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Dissertations / Theses on the topic 'Polymerization'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Hajime, Kammiyada. "Ring-Expansion Cationic Polymerization：A New Precision Polymerization for Cyclic Polymers." 京都大学 (Kyoto University), 2017. http://hdl.handle.net/2433/225628.

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2

Aran, Bengi. "Polymerization And Characterization Of Methylmethacrylate By Atom Transfer Radical Polymerization." Master's thesis, METU, 2004. http://etd.lib.metu.edu.tr/upload/12605042/index.pdf.

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In this work, methylmethacrylate, MMA was polymerized by ATRP method to obtain low molecular weight living polymers. The initiator was p-toluenesulfonylchloride and catalyst ligand complex system were CuCl-4,4&rsquo<br>dimethyl 2,2&rsquo<br>bipyridine. Polymers with controlled molecular weight were obtained. The polymer chains were shown by NMR investigation to be mostly syndiotactic. The molecular weight and molecular weight distribution of some polymer samples were measured by GPC method. The K and a constants in [h]=K Ma equation were measured as 9.13x10-5 and 0.74, respectively. FT-IR a

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3

Barnette, Darrell Thomas. "Continuous miniemulsion polymerization." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/12518.

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4

Endsor, Robert M. "Living cationic polymerization." Thesis, Aston University, 1997. http://publications.aston.ac.uk/9597/.

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The kinetics of the polymerization of styrene iniated by 1-chloro-1-phenyltehane/tin (IV) chloride in the presence of tetrabutylammonium chloride have been studied. Dilatometry studies at 25 °C were conducted and the orders of reaction were established. Molecular weight studies were conducted for these experiments using size exclusion chromatography. These studies indicated that transfer/termination reactions were present. The observed kinetics may be explained by a polymerization mechanism involving a single propagating species which is present in low concentrations. Reactions at 0 °C and -15

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5

Brodsky, Colin John. "Graft polymerization lithography." Access restricted to users with UT Austin EID Full text (PDF) from UMI/Dissertation Abstracts International, 2001. http://wwwlib.umi.com/cr/utexas/fullcit?p3024998.

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6

Vale, Hugo. "Population Balance Modeling of Emulsion Polymerization Reactors : applications to Vinyl Chloride Polymerization." Lyon 1, 2007. http://www.theses.fr/2007LYO10034.

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This thesis is a contribution to the development of population balance models of emulsion polymerization and, more particularly, to the modeling of particle formation and particle size distribution (PSD) in vinyl chloride emulsion polymerization. The rst part of the work is dedicated to the acquisition of experimental data. Ab initio polymerizations were done to obtain reliable data regarding the dependence of the particle number on the concentration of surfactant, as well as to analyze the effect of the initiator concentration, stirring rate, and monomer-to-water ratio upon the particle numbe

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7

Ding, Shijie. "Atom transfer radical polymerization." Laramie, Wyo. : University of Wyoming, 2006. http://proquest.umi.com/pqdweb?did=1225138911&sid=1&Fmt=2&clientId=18949&RQT=309&VName=PQD.

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8

Song, Zhiqiang. "Kinetics of emulsion polymerization." Diss., Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/10148.

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9

Wong, Ji Sam. "Modeling polymerization-based amplification." Thesis, Massachusetts Institute of Technology, 2016. http://hdl.handle.net/1721.1/104123.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemical Engineering, 2016.<br>This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections.<br>Cataloged from student-submitted PDF version of thesis.<br>Includes bibliographical references (pages 117-120).<br>Eosin, a photoreducible xanthene derivative, acts as a Type II photoinitiator of free radical polymerizations when used in combination with alcohols or amines as co-initiators. Previous work utilizing eosin in polymerizations focused o

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10

Qi, Genggeng. "Unconventional radical miniemulsion polymerization." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/26547.

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Thesis (Ph.D)--Chemical Engineering, Georgia Institute of Technology, 2009.<br>Committee Chair: Jones, Christopher W.; Committee Chair: Schork, F. Joseph; Committee Member: Koros, William J.; Committee Member: Lyon, Andrew; Committee Member: Nenes, Athanasios. Part of the SMARTech Electronic Thesis and Dissertation Collection.

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11

Lin, Anna. "Nitroxide-mediated photo-polymerization." Electronic Thesis or Diss., Aix-Marseille, 2019. http://www.theses.fr/2019AIXM0264.

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De nos jours, la photopolymérisation est devenue un procédé important dans le domaine de la science des polymères. Cette méthode présente de nombreux avantages : la rapidité de la réaction, l‘aspect environnemental (formation limitée de composés organiques volatils et possibilité de réaction à température ambiante) ou encore un contrôle spatial et temporel. Ce mode d‘activation photochimique appliqué pendant les dernières décennies aux techniques de polymérisation radicalaire contrôlée telles que l‘ATRP, la RAFT ou la NMP permet de contrôler les propriétés des polymères mais aussi la préparati

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12

Reeves, Jennifer Anne. "Photochemistry: Its Application to Reversible Deactivation Radical Polymerization, Degradation, and Post-polymerization Modification." Miami University / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=miami154297403540796.

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13

Aoshima, Sadahito. "Syntheses of Functional Polymers by Cationic Polymerization: Living Polymerization and Controlled Chain Transfer." Kyoto University, 1986. http://hdl.handle.net/2433/74688.

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14

Salehpour, Somaieh. "Biodiesel: A green polymerization solvent." Thesis, University of Ottawa (Canada), 2007. http://hdl.handle.net/10393/27916.

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A number of polymer products are traditionally made using a solution polymerization technique. However, with increased environmental awareness and thus, concerns over the volatile organic content (VOC) associated with various polymer processes, there is an ongoing effort to find alternatives to traditional solvents. In an effort to use cleaner technologies, fatty acid methyl ester (FAME) was used for the first time as a polymerization solvent. Biodiesel or FAME has garnered much attention in recent years as an alternative to diesel fuel. It is environmentally benign and has a low volatility. B

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15

Reinhardt, Jeff C. "Precipitation/dispersion polymerization of acrylamide." Thesis, Georgia Institute of Technology, 1985. http://hdl.handle.net/1853/10210.

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16

Vogt, Marc. "Polymerization dynamics in nonequilibrium environments." Diss., Georgia Institute of Technology, 2002. http://hdl.handle.net/1853/27698.

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17

Howard, Bruce. "Polymerization of 2D gravity models." Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.301443.

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18

Ishihara, Nobuhide. "Transition metal catalyzed olefin polymerization." Thesis, University of Oxford, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.253375.

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19

Walker, Dennis Allan. "New approaches to polymerization catalysis." Thesis, University of East Anglia, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.251449.

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20

Ryan, Martin Edward. "Mechanistic studies of plasma polymerization." Thesis, Durham University, 1995. http://etheses.dur.ac.uk/5455/.

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Plasma polymerization is a solventless method for depositing polymeric layers onto any substrate at room temperature. This technique comprises excitation, fragmentation, and polymerization of precursor molecules by an electrical discharge. Although widely used, the fundamental molecular processes associated with plasma polymerization are not fully understood. Basic plasma / polymer interactions were studied by investigating the surface treatment of polytetrafluoroethylene (PTFE) using inert and reactive gas discharges. Depending upon the feed gas employed, chemical, UV, or ion beam modificatio

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21

Ren, Wendong. "Photoinduced Atom Transfer Radical Polymerization." University of Akron / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=akron1619122320374689.

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22

Tapper, Tristan T. "Living cationic polymerization of isobutene." Thesis, Aston University, 1999. http://publications.aston.ac.uk/9621/.

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The polymerization of isobutene initiated by 1-chloro-1-phenylethane has been investigated, and molecular weight studies conducted using size exclusion chromatography. Polymerizations carried out in a 40/60 (v/v) mixture of dichloromethaneIcyclohexane, using titanium (IV) chloride as a catalyst in the presence of pyridine at -30 °C were found to be controlled and living. The number average molecular weights of the polymers increased linearly with monomer conversion, and the molecular weight distributions were between 1.15 and 1.20. Efficiencies of initiation were between 80 and 100%, and evide

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23

Brunier, Barthélémy. "Modeling of Pickering Emulsion Polymerization." Thesis, Lyon 1, 2015. http://www.theses.fr/2015LYO10320/document.

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L’objectif du présent projet est de développer une méthodologie pour la modélisation fondamentale de procédés de polymérisation en émulsion sans tensioactif stabilisés par des particules inorganiques, dénommées "polymérisation en émulsion Pickering". La modélisation des systèmes de polymérisation en émulsion nécessite la modélisation de la distribution de taille des particules (PSD), qui est une propriété importante d'utilisation finale du latex. Cette PSD comprend des sous-modèles dédiés à la nucléation des particules, le transfert de masse entre les différentes phases (monomère, radicaux, st

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24

Sisson, Thomas Michael 1966. "Crosslinking polymerization in supramolecular assemblies." Diss., The University of Arizona, 1997. http://hdl.handle.net/10150/282566.

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Supramolecular assemblies are composed of noncovalently associated molecules which organize in water to yield 2-D and 3-D architectures. Crosslinking polymerization of supramolecular assemblies provides an effective means to modify their chemical and physical properties. Two methods of characterizing crosslinked polymeric assemblies were developed. These techniques rely on experimentally observed changes in polymer solubility and assembly stability in the presence of nonionic surfactants. The results show an inefficient crosslinking mechanism in organized media compared to isotropic polymeriza

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25

Miller, Thomas Jerome. "Comparing microwave induced polymerization to thermal induced polymerization of the resin bisphenol A-glycidyl methacrylate." College Park, Md. : University of Maryland, 2004. http://hdl.handle.net/1903/1520.

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Thesis (M.S.) -- University of Maryland, College Park, 2004.<br>Thesis research directed by: Dept. of Electrical and Computer Engineering. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.

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26

Thongnuanchan, Bencha. "A low temperature alkoxyamine designed for use in nitroxide-mediated miniemulsion polymerization." Thesis, University of Manchester, 2011. https://www.research.manchester.ac.uk/portal/en/theses/a-low-temperature-alkoxyamine-designed-for-use-in-nitroxidemediated-miniemulsion-polymerization(9dddd46a-9756-41a2-8b66-66fac7d360c9).html.

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The basis for this research project is based on the discovery in the previous research that 2,2' ,5-trimethyl-3-( I-phenylethoxy)-4-tert-butyl-3-azahexane, (Styryl- TITNO) is able to control bulk polymerization of styrene at temperature as low as 70°C. The principle objective of this project was to evaluate the feasibility of using Styryl- TITNO to control radical solution and miniemulsion polymerizations at temperatures below 100°C. Styryl- TITNO was shown to effect solution polymerizations of both n-butyl acrylate (BA) and styrene below 100°C. Polymerization temperature was shown to be a cru

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27

Valente, Andreia. "Lanthanide based coordinative chain transfer polymerization for architecture control in (co)polymers and ruthenium catalyzed ring-opening polymerization : two aspects of atom economy in polymerization catalysis." Thesis, Lille 1, 2010. http://www.theses.fr/2010LIL10061.

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Le nouveau complexe Cp*La(BH4)2(THF)2 a été utilisé en combinaison avec des alkyles magnésiens et aluminiques pour la (co)polymérisation coordinative par transfert de chaîne (CCTP) du styrène et de l’isoprène. En développant ce concept nous avons obtenu la première croissance de chaîne catalysée du styrène et de l’isoprène avec contrôle de la microstructure. L’application de la CCTP à la copolymérisation statistique est une voie nouvelle et originale pour le contrôle de la composition de copolymères.Par ailleurs, une étude mécanistique a été réalisée pour la polymérisation de l’ ε-caprolactone

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28

Samer, Charles J. "Dynamic modeling of continuous miniemulsion polymerization reactors." Thesis, Georgia Institute of Technology, 1995. http://hdl.handle.net/1853/10228.

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29

Shoaf, Glenn Lewis. "Feasibility study for continuous emulsion copolymerization of ethyl acrylate and methacrylic acid." Thesis, Georgia Institute of Technology, 1986. http://hdl.handle.net/1853/10254.

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30

Fontenot, Kevin. "Nucleation and growth in mini/macro emulsion polymerization systems." Diss., Georgia Institute of Technology, 1991. http://hdl.handle.net/1853/10922.

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31

Mead, Richard Norman. "Emulsion copolymerization in continuous reactors." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/11030.

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32

Azmus, Dora J. Taylor. "Synthesis of polybenzimidazoles from monomers containing flexible linkages." Thesis, Corvallis, Oregon : Oregon State University, 1992. http://handle.dtic.mil/100.2/ADA256976.

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Thesis (M.S.)--Oregon State University, 1993.<br>Description based on title screen as viewed on April 8, 2009. "Completed 13 May 1992, Commencement June 1993." Includes bibliographical references (p. 73-75). Also available in print.

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33

Plummer, Ronda. "Living polymerization of novel hydrophilic polymers /." [St. Lucia, Qld.], 2005. http://www.library.uq.edu.au/pdfserve.php?image=thesisabs/absthe19201.pdf.

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34

Matthews, Jermey N. A. "Thermodynamics and relaxation during actin polymerization." College Park, Md. : University of Maryland, 2005. http://hdl.handle.net/1903/2346.

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Thesis (Ph. D.) -- University of Maryland, College Park, 2005.<br>Thesis research directed by: Chemical Engineering. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.

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35

Ha, Seung-kyu. "Starch incorporated polymerization of thermoplastic polyurethan." [S.l. : s.n.], 2002. http://deposit.ddb.de/cgi-bin/dokserv?idn=965659852.

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36

Ali, Mir Mukkaram Stöver Harald D. H. "Polymer capsules by living radical polymerization /." *McMaster only, 2004.

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37

Vardareli, Tugba. "Polymerization And Characterization Of Allyl Methacrylate." Master's thesis, METU, 2006. http://etd.lib.metu.edu.tr/upload/12607469/index.pdf.

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Allyl methacrylate, AMA was polymerized by chemical initiator and by &amp<br>#947<br>-radiation under different conditions. The polymer obtained is mostly gel type with some soluble fractions at lower conversions. Arrhenius activation energy is 82.3 kJ/mol for chemical initiated polymerization. The polymer was characterized by FT-IR, NMR, DSC, TGA, XPS, XRD, DLS, and MS methods. It was found that about 98-99% of allyl side groups retained as pendant even after completion of the polymerization, while 1-2% may give crosslinking and/or cyclization that yields lactones and anhydrides. The spectros

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38

Kozanoglu, Selin. "Polymerization And Charaterization Of N-vinylcaprolactam." Master's thesis, METU, 2008. http://etd.lib.metu.edu.tr/upload/12609947/index.pdf.

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Poly(N-vinylcaprolactam), PNVCL, is a nonionic, nontoxic, water soluble, thermally sensitive and biocompatible polymer. It contains hydrophilic carboxylic and amide groups with hydrophobic carbon-carbon backbone chain so its hydrolysis does not produce small amide compounds which are often not desired for biomedical applications. Moreover PNVCL possesses lower critical solution temperature, (LCST) in the range of physiological temperature (32-34 oC). These properties make the polymer suitable for use in some biotechnology applications such as implantation of artificial organs and tissues, puri

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39

Nozari, Samira. "Towards understanding RAFT aqueous heterophase polymerization." Phd thesis, Universität Potsdam, 2005. http://opus.kobv.de/ubp/volltexte/2005/580/.

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Reversible addition-fragmentation transfer (RAFT) was used as a controlling technique for studying the aqueous heterophase polymerization. The polymerization rates obtained by calorimetric investigation of ab initio emulsion polymerization of styrene revealed the strong influence of the type and combination of the RAFT agent and initiator on the polymerization rate and its profile. The studies in all-glass reactors on the evolution of the characteristic data such as average molecular weight, molecular weight distribution, and average particle size during the polymerization revealed the importa

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40

Chen, Jianxin. "Cinnamated PDMS Polymerization for MEMS Applications." Fogler Library, University of Maine, 2008. http://www.library.umaine.edu/theses/pdf/ChenJ2008.pdf.

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41

LaFratta, Christopher N. "Multiphoton absorption polymerization issues and solutions /." College Park, Md. : University of Maryland, 2006. http://hdl.handle.net/1903/4091.

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Thesis (Ph. D.)--University of Maryland, College Park, 2006.<br>Thesis research directed by: Chemistry. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.

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42

Wang, Aileen Ruiling Zhu Shiping. "Diffusion-controlled atom transfer radical polymerization." *McMaster only, 2005.

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43

Holmgren, Anders. "Biochemical Control Aspects in Lignin Polymerization." Doctoral thesis, Stockholm Stockholm : KTH, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4632.

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44

Weng, Weijun Ferrone Frank A. "Universal metastability of sickle hemoglobin polymerization /." Philadelphia, Pa. : Drexel University, 2008. http://hdl.handle.net/1860/2832.

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45

Chern, Chorng-Shyan. "Polymerization in non-uniform latex particles." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/12170.

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46

Huang-Hobbs, Helen. "Dissecting the mechanism of ETV6 polymerization." Thesis, University of British Columbia, 2013. http://hdl.handle.net/2429/45691.

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ETV6 (or TEL), a member of the ETS family of eukaryotic transcription factors, normally functions as a transcriptional repressor and putative tumor suppressor. ETV6 is modular, containing a SAM (or PNT) domain and a DNA-binding ETS domain joined by a flexible linker sequence. The ETV6 SAM domain self-associates in a head-to-tail fashion, forming helical polymers proposed to generate extended repressive complexes at target DNA sites. ETV6 is also frequently involved in chromosomal translocations yielding unregulated chimeric oncoproteins with the SAM domain fused to the catalytic domain of a ty

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47

Carrel, Hyman A. (Hyman Andrew) 1979. "Giant vesicles compressed by actin polymerization." Thesis, Massachusetts Institute of Technology, 2004. http://hdl.handle.net/1721.1/16646.

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Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Physics, 2004.<br>Includes bibliographical references (p. 45-46).<br>This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections.<br>Actin polymerization plays a critical role in generating propulsive force to drive many types of cell motility. The discovery of actin based motility of the bacterial pathogen Listeria monocytogenes has lead to clearer understandings of the essential ingredients required for cell motility. The biophysical mechanisms

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48

Klumperman, Bert. "NMR studies of radical polymerization processes." Thesis, Stellenbosch : Stellenbosch University, 2012. http://hdl.handle.net/10019.1/71596.

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Thesis (DSc)--Stellenbosch University, 2012.<br>ENGLISH ABSTRACT: Examples of the use of NMR spectroscopy in the study of radical polymerization processes have been described. The studies presented have made a significant contribution to the understanding of the fundamental mechanistic processes in these polymerization systems. It is pointed out that NMR in conventional radical polymerization is of limited use due to the concurrent occurrence of all elementary reactions (initiation, propagation and termination). Conversely, for

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49

Schütze, Mike. "Bimetallic Complexes for Cooperative Polymerization Catalysis." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/11858/00-1735-0000-002E-E4A0-A.

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50

Summers, Mark James. "Polymerization of nano-structured surfactant assemblies." Thesis, University of Bristol, 2002. http://hdl.handle.net/1983/e4abbe4b-807c-462f-acdf-dceb786d55d7.

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