planted stands that were considered representative of the species distribution in Portugal were chosen. Height and diameter at breast height (DBH) was measured and the general state of these stands evaluated. Overall, no mortality was observed except in Paredes de Coura, where trees manifested poor growth. Schumacher model was tested for the prediction of DBH growth and provided satisfying results in terms of the model fitness. Wood traits evaluation revealed that P. nigra had identical or slightly higher values of wood density components, similar growth rate and mechanical properties, higher fiber length and extractive content and lower Klason lignin and H/G ratio than Pinus pinaster which constitutes the main species used by the Portuguese forestry industry. In this sense, P. nigra could be used to satisfy wood national demands. Concerning the genetic results achieved with dominant inter-simple sequence repeats (ISSRs) and Start Codon Targeted (SCoT) markers, 127 P. nigra individuals planted in Portugal were clustered per population. Genetic differentiation was higher within rather than among populations. The pooled ISSR and SCoT data indicated that the Portuguese populations had higher genetic proximity with foreign samples of subspecies laricio. Also, the separate analysis per marker system revealed that two varieties of subspecies laricio (corsicana and calabrica) may have been used in the plantations of the Portuguese P. nigra stands. Upon molecularly analysed with codominant markers simple sequence repeats (SSRs), the same planted populations also revealed higher intra-population diversity but a genetic structure defined into two clusters with low differentiation. This last feature might suggest two provenances or infraspecific taxa, corroborating the results achieved with the dominant markers. Despite the comparison of the SSR data among Portuguese and foreign P. nigra samples from different subspecies, it was not possible to infer unequivocally the origin and/or infraspecific taxonomy of the planted populations. Although the multidisciplinary characterizations performed during this work in the P. nigra planted in Portugal provided useful information for future studies on forest management, afforestation and germplasm use, research involving the comparison of the Portuguese samples with others from different provenances and infraspecific taxa, and the use of other marker systems, should not be discarded.
Pinus nigra Arnold é uma conífera do período Terciário, de classificação botânica complexa. A sua distribuição natural é ampla e fragmentada, abrangendo desde o Norte do Mediterrâneo, Norte de África e, a Este, o Mar Negro, bem como as ilhas de Córsega e Sicília. Em Portugal, as populações de P. nigra são alóctones, foram plantadas há 50 a 90 anos com material vegetal de origem desconhecida, e até ao início deste trabalho, foram apenas caracterizadas morfologicamente por Louro em 1982. Este trabalho pretendeu avaliar a aptidão dos povoamentos de P. nigra plantados no Norte e Centro de Portugal, as suas características de densidade, crescimento e qualidade da madeira, e caracterizar molecularmente a estrutura, variabilidade e relações genéticas para inferir sobre a sua origem e/ou taxonomia infraespecífica por comparação com amostras de P. nigra de diferentes origens e com classificação taxonómica conhecida. Para este trabalho foram escolhidos seis povoamentos plantados considerados representativos da distribuição da espécie em Portugal. Foi avaliado o estado geral dos povoamentos através da altura e diâmetro à altura do peito (DAP). No geral, nenhuma mortalidade foi observada, exceto em Paredes de Coura, onde as árvores manifestaram fraco crescimento. O modelo de Schumacher foi testado para a previsão do crescimento do DAP, fornecendo resultados satisfatórios e adequados para a espécie. A avaliação das características da madeira revelou que P. nigra demonstrava valores idênticos ou ligeiramente superiores de componentes de densidade de madeira, taxa de crescimento, propriedades mecânicas semelhantes, maior comprimento das fibras e conteúdo extrativo e menor lenhina Klason e razão H/G comparativamente com Pinus pinaster, que constitui uma das principais espécies utilizadas pela indústria florestal portuguesa. Neste sentido, P. nigra poderia ser utilizada para atender às necessidades nacionais da indústria florestal. Relativamente aos resultados genéticos alcançados com os marcadores dominantes intermicrossatélites (ISSR) e SCoT (“Start Codon Targeted”), 127 indivíduos de P. nigra plantados em Portugal foram agrupados por população. A diferenciação genética foi maior dentro da população do que entre as populações. A totalidade dos dados ISSR e SCoT indicaram que as populações portuguesas tinham maior proximidade genética com amostras estrangeiras da subespécie laricio. Adicionalmente, a análise separada por sistema marcador revelou que as duas variedades da subespécie laricio (corsicana e calabrica) podem ter sido usadas nas plantações dos povoamentos portugueses de P. nigra. Após a análise molecular realizada com os marcadores codominantes microssatélites (SSR), as mesmas populações plantadas também revelaram maior diversidade intra-populacional mas uma estrutura genética definida em dois grupos com baixa diferenciação. Este facto pode sugerir duas proveniências ou taxa infraespecíficos, corroborando os resultados alcançados com os marcadores dominantes. Apesar da comparação dos dados SSR entre amostras portuguesas e estrangeiras de P. nigra de diferentes subespécies, não foi possível inferir de forma inequívoca a origem e/ou a taxonomia infraespecífica das populações plantadas. Embora as caracterizações multidisciplinares realizadas ao longo deste trabalho nas populações de P. nigra plantadas em Portugal tenham fornecido informações úteis para a gestão florestal, florestação e utilização de germoplasma, pesquisas futuras envolvendo a comparação das amostras portuguesas com outras de diferentes proveniências e taxa infraespecíficos, e o uso de outros sistemas marcadores, não devem ser descartadas.