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Journal articles on the topic 'Poly-ligand electrolyte'

Author: Grafiati

Published: 30 May 2022

Last updated: 31 July 2025

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1

Hapon, Yuliana, Maryna Chyrkina, Dmytro Tregubov, and Olesia Romanova. "Co-Mo-W Galvanochemical Alloy Application as Cathode Material in the Industrial Wastewater Treatment Processes." Materials Science Forum 1038 (July 13, 2021): 251–57. http://dx.doi.org/10.4028/www.scientific.net/msf.1038.251.

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The article deals with the role of electrodes materials in improving the industrial wastewater treatment from pollutants by electrochemical action. The instability constants of the complexes and coordinated ligand molecules were calculated. Based on the research conducted regarding the rationalisation of the poly-ligand electrolytes and electrolysis modes, a variative flow scheme of the coatings deposition by triple alloy has been developed. The corrosion resistance characteristics of the coatings obtained in the form of alloy, that were obtained from complex electrolyte that satisfy the neces

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2

Karushev, Mikhail, Evgenia Smirnova, and Irina Chepurnaya. "Nickel(II) Complex of N4 Schiff Base Ligand as a Building Block for a Conducting Metallopolymer with Multiple Redox States." Molecules 26, no. 9 (2021): 2646. http://dx.doi.org/10.3390/molecules26092646.

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Metal–ligand interactions in monomeric and polymeric transition metal complexes of Schiff base ligands largely define their functional properties and perspective applications. In this study, redox behavior of a nickel(II) N4-anilinosalen complex, [NiAmben] (where H2Amben = N,N′-bis(o-aminobenzylidene)ethylenediamine) was studied by cyclic voltammetry in solvents of different Lewis basicity. A poly-[NiAmben] film electrochemically synthesized from a 1,2-dichloroethane-based electrolyte was investigated by a combination of cyclic voltammetry, electrochemical quartz crystal microbalance, in situ

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3

Li, Sibo, Mengying Tian, Jirong Wang, Feipeng Du, Liang Li, and Zhigang Xue. "Poly (Ethylene Oxide)-Based Block Copolymer Electrolytes Formed via Ligand-Free Iron-Mediated Atom Transfer Radical Polymerization." Polymers 12, no. 4 (2020): 763. http://dx.doi.org/10.3390/polym12040763.

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The Br-terminated poly (ethylene oxide) (PEO-Br) is used as a green and efficient macroinitiator in bulk Fe-catalyzed atom transfer radical polymerization (ATRP) without the addition of any organic ligands. The polymerization rate is able to be mediated by PEO-Br with various molecular weights, and the decrease in redox potential of FeBr2 in cyclic voltammetry (CV) curves indicates that an increased coordination effect is deteriorated with the depressing reaction activity in the longer ethylene oxide (EO) chain in PEO-Br. In combination with the study of different catalysts and catalytic conte

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4

Nenastina, T., M. Sakhnenko, S. Oksak, et al. "Study of Complexation Patterns in the System Ni2+, MoO42–, P2O74–, Cit3–for the Development of Poly-Ligand Electrolytes (Study of complexation patterns)." Eurasian Chemico-Technological Journal 26, no. 3 (2024): 155–60. http://dx.doi.org/10.18321/ectj1638.

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The complexation behavior in systems containing Ni2+, MoO42−, P2O74−, Cit3− - ions have been thoroughly investigated. The study determined the composition and instability constants of both mono- and biligand complex compounds at a constant ionic strength of the solution (Ic=1). By analyzing the concentration ratios of the complexing agent and ligands, the composition of mono- and polyligand complexes was elucidated. The complexation study utilized the potentiometric method, which is based on the functional dependence of the potential of the indicator electrode on the concentration of the compl

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5

Gaddie, Ross S., Christopher B. Moss, and C. Michael Elliott. "Cyclic Voltammetric Study of Cobalt Poly-4-t-butylpyridine Ligand Complexes on Glassy Carbon Electrodes: Electrolyte Dependence and Mechanistic Considerations." Langmuir 29, no. 2 (2013): 825–31. http://dx.doi.org/10.1021/la304262a.

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6

Feng, Jun, Jin Li, Jian Feng, Zhong Wei, Ziqing Wang, and Xiaoling Song. "Synthesis of Aliphatic Polycarbonates from Diphenyl Carbonate and Diols over Zinc (II) Acetylacetonate." Molecules 27, no. 24 (2022): 8958. http://dx.doi.org/10.3390/molecules27248958.

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APCs (aliphatic polycarbonates) are one of the most important types of biodegradable polymers and widely used in the fields of solid electrolyte, biological medicine and biodegradable plastics. Zinc-based catalysts have the advantages of being low cost, being non-toxic, having high activity, and having excellent environmental and biological compatibility. Zinc (II) acetylacetonate (Zn(Acac)2) was first reported as a highly effective catalyst for the melt transesterification of biphenyl carbonate with 1,4-butanediol to synthesize poly(1,4-butylene carbonate)(PBC). It was found that the weight-a

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7

Watabe, Yusuke, Masahiro Fujita, Yuko Takeoka, and Masahiro Rikukawa. "Synthesis and Evaluation of Silica Particles Grafted with Electrolyte Unit (VI)-Improvement of Polymer Introduction Rate." ECS Meeting Abstracts MA2024-02, no. 43 (2024): 2893. https://doi.org/10.1149/ma2024-02432893mtgabs.

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Next-generation PEFC electrolyte membranes will require high proton conductivity and durability under high temperature and low relative humidity conditions. Core-shell organic-inorganic hybrid materials are expected to utilize the characteristics of organic and inorganic materials to overcome the problems of conventional PEM materials. In this study, silica particles (SiPs) were selected as the inorganic core to increase mechanical properties and thermal resistance, and the polymers having sulfo groups were selected as the organic shell to develop proton conductivity. Surface-grafted polymeriz

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8

Moges, Endalkachew Asefa Asefa, Meng-Che Tsai, Wei-Nien Su, and Bing Joe Hwang. "Homoleptic and Heteroleptic Coordination Environment of Palladium Molecular Catalysts for Oxygen Reduction to Hydrogen Peroxide." ECS Meeting Abstracts MA2024-02, no. 56 (2024): 3756. https://doi.org/10.1149/ma2024-02563756mtgabs.

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Hydrogen peroxide (H2O2) serves a wide range of purposes in industries such as chemical manufacturing, energy production, and wastewater treatment, either alone or in combination with other oxidizers. The demand for H2O2 has seen a notable increase due to its heightened use in disinfection amid the COVID-19 pandemic. Currently, industrial synthesis of H2O2 relies on anthraquinone technology, a complex process involving multiple steps including the use of H2 gas, transfer of H2O2 between solvents, distillation of concentrated H2O2, and potentially hazardous transportation. Thus, advancements in

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9

Wang, Wentao, Fadi Aldeek, Xin Ji, Birong Zeng, and Hedi Mattoussi. "A multifunctional amphiphilic polymer as a platform for surface-functionalizing metallic and other inorganic nanostructures." Faraday Discuss. 175 (2014): 137–51. http://dx.doi.org/10.1039/c4fd00154k.

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We designed a new set of polymer ligands that combine multiple metal-coordinating groups and short polyethylene glycol (PEG) moieties in the same structure. The ligand design relies on the controlled grafting of a large number of amine-terminated histamines and PEG short chains onto a poly(isobutylene-alt-maleic anhydride) backbone,viaa one-step nucleophilic addition reaction. This addition reaction is highly efficient, can be carried out in organic media and does not require additional reagents. We show that when imidazole groups are used the resulting polymer ligand can strongly ligate onto

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10

Okazawa, Atsushi, Takayuki Kakuchi, Keisuke Akahori, Kosuke Kawai, and Masashi Okubo. "Solubility-Enhanced Iron Complex Posolytes for Redox Flow Batteries." ECS Meeting Abstracts MA2024-02, no. 1 (2024): 16. https://doi.org/10.1149/ma2024-02116mtgabs.

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Redox flow batteries (RFBs) are promising stationary energy storage devices for renewables. Commercial RFBs possess potential disadvantages such as cost and resource constraint due to the use of vanadium. Therefore, organic compounds and metal coordination complexes have drawn much attention as redox active materials for RFB electrolytes. We focus on less expensive terpyridine iron complexes that have higher redox potential of approximately 1 V (vs. SHE) as an active material for both aqueous and non-aqueous RFB posolytes.[1] However, terpyridine iron complexes generally possess low solubility

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11

Wang, Caixing, Xuemei Wang, Huaizhu Wang, et al. "An Organometallic Chelated Electrolyte Based on 5‐Sulfosalicylic Group Coordination for Elevated Performance in Aqueous Zinc‐Ion Batteries." Advanced Functional Materials, April 30, 2025. https://doi.org/10.1002/adfm.202424024.

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AbstractIn aqueous ZnSO4 electrolyte, the highly reactive water ligands induce severe dendrite formation, hydrogen evolution reaction (HER), and zinc anode corrosion, significantly hampering the plating/stripping efficiency and cycling durability of aqueous zinc‐ion batteries (AZIBs). To address these challenges, a metal‐organic chelated electrolyte is developed utilizing 5‐sulfosalicylic acid (SA) group coordinated zinc salt (ZSA). Theoretical calculations reveal that the lowest unoccupied molecular orbital (LUMO) of ZSA is predominantly localized on the SA2− ligand rather than on H2O, result

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12

Qin, Tianfeng, Hao Chen, Wenzhang Fang, Guozhong Cao, and Chao Gao. "‘Poly(ions-water ligand) network’ electrolyte enables high-voltage high-conductivity aqueous metal-ions chemistries." Journal of Materials Chemistry A, 2022. http://dx.doi.org/10.1039/d2ta05705k.

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Aqueous electrolytes are essential for ensuring safe and environmentally friendly energy storage devices. Low-concentrated aqueous electrolytes exhibit narrow electrochemical stable windows (ESWs) of 1.23 V, but they have high ionic...

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13

Park, Hye Rin, Gun Jang, Jin Suk Byun, et al. "Hierarchically Structured Conductive Lanthanide Metal Organic Framework Nanorods for Ultrastable Flexible Magnesium Ion Capacitors." Advanced Functional Materials, October 28, 2024. http://dx.doi.org/10.1002/adfm.202417288.

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AbstractAqueous multivalent metal ion capacitors are very attractive owing to their high capacitance, low cost, environmental benignity, and safety. Herein, hierarchically structured, conductive lanthanide metal‐organic frameworks (MOFs) assembled by nanorods for ultrastable flexible magnesium ion capacitors (MICs) is designed. Three MOFs, consisting of lanthanide metals (La, Ho, and Yb) and 2,3,6,7,10,11‐hexahydroxytriphenylene (HHTP), are structurally stabilized through the covalent bonds and electronically conductive due to π‐d conjugation. Among 3 MOFs, Ho‐HHTP electrodes in a full‐cell sy

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14

Zhu, Qiannan, Ke Yang, Likun Chen, et al. "Activating Interfacial Ion Exchange in Composite Electrolyte to Realize High‐Rate and Long‐Cycling Solid‐State Lithium Batteries." Angewandte Chemie International Edition, March 28, 2025. https://doi.org/10.1002/anie.202425221.

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Composite solid electrolytes (CSEs) are promising candidates for solid‐state lithium metal batteries. However, the poor cross‐phase Li+ transport restricts the rate performance and cycle life of the batteries. Herein, we revealed the Li+ percolation behavior in poly(vinylidene fluoride) (PVDF)‐based CSEs with Li6.4La3Zr1.4Ta0.6O12 filler. The de‐coordination barrier from Li+ clusters determines interfacial Li+ transport capability. We then employed a designed N‐methyl‐2,2,2‐trifluoroacetamide (NMTFA) ligand to lower the de‐coordination energy and activate interfacial Li+ exchange, The ionic co

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15

Zhu, Qiannan, Ke Yang, Likun Chen, et al. "Activating Interfacial Ion Exchange in Composite Electrolyte to Realize High‐Rate and Long‐Cycling Solid‐State Lithium Batteries." Angewandte Chemie, March 28, 2025. https://doi.org/10.1002/ange.202425221.

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Composite solid electrolytes (CSEs) are promising candidates for solid‐state lithium metal batteries. However, the poor cross‐phase Li+ transport restricts the rate performance and cycle life of the batteries. Herein, we revealed the Li+ percolation behavior in poly(vinylidene fluoride) (PVDF)‐based CSEs with Li6.4La3Zr1.4Ta0.6O12 filler. The de‐coordination barrier from Li+ clusters determines interfacial Li+ transport capability. We then employed a designed N‐methyl‐2,2,2‐trifluoroacetamide (NMTFA) ligand to lower the de‐coordination energy and activate interfacial Li+ exchange, The ionic co

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16

Lin, Ruifan, Yingmin Jin, Yumeng Li, et al. "Decoupling Interfacial Stability and Ion Transport in Solid Polymer Electrolyte by Tailored Ligand Chemistry for Lithium Metal Battery." Advanced Functional Materials, December 29, 2024. https://doi.org/10.1002/adfm.202421880.

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AbstractAchieving fast ion transport kinetics and high interfacial stability simultaneously is challenging for polymer electrolytes in solid‐state lithium batteries, as the coordination environment optimal for Li+ conduction struggles to generate desirable interphase chemistry. Herein, the adjustable property of organic ligands is exploited in metal–organic frameworks (MOFs) to develop a hierarchical composite electrolyte, incorporating heterogeneous and spatially confined MOF nanofillers into a poly‐1,3‐dioxolane matrix. The defect‐engineered University of Oslo‐66 MOFs (UiO‐66d) with tailored

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17

Sikes, Jazlynn C., Isabelle Nyonshuti, Kannasoot Kanokkanchana, Jingyi Chen, Kristina Tschulik, and Ingrid Fritsch. "Single Particle Electrochemical Oxidation of Polyvinylpyrrolidone-Capped Silver Nanospheres, Nanocubes, and Nanoplates in Potassium Nitrate and Potassium Hydroxide." Journal of The Electrochemical Society, April 4, 2022. http://dx.doi.org/10.1149/1945-7111/ac63f3.

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Abstract Single particle electrochemical oxidation of poly(vinylpyrrolidone)-capped silver nanoparticles at a microdisk electrode was investigated as a function of particle shape (spheres, cubes, and plates) in potassium nitrate and potassium hydroxide solutions. In potassium nitrate, extreme anodic potentials (≥1500 mV vs. Ag/AgCl (3 M KCl)) were necessary to achieve oxidation, while lower anodic potentials were required in potassium hydroxide (≥900 mV vs. Ag/AgCl (saturated KCl)). Upon oxidation, silver oxide is formed, readily catalyzing water oxidation, producing a spike-step current respo

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18

sprotocols. "Stereo-separations of Peptides by Capillary Electrophoresis and Chromatography." December 31, 2014. https://doi.org/10.5281/zenodo.13666.

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Authors: Afzal Hussain, Iqbal Hussain, Mohamed F. Al-Ajmi & Imran Ali ### Abstract Small peptides (di-, tri-, tetra- penta- hexa etc. and peptides) control many chemical and biological processes. The biological importance of stereomers of peptides is of great value. The stereo-separations of peptides are gaining importance in biological and medicinal sciences and pharmaceutical industries. There is a great need of experimental protocols of stereo-separations of peptides. The various chiral selector used were polysaccharides, cyclodextrins, Pirkle’s types, macrocyclic antibiotics, crown eth

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