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Dissertations / Theses on the topic 'Platinum(II)'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Chantson, Janine. "Platinum (II) complexes of heteroaromatic derivatives." Pretoria : [s.n.], 2002. http://upetd.up.ac.za/thesis/available/etd-08012005-143742/.

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2

Pike, Sarah Jane. "Dynamic platinum(II)- based metallosupramolecular architectures." Thesis, University of Edinburgh, 2012. http://hdl.handle.net/1842/7942.

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Over the past two decades, transitions metals have been extensively employed towards the construction (using coordination driven assembly) and operation (using reversible metal-ligand switching motifs) of supramolecular architectures. This Thesis details the investigation of an array of dynamic platinum(II)-based metallosupramolecular architectures and includes a series of model studies on switchable platinum(II) coordination modes. Chapter Two describes the synthesis and study of a series of prototype noninterlocked molecular machines. The inherent dynamics of intramolecular metalligand subst

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3

Grady, Thomas James. "Platinum(II) Complexes for Biological Applications." Thesis, Curtin University, 2021. http://hdl.handle.net/20.500.11937/82825.

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In this study the synthesis, photophysical properties, and potential biological applications of a range of platinum(II) complexes were investigated. A family of platinum(II) complexes bearing cyclometallated NHC ligands alongside were developed and found to have favourable photophysical properties. Two palladium analogues of platinum(II) complexes were reported and investigated for antimicrobial activity. Finally, the synthesis of a terdentate C^C^N coordinated platinum(II) complexes was investigated, and a number of significant challenges identified.

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4

Pascu, Sofia I. "Nickel (II), palladium (II), platinum (II) and rhodium (I) complexes of iminophosphine ligands." Thesis, University of Oxford, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270258.

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5

Norton, Amie E. "Investigations of Stimuli-Responsive Platinum(II) Salts." University of Cincinnati / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1504781443162754.

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6

Miyoshi, Emi. "Platinum(II) complexes : studied by diffusion NMR." Thesis, View thesis, 2008. http://handle.uws.edu.au:8081/1959.7/33587.

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Six novel platinum(II) intercalators of the form [Pt(AL)(IL)]Cl2, where AL = ethylenediamine (en), 1R,2R-diaminocyclohexane (R,R-dach), or 1S,2S-diaminocyclohexane (S,S-dach) and IL = 4,7-dihydroxy-1,10-phenanthroline (4,7-dhp) or 4,7-dicarboxy-1,10-phenanthroline (4,7-dcp), were synthesised. All complexes were prepared by the addition of the intercalating ligand followed by the addition of the diamine ancillary ligand. The complexes with 4,7-dhp were soluble in DMSO and were characterised by 1H, 13C, and 195Pt NMR, elemental analysis, UV-vis, ESI-MS, and CD. The complexes with 4,7-dcp were on

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7

Miyoshi, Emi. "Platinum(II) complexes studied by diffusion NMR /." View thesis, 2008. http://handle.uws.edu.au:8081/1959.7/33587.

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Thesis (M.Sc.) (Hons)--University of Western Sydney, 2008.<br>A thesis presented to the University of Western Sydney, College of Health and Science, School of Biomedical and Health Sciences, in fulfilment of the requirements for the degree of Master of Science (Honours). Includes bibliographies.

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8

羅政藩 and Chang-fan Lo. "Substitution and redox reactions of some binuclear platinum (II) and platinum (III) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31231901.

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9

Lo, Chang-fan. "Substitution and redox reactions of some binuclear platinum (II) and platinum (III) complexes /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12505304.

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10

Shaykh, B. A. M. "Reactivity of triborane with phosphino palladium(II) and platinum(II) chlorides." Thesis, University of Cambridge, 1990. https://www.repository.cam.ac.uk/handle/1810/272948.

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11

Howard, Warren A. "Synthesis and characterisation of platinum(II) and ruthenium(II) polyamide conjugates." Thesis, View thesis, 2008. http://handle.uws.edu.au:8081/1959.7/43899.

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This thesis reports the synthesis and characterisation of two novel metallo-polyamide conjugates; LLSP4-Pt and LLSP4-Ru. Several synthetic strategies were employed in the development of the polyamides, beginning with solution phase chemistry. Construction of the polyamide was attempted via chain elongation with sequential additions of pyrrole monomers, however, solution phase methods were unable to achieve the coupling of four consecutive pyrrole rings. Solid phase chemistry, using a peptide synthesiser, was then used as an alternative. Synthesis using solid phase chemistry required the produc

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12

Howard, Warren A. "Synthesis and characterisation of platinum(II) and ruthenium(II) polyamide conjugates." View thesis, 2008. http://handle.uws.edu.au:8081/1959.7/43899.

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Thesis (Ph.D.)--University of Western Sydney, 2008.<br>A thesis presented to the University of Western Sydney, College of Health and Science, School of Biomedical and Health Sciences, in fulfilment of the requirements for the degree of Doctor of Philosophy. Includes bibliographies.

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13

Fazio, Daniela. "Synthesis and mesomorphism of polycatenar complexes of palladium (II) and platinum (II)." Thesis, University of Exeter, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.366619.

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14

尹錦濤 and Kam-to Wan. "Syntheses and photochemistry of monomeric platinum (II) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1990. http://hub.hku.hk/bib/B31209476.

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15

Grove, Levi James. "Synthesis and Characterization of Vapochromic Platinum(II) Complexes." University of Cincinnati / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1196030530.

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16

Wan, Kam-to. "Syntheses and photochemistry of monomeric platinum (II) complexes /." [Hong Kong : University of Hong Kong], 1990. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12757949.

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17

Osborn, Maire. "Cellular RNA Targeting by Platinum (II) Anticancer Therapeutics." Thesis, University of Oregon, 2014. http://hdl.handle.net/1794/17920.

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Cis-diamminedichloroplatinum (II), or cisplatin, is a widely prescribed anticancer compound, currently one of only three platinum (II) complexes FDA approved for cancer treatment. Despite its widespread use, we lack a comprehensive picture of global drug targets, which would lend valuable insights into the molecular mechanisms of action and resistance in different tissues. Drug binding to genomic DNA is an accepted cause of downstream apoptotic signaling, but less than 10% of Pt (in the case of cisplatin) accumulates within genomic DNA. Non-genomic contributions to cisplatin's therapeutic acti

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18

FAGNANI, FRANCESCO. "NEW NCN-PLATINUM(II) COMPLEXES WITH LUMINESCENT PROPERTIES." Doctoral thesis, Università degli Studi di Milano, 2022. http://hdl.handle.net/2434/938787.

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During the doctoral period, my research has been focused on the synthesis and characterization of novel NCN-based platinum(II) complexes, obtaining more than twenty completely new compounds. These complexes have a terdentate chelating ligand with the general scaffold of a 1,3-di(2-pyridyl)benzene and were designed following different strategies: i) Complexes PtCl1-PtCl7 have unsubstituted pyridines and different groups in position 5 of the benzene ring, i.e. a mesityl, a triphenylamine, a pyrenyl, a phenyl-carbazole, a carbazole, a 2-thienyl and a methyl. The synthesis of the NCN liga

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19

Barkhuysen, Shani. "High resolution 195Pt and 119Sn NMR characterization of platinum(II)-tin(II) complexes." Thesis, Stellenbosch : Stellenbosch University, 2011. http://hdl.handle.net/10019.1/17841.

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20

Rapolu, Chaitanya. "Inhibition of Cysteine Protease by Platinum (II) Diamine Complexes." TopSCHOLAR®, 2011. http://digitalcommons.wku.edu/theses/1137.

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Chemotherapy is the first line of treatment used in cancer. Chemotherapy drugs such as cisplatin, carboplatin and oxaliplatin are used in treatment. Cisplatin enters the cell through copper transporter CTR1 by passive diffusion and bind to DNA and proteins. Cisplatin is found to inhibit several enzymes targeting cysteine, histidine and methionine residues, which are expected to be responsible for its anticancer activity. A better understanding of how the size and shape and leaving ligands of platinum complexes affect cysteine protease, papain enzyme are studied. This could give new ways to opt

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21

鄺海倫 and Hoi-lun Kwong. "Photochemistry of binuclear platinum (II) and gold (I) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31208678.

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22

Huxley, Martin. "Testosterone as a delivery vector for platinum(II) metallodrugs." Thesis, University of Warwick, 2006. http://wrap.warwick.ac.uk/4078/.

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A total of 6 steroidal ligands have been synthesised from simple starting materials using Sonogashira coupling reactions. The ligands are based on testosterone substituted in the l7a-position with ethnynyl-pyridine, ethnynyl-quinoline or ethnynyl-isoquinoline. A range of platinum(II) complexes have been synthesised using these ligands of the type trans- and cis- [Pt(NH3)2(L)(Cl][N03], where L is the steroidal ligand, alongside control complexes containing simple aromatic amines for comparison. The addition of the steroid imparted a substantional ability of the steroidal platinum(II) complexes

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23

Quyoum, Ruhksana. "Pentamethylcyclopentadienyl complexes of platinum(II) : their synthesis and reactivity." Thesis, University of Salford, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.315362.

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24

Newman, Christopher P. "Phenylpyridine and N-heterocyclic carbene complexes of platinum (II)." Thesis, University of Warwick, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.425555.

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25

Watkins, W. N. "The chemistry of some sterically-hindered platinum (II) alkyls." Thesis, Imperial College London, 1985. http://hdl.handle.net/10044/1/37889.

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26

Ankianiec, Bernardeta Celina. "Synthetic and mechanistic studies of sila-alkyl platinum(II)." Thesis, Imperial College London, 1990. http://hdl.handle.net/10044/1/47749.

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27

Hua, Fei. "Synthesis and Photophysics of Platinum (II) Diimine Acetylide Complexes." Bowling Green State University / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1187329346.

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28

Li, Jian-Jun. "Platinum(II) hydroxo, oxo, amido, imido and hydrazido complexes /." free to MU campus, to others for purchase, 1996. http://wwwlib.umi.com/cr/mo/fullcit?p9720553.

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29

Kwong, Hoi-lun. "Photochemistry of binuclear platinum (II) and gold (I) complexes /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12434000.

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30

Turner, Matthew. "Modelling platinum(II) interactions with the Amyloid-b peptide." Thesis, Cardiff University, 2018. http://orca.cf.ac.uk/109924/.

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The Ab peptide is a key molecule in the development of Alzheimer’s Disease - Ab peptides form toxic aggregates in the brain. Density functional theory (DFT), Parametric Model 7 (PM7) and ligand-Field Molecular Mechanics (LFMM) methods have been used to model the interactions of a series of potential therapeutic PtII(ligand) complexes with various fragments of the Ab peptide. LFMM calculations with the AMBER forcefield were used to generate conformations of PtII-Ab6-14 via LowMode MD and results validated against BHandH. While LFMM showed insufficient agreement with DFT, the semi-empirical PM7

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31

Contaldi, Simone <1982&gt. "Synthesis and Structures of palladium(II) and platinum(II) complexes containing cyclometallated 2-thienylpyridines." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2010. http://amsdottorato.unibo.it/2727/1/contaldi_simone_tesi.pdf.

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32

Contaldi, Simone <1982&gt. "Synthesis and Structures of palladium(II) and platinum(II) complexes containing cyclometallated 2-thienylpyridines." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2010. http://amsdottorato.unibo.it/2727/.

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33

Li, Minghang. "Device Engineering for Enhanced Efficiency from Platinum(II) Phosphorescent OLEDs." Thesis, University of North Texas, 2010. https://digital.library.unt.edu/ark:/67531/metadc30482/.

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Phosphorescent organic light emitting diodes (PHOLEDs) based on efficient electrophosphorescent dopant, platinum(II)-pyridyltriazolate complex, bis[3,5-bis(2-pyridyl)-1,2,4-triazolato]platinum(II) (Pt(ptp)2) have been studied and improved with respect to power efficiency, external efficiency, chromacity and efficiency roll-off. By studying the electrical and optical behavior of the doped devices and functionality of the various constituent layers, devices with a maximum EQE of 20.8±0.2 % and power efficiency of 45.1±0.9 lm/W (77lm/W with luminaries) have been engineered. This improvement com

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34

Xiang, Haifeng. "Organic optoelectronic devices based on platinum(II) complexes and polymers." Thesis, Click to view the E-thesis via HKUTO, 2005. http://sunzi.lib.hku.hk/hkuto/record/B3483011X.

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35

Westlund, Robert. "Nonlinear Absorbing platinum(II) Acetylides for Optical Power Limiting Applications." Doctoral thesis, KTH, Ytbehandlingsteknik, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-9169.

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During the past few decades, laser technology has had a strong impact on our society, providing important contributions to materials processing, data storage, communications, medicine, and defense applications. However, the progress in laser technology has also brought about the development of harmful portable high‐power lasers and tactical laser weapons. As a result, the hazard of being blinded by lasers (accidentally or from hostile use) has increased significantly. Hence, the need for protection against lasers has emerged. In order to protect optical sensors against harmful laser radiation,

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36

Anderson, Bernard Marshall. "A study of polymeric platinum (II) compounds and nanoscale materials." Diss., Montana State University, 2004. http://etd.lib.montana.edu/etd/2004/anderson/AndersonB0504.pdf.

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37

Robey, Stephanie. "Reactions of Platinum(II) Compounds with Selenium Containing Amino Acids." TopSCHOLAR®, 2013. http://digitalcommons.wku.edu/theses/1252.

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Platinum(II) anticancer medications essentially react with DNA forming kinks inthe double helix of DNA and causing apoptosis. It has also been noted that theseanticancer medications react with methionine and cysteine in the body. With the new discoveries of selenium containing amino acids including selenomethionine and selenocysteine, new research is ongoing to see what types of products can be formed from these amino acids. Our research reacts [Pt(Met-S,N)Cl2] 2+ with selenomethionine to determine what types of products are produced. Monochelates including [Pt(SeMet-Se,N)Cl2] 2+ have formed t

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38

Priqueler, Julien. "Synthesis and characterization of platinum (II) comlplexes with diazine ligands." Thesis, McGill University, 2011. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=96898.

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Several series of platinum(II) based complexes have been synthesized. The ligands used include halides and sulfoxides, but also pyrazine and 2,5-dimethylpyrazine. Both diazines were also employed as bridging ligands to prepare dimeric compounds, such as trans,trans-Pt(TMSO)Cl2(pz)Pt(R2SO)Cl2 or trans,trans-{Pt(DEtSO)Cl2}2(pz). The complexes have been characterized by IR, Raman and multinuclear magnetic resonance spectroscopies (1H, 13C and 195Pt). 195Pt-NMR spectroscopy, a key technique of this project, has been studied more in details in the form of a review paper. The reaction of 2,5-dimethy

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39

Walker, Shonagh. "Novel methods to deliver platinum(II) chemotherapeutics to the nose." Thesis, University of Strathclyde, 2013. http://oleg.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=22648.

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Efforts to reduce side effects and improve efficacy of platinum-based drugs have seen the focus shift away from developing new drugs, towards improving the delivery of existing ones. This thesis presents an investigation into improving the delivery of platinum(II) drugs using lyophilised hydroxypropyl methylcellulose (HPMC) nasal insert formulations, designed to resist rapid mucociliary clearance in vivo and extend drug absorption. Cisplatin was conjugated to carbon nanotubes (CNTs), which was expected to improve tumour targeting through the enhanced permeability and retention effect; however

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40

Watchman, Elaine Beth. "Platinum(II) aminophosphine anticancer complexes and their interactions with nucleotides." Thesis, University of Edinburgh, 2002. http://hdl.handle.net/1842/14637.

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A series of platinum(II) aminophosphine complexes has been prepared and their interactions with nucleotides studied, such complexes are potential anticancer agents combining cytotoxic phosphines with features of platinum am(m)ine drugs. Ligands of the form Ph<sub>2</sub>P(CH<sub>2</sub>)<sub>3</sub>NRR’ have been prepared, where R and R’ are alkyl groups of varying steric bulk. On complexation with platinum the ligands form six-membered chelate rings bound via P and N and the extent of chelation has been shown to be controlled by the bulk of the substituents. Chelate formation is also pH depen

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41

Barker, Nathaniel M. "The Influence of Structure in Platinum(II) Polypyridyl Polymorphic Complexes." University of Cincinnati / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1627665370500068.

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42

Browning, Charles. "Diimine(dithiolate)platinum(ii) Chromophores: Synthesis, Spectroscopy, and Material Applications." Thesis, University of North Texas, 2014. https://digital.library.unt.edu/ark:/67531/metadc699877/.

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A series of 28 square-planar dithiol(diimine)platinum(II) chromophoric complexes have been synthesized, characterized, and evaluated for potential efficacy in sensitization of solid state photovoltaic devices to the near-infrared regions of the electromagnetic spectrum. The effect of molecular stacking in the solid state and self-association in solution are shown to influence spectral, electronic, and magnetic properties of the chromophores. Such properties are investigated in the pure form and as partners in donor-acceptor charge transfer adducts. Finally, selected chromophores have been inco

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43

Li, Jun. "Synthesis, characterization and application studies of ionic platinum(II) complexes." HKBU Institutional Repository, 2017. https://repository.hkbu.edu.hk/etd_oa/394.

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This thesis is dedicated to developing novel charged Pt(II) complexes and exploring their applications in electroluminescence, bio-imaging and the preparation of soft salts. At the beginning, a brief introduction about the development of ionic transition metal complexes and an overview of their applications in electroluminescence, bio-imaging and soft salts are presented. In chapter 2, a series of anionic Pt(II) complexes were successfully synthesized and fully characterized for their application in electroluminescence with relatively small current density. All the complexes show highly intens

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44

曾炳堯 and Biing-chiau Tzeng. "Design, structures, spectroscopic, and photophysical properties of supramoleculsar gold(I), platinum(II), and palladium(II) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B31237782.

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45

Tzeng, Biing-chiau. "Design, structures, spectroscopic, and photophysical properties of supramoleculsar gold(I), platinum(II), and palladium(II) complexes /." Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B19471397.

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46

Datt, Michael Steven. "Synthesis and characterisation of novel platinum (II) complexes potential chemotherapeutic drugs." Thesis, Rhodes University, 2001. http://hdl.handle.net/10962/d1005031.

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The present study involves the preparation of novel mixed-ligand platinum(II) complexes in the hope of expanding the range of platinum(II) complexes that exhibit anticancer activity and which are less toxic and have a broader spectrum of activity than cisplatin and its analogues. To this end, N-(3-R-benzoyl)-N’,N’-diethylthiourea, N-(3-R-benzoyl)-N’-morpholinothiourea, N-(3-Rbenzoyl)-N’,N’-di(2-hydroxyethyl)thiourea (R = NO2, Cl, H, CH3, OCH3), N,N-diethyl-N’-menthyloxycarbonylthiourea and N-menthyloxycarbonyl-N’-morpholinothiourea ligands, and their corresponding mixed-ligand platinum(II) com

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47

Allenbaugh, Rachel J. Schauer Cynthia Karen. "Supramolecular ordering through axial interactions in mono and mixed valent metellomesogenic systems of platinum(II) and platinum(IV)." Chapel Hill, N.C. : University of North Carolina at Chapel Hill, 2006. http://dc.lib.unc.edu/u?/etd,360.

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Thesis (Ph. D.)--University of North Carolina at Chapel Hill, 2006.<br>Title from electronic title page (viewed Oct. 10, 2007). "... in partial fulfillment of the requirements for the degree of the Doctor of Philosophy in the Department of Chemistry." Discipline: Chemistry; Department/School: Chemistry.

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48

Hudson, Joshua M. Omary Mohammad A. "Photophysical studies of silver(I), platinum(II), palladium(II), and nickel(II) complexes and their use in electronic devices." [Denton, Tex.] : University of North Texas, 2007. http://digital.library.unt.edu/permalink/meta-dc-5165.

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49

Hudson, Joshua M. "Photophysical studies of silver(I), platinum(II), palladium(II), and nickel(II) complexes and their use in electronic devices." Thesis, University of North Texas, 2007. https://digital.library.unt.edu/ark:/67531/metadc5165/.

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This dissertation deals with two major topics that involve spectroscopic studies of (a) divalent group 10 metals and (b) silver(I)-phosphine complexes. The scope of the work involved the delineation of the electronic structure of these complexes in different environments and their use in electronic devices. The first topic is a look at the luminescence of tetrahedral silver(I)-phosphine complexes. Broad unstructured emissions with large Stokes shifts were found for these complexes. Computational analysis of the singlet and triplet state geometries suggests that this emission is due to a Jahn-T

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50

Liu, Li. "The chemistry of luminescent mercury (II) alkynyl complexes and their platinum (II) and gold (I) counterparts." HKBU Institutional Repository, 2005. http://repository.hkbu.edu.hk/etd_ra/627.

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