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Dissertations / Theses on the topic 'Polymer supports'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 April 2022

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1

Pitfield, Ian David. "Perfluorocarbon chromatographic supports." Thesis, University of Cambridge, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.260381.

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2

Gooneratne, Samantha Indira. "Polymer supports for solid-phase organic chemistry reactors." Thesis, University of Cambridge, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.609539.

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3

Breed, Peter G. "Organic chemistry on highly functionalised supports." Thesis, University of Oxford, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.312151.

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4

Edwards, Christopher. "Phosphorus functionalised polymeric supports." Thesis, University of Warwick, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.342700.

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5

Ortiz-Acosta, Denisse. "Phase selectively soluble polymer supports to facilitate homogeneous catalysis." [College Station, Tex. : Texas A&M University, 2007. http://hdl.handle.net/1969.1/ETD-TAMU-2451.

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6

GRIFFIN, KAITLYN RENEE. "STRUCTURE AND FLUIDITY OF LIPID MEMBRANES ON POLYMER SUPPORTS." Thesis, The University of Arizona, 2016. http://hdl.handle.net/10150/612957.

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Cell membranes are composed primarily of amphipathic lipids either in a single circular layer or as a bilayer in which all of the hydrophilic and hydrophobic groups face the same direction respectively. Diffusion across a lipid membrane can occur spontaneously or be facilitated by integral membrane proteins. The extent of this diffusion relies on the structure of both the membrane and the diffusing species. Artificial lipid membranes that mimic some of the properties of natural cell membranes can be prepared on synthetic supports for use in membrane-based biosensors. We are working to develop

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7

Bartels, Carl. "Coronae of block copolymer micelles as supports for organometallic catalysis." Thesis, McGill University, 2003. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=82827.

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This thesis presents the results of several studies, the overall goal of which was the design and understanding of a block copolymer micelle in which the coronal chains act as a catalyst support for organometallic species. A model system consisting of reverse micelles of polystyrene-block -poly (sodium acrylate), PS-b-PANa, with coronal chain composed of ca. 210 styrene repeat units and a core radius of ca. 3.0 nm was used in the first study. The coronal chains were loaded to varying extents with Cr(CO)3 fragments in an effort to observe the effect of loading on the corona. The hydrodyn

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8

Worsdale, Matthew Clive. "Ab-initio investigation into catalyst supports for polymer electrolyte fuel cells." Thesis, University of Southampton, 2016. https://eprints.soton.ac.uk/413850/.

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One of the most promising families of catalyst support materials from the point of view of durability in the PEFC are metal oxides. SnO2 can only corrode, in a strong acid, at potentials ! 1.4V, progressing through surface hydroxide formation. The bulk stability is backed up by simulated potential cycling, with minimal ESCA loss at 1.6V. The conductivity of pure SnO2, which forms the rutile crystal structure, is very small compared to C but can increase by orders of magnitude with formation of certain intrinsic defects which create electron donor levels in the band gap (which, at 3.6 eV, class

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9

Mansor, N. B. "Development of catalysts and catalyst supports for polymer electrolyte fuel cells." Thesis, University College London (University of London), 2015. http://discovery.ucl.ac.uk/1460064/.

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Polymer Electrolyte Membrane fuel cells (PEMFC) are clean and efficient electrochemical energy converters that can be adapted to a wide range of domestic and automotive applications. However, large-scale commercialisation is hindered by issues of cost and durability relating to the catalyst layer. This work aims to address the need for cheaper and durable catalysts through the development of novel catalyst and catalyst support. The initial aim of this work is to investigate the potential application of Pd-based alloy catalyst in PEMFC. Pd is about 42% cheaper than Pt and 50 times more abundant

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10

Stranix, Brent R. "Functional polymers from (vinyl)polystyrene : solid-phase reagents, catalysts, supports and fluorescent sensors." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/tape16/PQDD_0006/NQ37028.pdf.

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11

Furyk, Steven Michael. "Studies of phase separable soluble polymers." Texas A&M University, 2003. http://hdl.handle.net/1969.1/3860.

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The technique of phase labeling has the ability to greatly enhance synthetic protocol by simplifying purification and increasing efficiency. Traditional insoluble supports offer efficient and simple recovery of the Âphase taggedÂ material but suffer from problems inherent to their heterogeneous nature. A solution to these problems has been to utilize phase separable soluble polymers in the design of ÂsmartÂ responsive systems that offer the option of homogenous reaction conditions with heterogeneous separation conditions. The subject of this dissertation focuses on the application of solub

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12

Fontaine, Laurent. "Acces aux polyesters phosphoriques supports de principes actifs : polymerisation par ouverture de cycle et modification chimique." Le Mans, 1988. http://www.theses.fr/1988LEMA1009.

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Etude de la preparation de polyesters phosphoriques hydrosolubles et potentiellement biodegradables par polymerisation par ouverture de cycle et par modification chimique de poly(hydrogenophosphonate alkylene)

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13

Coyle, Mhairi Henderson. "The single step purification and immobilisation of proteins on molecularly imprinted polymer supports." Thesis, University of Strathclyde, 2010. http://oleg.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=22625.

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The molecular imprinting of proteins is a highly appealing area of research since polymers that can bind selectively to proteins can be applied in a number of interesting fields, including affinity separation, chemical sensing and molecular diagnostics. Generally speaking, proteins are significantly more difficult to imprint than low molar mass templates due to their physical size, thermal instability and their tendency to denature in the solvents used typically in molecular imprinting protocols. However, this has not deterred research in this area. Previous protein imprinting reports include

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14

Hoang, Dinh Dien Vinh. "New PEG-based polymer supports for solid phase hybrid chemical and bio-syntheses." Thesis, University of Strathclyde, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.431836.

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15

Abrahams, Sara R. "Fibrin Polymer Formation Supports the Development of High Fat Diet Induced Obesity and Downstream Sequelae." University of Cincinnati / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1535636334953545.

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16

Dong, Hong. "Polymer fiber templates for the preparation of coaxial fibers and tubes, and as metal nanoparticle supports." Diss., Online access via UMI:, 2005.

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17

Costa, Maryline. "Synthèse de supports polymères et greffage de ferrocène pour une application en tant que batteries moléculaires." Thesis, Bordeaux 1, 2011. http://www.theses.fr/2011BOR14230/document.

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Des poly(styrène)s (PS) et poly(oxyde d'éthylène)s (PEO) d'architectures ramifiées et des particules semi-conductrices de poly(3,4-ethylènedioxythiophène)s (PEDOT) ont été synthétisés et utilisés comme supports pour le greffage de ferrocènes (Fc) en leur périphérie. Le greffage s’est effectué par cycloaddition de Huisgen dans le cas des PS et par estérification dans le cas des POE et des PEDOT. La mise en évidence d’une possible interaction entre la terminaison azoture des PS et le système catalytique employé pour la polymérisation radicalaire contrôlée a été faite dans ce travail. Les système

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18

Thorn, Zoe Elizabeth. "The development of novel polymers for use as substrates and supports in combinatorial chemistry." Thesis, Imperial College London, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.391809.

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19

Meszynska, Anna. "Iterative synthesis of sequence-defined polymers using solid and soluble supports." Thesis, Strasbourg, 2014. http://www.theses.fr/2014STRAF007/document.

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Dans ce travail, des méthodes itératives ont été étudiées afin de préparer des oligomères à séquences bien définies en utilisant des supports solides ou solubles. Trois stratégies de couplage de monomères ont été exploitées (i) AB + AB, (ii) AB + CD et (iii) AA + BB. La première méthode a permis la synthèse d’oligopeptides en utilisant les protocoles classiques de la synthèse peptidique à partir notamment d’amino-acides protégés par des groupements Fmoc. Les deux autres stratégies ont permis de préparer des oligo(alcoxyamine amide)s et des oligoamides, en l’absence de groupements protecteurs.

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20

Gill, Christopher Stephen. "Novel hybrid organic/inorganic single-sited catalysts and supports for fine chemical and pharmaceutical intermediate synthesis." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/28218.

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Thesis (M. S.)--Chemical Engineering, Georgia Institute of Technology, 2009.<br>Committee Chair: Jones, Christopher; Committee Member: Agrawal, Pradeep; Committee Member: Teja, Amyn; Committee Member: Weck, Marcus; Committee Member: Zhang, John.

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21

Chinnusamy, Tamilselvi [Verfasser], and Oliver [Akademischer Betreuer] Reiser. "Synthesis and immobilization of catalysts on polymer supports and its application in chemo- and enantioselective oxidation reactions / Tamilselvi Chinnusamy. Betreuer: Oliver Reiser." Regensburg : Universitätsbibliothek Regensburg, 2010. http://d-nb.info/1022819534/34.

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22

Chirowodza, Helen. "Polymer-clay nanocomposites prepared by RAFT-supported grafting." Thesis, Stellenbosch : Stellenbosch University, 2012. http://hdl.handle.net/10019.1/71914.

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Thesis (PhD)--Stellenbosch University, 2012.<br>ENGLISH ABSTRACT: In materials chemistry, surface-initiated reversible deactivation radical polymerisation (SI-RDRP) has emerged as one of the most versatile routes to synthesising inorganic/organic hybrid materials consisting of well-defined polymers. The resultant materials often exhibit a remarkable improvement in bulk material properties even after the addition of very small amounts of inorganic modifiers like clay. A novel cationic reversible addition–fragmentation chain transfer (RAFT) agent with the dual purpose of modifying the surface o

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23

Aydinlioglu, Esra. "Auto-assemblages à base de polypeptides sensibles au pH en tant que supports de délivrance de médicaments et de gènes." Thesis, Bordeaux, 2020. http://www.theses.fr/2020BORD0023.

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Cette thèse, nous avons conçu et synthétisé différents copolymères biocompatibles auto-assemblés par copolymérisation par ouverture de cycle (coROP) de trois différents N-hydroxycarboanhydride (NCA) d’alpha-aminoacides, avec du poly(oxyde d'éthylène) (POE-NH2) comme macro-amorceur, formant un bloc hydrophile. Différents degrés de polymérisation du POE ont été utilisés (DP=17,46,114), et la composition du bloc copolypeptidique amphiphile a été ajustée par coROP de l'acide L-glutamique anionique ou de la L-lysine cationique, qui apportent une charge dépendante du pH, et du comonomère L-phénylala

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24

Sommer, William J. "Supported catalysts, from polymers to gold nanoparticles supports." Diss., Available online, Georgia Institute of Technology, 2007, 2007. http://etd.gatech.edu/theses/available/etd-07062007-225935/.

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Thesis (Ph. D.)--Chemistry and Biochemistry, Georgia Institute of Technology, 2008.<br>Christoph J. Fahrni, Committee Member ; Mostapha A. El-Sayed, Committee Member ; Christopher W. Jones, Committee Member ; Marcus Weck, Committee Chair ; E. Kent Barefield, Committee Member.

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25

Yin, Hongfeng. "New methods in synthesis of cyclic oligoesters and cyclodepsipeptides." Columbus, Ohio : Ohio State University, 2006. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1158668617.

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26

Petroffe, Gwendoline. "Contrôle Thermique actif des Satellites par des Dispositifs auto-supportés à matériaux électroactifs organiques." Thesis, Cergy-Pontoise, 2018. http://www.theses.fr/2018CERG0996.

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L’objectif de cette thèse était de réaliser de nouveaux matériaux à émissivité variable dans l’infrarouge pour une application de régulation thermique des satellites artificiels. Dans ce contexte, l’étude s’est concentrée sur l’élaboration et la caractérisation de dispositifs électroémissifs à base d’un polymère conducteur électronique, le poly(3,4-éthylènedioxythiophène) (PEDOT) obtenu par électropolymérisation. Ces dispositifs électroémissifs ont ensuite été évalués dans des conditions partiellement représentatives de l’environnement spatial.La première partie de ce manuscrit a été consacrée

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27

Pickard, Simeon. "The Vapor-Phase Dehydrogenation of Ethylbenzene Using Polymeric & Polymer-Supported Quinones." TopSCHOLAR®, 1986. https://digitalcommons.wku.edu/theses/2710.

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Polymer-supported and polymeric quinones were synthesized and evaluated in their ability to dehydrogenate ethylbenzene in the vapor phase. The polymeric quinones were found to be more useful agents for dehydrogenation than the polymer-supported quinones, probably due to the higher concentration of quinone per given mass of polymer. The factors that affected the yield of styrene using the polymeric quinone were the nature of the polymer, the space velocity in the column, and the reaction temperature. The space velocity was evaluated by holding constant the flow rate of the carrier gas and varyi

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28

Savych, Maciejasz Juliia. "Synthèse et caractérisation de nanocomposites platine/nanofibres pour électrodes de pile à combustible à électrolyte polymère." Thesis, Montpellier 2, 2014. http://www.theses.fr/2014MON20152/document.

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Cette thèse s'inscrit dans le contexte général des efforts de recherche pour développer des supports de catalyseur résistant à la corrosion qui peuvent potentiellement remplacer le carbone dans les piles à combustible à électrolyte polymère. Des nanofibres et des nanotubes à base de TiO2 et SnO2 dopés par Nb ont été préparés par filage électrostatique et caractérisés par diffraction des rayons X, spectroscopie des photoélectrons de rayons X, spectroscopie Raman, mesures de surface spécifique et de conductivité électronique. Les nanofibres de TiO2 et SnO2 dopées par Nb présentent une conductivi

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29

Zwaneveld, Nikolas Anton Amadeus Chemical Engineering &amp Industrial Chemistry UNSW. "Surface grafting of polymers via living radical polymerization techniques; polymeric supports for combinatorial chemistry." Awarded by:University of New South Wales. Chemical Engineering and Industrial Chemistry, 2006. http://handle.unsw.edu.au/1959.4/33361.

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The use of living radical polymerization methods has shown significant potential to control grafting of polymers from inert polymeric substrates. The objective of this thesis is to create advanced substrates for use in combinatorial chemistry applications through the use of g-radiation as a radical source, and the use of RAFT, ATRP and RATRP living radical techniques to control grafting polymerization. The substrates grafted were polypropylene SynPhase lanterns from Mimotopes and are intended to be used as supports for combinatorial chemistry. ATRP was used to graft polymers to SynPhase lante

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30

Mortimer, Duncan A. B. "Polymer supported chiral auxiliaries." Thesis, University of Oxford, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270665.

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31

Pan, Lin. "Electrospinning of Spring Supported Tubular Nanofiber Media and Its Application." University of Akron / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=akron157359914742377.

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32

Pollock, Catherine M. "Protodestannylation of polymer-supported arylstannanes." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/tape16/PQDD_0020/MQ28638.pdf.

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33

Innocent, Christophe. "Immobilisation de biomolécules dans des polypyrroles fonctionnalisés : application à l'électroanalyse." Université Joseph Fourier (Grenoble ; 1971-2015), 1995. http://www.theses.fr/1995GRE10152.

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L'utilisation de monomeres pyrroliques fonctionnalises electropolymerisables afin d'immobiliser des biomolecules (enzymes, metabolites) a conduit a la creation de nouveaux biomateriaux d'electrode. Les proprietes d'echange d'anions des films de poly(pyrrole ammonium) et poly(pyrroles viologene) ont ete utilisees pour l'immobilisation et l'activation electrochimiques d'un coenzyme ainsi que pour l'incorporation et la liberation electrochimiquement controlee d'adenosine triphosphate et d'acide 3 ;4 dihydroxyphenylacetique. Une nouvelle technique d'immobilisation d'enzymes a partir de monomeres p

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34

Yang, Die Daisy. "Development of polymers for electroplating waste water purification, polymer-supported reagents for organic synthesis and heterogeneous catalysts for aerobic alcohol oxidation reactions." Click to view the E-thesis via HKUTO, 2008. http://sunzi.lib.hku.hk/hkuto/record/B39848887.

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35

Lemée, Frédéric. "Composés polyioniques contraints bioactifs libres et supportés : accès à de nouveaux matériaux antibactériens." Thesis, Université de Lorraine, 2015. http://www.theses.fr/2015LORR0047/document.

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La mise au point de nouveaux matériaux possédant des propriétés antibactériennes est un sujet intéressant le monde médical et environnemental. Pour cela, les polymères commerciaux de Merrifield et de Wang-benzaldéhyde ont été modifiés par greffage de motifs calixarèniques polycationiques antibactériens inspirés des travaux du laboratoire et désignés pour interagir avec la surface bactérienne chargée négativement. Ces calixarènes ont été modifiés sur la partie basse, de façon contrôlée, par incorporation d'un groupe espaceur fonctionnel permettant d'accéder à un greffage ciblé du polymère. Nous

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36

Lecarpentier, Patrick. "Polymer-supported reducing and oxidising reagents." Thesis, University of Southampton, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.548260.

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37

Choi, Kwok-wai Matthew, and 蔡國偉. "Development of new polymer supported reagents." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2003. http://hub.hku.hk/bib/B29230524.

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38

Lindsay, D. "Polymer-supported ligands for hydrometallurgical applications." Thesis, University of Strathclyde, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.381352.

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39

Wambua, Pasco M. "Chemistry of Magnesium and Zinc Complexes Supported by Bulky Ancillary Ligands and their Applications in the Ring-Opening Polymerization Studies of Cyclic Esters." The Ohio State University, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=osu1406125367.

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40

Yang, Die Daisy, and 楊蝶. "Development of polymers for electroplating waste water purification, polymer-supported reagents for organic synthesis and heterogeneouscatalysts for aerobic alcohol oxidation reactions." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2008. http://hub.hku.hk/bib/B39848887.

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41

Mouflou, Zoubida. "Reseaux polymeres hydrophiles : synthese et application en chromatographie d'exclusion sterique en milieu aqueux." Université Louis Pasteur (Strasbourg) (1971-2008), 1987. http://www.theses.fr/1987STR13150.

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Polymeres tridimensionnels non ioniques presentant une bonne tenue mecanique constitues par un squelette hydrophobe rigide reticule, dotes de greffons hydrophiles polyoxiranne. Broyage des gels et tamisage des grains

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42

Houghton, Mark Phillip. "Polymer-supported reactions using ion-exchange resins." Thesis, Lancaster University, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.255343.

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43

Sechi, Gianluca. "Synthesis and applications of polymer supported peracids." Thesis, University of Edinburgh, 2009. http://hdl.handle.net/1842/11906.

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In recent years, polymer-assisted solution-phase synthesis has become a prevalent method because of its various advantages over conventional solution-phase chemistry, such as the ease of separation of the supported species from a reaction mixture by filtration and washing, the opportunity to use an excess of the reagent to force the reaction to completion, and the adaptability to continuous-flow processes. Peroxycarboxylic acids are common oxidants in a wide range of chemical transformations, but their use is often limited because of the associated handling risks. Some relatively stable peraci

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44

Santry, B. A. "Preparation and applications of polymer-supported dioxiranes." Thesis, Queen's University Belfast, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.396568.

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45

Maddocks, Suzanne. "Novel polymer supported reagents for asymmetric catalysis." Thesis, Loughborough University, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.274897.

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46

Sung, Shayna D. "Phase selectively soluble polymers for homogeneously supported catalysts." Texas A&M University, 2006. http://hdl.handle.net/1969.1/4312.

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Soluble polymer supports that could be used in thermomorphic and latent biphasic systems have been prepared and analyzed for their potential application as supports for facilitated synthesis and catalysis. Phase selective solubilities were evaluated using polymers tagged with either visible dyes or fluorescent probes. Heptane/DMF, heptane/90% ethanol-water, heptane/ethyl acetate, heptane/ ethanol and heptane/tert-butanol solvent mixtures were all studied as examples of thermomorphic or latent biphasic systems. A range of polymers, including poly-(tert-butylstyrene) (PTBS), poly(alkylsiloxanes)

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47

Wambua, Pasco M. "Synthesis and Characterization of Monomeric Magnesium and Zinc complexes supported by 1,5,9-Trimesityldipyrromethene for use in polymerization studies." The Ohio State University, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=osu1308265029.

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48

Mynett, Donna Maria. "New methods for organic synthesis on solid supports." Thesis, University of Cambridge, 1995. https://www.repository.cam.ac.uk/handle/1810/271988.

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49

Moore, Martin. "New Dipolar Cycloaddition reactions of a Carbohydrate-derived Vinyl Sulfoxide Alkyne Equivalent and a Polymer-supported Alkyne with Azides." Connect to online version at OhioLINK ETD Connect to online version at Digital.Maag, 1998. http://hdl.handle.net/1989/4782.

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50

Atwal, Upinder S. "Novel polymers for artificial liver support systems." Thesis, Aston University, 1985. http://publications.aston.ac.uk/11727/.

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