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Journal articles on the topic 'Polyester hydrolysis'

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1

Kumagai, Shogo, Yuto Morohoshi, Guido Grause, Tomohito Kameda, and Toshiaki Yoshioka. "Pyrolysis versus hydrolysis behavior during steam decomposition of polyesters using 18O-labeled steam." RSC Advances 5, no. 76 (2015): 61828–37. http://dx.doi.org/10.1039/c5ra08577b.

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A method was developed to distinguish between hydrolysis and pyrolysis pathways in the steam degradation of various polyesters. Selectivity was shown to be strongly influenced by the polyester structure.
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2

Wang, Haizhen, Tianrui Zhang, Kaixiang Chen, Liangkun Long, and Shaojun Ding. "Biochemical Characterization and Polyester-Binding/Degrading Capability of Two Cutinases from Aspergillus fumigatus." Microorganisms 13, no. 5 (2025): 1121. https://doi.org/10.3390/microorganisms13051121.

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Two recombinant cutinases, AfCutA and AfCutB, derived from Aspergillus fumigatus, were heterologously expressed in Pichia pastoris and systematically characterized for their biochemical properties and polyester-degrading capabilities. AfCutA demonstrated superior catalytic performance compared with AfCutB, displaying higher optimal pH (8.0–9.0 vs. 7.0–8.0), higher optimal temperature (60 °C vs. 50 °C), and greater thermostability. AfCutA exhibited increased hydrolytic activity toward p-nitrophenyl esters (C4–C16) and synthetic polyesters. Additionally, AfCutA released approximately 3.2-fold mo
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3

Di Bisceglie, Federico, Felice Quartinello, Robert Vielnascher, Georg M. Guebitz, and Alessandro Pellis. "Cutinase-Catalyzed Polyester-Polyurethane Degradation: Elucidation of the Hydrolysis Mechanism." Polymers 14, no. 3 (2022): 411. http://dx.doi.org/10.3390/polym14030411.

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Polyurethanes (PU) are one of the most-used classes of synthetic polymers in Europe, having a considerable impact on the plastic waste management in the European Union. Therefore, they represent a major challenge for the recycling industry, which requires environmentally friendly strategies to be able to re-utilize their monomers without applying hazardous and polluting substances in the process. In this work, enzymatic hydrolysis of a polyurethane-polyester (PU-PE) copolymer using Humicola insolens cutinase (HiC) has been investigated in order to achieve decomposition at milder conditions and
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4

Fu, Hao, Linbo Gong, and Shuling Gong. "A New Approach Utilizing Aza-Michael Addition for Hydrolysis-Resistance Non-Ionic Waterborne Polyester." Polymers 14, no. 13 (2022): 2655. http://dx.doi.org/10.3390/polym14132655.

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This work first synthesized a series of linear polyesters by step-growth polycondensation, then an amino-terminated hydrophilic polyether was grafted to the polyester as side-chains through aza-Michael addition to prepare a self-dispersible, non-ionic waterborne comb-like polyester (NWCPE). In contrast to traditional functionalization methods that usually require harsh reaction conditions and complex catalysts, the aza-Michael addition proceeds efficiently at room temperature without a catalyst. In this facile and mild way, the NWCPE samples with number-average molecular weight (Mn) of about 8
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5

Zhang, Heng, Xiao Ze Jiang, Xiao Yun Pan, et al. "Exploring the Effect of Molecular Components on Hydrolysis-Resistance Performance and Hydrophilicity of Amphiphilic Poly(Ester-Block-Ether) Copolymers." Materials Science Forum 848 (March 2016): 99–110. http://dx.doi.org/10.4028/www.scientific.net/msf.848.99.

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In this study, four poly (ester-block-ether) copolymers were synthesized via the macromolecular transesterification method from different hydrophobic polyester segments prepared from precursors, dimethyl terephthalate (DMT), ethylene glycol (EG), dimethyl-5-hydroxyisophthalate (DHIP) and neopentyl glycol (NPG), and hydrophilic polyether, polyethylene glycol (PEG) or polyetheramine (PEA). The hydrolysis-resistance performance at alkaline condition and hydrophilicity of these four synthetic poly (ester-block-ether) copolymers were characterized by hydrolysis degree and water solubility with Nucl
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Kupczak, Maria, Anna Mielańczyk, and Dorota Neugebauer. "The Influence of Polymer Composition on the Hydrolytic and Enzymatic Degradation of Polyesters and Their Block Copolymers with PDMAEMA." Materials 14, no. 13 (2021): 3636. http://dx.doi.org/10.3390/ma14133636.

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Well-defined, semi-degradable polyester/polymethacrylate block copolymers, based on ε-caprolactone (CL), d,l-lactide (DLLA), glycolide (GA) and N,N′-dimethylaminoethyl methacrylate (DMAEMA), were synthesized by ring-opening polymerization (ROP) and atom transfer radical polymerization. Comprehensive degradation studies of poly(ε-caprolactone)-block-poly(N,N′-dimethylaminoethyl methacrylate) (PCL-b-PDMAEMA) on hydrolytic degradation and enzymatic degradation were performed, and those results were compared with the corresponding aliphatic polyester (PCL). The solution pH did not affect the hydro
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7

Aneja, Arun, Karel Kupka, Jiří Militký, and Mohanapriya Venkataraman. "Kinetics of Hydrolytic Depolymerization of Textile Waste Containing Polyester." Fibers 12, no. 10 (2024): 82. http://dx.doi.org/10.3390/fib12100082.

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Textile products comprise approximately 10% of the total global carbon footprint. Standard practice is to discard apparel textile waste after use, which pollutes the environment. There are professional collectors, charity organizations, and municipalities that collect used apparel and either resell or donate them. Non-reusable apparel is partially recycled, mainly through incineration or processed as solid waste during landfilling. More than 60 million tons of textiles are burnt or disposed of in landfills annually. The main aim of this paper is to model the heterogeneous kinetics of hydrolysi
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8

Bengtsson, Jenny, Anna Peterson, Alexander Idström, Hanna de la Motte, and Kerstin Jedvert. "Chemical Recycling of a Textile Blend from Polyester and Viscose, Part II: Mechanism and Reactivity during Alkaline Hydrolysis of Textile Polyester." Sustainability 14, no. 11 (2022): 6911. http://dx.doi.org/10.3390/su14116911.

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Chemical recycling of textiles holds the potential to yield materials of equal quality and value as products from virgin feedstock. Selective depolymerization of textile polyester (PET) from regenerated cellulose/PET blends, by means of alkaline hydrolysis, renders the monomers of PET while cellulose remains in fiber form. Here, we present the mechanism and reactivity of textile PET during alkaline hydrolysis. Part I of this article series focuses on the cellulose part and a possible industrialization of such a process. The kinetics and reaction mechanism for alkaline hydrolysis of polyester p
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9

Dong, Zhao Qin, and Guo Qiang Chen. "Alkaline Hydrolysis of Polyester in the Presence of Ionic Liquids." Advanced Materials Research 441 (January 2012): 661–65. http://dx.doi.org/10.4028/www.scientific.net/amr.441.661.

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The alkaline hydrolysis of polyester fabric in NaOH solution in the presence of several 1-alkyl-3-methylimidazolium bromine ionic liquids (ILs), CnMImBr (n=8, 12, 14, 16) was examined in comparison to the use of cetyltrimethyl ammonium bromide (CTAB) as an accelerant. The weight loss of polyester fabric was found to be greatly dependent on the concentrations of ILs and the length of alkyl groups in ILs. C14MImBr and C16MImBr exhibited good catalytic actions. The use of C16MImBr as an accelerator could endow polyester fabrics with slightly higher weight loss in comparison with CTAB. In the pres
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10

Cammarano, Aniello, Giovanna Luca, and Eugenio Amendola. "Surface modification and adhesion improvement of polyester films." Open Chemistry 11, no. 1 (2013): 35–45. http://dx.doi.org/10.2478/s11532-012-0135-x.

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AbstractFacile surface modification of polyester films was performed via chemical solutions treatment. Surface hydrolysis was carried out by means of sodium hydroxide solutions, leading to the formation of carboxylate groups. Three commercial polyester films of 100 μm in thickness were used in this work: AryLite™, Mylar™, and Teonex™, hydrolysis time being the main modification parameter. FTIR-ATR analysis, topography and contact angle (CA) measurements, surface free energy (SFE) and T-Peel adhesion tests were carried out to characterize the modified films. A quantitative estimate of the carbo
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11

Greimel, Katrin, Annemarie Marold, Christian Sohar, et al. "Enzymatic hydrolysis of polyester based coatings." Reactive and Functional Polymers 73, no. 10 (2013): 1335–39. http://dx.doi.org/10.1016/j.reactfunctpolym.2013.03.020.

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12

Nourbakhsh, Shirin, Majid Montazer, and Zoha khandaghabadi. "Zinc oxide nano particles coating on polyester fabric functionalized through alkali treatment." Journal of Industrial Textiles 47, no. 6 (2016): 1006–23. http://dx.doi.org/10.1177/1528083716657819.

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In recent years, zinc oxide nano particles coating on textiles such as polyester is considered because of UV blocking and self-cleaning properties. Alkaline hydrolysis of polyester is a method in textile industry for surface treatment in large scale to enhance wettability. In the present work, polyester fabric was treated with sodium hydroxide, then was coated with ZnO nano particles, and also polyester fabric was treated with sodium hydroxide and ZnO nano particles at the same time. The bending length, water adsorption time, bactericidal properties, atomic absorption spectroscopy, and self-cl
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13

C., T. Ravichandran, Revathi E., and Ulaganathan S. "SYNTHESIS AND CHARACTERIZATION OF NOVEL BIODEGRADABLE ALIPHATIC AND AROMATICCOPOLYESTERSPOLY ETHYLENE SUCCINATE-CO-ETHYLENESEBACATE), POLY (BUTYLENE ADIPATE-CO-BUTYLENE TEREPHTHALATE)." International Journal of Applied and Advanced Scientific Research 1, no. 2 (2017): 17–21. https://doi.org/10.5281/zenodo.256154.

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In this paper, we report on the synthesis of certain novel aliphatic biodegradable copolyesters namelypoly(ethylene succinate-co- ethylene sebacate), poly(butylene adipate-co- butylene terephthalate)were carried out using Poly(ethylene succinate), Poly(ethylene sebacate)polybutyleneadipateand Poly(butylene terephthalate) in presence of Poly Phosphoric acid. The polyesters were characterised by solubility, viscosity measurements, IR, <sup>1</sup>H NMR and <sup>13</sup>C NMR spectral methods. The thermal properties were studied using differential scanning calorimetry. The X ray patterns were col
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14

Polidar, Matthias, Elke Metzsch-Zilligen, and Rudolf Pfaendner. "Controlled and Accelerated Hydrolysis of Polylactide (PLA) through Pentaerythritol Phosphites with Acid Scavengers." Polymers 14, no. 19 (2022): 4237. http://dx.doi.org/10.3390/polym14194237.

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This study provides insight into the accelerated hydrolysis of polyester PLA through the addition of phosphites based on pentaerythritol. To control hydrolysis and ensure processing stability, different types of phosphites and combinations of phosphites with acid scavengers were studied. Therefore, commercially available PLA was compounded with selected additives on a twin-screw extruder, and hydrolysis experiments were performed at 23 °C, 35 °C and 58 °C in deionized water. Hydrolysis of PLA was evaluated by the melt volume rate (MVR) and size-exclusion chromatography (SEC). For example, afte
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15

Kaurin, Tea, Tanja Pušić, and Mirjana Čurlin. "Biopolymer Textile Structure of Chitosan with Polyester." Polymers 14, no. 15 (2022): 3088. http://dx.doi.org/10.3390/polym14153088.

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The research deals with functionalization of a standard polyester fabric with biopolymer chitosan, whose premises are multifunctional and favour ecological effects. Due to the incompatibility of synthetic and natural polymers, the chitosan treatment was preceded by alkaline hydrolysis with sodium hydroxide with the addition of cationic and anionic surfactants as promoters. Compatibility of the chitosan with untreated and alkali-hydrolyzed fabrics was performed by analysis of mechanical and physico-chemical properties. The number of characterisation procedures performed required the use of hier
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16

IMADA, Yasunori, Yasuteru KAJIKAWA, Masayuki TANIGUCHI, Kenji KOUMOTO, Ikuo TAKAHASHI, and Takashi MASUDA. "Synthesis of Aliphatic Polyester and Enzymatic Hydrolysis." KOBUNSHI RONBUNSHU 55, no. 8 (1998): 497–99. http://dx.doi.org/10.1295/koron.55.497.

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17

Pavlopoulou, Kalliopi Elli, Kateřina Hrůzová, May Kahoush, et al. "Textile Recycling: Efficient Polyester Recovery from Polycotton Blends Using the Heated High-Ethanol Alkaline Aqueous Process." Polymers 16, no. 21 (2024): 3008. http://dx.doi.org/10.3390/polym16213008.

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Textile production has doubled in the last 20 years, but only 1% is recycled into new fibers. It is the third largest contributor to water pollution and land use, accounting for 10% of global carbon emissions and 20% of clean water pollution. A key challenge in textile recycling is blended yarns, such as polycotton blends, which consist of polyester and cotton. Chemical recycling offers a solution, in particular, alkali treatment, which hydrolyzes polyester (PET) into its components while preserving cotton fibers. However, conventional methods require high temperatures, long durations, or cata
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18

Rajić, Ivona, Emi Govorčin Bajsić, and Tamara Holjevac Grgurić. "Application of polyurethane in the production of shoe soles." Koža & obuća 69, no. 1 (2021): 7–9. http://dx.doi.org/10.34187/ko.69.1.2.

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Good footwear should be comfortable, long-lasting and fit for purpose, polyurethanes allow designers to meet all of these objectives. Polyurethanes are used in the footwear industry to make insoles and shoe soles.There are two types of PU soles a polyether and polyester based PU sole. Polyether based PU soles have a high resistance against hydrolysis and low oil resistance while polyester based PU soles have a low resistance against hydrolysis and high oil resistance. In this work thermal and mechanical properties of PU elastomers with polyether and polyester polols with different hard segment
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19

Čorak, Ivana, Anita Tarbuk, Dragan Đorđević, Ksenija Višić, and Lea Botteri. "Sustainable Alkaline Hydrolysis of Polyester Fabric at Low Temperature." Materials 15, no. 4 (2022): 1530. http://dx.doi.org/10.3390/ma15041530.

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High crystallinity leads to low hydrophilicity of fabric made of (poly(ethylene terephthalate)) fibers (PET) causing problems in finishing, washing, and dyeing processes. To improve these properties, the surface of PET fibers is usually modified by hydrolysis. Alkaline hydrolysis is a conventional process usually performed at a temperature higher than 100 °C for more than 1 h. However, the use of strong alkali and high processing temperatures (&gt;100 °C) can lead to fabric damage and a negative impact on the environment. Therefore, in this paper, the possibility of hydrolysis of the PET fiber
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20

Kumar, Jeyaraman Anandha, and M. Senthil Kumar. "A Study on Improving Dyeability of Polyester Fabric Using Lipase Enzyme." Autex Research Journal 20, no. 3 (2020): 243–49. http://dx.doi.org/10.2478/aut-2019-0030.

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AbstractEnzymatic hydrolysis on synthetic fibers enhances the hydrophilicity and solves the concerns regarding the environmental issues of textile industry. Lipase hydrolyses ester linkages in polyethylene terephthalate and produces polar hydroxyl and carboxylic groups. The study aims to identify and investigate the effect of enzyme treatment on weight loss and surface modification of polyester fabrics. Also the functional groups present before and after treatment and the effect of enzyme treatment on the improvement of dye uptake are studied. The test indicates that enzymatic process creates
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21

Li, Xiao Ning, Guo Zheng, and Hong Xiang Yang. "Study on Synthesis and Properties of a Novel Borate Ester Surfactant." Advanced Materials Research 129-131 (August 2010): 857–61. http://dx.doi.org/10.4028/www.scientific.net/amr.129-131.857.

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A new type of surfactant was prepared. The structure of the novel borate ester formed by reacting boric acid and lauryl alcohol and with diethanol amine was established by 11B, 1H NMR spectroscopy and IR spectrum. Testing it antistatic property, we found 0.3wt% dodecanol diethanol amine borate ester surfactant (the final product LNB) can make specific resistance of the polyester staple fiber be decreased from 1012 to 108 at the condition of 60% RH and 18°C. Because Amine compounds with nonbonding electrons can form the extra molecular coordination bond of nitrogen to boron and prevent hydrolys
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22

Richter, P.K., P. Blázquez-Sánchez, Z. Zhao, et al. "Structure and function of the metagenomic plastic-degrading polyester hydrolase PHL7 bound to its product." Nature Communications 14 (April 5, 2023): 1905. https://doi.org/10.1038/s41467-023-37415-x.

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The recently discovered metagenomic-derived polyester hydrolase PHL7 is able to efficiently degrade amorphous polyethylene terephthalate (PET) in post-consumer plastic waste. We present the cocrystal structure of this hydrolase with its hydrolysis product terephthalic acid and elucidate the influence of 17 single mutations on the PET-hydrolytic activity and thermal stability of PHL7. The substrate-binding mode of terephthalic acid is similar to that of the thermophilic polyester hydrolase LCC and deviates from the mesophilic IsPETase. The subsite I modifications L93F and Q95Y, derived from LCC
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TOKIWA, Yutaka, Tomoo SUZUKI, and Kiyoshi TAKEDA. "Two types of lipases in hydrolysis of polyester." Agricultural and Biological Chemistry 52, no. 8 (1988): 1937–43. http://dx.doi.org/10.1271/bbb1961.52.1937.

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24

Chen, Da-Wei, Robert J. Kubiak, Jon A. Ashley, and Kim D. Janda. "Reactive immunization elicits catalytic antibodies for polyester hydrolysis." Journal of the Chemical Society, Perkin Transactions 1, no. 21 (October 9, 2001): 2796–803. http://dx.doi.org/10.1039/b105412k.

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25

Tokiwa, Yutaka, Tomoo Suzuki, and Kiyoshi Takeda. "Two Types of Lipases in Hydrolysis of Polyester." Agricultural and Biological Chemistry 52, no. 8 (1988): 1937–43. http://dx.doi.org/10.1080/00021369.1988.10868966.

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26

Kim, Mal-Nam, Boo-Young Lee, Ick-Mo Lee, Han-Sup Lee, and Jin-San Yoon. "TOXICITY AND BIODEGRADATION OF PRODUCTS FROM POLYESTER HYDROLYSIS." Journal of Environmental Science and Health, Part A 36, no. 4 (2001): 447–63. http://dx.doi.org/10.1081/ese-100103475.

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27

Kijchavengkul, Thitisilp, Rafael Auras, Maria Rubino, Susan Selke, Mathieu Ngouajio, and R. Thomas Fernandez. "Biodegradation and hydrolysis rate of aliphatic aromatic polyester." Polymer Degradation and Stability 95, no. 12 (2010): 2641–47. http://dx.doi.org/10.1016/j.polymdegradstab.2010.07.018.

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28

Valiente, Nathalie, Thierry Lalot, Maryvonne Brigodiot, and Ernest Mar�chal. "Enzyme-catalyzed hydrolysis of unsaturated polyester networks. II. enzyme-catalyzed hydrolysis of polyester networks prepared from poly(1,2-propanediyl fumarate)." Journal of Polymer Science Part A: Polymer Chemistry 35, no. 1 (1997): 35–40. http://dx.doi.org/10.1002/(sici)1099-0518(19970115)35:1<35::aid-pola5>3.0.co;2-1.

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29

Pušić, Tanja, Tea Bušac, and Julija Volmajer Valh. "Influence of Cross-Linkers on the Wash Resistance of Chitosan-Functionalized Polyester Fabrics." Polymers 16, no. 16 (2024): 2365. http://dx.doi.org/10.3390/polym16162365.

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This study investigates the wash resistance of polyester fabrics functionalized with chitosan, a biopolymer known for its biocompatibility, non-toxicity, biodegradability and environmentally friendly properties. The interaction of chitosan with synthetic polymers, such as polyester, often requires surface treatment due to the weak natural affinity between the two materials. To improve the interaction and stability of chitosan on polyester, alkaline hydrolysis of the polyester fabric was used as a surface treatment method. The effectiveness of using cross-linking agents 1,2,3,4-butane tetracarb
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30

Qu, Dezhi, Ziheng Yang, Jinyu Zhang, Shuyu Wang, and Yao Lu. "Brief Analysis on the Degradation of Sugar-Based Copolyesters." Polymers 15, no. 22 (2023): 4372. http://dx.doi.org/10.3390/polym15224372.

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Isosorbide can be used as a third monomer in the synthesis of aliphatic polyesters, and its V-shaped bridging ring structure can effectively improve the rigidity of the copolyester molecular chain. In this work, a series of degradable polyester materials were prepared by modifying polybutylene succinate and using isosorbide as the third monomer. The degradation tests in this paper were implemented through the hydrolysis of copolyesters in distilled water, degradation in natural water and degradation tests in simulated natural environments. The results showed that PBS and its copolyesters can d
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31

Koo, J. M., S. H. Kim, and S. S. Im. "Structural deformation phenomenon of synthesized poly(isosorbide-1,4-cyclohexanedicarboxylate) in hot water." RSC Advances 7, no. 11 (2017): 6315–22. http://dx.doi.org/10.1039/c6ra26532d.

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Water induced deformation phenomena of synthesized polyester including isosorbide shares analogous mechanism of solvent induced crystallization. This structural deformation is effected by pH, open-ring ISB and ester hydrolysis.
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32

Frank, R., D. Krinke, C. Sonnendecker, W. Zimmermann, and H.-G. Jahnke. "Real-Time Noninvasive Analysis of Biocatalytic PET Degradation." ACS Catalysis 12, no. 1 (2021): 25–35. https://doi.org/10.5281/zenodo.8370242.

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The Earth has entered the&nbsp;<em>Anthropocene</em>, which is branded by ubiquitous and devastating environmental pollution from plastics such as polyethylene terephthalate (PET). Ecofriendly and at the same time economical solutions for plastic recycling and reuse are being sought more urgently now than ever. With the possibility to recover its building blocks, the hydrolysis of PET waste by its selective biodegradation with polyester hydrolases is an appealing solution. We demonstrate how changing the dielectric properties of PET films can be used to evaluate the performance of polyester hy
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Koksharov, Sergey A., Nadezda L. Kornilova, and Sergey V. Fedosov. "MODIFICATION OF POLYESTER FIBERS TO CREATE COMPOSITE MATERIALS WITH ADJUSTABLE RIGIDITY." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENIY KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 59, no. 6 (2018): 105. http://dx.doi.org/10.6060/tcct.20165906.5364k.

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Research aims at experimental study of an effective method of creating polymer-fiber composite materials with a comb structure of an interfacial layer. To change the surface micro-relief of polyester fiber method of surface saponification in the presence of a quaternary ammonium compound was used. This method provides localized hydrolysis reacting of polymer to form dotted etch wells. Fiber modification allows synthesizing comb polymer chains of the binder with the penetration of the lateral branches into the formed pore spaces of the textile carrier. Condition of polyester fiber after saponif
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34

Mikhailovskaya, A. P., and A. A. Kaporov. "Effect of Ammonium Salts on Hydrolysis of Polyester Fiber." Fibre Chemistry 52, no. 5 (2021): 341–45. http://dx.doi.org/10.1007/s10692-021-10209-x.

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35

Kimizu, Mitsugu, Yoshimasa Shimbo, Toshikazu Abe, and Teruo Hori. "Alkali Hydrolysis of Polyester Fabric under Ultra-High Pressure." FIBER 61, no. 4 (2005): 109–14. http://dx.doi.org/10.2115/fiber.61.109.

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36

Xu, Weilin, and Chaoli Yang. "Hydrolysis and dyeing of polyester fabric using microwave irradiation." Coloration Technology 118, no. 5 (2002): 211–14. http://dx.doi.org/10.1111/j.1478-4408.2002.tb00101.x.

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Sato, Maki, Seiji Endo, Yoshio Araki, Go Matsuoka, Shoichi Gyobu, and Hideo Takeuchi. "The flame-retardant polyester fiber: Improvement of hydrolysis resistance." Journal of Applied Polymer Science 78, no. 5 (2000): 1134–38. http://dx.doi.org/10.1002/1097-4628(20001031)78:5<1134::aid-app230>3.0.co;2-5.

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38

Dave, Jayshree, Raj Kumar, and H. C. Srivastava. "Studies on modification of polyester fabrics I: Alkaline hydrolysis." Journal of Applied Polymer Science 33, no. 2 (1987): 455–77. http://dx.doi.org/10.1002/app.1987.070330215.

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39

Seo, Kab S., and James D. Cloyd. "Kinetics of hydrolysis and thermal degradation of polyester melts." Journal of Applied Polymer Science 42, no. 3 (1991): 845–50. http://dx.doi.org/10.1002/app.1991.070420330.

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40

Haß, Jan, Marcel Gausmann, and Andreas Jupke. "Electro-Oxidation of Diols in Polymer Recycling: Facilitating Separation and Refining Products." ECS Meeting Abstracts MA2023-02, no. 25 (2023): 1368. http://dx.doi.org/10.1149/ma2023-02251368mtgabs.

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Increasing environmental awareness has highlighted the importance of plastic recycling and rightfully so, considering plastic pollution and an ever-increasing consumption of plastic products. Currently, numerous recycling strategies are being investigated with varying approaches depending on the type of polymer [1]. One attractive process is the chemical recycling of polyesters via alkaline hydrolysis which produces the dicarboxylic acid salts and diols of the respective polyester. The dicarboxylic acids can be separated by crystallization, while the diol separation remains a challenge. A proc
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Lee, Suhyun. "Superhydrophobicity and conductivity of polyester-conductive fabrics using alkaline hydrolysis." RSC Advances 12, no. 35 (2022): 22911–21. http://dx.doi.org/10.1039/d2ra03996f.

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42

Sabli, Nordin, Shamsainon Abu Toat, Hiroyuki Yoshida, and Shamsul Izhar Shamsul Izhar. "Hydrolysis of Blended Cotton/Polyester Fabric from Hospital Waste using Subcritical Water." Sains Malaysiana 52, no. 1 (2023): 139–51. http://dx.doi.org/10.17576/jsm-2023-5201-11.

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Currently in Malaysia, most wastes are disposed into poorly managed systems with little or no pollution protection measures. Large amounts of wastes such as textiles are generated through hospitals and health care centers. However, the improper management of these abundantly generated wastes may pose an environmental pollution problems and fire hazard. Cotton textile is a potential biomass for bioethanol production. Subcritical water (Sub-CW) hydrolysis was investigated as an alternative technology for the recycling of cotton textile waste for current health care waste management. The aim of t
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Valh, Julija Volmajer, Bojana Vončina, Aleksandra Lobnik, Lidija Fras Zemljič, Lidija Škodič, and Simona Vajnhandl. "Conversion of polyethylene terephthalate to high-quality terephthalic acid by hydrothermal hydrolysis: the study of process parameters." Textile Research Journal 90, no. 13-14 (2019): 1446–61. http://dx.doi.org/10.1177/0040517519893714.

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A new circular economy concept is presented for the textile sector to convert unwearable polyester textile waste into valuable chemical feedstock. The idea behind it is to develop a new circular economy concept for the most used material in the textile industry, that is, polyester. Hydrothermal hydrolysis, an environmentally friendly process, has been studied for recovering polyester monomeric units. Under high-temperature and high-pressure conditions complete chemical depolymerization of pure poly(ethylene terephthalate) (PET) to terephthalic acid (TPA) was achieved at high yield. The produce
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Vayshbeyn, Leonid Ilyich, Elena Evgenyevna Mastalygina, Anatoly Aleksandrovich Olkhov, and Maria Victorovna Podzorova. "Poly(lactic acid)-Based Blends: A Comprehensive Review." Applied Sciences 13, no. 8 (2023): 5148. http://dx.doi.org/10.3390/app13085148.

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Aliphatic and aromatic polyesters of hydroxycarboxylic acids are characterized not only by biodegradability, but also by biocompatibility and inertness, which makes them suitable for use in different applications. Polyesters with high enzymatic hydrolysis capacity include poly(lactic acid), poly(ε-caprolactone), poly(butylene succinate) and poly(butylene adipate-co-terephthalate), poly(butylene succinate-co-adipate). At the same time, poly(lactic acid) is the most durable, widespread, and cheap polyester from this series. However, it has a number of drawbacks, such as high brittleness, narrow
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Hisaki, H., Y. Nakano, and S. Suzuki. "Adhesion of Polyester Tire Cord to Rubber and Cord Strength of Polyester Improved by Using Carboxylated VP-Latex." Tire Science and Technology 19, no. 3 (1991): 163–75. http://dx.doi.org/10.2346/1.2141714.

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Abstract The adhesion of polyester tire cord to rubber decreases during service when it is used in large tires. This phenomenon is recognized as the result of hydrolysis of the polyester by the amine compounds contained in rubber. The carboxylated latex based on the conventional vinylpyridine-butadiene-styrene latex was found to have the function of improving both the adhesion and the cord strength. For further improvement, a latex having more functional groups possessing a function of penetration prevention of amines was found to be effective when it is used in a double layer adhesive system.
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Lee, Su Jin, Changsang Yun, and Chung Hee Park. "Electrically conductive and superhydrophobic textiles via pyrrole polymerization and surface hydrophobization after alkaline hydrolysis." Textile Research Journal 89, no. 8 (2018): 1436–47. http://dx.doi.org/10.1177/0040517518773371.

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The objective of this study was to impart the electrical conductivity to the polyester fabric by applying polypyrrole having a good atmospheric stability, and to fabricate the superhydrophobic surface by using perfluorodecyltriethoxysilane to increase the durability and practicality of electrically conductive fabric. Nanoscale roughness that is essential for superhydrophobicity was given to polyester fabric by the alkaline hydrolysis. Samples simultaneously subjected to surface hydrophobization and the treatment for electrical conductivity exhibited the excellent electrical conductivity (0.55
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Vieira, A. C., J. C. Vieira, R. M. Guedes, and A. T. Marques. "Degradation and Viscoelastic Properties of PLA-PCL, PGA-PCL, PDO and PGA Fibres." Materials Science Forum 636-637 (January 2010): 825–32. http://dx.doi.org/10.4028/www.scientific.net/msf.636-637.825.

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Aliphatic polyesters, such as polylactic acid (PLA), polyglycolic acid (PGA), polycaprolactone (PCL), polydioxone (PDO) and others, have been commonly used in biodegradable products. Hydrolytic and/or enzymatic chain cleavage of these materials leads to α-hydroxyacids, which, in most cases, are ultimately assimilated in human body or in a composting environment. However, each of these has some shortcomings, in terms of mechanical properties and degradation time, which restrict its applications. The combination of these materials, by copolymerization or blending, enables a range of mechanical p
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Gupta, Deepti, Harshita Chaudhary, and Charu Gupta. "Topographical changes in polyester after chemical, physical and enzymatic hydrolysis." Journal of The Textile Institute 106, no. 7 (2014): 690–98. http://dx.doi.org/10.1080/00405000.2014.934046.

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Hsieh, You-Lo, and Lisa A. Cram. "Enzymatic Hydrolysis to Improve Wetting and Absorbency of Polyester Fabrics." Textile Research Journal 68, no. 5 (1998): 311–19. http://dx.doi.org/10.1177/004051759806800501.

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Chen, Da-Wei, Robert J. Kubiak, Jon A. Ashley, and Kim D. Janda. "ChemInform Abstract: Reactive Immunization Elicits Catalytic Antibodies for Polyester Hydrolysis." ChemInform 33, no. 12 (2010): no. http://dx.doi.org/10.1002/chin.200212044.

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