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Relevant bibliographies by topics / Polymerization Mechanism

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Academic literature on the topic 'Polymerization Mechanism'

Author: Grafiati

Published: 4 June 2021

Last updated: 4 February 2022

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Journal articles on the topic "Polymerization Mechanism"

1

Zhang, Xiaoqian, Wenli Guo, Yibo Wu, et al. "Cationic polymerization of p-methylstyrene in selected ionic liquids and polymerization mechanism." Polymer Chemistry 7, no. 32 (2016): 5099–112. http://dx.doi.org/10.1039/c6py00796a.

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Wen, Shao Guo, Shi Gao Song, Hong Bo Liu, Ji Hu Wang, Qian Xu, and Yan Shen. "Application of a Novel Initiator on Acrylic Emulsion Polymerization." Advanced Materials Research 233-235 (May 2011): 1415–18. http://dx.doi.org/10.4028/www.scientific.net/amr.233-235.1415.

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New initiator of FFM6 is used to initiate the acrylic emulsion polymerization. The influences of concentration of FFM6 (c[I]) and polymerization temperature (T) on polymerization reaction rate (Rp) were discussed. Rp is proportional to (c[I])1.4 which is different with classical emulsion polymerization whose Rp is proportion to (c[I])0.4, that indicate polymerization mechanism of the reaction in the study is different with classical mechanism. The value of Ea, 56.4 kJ/mol, is lower than the value of general radical polymerization’s Ea (80.0-96.0 kJ/mol), which indicates the FFM6 can initiate a

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Vanderhoff, John W. "Mechanism of emulsion polymerization." Journal of Polymer Science: Polymer Symposia 72, no. 1 (2007): 161–98. http://dx.doi.org/10.1002/polc.5070720121.

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Bauld, Nathan L., J. Todd Aplin, Wang Yueh, Haripada Sarker, and Dennis J. Bellville. "Cation Radical Polymerization. A Fundamentally New Polymerization Mechanism." Macromolecules 29, no. 10 (1996): 3661–62. http://dx.doi.org/10.1021/ma951694c.

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Zhang, Jinghan, Yibo Wu, Kaixuan Chen, et al. "Characteristics and Mechanism of Vinyl Ether Cationic Polymerization in Aqueous Media Initiated by Alcohol/B(C6F5)3/Et2O." Polymers 11, no. 3 (2019): 500. http://dx.doi.org/10.3390/polym11030500.

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Aqueous cationic polymerizations of vinyl ethers (isobutyl vinyl ether (IBVE), 2-chloroethyl vinyl ether (CEVE), and n-butyl vinyl ether (n-BVE)) were performed for the first time by a CumOH/B(C6F5)3/Et2O initiating system in an air atmosphere. The polymerization proceeded in a reproducible manner through the careful design of experimental conditions (adding initiator, co-solvents, and surfactant or decreasing the reaction temperature), and the polymerization characteristics were systematically tested and compared in the suspension and emulsion. The significant difference with traditional cati

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Buback, Michael, Wibke Meiser, and Philipp Vana. "Mechanism of CPDB-Mediated RAFT Polymerization of Methyl Methacrylate: Influence of Pressure and RAFT Agent Concentration." Australian Journal of Chemistry 62, no. 11 (2009): 1484. http://dx.doi.org/10.1071/ch09219.

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Reversible addition–fragmentation chain transfer (RAFT) polymerizations of methyl methacrylate (MMA) in bulk at 60°C were performed at five pressures up to 200 MPa using 2-(2′-cyanopropyl)dithiobenzoate (CPDB) as RAFT agent at concentrations between 1.5 × 10–3 and 2.0 × 10–2 mol L–1. Applying high pressure during polymerization increases the rate of polymerization, but no effect on polydispersity was observed. Molecular weight distributions and average molecular weights of the final polymer indicated the successful control of MMA polymerization even at low CPDB concentrations. The slight retar

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YAMAGO, Shigeru, and Yasuyuki NAKAMURA. "Living Radical Polymerization: 1. Polymerization Mechanism and Methods: 1." NIPPON GOMU KYOKAISHI 82, no. 3 (2009): 135–40. http://dx.doi.org/10.2324/gomu.82.135.

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YAMAGO, Shigeru, and Yasuyuki NAKAMURA. "Living Radical Polymerization: 2. Polymerization Mechanism and Methods: 2." NIPPON GOMU KYOKAISHI 82, no. 8 (2009): 363–69. http://dx.doi.org/10.2324/gomu.82.363.

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Rehor, A., N. Tirelli, and J. A. Hubbell. "A New Living Emulsion Polymerization Mechanism: Episulfide Anionic Polymerization." Macromolecules 35, no. 23 (2002): 8688–93. http://dx.doi.org/10.1021/ma0211378.

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Gozlan, A., and A. Zilkha. "Electrochemical polymerization of dicarboxylic acids—VI. Mechanism of polymerization." European Polymer Journal 23, no. 7 (1987): 515–23. http://dx.doi.org/10.1016/0014-3057(87)90106-6.

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Dissertations / Theses on the topic "Polymerization Mechanism"

1

Huang-Hobbs, Helen. "Dissecting the mechanism of ETV6 polymerization." Thesis, University of British Columbia, 2013. http://hdl.handle.net/2429/45691.

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ETV6 (or TEL), a member of the ETS family of eukaryotic transcription factors, normally functions as a transcriptional repressor and putative tumor suppressor. ETV6 is modular, containing a SAM (or PNT) domain and a DNA-binding ETS domain joined by a flexible linker sequence. The ETV6 SAM domain self-associates in a head-to-tail fashion, forming helical polymers proposed to generate extended repressive complexes at target DNA sites. ETV6 is also frequently involved in chromosomal translocations yielding unregulated chimeric oncoproteins with the SAM domain fused to the catalytic domain of a ty

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2

Kashirsagar, Ravindra S. "Study of entry mechanism in emulsion polymerization." Thesis, Georgia Institute of Technology, 1993. http://hdl.handle.net/1853/11747.

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Koss, Hans. "Mechanism of actin polymerization with yeast formin Bni1p." Diss., lmu, 2012. http://nbn-resolving.de/urn:nbn:de:bvb:19-149371.

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Prehl, Janett, and Constantin Huster. "Morphology on Reaction Mechanism Dependency for Twin Polymerization." MDPI, 2019. https://monarch.qucosa.de/id/qucosa%3A34346.

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An in-depth knowledge of the structure formation process and the resulting dependency of the morphology on the reaction mechanism is a key requirement in order to design application-oriented materials. For twin polymerization, the basic idea of the reaction process is established, and important structural properties of the final nanoporous hybrid materials are known. However, the effects of changing the reaction mechanism parameters on the final morphology is still an open issue. In this work, the dependence of the morphology on the reaction mechanism is investigated based on a previously intr

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Hibi, Yusuke. "Sequence Regulation in Radical Polymerization via Template Mechanism." 京都大学 (Kyoto University), 2014. http://hdl.handle.net/2433/188611.

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Sendall, Timothy James. "Investigating the molecular mechanism of serpin polymerisation." Thesis, University of Cambridge, 2012. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.610868.

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Li, Xiaopei. "Elucidation of the Termination Reaction Mechanism of Radical Polymerization." Doctoral thesis, Kyoto University, 2021. http://hdl.handle.net/2433/263689.

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Leswin, Joost Sieger Kaspar. "Particle Formation in RAFT-mediated Emulsion Polymerization." University of Sydney, 2007. http://hdl.handle.net/2123/2176.

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Doctor of Philosophy(PhD)<br>Particle formation in RAFT-mediated emulsion polymerization has been studied using reaction calorimetry. By measuring the heat flow during controlled feed ab-initio emulsion polymerization in the presence of amphipathic RAFT agents, particle formation by self-assembly of these species could be observed. Two different monomer systems, i.e. styrene and n-butyl acrylate, and various degrees of hydrophobicity of the initial macro-RAFT agents have been studied and compared. The different macro-RAFT agents were synthesized by first forming a hydrophilic block of poly(acr

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Sörensen, Nicolai. "Kinetics and Mechanism of Cu-Catalyzed Atom Transfer Radical Polymerization." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2015. http://hdl.handle.net/11858/00-1735-0000-0023-9662-7.

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Xu, Jie. "Polymerization mechanism, micro-macro properties, and carbonization of polyurethane foams." Thesis, University of Nottingham, 2017. http://eprints.nottingham.ac.uk/43925/.

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Polyurethane is one of the most diversified macropolymers with versatile properties for many applications including construction, transportation, personal wear, household appliance, etc. The research of this PhD study covers many aspects of polyurethane, including modelling on urethanisation and foaming mechanism, cell microstructure and packing polyhedrons, macroscopic properties and performance, and functional carbon materials developed from carbonisation of polyisocyanurate (PIR) foams. The work contains both theoretical modelling and experimental measurements. Urethanisation Kinetics The c

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Books on the topic "Polymerization Mechanism"

1

Kučera, Miloslav. Mechanism and kinetics of addition polymerizations. 2nd ed. Elsevier, 1992.

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2

NATO Advanced Study Institute on Olefin Metathesis and Polymerization Catalysts (1989 Akçay, Balıkesir İli, Turkey). Olefin metathesis and polymerization catalysts: Synthesis, mechanism, and utilization. Kluwer, 1990.

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International Symposium on Free-Radical Polymerization: Kinetics and Mechanism (4th 2006 Il Ciocco, Italy). Radical polymerization: Kinetics and mechanism ; selected contributions from the conference in Il Ciocco (Italy), September 3-8, 2006. Edited by Buback Michael and Herk Alex van. Wiley-VCH, 2007.

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4

Erusalimskii, B. L. Mechanisms of Ionic Polymerization. Springer US, 1987. http://dx.doi.org/10.1007/978-1-4684-8392-5.

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Matyjaszewski, Krzysztof, Brent S. Sumerlin, Nicolay V. Tsarevsky, and John Chiefari, eds. Controlled Radical Polymerization: Mechanisms. American Chemical Society, 2015. http://dx.doi.org/10.1021/bk-2015-1187.

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Erusalimskii, B. L. Mechanisms of Ionic Polymerization: Current Problems. Springer US, 1987.

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Erusalimskiĭ, B. L. Mechanisms of ionic polymerization: Current problems. Consultants Bureau, 1986.

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8

Matyjaszewski, K., Brent S. Sumerlin, and Nicolay V. Tsarevsky. Progress in controlled radical polymerization: Mechanisms and techniques. American Chemical Society, 2012.

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9

Matyjaszewski, Krzysztof, Haifeng Gao, Brent S. Sumerlin, and Nicolay V. Tsarevsky, eds. Reversible Deactivation Radical Polymerization: Mechanisms and Synthetic Methodologies. American Chemical Society, 2018. http://dx.doi.org/10.1021/bk-2018-1284.

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Matyjaszewski, Krzysztof, Brent S. Sumerlin, and Nicolay V. Tsarevsky, eds. Progress in Controlled Radical Polymerization: Mechanisms and Techniques. American Chemical Society, 2012. http://dx.doi.org/10.1021/bk-2012-1100.

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Book chapters on the topic "Polymerization Mechanism"

1

Kissin, Y. V. "Mechanism of Isospecific Olefin Polymerization." In Isospecific Polymerization of Olefins. Springer New York, 1985. http://dx.doi.org/10.1007/978-1-4612-5084-5_5.

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HARWOOD, H. JAMES. "Mechanism ofN-Carboxy Anhydride Polymerization." In ACS Symposium Series. American Chemical Society, 1985. http://dx.doi.org/10.1021/bk-1985-0286.ch005.

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Moad, Graeme, Roshan T. A. Mayadunne, Ezio Rizzardo, Melissa Skidmore, and San H. Thang. "Kinetics and Mechanism of RAFT Polymerization." In ACS Symposium Series. American Chemical Society, 2003. http://dx.doi.org/10.1021/bk-2003-0854.ch036.

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4

Boschmann, D., M. Mänz, M. G. Fröhlich, G. Zifferer, and P. Vana. "Mechanism of Z-RAFT Star Polymerization." In ACS Symposium Series. American Chemical Society, 2009. http://dx.doi.org/10.1021/bk-2009-1024.ch014.

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Guo, J. S., E. David Sudol, J. W. Vanderhoff, and Mohamed S. El-Aasser. "Kinetics and Mechanism of Styrene Microemulsion Polymerization." In ACS Symposium Series. American Chemical Society, 1992. http://dx.doi.org/10.1021/bk-1992-0492.ch007.

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Siedle, A. R., W. M. Lamanna, J. M. Olofson, B. A. Nerad, and R. A. Newmark. "Mechanism and Selectivity in Catalytic Olefin Polymerization." In ACS Symposium Series. American Chemical Society, 1993. http://dx.doi.org/10.1021/bk-1993-0517.ch011.

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7

Sinn, Hansjörg, Ingrid Schimmel, Mathias Ott, et al. "Formation, structure and mechanism of oligomeric methylaluminoxanes (MAO)." In Metalorganic Catalysts for Synthesis and Polymerization. Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/978-3-642-60178-1_10.

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8

Jossifov, Christo. "A Possible Mechanism of Polymer Formation from α,β-Unsaturated Carbonyl Compounds Under the Influence of Metathesis Catalytic Systems." In Metathesis Polymerization of Olefins and Polymerization of Alkynes. Springer Netherlands, 1998. http://dx.doi.org/10.1007/978-94-011-5188-7_25.

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9

Kissin, Yury V., and Laura A. Rishina. "Hydrogen Effects in Propylene Polymerization with Ti-Based Ziegler-Natta Catalysts. Chemical Mechanism." In Organometallic Catalysts and Olefin Polymerization. Springer Berlin Heidelberg, 2001. http://dx.doi.org/10.1007/978-3-642-59465-6_19.

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Storey, R. F., C. L. Curry, and T. L. Maggio. "Kinetics and Mechanism of Living Cationic Polymerization of Olefins." In Ionic Polymerizations and Related Processes. Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4627-2_10.

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Conference papers on the topic "Polymerization Mechanism"

1

Ling, Huaxu, Xiaoxiang Yu, Shifan Wang, Xiaohui Wang, and Liming Dong. "Study on ultrasonic assisted mechanism of ring opening polymerization of octamethylcyclotetrasiloxane (D4)." In MATERIALS SCIENCE, ENERGY TECHNOLOGY AND POWER ENGINEERING II (MEP2018). Author(s), 2018. http://dx.doi.org/10.1063/1.5041098.

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Furey, Michael J., Czeslaw Kajdas, Gustavo J. Molina, and Brian Vick. "A Critical Assessment of Tribopolymerization as an Antiwear Mechanism." In World Tribology Congress III. ASMEDC, 2005. http://dx.doi.org/10.1115/wtc2005-63308.

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By tribopolymerization, we mean the planned, intentional, and continuous formation of protective polymeric films on tribological surfaces by the use of minor concentrations of selected monomers capable of forming polymer films “in situ” by polycondensation or addition polymerization. The approach involves the design of molecules which will form polymeric surface films in critical regions of boundary lubrication. The concept has been shown to be effective in reducing wear with ceramics as well as metals in both liquid and vapor phase applications. The purpose of this paper is threefold, namely:

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3

Lu, Youmei, and Toshiyuki Watanabe. "Determination of electron transfer mechanism of two-photon-induced polymerization via an efficient way: one-photon process." In Optics & Photonics 2005, edited by Manfred Eich. SPIE, 2005. http://dx.doi.org/10.1117/12.626568.

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Pingali, Rushil, and Sourabh K. Saha. "Reaction-Diffusion Modeling of Photopolymerization During Femtosecond Projection Two-Photon Lithography." In ASME 2021 16th International Manufacturing Science and Engineering Conference. American Society of Mechanical Engineers, 2021. http://dx.doi.org/10.1115/msec2021-60255.

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Abstract Two-photon lithography (TPL) is a polymerization-based direct laser writing process that is capable of fabricating arbitrarily complex three-dimensional (3D) structures with submicron features. Traditional TPL techniques have limited scalability due to the slow point-by-point serial writing scheme. The femtosecond projection TPL (FP-TPL) technique increases printing rate by a thousand times by enabling layer-by-layer parallelization. However, parallelization alters the time and the length scales of the underlying polymerization process. It is therefore challenging to apply the models

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Kubarev, Alexey. "Development of the in-situ fluorescence microscopy approach to reveal the mechanism of interfacial polymerization of polyamide membranes." In European Microscopy Congress 2020. Royal Microscopical Society, 2021. http://dx.doi.org/10.22443/rms.emc2020.606.

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Mirshahi, M., J. Soria, C. Soria, et al. "MODIFICATION OF FIBRIN POLYMERIZATION INDUCED BY MONOCLONAL ANTIBODIES AGAINST FRAGMENT D DOMAIN OF FIBRIN/OGEN DEGRADATION PRODUCTS." In XIth International Congress on Thrombosis and Haemostasis. Schattauer GmbH, 1987. http://dx.doi.org/10.1055/s-0038-1643322.

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Monoclonal antibodies (McAb) are often used to detect the domains of a molecule involved in an important function of a biological system.In this work, the effect of 20 McAb directed against the D domain of fibrin/ogen degradation products (FbDP) were analyzed on fibrin polymerization. Two McAb which react with fragment D1 but not with fragment D3 inhibited both thrombin and reptilase-induced fibrin formation. It is therefore suggested that these 2 McAb recognize an epitope in the vicinity of the polymerization site "a" located in the JT 374-396 domain in fibrin/ogen molecule. (This sequence is

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Jamaluddin, Moideen P., C. Sreedevi, Ancy Thomas, and Lissy K. Krishnan. "A MOLECULAR MECHANISM FOR THE DITHI0THREIT0L-MEDIAT5D PLATELET AGGREGATION." In XIth International Congress on Thrombosis and Haemostasis. Schattauer GmbH, 1987. http://dx.doi.org/10.1055/s-0038-1644495.

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Biochemical mechanisms of stimulus response coupling is an intricate problem in platelet biochemistry. Recently we obtained evidence that support the view that conformational changes of an (unsaturated fatty acid – and U46619-binding) haemoprotein induced by the binding of arachidonic acid, H2O2 or PGH2 liberated in apparently different platelet compartments in response to different stimuli could constitute a mechanism (L.K. Krishnan … M.P. Jamaluddin, FEBS Lett, in the press). We investigated the effect of dithiothreitol (DTT), a platelet agonist whose mechanism of action is unknown, on the p

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Ruf, W., A. Bender, K. T. Preissner, D. A. Lane, and G. Müller-Berghaus. "FIBRINOPEPTIDE B RELEASE FROM NORMAL FIBRINOGEN AND FIBRINOGEN LONDON I IN THE PRESENCE OF INHIBITORS OF FIBRIN POLYMERIZATION." In XIth International Congress on Thrombosis and Haemostasis. Schattauer GmbH, 1987. http://dx.doi.org/10.1055/s-0038-1643341.

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The fibrinopeptides A and B (FPA and FPB) are cleaved from the fibrinogen molecule with different rates. In the initial phase of the thrombin-fibrinogen reaction, FPB is released with a slow rate, which is enhanced upon polymerization of desA-fi-brin monomers. The aim of the present study was to further characterize the mechanism leading to the enhanced rate of FPB release during polymerization. For this purpose, the release of FPB from normal fibrinogen and from fibrinogen London I, which exhibits a polymerization defect located in the D-domain, was studied in the presence and absence of the

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Malakooti, Mohammad H., Patrick L. Anderson, and Henry A. Sodano. "Visualization of Particle-Toughening Mechanism in Transparent Polyurethanes." In ASME 2014 Conference on Smart Materials, Adaptive Structures and Intelligent Systems. American Society of Mechanical Engineers, 2014. http://dx.doi.org/10.1115/smasis2014-7450.

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Highly cross-linked polyurethanes have a high elastic modulus and creep resistance, but they undergo a brittle fracture below the glass transition temperature. Unfortunately, a large number of glassy polyurethanes are prone to brittle fracture without undergoing large elastic deformations; in particular, brittle failure is common under conditions such as low temperature and high strain rates. While the rigidity in polymers is required for practical applications, the lack of resistance against crack propagation is essential to avoid catastrophic failures. The toughening of polymers is a crucial

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Guan, Zhongyuan, and Biyuan Shui. "The New Progress of Drag Reducing Agents in World Research." In 2006 International Pipeline Conference. ASMEDC, 2006. http://dx.doi.org/10.1115/ipc2006-10025.

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Frictional pressure drop (or drag) restricts the flow of liquid in a pipeline, limiting throughput and requiring greater amounts of energy for pumping. Flow improvers used for reducing drag are commonly referred to in the industry as drag reduction agents (DRA). This article presents the latest achievements in research related to DRA’s mechanism and production. A higher molecular weight of polyalpha-olefin will be obtained by bulk polymerization. There are breakthroughs either in research of solution polymerization of alpha-olefin. The DRA’s post-treating processes become better and approach p

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Reports on the topic "Polymerization Mechanism"

1

Matyjaszewski, K. Mechanism of the Initiation of the Cationic Polymerization of Styrenes by Silanes and Activated Covalent Esters. Defense Technical Information Center, 1989. http://dx.doi.org/10.21236/ada206502.

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Wallace, Kevin C., Andy H. Liu, John C. Dewan, and Richard R. Schrock. Preparation and Reactions of Tantalum Alkylidene Complexes Containing Bulky Phenoxide or Thiolate Ligands. Controlling Ring-Opening Metathesis Polymerization Activity and Mechanism Through Choice of Anionic Ligand. Defense Technical Information Center, 1988. http://dx.doi.org/10.21236/ada198293.

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Katz, Thomas J. Polymer Syntheses and Mechanisms of Polymerization. Defense Technical Information Center, 1991. http://dx.doi.org/10.21236/ada233034.

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Daniel Szymanski. The Arabidopsis Wave Complex: Mechanisms Of Localized Actin Polymerization And Growth. Office of Scientific and Technical Information (OSTI), 2012. http://dx.doi.org/10.2172/1053522.

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