Academic literature on the topic 'Platinum compounds Platinum compounds Transition metal complexes Transition metal complexes'

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Journal articles on the topic "Platinum compounds Platinum compounds Transition metal complexes Transition metal complexes"

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Melník, Milan, Peter Mikuš, and Clive Holloway. "Crystalographic and structural characterization of heterometallic platinum compounds. Part III: heterotrinuclear compounds." Open Chemistry 11, no. 6 (2013): 827–900. http://dx.doi.org/10.2478/s11532-013-0226-3.

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AbstractThis review article includes over three hundred and sixty heterotrinuclear platinum complexes of the composition Pt2M (205 examples), PtM2 (132 examples) and PtMM (24 examples). The heterometals include the non-transition and transition metals. Three metal atoms form a wide variability of frameworks: M3 triangular, dicapped M3 triangular, V shaped M3, M3 linear, five-, six- and seven- metallocycles and unique structures of which triangular and linear are the most common. This has led to a rich chemistry of platinum not only from variability of metals, but also from their framework and
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Lu, Guo-Liang, Cheuk-Lam Ho, Qiwei Wang, et al. "Synthesis and Characterization of Some Metal Complexes of 4,5-Diazafluoren-9-one and their Biological Effects on Human Carcinoma Cells." Australian Journal of Chemistry 61, no. 12 (2008): 975. http://dx.doi.org/10.1071/ch08342.

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Three new transition metal complexes of 4,5-diazafluoren-9-one, [(DAFO)PdCl2], [(DAFO)PtCl2], and [(DAFO)ZnCl2], were prepared in good yields by the reactions between appropriate metal chloride precursors and 4,5-diazafluoren-9-one under ambient conditions. The structures of these metal complexes were established by spectroscopic (Fourier-transform IR, NMR, and fast-atom bombardment mass spectrometry) techniques. The possible biological activity of these compounds on three human cancer cell lines including Hep3B, MDAMB-231, and SKHep-1 was investigated. The results obtained showed that both zi
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Zykova, A. "Synthesis and Structure of Aryl Phosphorus Compounds." Bulletin of the South Ural State University series "Chemistry" 12, no. 4 (2020): 5–50. http://dx.doi.org/10.14529/chem200401.

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Based on an analysis of the literature published from the late 20th century to the beginning of the 21st century, methods for the synthesis of some complex tetraorganylphosphonium salts are systematized and described, along with the features of the chemical transformations of pentaphenylphosphorus, which was first obtained in 1953. The tetraorganylphosphonium salts were known much earlier, however, the features of the synthesis of transition metal complexes, which are usually obtained from tetraorganylphosphorus halides and metal halides, have not been sufficiently studied. The present review
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Radonjic, Katarina, Isidora Stojic, Vladimir Zivkovic, et al. "The Platinum(II) Complexes Induced Oxidative Stress of Isolated Rat Heart." Serbian Journal of Experimental and Clinical Research 18, no. 2 (2017): 111–17. http://dx.doi.org/10.1515/sjecr-2016-0059.

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AbstractInterest for the clinical application of transition metal complexes as chemotherapeutic agents initially started with discovery of cisplatin. Despite the remarkable clinical success, cisplatin treatment is limited due to its resistance and side effects. Over the last 40 years, numerous transition metal complexes were synthesized and investigated in vitro and in vivo in order to establish a metallopharmaceutical that will exert less toxicity and equal or higher potency. We have compared the cardiotoxicity of 2 platinum complexes, one ligand, and a starting salt for complex synthesis usi
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Johnstone, Timothy C., Kogularamanan Suntharalingam, and Stephen J. Lippard. "Third row transition metals for the treatment of cancer." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 373, no. 2037 (2015): 20140185. http://dx.doi.org/10.1098/rsta.2014.0185.

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Platinum compounds are a mainstay of cancer chemotherapy, with over 50% of patients receiving platinum. But there is a great need for improvement. Major features of the cisplatin mechanism of action involve cancer cell entry, formation mainly of intrastrand cross-links that bend and unwind nuclear DNA, transcription inhibition and induction of cell-death programmes while evading repair. Recently, we discovered that platinum cross-link formation is not essential for activity. Monofunctional Pt compounds such as phenanthriplatin, which make only a single bond to DNA nucleobases, can be far more
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Niehaus, Thomas A., Thomas Hofbeck, and Hartmut Yersin. "Charge-transfer excited states in phosphorescent organo-transition metal compounds: a difficult case for time dependent density functional theory?" RSC Advances 5, no. 78 (2015): 63318–29. http://dx.doi.org/10.1039/c5ra12962a.

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A series of 17 platinum(ii) and iridium(iii) complexes have been investigated theoretically and experimentally to elucidate the charge-transfer character in emission from the lowest triplet state. TDDFT is found to be surprisingly accurate.
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Czarnomysy, Robert, Dominika Radomska, Anna Muszyńska, et al. "Evaluation of the Anticancer Activities of Novel Transition Metal Complexes with Berenil and Nitroimidazole." Molecules 25, no. 12 (2020): 2860. http://dx.doi.org/10.3390/molecules25122860.

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Novel transition metal complexes (Au, Pd, Pt) with berenil and 2-(1-methyl-5-nitroimidazol-2-yl)ethanol were obtained through two-step synthesis. The cytotoxicity assay against MCF-7 and MDA-MB-231 breast cancer cells revealed that novel platinum and palladium complexes cause a reduction on the viability of MCF-7 and MDA-MB-231 breast cancer cells to a greater extent than cisplatin. The complexes showed lower cytotoxicity on normal MCF-10A human breast epithelial cells than on tumor cells. Furthermore, we observed that these complexes selectively concentrate in tumor cell mitochondria due to t
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Ryabov, Alexander D. "The Exchange of Cyclometalated Ligands." Molecules 26, no. 1 (2021): 210. http://dx.doi.org/10.3390/molecules26010210.

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Reactions of cyclometalated compounds are numerous. This account is focused on one of such reactions, the exchange of cyclometalated ligands, a reaction between a cyclometalated compound and an incoming ligand that replaces a previously cyclometalated ligand to form a new metalacycle: + H-C*~Z ⇄ + H-C~Y. Originally discovered for PdII complexes with Y/Z = N, P, S, the exchange appeared to be a mechanistically challenging, simple, and convenient routine for the synthesis of cyclopalladated complexes. Over four decades it was expanded to cyclometalated derivatives of platinum, ruthenium, mangane
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Dube, Jonathan W., Vanessa A. Béland, Paul D. Boyle, and Paul J. Ragogna. "Utilizing a zwitterionic approach for the synthesis of late transition metal – triphosphenium ion coordination compounds." Canadian Journal of Chemistry 93, no. 2 (2015): 253–64. http://dx.doi.org/10.1139/cjc-2014-0204.

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Zwitterionic dicoordinate phosphorus(I) compounds (1 and 2), formally a charge neutral triphosphenium ion or phosphanide, are shown to coordinate to a variety of late transition metals. The reaction of the phosphanide proligands with {Rh(COD)Cl}2 results in an equilibrium process that varies as a function of temperature or reaction stoichiometry. Palladium(II) compounds have a tendency to chlorinate the borate backbone while giving dimeric coordination compounds (1Pd) and also a decomposition product (3) where the P(I) atom was replaced. Both “lone pairs” of electrons on phosphorus are utilize
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Khalimon, Andrey, Kristina Gudun, and Davit Hayrapetyan. "Base Metal Catalysts for Deoxygenative Reduction of Amides to Amines." Catalysts 9, no. 6 (2019): 490. http://dx.doi.org/10.3390/catal9060490.

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The development of efficient methodologies for production of amines attracts significant attention from synthetic chemists, because amines serve as essential building blocks in the synthesis of many pharmaceuticals, natural products, and agrochemicals. In this regard, deoxygenative reduction of amides to amines by means of transition-metal-catalyzed hydrogenation, hydrosilylation, and hydroboration reactions represents an attractive alternative to conventional wasteful techniques based on stoichiometric reductions of the corresponding amides and imines, and reductive amination of aldehydes wit
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Dissertations / Theses on the topic "Platinum compounds Platinum compounds Transition metal complexes Transition metal complexes"

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Luedtke, Avery T. "Synthesis, structure, and reactivity of five-coordinate platinum(IV) complexes /." Thesis, Connect to this title online; UW restricted, 2007. http://hdl.handle.net/1773/11565.

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Li, Jun. "Synthesis, characterization and application studies of ionic platinum(II) complexes." HKBU Institutional Repository, 2017. https://repository.hkbu.edu.hk/etd_oa/394.

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This thesis is dedicated to developing novel charged Pt(II) complexes and exploring their applications in electroluminescence, bio-imaging and the preparation of soft salts. At the beginning, a brief introduction about the development of ionic transition metal complexes and an overview of their applications in electroluminescence, bio-imaging and soft salts are presented. In chapter 2, a series of anionic Pt(II) complexes were successfully synthesized and fully characterized for their application in electroluminescence with relatively small current density. All the complexes show highly intens
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Williams, Burke Scott. "Studies of the reactivities of organometallic complexes containing platinum(IV)-oxygen bonds /." Thesis, Connect to this title online; UW restricted, 2000. http://hdl.handle.net/1773/8703.

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Smythe, Nicole. "Reactivity studies of platinum(IV) hydroxide and methoxide complexes and the study of pincer palladium(II) complexes as potential catalysts for olefin epoxidation /." Thesis, Connect to this title online; UW restricted, 2004. http://hdl.handle.net/1773/8618.

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Thu, Hung-yat. "Catalytic C-H bond functionalization reactions catalyzed by rhodium(III) porphyrin, palladium(II) and platinum(II) acetate complexes." View the Table of Contents & Abstract, 2006. http://sunzi.lib.hku.hk/hkuto/record/B38027872.

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Chan, Ka-man Carmen. "Design and synthesis of luminescent branched multinuclear platinum(II) alkynyl complexes and the study of their two-photon absorption properties." Click to view the E-thesis via HKUTO, 2010. http://sunzi.lib.hku.hk/hkuto/record/B43703653.

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Tao, Chi-hang, and 陶志恆. "Synthesis and luminescence studies of branched carbonrich platinum(II)and palladium(II) alkynyl complexes: versatile building blocks for multinuclear assemblies." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B31246011.

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Lin, Yongyue, and 林勇躍. "Luminescent platinum(II), copper(I), silver(I) and zinc(II) complexes with functional pyridyl and arylacetylide ligands: structures, spectroscopic properties and applications." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2001. http://hub.hku.hk/bib/B31243381.

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Lin, Yongyue. "Luminescent platinum(II), copper(I), silver(I) and zinc(II) complexes with functional pyridyl and arylacetylide ligands : structures, spectroscopic properties and applications /." Hong Kong : University of Hong Kong, 2001. http://sunzi.lib.hku.hk/hkuto/record.jsp?B25155325.

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Crumpton, Dawn M. "Mechanistic studies of carbon-carbon and carbon-hydrogen reductive elimination reactions from platinum(IV) complexes /." Thesis, Connect to this title online; UW restricted, 2000. http://hdl.handle.net/1773/8484.

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Books on the topic "Platinum compounds Platinum compounds Transition metal complexes Transition metal complexes"

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Elena, Soriano, José Marco-Contelles, and B. Alcaide. Computational mechanisms of Au and Pt catalyzed reactions. Springer, 2011.

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Soriano, Elena, and José Marco-Contelles. Computational Mechanisms of Au and Pt Catalyzed Reactions. Springer, 2011.

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Soriano, Elena, and José Marco-Contelles. Computational Mechanisms of Au and Pt Catalyzed Reactions. Springer, 2013.

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Book chapters on the topic "Platinum compounds Platinum compounds Transition metal complexes Transition metal complexes"

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Ogawa, A., and T. Hirao. "Platinum–Cyclopentadienyl Complexes." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00281.

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Ogawa, A., and T. Hirao. "Platinum–Diene Complexes." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00285.

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Ogawa, A., and T. Hirao. "Platinum–Allyl Complexes." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00295.

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Ogawa, A., and T. Hirao. "Platinum–Alkyne Complexes." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00301.

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Ogawa, A., and T. Hirao. "Platinum–Alkene Complexes." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00311.

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Ogawa, A., and T. Hirao. "Platinum(0)–Alkyne Complexes Starting from Platinum(II) Complexes." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00303.

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Ogawa, A., and T. Hirao. "Platinum(0)–Monoalkene Monodentate Complexes Starting from Platinum(II) Complexes." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00315.

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Ogawa, A., and T. Hirao. "Organometallic Complexes of Platinum." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00280.

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Ogawa, A., and T. Hirao. "Platinum(0)–Allene Complexes." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00287.

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Ogawa, A., and T. Hirao. "Platinum(II)–Allene Complexes." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00288.

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