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Journal articles on the topic 'Polyphosphate electrolytes'

Author: Grafiati

Published: 28 May 2022

Last updated: 31 July 2025

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1

Rudnev, V. S., D. L. Boguta, P. M. Nedozorov, and T. A. Kaidalova. "Anodic layers formed in polyphosphate electrolytes on rectifying metals." Russian Journal of Applied Chemistry 79, no. 2 (2006): 256–63. http://dx.doi.org/10.1134/s1070427206020169.

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2

Kluy, N., B. B. L. Reeb, O. Paschos, et al. "Ammonium Polyphosphate Composite Based Electrolytes for Intermediate Temperature Fuel Cells." ECS Transactions 50, no. 2 (2013): 1255–61. http://dx.doi.org/10.1149/05002.1255ecst.

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3

Imbirovych, N. "Modification of the surface of titanium alloys by the synthesis of coatings by the PEO method in alkaline electrolytes saturated with diatomite." Товарознавчий вісник 17, no. 1 (2024): 17–26. http://dx.doi.org/10.62763/ef/1.2024.17.

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One of the most promising directions of modern materials science is the search for methods of improving the biocompatibility properties of metals used in implantology, which will allow to reduce the percentage of rejection of implants by the living organism. Therefore, it is promising to use processing methods to change the state of the surface of metals due to surface modification, which includes the method of plasma electrolytic oxidation. The main goal of this work was to develop a technological process for obtaining coatings with higher biocompatibility compared to the base metal due to th

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4

Denmark, Iris, Samantha Macchi, Fumiya Watanabe, Tito Viswanathan, and Noureen Siraj. "Effect of KOH on the Energy Storage Performance of Molasses-Based Phosphorus and Nitrogen Co-Doped Carbon." Electrochem 2, no. 1 (2021): 29–41. http://dx.doi.org/10.3390/electrochem2010003.

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In this study, we have evaluated the effect of potassium hydroxide (KOH) on the energy storage performance of metal-free carbon-based materials prepared from molasses. Molasses are a renewable-resource biomass and economical by-product of sugar refinement, used here as a carbon precursor. Two co-doped carbon materials using molasses were synthesized via a time and cost-efficient microwave carbonization process, with ammonium polyphosphate as a phosphorus and nitrogen doping agent. The phosphorus and nitrogen co-doped carbon (PNDC) samples were prepared in the presence and absence of a chemical

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5

Denmark, Iris, Amna Khan, Taylor Scifres, Tito Viswanathan, Fumiya Watanabe, and Noureen Siraj. "Synthesis and Characterization of Supercapacitor Materials from Soy." Electrochem 2, no. 4 (2021): 534–45. http://dx.doi.org/10.3390/electrochem2040034.

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Renewable resources and their byproducts are becoming of growing interest for alternative energy. Here, we have demonstrated the use of Arkansas’ most important crop, soy, as a carbon precursor for the synthesis of carbonized activated materials for supercapacitor applications. Different soy products (soymeal, defatted soymeal, soy flour and soy protein isolate) were converted into carbonized carbon and co-doped with phosphorus and nitrogen simultaneously, using a facile and time-effective microwave synthesis method. Ammonium polyphosphate was used as a doping agent which also absorbs microwav

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6

Boguta, D. L., V. S. Rudnev, O. P. Terleeva, V. I. Belevantsev, and A. I. Slonova. "Effect of ac Polarization on Characteristics of Coatings formed from Polyphosphate Electrolytes of Ni(II) and Zn(II)." Russian Journal of Applied Chemistry 78, no. 2 (2005): 247–53. http://dx.doi.org/10.1007/s11167-005-0269-0.

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7

Rudnev, V. S., T. P. Yarovaya, D. L. Boguta, L. M. Tyrina, P. M. Nedozorov, and P. S. Gordienko. "Anodic spark deposition of P, Me(II) or Me(III) containing coatings on aluminium and titanium alloys in electrolytes with polyphosphate complexes." Journal of Electroanalytical Chemistry 497, no. 1-2 (2001): 150–58. http://dx.doi.org/10.1016/s0022-0728(00)00483-6.

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8

Song, L., Y. Kou, Y. Song, D. Shan, G. Zhu, and E. H. Han. "Fabrication and characterization of micro-arc oxidation (MAO) coatings on Mg-Li alloy in alkaline polyphosphate electrolytes without and with the addition of K2 TiF6." Materials and Corrosion 62, no. 12 (2011): 1124–32. http://dx.doi.org/10.1002/maco.201006050.

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9

Dixon, Brian G., R. Scott Morris, and Steven Dallek. "Non-flammable polyphosphonate electrolytes." Journal of Power Sources 138, no. 1-2 (2004): 274–76. http://dx.doi.org/10.1016/j.jpowsour.2004.06.016.

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10

Ma, Chunxiang, Yi Lu, Pengpeng Sun, Yi Yuan, Xiaoyan Jing, and Milin Zhang. "Characterization of plasma electrolytic oxidation coatings formed on Mg–Li alloy in an alkaline polyphosphate electrolyte." Surface and Coatings Technology 206, no. 2-3 (2011): 287–94. http://dx.doi.org/10.1016/j.surfcoat.2011.07.019.

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11

Sun, Chunwen, Carlos Alberto López, and José Antonio Alonso. "Elucidating the diffusion pathway of protons in ammonium polyphosphate: a potential electrolyte for intermediate temperature fuel cells." Journal of Materials Chemistry A 5, no. 17 (2017): 7839–44. http://dx.doi.org/10.1039/c7ta01404j.

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12

Abdali, Narges, Farhan Younas, Samaneh Mafakheri, et al. "Identification and characterization of smallest pore-forming protein in the cell wall of pathogenic Corynebacterium urealyticum DSM 7109." BMC Biochemistry 19, no. 1 (2018): 3. https://doi.org/10.1186/s12858-018-0093-9.

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<strong>Background: </strong> <i>Corynebacterium urealyticum</i>, a pathogenic, multidrug resistant member of the mycolata, is known as causative agent of urinary tract infections although it is a bacterium of the skin flora. This pathogenic bacterium shares with the mycolata the property of having an unusual cell envelope composition and architecture, typical for the genus <i>Corynebacterium</i>. The cell wall of members of the mycolata contains channel-forming proteins for the uptake of solutes.<strong>Results: </strong>In this study, we provide novel information on the identification and ch

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13

Popovic-Neuber, Jelena. "(Invited) Cation Conducting Binders: From Liquid to Solid-State Batteries." ECS Meeting Abstracts MA2023-02, no. 6 (2023): 917. http://dx.doi.org/10.1149/ma2023-026917mtgabs.

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Binders play an important role in providing connection between active electrode materials with the conductive agent, thus enabling electronic/ionic pathways and good mechanical properties of battery electrodes.1 In the first part of my talk, I will discuss the case of binders for high volume expansion electrodes (e.g. Si), where cycle life is strongly reduced by cracking of active particles and solid electrolyte interphases (SEIs), the process which in turn consumes the electrolyte continuously. Here, development of multi-functional polymeric binders with ionic conductivity (and potentially se

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14

Maki, Hideshi, Kie Ibaragi, Yoshiaki Fujimoto, Hiroyuki Nariai, and Minoru Mizuhata. "Transitions from simple electrolyte to polyelectrolyte in a series of polyphosphates." Colloids and Surfaces A: Physicochemical and Engineering Aspects 484 (November 2015): 153–63. http://dx.doi.org/10.1016/j.colsurfa.2015.07.064.

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15

Iliescu, Smaranda, Nicoleta Plesu, and Gheorghe Ilia. "Synthetic routes to polyphosphoesters as solid polymer electrolytes for lithium ion batteries." Pure and Applied Chemistry 88, no. 10-11 (2016): 941–52. http://dx.doi.org/10.1515/pac-2016-0702.

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AbstractPolyphosphoesters are environmentally friendly and multifunctional materials. They were noted for their special properties, i.e. fire resistance, plasticity, lubricity, high physical-mechanical performance, thermal stability, and as degradable biopolymers which properties can be modified specifically to desired application in medicine, biology and agriculture. They have a wide range of application as: flame retardants, scaffolds for tissue engineering, gene carriers, drug delivery, carriers for the sustained release of nerve growth factor, pH/thermoresponsive materials, or as solid pol

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16

Shamsi, Shahab A., and Neil D. Danielson. "Ribonucleotide Electrolytes for Capillary Electrophoresis of Polyphosphates and Polyphosphonates with Indirect Photometric Detection." Analytical Chemistry 67, no. 11 (1995): 1845–52. http://dx.doi.org/10.1021/ac00107a014.

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17

Akamatsu, T., Toshihiro Kasuga, and Masayuki Nogami. "Preparation of Fast Proton-Conducting Phosphate Glass-Derived Hydrogels and their Electrochemical Properties." Advanced Materials Research 15-17 (February 2006): 327–32. http://dx.doi.org/10.4028/www.scientific.net/amr.15-17.327.

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When fine-sized 45ZnO·55P2O5 glass powders were mixed with water, hydration immediately occurred, resulting in the formation of a viscous hydrogel. 31P MAS-NMR spectra showed that the hydrogel contains orthophosphates and long polyphosphates. 45ZnO·55P2O5 glass-derived hydrogel (45ZP gel) showed high conductivities of 9.9 mS/cm at 30 °C. The conductivities were related to the proton amount in the hydrogel. The electric double-layer capacitor (EDC) cell for the 45ZP gel showed no oxidation-reduction processes in the range of 0~1 V and the specific capacities of 2.40 F/g. The possibility as an E

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18

Martel, Anna, Behzad Mahdavi, Jean Lessard, Hugues Ménard, and Louis Brossard. "Electrocatalytic hydrogenation of phenol on various electrode materials." Canadian Journal of Chemistry 75, no. 12 (1997): 1862–67. http://dx.doi.org/10.1139/v97-619.

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The electrocatalytic hydrogenation (ECH) of phenol was investigated at room temperature under galvanostatic control in aqueous sulfuric acid solutions on platinized platinum (Pt/Pt) electrodes and on composite Rh/Ni and Ru/Ni electrodes consisting of rhodium or ruthenium chemically deposited on nickel particles dispersed in a lanthanum polyphosphate matrix. The order of electrocatalytic activity at a current density (based on the geometric area) of 1 mA/cm2 was found to be Ru/Ni > Pt/Pt > Rh/Ni. The efficiency decreased with increased current density. For the Ru/Ni electrodes, the effici

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19

Liu, Xueqing, Chang Zhang, Shuyu Gao, et al. "A novel polyphosphonate flame-retardant additive towards safety-reinforced all-solid-state polymer electrolyte." Materials Chemistry and Physics 239 (January 2020): 122014. http://dx.doi.org/10.1016/j.matchemphys.2019.122014.

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20

Mathur, Lakshya, Aniket Kumar, In-Ho Kim, Hohan Bae, Jun-Young Park, and Sun-Ju Song. "Novel organic-inorganic polyphosphate based composite material as highly dense and robust electrolyte for low temperature fuel cells." Journal of Power Sources 493 (May 2021): 229696. http://dx.doi.org/10.1016/j.jpowsour.2021.229696.

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21

Lin, Hui-Min, Yen-Con Hung, and Shang-Gui Deng. "Effect of partial replacement of polyphosphate with alkaline electrolyzed water (AEW) on the quality of catfish fillets." Food Control 112 (June 2020): 107117. http://dx.doi.org/10.1016/j.foodcont.2020.107117.

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22

Reusch, Rosetta N. "Low molecular weight complexed poly(3-hydroxybutyrate): a dynamic and versatile molecule in vivo." Canadian Journal of Microbiology 41, no. 13 (1995): 50–54. http://dx.doi.org/10.1139/m95-167.

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It is increasingly clear that poly(3-hydroxybutyrate) (PHB) is not just an inert storage polymer, confined to certain bacteria, but a ubiquitous, interactive, solvating biopolymer involved in important physiological functions. Low molecular weight PHB, complexed to other macromolecules (c-PHB), is widely distributed in biological cells, being found in representative organisms of nearly all phyla. Complexation modifies the physical and chemical properties of c-PHB, allowing it to pervade aqueous as well as hydrophobic regions of the cell, and as a result c-PHB can be found in cytoplasm and intr

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23

Apaydin, Kadir, Abdelghani Laachachi, Jérôme Bour, Valérie Toniazzo, David Ruch, and Vincent Ball. "Polyelectrolyte multilayer films made from polyallylamine and short polyphosphates: Influence of the surface treatment, ionic strength and nature of the electrolyte solution." Colloids and Surfaces A: Physicochemical and Engineering Aspects 415 (December 2012): 274–80. http://dx.doi.org/10.1016/j.colsurfa.2012.09.036.

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24

Wang, Tianlin, and Sam F. Y. Li. "Separation of polyphosphates and polycarboxylates by capillary electrophoresis in a carrier electrolyte containing adenosine 5′-triphosphate and cetyltrimethylammonium bromide with indirect UV detection." Journal of Chromatography A 723, no. 1 (1996): 197–205. http://dx.doi.org/10.1016/0021-9673(95)00824-1.

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25

Latty, Monique hazel, James Sullivan, and Paul Gaskin. "Salmon Sperm DNA As a Corrosion Inhibitor on Ductile Cast for Use in Water Distribution System Pipes." ECS Meeting Abstracts MA2022-01, no. 16 (2022): 1018. http://dx.doi.org/10.1149/ma2022-01161018mtgabs.

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Ductile cast iron (DCI) is a high carbon iron alloy with a composition of up to 3.7% C, 2.3% Si, 0.35% Mn and various smaller constitutes. Upon casting of DCI, the high carbon content results in solidification in a secondary phase in the form of graphite nodules. These graphite nodules form around a matrix of ferrite (α-Fe) and pearlite (α-Fe + Fe3C) and impart desirable properties such as high strength properties and corrosion resistance due to graphite’s cathodic potential. DCI is commonly used for water distribution pipework and contribute to 40% of all drinking water distribution pipes in

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26

"Ammonium Polyphosphate Composite Based Electrolytes for Intermediate Temperature Fuel Cells." ECS Meeting Abstracts, 2012. http://dx.doi.org/10.1149/ma2012-02/13/1404.

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27

Xu, Ke, Robert Oestreich, Takin Haj Hassani Sohi, et al. "Polyphosphonate covalent organic frameworks." Nature Communications 15, no. 1 (2024). http://dx.doi.org/10.1038/s41467-024-51950-1.

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AbstractHerein, we report polyphosphonate covalent organic frameworks (COFs) constructed via P-O-P linkages. The materials are synthesized via a single-step condensation reaction of the charge-assisted hydrogen-bonded organic framework, which is constructed from phenylphosphonic acid and 5,10,15,20‐tetrakis[p‐phenylphosphonic acid]porphyrin and is formed by simply heating its hydrogen-bonded precursor without using chemical reagents. Above 210 °C, it becomes an amorphous microporous polymeric structure due to the oligomerization of P-O-P bonds, which could be shown by constant-time solid-state

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28

Wang, Xunlu, Huashuai Hu, Junnan Song, et al. "Surface Anticorrosion Engineering by Polyphosphate Oxyanions for Durable Seawater Oxidation." Advanced Energy Materials, August 29, 2024. http://dx.doi.org/10.1002/aenm.202402883.

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AbstractElectrolysis of seawater represents great potentials for sustainable hydrogen production. However, both competitive Cl− adsorption and catalysts corrosion caused by chlorine oxidation reaction (ClOR) are major challenges in seawater electrolysis. Inspired by the concept of hard and soft acids and bases (HSAB), polyphosphate oxyanions (P3O105−) on Ni(OH)2 surface is coordinated to obtain harder acid Ni sites, which could obtain 160 times stability enhancement compared to pure Ni(OH)2 for oxygen evolution reaction (OER) in alkaline seawater at 800 mA cm−2. Also, the turnover frequency va

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29

Xie, Huixian, Lingwen Liu, Hongyi Chen, et al. "Fast‐Charging Phosphorus Anodes Enabled by Fluorinated Weakly Solvated Electrolytes for Stable and High‐Rate Lithium Storage." Advanced Materials, May 7, 2025. https://doi.org/10.1002/adma.202504248.

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AbstractPhosphorus‐based anodes hold promise for energy storage due to their high theoretical capacity and favorable lithiation potential. However, their practical application is hindered by sluggish reaction kinetics and irreversible capacity loss, primarily attributed to multiphase lithiation/delithiation reactions and the dissolution of lithium polyphosphide intermediates. Herein, a universal design principle of weakly solvated electrolytes (WSEs) tailored for phosphorus‐based anodes is proposed. Combined with a high dielectric constant, and significant dipole moment, a fluorinated cosolven

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30

Ait-Salah, Atmane, Chintalapalle V. Ramana, François Gendron, et al. "A New Lithium Iron Phosphate LiFe2P3O10 Synthesized at 600 °C from Precursor Obtained by Wet Chemistry." MRS Proceedings 972 (2006). http://dx.doi.org/10.1557/proc-0972-aa06-13.

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AbstractWe present the synthesis and characterization of a novel lithium iron polyphosphate LiFe2P3O10 prepared by wet-chemical technique from nitrate precursors. The crystal system is shown to be monoclinic (P21/m space group) and the refined cell parameters are a=4.596 Å, b=8.566 Å, c=9.051 Å and β=97.46°. LiFe2P3O10 has a weak antiferromagnetic ordering below the Néel temperature TN=19 K. Electrochemical measurements carried out at 25 °C in lithium cell with LiPF6-EC-DEC electrolyte show a capacity 70 mAh/g in the voltage range 2.7-3.9 V.

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31

Yadav, Shashikant, Dipendra Kumar Verma, Rudramani Tiwari, et al. "Sodium‐Ion‐Conducting Alginate‐Based Electrolyte Material for Energy Storage Applications." Energy Technology, March 17, 2025. https://doi.org/10.1002/ente.202401912.

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A green pseudosolid polymer electrolyte is prepared using sodium alginate and sodium polyphosphate via a sustainable solution‐cast method with water as the medium. The amorphous anionic polymer backbone enables easy cationic movement, enhancing ionic conductivity. This water‐in‐salt electrolyte exhibits an electrochemical stability window of 3.2 V and a cationic transport number of 0.90%. Thermal analysis confirms stability up to 150 °C, making it suitable for high‐temperature applications. X‐ray diffraction analysis verifies its amorphous nature, facilitating smooth ion transport, while scann

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32

Billakanti, Srinivas, Anjana K. Othayoth, Heeralal Vignesh Babu, Andikkadu M. Shanmugharaj, Prachuritha Bantumelli, and Krishnamurthi Muralidharan. "2D-Channel-Forming Catechol-Based Polyphosphates as Solid Polymer Electrolytes and Their Microstructure-Assisted Li-Ion Conductivity." ACS Applied Energy Materials, May 3, 2023. http://dx.doi.org/10.1021/acsaem.3c00150.

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33

Li, Yan, Yun‐Chao Yin, Wei Shu, et al. "A Collaboration of Interfacial Engineering and Particle Assembly Enables Highly Stable Li‐Rich Layered Cathodes for Li‐ion Batteries." Advanced Functional Materials, December 4, 2024. https://doi.org/10.1002/adfm.202419603.

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AbstractLithium‐rich layered oxide cathodes (LLO) are renowned for their high specific capacity (>250 mAh g−¹) and have emerged as promising candidates for lithium‐ion batteries. However, significant capacity fades and voltage decay pose challenges to their commercialization, primarily due to the degradation of their original structure. In this study, a simple and rapid approach is presented that combines interfacial engineering and particle assembly to achieve a highly stable LLO cathode. This cathode features a single‐crystal LLO reassembled into a porous microsphere structure, along with

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34

Daffan, Gil, Avinash Kothuru, Assaf Eran, and Fernando Patolsky. "In‐Situ Laser Synthesis of Molecularly Dispersed and Covalently Bound Phosphorus‐Graphene Adducts as Self‐Standing 3D Anodes for High‐Performance Fast‐Charging Lithium‐Ion Batteries." Advanced Energy Materials, June 25, 2024. http://dx.doi.org/10.1002/aenm.202401832.

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AbstractPhosphorus shows promise as a next‐generation anode material due to its high theoretical capacity of 2596 mAh g−1. However, challenges such as low conductivity, severe volume expansion, and the dissolution and migration of electrolyte‐soluble lithium polyphosphides hamper high‐performance capabilities. While carbon composites are widely researched as a solution through the physical encapsulation of micro‐nano‐phosphorus domains, anodes still exhibit low cycling stability and rate performance. In response, this work proposes a new approach, focusing on chemical anchoring and molecular d

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