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Dissertations / Theses on the topic 'Polyenen'

Author: Grafiati
Published: 4 June 2021
Last updated: 28 July 2025

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1

Ebenezer, Warren James. "Synthesis with polyenes and polyene epoxides." Thesis, University of Nottingham, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.315064.

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2

Madden, Katrina Sophie. "Synthesis of polyene natural products." Thesis, Durham University, 2017. http://etheses.dur.ac.uk/12052/.

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A convergent approach was applied to the synthesis of a range of Xanthomonas pigments and a number of selected analogues, with a view to understanding more about their photoprotective properties, and utilising the group’s iterative Heck-Mizoroki/ iododeboronation cross-coupling methodology to access polyenyl intermediates. This involved the synthesis of a number of key arenyl building blocks. Three polyenyl building blocks were accessed via sequential Heck-Mizoroki and iododeboronation reactions, providing flexibility in the construction of the pigments and their analogues. Following some opti
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3

Charoenying, Patchanee. "Pyrylium-based routes to conjugated polyenes." Thesis, University of York, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.337655.

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4

Butler, A. R. "Genetic studies on polyene producing streptomycete." Thesis, University of Nottingham, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383795.

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5

Soleymanzadeh, Fariba. "Tandem synthesis of polysubstituted olefins an approach toward the first total synthesis of astaxanthin [beta]-D-diglucoside /." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0018/MQ59205.pdf.

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6

Wachsmann-Hogiu, Sebastian. "Vibronic coupling and ultrafast electron transfer studied by picosecond time resolved resonance Raman and CARS spectroscopy." Doctoral thesis, [S.l. : s.n.], 2000. http://deposit.ddb.de/cgi-bin/dokserv?idn=960830898.

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7

Twiddle, Steven John Robert. "The stereoselective synthesis of polyene natural products." Thesis, Durham University, 2005. http://etheses.dur.ac.uk/2771/.

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A strategy for the stereocontrolled synthesis of polyene units was developed which centred around the chemistry of the vinyl boronate ester 4,4,6-trimethyl-2-vinyl-l,3,2- dioxaborinane 123. Reaction conditions have been developed to allow the Heck coupling of 123 with a range of aryl and alkenyl electrophiles. The reaction is promoted by cationic palladium species which can be generated through the addition of metal salts to the reaction mixture. Conversely conditions have also been developed which allows 123 to react exclusively at the boron functionality along the Suzuki-Miyaura pathway, the
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8

Simonian, Houri. "Acyl radical mediated polyene cyclisations in synthesis." Thesis, University of Nottingham, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.307815.

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9

Terapane, Michael John. "The study of electron transfer in unique organic systems." Diss., Georgia Institute of Technology, 2000. http://hdl.handle.net/1853/28002.

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10

Walczak, Matthew C. "Total Synthesis Of Polyene Natural Products Lucilactaene And Gymnoconjugatin: Development Of A Boron-Tin Linchpin." Columbus, Ohio : Ohio State University, 2008. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1206036742.

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11

Wilkes, A. G. "Energy transfer studies on polyene and aromatic systems." Thesis, University of Nottingham, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376478.

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12

CROUSSE, BENOIT. "Nouvelle approche stereoselective aux polyenes conjugues et composes polyinsatures." Paris 6, 1995. http://www.theses.fr/1995PA066297.

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Nous avons tout d'abord etudie, en presence de pdcl#2(phcn)#2, la tres bonne reactivite des chloroenynes et chlorodienes fonctionnalises avec des alcynes terminaux, pour conduire stereospecifiquement, avec de tres bons rendements, a des enediynes et a des dienynes en un temps court (30 min a 1 h). Nous avons aussi decrit la substitution sequentielle stereospecifique en un pot des dichloroethylenes e et z pour conduire aux enediynes dissymetriques fonctionnalises e et z qui sont d'utiles intermediaires de synthese. Nous avons ensuite montre a travers quelques exemples appropries, que ces reacti
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13

Reid, Richard D. "Feynman-Dyson perturbation theory applied to model linear polyenes." Diss., Virginia Polytechnic Institute and State University, 1986. http://hdl.handle.net/10919/76488.

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In the work described in this thesis, the Feynman-Dyson perturbation theory, developed from quantum field theory, was employed in semiempirical calculations on trans - polyacetylene. A variety of soliton-like excited states of the molecule were studied by the PPP-UHF-RPA method. The results of this study provide useful information on the nature of these states, which are thought to account for the unique electrical conduction properties of trans - polyacetylene and similar conducting polymers. Feynman-Dyson perturbation theory was also used to extend Hartree-Fock theory by the inclusion of
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14

Hennes, Matthias. "Über Homotopietypen von vierdimensionalen Polyedern /." Bonn : [s.n.], 1991. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=005065761&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.

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15

Sun, Daqing. "A new polyene cyclization process and its synthetic applications." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp02/NQ34844.pdf.

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16

Eade, Serena J. "Biomimetic synthesis of natural products from polyene-pyrone precursors." Thesis, University of Oxford, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.441306.

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17

Boyce, Richard J. "Synthetic studies with naturally occurring methylthiazolines and polyene macrolides." Thesis, University of Nottingham, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.307842.

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18

Lewis, Ian. "Studies in the synthesis of polyene tetramic acid antibiotics." Thesis, University of Edinburgh, 1988. http://hdl.handle.net/1842/12412.

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19

Kiliçkiran, Pinar. "Synthesis of polarized polyenes and polyenynes structure and reactivity studies /." [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=963172379.

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20

Kılıçkıran, Pınar. "Synthesis of polarized polyenes and polyenynes structure and reactivity studies /." [S.l. : s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=963172379.

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21

Rijkenberg, Rolf Arjan. "Spectroscopy and photophysics of excited states of olefins and polyenes." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2002. http://dare.uva.nl/document/65557.

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22

劉新權 and Sing-quan Lew. "Kinetic and mechanistic study of reactions of hydroxy, methoxy, methylthio, methylseleno and amino derivatives of some heterocyclicand homocyclic polyenes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1991. http://hub.hku.hk/bib/B31232322.

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23

Chen, Ligong. "Polyene cyclisations initiated by acyl radicals leading to polycycle constructions." Thesis, University of Nottingham, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.240260.

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24

Geue, Ferdinand. "Eckenabsuchende Verfahren unter Entartung : Theorie, Algorithmen und Vergleichstests /." Hamburg : Kovač, 1994. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=006291756&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.

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25

Thiebaut, Benedicte. "Co-ordinatively unsaturated complexes of tungsten (II)." Thesis, Heriot-Watt University, 1998. http://hdl.handle.net/10399/606.

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26

Thirsk, Carl Edward. "Stereoselective routes to the total synthesis of the polyene macrolide viridenomycin." Thesis, Durham University, 2003. http://etheses.dur.ac.uk/3153/.

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Viridenomycin 11 is a polyene macrolide possessing a wealth of biological activity. As part of an ongoing program examining the stereoselective synthesis of polyene natural products, a strategy was explored to effect the total synthesis of viridenomycin 11.As a consequence of the adopted retrosynthetic strategy, the project was naturally divided into three main areas: efforts directed towards the southern (E, E, E, Z)-tetraene 210, towards the northern (E, Z, Z)-triene 209, and towards the core cyclopentenone 211.Both polyenic sections 209 and 210 were tackled with a view to utilizing palladiu
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27

Martin, Catherine. "Preparation d'olefines et de polyenes hydroxyles et amines enantiomeriquement enrichis. Applications synthetiques." Paris 11, 1998. http://www.theses.fr/1998PA112353.

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Ce memoire presente la synthese de composes olefiniques ou polyeniques hydroxyles et amines, intermediaires cle dans la synthese de nombreux composes naturels. Une premiere partie sur l'addition des organometalliques sur un lactol tricyclique avec determination du nombre necessaire d'equivalents de reactif organometallique, des differentes selectivites en fonction des organometalliques utilises ainsi que des effets de solvants, a permis de proposer de nouveaux modeles refletant bien les faits experimentaux. La deuxieme partie s'interesse aux rearrangements d'overman d'acetates et d'imidates al
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28

Rodger, Robert. "Fused ring systems in natural product synthesis." Thesis, The University of Sydney, 2022. https://hdl.handle.net/2123/27645.

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On the instigation of A/Prof C. S. P. McErlean I investigated the rapid synthesis of fused ring compounds by a key polyene cyclisation. Chapter 1 sets the scene by highlighting deficiencies in literature syntheses of selected fused-ring compounds, where synthetic strategies are often suboptimal. In particular, the scarcity of reported syntheses involving a direct cyclisation method is noted. Chapter 2 discusses the taiwaniaquinoids and previous synthetic approaches including McErlean group efforts which delivered the non-natural stereochemistry. A method to produce the desired trans stereo
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29

Hunziker, Christoph. "Crystalline thiophene and phenolic polyene derivatives for organic electronic and photonic applications /." Zürich : ETH, 2008. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=18032.

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30

ADAMY, MARC. "Alcool chiraux et polyenes tout trans. Application a la synthese de l'isobretonine a." Université Louis Pasteur (Strasbourg) (1971-2008), 1996. http://www.theses.fr/1996STR13129.

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Nous avons effectue la premiere synthese enantio et stereoselective de l'isobretonine a, produit naturel isole d'une eponge recoltee en mer du nord. Il s'agit d'un ether glycerique dont la chiralite est due uniquement a la presence de deux substituants differents sur les atomes d'oxygene des alcools primaires : un ester p-hydroxybenzoique et un ether trienique de configuration (e,e,e). Cette synthese illustre bien l'obtention d'alcools chiraux optiquement purs par l'intermediaire des sulfoxydes et la synthese de polyenes de configuration trans a partir de dibenzoates allyliques. Nous avons ega
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31

KALAI, CHAKIB. "Nouvelles methodes de synthese de polyenes tout-trans. Application a des molecules naturelles." Université Louis Pasteur (Strasbourg) (1971-2008), 1999. http://www.theses.fr/1999STR13042.

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Dans un premier temps, nous avons montre l'efficacite de la reaction d'elimination reductrice a l'amalgame de sodium de motifs 1,8-dibenzoates-2,4,6-trienes, en l'appliquant a la synthese d'un produit naturel : l'ester methylique de l'acide -parinarique. Cette methodologie qui a prouve son efficacite dans la formation stereoselective de fragments trieniques tout-trans dans la synthese de differentes molecules naturelles pourra etre appliquee dorenavant pour generer les chaines tetraeniques (e,e,e,e) lors de differentes syntheses totales. Dans un deuxieme temps, nous avons essaye de developper
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32

Ashford, Neil F. "Kinetic studies of polyene exchange and substitution in low valent octahedral metal complexes." Thesis, Keele University, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.716856.

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33

Liblikas, Ilme. "Syntheses and behaviour activity of conjugated polyenic pheromone components." Doctoral thesis, KTH, Chemistry, 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3790.

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<p>This thesis deals with the synthesis of conjugated dienicand trienic pheromone components- C<sub>12</sub>-C<sub>16</sub>alcohols, acetates and aldehydes and theirapplications in pheromone communication studies.</p><p>Insect pheromones are widely used in modern pest management.The development of effective tools for plant protection is aresult of complex broad, interdisciplinary basic and appliedresearch. A practical use of pheromones for pest managementusually requires that specific active chemicals must beisolated,identified and produced synthetically. The creationof pheromone materials bes
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34

Shesham, Vaishnavi. "Assessing Diphenyl Polyenes as PH Sensitive Colorimetric Probes of Proton Gradients in Polymer Coatings." University of Dayton / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1620133505202436.

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35

Hafer, Jillian E. (Jillian Elizabeth). "Discrete polyene oligomer synthesis and related polymer characterization : (Appendix I: Reduced tungsten dimeric compounds)." Thesis, Massachusetts Institute of Technology, 2006. http://hdl.handle.net/1721.1/36284.

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Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2006.<br>Includes bibliographical references (leaves 96-97).<br>Molybdenum complexes ... were used to synthesize polyene oligomeric compounds with up to 15 conjugated double bonds by reaction with aldehyde compounds in a Wittig-like fashion. The optical properties of highly nr-conjugated systems are investigated due to potential application in photooptical materials. To this end, discrete oligomers have been synthesized in order to study properties of the varying lengths and to what extent solvent and substitution patter
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36

Kildahl-Andersen, Geir. "Polyenyl cations and radical cations – synthesis, spectroscopic properties and reactions." Doctoral thesis, Norwegian University of Science and Technology, Department of Chemistry, 2007. http://urn.kb.se/resolve?urn=urn:nbn:no:ntnu:diva-1790.

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<p>In the present work, polyene precursors for the formation of charged polyenyl species were synthesised. Their conversion to charge delocalised radical cations and diamagnetic mono- and dications was carried out by treatment with Brønsted and Lewis acids. Reaction conditions were optimised to achieve sufficient stability of the charged polyenes for characterisation by modern spectroscopic methods; in particular nearinfrared absorption spectroscopy (NIR), two-dimensional nuclear magnetic resonance (2D NMR), electron paramagnetic resonance (EPR) and dynamic light scattering.</p><p>The full ass
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37

Schomaker, Joseph Anthony. "Constraints for conductivity in base treated or reduced polyacetylenes, segmented polyacetylenes, and w-diphenyl polyenes." Diss., Georgia Institute of Technology, 1990. http://hdl.handle.net/1853/30949.

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38

Ekeroth, Sara, and Elvira Lind. "Avfallsplast i asfaltvägar : En granskning av möjligheten att implementera polyeten som polymertillsats i svenska vägar." Thesis, KTH, Hållbar utveckling, miljövetenskap och teknik, 2020. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-277714.

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Denna rapport utreder möjligheten att implementera avfallsplast, specifikt polyeten, som polymertillsats i svenska asfaltvägar. Tekniken, med avseende på avfallsplast, används idag i begränsad utsträckning i andra länder samt utreds på flera håll som en möjlig metod att främja hållbar utveckling genom att öka materialåtervinningen av plast. I Sverige förbränns idag en stor mängd plast för energiåtervinning och införandet av metoden skulle, förutsatt att den ersätter en del av energiåtervinningen, bidra till att minska växthusgasutsläpp från fossila material. Det anvä
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39

Nieves, Calatrava Ingrid. "Polyene sphingolipids with latent fluorescence: new tools to study the biophysical properties of cellular membranes." Doctoral thesis, Universitat de Barcelona, 2015. http://hdl.handle.net/10803/347964.

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One of the ultimate goals in biomedicine is to understand the relationship between structure, function, and dynamics of biomolecules in living cells. The biophysical tools designed to gain more insight into metabolism, trafficking and interaction of the sphingolipids (SLs), require the use of high molar concentrations of fluorescence lipid analogues, labelled with bulky chromophores, such BODIPY or NBD, resulting in altered biophysical properties of the cell membrane. Recently, lipids tagged with conjugated linear polyene moieties, which are strongly absorbing chromophores that may attain
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40

Bedore, Matthew William. "Synthesis of Key Fragments Contained in the Framework of Amphidinol 3." The Ohio State University, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=osu1211485773.

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41

Jørgensen, Hanne. "Analysis of genes for the biosynthesis of polyene macrocyclic compounds in streptomycetes isolated from the Trondheimsfjord." Doctoral thesis, Norges teknisk-naturvitenskapelige universitet, Institutt for bioteknologi, 2009. http://urn.kb.se/resolve?urn=urn:nbn:no:ntnu:diva-5577.

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The isolation of microbial producers of bioactive natural products from environmental samples has historically been a great success and laid the foundation for the modern medical science we enjoy the fruits of today. To sustain and further improve the treatment of diseases, we rely upon the continued discovery and development of new bioactive compounds. The work presented in this thesis describes the screening of more than 4000 actinomycete isolates recovered from sediment and neuston layer samples collected in the Trondheimsfjord. The objective was to discover producers of new compounds with
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42

Ronson, Thomas O. "Development of cross-coupling routes to macrocyclic polyenes : the first total synthesis of phacelocarpus 2-pyrone A." Thesis, University of York, 2015. http://etheses.whiterose.ac.uk/9480/.

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This thesis describes the development of a synthetic approach to an unusual pyrone-containing macrocyclic natural product isolated from the marine alga Phacelocarpus labillardieri. This comprises the synthesis of a simplified model system followed by the completion of the first total synthesis of the natural product and its suggested stereochemical reassignment, as well as studies on related palladium catalysis methodology. An overview of macrocyclic 2-pyrone natural products is given initially, along with a discussion of 2-pyrone reactivity and general macrocyclisation strategies in natural p
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43

Lyskov, Igor [Verfasser]. "Redesign and Reparameterization of the DFT/MRCI Hamiltonian and its Application to Electronically Excited Linear Polyenes / Igor Lyskov." Düsseldorf : Universitäts- und Landesbibliothek der Heinrich-Heine-Universität Düsseldorf, 2017. http://d-nb.info/1125597534/34.

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44

Abraham, Emmanuel. "Photodynamique picoseconde et non-linéarité optiques à l'état excité : étude de dérivés de la famille des diphényl-polyenes." Bordeaux 1, 1997. http://www.theses.fr/1997BOR10571.

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Nous avons developpe des methodes de spectroscopie lineaire (methode pompe-sonde) et non-lineaire (diffusion raman anti-stokes coherente, melange degenere a quatre ondes et effet kerr optique) ayant une resolution temporelle picoseconde. Ces techniques ont ete utilisees pour etudier l'evolution, apres excitation, de composes organiques de la famille des diphenyl-polyenes. Nous avons pu ainsi mettre en evidence, en solvants polaires, un processus de photoionisation monophotonique et un mecanisme de transfert de charge assiste par torsion. Les temps de formation des radicaux cations et de l'etai
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45

Hakkou, Abdelkader. "Mode d'action des antifongiques polyéniques sur l'enveloppe cellulaire de la levure Kluyveromyces lactis : étude du phénomène de résistance." Nancy 1, 1988. http://www.theses.fr/1988NAN12023.

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46

Cornil, Johan. "Couplages et hétérocyclisations métallo-catalysés : approche synthétique de la mirabaline." Thesis, Paris 6, 2014. http://www.theses.fr/2014PA066404.

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Les enchaînements polyéniques linéaires sont des motifs couramment rencontrés dans de nombreuses molécules naturelles. L'accès à ces structures nécessite souvent des réactifs fonctionnalisés dont la synthèse est parfois longue et laborieuse. Nous décrivons dans ce manuscrit une nouvelle méthode efficace et rapide de couplage de Heck entre un iodure vinylique fonctionnalisé par un boronate MIDA et des oléfines variées pour accéder à des boronates MIDA diéniques. Ces briques moléculaires stables ont été valorisées par la formation de polyènes fonctionnalisés.Cette stratégie a été appliquée à la
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47

Tovar, Michael. "Thermisches Verhalten von CuOn-Polyedern in ausgewählten Verbindungen Wechselspiel zwischen lokaler Strukturverzerrung und Kristalltopologie /." [S.l. : s.n.], 2000. http://deposit.ddb.de/cgi-bin/dokserv?idn=961521090.

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48

Vogelgesang, V. G. [Verfasser]. "Parallelisierbare Erkennung trihedraler, starrer und statischer Polyeder in einzelnen hochauflösenden Abstandsbildern / V. G. Vogelgesang." Karlsruhe : KIT-Bibliothek, 1997. http://d-nb.info/1102250074/34.

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49

Hagmayer, Steffen. "Struktur von Projektplanungsproblemen aus polyedertheoretischer Sicht /." Aachen : Shaker, 2006. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=014959109&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.

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50

Anderbrink, Emelie. "Att komma fram till en möjlig lösning av många : Pocketspring sits steg för steg." Thesis, Mittuniversitetet, Avdelningen för design, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:miun:diva-31271.

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Uppsatsens upplägg beskriver med skisser och diskussioner med min lärare om hur man kan bygga upp en sits på en möbel med moderna stoppningstekniken. Med hjälp från skisser och förklaringar steg för steg hur man arbetar med modern stoppningsteknik. De material man använder inom traditinell stoppningsteknik är tagel, krollsprint och celocrin. Tagel består av hästhår, krollsprint är fibrer från dvärgpalm och celocrin kommer ifrån kokosfibrer. Det jag kommer fördjupa mig i denna uppsats är hur man bygger upp en möbel med modern stoppningsteknik från stomme till en färdig sits, som visas vilka mat
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