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1

Bezik, Cody. "Poly(High Internal Phase Emulsion) Foams and Fibers: Structure-Property Relationships." Case Western Reserve University School of Graduate Studies / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=case1436458970.

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2

Khan, Amir. "Vibro-acoustic products from re-cycled raw materials using a cold extrusion process : a continuous cold extrusion process has been developed to tailor a porous structure from polymeric waste, so that the final material possesses particular vibro-acoustic properties." Thesis, University of Bradford, 2008. http://hdl.handle.net/10454/4289.

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A cold extrusion process has been developed to tailor a porous structure from polymeric waste. The use of an extruder to manufacture acoustic materials from recycled waste is a novel idea and the author is not aware of any similar attempts. The extruder conveys and mixes the particulates with a reacting binder. The end result is the continuous production of bound particulates through which a controlled amount of carbon dioxide gas that is evolved during the reaction is used to give the desired acoustic properties. The cold extrusion process is a low energy consuming process that reprocesses th
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3

Шемедюк, О. Л. "Метаматеріали на основі пористих полімерних структур з властивостями невідбиваючого поглинання ультразвукової хвилі". Thesis, Сумський державний університет, 2016. http://essuir.sumdu.edu.ua/handle/123456789/45750.

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Метаматеріали синтезуються введенням у природній матеріал періодичних структур різних геометричних форм, які модифікують властивості початкового матеріалу. Пористий метаекран, тобто один шар газових включень в пластичну і тверду речовину, може бути змодельований у вигляді відкритого резонатора акустичної хвилі, поведінка якого описується певними аналітичними виразами. Розрахунок параметрів поздовжньої хвилі у такій структурі доволі складний. Проте не так давно була запропонована відносно проста модель для розрахунку коефіцієнтів пропускання і відбивання УЗ-хвиль від одного шару пор метаекрану,
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4

Gonçalves, Bianca Leopoldo. "Porous structures for the purification of biopharmaceuticals." Master's thesis, Faculdade de Ciências e Tecnologia, 2014. http://hdl.handle.net/10362/12128.

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This work aimed at the development of a (bio)polymeric monolithic support for biopharmaceuticals purification and/or capture. For that, it was assured that functional groups on its surface were ready to be involved in a plethora of chemical reactions for incorporation of the desired and most suitable ligand. Using cryogelation as preparation method a screening on multiple combinations of materials was performed in order to create a potentially efficient support with the minimal footprint, i.e. a monolithic support with reasonable mechanical properties, highly permeable, biocompatible, ready to
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5

Jande, Yusufu Abeid Chande. "Manufacturing And Characterization Of Uniformly Porous And Graded Porous Polymeric Structures Via Selective Laser Sintering." Master's thesis, METU, 2009. http://etd.lib.metu.edu.tr/upload/12611406/index.pdf.

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Selective laser sintering is a rapid prototyping method (RP), which was originally developed, along with other RP methods, to speed up the prototyping stage of product design. The sole needed input for production being the solid model of the part, the mold/tool-free production characteristics and the geometric part complexity that can be achieved due to layer-by-layer production have extended the applicability/research areas of these methods beyond prototyping towards new applications and material development. Local pore formation in a part that occurs as a result of the discrete manufacturin
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6

Hansen, Eddy W., and Hans Christian Gran. "Probing pore-structure within porous polymer particles by NMR." Universitätsbibliothek Leipzig, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-194852.

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7

Hansen, Eddy W., and Hans Christian Gran. "Probing pore-structure within porous polymer particles by NMR." Diffusion fundamentals 3 (2005) 21, S. 1-2, 2005. https://ul.qucosa.de/id/qucosa%3A14312.

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8

Zhao, Wuxue, Fan Zhang, Lingyun Yang, et al. "Anionic porous polymers with tunable structures and catalytic properties." Royal Society of Chemistry, 2016. https://tud.qucosa.de/id/qucosa%3A30348.

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A series of boron-containing conjugated microporous polymers with hierarchical porous structures have been readily prepared via typical transition metal-catalyzed coupling reactions. The distribution of micro- and mesopores in the networks as well as the specific surface areas are tunable via tailoring the structures of the building blocks. The distinct capability of the resulting Lewis acid-based neutral porous polymers to selectively capture fluoride ions provides a high-efficiency conversion into stable anionic porous polymers. For the first time, fluoride anion binding to boron atoms in a
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9

Zhao, Wuxue, Fan Zhang, Lingyun Yang, et al. "Anionic porous polymers with tunable structures and catalytic properties." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2017. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-225647.

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A series of boron-containing conjugated microporous polymers with hierarchical porous structures have been readily prepared via typical transition metal-catalyzed coupling reactions. The distribution of micro- and mesopores in the networks as well as the specific surface areas are tunable via tailoring the structures of the building blocks. The distinct capability of the resulting Lewis acid-based neutral porous polymers to selectively capture fluoride ions provides a high-efficiency conversion into stable anionic porous polymers. For the first time, fluoride anion binding to boron atoms in a
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10

Evans, Nathan Timothy. "Processing-structure-property relationships of surface porous polymers for orthopaedic applications." Diss., Georgia Institute of Technology, 2016. http://hdl.handle.net/1853/55004.

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The use of polymers in orthopaedics is steadily increasing. In some markets, such as spinal fusion and soft tissue anchors, the polymer polyetheretherketone (PEEK) is already the material of choice in the majority of implants. Despite PEEK’s widespread use, it is often associated with poor osseointegration, which can lead to implant loosening and ultimately failure of the device. Many attempts have been explored to improve the osseointegration of PEEK but none have had widespread clinical success. In this dissertation, a novel surface porous structure has been created, where limiting the poros
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11

Yang, Xuebin. "Bone tissue engineering : biomimetic structures for human osteoprogenitor growth." Thesis, University of Southampton, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270664.

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12

Agirtopcu, Yasin. "Investigations On The Permeability Of Acrylic Powder Structures." Master's thesis, METU, 2003. http://etd.lib.metu.edu.tr/upload/4/1045343/index.pdf.

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There are many examples where creation and usage of porous substrates play important roles in various fields of application in material science and technology. In the manufacture of ceramic products, as an alternative to the plaster molds, porous resin molds are used in order to resolve the drawbacks that result A porous substrate can be produced by various ways. In this study, porous polymeric matrices of poly(methyl methacrylate) (PMMA) and poly(methyl methacrylate-co-2-hydroxyethyl methacrylate) [poly(MMA-HEMA)] polymers were prepared by connecting the polymer microspheres to each other by
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13

Kitao, Takashi. "Controlled Assembly Structures of Conjugated Polymers Mediated by Coordination Nanospaces." 京都大学 (Kyoto University), 2017. http://hdl.handle.net/2433/225635.

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14

Zhang, Wei. "Controllable growth of porous structures from co-continuous polymer blend." Diss., Georgia Institute of Technology, 2011. http://hdl.handle.net/1853/39608.

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Due to their large internal surface area, microporous materials have been widely used in applications where high surface activity is desired. Example applications are extracellular scaffolds for tissue engineering, porous substrates for catalytic reaction, and permeable media for membrane filtration, etc. To realize these potential applications, various techniques such as TIPS (thermal induced phase separation), particle leaching, and SFF (solid freeform fabrication) were proposed and investigated. Despite of being able to generate microporous for specific applications, these available fabrica
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15

Zocca, Andrea [Verfasser]. "Additive manufacturing of porous ceramic structures from preceramic polymers / Andrea Zocca." Clausthal-Zellerfeld : Universitätsbibliothek Clausthal, 2016. http://d-nb.info/1093614021/34.

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16

Matsuda, Ryotaro. "Studies on syntheses, structures and porous properties of microporous coordination polymers." 京都大学 (Kyoto University), 2005. http://hdl.handle.net/2433/144533.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(工学)<br>甲第11794号<br>工博第2554号<br>新制||工||1354(附属図書館)<br>23534<br>UT51-2005-F824<br>京都大学大学院工学研究科合成・生物化学専攻<br>(主査)教授 北川 進, 教授 村上 正浩, 教授 宮原 稔<br>学位規則第4条第1項該当
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17

Marshall, Andrew J. "Porous hydrogels with well-defined pore structure for biomaterials applications /." Thesis, Connect to this title online; UW restricted, 2004. http://hdl.handle.net/1773/8559.

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18

Greco, Pier Paolo. "Development of novel polymeric and composite nano-structured micro-porous materials for impact resistance applications." Thesis, University of Newcastle upon Tyne, 2014. http://hdl.handle.net/10443/2517.

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Impact resistant materials (IRMs) are widely used in the automotive and packaging industry. Their main purpose is the protection of the transported occupants or goods. Cellular materials as well as structures combine lightness with large deformation under load. The energy absorption mechanism is provided by limiting the peak load and ensuring the elastic deformation of the IRMs. Polymeric foams are largely used as IRMs due to their cellular structure. Prediction of the foam properties in terms of Young’s Modulus (Elastic Modulus) and the onset of Plateau Region can be related to the foam densi
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19

Harding, S. G. "NMR studies of structure-transport relationships in porous media : liquid diffusion in polymers." Thesis, University of Cambridge, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.603691.

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The main motivation behind this work was to explore the potential of nuclear magnetic resonance (NMR) to study small molecule diffusion in porous materials and the relationship between structure and transport processes, with particular emphasis on liquid diffusion in polymers. The diffusion of small hydrocarbons into a range of semicrystalline polyethylene (PE) samples is studied. Under the penetration conditions employed the polymer crystallinity is retained, supporting the idea that the penetrant resides only in the amorphous region. Magnetic resonance imaging (MRI) is used to monitor the bu
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20

Andrew, Harold Gibbons. "Design and Application of Optical Polymers." Kyoto University, 2019. http://hdl.handle.net/2433/242585.

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21

Liu, Kewei. "Macro Porous Graphene from Hollow Ni Templates via Polymer Templates with Bi-Continuous." University of Akron / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=akron1397135127.

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22

Fleming, Steven. "Agro-process intensification using nano-structured micro-porous polymers as soil additives to enhance crop production." Thesis, University of Newcastle upon Tyne, 2012. http://hdl.handle.net/10443/1894.

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Polymerised High Internal Phase Emulsion Polymer (PHP) is a nano-structured microporous polymeric material with a variety of applications. PHPs may have a role to play in sustaining or enhancing crop yields in increasingly alien environments. An elastic hydrophilic version has been developed that has been shown to increase crop yields when used as a soil additive. Soil is a natural carrier of water and nutrients as well as bacteria all of which are widely distributed in the soil and inefficiently maintained and utilised by plants. When polymer is added to the soil, water is attracted to the po
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23

Gorka, Joanna. "Polymer-based mesoporous carbons: soft-templating synthesis, adsorption and structural properties." Kent State University / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=kent1290460109.

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24

Song, Lulu. "Study of Ordered Macroporous Polymer Films by Templating Breath Figures." Diss., Georgia Institute of Technology, 2005. http://hdl.handle.net/1853/7004.

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Study of Ordered Macroporous Polymer Films by Templating Breath Figures Lulu Song 193 pages Directed by Dr. Mohan Srinivasarao Macroporous films with highly ordered pore patterns have many potential applications. Some examples include microstructured electrode surfaces, photonic band gap materials and filters for cell sorting and bio-interfaces. In this dissertation we discuss a moist-casting method to prepare hexagonally-ordered macroporous films with pore sizes in the range of sub-micron to several microns, where condensed water droplets (breath figures) work as templates. Compared with
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25

Pally, Nitin Kumar. "Synthesis and Structures of New Three-Dimensional Copper Metal-Organic Frameworks." TopSCHOLAR®, 2013. http://digitalcommons.wku.edu/theses/1295.

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Metal-organic frameworks (MOFs) are crystalline materials with metal ions covalently bonded to organic ligands. The ligands act as spacers often creating a porous structure with very high pore volume and surface area. MOFs are known for their robust structures, high porosity, and different chemical functionalities and are considered for applications in adsorptions, separations, catalysis and gas storage. This work focuses on the synthesis of new MOFs using copper compounds. Different types of carboxylate ligands were used for the synthesis. Two new copper-organic frameworks, [Cu3(pyz)(btc)] (1
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26

Assi, Hala. "Nouveaux polymères de coordination à base de titane et de dérivés phénoliques." Thesis, Université Paris-Saclay (ComUE), 2016. http://www.theses.fr/2016SACLV072/document.

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Les solides hybrides poreux ou les « MOFs » sont l'une des classes les plus récentes de polymères de coordination poreux cristallins. En raison de la variété de leur structure et leur composition, Ils sont actuellement considérés comme des candidats prometteurs dans divers domaines (le stockage de gaz, la séparation des fluides, la catalyse, la biomédecine…). Cependant, la littérature sur l'activité photocatalytique de ces solides n’a commencé à s’exploser que très récemment, bien que l’utilisation de ces matériaux comme photocatalyseurs hétérogènes soit avantageux en comparaison avec les semi
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27

Grünker, Ronny, Irena Senkovska, Ralf Biedermann, et al. "A highly porous flexible Metal–Organic Framework with corundum topology." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2014. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-138599.

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A flexible Metal–Organic Framework Zn4O(BenzTB)3/2 (DUT-13) was obtained by combination of a tetratopic linker and Zn4O6+ as connector. The material has a corundum topology and shows the highest pore volume among flexible MOFs<br>Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich
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28

Grünker, Ronny, Irena Senkovska, Ralf Biedermann, et al. "A highly porous flexible Metal–Organic Framework with corundum topology." Royal Society of Chemistry, 2011. https://tud.qucosa.de/id/qucosa%3A27762.

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A flexible Metal–Organic Framework Zn4O(BenzTB)3/2 (DUT-13) was obtained by combination of a tetratopic linker and Zn4O6+ as connector. The material has a corundum topology and shows the highest pore volume among flexible MOFs.<br>Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
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29

Das, Pritam. "Membrane micro-structurée utilisable comme support au développement de cellule humaine : développement, caractérisation et interaction cellule-matrice." Thesis, Toulouse 3, 2018. http://www.theses.fr/2018TOU30282/document.

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Les matériaux à structure tridimensionnelle laissent entrevoir de nombreuses applications prometteuses dans le domaine de l'ingénierie tissulaire et de la médecine régénérative en fournissant un micro-environnement approprié pour l'incorporation de cellules ou de facteurs de croissance afin de régénérer des tissus ou organes endommagés. Dans ce contexte, une membrane a été élaborée à partir d'un mélange de poly (ε-caprolactone) PCL / chitosan CHT à partir d'une technique d'inversion de phase permettant un apport localisé de non solvent. La technique permet d'obtenir une double morphologie pore
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30

Brien, Joshua V. "DEVELOPMENT OF CEMENTITIOUS MATERIALS FOR ADHESION TYPE APPLICATIONS COMPRISING CALCIUM SULFOALUMINATE (CSA) CEMENT AND LATEX POLYMER." UKnowledge, 2014. http://uknowledge.uky.edu/ce_etds/19.

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The objective of this research was to develop high performing polymer modified calcium sulfoaluminate (CSA) cement materials for use in applications requiring superior adhesion characteristics. Little information is available describing interactions of CSA cement containing minor phase tri-calcium aluminate (C3A) with commonly used admixtures. Given the scarcity of information, a basic approach for developing cementitious materials was followed. The basic approach consisted of four tasks: cement design, admixture design, polymer design and testing developed materials. The iterative, time consu
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31

Mouquet, Aymeric. "Structure et élasticité des films moussés : Effets de la distribution des tailles des bulles." Thesis, Paris Est, 2018. http://www.theses.fr/2018PESC1108/document.

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L’objet de ce travail expérimental est l’étude de la mécanique de films de mousses dont la structure est confinée par leur faible épaisseur. A partir d’une méthode de moussage de dispersion de particules de polyuréthane, nous sommes parvenus à contrôler, de façon indépendante, la fraction d’air (ou la densité) de ces films, leur épaisseur e et la distribution des tailles de leurs pores (de diamètre moyen D ̅_b). Pour ce dernier paramètre, nous nous sommes intéressés au cas de distributions monodisperse, bidisperse et polydisperses. Les différentes structures obtenues ont été étudiées par tomog
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32

Zhou, Chongfu. "Carbon Nanotube Based Electrochemical Supercapacitors." Diss., Georgia Institute of Technology, 2006. http://hdl.handle.net/1853/19747.

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Several approaches have been used to develop carbon nanotube (CNT) based electrochemical supercapacitors. These approaches include the following: (a) stabilization and carbonization of ternary composites of polyacrylonitrile (PAN), poly (styrene co-acrylonitrile) (SAN) copolymer, and single wall carbon nanotubes (SWNTs); (b) SWNT membranes functionalized with aryl chloride, sodium sulfonate, aryl sulfonic acid, bis(3,5-di-tert-butylphenyl)5-aminobenzene-1,3-dioate, and 4,4 -methylenedianiline; and (c) pyrrole treated SWNTs. In addition nitric acid functionalized and heat-treated SWNT membra
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33

Tripathy, Jagnyaseni. "Template-Assisted Fabrication of Ferromagnetic Nanomaterials." ScholarWorks@UNO, 2014. http://scholarworks.uno.edu/td/1951.

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Abstract Template assisted deposition was used to produce various nanomaterials including simple nanowires, nanorods, multi-segmented metal nanowires, core-shell nanowires, alloy and polymer wires and tubes. Anodized aluminum oxide (AAO) membranes were used as templates for the growth of the various structures using an electrochemical deposition method and also by wetting the porous templates. In the electrochemical deposition method, the pore size of the templates affects the rate of synthesis and the structures of the nanomaterials while in the wetting method, the viscosity and reaction tim
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34

Lemarinier, Pavel. "Propagation du son dans des mousses et une laine de verre a structures rigides saturees par de l'air : validation experimentale de modeles thermiques, analogie dielectrique, impregnation polymere d'une mousse." Le Mans, 1997. http://www.theses.fr/1997LEMA1004.

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Dans un contexte de materiaux absorbants, des valeurs experimentales du facteur de forme m' sont obtenues lors de mesures dynamiques de la compressibilite de l'air dans des mousses polyuethanes reticulees et une laine de verre. Une reflexion est menee concernant la validite des modeles thermiques de propagation du son dans ces structures, le cas d'un echauffement partiel du solide etant pris en compte. Une analogie avec les dielectriques est utilisee pour preciser la nature de la relaxation des susceptibilites etudiees. On montre la similitude de ces fonctions aux formes de relaxation bien con
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35

Bardot, Anne. "Modélisation acoustique basses fréquences de cavités en présence d'absorbants sur parois rigides ou élastiques." Compiègne, 1992. http://www.theses.fr/1992COMP0424.

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Ces travaux concernent l'amélioration de la compréhension physique et la modélisation des phénomènes vibro-acoustiques de cavités en présence de matériaux absorbants en vue d'améliorer la modélisation vibro-acoustique d'un habitacle automobile pour des problèmes de bourdonnement [50-200Hz]. La caractérisation acoustique des matériaux absorbants, plus particulièrement des matériaux polyuréthanes est basée sur une procédure originale associant mesures et modèle de Biot pour caractériser l'impédance acoustique des matériaux en basses fréquences, sous l'incidence d'ondes planes normales ou oblique
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Bardot, Anne. "Modélisation acoustique basses fréquences de cavités en présence d'absorbants sur parois rigides ou élastiques." Compiègne, 1992. http://www.theses.fr/1992COMPD424.

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Ces travaux concernent l'amélioration de la compréhension physique et la modélisation des phénomènes vibro-acoustiques de cavités en présence de matériaux absorbants en vue d'améliorer la modélisation vibro-acoustique d'un habitacle automobile pour des problèmes de bourdonnement [50-200Hz]. La caractérisation acoustique des matériaux absorbants, plus particulièrement des matériaux polyuréthanes est basée sur une procédure originale associant mesures et modèle de Biot pour caractériser l'impédance acoustique des matériaux en basses fréquences, sous l'incidence d'ondes planes normales ou oblique
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37

Campo, Mireille. "Milieux poreux et modification de la porosité. Influence de l'incorporation de fines minérales et organiques dans les matrices cimentaires." Toulouse, INSA, 1993. http://www.theses.fr/1993ISAT0025.

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Pour modifier la porosite de materiaux cimentaires, dans un contexte industriel contraignant (materiaux secs et mise en place forcee), deux procedes bases sur l'incorporation ont ete examines. Une grande variete de produits a ete etudiee, pour comprendre les processus de modification: fines minerales et fines organiques. L'ajout de fines minerales inertes ou reactives a mis en evidence le faible role du remplissage physique. L'incorporation doit etre suivie d'une cure hydrique precoce. Elle fait apparaitre une correlation entre le volume total poreux et le taux d'avancement de la reaction d'hy
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38

Castro, Lopez William Camilo. "Modélisation du comportement diffuso-mécanique d'un polymère semi-cristallin sous pression d'eau." Thesis, Chasseneuil-du-Poitou, Ecole nationale supérieure de mécanique et d'aérotechnique, 2015. http://www.theses.fr/2015ESMA0010.

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La compréhension des couplages hydro-mécaniques pouvant influencer le comportement mécanique d’un polymère semi-cristallin (PSC) sous forte pression d’eau est à l’origine de ce travail de recherche.Afin de décrire des phénomènes de diffusion d’eau et leurs impacts sur le comportement mécanique du matériau lors d’un chargement multiaxial, l’influence des caractéristiques microstructurales sur le comportement diffuso-mécanique du matériau a été considérée dans la modélisation. Un modèle de comportement mécanique permettant de rendre compte du phénomène de cavitation généré par d’importantes défo
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39

Ponsot, Inès. "Glasses and Glass-Ceramic Components from Inorganic Waste and Novel Processing." Doctoral thesis, Università degli studi di Padova, 2015. http://hdl.handle.net/11577/3424636.

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Thanks to European environmental rules and regulations establishment, waste recycling has become a more and more relevant problematic. For manufacturing plants, especially those producing hazardous wastes, expenses linked to waste production have drastically increased over the last decades. In the proposed work, various hazardous and non-hazardous wastes, among: soda-lime and borosilicate glass cullet, cathode ray tubes glass, exhausted lime from fume abatement systems residues, sludge and slags from ferrous and non-ferrous metallurgy, and pre-stabilized municipal solid waste incinerators ashe
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40

MANNELLA, Gianluca Antonio. "POLYMERIC POROUS STRUCTURES VIA PHASE SEPARATION." Doctoral thesis, 2012. http://hdl.handle.net/10447/94658.

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41

Hashemi, Sangdehi Ashraf Alsadat. "Newly-developed parameters to quantify texture : application to polymeric porous structures." Thèse, 2005. http://hdl.handle.net/1866/15640.

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42

Lopes, Ana Catarina Teixeira Castro. "Development of electroactive polymer nanocomposites with porous structured materials." Doctoral thesis, 2013. http://hdl.handle.net/1822/27351.

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Tese de doutoramento em Ciências (área de especialização em Física)<br>Electroactive polymer composites are interesting materials for advance technological applications due to the possibility to combine the electroactive properties of the polymer matrix with a large variety of fillers that allow tailored responses for specific applications. The best all-around electroactive polymers are poly(vinylidene fluoride) (PVDF) and its copolymers which allied with the properties of porous zeolite materials, with tailored shape, size and Si/Al ratio, among others, leads to the possibility of deve
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Khodabandeh, A. "Polymer nanoparticles and their supracolloidal monolithic structures for applications in separation science." Thesis, 2017. https://eprints.utas.edu.au/23768/1/Khodabandeh_whole_thesis.pdf.

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Porous polymers generated from high internal phase emulsions (HIPEs), having interconnected open-void morphology, low density and high porosity up to 95%, are finding various applications including separation science due to their exceptional properties, such as tunable pore size and surface characters. A new class of polyHIPE materials has been prepared using HIPE template stabilized by a series of tailor-made polymeric surfactant as sole stabilizer. These polymeric surfactants were synthesized by radical addition-fragmentation chain transfer (RAFT) polymerization, which from the obtained cop
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Siao, Bo-Wun, and 蕭博文. "Injection Molding of Composited Polymer Plate with Porous Anodic Alumina Structures." Thesis, 2014. http://ndltd.ncl.edu.tw/handle/5479mk.

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碩士<br>國立臺灣科技大學<br>機械工程系<br>102<br>This research is to develop a novel process with the porous anodic aluminum (PAA) to produce the nano-porous ceramic template and then combines with a thermoplastics plate by the quasi-inserted injection molding process. The composited polymer plate containing aluminum material on PAA template has the ability to enhance heat transfer capability of local heat source. Effects of injection molding parameters on the thermal conductivity coefficient of the composited polymer plate have been investigated with the height of polymer inside the PAA template by bonding
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Batuca, Ana Raquel dos Reis. "Development of 3D porous structures for buccal drug delivery." Master's thesis, 2016. http://hdl.handle.net/10362/63364.

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Advances in polymer science and engineering has led to the development of new poly-meric systems for controlled drug delivery in the oral cavity. In this work, pH responsive scaf-folds were prepared by two distinct methods: freeze-drying and gelation process followed by scCO2-assisted drying. The objective was to obtain two distinct porous structures, a gum and a candy to treat oral diseases. The scaffolds of chitosan (CHT), xanthan gum (XG) and polymer m (PM) were prepared with and without crosslinkers (N,N’-methylene-bis-acrylamide (MBA), tet-ramethylenediamine (TEMED) and ammonium persulfat
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Hendricks, Nicholas. "Porous Metal Oxide Materials Through Novel Fabrication Procedures." 2012. https://scholarworks.umass.edu/open_access_dissertations/609.

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Porous metal oxide materials, particularly those comprised of silica or titania, find use in many applications such as low-k dielectric materials for microelectronics as well as chemical sensors, micro/nanofluidic devices, and catalyst substrates. For this dissertation, the focus will be on the processing of porous metal oxide materials covering two subjects: hierarchical porosity exhibited over two discrete length scales and incorporation of functional nanomaterials. To generate the porous silica materials, the technique of supercritical carbon dioxide infusion (scCO2) processing was heavily
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Desire, CT. "The development and evaluation of supracolloidal monolithic structures for applications in separation science." Thesis, 2018. https://eprints.utas.edu.au/28367/1/Desire_whole_thesis_ex_pub_mat.pdf.

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This thesis focuses on the development of polymer monoliths from emulsions for applications in liquid chromatography, in particular the use of high internal phase emulsions to produce monoliths with controlled morphology. An initial study focused on the preparation of hydrophilic polymer monoliths using oil-in-water emulsions. Here, the internal phase volume of the emulsion was varied to produce monoliths with improved mechanical properties under compression. A systematic study was then employed focusing on the influence of the internal phase volume, surfactant concentration and the emulsific
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Adhikari, Debabrata. "Resin flow in porous preform during VARTM: A theoretical and experimental investigation." Thesis, 2019. https://etd.iisc.ac.in/handle/2005/4958.

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In recent times, fiber reinforced polymer (FRP) composites have received enormous attention due to their exhibited improved mechanical properties, lightweight and design flexibility to manufacture large structures as an attractive alternative structural material compared to conventional metals for marine, aerospace, automobile, and civil industries. FRP manufacturing technology strives to completely saturate the dry fiber phase with thermoplastic or thermoset resins to yield a heterogeneous material with enhanced capabilities. This work focuses on the physics of resin impregnation in dry
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Ding, Miao-Tzu, and 丁妙慈. "Soluble Metal-Organic Frameworks: Dissolution/Reassembly towards the Structural Rearrangement of Porous Cobalt(II)- and Nickel(II)–Carboxylate Coordination Polymers." Thesis, 2008. http://ndltd.ncl.edu.tw/handle/40897218316524320914.

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碩士<br>國立中央大學<br>化學研究所<br>96<br>The goal of this study was to develop a self-assembly synthetic strategy for the preparation of metal–organic coordination polymers using benzene-1,2,4,5-tetracarboxylic acid (H4btec) and transition-metal ions (CoII, NiII). Four three-dimensional, soluble, porous metal–organic coordination networks {K2[Co3(btec)2(H2O)4]∙6H2O}n (1•6H2O), {K2[Ni3(btec)2(H2O)4]•4H2O}n (2•4H2O), {Cs2[Co3(btec)2(H2O)4]•3H2O}n (3•3H2O), and {Cs2[Ni3(btec)2(H2O)4]•3H2O}n (4•3H2O) with near identical structural features were hydrothermally prepared. These structures adopt a (4,8)-co
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Makal, Trevor Arnold. "Pendant Functional Groups in Metal-Organic Frameworks - Effects on Crystal Structure, Stability, and Gas Sorption Properties." Thesis, 2013. http://hdl.handle.net/1969.1/149331.

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The primary goal of this research concerns the synthesis and characterization of metal-organic frameworks (MOFs) grafted with pendant alkyl substituents to enhance stability and gas sorption properties for use in clean-energy related technologies. Initially, the focus of this work was on the synthesis and comparison of two isostructural MOFs built upon octahedral secondary building blocks; one with no alkyl substituents, and its dimethyl-substituted counterpart. The dimethyl-substituents are observed to enhance the stability of the framework, resulting in high Langmuir surface area (4859 m2 g-
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