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Journal articles on the topic 'Polymer backbone'

Author: Grafiati

Published: 9 March 2023

Last updated: 31 July 2025

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1

Saha, Debasish, Karthik R. Peddireddy, Jürgen Allgaier, et al. "Amphiphilic Comb Polymers as New Additives in Bicontinuous Microemulsions." Nanomaterials 10, no. 12 (2020): 2410. http://dx.doi.org/10.3390/nano10122410.

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It has been shown that the thermodynamics of bicontinuous microemulsions can be tailored via the addition of various different amphiphilic polymers. In this manuscript, we now focus on comb-type polymers consisting of hydrophobic backbones and hydrophilic side chains. The distinct philicity of the backbone and side chains leads to a well-defined segregation into the oil and water domains respectively, as confirmed by contrast variation small-angle neutron scattering experiments. This polymer–microemulsion structure leads to well-described conformational entropies of the polymer fragments (back

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2

Kot, E., R. K. K. Saini, L. R. R. Norman, and A. Bismarck. "Novel Drag-Reducing Agents for Fracturing Treatments Based on Polyacrylamide Containing Weak Labile Links in the Polymer Backbone." SPE Journal 17, no. 03 (2012): 924–30. http://dx.doi.org/10.2118/141257-pa.

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Summary Water-soluble polymers have found extensive use in the oil and gas industry. For instance, high-molecular-weight polymers are very efficient drag-/friction-reducing agents and viscosifiers. Unfortunately, the adsorption of the polymer on the reservoir formation reduces the effectiveness of the recovery of oil and gas from low-permeability formations, such as shale. The availability of water-soluble polymers containing weak links in the backbone of the polymer that can be degraded upon experiencing a certain trigger, such as temperature, pH, or reducing agent, would be very advantageous

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3

Dyson, Matthew J., Eirini Lariou, Jaime Martin, et al. "Managing Local Order in Conjugated Polymer Blends via Polarity Contrast." Chemistry of Materials 31, no. 17 (2019): 6540–47. https://doi.org/10.1021/acs.chemmater.8b05259.

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<strong>Abstract:</strong> The optoelectronic landscape of conjugated polymers is intimately related to their molecular arrangement and packing, with minute changes in local order, such as chain conformation and torsional backbone order/disorder, frequently having a substantial effect on macroscopic properties. While many of these local features can be manipulated via chemical design, the synthesis of a series of compounds is often required to elucidate correlations between chemical structure and macromolecular ordering. Here, we show that blending semiconducting polymers with insulating commo

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4

Kanatieva, Anastasiia Yu, Dmitry A. Alentiev, Valeria E. Shiryaeva, Alexander A. Korolev, and Alexander A. Kurganov. "Impact of the Polymer Backbone Structure on the Separation Properties of New Stationary Phases Based on Tricyclononenes." Polymers 14, no. 23 (2022): 5120. http://dx.doi.org/10.3390/polym14235120.

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The main purpose of this paper is to compare the chromatographic properties of capillary columns prepared with polymers with different backbone structures and to demonstrate the possibility of polymer differentiation via inverse gas chromatography. With the use of addition and metathesis types of polymerization of tricyclononenes, two new stationary phases were prepared. The metathesis polymer contained double bonds in the polymeric backbone while the backbone of the addition polymer was fully saturated and relatively mobile. A comparison of the separation and adsorption properties of new phas

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5

Park, Kyung Sun, Justin J. Kwok, Rishat Dilmurat, et al. "Tuning conformation, assembly, and charge transport properties of conjugated polymers by printing flow." Science Advances 5, no. 8 (2019): eaaw7757. http://dx.doi.org/10.1126/sciadv.aaw7757.

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Intrachain charge transport is unique to conjugated polymers distinct from inorganic and small molecular semiconductors and is key to achieving high-performance organic electronics. Polymer backbone planarity and thin film morphology sensitively modulate intrachain charge transport. However, simple, generic nonsynthetic approaches for tuning backbone planarity and the ensuing multiscale assembly process do not exist. We first demonstrate that printing flow is capable of planarizing the originally twisted polymer backbone to substantially increase the conjugation length. This conformation chang

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6

Li, Zongze, Gregory M. Treich, Mattewos Tefferi, et al. "High energy density and high efficiency all-organic polymers with enhanced dipolar polarization." Journal of Materials Chemistry A 7, no. 25 (2019): 15026–30. http://dx.doi.org/10.1039/c9ta03601f.

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7

Lv, Lei, Xiaofen Wang, Tao Dong, et al. "Significantly improving the efficiency of polymer solar cells through incorporating noncovalent conformational locks." Materials Chemistry Frontiers 1, no. 7 (2017): 1317–23. http://dx.doi.org/10.1039/c6qm00296j.

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8

Tanaka, Tomonari. "Recent Advances in Polymers Bearing Activated Esters for the Synthesis of Glycopolymers by Postpolymerization Modification." Polymers 16, no. 8 (2024): 1100. http://dx.doi.org/10.3390/polym16081100.

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Glycopolymers are functional polymers with saccharide moieties on their side chains and are attractive candidates for biomaterials. Postpolymerization modification can be employed for the synthesis of glycopolymers. Activated esters are useful in various fields, including polymer chemistry and biochemistry, because of their high reactivity and ease of reaction. In particular, the formation of amide bonds caused by the reaction of activated esters with amino groups is of high synthetic chemical value owing to its high selectivity. It has been employed in the synthesis of various functional poly

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9

Cheng, Heung-Kiu, and Vivian Wing-Wah Yam. "Luminescent alkynylplatinum(II) terpyridine-containing conjugated polymers: synthesis, characterization and photophysical studies." Chemical Synthesis 3, no. 2 (2023): 13. http://dx.doi.org/10.20517/cs.2022.43.

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A series of alkynylplatinum(II) terpyridine complexes and alkynylplatinum(II) terpyridine-containing conjugated polymers with different polymer backbones has been synthesized, and their spectroscopic properties and Förster resonance energy transfer (FRET) processes has been investigated. The platinum(II)-containing polymers exhibit dual emissive features with emission maxima at ca. 416-465 nm and ca. 671-673 nm, which are assigned to be originated from singlet intraligand (1IL) excited states from the polymer backbone and triplet metal-metal-to-ligand charge transfer (3MMLCT) excited states fr

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10

Hou, Qiong, Jie Luo, Sui Lian Luo, Hong Zhu, and Guang Shi. "White Electroluminescence from a Single Fluorene-Based Copolymer." Advanced Materials Research 160-162 (November 2010): 732–36. http://dx.doi.org/10.4028/www.scientific.net/amr.160-162.732.

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White light emitting polymers were synthesized through incorporating of low-band gap red light emitting 4,7-di(4-hexyl-thien-2-yl)-2,1,3-benzothiadiazole (DHTBT) moieties into the backbone of a blue-light-emitting poly(9,9-dioctylfluorene) (PFO). Incomplete energy transfer from the blue electroluminescent PFO backbone to the red light emitting unit occurred by carefully controlling the relative content of the low-band gap unit DHTBT in the resulting polymers. Pure white light electroluminescence from a single polymer has been obtained in a device with a configuration of ITO/PVK/polymer/Ba/Al.T

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11

Wang, Yu, Yudong Wang, Sushant Sahu, August A. Gallo, and Xiao-Dong Zhou. "Efficient Synthesis of High-Performance Anion Exchange Membranes by Applying Clickable Tetrakis(dialkylamino)phosphonium Cations." Polymers 15, no. 2 (2023): 352. http://dx.doi.org/10.3390/polym15020352.

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Tetrakis(dialkylamino)phosphonium (TKDAAP) compounds exhibit extraordinary base resistance, a prerequisite feature for high-performance anion exchange membranes (AEMs). It is, however, challenging to synthesize a TKDAAP compound with reactive functionality that can be used to link the cation to a polymer backbone. In this study, two TKDAAP compounds with alkyne functionality were synthesized and incorporated into an azide-modified SBS triblock copolymer backbone via Cu(I)-catalyzed alkyne–azide cycloaddition (CuAAC) “click” chemistry. The properties of the resulting AEMs were characterized. It

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12

Chen, Bing, Zhanhai Xiao, Yanhu Li, Lei Yu, Wei Yang та Jiwen Feng. "Bipolar π-conjugation interrupted host polymers by metal-free superacid-catalyzed polymerization for single-layer electrophosphorescent diodes". RSC Adv. 4, № 91 (2014): 50027–34. http://dx.doi.org/10.1039/c4ra06540a.

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13

Liu, Delong, Ying Zhang, Lingling Zhan, et al. "Design of wide-bandgap polymers with deeper ionization potential enables efficient ternary non-fullerene polymer solar cells with 13% efficiency." Journal of Materials Chemistry A 7, no. 23 (2019): 14153–62. http://dx.doi.org/10.1039/c9ta04237g.

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14

O’Harra, Kathryn E., Danielle M. Noll, Irshad Kammakakam, et al. "Designing Imidazolium Poly(amide-amide) and Poly(amide-imide) Ionenes and Their Interactions with Mono- and Tris(imidazolium) Ionic Liquids." Polymers 12, no. 6 (2020): 1254. http://dx.doi.org/10.3390/polym12061254.

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Here we introduce the synthesis and thermal properties of a series of sophisticated imidazolium ionenes with alternating amide-amide or amide-imide backbone functionality, and investigate the structural effects of mono(imidazolium) and unprecedented tris(imidazolium) ionic liquids (ILs) in these ionenes. The new set of poly(amide-amide) (PAA) and poly(amide-imide) (PAI) ionenes represent the intersection of conventional high-performance polymers with the ionene archetype–presenting polymers with alternating functional and ionic elements precisely sequenced along the backbone. The effects of po

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15

Ngo, An Thien, Pierre Karam, and Gonzalo Cosa. "Conjugated polyelectrolyte–lipid interactions: Opportunities in biosensing." Pure and Applied Chemistry 83, no. 1 (2010): 43–55. http://dx.doi.org/10.1351/pac-con-10-11-02.

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Fluorescent conjugated polyelectrolytes (CPEs) have attracted considerable interest over the past decade as novel materials for developing biosensing schemes and sensing devices for biomolecules. This interest stems from the exquisite polymer sensitivity to the presence of fluorescence quenchers, enabling amplified sensing of molecules of interest. Efficient energy transport along the polymer backbone is critical to their sensing capabilities. Considerable research efforts have thus gone into understanding and controlling energy transport along the polymer backbone. In particular, it has been

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16

Duan, Chunhui, Jacobus J. van Franeker, Martijn M. Wienk, and René A. J. Janssen. "High open circuit voltage polymer solar cells enabled by employing thiazoles in semiconducting polymers." Polymer Chemistry 7, no. 36 (2016): 5730–38. http://dx.doi.org/10.1039/c6py01083k.

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17

Kang, So-Huei, Junghoon Lee, Dahyeon Yoo, Byoung Hoon Lee, and Changduk Yang. "Dithienosilole-co-5-fluoro-2,1,3-benzothiadiazole-containing regioisomeric polymers for organic field-effect transistors." Journal of Materials Chemistry C 7, no. 28 (2019): 8522–26. http://dx.doi.org/10.1039/c9tc02414j.

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18

Chen, Yunxiang, and Fang Chen. "Fluorination effects on bithiophene unit in benzodithiophene-4,8-dione based D–A type alternating copolymers for highly efficient polymer solar cells." RSC Advances 12, no. 55 (2022): 36038–45. http://dx.doi.org/10.1039/d2ra05925h.

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19

Kim, Junho, Eui Hyun Suh, Kyumin Lee, et al. "Development of Alkylthiazole-Based Novel Thermoelectric Conjugated Polymers for Facile Organic Doping." Nanomaterials 13, no. 7 (2023): 1286. http://dx.doi.org/10.3390/nano13071286.

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In this study, we developed two novel conjugated polymers that can easily be doped with F4TCNQ organic dopants using a sequential doping method and then studied their organic thermoelectric (OTE) properties. In particular, to promote the intermolecular ordering of OTE polymers in the presence of the F4TCNQ dopant, alkylthiazole-based conjugated building blocks with highly planar backbone structures were synthesized and copolymerized. All polymers showed strong molecular ordering and edge-on orientation in the film state, even in the presence of the F4TCNQ organic dopant. Thus, the sequential d

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20

Kozanecka-Szmigiel, Anna, Ewa Schab-Balcerzak, Dariusz Szmigiel, and Jolanta Konieczkowska. "The unexpected photomechanical effect in glassy “T-type” azopolyimides." Journal of Materials Chemistry C 7, no. 14 (2019): 4032–37. http://dx.doi.org/10.1039/c8tc06518g.

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21

Ramey, Erin E., Elizabeth L. Whitman, Cole E. Buller, et al. "A Biodegradable, Polymer-Supported Oxygen Atom Transfer Reagent." Polymers 15, no. 9 (2023): 2052. http://dx.doi.org/10.3390/polym15092052.

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Biodegradable polymers are desirable to mitigate the environmental impact of plastic waste in the environment. Over the past several decades, the development of organocatalytic ring-opening polymerization (OROP) has made the synthesis of many new types of biodegradable polymers possible. In this research article, the first example of an oxygen atom transfer reagent pendant on a biodegradable polymer backbone is reported. The monomers for the polycarbonate backbone are sourced from the biodegradable 2,2-bis(hydroxymethyl) propionic acid molecule, and an iodoaryl group is installed pendant to th

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22

Osaka, Itaru. "(Invited) Design and Synthesis of π-Conjugated Polymers for High-Efficiency Organic Photovoltaics". ECS Meeting Abstracts MA2024-02, № 19 (2024): 1767. https://doi.org/10.1149/ma2024-02191767mtgabs.

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Bulk-heterojunction organic solar cells based on π-conjugated polymers as the p-type semiconductor (electron donor) have been intensively investigated in the last few decades since they can enable lightweight, flexible, semi-transparent, low-cost, and low-energy fabrication in contrast to the conventional silicon solar cells. While fullerene derivatives have been used as the n-type semiconductor (electron acceptor), which afford power conversion efficiencies of more than 10% when combined with a narrow-bandgap π-conjugated polymer, recently non-fullerene acceptors having low bandgap have been

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23

Liu, Meng, Lu Yin, Shuangshuang Zhang, Zhengbiao Zhang, Wei Zhang, and Xiulin Zhu. "Design and Synthesis of a Cyclic Double-Grafted Polymer Using Active Ester Chemistry and Click Chemistry via A “Grafting onto” Method." Polymers 11, no. 2 (2019): 240. http://dx.doi.org/10.3390/polym11020240.

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Combing active ester chemistry and click chemistry, a cyclic double-grafted polymer was successfully demonstrated via a “grafting onto” method. Using active ester chemistry as post-functionalized modification approach, cyclic backbone (c-P2) was synthesized by reacting propargyl amine with cyclic precursor (poly(pentafluorophenyl 4-vinylbenzoate), c-PPF4VB6.5k). Hydroxyl-containing polymer double-chain (l-PS-PhOH) was prepared by reacting azide-functionalized polystyrene (l-PSN3) with 3,5-bis(propynyloxy)phenyl methanol, and further modified by azide group to generate azide-containing polymer

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24

Li, Fei, Yuxiang Wang, Yuan Sheng, Guo Wei, Yixiang Cheng, and Chengjian Zhu. "CPL emission of chiral BINOL-based polymers via chiral transfer of the conjugated chain backbone structure." RSC Advances 5, no. 128 (2015): 105851–54. http://dx.doi.org/10.1039/c5ra23329a.

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Chiral BINOL-based polymers incorporating phenothiazine moieties can exhibit strong mirror image Cotton effects and emit green color CPL signals via effective chiral transfer of the conjugated polymer chain backbone.

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25

Wang, Deyin, Xiaohui Wen, Dong Zhang, and Jiajun Tang. "Dynamical and Structural Properties of Comb Long-Chain Branched Polymer in Shear Flow." International Journal of Molecular Sciences 23, no. 19 (2022): 11290. http://dx.doi.org/10.3390/ijms231911290.

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Using hybrid multi-particle collision dynamics (MPCD) and a molecular dynamics (MD) method, we investigate the effect of arms and shear flow on dynamical and structural properties of the comb long-chain branched (LCB) polymer with dense arms. Firstly, we analyze dynamical properties of the LCB polymer by tracking the temporal changes on the end-to-end distance of both backbones and arms as well as the orientations of the backbone in the flow-gradient plane. Simultaneously, the rotation and tumbling behaviors with stable frequencies are observed. In other words, the LCB polymer undergoes a proc

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26

Gao, Wenli, Rui Tang, Minghao Bai, et al. "Dynamic covalent polymer networks with mechanical and mechanoresponsive properties reinforced by strong hydrogen bonding." Polymer Chemistry 13, no. 15 (2022): 2173–77. http://dx.doi.org/10.1039/d2py00179a.

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Mechanoresponsive dynamic covalent networks were designed and synthesized by embedding radical mechanophores into the polymer backbone as crosslinkers. The mechanical properties and mechanoresponsiveness of the polymers were reinforced by hydrogen bonds.

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27

Mukherjee, Soma, William L. A. Brooks, Yuqiong Dai, and Brent S. Sumerlin. "Doubly-dynamic-covalent polymers composed of oxime and oxanorbornene links." Polymer Chemistry 7, no. 10 (2016): 1971–78. http://dx.doi.org/10.1039/c5py02046h.

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Two sets of reversible covalent linkages distributed in series along a polymer backbone were used to prepare a new class of doubly dynamic-covalent polymers capable of reversibly dissociatingviatwo distinct pathways.

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28

Yap, Jeaniffer E., Neil Mallo, Donald S. Thomas, Jonathon E. Beves, and Martina H. Stenzel. "Comparing photoswitching of acrylate or methacrylate polymers conjugated with donor–acceptor Stenhouse adducts." Polymer Chemistry 10, no. 47 (2019): 6515–22. http://dx.doi.org/10.1039/c9py01345h.

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Polymers with donor–acceptor Stenhouse adduct (DASA) groups were synthesized using RAFT methods to evaluate the effect of polymer length (20 vs. 100 DP units) and backbone rigidity (acrylate and methacrylate blocks).

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29

Zalewski, Karol, Zbigniew Chyłek, and Waldemar A. Trzciński. "A Review of Polysiloxanes in Terms of Their Application in Explosives." Polymers 13, no. 7 (2021): 1080. http://dx.doi.org/10.3390/polym13071080.

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Polysiloxanes are reviewed for their properties depending on the functionalization of a silicon–oxygen backbone chain. Next, the properties were referred to the requirements that polymers used in plastic/polymer-bonded explosive (PBX)-type explosives must meet. Finally, the current state and prospects for the implementation of polysiloxanes in plastic/polymer-bonded explosive (PBX) formulations are presented.

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30

Vũ, Nam Đức, Aurélie Boulegue-Mondière, Nicolas Durand, et al. "Gallium-catalyzed recycling of silicone waste with boron trichloride to yield key chlorosilanes." Science 388, no. 6745 (2025): 392–400. https://doi.org/10.1126/science.adv0919.

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Chemical recycling to monomers is a key strategy for a sustainable circular polymer economy. However, most efforts have focused on polymers with carbon backbones. Recycling of silicone polymers and corresponding materials, featuring a robust inorganic backbone and tunable properties, remains in its infancy. We present a general method for depolymerization of a very wide range of silicone-based materials and postconsumer waste, including end-of-life cross-linked polydimethylsiloxane-based networks within formulated materials. The reaction proceeds at 40°C, harnessing an efficient gallium cataly

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31

Maehara, Takayuki, Hiroshi Hashimoto, and Joji Ohshita. "Synthesis and Heat Resistance of Arylenedioxy-organosilanylene Polymers with Adamantane Units." Zeitschrift für Naturforschung B 64, no. 11-12 (2009): 1567–70. http://dx.doi.org/10.1515/znb-2009-11-1241.

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Arylenedioxy-organosilanylene polymers with adamantane units in the backbone were prepared by Rh-catalyzed dehydrocoupling of bis(4-hydroxyphenyl)adamantanes with organohydrosilanes, and their heat resistance was evaluated by thermogravimetric analysis in nitrogen. Among these polymers, the highest Td10 (10% weight loss temperature) of 547 °C was achieved for polymer 2a prepared from 1,3-bis(4-hydroxyphenyl)adamantane and phenylsilane. Polymer 2a exhibited good heat resistance even in air with Td10 = 387 °C, and standing of the polymer at 150 °C for 8 h resulted in no evident weight loss

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32

Greco, Jeffrey F., and Patricia A. Bianconi. "A carbon network backbone polymer functionalized with polymer brushes." Polymer Journal 42, no. 4 (2010): 298–303. http://dx.doi.org/10.1038/pj.2009.343.

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33

Li, Fei, Yuxiang Wang, Ziyu Wang, Yixiang Cheng, and Chengjian Zhu. "Red colored CPL emission of chiral 1,2-DACH-based polymers via chiral transfer of the conjugated chain backbone structure." Polymer Chemistry 6, no. 38 (2015): 6802–5. http://dx.doi.org/10.1039/c5py01148e.

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Chiral polymers incorporating a chiral 1,2-DACH moiety and BODIPY can exhibit strong mirror image Cotton effects and emit red colored CPL signals via the effective chiral transfer of the conjugated polymer chain backbone.

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34

Ghosh, Malay. "New Polymer Synthesis: Polymers Possessing Diiminosulfoxide Functionality in the Backbone." Journal of Macromolecular Science: Part A - Chemistry 27, no. 2 (1990): 137–47. http://dx.doi.org/10.1080/00222339009351492.

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35

Ghosh, Malay. "New Polymer Synthesis: Polymers Possessing Diiminosulfoxide Functionality in the Backbone." Journal of Macromolecular Science, Part A 27, no. 2 (1990): 137–47. http://dx.doi.org/10.1080/10601329008544719.

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36

OKADA, S., and H. NAKANISHI. "RECENT PROGRESS IN POLYDIACETYLENE MATERIAL RESEARCH FOR NONLINEAR OPTICS." Journal of Nonlinear Optical Physics & Materials 03, no. 04 (1994): 501–9. http://dx.doi.org/10.1142/s0218199194000298.

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In order to enhance the third-order nonlinear optical susceptibilities (χ(3) s ) of polydiacetylenes, polydiacetylenes with π-conjugation between polymer backbone and acetylenic substituents were synthesized. In the case of hexatriyne monomer, solid-state polymerization proceeded via 1, 4-addition to give polydiacetylene with directly bound ethynyl substituents. Also 1, 4-addition polymerization took place in the case of octatetrayne and dodecahexayne monomers and gave polydiacetylenes with butadiynyl and octatetraynyl substituents, respectively. These butadiynyl and octatetraynyl moieties of

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37

Yin, Xiaodong, Yali Qiao, Matthew R. Gadinski, Qing Wang, and Chuanbing Tang. "Flexible thiophene polymers: a concerted macromolecular architecture for dielectrics." Polymer Chemistry 7, no. 17 (2016): 2929–33. http://dx.doi.org/10.1039/c6py00233a.

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Highly flexible and transparent free-standing films can be readily obtained from oligothiophene-containing norbornene polymers and their hydrogenated derivatives prepared by ROMP. The rigidness/softness of the polymer backbone and polar side chains dictate dielectric properties.

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38

Hou, Qiong, Lin Tao Hou, Jie Luo, Nai Yuan Li, Hong Zhu, and Guang Shi. "White and Red Electroluminescence from a Single Copolymers of Fluorene and 4-Thienyl-2,1,3-Benzothiadiazole." Advanced Materials Research 160-162 (November 2010): 762–67. http://dx.doi.org/10.4028/www.scientific.net/amr.160-162.762.

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We have developed efficient pure white- and red-light-emitting polymers through incorporating of low-band gap orange-light-emitting 4-thienyl-2,1,3-benzothiadiazole (BTT) moieties into the backbone of a blue-light-emitting poly(9,9-dioctylfluorene) (PFO). Partial or complete energy transfer from the blue electroluminescent PFO backbone to the orange- light-emitting unit occurred by carefully controlling the relative content of the low-band gap unit BTT in the resulting polymers. Pure white- and red-light electroluminescence from a single polymer has been obtained in a device with a configurati

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39

Jeong, WonJo, Kyumin Lee, Jaeyoung Jang, and In Hwan Jung. "Development of Benzobisoxazole-Based Novel Conjugated Polymers for Organic Thin-Film Transistors." Polymers 15, no. 5 (2023): 1156. http://dx.doi.org/10.3390/polym15051156.

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Benzo[1,2-d:4,5-d′]bis(oxazole) (BBO) is a heterocyclic aromatic ring composed of one benzene ring and two oxazole rings, which has unique advantages on the facile synthesis without any column chromatography purification, high solubility on the common organic solvents and planar fused aromatic ring structure. However, BBO conjugated building block has rarely been used to develop conjugated polymers for organic thin film transistors (OTFTs). Three BBO-based monomers, BBO without π-spacer, BBO with non-alkylated thiophene π-spacer and BBO with alkylated thiophene π-spacer, were newly synthesized

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40

Klinpituksa, Pairote, Anont Chaisuriyathepkul, Pranee Phinyocheep, Charoen Nakason, and Sumet Kittipoom. "Synthesis of acrylated styrene-isoprene-styrene copolymer." e-Polymers 8, no. 1 (2008). http://dx.doi.org/10.1515/epoly.2008.8.1.1627.

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AbstractVulcanization of polymer by ultraviolet irradiation has been playing an important role in the industrial sector especially for coating, ink and printing applications. Polymers used in this area are sensitive to ultraviolet (UV) radiation. Their final products have properties required for particular specifications. One of the methods to synthesize ultraviolet-sensitive polymers is the grafting of ultraviolet-sensitive units onto other polymer backbones. In this work, styreneisoprene- styrene copolymer (SIS) was selected as a polymer backbone whilst acrylic acid served as an ultraviolet

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41

Li, Zhuang, Xiaohui Zhang, Yajun Zhao, and Shan Tang. "Mechanochemical Backbone Editing for Controlled Degradation of Vinyl Polymers." Angewandte Chemie, May 27, 2024. http://dx.doi.org/10.1002/ange.202408225.

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The chemically inert nature of fully saturated hydrocarbon backbones endows vinyl polymers with desirable durability, but it also leads to their significant environmental persistence. Enhancing the sustainability of these materials requires a pivotal yet challenging shift: transforming the inert backbone into one that is degradable. Here, we present a versatile platform for mechanochemically editing the fully saturated backbone of vinyl polymers towards degradable polymer chains by integrating cyclobutene‐fused succinimide (CBS) units along backbone through photo‐iniferter reversible addition‐

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42

Li, Zhuang, Xiaohui Zhang, Yajun Zhao, and Shan Tang. "Mechanochemical Backbone Editing for Controlled Degradation of Vinyl Polymers." Angewandte Chemie International Edition, May 27, 2024. http://dx.doi.org/10.1002/anie.202408225.

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The chemically inert nature of fully saturated hydrocarbon backbones endows vinyl polymers with desirable durability, but it also leads to their significant environmental persistence. Enhancing the sustainability of these materials requires a pivotal yet challenging shift: transforming the inert backbone into one that is degradable. Here, we present a versatile platform for mechanochemically editing the fully saturated backbone of vinyl polymers towards degradable polymer chains by integrating cyclobutene‐fused succinimide (CBS) units along backbone through photo‐iniferter reversible addition‐

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43

Takada, Kenji, Miyu Ito, Naoya Fukui, and Hiroshi Nishihara. "Modulation between capacitor and conductor for a redox-active 2D bis(terpyridine)cobalt(II) nanosheet via anion-exchange." Communications Chemistry 7, no. 1 (2024). http://dx.doi.org/10.1038/s42004-024-01274-4.

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AbstractIonic polymers are intriguing materials whose functionality arises from the synergy between ionic polymer backbones and counterions. A key method for enhancing their functionality is the post-synthetic ion-exchange reaction, which is instrumental in improving the chemical and physical properties of polymer backbones and introducing of the functionalities of the counterions. Electronic interaction between host polymer backbone and guest ions plays pivotal roles in property modulation. The current study highlights the modulation of responses to external electric field in cationic bis(ter

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44

Meng, Zhihao, Fan Sun, Tianyang Wang, Jun Jin, Xiaohui Jia, and Yonggang Zhen. "Anthracene‐based polymers containing two similar units bithophene and cyclopentadithiophene but with distinctly different charge transport characteristics." Chemistry – An Asian Journal, February 10, 2025. https://doi.org/10.1002/asia.202401343.

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Anthracenes have become a rising star in organic semiconducting materials owing to the high stability and superior mobility. In spite of solution processability for large area fabrication, anthracene‐based polymers lag far behind small‐molecule counterparts in terms of molecular diversity and carrier mobility. Herein, we synthesized two anthracene‐based polymers via Stille reaction by incorporation of two structurally similar units bithophene and cyclopentadithiophene. Anthracene‐bithophene alternating polymer (PAnBT) polymer was calculated to take a twisted backbone conformation, showing very

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45

Battaglia, Alicia M., Eloi Grignon, Jiang Tian Liu, and Dwight S. Seferos. "Mussel‐Inspired Polymer Binders for Organic Electrodes." Small, August 14, 2024. http://dx.doi.org/10.1002/smll.202405118.

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AbstractThe development of polymer binders is necessary to meet the growing demands of modern energy storage technologies. While catechol‐containing materials are proven successful in silicon anodes, their application in organic batteries remains unexplored. In this contribution, the synthesis of four polymers are described with nearly identical side chain composition but varying backbone structures. The materials are used to investigate the effect of polymer backbone structure on the binding abilities of catechol‐containing materials. Comparative analysis with the commonly used polyvinylidene

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46

Watanabe, Y., та N. Koide. "Synthesis and Physical Properties of π -Conjugated Polymers Containing Mesogenic Group". MRS Proceedings 425 (1996). http://dx.doi.org/10.1557/proc-425-79.

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AbstractNovel side chain type liquid crystalline polymers, polythiophene and poly(aryleneethynylene) [PAE], containing a mesogenic group in the side chain were synthesized. Polythiophene derivatives were obtained by dehalogenative polycondensation with zero-valence nickel complex under mild condition. PAE type polymers were obtained by coupling dihalo aromatic compound with diethynyl aromatic compound. Their thermal properties were examined by differential scanning calorimetry, optical microscopy and X-ray diffractometry. All polymers exhibited a smectic or nematic mesophase depending upon the

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47

Yu, Hang, Adam Marks, Sachetan M. Tuladhar, et al. "The Influence of Alkyl Spacers and Molecular Weight on the Charge Transport and Storage Properties of Oxy‐Bithiophene‐Based Conjugated Polymers." Angewandte Chemie International Edition, December 23, 2024. https://doi.org/10.1002/anie.202417897.

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AbstractConjugated polymers (CPs) with polar side chains can conduct electronic and ionic charges simultaneously, making them promising for bioelectronics, electrocatalysis and energy storage. Recent work showed that adding alkyl spacers between CP backbones and polar side chains improved electronic charge carrier mobility, reduced swelling and enhanced stability, without compromising ion transport. However, how alkyl spacers impact polymer backbone conformation and, subsequently, electronic properties remain unclear. In this work, we design two oxy‐bithiophene‐based CP series, each featuring

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48

Yu, Hang, Adam Marks, Sachetan M. Tuladhar, et al. "The Influence of Alkyl Spacers and Molecular Weight on the Charge Transport and Storage Properties of Oxy‐Bithiophene‐Based Conjugated Polymers." Angewandte Chemie, December 23, 2024. https://doi.org/10.1002/ange.202417897.

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Abstract:

AbstractConjugated polymers (CPs) with polar side chains can conduct electronic and ionic charges simultaneously, making them promising for bioelectronics, electrocatalysis and energy storage. Recent work showed that adding alkyl spacers between CP backbones and polar side chains improved electronic charge carrier mobility, reduced swelling and enhanced stability, without compromising ion transport. However, how alkyl spacers impact polymer backbone conformation and, subsequently, electronic properties remain unclear. In this work, we design two oxy‐bithiophene‐based CP series, each featuring

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49

Palmans, Anja, Andrea Montali, Christoph Weder, and Paul Smith. "Photoluminescent Polymer Films for Display Applications." MRS Proceedings 558 (1999). http://dx.doi.org/10.1557/proc-558-293.

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ABSTRACTNovel poly(p-phenylene ethynylene) polymers, ANT-OPPE and COU-OPPE, have been prepared, in which anthracene and coumarin sensitizer molecules are covalently attached to the conjugated polymer backbone via a flexible spacer. These polymers show efficient energy transfer from the pendent sensitizer molecule to the PPE backbone, both in dilute solution as well as in an oriented polyethylene matrix. In case of ANT-OPPE, we found that the PPE backbone adapts the orientation of the matrix and is efficiently oriented, while the anthracene moiety remains essentially isotropic, resulting in a s

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50

Palmans, Anja, Andrea Montali, Christoph Weder, and Paul Smith. "Photoluminescent Polymer Films for Display Applications." MRS Proceedings 560 (1999). http://dx.doi.org/10.1557/proc-560-265.

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ABSTRACTNovel poly(ρ-phenylene ethynylene) polymers, ANT-OPPE and COU-OPPE, have been prepared, in which anthracene and coumarin sensitizer molecules are covalently attached to the conjugated polymer backbone via a flexible spacer. These polymers show efficient energy transfer from the pendent sensitizer molecule to the PPE backbone, both in dilute solution as well as in an oriented polyethylene matrix. In case of ANT-OPPE, we found that the PPE backbone adapts the orientation of the matrix and is efficiently oriented, while the anthracene moiety remains essentially isotropic, resulting in a s

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