Academic literature on the topic 'Polypyridyl'

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Journal articles on the topic "Polypyridyl"

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Mazuryk, Olga, Przemysław Gajda-Morszewski, and Małgorzata Brindell. "Versatile Impact of Serum Proteins on Ruthenium(II) Polypyridyl Complexes Properties - Opportunities and Obstacles." Current Protein & Peptide Science 20, no. 11 (October 24, 2019): 1052–59. http://dx.doi.org/10.2174/1389203720666190513090851.

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Ruthenium(II) polypyridyl complexes have been extensively studied for the past few decades as promising anticancer agents. Despite the expected intravenous route of administration, the interaction between Ru(II) polypyridyl compounds and serum proteins is not well characterized and vast majority of the available literature data concerns determination of the binding constant. Ru-protein adducts can modify the biological effects of the Ru complexes influencing their cytotoxic and antimicrobial activity as well as introduce significant changes in their photophysical properties. More extensive res
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O’Neill, Luke, Laura Perdisatt, and Christine O’Connor. "Structure-Property Relationships for a Series of Ruthenium(II) Polypyridyl Complexes Elucidated through Raman Spectroscopy." Journal of Spectroscopy 2018 (November 1, 2018): 1–11. http://dx.doi.org/10.1155/2018/3827130.

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A series of ruthenium polypyridyl complexes were studied using Raman spectroscopy supported by UV/Vis absorption, luminescence spectroscopy, and luminescence lifetime determination by time-correlated single photon counting (TCSPC). The complexes were characterised to determine the influence of the variation of the conjugation across the main polypyridyl ligand. The systematic and sequential variation of the main polypyridyl ligand, 2-(4-formylphenyl)imidazo[4,5-f][1,10]phenanthroline (FPIP), 2-(4-cyanophenyl)imidazo[4,5-f][1,10]phenanthroline (CPIP), 2-(4-bromophenyl)imidazo[4,5-f][1,10]phenan
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Lu, Xiaoqing, Shuxian Wei, Chi-Man Lawrence Wu, Ning Ding, Shaoren Li, Lianming Zhao, and Wenyue Guo. "Theoretical Insight into the Spectral Characteristics of Fe(II)-Based Complexes for Dye-Sensitized Solar Cells—Part I: Polypyridyl Ancillary Ligands." International Journal of Photoenergy 2011 (2011): 1–11. http://dx.doi.org/10.1155/2011/316952.

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The design of light-absorbent dyes with cheaper, safer, and more sustainable materials is one of the key issues for the future development of dye-sensitized solar cells (DSSCs). We report herein a theoretical investigation on a series of polypyridyl Fe(II)-based complexes of FeL2(SCN)2, [FeL3]2+, [FeL′(SCN)3]-, [FeL′2]2+, and FeL′′(SCN)2(L = 2,2′-bipyridyl-4,4′-dicarboxylic acid, L′ = 2,2′,2″-terpyridyl-4,4′,4″-tricarboxylic acid, L″= 4,4‴-dimethyl-2,2′ : 6′,2″ :6″,2‴-quaterpyridyl-4′,4″-biscarboxylic acid) by density functional theory (DFT) and time-dependent DFT (TD-DFT). Molecular geometrie
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Nandhini, T., K. R. Anju, V. M. Manikandamathavan, V. G. Vaidyanathan, and B. U. Nair. "Interactions of Ru(ii) polypyridyl complexes with DNA mismatches and abasic sites." Dalton Transactions 44, no. 19 (2015): 9044–51. http://dx.doi.org/10.1039/c5dt00807g.

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Amiri, Mona, Octavio Martinez Perez, Riley T. Endean, Loorthuraja Rasu, Prabin Nepal, Shuai Xu, and Steven H. Bergens. "Solid-phase synthesis and photoactivity of Ru-polypyridyl visible light chromophores bonded through carbon to semiconductor surfaces." Dalton Transactions 49, no. 29 (2020): 10173–84. http://dx.doi.org/10.1039/d0dt01776k.

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Race, N. A., W. Zhang, M. E. Screen, B. A. Barden, and W. R. McNamara. "Iron polypyridyl catalysts assembled on metal oxide semiconductors for photocatalytic hydrogen generation." Chemical Communications 54, no. 26 (2018): 3290–93. http://dx.doi.org/10.1039/c8cc00453f.

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Pierroz, Vanessa, Riccardo Rubbiani, Christian Gentili, Malay Patra, Cristina Mari, Gilles Gasser, and Stefano Ferrari. "Dual mode of cell death upon the photo-irradiation of a RuIIpolypyridyl complex in interphase or mitosis." Chemical Science 7, no. 9 (2016): 6115–24. http://dx.doi.org/10.1039/c6sc00387g.

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Liu, Ze-Yu, Jin Zhang, Yan-Mei Sun, Chun-Fang Zhu, Yan-Na Lu, Jian-Zhong Wu, Jing Li, Hai-Yang Liu, and Yong Ye. "Photodynamic antitumor activity of Ru(ii) complexes of imidazo-phenanthroline conjugated hydroxybenzoic acid as tumor targeting photosensitizers." Journal of Materials Chemistry B 8, no. 3 (2020): 438–46. http://dx.doi.org/10.1039/c9tb02103e.

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Martin, Aaron, Aisling Byrne, Ciarán Dolan, Robert J. Forster, and Tia E. Keyes. "Solvent switchable dual emission from a bichromophoric ruthenium–BODIPY complex." Chemical Communications 51, no. 87 (2015): 15839–41. http://dx.doi.org/10.1039/c5cc07135f.

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Leem, Gyu, Shahar Keinan, Junlin Jiang, Zhuo Chen, Toan Pho, Zachary A. Morseth, Zhenya Hu, et al. "Ru(bpy)32+ derivatized polystyrenes constructed by nitroxide-mediated radical polymerization. Relationship between polymer chain length, structure and photophysical properties." Polymer Chemistry 6, no. 47 (2015): 8184–93. http://dx.doi.org/10.1039/c5py01289a.

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Dissertations / Theses on the topic "Polypyridyl"

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Zheng, Sipeng. "The reactions of ruthenium (ii) polypyridyl complexes." Thesis, Nelson Mandela Metropolitan University, 2009. http://hdl.handle.net/10948/1089.

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Ruthenium (II) polypyridine complexes in general have been extensively studied because of their unique redox and photochemical properties. A typical example of such complexes is tris(2,2’-bipyridyl) ruthenium (II). In this study, this complex was synthesized and then characterized using electronic spectroscopy and cyclic voltammetry. It was also shown that the ruthenium concentration could be accurately determined using ICP-MS. It was found that the complex is very stable in various chemical environments. It was observed from spectrophotometric investigations that persulphate and lead dioxide
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Williams, R. Lee. "Ruthenium-Platinum Polypyridyl Complexes: Synthesis and Characterization." Thesis, Virginia Tech, 2001. http://hdl.handle.net/10919/44315.

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A series of bimetallic (RuII, PtII) complexes were synthesized with the general formula [(tpy)RuCl(BL)PtCl2](PF6) (tpy = 2,2':6',2"-terpyridine and BL = bridging ligand) and their spectroscopic, electrochemical, and DNA binding properties studied. The bridging ligands used in these complexes were 2,3-bis(2'-pyridyl)pyrazine (dpp), 2,3-bis(2'-pyridyl)quinoxaline (dpq) and 2,3-bis(2'-pyridyl)benzoquinoxaline (dpb). These complexes combine light-absorbing RuII-polypyridyl chromophores and a cis-PtCl2 structural motif known to bind DNA. The Ru-bound chloride may be substituted, enabling furthe
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Johansson, Olof. "Ruthenium(II) Polypyridyl Complexes : Applications in Artificial Photosynthesis." Doctoral thesis, Stockholm : Institutionen för organisk kemi, Univ, 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-93.

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Jones, Lucy. "Two-photon applications of transition metal polypyridyl complexes." Thesis, University of Manchester, 2017. https://www.research.manchester.ac.uk/portal/en/theses/twophoton-applications-of-transition-metal-polypyridyl-complexes(a236f479-d27c-4a92-8b13-bfac51bb14d7).html.

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Materials that undergo two-photon absorbtion (2PA), the simultaneous absorption of two photons, are finding increasing use in many applications including 3D fluorescence microscopy, 3D data storage, and photodynamic therapy (PDT). For efficient use, a large two-photon cross-section is desired which can arise from centrosymmetric charge transfer in push-pull electron donor-acceptor (D-A) diads. These structural motifs have been applied to the construction of organic-based chromophores yielding materials with remarkably high two-photon absorption cross-sections, yet, few metal based examples hav
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Smith, Nichola Ann. "Photoactivatable Ru(II) polypyridyl complexes as antibacterial agents." Thesis, University of Warwick, 2015. http://wrap.warwick.ac.uk/76173/.

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Novel photoactive ruthenium(II) complexes were designed to incorporate existing anti-tuberculosis drugs, isoniazid and nicotinamide, that could be released from the ruthenium(II) cage by photoactivation with visible light. Two sets of complexes were synthesised based on cis-[Ru(N-N')2(L)2][PF6]2and cis-[Ru(N-N')2(L)X][PF6], where N-N' is 2,2'-bipyridine (bpy) or 1,10-phenanthroline (phen), L is isoniazid (INH) or nicotinamide (NA) and X is either Cl or I. Their dynamic behaviour in solution was explored using NMR to probe the presence of atropisomers. In the case of cis-[Ru(bpy)2(NA)Cl][PF6] (
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Greguric, Antun, University of Western Sydney, of Science Technology and Environment College, and of Science Food and Horticulture School. "The DNA binding interactions of Ru(II) polypyridyl complexes." THESIS_CSTE_SFH_Greguric_A.xml, 2002. http://handle.uws.edu.au:8081/1959.7/620.

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This thesis reports on the synthesis, characterisation, enantiomeric resolution, 1H NMR structural study and physical evaluation of a series of certain bidentate ligand metal complexes, where ‘L-L’ denotes the ancillary bidentate ligand and ‘intercalator’ indicates the intercalating bidentate ligand. The L-L series varies in size and shape. Results of many tests and projects conducted are explained in detail.<br>Master of Science (Hons)
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McDonnell, Ursula J. "Synthesis and DNA Binding of Novel Ruthenium Polypyridyl Complexes." Thesis, University of Warwick, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.526217.

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Yang, Mei. "Iron(II) and ruthenium(II) polypyridyl complexes as photosensitizers." Available to US Hopkins community, 2003. http://wwwlib.umi.com/dissertations/dlnow/3080801.

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Greguric, Antun. "The DNA binding interactions of Ru(II) polypyridyl complexes." Thesis, View thesis View thesis, 2002. http://handle.uws.edu.au:8081/1959.7/620.

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This thesis reports on the synthesis, characterisation, enantiomeric resolution, 1H NMR structural study and physical evaluation of a series of certain bidentate ligand metal complexes, where ‘L-L’ denotes the ancillary bidentate ligand and ‘intercalator’ indicates the intercalating bidentate ligand. The L-L series varies in size and shape. Results of many tests and projects conducted are explained in detail.
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Greguric, Antun. "The DNA binding interactions of Ru(II) polypyridyl complexes /." View thesis View thesis, 2002. http://library.uws.edu.au/adt-NUWS/public/adt-NUWS20030410.094714/index.html.

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Thesis (M. Sc.) (Hons.) -- University of Western Sydney, 2002.<br>A thesis presented to the University of Western Sydney in partial fulfilment of the rquirements for the degree of Master of Science (Honours), February, 2002. Includes bibliographical references.
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Book chapters on the topic "Polypyridyl"

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Orkey, Nikita, Paul Wormell, and Janice Aldrich-Wright. "Ruthenium Polypyridyl Metallointercalators." In Metallointercalators, 27–67. Vienna: Springer Vienna, 2011. http://dx.doi.org/10.1007/978-3-211-99079-7_2.

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Serpone, N., and M. Z. Hoffman. "Multiphoton-Induced Picosecond Photophysics of Chromium(III)- Polypyridyl Complexes." In Photochemistry and Photophysics of Coordination Compounds, 61–67. Berlin, Heidelberg: Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-72666-8_12.

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Gill, Martin R., and Jim A. Thomas. "Targeting cellular DNA with Luminescent Ruthenium(II) Polypyridyl Complexes." In Ruthenium Complexes, 221–38. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2017. http://dx.doi.org/10.1002/9783527695225.ch11.

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Orellana, Guillermo, and David García-Fresnadillo. "Environmental and Industrial Optosensing with Tailored Luminescent Ru(II) Polypyridyl Complexes." In Optical Sensors, 309–57. Berlin, Heidelberg: Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-662-09111-1_13.

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Smeigh, Amanda L., and James K. McCusker. "Ultrafast Dynamics of Fe(II) Polypyridyl Chromophores: Design Implications for Dye-Sensitized Photovoltaics." In Ultrafast Phenomena XV, 273–75. Berlin, Heidelberg: Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-68781-8_88.

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Hoffman, M. Z., and N. Serpone. "Excited State Behavior as a Probe of Ground-State Ion-Pair Interactions in Chromium(III)-Polypyridyl Complexes." In Photochemistry and Photophysics of Coordination Compounds, 43–47. Berlin, Heidelberg: Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-72666-8_9.

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Srikanth, K., and Manoj K. Mishra. "Role of Electronic Structure of Ruthenium polypyridyl Dyes in the Photoconversion Efficiency of Dye - Sensitized Solar cells: A Semi-Empirical Investigation." In Current Developments in Atomic, Molecular, and Chemical Physics with Applications, 135–41. Boston, MA: Springer US, 2002. http://dx.doi.org/10.1007/978-1-4615-0115-2_18.

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Palmer, Richard A., Pingyun Chen, Susan E. Plunkett, and James L. Chao. "Excited State Structure and Relaxation Dynamics of Polypyridyl Complexes of Low Spin d 6 Metal Ions by Means of Step-Scan FTIR Time-Resolved Spectroscopy (S2FT-IR TRS)." In Progress in Fourier Transform Spectroscopy, 595–97. Vienna: Springer Vienna, 1997. http://dx.doi.org/10.1007/978-3-7091-6840-0_149.

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Tsubonouchi, Yuta, Eman A. Mohamed, Zaki N. Zahran, and Masayuki Yagi. "Mechanisms of Photoisomerization and Water Oxidation Catalysis of Ruthenium(II) Aquo Complexes." In Ruthenium - an Element Loved by Researchers [Working Title]. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.99730.

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Polypyridyl ruthenium(II) complexes have been widely researched as promising functional molecules. We have found unique photoisomerization reactions of polypyridyl ruthenium(II) aquo complexes. Recently we have attempted to provide insight into the mechanism of the photoisomerization of the complexes and distinguish between the distal−/proximal-isomers in their physicochemical properties and functions. Moreover, polypyridyl ruthenium(II) aquo complexes have been intensively studied as active water oxidation catalysts (WOCs) which are indispensable for artificial photosynthesis. The catalytic aspect and mechanism of water oxidation by the distal-/proximal-isomers of polypyridyl ruthenium(II) aquo complexes have been investigated to provide the guided thought to develop more efficient molecular catalysts for water oxidation. The recent progress on the photoisomerization and water oxidation of polypyridyl ruthenium(II) aquo complexes in our group are reviewed to understand the properties and functions of ruthenium complexes.
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Kumar, Pramod, and Sushil Kumar. "Detection of Bio-Relevant Metal Ions by Luminescent Ru(II)-Polypyridyl Based Sensors." In Ruthenium - an Element Loved by Researchers [Working Title]. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.96453.

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Biorelevant metal ions such as Cu2+ and Fe2+/Fe3+ participate in various biological events which include electron transfer reactions, delivery and uptake of oxygen, DNA and RNA syntheses, and enzymatic catalysis to maintain fundamental physiological processes in living organisms. So far, several analytical techniques have been investigated for their precise detection; however, luminescence-based sensing is often superior due to its high sensitivity, selectivity, fast and easy operation and convenient cellular imaging. Owing to their immense photophysical and photochemical properties stemming from large Stokes shift, absorption in visible region, good photostability and long excited state lifetimes, Ru(II)-polypyridyl-based complexes have gained increasing interest as luminophores. Over past few decades, several Ru(II)-polypyridyl based chemosensors have rapidly been developed for detection of different biorelevant and other metal ions. The main object of this book chapter is to cover a majority of Ru(II)-polypyridyl based chemosensors showing a selective and sensitive detection of bio-relevant Cu2+ and Fe2+/Fe3+ ions. The photophysical properties of Ru(II) complexes, detection of metal ions, sensing mechanism and applications of these sensors are discussed at a length.
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Conference papers on the topic "Polypyridyl"

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Pong, R. G. S., S. R. Flora, J. S. Shirk, T. V. Duncan, and M. J. Therien. "Nonlinear transmission of highly conjugated (polypyridyl)metal-(porphinato)zinc(II) compounds." In 2005 Conference on Lasers and Electro-Optics (CLEO). IEEE, 2005. http://dx.doi.org/10.1109/cleo.2005.202349.

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Durand, Nicolas, Paul Savel, Huriye Akdas-Kilic, Abdou Boucekkine, Jean-Pierre Malval, and Jean-Luc Fillaut. "Polypyridyl Ruthenium Complexes: Versatile Tools for Linear and Non-Linear Optics." In 2019 21st International Conference on Transparent Optical Networks (ICTON). IEEE, 2019. http://dx.doi.org/10.1109/icton.2019.8840409.

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Zhang, Ye, Ning Zhou, and Bing Xu. "Cell Compatible Polypyridyl Ru-Complex Based Fluorophore as Long-Life Lysosome Tracker." In Biomedical Optics. Washington, D.C.: OSA, 2014. http://dx.doi.org/10.1364/biomed.2014.bt3a.53.

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Gordon, Keith C., Michael G. Fraser, Raphael Horvath, P. M. Champion, and L. D. Ziegler. "Resonance Raman Spectroscopy Of Rhenium(I) Complexes With Sulfur-Containing Polypyridyl Ligands." In XXII INTERNATIONAL CONFERENCE ON RAMAN SPECTROSCOPY. AIP, 2010. http://dx.doi.org/10.1063/1.3482689.

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Smeigh, Amanda L., and James K. McCusker. "Ultrafast Dynamics of Fe(II) Polypyridyl Chromophores: Design Implications for Dye-Sensitized Photovoltaics." In International Conference on Ultrafast Phenomena. Washington, D.C.: OSA, 2006. http://dx.doi.org/10.1364/up.2006.wd3.

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Israil, R., L. Schüssler, M. Schmitt, M. Grupe, P. Hütchen, W. R. Thiel, R. Diller, and C. Riehn. "Ultrafast Dynamics of RuII-polypyridyl Complexes – Photoinduced Ligand Dissociation Dynamics in Gas Phase and Solution." In International Conference on Ultrafast Phenomena. Washington, D.C.: Optica Publishing Group, 2022. http://dx.doi.org/10.1364/up.2022.tu4a.4.

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Ultrafast electronic dynamics and UV absorption of [RuII(bipyridine)2(nicotinamide)2]2+ isolated in an ion trap reveal by transient photodissociation short time constants and spectra comparable to transient absorption in solution. Ligand dissociation dynamics are elucidated.
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Handy, Erik S., Erika D. Abbas, Amlan J. Pal, and Michael F. Rubner. "Development of the tris-chelated polypyridyl ruthenium (II) complex as a solid state light emitter." In SPIE's International Symposium on Optical Science, Engineering, and Instrumentation, edited by Zakya H. Kafafi. SPIE, 1998. http://dx.doi.org/10.1117/12.332600.

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Miloradovic, Ivan R., Yuxia Zhao, Kurt Wostyn, Inge Asselberghs, H. T. Uyeda, Andre P. Persoons, Koen J. Clays, and Michael J. Therien. "Effect of electronic structure on molecular first hyperpolarizabilities of highly conjugated (polypyridyl)metal-(porphinato)zinc(II) chromophores." In Optical Science and Technology, SPIE's 48th Annual Meeting, edited by Mark G. Kuzyk, Manfred Eich, and Robert A. Norwood. SPIE, 2003. http://dx.doi.org/10.1117/12.509147.

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Premkumar, P., Krishnan Namboori P.K., M. Sathishkumar, K. I. Ramachandran, and Deepa Gopakumar. "Quantum Mechanical Modeling and Molecular Dynamic Simulation of Ruthenium (Ru) Polypyridyl Complexes to Study Feasibility of Artificial Photosynthesis." In 2009 International Conference on Advances in Recent Technologies in Communication and Computing. ARTCom 2009. IEEE, 2009. http://dx.doi.org/10.1109/artcom.2009.129.

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Reports on the topic "Polypyridyl"

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Steffan, C. Reactions of the excited state of polypyridyl chromium(III) ion. Office of Scientific and Technical Information (OSTI), September 1990. http://dx.doi.org/10.2172/6764870.

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