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Journal articles on the topic 'Polysulphides'

Author: Grafiati

Published: 4 June 2021

Last updated: 28 July 2025

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1

Balach, J., T. Jaumann, S. Mühlenhoff, J. Eckert, and L. Giebeler. "Enhanced polysulphide redox reaction using a RuO2 nanoparticle-decorated mesoporous carbon as functional separator coating for advanced lithium–sulphur batteries." Chemical Communications 52, no. 52 (2016): 8134–37. http://dx.doi.org/10.1039/c6cc03743g.

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A multi-functional RuO<sub>2</sub> nanoparticle-embedded mesoporous carbon-coated separator is used as an electrocatalytic and adsorbing polysulphide-net to enhance the redox reaction of migrating polysulphides.

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2

Kolosnitsyn, Vladimir Sergeevich, Aleksei Leonidovich Ivanov, Elena Vladimirovna Karaseva, Elena Vladimirovna Kuz'mina, and Sergei Ernstovich Mochalov. "The effect of lithium polysulphides on the cycling performance of a lithium electrode in 1M LiClO4 in sulfolane." Electrochemical Energetics 13, no. 3 (2013): 144–49. http://dx.doi.org/10.18500/1608-4039-2013-13-3-144-149.

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The effect of lithium polysulphides on the cyclic deposition/and dissolution of lithium metal on an inert stainless steel electrode and on a lithium metal electrode in sulfolane solutions has been studied. It has been shown that the addition of lithium polysulphides to sulfolane solutions leads to a significant increase in the cycle life (2 or more times) and cycling efficiency of a lithium metal electrode and a lithium metal on inert stainless steel electrode. It also results in the reduction of the corrosion rate of the lithium cathodic deposits. The positive influence of lithium polysulphid

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3

Cleaver, Brian, and Stephen M. Upton. "Properties of fused Polysulphides—VIII. Sulphur activity and polysulphide chain-length distribution in molten lithium and sodium polysulphides and their mixtures." Electrochimica Acta 36, no. 3-4 (1991): 679–87. http://dx.doi.org/10.1016/0013-4686(91)85158-4.

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4

Takaoka, P. T., and J. J. Ganczarczyk. "Feasibility of Polysulfide Detoxification of Concentrated Waste-water." Water Quality Research Journal 20, no. 1 (1985): 118–28. http://dx.doi.org/10.2166/wqrj.1985.010.

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Abstract Collecting of concentrated cyanide solutions in electroplating shops is quite a common occurrence. These accumulations of 4.5 to 9.0 cu m volume, which may be collected over a period of years, are usually in the concentration range of 1 to 3 per cent cyanide and present considerable dangers as they are stored on-site or transported for treatment or disposal. Common technologies available for the treatment of cyanide-containing wastewaters are generally not applicable to concentrated cyanide solutions, and some special technologies which could be applicable, usually show high capital c

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5

Buemi, Giuseppe, Felice Zuccarello, and Antonio Raudino. "Conformational study of cyclic polysulphides." Journal of Molecular Structure: THEOCHEM 167, no. 3-4 (1988): 245–51. http://dx.doi.org/10.1016/0166-1280(88)80229-x.

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6

Cleaver, Brian, and Stephen M. Upton. "Properties of fused polysulphides—VI. Preparation, density and electrical conductivity of molten lithium polysulphides." Electrochimica Acta 36, no. 3-4 (1991): 667–71. http://dx.doi.org/10.1016/0013-4686(91)85156-2.

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7

Andrea Wilford, Mrs. "Odour‐free polysulphides for epoxy modification." Pigment & Resin Technology 18, no. 3 (1989): 12–15. http://dx.doi.org/10.1108/eb042592.

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8

Benevides, Paulo José Coelho, Maria Claudia M. Young, Astréa M. Giesbrecht, Nı́dia F. Roque, and Vanderlan da S. Bolzani. "Antifungal polysulphides from Petiveria alliacea L." Phytochemistry 57, no. 5 (2001): 743–47. http://dx.doi.org/10.1016/s0031-9422(01)00079-6.

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9

Chernyshev, E. A., O. V. Kuz'min, A. V. Lebedev, V. G. Zaikin, and A. I. Mikaya. "Pyrolysis of silicon-containing cyclic polysulphides." Journal of Organometallic Chemistry 289, no. 2-3 (1985): 231–37. http://dx.doi.org/10.1016/0022-328x(85)87400-3.

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10

Angulakshmi, N., R. Baby Dhanalakshmi, Paulina Półrolniczak, et al. "An efficient bi-functional permselective separator coated with cubic type-Li7La3Zr2O12 and activated carbon for lithium–sulfur batteries." Sustainable Energy & Fuels 4, no. 7 (2020): 3500–3510. http://dx.doi.org/10.1039/d0se00594k.

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Controlling the shuttling of lithium polysulphides (LiPS) to enhance the utilization of elemental sulfur has been considered as an important issue to improve the energy density and coulombic efficiency of lithium–sulfur batteries.

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11

Zhang, Sheng S. "The redox mechanism of FeS2 in non-aqueous electrolytes for lithium and sodium batteries." Journal of Materials Chemistry A 3, no. 15 (2015): 7689–94. http://dx.doi.org/10.1039/c5ta00623f.

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Electrochemical processes of FeS<sub>2</sub> in non-aqueous electrolytes are reviewed and proposed to consist of two conversion reactions between sulphur or lithium polysulphides and sulphide for the upper voltage plateau and between FeS and metallic Fe for the lower voltage plateau.

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12

Kopczyński, Kacper, Grzegorz Milczarek, and Grzegorz Lota. "Polysulphides reversible faradaic reactions in supercapacitor application." Electrochemistry Communications 68 (July 2016): 28–31. http://dx.doi.org/10.1016/j.elecom.2016.04.016.

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13

Rämö, J., M. Sillanpää, and O. Hyökyvirta. "Interactions between polysulphides and stainless steel materials." Materials and Corrosion 54, no. 1 (2003): 37–39. http://dx.doi.org/10.1002/maco.200390004.

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14

Kohnen, M. E. L., J. S. Sinninghe Damsté, H. L. ten Haven, and J. W. de Leeuw. "Early incorporation of polysulphides in sedimentary organic matter." Nature 341, no. 6243 (1989): 640–41. http://dx.doi.org/10.1038/341640a0.

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15

Singer, Eris, та H. J. Möckel. "RPLC retention of 1,ω-di(alkoxy)-polysulphides". Chromatographia 27, № 1-2 (1989): 27–30. http://dx.doi.org/10.1007/bf02290400.

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16

Sharivker, V. S., S. K. Ratkje, and B. Cleaver. "Determination of the entropy of molten disodium polysulphides." Electrochimica Acta 41, no. 15 (1996): 2381–84. http://dx.doi.org/10.1016/0013-4686(96)00017-5.

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17

Gaillard, F., E. Levillain, M. C. Dhamelincourt, P. Dhamelincourt, and J. P. Lelieur. "Polysulphides in dimethylformamide: a micro-Raman spectroelectrochemical study." Journal of Raman Spectroscopy 28, no. 7 (1997): 511–17. http://dx.doi.org/10.1002/(sici)1097-4555(199707)28:7<511::aid-jrs119>3.0.co;2-4.

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18

V., BALIAH, and APARAJITHAN K. "Dipole Moments of Polyphenylene Polyethers and Polyphenylene Polysulphides." Journal of Indian Chemical Society Vol. 68, Nov 1991 (1991): 593–95. https://doi.org/10.5281/zenodo.5968867.

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Department of Chemistry, Annamalai University, Annamalainagar-608 002 <em>Manuscript received 19 January 1990, revised 19 August 1991, accepted 7 November 1991</em> The dipole moments or some polyphenylene polyethers and polyphenylene polysulphides have been determined and the values compared with the calculated ones assuming free rotation of all the dipoles. The lack of agreement between the two values for C<sub>6</sub>H<sub>6</sub>OC<sub>6</sub>H<sub>4</sub>OC<sub>6</sub>H<sub>4</sub>OC<sub>6</sub>H<sub>4</sub>OC<sub>6</sub>H<sub>5  </sub>C<sub>6</sub>H<sub>6</sub>SC<sub>6</sub>H<s

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19

Khutoryanskiy, V. A., O. V. Kustova, V. V. Khakhinov, I. D. Ulzetueva, and A. G. Gorshkov. "Polysulphides of Thermal Sulphide Waters of Republic of Buryat." Bulletin of Irkutsk State University. Series Earth Sciences 23 (2018): 106–21. http://dx.doi.org/10.26516/2073-3402.2018.23.106.

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20

McGrath, L., and K. A. Prebble. "Organic polysulphides in town gas: I. The corrosion problem." Journal of Applied Chemistry and Biotechnology 22, no. 7 (2007): 811–21. http://dx.doi.org/10.1002/jctb.5020220703.

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21

Cuisinier, M., P. E. Cabelguen, B. D. Adams, A. Garsuch, M. Balasubramanian, and L. F. Nazar. "Unique behaviour of nonsolvents for polysulphides in lithium–sulphur batteries." Energy Environ. Sci. 7, no. 8 (2014): 2697–705. http://dx.doi.org/10.1039/c4ee00372a.

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Combination of a solvent–salt complex [acetonitrile(ACN)<sub>2</sub>–LiTFSI] with a hydrofluoroether (HFE) co-solvent unveils a new class of Li–S battery electrolytes that possess essentially no solubility for lithium polysulfides, yet exhibit excellent capacity and very good rate capability..

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22

Moers, M. E. C., J. W. de Leeuw, H. C. Cox, and P. A. Schenck. "Interaction of glucose and cellulose with hydrogen sulphide and polysulphides." Organic Geochemistry 13, no. 4-6 (1988): 1087–91. http://dx.doi.org/10.1016/0146-6380(88)90293-8.

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23

Paris, J., G. Bosser, and V. Plichon. "Complex formation between S−6 and organic polysulphides in dimethylacetamide." Electrochimica Acta 31, no. 4 (1986): 457–61. http://dx.doi.org/10.1016/0013-4686(86)80109-8.

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24

Dominko, Robert, Rezan Demir-Cakan, Mathieu Morcrette, and Jean-Marie Tarascon. "Analytical detection of soluble polysulphides in a modified Swagelok cell." Electrochemistry Communications 13, no. 2 (2011): 117–20. http://dx.doi.org/10.1016/j.elecom.2010.11.029.

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25

De Graaf, Wim, Jaap S. Sinninghe Damsté, and Jan W. de Leeuw. "Laboratory simulation of natural sulphurization: I. Formation of monomeric and oligomeric isoprenoid polysulphides by low-temperature reactions of inorganic polysulphides with phytol and phytadienes." Geochimica et Cosmochimica Acta 56, no. 12 (1992): 4321–28. http://dx.doi.org/10.1016/0016-7037(92)90275-n.

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26

Sharivker, V. S. "Thermodynamics and Kinetics of Electrode Processes in Sodium and Potassium Polysulphides." ECS Proceedings Volumes 1994-13, no. 1 (1994): 828–33. http://dx.doi.org/10.1149/199413.0828pv.

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27

Wajon, J. E., R. Alexander, and R. I. Kagi. "Determination of trace levels of dimethyl polysulphides by capillary gas chromatography." Journal of Chromatography A 319 (January 1985): 187–94. http://dx.doi.org/10.1016/s0021-9673(01)90553-9.

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28

Cleaver, Brian, and Stephen M. Upton. "Properties of fused polysulphides—VII. The phase diagram Li2S/Na2S/S." Electrochimica Acta 36, no. 3-4 (1991): 673–77. http://dx.doi.org/10.1016/0013-4686(91)85157-3.

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29

Phadke, Satyajit, Julie Pires, Alexander Korchenko, and Mérièm Anouti. "How do organic polysulphides improve the performance of Li-S batteries?" Electrochimica Acta 330 (January 2020): 135253. http://dx.doi.org/10.1016/j.electacta.2019.135253.

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30

Kn�dler, Reinhard. "Kinetics of thermal cycling of sodium polysulphides in sodium/sulphur cells." Journal of Materials Science Letters 4, no. 8 (1985): 1038–41. http://dx.doi.org/10.1007/bf00721114.

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31

Shapkin, N. P., V. I. Nedelkin, G. M. Svistunov та V. A. Sergeev. "Synthesis and properties of polysulphides based on trifunctional metal β-diketonates". Polymer Science U.S.S.R. 32, № 9 (1990): 1824–31. http://dx.doi.org/10.1016/0032-3950(90)90292-e.

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32

Keusgen, Michael. "Unusual Cystine Lyase Activity of the Enzyme Alliinase: Direct Formation of Polysulphides." Planta Medica 74, no. 1 (2008): 73–79. http://dx.doi.org/10.1055/s-2007-993777.

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33

Smart, Roger St C., William M. Skinner, and Andrea R. Gerson. "XPS of sulphide mineral surfaces: metal-deficient, polysulphides, defects and elemental sulphur." Surface and Interface Analysis 28, no. 1 (1999): 101–5. http://dx.doi.org/10.1002/(sici)1096-9918(199908)28:1<101::aid-sia627>3.0.co;2-0.

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34

Tripathi, Balram, Claudia C. Zuluaga Gomez, Ivan Castillo, et al. "Bi₂O₃ Intercalated SWCNT/Sulphur (S) Composite Electrodes for Stable & High Performance Li-S Batteries." ECS Meeting Abstracts MA2023-01, no. 2 (2023): 581. http://dx.doi.org/10.1149/ma2023-012581mtgabs.

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In the present work, bismuth oxide (Bi2O3) nanoparticles have been coupled chemically with SWCNT/sulphur (S) composites. Here an architecture constructed by rooting bismuth oxide into SWCNT/sulphur composites could enhance the electrochemical performance of the system. X-ray diffraction (XRD), Raman & Scanning electron microscopy (SEM) measurements of prepared composites were executed to study structural and morphological properties. High theoretical discharge capacity (690 mAh/g) and rate capability expected due to favourable surface structures of SWCNT/S composites which may cause fast r

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35

Kim, Soochan, and Youngkwan Lee. "Electropolymerisation Technologies for Next-Generation Lithium–Sulphur Batteries." Polymers 15, no. 15 (2023): 3231. http://dx.doi.org/10.3390/polym15153231.

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Lithium–sulphur batteries (LiSBs) have garnered significant attention as the next-generation energy storage device because of their high theoretical energy density, low cost, and environmental friendliness. However, the undesirable “shuttle effect” by lithium polysulphides (LPSs) severely inhibits their practical application. To alleviate the shuttle effect, conductive polymers have been used to fabricate LiSBs owing to their improved electrically conducting pathways, flexible mechanical properties, and high affinity to LPSs, which allow the shuttle effect to be controlled. In this study, the

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36

McGrath, L., and K. A. Prebble. "Organic polysulphides in town gas: II. The chemistry of the mercaptan/sulphur reaction." Journal of Applied Chemistry and Biotechnology 22, no. 7 (2007): 823–37. http://dx.doi.org/10.1002/jctb.5020220704.

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37

Kage, S., T. Nagata, and K. Kudo. "Determination of polysulphides in blood by gas chromatography and gas chromatography—mass spectrometry." Journal of Chromatography B: Biomedical Sciences and Applications 564, no. 1 (1991): 163–69. http://dx.doi.org/10.1016/0378-4347(91)80078-q.

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38

Montaudo, Giorgio, Emilio Scamporrino, Concetto Puglisi, and Daniele Vitalini. "Identification of pyrolysis products of polysulphides by collisionally activated decomposition linked scanning mass spectrometry." Journal of Analytical and Applied Pyrolysis 10, no. 4 (1987): 283–90. http://dx.doi.org/10.1016/0165-2370(87)80018-9.

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39

Marquardt, Ute, H. J. Möckel та S. F. Nelsen. "Retention of 1,ω-bis-(dialkylamino)-polysulphides and related compounds in reversed-phase HPLC". Chromatographia 27, № 3-4 (1989): 113–17. http://dx.doi.org/10.1007/bf02265861.

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40

Montaudo, G., E. Scamporrino, C. Puglisi, and D. Vitalini. "Thermal decomposition processes in alphatic-aromatic polysulphides investigated by electron impact and chemical ionization mass spectrometry." Polymer 28, no. 3 (1987): 477–83. http://dx.doi.org/10.1016/0032-3861(87)90202-3.

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41

Jusupova, A. A., R. T. Akhmetova, L. R. Baraeva, G. A. Medvedeva, and Zh V. Mezhevich. "Development of low-waste technology for the processing of sulphur into polysulphides and materials based on them." IOP Conference Series: Materials Science and Engineering 450 (November 30, 2018): 062007. http://dx.doi.org/10.1088/1757-899x/450/6/062007.

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42

Schouten, Stefan, Wim de Graaf, Jaap S. Sinninghe Damsté, Giel B. van Driel, and Jan W. de Leeuw. "Laboratory simulation of natural sulphurization: II. Reaction of multi-functionalized lipids with inorganic polysulphides at low temperatures." Organic Geochemistry 22, no. 3-5 (1994): 825—IN14. http://dx.doi.org/10.1016/0146-6380(94)90142-2.

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43

Kim, Heekang, Frank Rosenblum, Ozan Kökkılıç, and Kristian Waters. "Role of Elemental Sulphur in Stage B Self-Heating of Sulphide Minerals, and the Potential Role of Polysulphides." Minerals 13, no. 7 (2023): 923. http://dx.doi.org/10.3390/min13070923.

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Sulphide minerals undergo numerous stages of mineral processing to extract the desired metal. When they are exposed to certain environmental conditions, some sulphide minerals can spontaneously heat up, a process called self-heating (SH), which, if left unchecked, can be a major hazard. Self-heating occurs in three distinct temperature stages, termed Stage A (temperature below 100 °C), Stage B (temperature range of 100 °C–350 °C), and Stage C (above 350 °C). Historically, it was understood that elemental sulphur generated in Stage A fuels Stage B reactions; however, the full extent of this beh

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44

Thomas, J. D. R. "Ion-selective electrode and enzyme sensors for flow-type environmental analysis." Collection of Czechoslovak Chemical Communications 56, no. 1 (1991): 178–91. http://dx.doi.org/10.1135/cccc19910178.

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Illustrative examples from researches in the author’s laboratories are given of potentiometric ion-selective electrodes (ISEs) and catalytic membrane amperometric electrodes suitable for environmental analysis. The uses of sulphide ISEs are demonstrated for monitoring the activities of sulphate-reducing bacteria, in effluent analysis for sulphide, and in process/effluent analysis for sulphide, thiols and polysulphides. Diquat and paraquat ISEs are discussed in relation to their optimisation in terms of appropriate crown ether and ion-pairing agents, together with prospects of their uses. Catal

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45

Roberts, N. J., H. R. Burton, and G. A. Pitson. "Volatile organic compounds from Organic Lake, an Antarctic, hypersaline, meromictic lake." Antarctic Science 5, no. 4 (1993): 361–66. http://dx.doi.org/10.1017/s0954102093000483.

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Five volatile organic compounds were identified throughout 1991 in the hypolimnion of Organic Lake. These were dimethylsulphide (DMS), dimethyldisulphide (DM2S), dimethyltrisulphide (DM3S), dimethyltetrasulphide (DM4S) and phenol. The concentration of these compounds increased with lake depth. The concentration of DMS and DM2S was higher in the sediment than in the water column. Carbon disulphide occurred only in the sediment. DMS was the only volatile organic compound detected in the epilimnion of the lake, where its concentration increased from winter onwards. The source of DMS was not dimet

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46

Mycroft, J. R., G. M. Bancroft, N. S. McIntyre, J. W. Lorimer, and I. R. Hill. "Detection of sulphur and polysulphides on electrochemically oxidized pyrite surfaces by X-ray photoelectron spectroscopy and Raman spectroscopy." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 292, no. 1-2 (1990): 139–52. http://dx.doi.org/10.1016/0022-0728(90)87332-e.

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47

Mirza, Jahangir. "JOINT SEALS FOR HYDRAULIC STRUCTURES IN SEVERE CLIMATES." JOURNAL OF CIVIL ENGINEERING AND MANAGEMENT 20, no. 1 (2014): 38–46. http://dx.doi.org/10.3846/13923730.2013.799092.

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This paper presents laboratory test data on 21 joint seals: 10 field-moulded sealants (FMS; 1- and 2-components polyurethanes, polysulphides, silicones, etc.) and 11 preformed seals (neoprene, silicone, high-density open-cell and low-density closed-cell foams, etc.). The aim was to evaluate their performance in submerged, partially submerged and essentially dry conditions in extremely severe climates. These seals were tested on cement mortar substrates as well as on steel substrates. The tests carried out on FMS were: adhesion-in-peel strength, compression-extension cycling at severe temperatu

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48

Hojaji, Elaheh, Eleftherios I. Andritsos, Zhuangnan Li, Manish Chhowalla, Constantina Lekakou, and Qiong Cai. "DFT Simulation-Based Design of 1T-MoS2 Cathode Hosts for Li-S Batteries and Experimental Evaluation." International Journal of Molecular Sciences 23, no. 24 (2022): 15608. http://dx.doi.org/10.3390/ijms232415608.

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The main challenge in lithium sulphur (Li-S) batteries is the shuttling of lithium polysulphides (LiPSs) caused by the rapid LiPSs migration to the anode and the slow reaction kinetics in the chain of LiPSs conversion. In this study, we explore 1T-MoS2 as a cathode host for Li-S batteries by examining the affinity of 1T-MoS2 substrates (pristine 1T-MoS2, defected 1T-MoS2 with one and two S vacancies) toward LiPSs and their electrocatalytic effects. Density functional theory (DFT) simulations are used to determine the adsorption energy of LiPSs to these substrates, the Gibbs free energy profile

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49

Iranshahi, Mehrdad, Mohammad Hassanzadeh-Khayat, Bibi Sedigheh Fazly Bazzaz, Zahra Sabeti, and Fatemeh Enayati. "High Content of Polysulphides in the Volatile Oil ofFerula latisectaRech. F. et Aell. Fruits and Antimicrobial Activity of the Oil." Journal of Essential Oil Research 20, no. 2 (2008): 183–85. http://dx.doi.org/10.1080/10412905.2008.9699986.

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50

Chadha, Utkarsh, Preetam Bhardwaj, Sanjeevikumar Padmanaban, et al. "Review—Carbon Electrodes in Magnesium Sulphur Batteries: Performance Comparison of Electrodes and Future Directions." Journal of The Electrochemical Society 168, no. 12 (2021): 120555. http://dx.doi.org/10.1149/1945-7111/ac4104.

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Magnesium-sulfur batteries have developed as a new and emerging technology benefiting from high energy density, low cost, reasonable safety, and excellent energy storage due to the high natural abundance of electrochemically active materials and low dendrite formation in magnesium. Here we report various enhancement strategies and also focus on using carbon electrodes, coating layers of carbon over the cathodes, carbon nanotubes, reduced graphene oxide, graphene-carbon nanotubes in magnesium-sulfur batteries because of its high conductivity and improved overall electrochemical functioning of t

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