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Dissertations / Theses on the topic 'Planar Complexes of Platinum(Il)'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Ringo, Jessica M. "Square planar d8 metal complexes with nitrogen-based ligands: structural analysis, metal-metal cooperativity, and applications." University of Cincinnati / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1562842509907911.

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2

Robinson, Matthew Elsworth. "Hierarchical solution self-assembly of square planar platinum(II) complexes and block copolymers containing a polyferrocenylsilane metalloblock." Thesis, University of Bristol, 2017. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.730847.

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3

Swan, Paul Lombard. "Synthesis of mixed ligand, water soluble square planar platinum (II) complexes and an investigation of their association with haematin and potential to inhibit the formation of synthetic malaria pigment." Master's thesis, University of Cape Town, 2002. http://hdl.handle.net/11427/9782.

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Includes bibliography.<br>To establish their potential as a template for novel anti-malarial drugs, a series of planinum (II) complexes were synthesised, their association with haematin determined in 40 aqueous DMSO, pH 7.4 at 25°C and their ability to inhibit the formation of β-haematin (synthetic malaria pigment) was investigated. The compounds synthesised and investigated contained a platinum (II) ion coordinated to acylthiourea and diimine ligands. The diimines used included both substituted and unsubstituted 2,2’-bipyridines and 1,10-phenanthrolines. 2-phenyl pyridine was also utilised as

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4

Wheate, Nial Joseph Chemistry Australian Defence Force Academy UNSW. "Platinum anti-cancer complexes." Awarded by:University of New South Wales - Australian Defence Force Academy. School of Chemistry, 2001. http://handle.unsw.edu.au/1959.4/38704.

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[Formulae and special characters can only be approximated here. Please see the pdf version of the Abstract for an accurate reproduction.] Several inert platinum complexes were synthesised: [(en)Pt([special character]-dpzm)2Pt(en)]4+, [{Pt(dien)}2[special character]-dpzm]4+, [{Pt(dien)}2[special character]-H2N-(CH2)6-NH2]4+, cis-[(NH3)2Pt([special character]--dpzm)2Pt(NH3)2]4+, trans-[Pt(NH3)2([special character]-dpzm)2]2+. Three active complexes, all with chloro ligands, were also synthesised: trans-[{Pt(NH3)Cl2}2[special character]-dpzm)], trans-[{Pt(NH3)2Cl}2[special character]-dpzm]2+ (di-

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5

McGowan, Geraldine. "Platinum picoline anticancer complexes." Thesis, University of Edinburgh, 2005. http://hdl.handle.net/1842/11119.

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The 2-picoline (2-methylpyridine) complex, <i>cis</i>-[PtCl<sub>2</sub>(NH<sub>3</sub>)(2-pic)] (AMD473), is promising new generation platinum antitumour agent currently in clinical trials and highly active cisplatin resistant cell-lines. The antitumour activity of <i>trans </i>platinum complexes has attracted renewed interest since it has been shown that some <i>trans</i> compounds, in particular those possessing planar amine ligands, are anticancer-active. Therefore, three <i>trans</i> isomers, <i>trans</i>-[PtCl<sub>2</sub>(NH<sub>3</sub>)(2-pic)] (1), <i>trans-</i>[PtCl<sub>2</sub>(NH<sub

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6

Davies, Sian E. "Novel platinum (O) complexes." Thesis, University of Sussex, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.335049.

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7

Lee, Daniel E. "Development of Non-Traditional Platinum Anticancer Agents: trans-Platinum Planar Amine Compounds and Polynuclear Platinum Compounds." VCU Scholars Compass, 2015. http://scholarscompass.vcu.edu/etd/3809.

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Development of Non-Traditional Platinum Anticancer Agents: trans-Platinum Planar Amine Compounds and Polynuclear Platinum Compounds By Daniel E. Lee, Ph.D. A dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at Virginia Commonwealth University. Virginia Commonwealth University, 2015 Major Director: Nicholas P Farrell, Ph.D., Professor, Department of Chemistry Platinum anticancer compounds with cis geometry, similar to cisplatin, have been explored to circumvent the cisplatin resistance; however, they were not considered broadly active in c

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8

Hindmarsh, Kathryn. "Kinetic studies of platinum complexes." Thesis, University of Canterbury. Chemistry, 1998. http://hdl.handle.net/10092/8647.

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Since the chance discovery, in 1967, of the anti-tumour activity of cisplatin, cis-dichlorodiammineplatinum(II), research has focussed on studying the reactions of this and other related complexes in an effort to elucidate the nature of the biological activity. This thesis presents a study of the aqueous solution chemistry of some platinum(II) and platinum(IV) complexes in order to extend what is known about the simple chemistry of this biologically important class of compounds. The chloride ion anation of diaqua (cis-[Pt(OH₂)₂(N)₂]²⁺) complexes is investigated as is the bromide ion anation o

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9

Mackay, Fiona S. "Photoactive platinum azide anticancer complexes." Thesis, University of Edinburgh, 2006. http://hdl.handle.net/1842/11085.

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Photoactive platinum compounds have the potential to reduce some of the debilitating side-effects associated with conventional chemotherapeutics, such as cisplatin. Stable, inert platinum(IV) compounds which are reduced to active platinum(II) species only upon irradiation, could provide a site-specific treatment. The Pt<sup>IV</sup> azide complexes, <i>cis, trans, cis-</i>[Pt(N<sub>3</sub>)<sub>2</sub>(OH)<sub>2</sub>(NH<sub>3</sub>)<sub>2</sub>] and <i>cis, trans-</i>[Pt(en)(N<sub>3</sub>)<sub>2</sub>, have previously been shown to be stable in the dark but reduced to Pt<sup>II</sup> upon irr

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10

Shaili, Evyenia. "Photoactivatable platinum (IV) anticancer complexes." Thesis, University of Warwick, 2013. http://wrap.warwick.ac.uk/59800/.

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In this work, trans-diazido Pt(IV) complexes with general formula [Pt(N3)2(OH)(OCOR)(pyr)2] (where OCOR is a carboxylate axial ligand) and [Pt(N3)2(OH)2(L1)(L2)] (where L1 and L2 are aromatic N-heterocyclic ligands) have been synthesised and characterised. The chemical and photochemical properties of these complexes, as well as their photobiological behaviour, have been studied in order to check their potential as photoactivatable anticancer drugs. Four trans-diazido Pt(IV) complexes with general formula trans, trans, trans- [Pt(N3)2(OH)(OCOR)(pyr)2] (OCOR= succinate, 4-oxo-4-propoxybutanoate,

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11

Park, Sunghan. "Planar chiral arene ruthenium complexes." Thesis, Canberra, ACT : The Australian National University, 1993. http://hdl.handle.net/1885/140056.

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12

Chantson, Janine. "Platinum (II) complexes of heteroaromatic derivatives." Pretoria : [s.n.], 2002. http://upetd.up.ac.za/thesis/available/etd-08012005-143742/.

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13

Aliprandi, Alessandro. "Platinum complexes and their luminescent assemblies." Thesis, Strasbourg, 2015. http://www.theses.fr/2015STRAF041/document.

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Cette thèse porte sur la synthèse et la caractérisation photophysique d'une série de composés neutres luminescents de platine (II) contenant un ligand tridentate dianionique chromophore N-donneur et un ligand auxiliaire monodentate. Les composés montrent un changement notable des propriétés de photoluminescence selon l'auto-assemblage en raison de la formation d'interactions intermoléculaires non covalentes faibles telles que metal-metal et π-π. Nous avons démontré comment les complexes de Pt (II) peuvent être auto-assemblés d'une manière contrôlée et précise en jouant sur les facteurs cinétiq

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14

Moulding, R. P. "Bis(diphenylphosphino)methane complexes of platinum." Thesis, University of Oxford, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.375283.

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15

Farley, Sarah J. "Platinum complexes as potential photochemotherapeutic agents." Thesis, University of Edinburgh, 2010. http://hdl.handle.net/1842/3769.

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A major challenge of platinum anticancer therapy lies in overcoming the severe side-effects associated with treatment. Photoactivatable PtIV azido complexes, which are stable in the dark and reduced to cytotoxic PtII species upon irradiation, have recently emerged as a potential site-specific treatment. This thesis is concerned with the investigation of PtII and PtIV azido complexes as potential cytotoxic and photochemotherapeutic agents. PtII azido complexes such as [Pt(en)(N3)2] were shown to bind to both 5'-guanosine monophosphate (5'-GMP) and glutathione, at a much reduced rate compared wi

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16

Cave, Gareth W. V. "Cyclometalation : 2,6-diphenylpyridine complexes of platinum." Thesis, University of Warwick, 1999. http://wrap.warwick.ac.uk/58582/.

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This thesis describes the synthesis and characterisation of novel cycloplatinated 2,6- diphenylpyridine complexes and an interesting platinum carbene complex formed by an unusual intermolecular C-H activation. 2,6-Diphenylpyridine, 2,6-bis(4'-alkoxyphenyl)pyridines, 4-(4-octyloxyphenyl)-2,6- diphenylpyridine and 2,4,6-tris-(4-alkoxyphenyl)-[1,3,5]triazine have all been mono- cycloplatinated to from chloride bridged dimers. These dimers have been cleaved with various ligands including trimethylphosphine, dimethylsulfoxide and carbon monoxide. The synthesis and characterisation of the cyclometal

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17

Spankie, S. A. A. "Ylide complexes of palladium and platinum." Thesis, Heriot-Watt University, 1987. http://hdl.handle.net/10399/1018.

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18

Wainwright, Julie Ann. "Carbonyl substitution in platinum pentamethylcyclopentadienyl complexes." Thesis, University of Salford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.245018.

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19

Peck, Lee Anthony. "Fluoro-complexes of iridium and platinum." Thesis, University of Leicester, 1995. http://hdl.handle.net/2381/33852.

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A range of low-valent iridium and platinum fluoro-complexes have been prepared and characterized by a combination of mass spectrometry, 19F 31P{1H}, 195Pt{1H} and infrared spectroscopies and EXAFS where possible. [Dichlorobis(amine)platinum(II)] complexes of the type [PtCl2(L)2] (L = NMe3, NH3, py; L2 = en, bipy) have been reacted with [XeF2], undergoing oxidative fluorination, to afford various isomers of platinum(IV) amine-fluoride species. The presence of anhydrous hydrofluoric acid (AHF) was observed to influence the nature of the products formed whilst the cis- or trans- stereochemistry o

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20

Roberts, Yvonne V. "Macrocyclic complexes of platinum group metals." Thesis, University of Edinburgh, 1991. http://hdl.handle.net/1842/11897.

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A series of half-sandwich complexes, [M([9]aneS<SUB>3</SUB>)*XY]<SUP>n</SUP>+ have been synthesised from MCl<SUB>2</SUB> [M = Pd, Pt,X = Y = Cl<SUP>-</SUP>(n = 0), PPh<SUB>3</SUB>0.5dppm, 0.5dppe,0.5x2, 2'-bipy(n = 2), X = Cl<SUP>-</SUP>, Y = PPh<SUB>3</SUB>(n&61 1); M = Pd, X = Y = 0.5oxytriphos, 0.5x1, 10-phen(n = 2), X = Cl<SUP>-</SUP>, Y = PCy<SUB>3</SUB>(n = 1)]. All but one of the crystal structures [M = Pd, X = Y = Cl<SUP>-</SUP>, PPh<SUB>3</SUB>, 0.5dppm, 0.5oxytriphos, 0.5x2,2'-bipy, 0.5x1,10-phen, X = Cl<SUP>-</SUP>, Y&61 PPh<SUB>3</SUB>; M = Pt, X = Y&61 PPh<SUB>3</SUB>, 0.5dppm] so

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21

Crofts, Rhona D. "Platinum metal complexes of macrocyclic ligands." Thesis, University of Edinburgh, 1995. http://hdl.handle.net/1842/13493.

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22

Bouché, Mathilde. "Carbene-platinum conjugated : novel anticancer complexes." Thesis, Strasbourg, 2017. http://www.theses.fr/2017STRAE013.

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Bien que les agents anticancéreux à base de platine soient bien établis en clinique, plusieurs paramètres restent à optimiser, notamment leur toxicité et les phénomènes de résistances. La combinaison platine-carbènes N-hétérocycliques (NHCs) a montré des résultats prometteurs dans la lutte antitumorale. Ainsi, afin de développer des agents anticancéreux innovants, ce travail résume les modifications structurales étudiées dans le but d’augmenter la cytotoxicité tout en réduisant les effets secondaires des complexes. Une stratégie développée ici porte sur l’introduction de pnictogènes par échang

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23

Clarke, Matthew Lee. "Asymmetric catalysis using novel platinum complexes." Thesis, University of Bath, 1999. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299846.

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24

Grady, Thomas James. "Platinum(II) Complexes for Biological Applications." Thesis, Curtin University, 2021. http://hdl.handle.net/20.500.11937/82825.

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In this study the synthesis, photophysical properties, and potential biological applications of a range of platinum(II) complexes were investigated. A family of platinum(II) complexes bearing cyclometallated NHC ligands alongside were developed and found to have favourable photophysical properties. Two palladium analogues of platinum(II) complexes were reported and investigated for antimicrobial activity. Finally, the synthesis of a terdentate C^C^N coordinated platinum(II) complexes was investigated, and a number of significant challenges identified.

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25

Arnold, Rachel Florence. "Complex Analysis on Planar Cell Complexes." Thesis, Virginia Tech, 2008. http://hdl.handle.net/10919/32230.

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This paper is an examination of the theory of discrete complex analysis that arises from the framework of a planar cell complex. Construction of this theory is largely integration-based. A combination of two cell complexes, the double and its associated diamond complex, allows for the development of a discrete Cauchy Integral Formula.<br>Master of Science

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26

Willis, Richard Ronald. "Synthesis and reactivity of heterobinuclear complexes of ruthenium-platinum and iron-platinum /." The Ohio State University, 1992. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487841548268408.

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27

Davis, John Christopher. "A Speciation study of the chloro-hydroxo complexes of Pt(II)." Thesis, Nelson Mandela Metropolitan University, 2009. http://hdl.handle.net/10948/1213.

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In this study a method was developed to identify and quantify platinum(II) complexes of the type [PtCl4-n(OH)n]2- and [PtCl4-n(H2O)n]2-n. Separation of the various species was achieved with the aid of a hyphenated reversed phase HPLC-ICP-MS technique coupled with an ion-pairing reagent, HMHDCl2. The adsorption of HMHD2+ onto a C-18 column was investigated by generating a series of breakthrough curves. It was found that the selectivity for high charge density anions originates from its low surface coverage relative to TBA+, which on the other hand could not separate Pt(II) complexes. The peaks

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28

Henderson, Steven G. D. "Spectroscopic studies of platinum halo-phosphine complexes." Thesis, University of Edinburgh, 1986. http://hdl.handle.net/1842/28226.

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29

Fogelström, Ewelina Rebecka [Verfasser]. "Subcellular distribution of platinum complexes / Ewelina Fogelström." Berlin : Freie Universität Berlin, 2013. http://d-nb.info/1033306746/34.

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30

Chan, Yew Boon Colin. "Synthesis and reactivity of platinum alkynyl complexes." Thesis, Imperial College London, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.395761.

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31

Dewa, Shaliza Zaini. "Novel 3,3-dialkyldiaziridine platinum and palladium complexes." Thesis, University of Sussex, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.296548.

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32

Fotheringham, John David. "Heterobimetallic complexes of the platinum group metals." Thesis, University of Edinburgh, 1987. http://hdl.handle.net/1842/10906.

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33

Muller, Philippe. "Photoactivatable platinum complexes as potential therapeutic agents." Thesis, University of Edinburgh, 2002. http://hdl.handle.net/1842/12698.

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Non-toxic and stable photoactivatable platinum compounds, which can be activated by visible light to toxic anticancer drugs, could strongly reduce the side-effects shown by cisplatin by providing site-specific cancer treatment. In this thesis, the synthesis and characterisation of novel photoactive Pt amine compounds, which can be converted into reactive Pt species by visible light irradiation, are presented and their potential as photoactivatable prodrugs investigated.

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34

Chan, Danny. "The chemistry of platinum complexes and hydrosilation." Thesis, University of York, 1999. http://etheses.whiterose.ac.uk/14173/.

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This thesis describes the study of a series of platinum complexes, with particular emphasis towards hydrosilation. Platinum bis(phosphine) azodicarbonyl complexes Pt(PRI 3)2(R20CNNCOR2) (RI = Ph, Me; R2 = Ph, Me, OEt, Pri) were synthesised and studied. Multinuclear NMR spectroscopy on Pt(PRI3)2(R20CNNCOR2) revealed that the dicarbonyl substituted azo ligand is co-ordinated asymmetrically, consistent with a five membered, Pt-N-N-C-O ring. The crystal structure of Pt(PPh3)2(Pri02CNNC02Pri) shows that the co-ordination sphere of platinum is essentially square planar and co-planar with the five-me

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35

Williams, R. Lee. "Ruthenium-Platinum Polypyridyl Complexes: Synthesis and Characterization." Thesis, Virginia Tech, 2001. http://hdl.handle.net/10919/44315.

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A series of bimetallic (RuII, PtII) complexes were synthesized with the general formula [(tpy)RuCl(BL)PtCl2](PF6) (tpy = 2,2':6',2"-terpyridine and BL = bridging ligand) and their spectroscopic, electrochemical, and DNA binding properties studied. The bridging ligands used in these complexes were 2,3-bis(2'-pyridyl)pyrazine (dpp), 2,3-bis(2'-pyridyl)quinoxaline (dpq) and 2,3-bis(2'-pyridyl)benzoquinoxaline (dpb). These complexes combine light-absorbing RuII-polypyridyl chromophores and a cis-PtCl2 structural motif known to bind DNA. The Ru-bound chloride may be substituted, enabling furthe

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36

Miyoshi, Emi. "Platinum(II) complexes : studied by diffusion NMR." Thesis, View thesis, 2008. http://handle.uws.edu.au:8081/1959.7/33587.

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Six novel platinum(II) intercalators of the form [Pt(AL)(IL)]Cl2, where AL = ethylenediamine (en), 1R,2R-diaminocyclohexane (R,R-dach), or 1S,2S-diaminocyclohexane (S,S-dach) and IL = 4,7-dihydroxy-1,10-phenanthroline (4,7-dhp) or 4,7-dicarboxy-1,10-phenanthroline (4,7-dcp), were synthesised. All complexes were prepared by the addition of the intercalating ligand followed by the addition of the diamine ancillary ligand. The complexes with 4,7-dhp were soluble in DMSO and were characterised by 1H, 13C, and 195Pt NMR, elemental analysis, UV-vis, ESI-MS, and CD. The complexes with 4,7-dcp were on

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37

Miyoshi, Emi. "Platinum(II) complexes studied by diffusion NMR /." View thesis, 2008. http://handle.uws.edu.au:8081/1959.7/33587.

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Thesis (M.Sc.) (Hons)--University of Western Sydney, 2008.<br>A thesis presented to the University of Western Sydney, College of Health and Science, School of Biomedical and Health Sciences, in fulfilment of the requirements for the degree of Master of Science (Honours). Includes bibliographies.

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38

Al-Resayes, S. I. "Phospha-alkyne complexes of the platinum metals." Thesis, University of Sussex, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.372068.

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39

Patel, M. K. "Some complexes of platinum and related metals." Thesis, University of Sussex, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.373898.

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40

Acharya, Suvra. "Platinum metal`s complexes: synthesis and characterization." Thesis, University of North Bengal, 2011. http://hdl.handle.net/123456789/1384.

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41

羅政藩 and Chang-fan Lo. "Substitution and redox reactions of some binuclear platinum (II) and platinum (III) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31231901.

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42

Lo, Chang-fan. "Substitution and redox reactions of some binuclear platinum (II) and platinum (III) complexes /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12505304.

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43

Essex, Sarah Jane. "Spectral intensities in planar copper(II) complexes." Thesis, University of Cambridge, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239622.

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44

Butikofer, Jeffrey L. "Synthesis, structure and characterization of dfmp platinum complexes." Laramie, Wyo. : University of Wyoming, 2005. http://proquest.umi.com/pqdweb?did=994234981&sid=1&Fmt=2&clientId=18949&RQT=309&VName=PQD.

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45

Look, Jennifer L. "Mechanistic studies of reactions between molecular oxygen and platinum alkyl and platinum hydrocarbyl hydride complexes /." Thesis, Connect to this title online; UW restricted, 2004. http://hdl.handle.net/1773/11599.

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46

Louw, Marissa. "New platinum and palladium complexes: their anticancer application." Thesis, Nelson Mandela Metropolitan University, 2010. http://hdl.handle.net/10948/d1016218.

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Novel non-leaving groups were employed in this dissertation to synthesize platinum complexes which can assist in the understanding or improvement of anticancer action. Emphasis was placed on (NS)-chelate and (NN)-chelate platinum complexes. Bidentate (NS)-donor ligands were used as non-leaving ligands in the synthesis of platinum(II) complexes with iodo, chloro, bromo and oxalato groups as leaving groups. These complexes were synthesized and studied since many questions regarding the interaction of sulfur-donors and platinum still exist. These relate to thermodynamic and kinetic factors and th

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47

Irwin, Michael J. "Oligomeric and polymeric complexes of gold and platinum." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/nq21292.pdf.

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48

Harding, Nigel Anthony. "β-thia-alkyl complexes of platinum group metals". Thesis, Imperial College London, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.283721.

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49

尹錦濤 and Kam-to Wan. "Syntheses and photochemistry of monomeric platinum (II) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1990. http://hub.hku.hk/bib/B31209476.

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50

Broadwood-Strong, Gillian. "Novel phosphine complexes of platinum and palladium (0)." Thesis, University of Sussex, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.385600.

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