Academic literature on the topic 'Polymeric isocyanate resin'

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Journal articles on the topic "Polymeric isocyanate resin"

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Buckley, C. J., C. Phanopoulos, N. Khaleque, A. Engelen, M. E. J. Holwill, and A. G. Michette. "Examination of the Penetration of Polymeric Methylene Di-Phenyl-Di-Isocyanate (pMDI) into Wood Structure Using Chemical-State X-Ray Microscopy." Holzforschung 56, no. 2 (2002): 215–22. http://dx.doi.org/10.1515/hf.2002.035.

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Summary The penetration behaviour of isocyanate-based wood resins was evaluated using x-ray microscopy. Aspen wood pieces were bonded together in a controlled manner. These were embedded in a methacrylate-based resinand thin sections were prepared, cut from the transverse face of thewoodcomposite. X-ray images of these sections were prepared at several selected x-ray energies to allow the isocyanate, cellulose, lignin and the embedding agent distributions to be mapped. The isocyanate resin was found to penetrate deeply into the wood. The resin enters large cell lumen, and wicks along the inner
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Asafu-Adjaye, Osei, Brian Via, and Sujit Banerjee. "Increasing Cold Tack of Polymeric Methylene Diphenyl Diisocyanate Resin with Partial Soy Flour Substitution." Forest Products Journal 70, no. 1 (2020): 143–44. http://dx.doi.org/10.13073/fpj-d-19-00049.

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Abstract Partial substitution of polymeric methylene diphenyl diisocyanate resin with soy flour increases the cold tack of the resin to the level achieved by urea formaldehyde resin. The tack can be fine-tuned by adjusting the amount of soy flour added. The increase in tack is caused by the reaction of the isocyanate resin with the water contained in soy flour, as well as with hydroxyl and other groups present in soy flour components. The higher cold tack should increase the stability of pre-press mats, especially in particleboard manufacturing.
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Gruver, T. Michael, and Nicole R. Brown. "Penetration and performance of isocyanate wood binders on selected wood species." BioResources 1, no. 2 (2006): 233–47. http://dx.doi.org/10.15376/biores.1.2.233-247.

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The penetration and performance of polymeric diphenylmethane diisocyanate (pMDI) wood binder was investigated according to three factors: substrate species (aspen, yellow-poplar, or southern yellow pine); anatomical bonding plane (radial or tangential); and moisture content (0%, 5%, or 12%). Compression shear block tests and fluorescence microscopy were used to examine bond performance and resin penetration. Statistically, each of the aforementioned factors impacted results. As moisture content increased, observed bond strengths and wood failure increased. Bond formation did not occur when the
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Wu, Guomin, Xinhao Feng, Can Jin, Zhenwu Kong, and Siqun Wang. "Effect of lignin-containing cellulose nanofibrils on the curing kinetics of polymeric diphenylmethane diisocyanate (PMDI) resin." Holzforschung 73, no. 9 (2019): 879–87. http://dx.doi.org/10.1515/hf-2018-0253.

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Abstract In order to increase the curing rate of polymeric diphenylmethane diisocyanate (PMDI) resin, different contents of lignin-containing cellulose nanofibrils (L-CNFs) were blended into the PMDI. Differential scanning calorimetry (DSC) was used to examine how the addition of L-CNFs influences the curing kinetics of PMDI resin. The activation energy (Ea) of the curing reaction of PMDI/L-CNF systems was calculated using the Kissinger, Friedman and Flynn-Wall-Ozawa model-free methods. The results showed that Ea values calculated by the aforementioned three methods varied in a similar trend w
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Zhu, Li Bin, Bo Han, Ji You Gu, Yan Hua Zhang, Hai Yan Tan, and Ying Feng Zuo. "Preparation of Water-Resistance Plywood with UF Resin Modified by Emulsifiable Polyisocyanate." Applied Mechanics and Materials 26-28 (June 2010): 1056–60. http://dx.doi.org/10.4028/www.scientific.net/amm.26-28.1056.

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The purpose of the study was to manufacture water-resistance plywood with using UF resin modified by emulsifiable polyisocyanate. The emulsifiable polyisocyanate which contains plenty of hydrophilic segments and teminal isocyanate groups were synthesized by reaction between various kinds of polyether polyols and polymeric methane dipthenyl diisocyanate (pMDI). A type of composite adhesive was obtained from the mixture of emulsifiable polyisocyanate and urea formaldehyde resin. The process parameters, such as the molar ratio of –NCO and –OH, mass fraction of emulsifiable polyisocyanate in UF re
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Barreto, Maria I. M., Victor De Araujo, Juliana Cortez-Barbosa, André L. Christoforo, and Jorge D. M. Moura. "Structural performance analysis of cross-laminated timber-bamboo (CLTB)." BioResources 14, no. 3 (2019): 5045–58. http://dx.doi.org/10.15376/biores.14.3.5045-5058.

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Construction systems based on cross-laminated timber (CLT) have versatility in material development and are an interesting alternative for construction. This study evaluated the structural performance of cross-laminated timber-bamboo produced from wood (Pinus spp.) and bamboo (Dendrocalamus giganteus). Panels were produced by strips (wood and bamboo) assorted, under non-destructive structural grading, to support a better panel configuration. Small-length pine pieces were also included in the study, considering their low added-value and underutilization in sawmills from Telêmaco Borba, Brazil.
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Aristri, Manggar Arum, Muhammad Adly Rahandi Lubis, Sumit Manohar Yadav, et al. "Recent Developments in Lignin- and Tannin-Based Non-Isocyanate Polyurethane Resins for Wood Adhesives—A Review." Applied Sciences 11, no. 9 (2021): 4242. http://dx.doi.org/10.3390/app11094242.

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This review article aims to summarize the potential of using renewable natural resources, such as lignin and tannin, in the preparation of NIPUs for wood adhesives. Polyurethanes (PUs) are extremely versatile polymeric materials, which have been widely used in numerous applications, e.g., packaging, footwear, construction, the automotive industry, the lighting industry, insulation panels, bedding, furniture, metallurgy, sealants, coatings, foams, and wood adhesives. The isocyanate-based PUs exhibit strong adhesion properties, excellent flexibility, and durability, but they lack renewability. T
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Lattimer, M. B., C. D. Weber, and Z. R. Hardt. "An Improved Adhesive System for Textile-Reinforced Rubber Products." Rubber Chemistry and Technology 58, no. 2 (1985): 383–91. http://dx.doi.org/10.5254/1.3536072.

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Abstract Resorcinol Formaldehyde Latex (RFL) adhesive systems have been used for over forty years to bond synthetic fibers to rubber compounds. The original RFL formulation was developed by Charch and Maney. The adhesive was applied primarily to rayon fibers and later extended to nylon and glass fibers. At the same time, the formulation evolved with the introduction of synthetic latexes and preformed resorcinol formaldehyde resin solutions. The RFL treated fibers are used to reinforce rubber products (e.g., tires, conveyor belts, hoses, V-belts). With the commercialization of polyester fibers,
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Pachha, R. R., J. R. Thakkar, and R. D. Patel. "Studies of vinyl ester resins and their urethanized derivatives." High Performance Polymers 5, no. 3 (1993): 207–12. http://dx.doi.org/10.1088/0954-0083/5/3/004.

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The epoxy resins diglycidyl ether of bisphenol A and triglycidyl p-amino phenol were reacted with acrylic acid to afford the corresponding acrylated resins. These vinyl ester resins were then reacted with toluene di-isocyanate to procure their urethanized derivatives. All these resins were characterized by their viscosity, number average molecular weight and infrared spectrophotometry. Curingconditions for these resins were established by differential scanning calorimetry. The results indicated that the curing reaction follows first-order kinetics, with activation energy in the range 53-84 kJ
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Jorda, Johannes, Günther Kain, Marius-Catalin Barbu, Alexander Petutschnigg, and Pavel Král. "Influence of Adhesive Systems on the Mechanical and Physical Properties of Flax Fiber Reinforced Beech Plywood." Polymers 13, no. 18 (2021): 3086. http://dx.doi.org/10.3390/polym13183086.

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In order to improve the acceptance of broader industrial application of flax fiber reinforced beech (Fagus sylvatica L.) plywood, five different industrial applicated adhesive systems were tested. Epoxy resin, urea-formaldehyde, melamine-urea formaldehyde, isocyanate MDI prepolymer, and polyurethane displayed a divergent picture in improving the mechanical properties—modulus of elasticity, modulus of rupture, tensile strength, shear strength and screw withdrawal resistance—of flax fiber-reinforced plywood. Epoxy resin is well suited for flax fiber reinforcement, whereas urea-formaldehyde, mela
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Dissertations / Theses on the topic "Polymeric isocyanate resin"

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Das, Sudipto. "Wood/Polymeric Isocyanate Resin Interactions: Species dependence." Diss., Virginia Tech, 2005. http://hdl.handle.net/10919/28745.

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The performance of polymeric diphenylmethane diisocyanate (PMDI) resin is known to be highly dependent on the wood species. This species dependence may be due to differences in: cure chemistry, interphase morphology, or both of these factors. This study addresses aspects of the cure chemistry and interphase morphology of wood/PMDI bondlines; specifically these effects are compared using two woods: yellow-poplar and southern pine. In this study, the cure chemistry of wood-PMDI system was analyzed with solid state NMR (SSNMR) using wood samples cured with doubly labeled (15N,13C) PMDI resin. Th
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Lee, Yvonne Siew Keng. "The isocyanate cured epoxy resins - isocyanurate-oxazolidone polymers." Thesis, Brunel University, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.328875.

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Book chapters on the topic "Polymeric isocyanate resin"

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Gooch, Jan W. "Isocyanate Resins." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_6504.

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Rasmussen, Jerald K., Steven M. Heilmann, Larry R. Krepski, and Howell K. Smith. "Functional, Telechelic Polymers Derived from Reactions of Nucleophilic Oligomers and Alkenyl Azlactones, Part II: Multiazlactones-Alternatives to Isocyanate and Epoxy Resins?" In Advances in Polymer Synthesis. Springer US, 1985. http://dx.doi.org/10.1007/978-1-4613-2121-7_11.

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"Isocyanate resins." In Encyclopedic Dictionary of Polymers. Springer New York, 2007. http://dx.doi.org/10.1007/978-0-387-30160-0_6399.

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Taber, Douglass F. "Carbon-Carbon Bond Formation." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0025.

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Akiya Ogawa of Osaka Prefecture University found (Tetrahedron Lett. 2010, 51, 6580) that the Sm-mediated reductive coupling of a halide 1 with CO2 to give the carboxylic acid 2 was strongly promoted by visible light. Gregory C. Fu of MIT designed (Angew. Chem. Int. Ed. 2010, 49, 6676) a Ni catalyst for the coupling of a primary borane 4 with a secondary alkyl halide 3. James P. Morken of Boston College devised (Org. Lett. 2010, 12, 3760) conditions for the carbonylative conjugate addition of a dialkyl zinc to an enone 6 to give the 1,4-dicarbonyl product 7. Louis Fensterbank of the Institut Parisien de Chimie Moléculaire developed (Angew. Chem. Int. Ed. 2010, 49, 8721; not illustrated) a protocol for the conjugate addition of alkyl boranes to enones. Hyunik Shin of LG Life Science, Daejeon, and Sang-gi Lee of Ewha Womans University showed (Tetrahedron Lett. 2010, 51, 6893) that the intermediate from Blaise homologation of a nitrile 8 was a powerful nucleophile, smoothly opening an epoxide 10 to deliver 11. Sébastien Reymond and Janine Cossy of ESPCI ParisTech found (J. Org. Chem. 2010, 75, 5151) that FeCl3 smoothly catalyzed the coupling of an alkenyl Grignard 13 with the primary iodide 12. The Ti-mediated coupling of an alkyne 16 with an allylic alkoxide 15 (J. Am. Chem. Soc. 2010, 132, 9576) developed by Glenn C. Micalizio of Scripps/Florida was the key step in the total synthesis (J. Am. Chem. Soc. 2010, 132, 11422) of lehualide B. Huanfeng Jiang of the South China University of Technology observed (Chem. Commun. 2010, 46, 8049) that KI added to a bromoalkyne 18 to give the dihalide 19 with high geometric control. Haruhiko Fuwa of Tohoku University improved (Org. Lett. 2010, 12, 5354) the selective hydroiodination of a methyl alkyne 20 to 21. Takuya Kurahashi and Seijiro Matsubara of Kyoto University devised (Chem. Commun. 2010, 46, 8055) the Ni-catalyzed three-component coupling of an alkyne 22, methyl acrylate 23, and phenyl isocyanate to give the doubly homologated lactam 24. Patrick H. Toy of the University of Hong Kong showed (Synlett 2010, 1997; Org. Lett. 2010, 12, 4996 for a polymer with covalently attached base) that resin-bound triphenylphosphine participated efficiently in the Wittig coupling of 26 with an aldehyde 25.
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Conference papers on the topic "Polymeric isocyanate resin"

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Edwards, Peter A., Michael Price, Nick Nimchuk, and Jeff Mahon. "Novel Water Loving Coatings (WLC) Lubricious and Durable Guidewires." In 2017 Design of Medical Devices Conference. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/dmd2017-3434.

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Hydrophilic coatings applied to guidewires or catheters, lower friction of the device thus improves handling and reduces damage to the vessel walls during access, delivery and retrieval. Peripheral guidewires typically consist of a polymer jacket, basecoat and topcoat. The polymer jacket is highly radiopaque for fluoroscopy visualization. Basecoat adheres to the polymer jacket and hydrophilic topcoat. Basecoat and topcoat play important roles towards coating device durability and lubricity. Water Loving Coatings (WLC) are the first developed 510(k) clearance guidewires utilizing epoxy polyuret
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McClung, Amber J. W., Joseph A. Shumaker, and Jeffery W. Baur. "Novel Bismaleimide-Based Shape Memory Polymers: Comparison to Commercial Shape Memory Polymers." In ASME 2011 Conference on Smart Materials, Adaptive Structures and Intelligent Systems. ASMEDC, 2011. http://dx.doi.org/10.1115/smasis2011-5044.

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A series of novel shape memory polymers, synthesized from 4-4-bismaleimidodiphenyl-methane, an extended chain aliphatic diamine, and a bis-isocyanate, have been created and characterized with the aim of providing a family of robust high temperature shape memory polymers with tailorable transition temperatures for use in reconfigurable aerospace structures. In the present study, three of the polymers are chosen for more detailed study of their thermomechanical properties. These materials are compared to commercial resins Veriflex® and Veriflex-E® which are styrene- and epoxy-based proprietary f
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