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Journal articles on the topic 'Polychalcogenides'

Author: Grafiati

Published: 4 June 2021

Last updated: 19 February 2022

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1

Dorhout, Peter K., Nichole B. Ford, and Casey C. Raymond. "Understanding the polychalcogenides as building blocks to solid state materials: Speciation of polychalcogenides in solutions." Coordination Chemistry Reviews 352 (December 2017): 537–50. http://dx.doi.org/10.1016/j.ccr.2017.10.017.

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2

Torubaev, Yury V., Ivan V. Skabitsky, and Abhinav Raghuvanshi. "The structural landscape of ferrocenyl polychalcogenides." Journal of Organometallic Chemistry 951 (October 2021): 122006. http://dx.doi.org/10.1016/j.jorganchem.2021.122006.

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3

Doert, Thomas, Carola J. Müller, Ulrich Schwarz, and Peer Schmidt. "High-pressure synthesis of rare earth metal polychalcogenides." Acta Crystallographica Section A Foundations of Crystallography 66, a1 (August 29, 2010): s47. http://dx.doi.org/10.1107/s0108767310098946.

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4

Mayasree, Oottil, Cheriyedath Raj Sankar, Katja M. Kleinke, and Holger Kleinke. "Cu clusters and chalcogenchalcogen bonds in various copper polychalcogenides." Coordination Chemistry Reviews 256, no. 13-14 (July 2012): 1377–83. http://dx.doi.org/10.1016/j.ccr.2012.03.016.

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5

Kysliak, Oleksandr, and Johannes Beck. "1D coordination polymers with polychalcogenides as linkers between metal atoms." Journal of Solid State Chemistry 203 (July 2013): 120–27. http://dx.doi.org/10.1016/j.jssc.2013.04.017.

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6

Tougait, O., and J. A. Ibers. "New tantalum polychalcogenides with infinite anionic chains: K12Ta6Se35 and KTaTe3." Solid State Sciences 1, no. 7-8 (October 1999): 523–34. http://dx.doi.org/10.1016/s1293-2558(00)80104-1.

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7

Liebing, Phil, Marcel Kühling, Claudia Swanson, Martin Feneberg, Liane Hilfert, Rüdiger Goldhahn, Tristram Chivers, and Frank T. Edelmann. "Catenated and spirocyclic polychalcogenides from potassium carbonate and elemental chalcogens." Chemical Communications 55, no. 99 (2019): 14965–67. http://dx.doi.org/10.1039/c9cc08347b.

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Reaction of potassium carbonate with elemental sulfur or selenium in acetone in the presence of [PPN]Cl (PPN = (Ph₃P)₂N) produces catena-[S₁₂]²⁻, the longest structurally characterised polysulfide dianion, or spiro-[Se₁₁]²⁻ as ion-separated [PPN]⁺ salts.

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8

Kanatzidis, Mercouri G. "Soluble Polychalcogenides of the Late Transition and Main Group Elements." Comments on Inorganic Chemistry 10, no. 4-5 (June 1990): 161–95. http://dx.doi.org/10.1080/02603599008048650.

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9

Bensch, Wolfgang, Christian Näther, and Peter Dürichen. "From Molecular to One-Dimensional Polychalcogenides: Preparation, Structure, and Reactivity of NaNbS6, the First Ternary Alkali Metal Niobium Polychalcogenide Exhibiting Infinite Anionic Chains." Angewandte Chemie International Edition 37, no. 1-2 (February 2, 1998): 133–35. http://dx.doi.org/10.1002/(sici)1521-3773(19980202)37:1/2<133::aid-anie133>3.0.co;2-c.

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10

Chen, John H., and Peter K. Dorhout. "Synthesis of Rare-Earth Polychalcogenides by Moderate Temperature Solid-State Metathesis." Journal of Solid State Chemistry 117, no. 2 (July 1995): 318–22. http://dx.doi.org/10.1006/jssc.1995.1279.

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11

BENSCH, W., C. NAETHER, and P. DUERICHEN. "ChemInform Abstract: From Molecular to One-Dimensional Polychalcogenides: Preparation, Structure, and Reactivity of NaNbS6, the First Ternary Alkali Metal Niobium Polychalcogenide Exhibiting Infinite Anionic Chains." ChemInform 29, no. 25 (June 22, 2010): no. http://dx.doi.org/10.1002/chin.199825001.

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12

Huang, Fu Qiang, and James A. Ibers. "Polar Titanium Polychalcogenides: Syntheses and Characterization of Cs6Ti6S27, Cs4BaTi6Se27, Rb5AgTi6Se27, and Cs5AgTi6Se27." Inorganic Chemistry 40, no. 5 (February 2001): 865–69. http://dx.doi.org/10.1021/ic000843r.

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13

Kysliak, Oleksandr, and Johannes Beck. "ChemInform Abstract: 1D Coordination Polymers with Polychalcogenides as Linkers Between Metal Atoms." ChemInform 44, no. 33 (July 25, 2013): no. http://dx.doi.org/10.1002/chin.201333016.

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14

Tougait, O., and J. A. Ibers. "ChemInform Abstract: New Tantalum Polychalcogenides with Infinite Anionic Chains: K12Ta6Se35 and KTaTe3." ChemInform 31, no. 9 (June 10, 2010): no. http://dx.doi.org/10.1002/chin.200009007.

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15

Kim, Kang-Woo, and Mercouri G. Kanatzidis. "Synthesis, structure and properties of the polychalcogenides [M4Te12]4− (M=Cd, Hg)." Inorganica Chimica Acta 224, no. 1-2 (October 1994): 163–69. http://dx.doi.org/10.1016/0020-1693(94)01014-5.

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16

Liao, Ju Hsiou, and Mercouri G. Kanatzidis. "Hydrothermal synthesis of metal polychalcogenides. Structural characterization of [Mo12Se56]12-. A cluster of clusters." Journal of the American Chemical Society 112, no. 20 (September 1990): 7400–7402. http://dx.doi.org/10.1021/ja00176a053.

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17

KIM, K. W., and M. G. KANATZIDIS. "ChemInform Abstract: Synthesis, Structure and Properties of the Polychalcogenides (M4Te12)4- (M: Cd, Hg)." ChemInform 25, no. 52 (August 18, 2010): no. http://dx.doi.org/10.1002/chin.199452031.

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18

Jafarzadeh, Parisa, Maegan R. Rodrigues, Yixuan Shi, Abdeljalil Assoud, Tianze Zou, Jan B. Kycia, and Holger Kleinke. "Effect of mixed occupancies on the thermoelectric properties of BaCu6−xSe1−yTe6+y polychalcogenides." Dalton Transactions 48, no. 25 (2019): 9357–64. http://dx.doi.org/10.1039/c9dt01616c.

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19

Kysliak, Oleksandr, and Johannes Beck. "Zn, Mn, and Fe hexammine and hexakis(methylamine) polychalcogenides – Ionic compounds by solvothermal syntheses." Inorganic Chemistry Communications 38 (December 2013): 146–51. http://dx.doi.org/10.1016/j.inoche.2013.10.015.

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20

Huang, Fu Qiang, and James A. Ibers. "ChemInform Abstract: Polar Titanium Polychalcogenides: Syntheses and Characterization of Cs6Ti6S27, Cs4BaTi6Se27, Rb5AgTi6Se27, and Cs5AgTi6Se27." ChemInform 32, no. 23 (May 26, 2010): no. http://dx.doi.org/10.1002/chin.200123011.

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21

Kanatzidis, Mercouri G. "Molten alkali-metal polychalcogenides as reagents and solvents for the synthesis of new chalcogenide materials." Chemistry of Materials 2, no. 4 (July 1990): 353–63. http://dx.doi.org/10.1021/cm00010a009.

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22

RAYMOND, C. C., and P. K. DORHOUT. "ChemInform Abstract: 175 Years of Polychalcogenides: Speciation in Aqueous Solutions - The Myths and the Magic." ChemInform 29, no. 10 (June 23, 2010): no. http://dx.doi.org/10.1002/chin.199810319.

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23

LIAO, J. H., and M. G. KANATZIDIS. "ChemInform Abstract: Hydrothermal Synthesis of Metal Polychalcogenides. Structural Characterization of (Mo12Se56)12-. A Cluster of Clusters." ChemInform 22, no. 1 (August 23, 2010): no. http://dx.doi.org/10.1002/chin.199101036.

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24

Kysliak, Oleksandr, and Johannes Beck. "ChemInform Abstract: Zn, Mn, and Fe Hexammine and Hexakis(methylamine) Polychalcogenides - Ionic Compounds by Solvothermal Syntheses." ChemInform 45, no. 7 (January 31, 2014): no. http://dx.doi.org/10.1002/chin.201407008.

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25

Podberezskaya, N. V., S. A. Magarill, N. V. Pervukhina, I. G. Vasilieva, and S. V. Borisov. "Crystal-chemical aspects of the structural similarity of rare earth polychalcogenides LnX2−x (x=0–0.25)." Journal of Structural Chemistry 37, no. 6 (November 1996): 963–85. http://dx.doi.org/10.1007/bf02439082.

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26

Mayasree, Oottil, Cheriyedath Raj Sankar, Yanjie Cui, Abdeljalil Assoud, and Holger Kleinke. "Synthesis, Structure, and Thermoelectric Properties of Barium Copper Polychalcogenides with Chalcogen-Centered Cu Clusters and Te22- Dumbbells." European Journal of Inorganic Chemistry 2011, no. 26 (May 26, 2011): 4037–42. http://dx.doi.org/10.1002/ejic.201100284.

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27

Bensch, W., P. Dürichen, and C. Näther. "The M2Q11 unit (M = Nb, Ta; Q = S, Se): A versatile building block to generate group 5 polychalcogenides." Solid State Sciences 1, no. 2-3 (March 1999): 85–108. http://dx.doi.org/10.1016/s1293-2558(00)80067-9.

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28

Nakata, Norio, Nobuhiro Takeda, and Norihiro Tokitoh. "Reactions of 2-Germanaphthalene with Elemental Sulfur and Selenium: Synthesis of Novel Cyclic Polychalcogenides Containing a Germanium, Trichalcogenagermolanes." Chemistry Letters 31, no. 8 (August 2002): 818–19. http://dx.doi.org/10.1246/cl.2002.818.

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29

Gales, Samantha L., William T. Pennington, and Joseph W. Kolis. "Oxidation of organometallic compounds with polychalcogenides: preparation and structure of [(Me5C5)Mo(S4)(S2CO)]− containing a dithiocarbonate ligand." Journal of Organometallic Chemistry 419, no. 1-2 (November 1991): C10—C13. http://dx.doi.org/10.1016/0022-328x(91)86185-s.

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30

Mayasree, Oottil, Cheriyedath Raj Sankar, Yanjie Cui, Abdeljalil Assoud, and Holger Kleinke. "ChemInform Abstract: Synthesis, Structure, and Thermoelectric Properties of Barium Copper Polychalcogenides with Chalcogen-Centered Cu Clusters and Te2-2 Dumbbells." ChemInform 42, no. 49 (November 10, 2011): no. http://dx.doi.org/10.1002/chin.201149008.

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31

Bensch, W., P. Duerichen, and C. Naether. "ChemInform Abstract: The M2Q11 Unit (M: Nb, Ta; Q: S, Se): A Versatile Building Block to Generate Group 5 Polychalcogenides." ChemInform 30, no. 35 (June 13, 2010): no. http://dx.doi.org/10.1002/chin.199935288.

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32

Fokwa Tsinde, Boniface Polequin, and Thomas Doert. "The ternary rare-earth polychalcogenides LaSeTe2, CeSeTe2, PrSeTe2, NdSeTe2, and SmSeTe2: Syntheses, crystal structures, electronic properties, and charge-density-wave-transitions." Solid State Sciences 7, no. 5 (May 2005): 573–87. http://dx.doi.org/10.1016/j.solidstatesciences.2005.02.006.

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33

Sunshine, Steven A., Doris Kang, and James A. Ibers. "A new low-temperature route to metal polychalcogenides: solid-state synthesis of potassium titanium sulfide (K4Ti3S14), a novel one-dimensional compound." Journal of the American Chemical Society 109, no. 20 (September 1987): 6202–4. http://dx.doi.org/10.1021/ja00254a060.

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34

Wendland, Frank, Christian Näther, and Wolfgang Bensch. "Syntheses and Crystal Structures of the Two New Polychalcogenides [Mn(C6H14N2)3]Se6 and [Mn(C6H14N2)3]2[C6H16N2](TeSe2)2Se." Zeitschrift für Naturforschung B 59, no. 6 (June 1, 2004): 629–34. http://dx.doi.org/10.1515/znb-2004-0602.

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The solvothermal reaction of MnCl2·4 H2O, K2Se3 and Se in trans-cyclohexane-1,2-diamine (chxn) at 433 K yields dark blue crystals of [Mn(chxn)3]Se6 (1), and the reaction of MnCl2 ・4 H2O, K2Se3 and Te under similar conditions gives dark blue crystals of [Mn(chxn)3]2[H2chxn](TeSe2)2Se (2). While compound (1) crystallises in the orthorhombic space group Pbcn with the lattice parameters a = 13.7017(9), b = 19.9073(8) and c = 10.8058(5)Å , compound (2) crystallises in the monoclinic space group P21 with the lattice parameters a = 9.4396(6), b = 24.2450(2), c = 12.8170(8) Å and β =91.6(1)◦. In both structures discrete complex cations and polychalcogenide anions are found. In (1) the Se62− anions form a pseudo-layer arrangement with nearly rectangular pores. The complex cations are encapsulated by the arrangement of the Se62− anions. Some short distances between the amino groups of the ligands and the anions indicate weak hydrogen bonding. In compound (2) two independent [Mn(chxn)3]2+ and one unique H2chxn dications, two unique TeSe22− as well as one Se2− dianion coexist. The two complex cations exhibit different conformations. One of the two TeSe22− anions has the di-protonated chxn molecule in the neighbourhood and short Se···H separations indicate weak hydrogen bonding. The isolated Se2− ion is located above the ring of the di-protonated trans-cyclohexane-1,2-diamine molecule and again a short Se···H separation may be due to a weak hydrogen bond. Compound (1) decomposes in a single step when heated in an Ar atmosphere. In contrast, the thermal decomposition of compound (2) is complex and at least five different steps can be identified.

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35

Nakata, Norio, Nobuhiro Takeda, and Norihiro Tokitoh. "ChemInform Abstract: Reactions of 2-Germanaphthalene with Elemental Sulfur and Selenium: Synthesis of Novel Cyclic Polychalcogenides Containing a Germanium, Trichalcogenagermolanes (I)." ChemInform 33, no. 50 (May 18, 2010): no. http://dx.doi.org/10.1002/chin.200250145.

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36

Tatsumi, Kazuyuki, Hiroyuki Kawaguchi, Koji Inoue, Kazuhide Tani, and Roger E. Cramer. "Lithium cations tightly bound to polychalcogenides: synthesis and solid-state structures of Li2S6(teeda)2, Li2S4(pmdeta)2, and Li2Se5(pmdeta)2." Inorganic Chemistry 32, no. 20 (September 1993): 4317–23. http://dx.doi.org/10.1021/ic00072a027.

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37

Feldmann, Claus, and Alexander Okrut. "Two Tricyclic Polychalcogenides in [Li(12-crown-4)2]2[Sb2Se12] and [Li(12-crown-4)2]4[Te12]·(12-crown-4)2." Zeitschrift für anorganische und allgemeine Chemie 635, no. 12 (October 2009): 1807–11. http://dx.doi.org/10.1002/zaac.200900178.

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38

Smiles, Danil E., Guang Wu, and Trevor W. Hayton. "Synthesis of Terminal Monochalcogenide and Dichalcogenide Complexes of Uranium Using Polychalcogenides, [En]2–(E = Te,n= 2; E = Se,n= 4), as Chalcogen Atom Transfer Reagents." Inorganic Chemistry 53, no. 19 (September 9, 2014): 10240–47. http://dx.doi.org/10.1021/ic501267f.

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39

Feldmann, Claus, and Alexander Okrut. "ChemInform Abstract: Two Tricyclic Polychalcogenides in [Li(12-crown-4)2]2[Sb2Se12] and [Li(12-crown-4)2]4 [Te12]Â·(12-crown-4)2." ChemInform 40, no. 51 (December 22, 2009): no. http://dx.doi.org/10.1002/chin.200951019.

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40

Wendland, Frank, Christian Näther, and Wolfgang Bensch. "Synthesis, Crystal Structures and Properties of the Polychalcogenides Manganese-tris(1,2-ethanediamine)-triselenide [Mn(en)3]Se3 and Manganese-tris(1,2-ethanediamine)-monotellurodiselenide [Mn(en)3 ]TeSe2." Zeitschrift für Naturforschung B 55, no. 9 (September 1, 2000): 871–76. http://dx.doi.org/10.1515/znb-2000-0911.

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The reaction of manganese(II)-chloride-tetrahydrate, caesium triselenide and elemental selenium or tellurium in 1,2-ethanediamine (en) under solvothermal conditions leads to the formation of two new isostructural compounds [Mn(en)3]Se3 (1) and [Mn(en)3]TeSe2 (2). The compounds crystallize in the orthorhombic space group Pbcn with the lattice parameters a = 1149.39(9), b = 1506.83(11), c = 935.96(6) pm for 1 and a = 1184.1(2), b = 1495.3(2), c = 949.8(1) pm for 2. Their crystal structures are built up of [Mn(en)3]2+ cations and Se32- or TeSe22- anions, respectively. Each cation is surrounded by six next neighbouring anions, and vice versa. Between the cations and the anions hydrogen bonding is observed. The thermal behaviour was investigated using differential thermal analysis, thermogravimetry as well as X-ray powder diffraction. Completely different properties were found. Compound 1 decomposes in two distinct endothermic steps, while compound 2 shows only one endothermic peak. The weight loss for 1 corresponds roughly to the emission of all en molecules, whereas the weight loss for 2 is significantly lower. The final products are composed of MnSe2 and elemental Se or Te, respectively, and an unknown crystalline phase which is different for the two samples

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41

Teske, Christoph L., and Wolfgang Bensch. "ChemInform Abstract: Polychalcogenides of Thallium with M2Q11 Groups as a Structural Building Block. Part 1. Preparation, Properties, X-Ray Diffractometry, and Spectroscopic Investigations of Tl4Nb2S11 and Tl4Ta2S11." ChemInform 32, no. 20 (May 15, 2001): no. http://dx.doi.org/10.1002/chin.200120021.

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42

Dürichen, Peter, and Wolfgang Bensch. "Reactions in Molten Alkalimetal Polychalcogenides: What Happens in the Melt? A Study of the Reactions in the System K-Nb-S Using Differential Scanning Calorimetry, Infrared Spectroscopy, and X-Ray Powder Diffraction." Zeitschrift für Naturforschung B 57, no. 12 (December 1, 2002): 1382–86. http://dx.doi.org/10.1515/znb-2002-1207.

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The reactions of potassium polysulfides with elemental Nb were investigated with different analytical techniques. The amount of the polysulfide applied has no influence onto product formation, i. e. the ratio K2Sx: Nb is not important. The length of the polsysulfide chain, i. e. the value of x in K2Sx determines what product is formed. In sulfur-poor melts, K3NbS4 is observed. Increasing x to 5 - 6, K4Nb2S11 is formed with a structure containing S22− anions. Finally, applying a melt with x > 6, K6Nb4S25 is found as the product with a crystal structure containing the S52− polysulfide anion. When K2Sx (x < 5) is heated with sulfur in the first step the pentasulfide K2S5 is formed. Immediately after melting of K2S5 a reaction with elemental Nb occurs. The results of FT-IR and X-ray investigations have demonstrated that after oxidation the anion [Nb2S11]4− is formed relatively fast, and after a short time crystalline K4Nb2S11 can be detected. After 24 h the reaction is complete.

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43

Kanatzidis, Mercouri G., and Song-Ping Huang. "Coordination chemistry of heavy polychalcogenide ligands." Coordination Chemistry Reviews 130, no. 1-2 (February 1994): 509–621. http://dx.doi.org/10.1016/0010-8545(94)80012-x.

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44

Holz, Birger, Reiner Lultkus, and Ralf Steudel. "New Titanacycles with Chelating Polychalcogenide Ligands1." Phosphorus, Sulfur, and Silicon and the Related Elements 65, no. 1-4 (February 1992): 157–60. http://dx.doi.org/10.1080/10426509208055342.

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45

Teske, Christoph L., Nicolai Lehnert, and Wolfgang Bensch. "On Polychalcogenides of Thallium with M2 Q11 Groups as a Structural Building Block. II. Tl4Ta2Se11: Synthesis, Crystal Structure, Properties and Spectroscopic Investigations of the First Polyselenide being Composed of a Discrete [Ta2Se11]4— Anion." Zeitschrift für anorganische und allgemeine Chemie 628, no. 12 (December 2002): 2651–55. http://dx.doi.org/10.1002/1521-3749(200212)628:12<2651::aid-zaac2651>3.0.co;2-w.

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46

Cowen, J. A., P. Michlin, J. Kraus, S. D. Mahanti, J. A. Aitken, and M. G. Kanatzidis. "EuSe2: A novel antiferromagnetic rare-earth polychalcogenide." Journal of Applied Physics 85, no. 8 (April 15, 1999): 5381–83. http://dx.doi.org/10.1063/1.369984.

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47

Kanatzidis, Mercouri G., and Song-Ping Huang. "Gold Inorganic Rings Based on Polychalcogenide Chains." Phosphorus, Sulfur, and Silicon and the Related Elements 64, no. 1-4 (January 1992): 153–60. http://dx.doi.org/10.1080/10426509208041141.

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48

Sheldrick, William S. "Polychalcogenide Anions: Structural Diversity and Ligand Versatility." Zeitschrift für anorganische und allgemeine Chemie 638, no. 15 (August 24, 2012): 2401–24. http://dx.doi.org/10.1002/zaac.201200241.

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49

Sutorik, Anthony C., and Mercouri G. Kanatzidis. "KCeSe4: A New Solid-State Lanthanide Polychalcogenide." Angewandte Chemie International Edition in English 31, no. 12 (December 1992): 1594–96. http://dx.doi.org/10.1002/anie.199215941.

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50

Choi, Nami, and Wataru Ando. "ChemInform Abstract: Cyclic Polychalcogenide Compounds with Silicon." ChemInform 30, no. 15 (June 16, 2010): no. http://dx.doi.org/10.1002/chin.199915329.

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