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Journal articles on the topic 'Poly[3-(3'

Author: Grafiati

Published: 3 June 2025

Last updated: 19 July 2025

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1

He, Ji-Dong, Man Ken Cheung, Peter H. Yu, and Guo-Qiang Chen. "Thermal analyses of poly(3-hydroxybutyrate), poly(3-hydroxybutyrate-co-3-hydroxyvalerate), and poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)." Journal of Applied Polymer Science 82, no. 1 (2001): 90–98. http://dx.doi.org/10.1002/app.1827.

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2

Sato, Masa-aki, Susumu Tanaka, Kyoji Kaeriyama, and Fumi-aki Tomonaga. "Poly(3-butylthiophene) and poly(3-benzylthiophene) films." Polymer 28, no. 7 (1987): 1071–74. http://dx.doi.org/10.1016/0032-3861(87)90244-8.

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3

Causin, Valerio, Carla Marega, Antonio Marigo, Luca Valentini, and Josè Maria Kenny. "Crystallization and Melting Behavior of Poly(3-butylthiophene), Poly(3-octylthiophene), and Poly(3-dodecylthiophene)." Macromolecules 38, no. 2 (2005): 409–15. http://dx.doi.org/10.1021/ma048159+.

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4

Conti, Denise Santos, Maria Irene Yoshida, Sérgio Henrique Pezzin, and Luiz Antônio Ferreira Coelho. "Phase behavior of poly(3-hydroxybutyrate)/poly(3-hydroxybutyrate-co-3-hydroxyvalerate) blends." Fluid Phase Equilibria 261, no. 1-2 (2007): 79–84. http://dx.doi.org/10.1016/j.fluid.2007.07.022.

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5

Li, Si-Dong, Peter H. Yu, and Man Ken Cheung. "Thermogravimetric analysis of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate)." Journal of Applied Polymer Science 80, no. 12 (2001): 2237–44. http://dx.doi.org/10.1002/app.1327.

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6

Bello, Antonio, Ernesto Perez, and Jose M. Gomez Fatou. "Crystalline poly(3-ethyl-3-methyloxetane)." Macromolecules 19, no. 10 (1986): 2497–501. http://dx.doi.org/10.1021/ma00164a007.

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7

El Kassmi, Ahmed, Fabienne Fache, and Marc Lemaire. "Poly(3-fluorothiophene)." Journal of Electroanalytical Chemistry 373, no. 1-2 (1994): 241–44. http://dx.doi.org/10.1016/0022-0728(93)03304-8.

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8

Bonartsev, A. P., G. A. Bonartseva, K. V. Shaitan, and M. P. Kirpichnikov. "Poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate)-based biopolymer systems." Biochemistry (Moscow) Supplement Series B: Biomedical Chemistry 5, no. 1 (2011): 10–21. http://dx.doi.org/10.1134/s1990750811010045.

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9

Qiao, Xiuying, Xianhong Wang, Xiaojiang Zhao, Zhishen Mo, and Hongfang Zhang. "Nonisothermal crystallization of poly(3-dodecylthiophene) and poly(3-octadecylthiophene)." Synthetic Metals 113, no. 1-2 (2000): 1–6. http://dx.doi.org/10.1016/s0379-6779(99)00131-9.

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10

Masuda, Hideyuki, and Kyoji Kaeriyama. "Electrochemical preparation of poly(3-propanoylpyrrole) and poly(3-phenylpyrrole)." Synthetic Metals 38, no. 3 (1990): 371–79. http://dx.doi.org/10.1016/0379-6779(90)90090-8.

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11

Liu, Qingsheng, Hongxia Zhang, Bingyao Deng, and Xiaoyan Zhao. "Poly(3-hydroxybutyrate) and Poly(3-hydroxybutyrate-co-3-hydroxyvalerate): Structure, Property, and Fiber." International Journal of Polymer Science 2014 (2014): 1–11. http://dx.doi.org/10.1155/2014/374368.

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Poly(3-hydroxybutyrate) [P(3HB)] and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) [P(3HB-co-3HV)] are produced by various microorganisms as an intracellular carbon and energy reserve from agricultural feedstocks such as sugars and plant oils under unbalanced growth conditions. P(3HB) and P(3HB-co-3HV) have attracted the attention of academia and industry because of its biodegradability, biocompatibility, thermoplasticity, and plastic-like properties. This review first introduced the isodimorphism, spherulites, and molecular interaction of P(3HB) and P(3HB-co-3HV). In addition, the effects of 3HV content on the melting temperature and crystallization rate were discussed. Then the drawbacks of P(3HB) and P(3HB-co-3HV) including brittleness, narrow melt processing window, low crystallization rate, slow biodegradation rate in body, and so on were summarized. At last, the preparation, structure, and properties of P(3HB) and P(3HB-co-3HV) fiber were introduced.

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12

Conti, D. S., M. I. Yoshida, S. H. Pezzin, and L. A. F. Coelho. "Miscibility and crystallinity of poly(3-hydroxybutyrate)/poly(3-hydroxybutyrate-co-3-hydroxyvalerate) blends." Thermochimica Acta 450, no. 1-2 (2006): 61–66. http://dx.doi.org/10.1016/j.tca.2006.07.018.

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13

Porselvi, L., and S. Jhancy Mary. "Synthesis and Studies on Electroactive Poly(3-chloroaniline), Poly(3-chloroaniline)- Blend-polyethyleneglycol and Poly(3-chloroaniline)-Blend-Poly(vinyl alcohol)." Asian Journal of Chemistry 26, no. 3 (2014): 783–89. http://dx.doi.org/10.14233/ajchem.2014.15540.

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14

Tajima, Kenji, Hatsumi Tannai, Yasuharu Satoh, and Masanobu Munekata. "Synthesis of Poly(3-hydroxybutyrate) by Immobilized Poly(3-hydroxybutyrate) Synthase." Polymer Journal 35, no. 4 (2003): 407–10. http://dx.doi.org/10.1295/polymj.35.407.

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15

Benincori, Tiziana, Elisabetta Brenna, Franco Sannicolò, Licia Trimarco, and Gianni Zotti. "Stereoelectronic effects in polythiophenes: poly(3-cyclopropylthiophene) and poly (3-cyclobutylthiophene)." Synthetic Metals 83, no. 1 (1996): 57–59. http://dx.doi.org/10.1016/s0379-6779(97)80052-5.

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16

Minkler, Michael J., Jihyuk Kim, Katherine E. Lawson, et al. "Solution processible statistical poly(3-methoxythiophene)-co-poly(3-hexylthiophene) copolymer." Materials Letters 256 (December 2019): 126563. http://dx.doi.org/10.1016/j.matlet.2019.126563.

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17

Basnett, P., K. Y. Ching, M. Stolz, et al. "Novel Poly(3-hydroxyoctanoate)/Poly(3-hydroxybutyrate) blends for medical applications." Reactive and Functional Polymers 73, no. 10 (2013): 1340–48. http://dx.doi.org/10.1016/j.reactfunctpolym.2013.03.019.

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18

Mergaert, J., A. Webb, C. Anderson, A. Wouters, and J. Swings. "Microbial degradation of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) in soils." Applied and Environmental Microbiology 59, no. 10 (1993): 3233–38. http://dx.doi.org/10.1128/aem.59.10.3233-3238.1993.

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19

Satoh, Hidenori, Naoko Yoshie, and Yoshio Inoue. "Hydrolytic degradation of blends of poly(3-hydroxybutyrate) with poly(3-hydroxybutyrate-co-3-hydroxyvalerate)." Polymer 35, no. 2 (1994): 286–90. http://dx.doi.org/10.1016/0032-3861(94)90692-0.

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20

Mergaert, Joris, Caroline Anderson, Ann Wouters, and Jean Swings. "Microbial degradation of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) in compost." Journal of Environmental Polymer Degradation 2, no. 3 (1994): 177–83. http://dx.doi.org/10.1007/bf02067443.

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21

Miguel, O., and J. J. Iruin. "Water transport properties in poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) biopolymers." Journal of Applied Polymer Science 73, no. 4 (1999): 455–68. http://dx.doi.org/10.1002/(sici)1097-4628(19990725)73:4<455::aid-app1>3.0.co;2-y.

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22

Conti, Denise Santos, Sérgio Henrique Pezzin, and Luiz Antônio Ferreira Coelho. "Mechanical and Morphological Properties of Poly(3-hydroxybutyrate)/Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Blends." Macromolecular Symposia 245-246, no. 1 (2006): 491–500. http://dx.doi.org/10.1002/masy.200651370.

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23

Ye, Hai-Mu, Zhen Wang, Hong-Hui Wang, Guo-Qiang Chen, and Jun Xu. "Different thermal behaviors of microbial polyesters poly(3-hydroxybutyrate-co-3-hydroxyvalerate-co-3-hydroxyhexanoate) and poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)." Polymer 51, no. 25 (2010): 6037–46. http://dx.doi.org/10.1016/j.polymer.2010.10.030.

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24

Izumi, Celly M. S., and Marcia L. A. Temperini. "FT-Raman investigation of biodegradable polymers: Poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate)." Vibrational Spectroscopy 54, no. 2 (2010): 127–32. http://dx.doi.org/10.1016/j.vibspec.2010.07.011.

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25

Mitomo, Hiroshi, Yuhei Watanabe, Isao Ishigaki, and Terumi Saito. "Radiation-induced degradation of poly(3-hydroxybutyrate) and the copolymer poly(3-hydroxybutyrate-co-3-hydroxyvalerate)." Polymer Degradation and Stability 45, no. 1 (1994): 11–17. http://dx.doi.org/10.1016/0141-3910(94)90173-2.

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26

Mukhopadhyay, Mahuya, A. Patra, and A. K. Paul. "Production of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by Rhodopseudomonas palustris SP5212." World Journal of Microbiology and Biotechnology 21, no. 5 (2005): 765–69. http://dx.doi.org/10.1007/s11274-004-5565-y.

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27

Berezina, Nathalie, Bopha Yada, Thomas Godfroid, Tangi Senechal, Ren Wei, and Wolfgang Zimmermann. "Enzymatic surface treatment of poly (3-hydroxybutyrate) (PHB), and poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV)." Journal of Chemical Technology & Biotechnology 90, no. 11 (2014): 2036–39. http://dx.doi.org/10.1002/jctb.4513.

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28

Chen, Yun, I.-Ning Chou, Ya-Hui Tsai, and Ho-Shing Wu. "Thermal degradation of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) in drying treatment." Journal of Applied Polymer Science 130, no. 5 (2013): 3659–67. http://dx.doi.org/10.1002/app.39616.

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29

Sombatmankhong, Korakot, Orawan Suwantong, Suchada Waleetorncheepsawat, and Pitt Supaphol. "Electrospun fiber mats of poly(3-hydroxybutyrate), poly(3-hydroxybutyrate-co-3-hydroxyvalerate), and their blends." Journal of Polymer Science Part B: Polymer Physics 44, no. 19 (2006): 2923–33. http://dx.doi.org/10.1002/polb.20915.

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30

Miguel, O., T. A. Barbari, and J. J. Iruin. "Carbon dioxide sorption and diffusion in poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-CO-3-hydroxyvalerate)." Journal of Applied Polymer Science 71, no. 14 (1999): 2391–99. http://dx.doi.org/10.1002/(sici)1097-4628(19990404)71:14<2391::aid-app11>3.0.co;2-q.

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31

Dufresne, Alain, and Marc Vincendon. "Poly(3-hydroxybutyrate) and Poly(3-hydroxyoctanoate) Blends: Morphology and Mechanical Behavior." Macromolecules 33, no. 8 (2000): 2998–3008. http://dx.doi.org/10.1021/ma991854a.

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32

Caple, G., B. L. Wheeler, R. Swift, T. L. Porter, and S. Jeffers. "Scanning tunneling microscopy of polythiophene, poly(3-methylthiophene), and poly(3-bromothiophene)." Journal of Physical Chemistry 94, no. 15 (1990): 5639–41. http://dx.doi.org/10.1021/j100378a002.

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33

McClain, Mark D., Douglas A. Whittington, Deanna J. Mitchell, and M. David Curtis. "Novel Poly(3-alkylthiophene) and Poly(3- alkylthienyl ketone) Syntheses via Organomercurials." Journal of the American Chemical Society 117, no. 13 (1995): 3887–88. http://dx.doi.org/10.1021/ja00118a033.

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34

Nguyen, My T., and Lê H. Dao. "Synthesis, characterization and properties of poly-(3-methyldiphenylamine) and poly(3-methoxydiphenylamine)." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 289, no. 1-2 (1990): 37–53. http://dx.doi.org/10.1016/0022-0728(90)87205-x.

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35

Aoyama, Yoshinori, Kouji Hatakeyama, Takuma Mukai, and Hitoshi Koizumi. "Electronic Properties of Poly[3-(1,1-dimethylpropyl)thiophene] and Poly(3-cyclohexylthiophene)." Bulletin of the Chemical Society of Japan 86, no. 1 (2013): 51–56. http://dx.doi.org/10.1246/bcsj.20120064.

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36

Chen, Show-An, and Jui-Ming Ni. "Thermal analysis of FeCl3-doped poly(3-butylthiophene) and poly(3-dodecylthiophene)." Polymer Bulletin 26, no. 6 (1991): 673–80. http://dx.doi.org/10.1007/bf00313223.

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37

Born, Max, Thomas C. Fessard, Lucas Göttemann, Jakob Plank, and Thomas M. Klapötke. "A GAP Replacement, Part 2: Preparation of Poly(3-azidooxetane) via Azidation of Poly(3-tosyloxyoxetane) and Poly(3-mesyloxyoxetane)." Journal of Organic Chemistry 87, no. 6 (2022): 4097–106. http://dx.doi.org/10.1021/acs.joc.1c02907.

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38

Chen, Zhifei, Shaoting Cheng, and Kaitian Xu. "Block poly(ester-urethane)s based on poly(3-hydroxybutyrate-co-4-hydroxybutyrate) and poly(3-hydroxyhexanoate-co-3-hydroxyoctanoate)." Biomaterials 30, no. 12 (2009): 2219–30. http://dx.doi.org/10.1016/j.biomaterials.2008.12.078.

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39

Kumagai, Yoshiharu, and Yoshiharu Doi. "Enzymatic degradation of poly(3-hydroxybutyrate)-based blends: poly(3-hydroxybutyrate)/poly(ethylene oxide) blend." Polymer Degradation and Stability 35, no. 1 (1992): 87–93. http://dx.doi.org/10.1016/0141-3910(92)90139-v.

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40

Wang, Gang, Zhen Ge, and Yunjun Luo. "Synthesis and Characterization of Poly(3-azidomethyl-3-methyl oxetane) by the Azidation of Poly(3-mesyloxymethyl-3-methyl oxetane)." Propellants, Explosives, Pyrotechnics 40, no. 6 (2015): 920–26. http://dx.doi.org/10.1002/prep.201500064.

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41

Sonoyama, Arisa, and Masayuki Yamaguchi. "Mechanical Modification of Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) by Addition of Crosslinked Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) Particles." Polymers 17, no. 10 (2025): 1318. https://doi.org/10.3390/polym17101318.

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In the present study, we prepared crosslinked particles of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBH) to investigate their performance as impact modifiers. The mechanical properties of crystalline PHBH comprising 5.6 mol% 3-hydroxyhexanoate (3HHx) were modified by the addition of amorphous particles of PHBH with 28 mol% 3HHx (PHBH28). The tensile impact strength of the mixture was improved by the addition of PHBH28 particles, particularly when they were crosslinked. The size of the dispersed uncrosslinked PHBH28 particles was sensitive to the processing method. However, the crosslinked PHBH28 particles retained their form under any processing conditions, and a smaller particle size was achieved, leading to shear yielding. The samples containing crosslinked PHBH28 particles exhibited intense stress-whitening after impact testing. The resulting voids were ascribed to cavitation in the particles, which must have been responsible for the improved mechanical properties of the samples. Moreover, the crosslinked particles did not affect the excellent biodegradability of PHBH in seawater.

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42

Doi, Yoshiharu, Youko Kanesawa, Masao Kunioka, and Terumi Saito. "Biodegradation of microbial copolyesters: poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and poly(3-hydroxybutyrate-co-4-hydroxybutyrate)." Macromolecules 23, no. 1 (1990): 26–31. http://dx.doi.org/10.1021/ma00203a006.

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43

Coskun, Suleyman, Feza Korkusuz, and Vasif Hasirci. "Hydroxyapatite reinforced poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based degradable composite bone plate." Journal of Biomaterials Science, Polymer Edition 16, no. 12 (2005): 1485–502. http://dx.doi.org/10.1163/156856205774576727.

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44

Mergaert, J., A. Wouters, J. Swings, and C. Anderson. "In situ biodegradation of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) in natural waters." Canadian Journal of Microbiology 41, no. 13 (1995): 154–59. http://dx.doi.org/10.1139/m95-182.

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The biodegradation of samples of poly(3-hydroxybutyrate) (P(3HB)), poly(3-hydroxybutyrate-co-10%-3-hydroxyvalerate) (P(3HB-co-10%-3HV)), and poly(3-hydroxybutyrate-co-20%-3-hydroxyvalerate) (P(3HB-co-20%-3HV)) was investigated in situ in natural waters. The degradation was studied by decrease in mass, molecular weight, and tensile strength. In two freshwater ponds the polymers were slowly degraded. After half a year of submersion the mass loss was less than 7%. After 358 days in a freshwater canal, 34% mass loss was recorded for the homopolymer, and 77% for the P(3HB-co-10%-3-HV) samples, while the P(3HB-co-20%-3HV) samples had completely disappeared. In seawater in the harbour of Zeebrugge, P(3HB) samples lost 31% of their initial mass, and the copolymers 49–52%, within 270 days. In all of these environments, the degradation rate was faster during the summer, when the temperature of the water was higher. No relevant changes in molecular weight could be detected, indicating that the degradation took place only at the surface of the samples. The degradation resulted in considerable loss of tensile strength of the copolymer samples. Ninety-two microorganisms, mainly bacteria, able to degrade P(3HB) in polymer overlayer plates, were isolated and identified by fatty acid analysis. The isolates from one freshwater pond belonged mainly to the bacterial genus Acidovorax, while the microorganisms from the other freshwater pond belonged to various bacterial genera, to Streptomyces, and to the mould genus Penicillium. Most of the 31 bacterial isolates from seawater were identified as Alteromonas haloplanktis. The results demonstrate that P(3HB) and P(3HB-co-3HV) samples are effectively biodegradable in natural waters under real-life conditions and reveal the biodiversity of the microflora responsible for this biodegradation.Key words: poly(3-hydroxybutyrate), poly(3-hydroxybutyrate-co-3-hydroxyvalerate), biodegradation, seawater, freshwater.

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45

Lütke-Eversloh, Tina, Klaus Bergander, Heinrich Luftmann, and Alexander Steinbüchel. "Biosynthesis of Poly(3-hydroxybutyrate-co-3-mercaptobutyrate) as a Sulfur Analogue to Poly(3-hydroxybutyrate) (PHB)." Biomacromolecules 2, no. 3 (2001): 1061–65. http://dx.doi.org/10.1021/bm015564p.

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46

Saito, M., Y. Inoue, and N. Yoshie. "Cocrystallization and phase segregation of blends of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate)." Polymer 42, no. 13 (2001): 5573–80. http://dx.doi.org/10.1016/s0032-3861(01)00011-8.

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47

Mansour, Ashraf A., Gamal R. Saad, and Amany H. Hamed. "II. Dielectric investigation of cold crystallization of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate)." Polymer 40, no. 19 (1999): 5377–91. http://dx.doi.org/10.1016/s0032-3861(98)00741-1.

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48

Sanyal, Puspita, Parama Samaddar, and A. K. Paul. "Degradation of Poly(3-hydroxybutyrate) and Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by Some Soil Aspergillus spp." Journal of Polymers and the Environment 14, no. 3 (2006): 257–63. http://dx.doi.org/10.1007/s10924-006-0022-7.

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49

Suwantong, Orawan, Suchada Waleetorncheepsawat, Neeracha Sanchavanakit, et al. "In vitro biocompatibility of electrospun poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) fiber mats." International Journal of Biological Macromolecules 40, no. 3 (2007): 217–23. http://dx.doi.org/10.1016/j.ijbiomac.2006.07.006.

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50

McKeown, George R., Yuan Fang, Nimrat K. Obhi, Joseph G. Manion, Dmitrii F. Perepichka, and Dwight S. Seferos. "Synthesis of Macrocyclic Poly(3-hexylthiophene) and Poly(3-heptylselenophene) by Alkyne Homocoupling." ACS Macro Letters 5, no. 10 (2016): 1075–79. http://dx.doi.org/10.1021/acsmacrolett.6b00603.

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