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1

Abdou, Mohamed S. A., and Steven Holdcroft. "Gold-Decorated Poly(3-alkylthiophenes)." Chemistry of Materials 8, no. 1 (January 1996): 26–31. http://dx.doi.org/10.1021/cm950241j.

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2

Gustafsson, G., O. Ingan⇒, S. Stafström, H. Österholm, and J. Laakso. "Stretch-oriented poly(3-alkylthiophenes)." Synthetic Metals 41, no. 1-2 (April 1991): 593–96. http://dx.doi.org/10.1016/0379-6779(91)91139-2.

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3

Shinohara, Yoshikazu, K. Ohara, Hachiro Nakanishi, Yoshio Imai, and Yukihiro Isoda. "Thermoelectric Properties of Poly(3-Alkylthiophenes)." Materials Science Forum 492-493 (August 2005): 141–44. http://dx.doi.org/10.4028/www.scientific.net/msf.492-493.141.

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Typical conductive polymers of poly(3-alkylthiophenes) were synthesized by oxidative polymerization. Alkyl side chains were CnH2n+1 with n=4, 6, 8, 12. The regioregularity with the HT linkage was larger than 99% based on NMR analysis. Completely regioregular head-to-tail (HT) poly(3-alkylthiophenes) were obtained. We have evaluated the effect of side chain size on the thermoelectric properties of Seebeck coefficient and electrical conductivity. The results were as follows: 1) Seebeck coefficient decreased with an increasing electrical conductivity. 2) High Seebeck coefficient >1mV/K was observed at low electrical conductivity <10-2S/cm. 3) The small side chain caused the higher electrical conductivity in the range of electrical conductivity <10- 1S/cm.
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4

Botta, C., A. Bolognesi, S. Luzzati, R. Tubino, and A. Borghesi. "Photoexcitation spectroscopy of poly-3-alkylthiophenes." Synthetic Metals 41, no. 3 (May 1991): 1323–26. http://dx.doi.org/10.1016/0379-6779(91)91616-i.

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5

Gustafsson, G., O. Inganäs, J. O. Nilsson, and B. Liedberg. "Thermal undoping in poly(3-alkylthiophenes)." Synthetic Metals 26, no. 3 (November 1988): 297–309. http://dx.doi.org/10.1016/0379-6779(88)90245-7.

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6

Stein, P. C., A. Bolognesi, M. Catellani, S. Destri, and L. Zetta. "NMR studies of poly(3-alkylthiophenes)." Synthetic Metals 41, no. 1-2 (April 1991): 559–62. http://dx.doi.org/10.1016/0379-6779(91)91132-t.

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7

Hsu, Wen Ping, Kalle Levon, Ko Shan Ho, Allan S. Myerson, and T. K. Kwei. "Side-chain order in poly(3-alkylthiophenes)." Macromolecules 26, no. 6 (November 1993): 1318–23. http://dx.doi.org/10.1021/ma00058a021.

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8

Watanabe, Itsuo, Keith Hong, and Michael F. Rubner. "Langmuir-Blodgett manipulation of poly(3-alkylthiophenes)." Langmuir 6, no. 6 (June 1990): 1164–72. http://dx.doi.org/10.1021/la00096a024.

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9

Gustafsson, G., O. Inganäs, and J. O. Nilsson. "Thermal instability of doped poly(3-alkylthiophenes)." Synthetic Metals 28, no. 1-2 (January 1989): 427–34. http://dx.doi.org/10.1016/0379-6779(89)90555-9.

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10

Winokur, M. J., Paula Wamsley, Jeff Moulton, Paul Smith, and A. J. Heeger. "Structural evolution in iodine-doped poly(3-alkylthiophenes)." Macromolecules 24, no. 13 (June 1991): 3812–15. http://dx.doi.org/10.1021/ma00013a011.

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11

Chun-Guey, Wu, Chan Mei-Jui, and Lin Yii-Chung. "Room temperature dedoping of conducting poly-3-alkylthiophenes." Journal of Materials Chemistry 8, no. 12 (1998): 2657–61. http://dx.doi.org/10.1039/a805462b.

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12

Louarn, Guy, Miroslaw Trznadel, J. P. Buisson, Jadwiga Laska, Adam Pron, Mieczyslaw Lapkowski, and Serge Lefrant. "Raman Spectroscopic Studies of Regioregular Poly(3-alkylthiophenes)." Journal of Physical Chemistry 100, no. 30 (January 1996): 12532–39. http://dx.doi.org/10.1021/jp960104p.

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13

Buvat, Pierrick, and Patrick Hourquebie. "Enhanced Infrared Properties of Regioregular Poly(3-alkylthiophenes)." Macromolecules 30, no. 9 (May 1997): 2685–92. http://dx.doi.org/10.1021/ma9618080.

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14

Mårdalen, Jostein, Emil J. Samuelsen, Odd R. Gautun, and Per H. Carlsen. "X-ray scattering from oriented poly(3-alkylthiophenes)." Synthetic Metals 48, no. 3 (July 1992): 363–80. http://dx.doi.org/10.1016/0379-6779(92)90239-f.

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15

Inganäs, O., G. Gustafsson, W. R. Salaneck, J. E. Österholm, and J. Laakso. "Thermochromism in thin films of poly(3-alkylthiophenes)." Synthetic Metals 28, no. 1-2 (January 1989): 377–84. http://dx.doi.org/10.1016/0379-6779(89)90549-3.

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16

Loponen, M. T., T. Taka, J. Laakso, K. Väkiparta, K. Suuronen, P. Valkeinen, and J. E. Österholm. "Doping and dedoping processes in poly (3-alkylthiophenes)." Synthetic Metals 41, no. 1-2 (April 1991): 479–84. http://dx.doi.org/10.1016/0379-6779(91)91111-m.

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17

Abdou, Mohamed S. A., and Steven Holdcroft. "Solid-state photochemistry of π-conjugated poly(3-alkylthiophenes)." Canadian Journal of Chemistry 73, no. 11 (November 1, 1995): 1893–901. http://dx.doi.org/10.1139/v95-234.

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Films of poly(3-alkylthiophenes) undergo simultaneous photobleaching, cross-linking, and chain scission when irradiated in air with UV or visible light. The quantum yields of the latter two processes were determined using Chalesby–Pinner theory. Under the irradiation conditions employed the cross-linking density is ~ 4.5 times greater than the fracture density (chain scission). This corroborates the observation that poly(3-alkylthiophenes) are negative-type photoresists. Although the quantum yield of cross-linking is relatively low, the polymer maintains a relatively high degree of π-conjugation following irradiation. The mechanism of cross-linking and insolubilization proceeds via a classical photooxidation route that is initiated by photolysis of residual iron impurities. Photobleaching involves photosensitization, and reaction of singlet oxygen. 1O2 undergoes a 1,4 Diels–Alder addition to thienyl units which results in a loss of π-conjugation, a blue shift in the absorption spectrum of the polymer, and a decrease in the optical density. Photobleaching, cross-linking, and chain scission are considerably reduced in the absence of oxygen. Keywords: photochemistry, polymers, thin films, degradation, cross-linking.
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18

Robinson, Linda, Joakim Isaksson, Nathaniel D. Robinson, and Magnus Berggren. "Electrochemical control of surface wettability of poly(3-alkylthiophenes)." Surface Science 600, no. 11 (June 2006): L148—L152. http://dx.doi.org/10.1016/j.susc.2006.03.039.

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19

Trznadel, M., A. Pron, and M. Zagorska. "Preparation and properties of fractionated regioregular poly(3-alkylthiophenes)." Synthetic Metals 101, no. 1-3 (May 1999): 118–19. http://dx.doi.org/10.1016/s0379-6779(98)01313-7.

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20

Abdou, Mohamed S. A., and Steven Holdcroft. "Mechanisms of photodegradation of poly(3-alkylthiophenes) in solution." Macromolecules 26, no. 11 (May 1993): 2954–62. http://dx.doi.org/10.1021/ma00063a047.

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21

Barta, P., S. Niziol/, P. Le Guennec, and A. Proń. "Doping-induced magnetic phase transition in poly(3-alkylthiophenes)." Physical Review B 50, no. 5 (August 1, 1994): 3016–24. http://dx.doi.org/10.1103/physrevb.50.3016.

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22

Jen, Kwan-Yue, G. G. Miller, and Ronald L. Elsenbaumer. "Highly conducting, soluble, and environmentally-stable poly(3-alkylthiophenes)." Journal of the Chemical Society, Chemical Communications, no. 17 (1986): 1346. http://dx.doi.org/10.1039/c39860001346.

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23

McCullough, Richard D., and Renae D. Lowe. "Enhanced electrical conductivity in regioselectively synthesized poly(3-alkylthiophenes)." Journal of the Chemical Society, Chemical Communications, no. 1 (1992): 70. http://dx.doi.org/10.1039/c39920000070.

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24

Koizumi, Hitoshi, Hiroshi Dougauchi, and Tsuneki Ichikawa. "Mechanism of Dedoping Processes of Conducting Poly(3-alkylthiophenes)." Journal of Physical Chemistry B 109, no. 32 (August 2005): 15288–90. http://dx.doi.org/10.1021/jp051989k.

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25

Sundberg, M., O. Inganäs, S. Stafström, G. Gustafsson, and B. Sjögren. "Optical absorption of poly(3-alkylthiophenes) at low temperatures." Solid State Communications 71, no. 6 (August 1989): 435–39. http://dx.doi.org/10.1016/0038-1098(89)90087-2.

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26

Łużny, W., M. Trznadel, and A. Proń. "X-ray diffraction study of regioregular poly(3-alkylthiophenes)." Synthetic Metals 81, no. 1 (July 1996): 71–74. http://dx.doi.org/10.1016/0379-6779(96)80231-1.

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27

Isotalo, H., M. Ahlskog, and H. Stubb. "Pressure dependence of d.c. conductivity in poly(3-alkylthiophenes)." Synthetic Metals 48, no. 3 (July 1992): 313–23. http://dx.doi.org/10.1016/0379-6779(92)90234-a.

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28

Inganäs, O., and G. Gustafsson. "Thermochromism in poly(3-alkylthiophenes) and their polymer blends." Synthetic Metals 37, no. 1-3 (August 1990): 195–205. http://dx.doi.org/10.1016/0379-6779(90)90147-d.

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29

Mådalen, J., E. J. Samuelsen, and O. R. Gautun. "X-ray diffraction studies of oriented poly(3-alkylthiophenes)." Synthetic Metals 41, no. 1-2 (April 1991): 598. http://dx.doi.org/10.1016/0379-6779(91)91141-v.

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30

Gustafsson, G., and O. Inganäs. "Spectroelectrochemical study of thermal undoping in poly (3-alkylthiophenes)." Synthetic Metals 43, no. 1-2 (June 1991): 2901. http://dx.doi.org/10.1016/0379-6779(91)91201-k.

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31

Lapkowski, M., M. Zagorska, I. Kulszewicz-Bajer, and A. Pron. "Memory effect in poly(4,4′-diakyl-2,2′-bithiophenes) and poly(3-alkylthiophenes)." Synthetic Metals 55, no. 2-3 (March 1993): 1570–73. http://dx.doi.org/10.1016/0379-6779(93)90286-6.

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32

z.xl;Lapkowski, Mieczysław, Małgorzata Zagórska, Irena Kulszewicz-Bajer, Krzysztof Kozieł, and Adam Proń. "Spectroelectrochemical properties of poly(4,4'-dialkyl-2,2'-bithiophenes) and poly( 3-alkylthiophenes)." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 310, no. 1-2 (July 1991): 57–70. http://dx.doi.org/10.1016/0022-0728(91)85252-k.

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33

Łapkowski, M., M. Zagórska, I. Kulszewicz-Bajer, and A. Proń. "Voltammetric properties of poly(4,4′-dialkyl-2,2′-bithiophenes) and poly(3-alkylthiophenes)." Journal of Electroanalytical Chemistry 341, no. 1-2 (December 1992): 151–63. http://dx.doi.org/10.1016/0022-0728(92)80481-i.

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34

Krinichnyi, V. I., H. K. Roth, and A. L. Konkin. "Multifrequency EPR study of charge transfer in poly(3-alkylthiophenes)." Physica B: Condensed Matter 344, no. 1-4 (February 2004): 430–35. http://dx.doi.org/10.1016/j.physb.2003.10.024.

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35

Yang, Cheng, and Steven Holdcroft. "Thermochromism and Band-Gap Tuning of Acrylated Poly(3-alkylthiophenes)." Synthetic Metals 84, no. 1-3 (January 1997): 563–64. http://dx.doi.org/10.1016/s0379-6779(97)80860-0.

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36

Sworakowski, Juliusz, Marcin Bieńkowski, Antoni Chyla, and Stanisław Kucharski. "Multicomponent lb films containing pre-formed poly(3-n -Alkylthiophenes)." Macromolecular Symposia 104, no. 1 (March 1996): 115–26. http://dx.doi.org/10.1002/masy.19961040114.

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37

Prosa, T. J., M. J. Winokur, Jeff Moulton, P. Smith, and A. J. Heeger. "X-ray diffraction studies of iodine-doped poly(3-alkylthiophenes)." Synthetic Metals 55, no. 1 (March 1993): 370–77. http://dx.doi.org/10.1016/0379-6779(93)90960-5.

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38

Kreja, L., W. Czerwiński, J. Kurzawa, and M. Kurzawa. "Structure and electrical properties of chemically modified poly(3-alkylthiophenes)." Synthetic Metals 72, no. 2 (May 1995): 153–58. http://dx.doi.org/10.1016/0379-6779(94)02324-r.

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39

Österholm, J. E., J. Laakso, P. Nyholm, H. Isotalo, H. Stubb, O. Inganäs, and W. R. Salaneck. "Melt and solution processable poly(3-alkylthiophenes) and their blends." Synthetic Metals 28, no. 1-2 (January 1989): 435–44. http://dx.doi.org/10.1016/0379-6779(89)90556-0.

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40

Barta, P., S. Niziol/, M. Zagórska, A. Proń, and Z. Trybul/a. "Magnetic studies ofFeCl4−-doped poly(3-alkylthiophenes) and poly(4,4’-dialkyl-2,2’-bithiophenes)." Physical Review B 48, no. 1 (July 1, 1993): 243–49. http://dx.doi.org/10.1103/physrevb.48.243.

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41

Luzny, W., P. Barta, and S. Niziol. "Transport and Structural Properties of Pure and Doped Poly(3-Alkylthiophenes)." Materials Science Forum 122 (January 1993): 105–12. http://dx.doi.org/10.4028/www.scientific.net/msf.122.105.

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42

Rieke, Reuben D., and Seung-Hoi Kim. "An Organozinc Route for the Preparation of Functionalized Poly-3-alkylthiophenes." Bulletin of the Korean Chemical Society 33, no. 6 (June 20, 2012): 2071–74. http://dx.doi.org/10.5012/bkcs.2012.33.6.2071.

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43

Ho, Victor, Bryan S. Beckingham, Hoi H. Ng, and Rachel A. Segalman. "Control of thermal and optoelectronic properties in conjugated poly(3-alkylthiophenes)." MRS Communications 4, no. 2 (March 26, 2014): 45–50. http://dx.doi.org/10.1557/mrc.2014.9.

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44

Bolognesi, A., G. Bajo, Z. Geng, W. Porzio, and F. Speroni. "Preparation of Langmuir-Blodgett multilayers with differently substituted poly(3-alkylthiophenes)." Thin Solid Films 243, no. 1-2 (May 1994): 683–86. http://dx.doi.org/10.1016/0040-6090(93)04088-a.

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45

Abdou, Mohamed S. A., and Steven Holdcroft. "Photochemistry Of Electronically Conducting Poly(3-alkylthiophenes) Containing FeCl4- Counter Ions." Chemistry of Materials 6, no. 7 (July 1994): 962–68. http://dx.doi.org/10.1021/cm00043a017.

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46

Łużny, W., and M. Zagórska. "Effect of Uniaxial Stretching on Structural Properties of Poly(3-Alkylthiophenes)." Acta Physica Polonica A 92, no. 3 (September 1997): 491–500. http://dx.doi.org/10.12693/aphyspola.92.491.

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47

Daoud, Walid A., and John H. Xin. "Regioregular poly(3-alkylthiophenes): Synthesis, characterization, and application in conductive fabrics." Journal of Applied Polymer Science 93, no. 5 (2004): 2131–35. http://dx.doi.org/10.1002/app.20695.

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48

Daoud, Walid A., and John H. Xin. "Regioregular poly(3-alkylthiophenes): Synthesis, characterization, and application in conductive fabrics." Journal of Applied Polymer Science 94, no. 4 (2004): 1853. http://dx.doi.org/10.1002/app.21378.

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49

de Santana, Henrique, Elaine Cristina Rodrigues Maia, Danielly Cristina Bento, Thiago Nogueira Marques Cervantes, and Gregory J. Moore. "Spectroscopic study of poly(3-alkylthiophenes) electrochemically synthesized in different conditions." Journal of Materials Science: Materials in Electronics 24, no. 9 (April 27, 2013): 3352–58. http://dx.doi.org/10.1007/s10854-013-1254-7.

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50

Granström, M., and O. Inganäs. "A kinetic study of thermal undoping in the poly(3-alkylthiophenes)." Synthetic Metals 48, no. 1 (June 1992): 21–31. http://dx.doi.org/10.1016/0379-6779(92)90046-l.

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