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Dissertations / Theses on the topic 'Primary amide'

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1

Robertson, Alan. "Elaboration and expansion of the chemistry of alkali metal primary amide complexes." Thesis, University of Strathclyde, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.248701.

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2

McMahon, Jennifer Anne. "Crystal engineering of novel pharmaceutical forms." [Tampa, Fla] : University of South Florida, 2006. http://purl.fcla.edu/usf/dc/et/SFE0001792.

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3

Farrell, Emma K. "Biosynthesis of fatty acid amides." Scholar Commons, 2010. http://scholarcommons.usf.edu/etd/1629.

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Primary fatty acid amides (PFAMs) and N-acylglycines (NAGs) are important signaling molecules in the mammalian nervous system, binding to many drug receptors and demonstrating control over sleep, locomotor activity, angiogenesis, vasodilatation, gap junction communication, and many other processes. Oleamide is the best-studied of the PFAMs, while the in vivo activity of the others is largely unstudied. Even less is known about the NAGs, as their discovery as novel compounds is much more recent due to low endogenous levels. Herein is described extraction and quantification techniques for PFAMs
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4

Septavaux, Jean. "Réduction stéréosélective de substrats d’intérêt pharmacologique à réactivité réduite." Thesis, Ecole centrale de Marseille, 2016. http://www.theses.fr/2016ECDM0002.

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Dans ce manuscrit sont décrites de nouvelles procédures pour la synthèse stéréosélective d’un composé d’intérêt pharmacologique ainsi que leurs implémentations pour la production en continu. Plusieurs procédures de modification de catalyseurs hétérogènes commerciaux ont été développées et ont permis d’augmenter significativement la diastéréosélectivité de la réaction d’hydrogénation d’un intermédiaire de synthèse. Une voie de synthèse alternative par dérivatisation a également été développée, permettant d’atteindre une diastéréosélectivité pus élevée. De plus, des réacteurs modulaires dédiés à
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5

Günler, Zeynep Inci. "Primary amine thioureas in asymmetric organocatalysis." Doctoral thesis, Universitat Rovira i Virgili, 2016. http://hdl.handle.net/10803/396191.

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Aquesta tesi es centra en organocatalitzadors de tipus tiourea amina primària (PAT). L’addició de Michael d’acetona a nitroestiré catalitzada per tiourees amina primària va ser estudiada en detall. Els efectes sinergístics de múltiples additius (aigua i àcid acètic) en aquesta reacció varen ser determinats mitjançant anàlisi espectroscòpica de 1H NMR. Els nostres estudis mecanístics van mostrar que l’àcid acètic facilita la hidròlisi dels intermedis d’imina, donant lloc a la catàlisi, i minimitza la formació del subproducte de doble addició. Per la seva banda, l’aigua alenteix la reacció però
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6

Meurer, Richard Achim Verfasser], Andrij [Akademischer Betreuer] Pich, and Ulrich [Akademischer Betreuer] [Schwaneberg. "Primary amine functionalized microgels / Richard Achim Meurer ; Andrij Pich, Ulrich Schwaneberg." Aachen : Universitätsbibliothek der RWTH Aachen, 2019. http://d-nb.info/1213678420/34.

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Meurer, Richard Achim [Verfasser], Andrij Akademischer Betreuer] Pich, and Ulrich [Akademischer Betreuer] [Schwaneberg. "Primary amine functionalized microgels / Richard Achim Meurer ; Andrij Pich, Ulrich Schwaneberg." Aachen : Universitätsbibliothek der RWTH Aachen, 2019. http://d-nb.info/1213678420/34.

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8

McCann, Judith. "Development of high amine content microgels and systems for use in enzyme responsive materials." Thesis, University of Manchester, 2014. https://www.research.manchester.ac.uk/portal/en/theses/development-of-high-amine-content-microgels-and-systems-for-use-in-enzyme-responsive-materials(7c9e8957-8b16-499f-8ad4-f1f022044066).html.

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This thesis presents a study of the preparation and characterisation of microgels (MGs) and microgel-based systems which contain a high proportion of primaryamine groups. This is carried out with the aim of being used as the precursor materials for the development of an enzyme responsive system. The particle preparations discussed in this thesis begin with a particle dispersion prepared by a polymer-polymer interaction between partially oxidised dextran (Dexox) and poly(allylamine)(PA) or poly(vinylamine) (PVAM). The particle dispersions did show good tunability of properties by altering certa
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9

Kazanjian, Garabet. "Primary production in shallow freshwater systems amid a rapidly changing world." Doctoral thesis, Humboldt-Universität zu Berlin, 2019. http://dx.doi.org/10.18452/20561.

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Kleine, flache Gewässer gelten als sogenannte „hotspots“ der Primärproduktion und Kohlenstoffbindung. Diese Doktorarbeit zielt darauf ab, die Primärproduktion verschiedener kleiner Gewässer zu quantifizieren sowie die Mechanismen, die den Kohlenstoffkreislauf dieser Systeme beeinflussen, zu analysieren. Der Fokus liegt dabei auf dem Einfluss globaler Veränderungen, die diese Mechanismen verändern können Im ersten Abschnitt wurde die Primärproduktion (PP) in kleinen, temporären Söllen untersucht, die sehr anfällig für Störungen sind. Ich konnte zeigen, dass die PP der Sölle im Sommer außergewö
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10

Mojarradi, Hotan. "Coupling of substances containing a primary amine to hyaluronan via carbodiimide-mediated amidation." Thesis, Uppsala universitet, Institutionen för biokemi och organisk kemi, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-149284.

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The purpose of this study was to investigate the carbodiimide-mediated amidation of hyaluronan (HA). The carbodiimide-mediated amidation includes the formation of a urea derivative, O-acylisourea, between the carbodiimide and a carboxylic group of HA, which a primary amine can displace, resulting in an amide bond. Reaction conditions were investigated and optimized, the molecular weights Mn and Mw were determined with size-exclusion chromatography and by-products were analysed with 1H NMR. The reaction is done at room temperature in slightly acidic pH, giving a degree of substitution between 5
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11

Bibi, Ahtaram [Verfasser]. "Primary Amine Containing Bifunctional Catalysts for Asymmetric Aldol and Mannich Reactions / Ahtaram Bibi." Bremen : IRC-Library, Information Resource Center der Jacobs University Bremen, 2012. http://d-nb.info/1035220229/34.

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12

Read, Elizabeth Sarah. "Synthesis of Primary Amine-based Methacrylic Polymers and Novel Shell Cross-linked Micelles." Thesis, University of Sheffield, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.505573.

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13

Sen, Mustafa Yasin. "SYNTHESIS OF MIDDLE-CHAIN CARBOXYL- AND PRIMARY AMINE-FUNCTIONALIZED POLYSTYRENES USING ANIONIC POLYMERIZATION TECHNIQUES." University of Akron / OhioLINK, 2005. http://rave.ohiolink.edu/etdc/view?acc_num=akron1132533104.

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14

Anderson, Mattias. "Amine Transaminases in Multi-Step One-Pot Reactions." Doctoral thesis, KTH, Industriell bioteknologi, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-199646.

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Amine transaminases are enzymes that catalyze the mild and selective formation of primary amines, which are useful building blocks for biologically active compounds and natural products. In order to make the production of these kinds of compounds more efficient from both a practical and an environmental point of view, amine transaminases were incorporated into multi-step one-pot reactions. With this kind of methodology there is no need for isolation of intermediates, and thus unnecessary work-up steps can be omitted and formation of waste is prevented. Amine transaminases were successfully com
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15

Kosky, Andrew Alfred. "Interdependence of asparagine deamidation with primary and [alpha]-helical secondary structure in model peptides /." Connect to full text via ProQuest. Limited to UCD Anschutz Medical Campus, 2006.

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Thesis (Ph.D. in Pharmaceutical Sciences) -- University of Colorado at Denver and Health Sciences Center, 2006.<br>Typescript. Includes bibliographical references (leaves 203-215). Free to UCDHSC affiliates. Online version available via ProQuest Digital Dissertations;
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16

Mouselmani, Rim. "Reduction of Organic Functional Groups Using Hypophosphites." Thesis, Lyon, 2018. http://www.theses.fr/2018LYSE1241/document.

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Récemment, les exigences en chimie ont évolué rapidement, car le développement durable a retenu plus d'attention. Les principes de la chimie verte ont encouragé les chimistes à développer des produits chimiques et des procédés qui réduisent ou éliminent les substances dangereuses. Les travaux de recherche décrits dans cette thèse portent sur le développement de nouveaux systèmes réducteurs en utilisant des hypophosphites comme substituts aux agents réducteurs toxiques traditionnels.Pour atteindre cet objectif, les nitriles aromatiques ont été réduits en aldéhydes correspondants par la formatio
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17

Turnquest, Britt E. "Rapid Inline Derivatization of Primary and Secondary Amine Containing Drugs by Capillary Electrophoresis with Laser-Induced Fluorescence." FIU Digital Commons, 2013. http://digitalcommons.fiu.edu/etd/998.

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Despite the ongoing “war on drugs” the seizure rates for phenethylamines and their analogues have been steadily increasing over the years. The illicit manufacture of these compounds has become big business all over the world making it all the more attractive to the inexperienced “cook”. However, as a result, the samples produced are more susceptible to contamination with reactionary byproducts and leftover reagents. These impurities are useful in the analysis of seized drugs as their identities can help to determine the synthetic pathway used to make these drugs and thus, the provenance of the
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18

Bu, Lulu. "Synthesis of NIR Dyes and Nanoparticles for in vivo Bioimaging and Dicyanovinyl Dyes for Primary Amine Detection." Thesis, Lyon, 2020. http://www.theses.fr/2020LYSEN086.

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L’imagerie de fluorescence et l'imagerie photo-acoustique (PA) sont deux outils puissants pour la visualisation des tissus et organes biologiques de manière non invasive. Toutefois, ces technologies sont actuellement limitées par le manque d'agents de contraste efficaces. Utiliser des longueurs d’onde de domaine du proche infrarouge (NIR, 650-900 nm), dont l'absorption et la diffusion dans les organismes est relativement faible, permet une imagerie in vivo plus profonde, induit moins d’auto-fluorescence et apporte un bon rapport signal/bruit. Par conséquent, la conception et la synthèse de nou
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19

Woodroffe, Josanne-Dee. "A Synthesis Approach Of TRP-Like Primary Amine Peptoid Side Chains Used In Cyclic Beta-Hairpin - Like Scaffolds." Scholar Commons, 2014. https://scholarcommons.usf.edu/etd/5156.

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In recent studies it was reported that the D-amino acid containing peptide HYD1 was used in the treatment of necrotic cell death in multiple myeloma cell lines and showed promising biological activity and in vivo activity. It was meaningful to explore strategies for increasing the therapeutic efficacy of HYD1, a linear peptide. These efforts led to the development of MT1-101 (cyclized peptidomimetics), a lead compound that showed increased in vitro activity and in vivo activity. MTI-101 was found to bind the cell adhesion molecule CD44 and induce programmed necrosis in myeloma cell lines. It w
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20

Cadena, Chamorro Judith Magali. "Metalociclos derivados de la (R)-1-(1-naftil)etilamina. Síntesis y aplicaciones como agentes de resolución de fosfinas monodentadas." Doctoral thesis, Universitat de Barcelona, 1999. http://hdl.handle.net/10803/131396.

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Se describe la ciclopaladación de aminas primarias y terciarias y iminas ópticamente puras. Los correspondientes compuestos ciclopaladados dinucleares con puente cloro ópticamente puros reaccionaron con fosfinas racémicas (P o alfa-quirales) para dar lugar a dos compuestos mononucleares diastereoisoméricos con una configuración trans-N,P. En muchos casos, estos complejos se separaron por cromatografía de columna preparativa, y en un caso, una fosfina P quiral terciaria ópticamente pura, se liberó del complejo mononuclear trans-N,P y se transfirió a un fragmento Pd(mu(3)-alilo)cloruro. El corre
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21

Kazanjian, Garabet [Verfasser], Sabine [Gutachter] Hilt, Kurt [Gutachter] Zoglauer, and Irmgard [Gutachter] Blindow. "Primary production in shallow freshwater systems amid a rapidly changing world / Garabet Kazanjian ; Gutachter: Sabine Hilt, Kurt Zoglauer, Irmgard Blindow." Berlin : Humboldt-Universität zu Berlin, 2019. http://d-nb.info/1197611282/34.

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22

Doidge, Euan Douglas. "Designing reagents for the solvent extraction of critical metal resources." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/31070.

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The work in this thesis aims to develop new systems for the more efficient recovery of metals from aqueous solution using solvent extraction. Understanding the underlying coordination chemistry to improve hydrometallurgical methods is crucial in order to meet the demand for critical metals for use in modern technologies, reduce the environment impact of recovery from primary mining deposits, and recycle valuable metals from secondary sources (e.g. mobile phones, WEEE). Chapter 2 examines the use of a simple primary amide that can load gold and other chloridometalates into a toluene phase throu
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23

Schade, Matthias. "Cross-Coupling of Benzylic Zinc Reagents, Preparation and Applications of Alkenyl Zinc Reagents, Preparation of Primary Amides and Synthesis of Functionalized Allenes." Diss., lmu, 2011. http://nbn-resolving.de/urn:nbn:de:bvb:19-131522.

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24

Javed, Hafsa Shamim. "Investigating co-crystallisation of primary amides and carboxylic acids : comparative analysis of Benzamide, Isonicotinamide and Nicotinamide co-crystal growth with carboxylic acid." Thesis, University of Bradford, 2010. http://hdl.handle.net/10454/5436.

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Crystal Engineering is the design of crystalline material using non-covalent synthesis. Co-crystals are multi-component crystals which are constructed from complementary intermolecular interactions, they are also known as supramolecular complexes. Design of such materials utilises the synthon approach, this involves the understanding of common intermolecular interactions which occur in the crystal packing and is used to design new solids with desired physical properties and chemical properties. Primary amides form supramolecular heterosynthons, these synthons represent an opportunity for a des
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Javed, Hafsa S. "Investigating co-crystallisation of primary amides and carboxylic acids. Comparative analysis of Benzamide, Isonicotinamide and Nicotinamide co-crystal growth with carboxylic acid." Thesis, University of Bradford, 2010. http://hdl.handle.net/10454/5436.

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Crystal Engineering is the design of crystalline material using non-covalent synthesis. Co-crystals are multi-component crystals which are constructed from complementary intermolecular interactions, they are also known as supramolecular complexes. Design of such materials utilises the synthon approach, this involves the understanding of common intermolecular interactions which occur in the crystal packing and is used to design new solids with desired physical properties and chemical properties. Primary amides form supramolecular heterosynthons, these synthons represent an opportunity for a des
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26

Krieger, Amandine. "Dédoublement cinétique d'amines par transfert d'acyle et approche synthétique du lyngbouilloside." Thesis, Paris 6, 2014. http://www.theses.fr/2014PA066671/document.

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Le développement de méthodes efficaces de dédoublement cinétique d'amines représente, encore aujourd'hui, un défi en chimie organique. C'est dans ce contexte que nous avons montré que le (1S,2S)-N-acetyl-1,2-bis-trifluoromethanesulfonamidocyclohexane pouvait être utilisé comme réactif d'acylation hautement efficace pour le dédoublement cinétique d'amines propargyliques. En effet, ce réactif est capable de fournir les acétamides correspondants avec des ees pouvant atteindre jusqu'à 96% (τc = 50%)) lorsqu'un sel tel que l'AliquatTM 336 est utilisé alors qu'une inversion de la sélectivité est obs
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27

Sinquin, Anne. "Alginates associatifs : synthèse et étude physico-chimique en milieu aqueux." Vandoeuvre-les-Nancy, INPL, 1995. http://www.theses.fr/1995INPL035N.

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La synthèse de polymères hydrosolubles présentant un caractère associatif a été effectuée, par réaction de diverses alkylamines à chaine longue (Cn-NH2, 8≤n≤16) sur l'alginate de propylène glycol (PGA), un dérivé partiellement estérifié d'un polysaccharide extrait des algues. Les propriétés physico-chimiques des dérivés hydrophobisés résultants ont été étudiées, comparativement à celles des polymères parents, en rhéologie, en spectrophotométrie de fluorescence et par des mesures de tension superficielle, dans l'eau pure ou en présence de sels. De façon générale, on observe que le caractère ass
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28

HADDAD-FAHED, OMAIMA. "Catalyse micellaire de reactions de substitution nucleophile aromatique comportant des reactifs electriquement charges." Paris 6, 1987. http://www.theses.fr/1987PA066419.

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29

Lavigne, André. "Oxydations cupro-catalysees des amines aliphatiques : etudes mecanistiques et applications synthetiques." Paris 6, 1987. http://www.theses.fr/1987PA066470.

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Preparation de nitriles a partir d'amines primaires et d'alpha -aminoacides. Les acides amines monosubstutitues rch(nh::(2))co::(2)h donnent le nitrile rcn, alors que les acides amines disubstitues rr'c(nh::(2))co::(2)h conduisent a l'azine rr'c=n-n=cr'r. Les mecanismes proposes font intervenir le cuivre (iii), forme in situ a partir du cuivre (i) et de l'oxygene
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30

Amara, Soumia. "CO2 capture in industry using chilled ammonia process." Thesis, KTH, Energiprocesser, 2021. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-292504.

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CO2 capture and storage (CCS) is estimated to reduce 14% of the global CO2 emissions in the 2 °C scenario presented by the International Energy Agency. Moreover, post combustion capture is identified as a potential method for CO2 capture from industry since it can be easily retrofitted without disturbing the core industrial process. Among the post-combustion capture methods, absorption using mono-ethanol amine (MEA) is the most mature technology that has been demonstrated at plant scale. However, using chilled ammonia process as a post combustion capture technology in a cement industry can red
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31

Hortala, Laurent. "Synthèse et étude de récepteurs d'amines primaires à structures pyridine et quinoléine oxazolines. Application à l'accélération d'une réaction d'aminolyse d'esters vers de nouveaux transporteurs d'aminoacides." Rouen, 2001. http://www.theses.fr/2001ROUES002.

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Ce travail nous a permis, dans un premier temps, d'évaluer la capacité des structures diPyridine méthane Bisoxazolines (diPyBox) et Pyridine Bisoxazolines (PyBox) à effectuer la reconnaissance fonctionnelle d'amines primaires par formation de liaisons hydrogène. La mesure des constantes d'association par R. M. N. 1H nous a montré que les composés PyBox ont une géométrie mieux adaptée à complexer ces amines et des complexes de stoechiométrie 1:1 ont pu être mis en évidence. Dans une deuxième partie, nous avons exploité la reconnaissance de la fonction amine par le récepteur PyBox dans l'optique
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32

Jacoby, Denis. "Synthese et reactivite des cyclopropanes actives." Paris 6, 1987. http://www.theses.fr/1987PA066439.

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Ce travail decrit des mises au point originales de preparations de pyrrolines et de dihydrofurannes a partir de cyclopropylcetoesters. Ces derniers sont prepares a partir de sels de triphenylphosphonium, precurseurs de derives cyclopropaniques. La reactivite de ces composes cyclopropaniques vis a vis de nucleophiles varies est etudiee. L'action des amines primaires permet d'obtenir des pyrrolines. Une etude biologique montre l'activite biocide des composes prepares
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33

Riondel, Alain. "Étude de la réactivité de carbonates et de carbamates chlorés vis-à-vis de nucléophiles. Formation d'anions à l'aide des bases complexes." Nancy 1, 1988. http://www.theses.fr/1988NAN10505.

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34

VALLEE, PAULE YOLANDE. "Obtention par thermolyse eclair et etude physicochimique de molecules conjuguees reactives d'interet synthetique ou astrophysique." Caen, 1988. http://www.theses.fr/1988CAEN2033.

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35

Lair, Delphine. "Organisation de films de Langmuir mixtes Amphiphile/Glucose oxydase. Etude comparative de l'acide béhénique et de la stéarylamine." Rouen, 1998. http://www.theses.fr/1998ROUES056.

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La structure et l'organisation dynamique de deux types de films de Langmuir mixtes acide béhénique/glucose oxydase (AB/GOx) et stéarylamine/glucose oxydase (SAm/GOx) ont été étudiées. Les films ont été caractérisés à l'interface eau/air par le tracé d'isothermes de compression et en suivant leur évolution, et après transfert, par spectroscopies I. R. , UV/Visible et microscopie à force atomique. Ces caractérisations ont été effectuées afin de réaliser une étude comparative sur l'organisation dynamique des deux films mixtes à l'interface eau/air, en étudiant l'incorporation de la glucose oxydas
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Maddaluno, Jacques. "Synthèse énantiosélective de composés d'intérêt biologique : approche de polyols vicinaux par aldolisation stéréocontrôlée, approche de bêta-amino esters par addition de Michael stéréocontrôlée sous haute pression." Paris 6, 1986. http://www.theses.fr/1986PA066240.

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La réaction d'aldolisation des benzoylaryacetates avec l'acétaldéhyde fait ressortir la capacité de ce synthon à effectuer un transfert d'asymétrie. Etude de la réactivité des alcoxy-3 acroléines. L'addition d'amines primaire sur des crotonates à haute pression permettent d'obtenir de meilleures sélectivités
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37

Haelters, Jean-Pierre. "Synthèse de dérivés phosphono-indoliques-benzofuranniques et -pyrroliques à partir d'hydrazones phosphonates." Brest, 1987. http://www.theses.fr/1987BRES2002.

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Des derives phosphonoindoliques sont prepares par cyclisation d'arylhydrazones d'oxoalkylphosphonates selon fisher et par cyclodeshydratation d'arylamino-1 et arylamino-3 oxo-2 propylphosphonates selon bischler. Des indolyl-2 et indolyl-3 phosphonates, des indolylmethyl-2 et des indolylmethyl-3 phosphonates diversement substitues et leurs acides phosphoniques correspondants sont decrits. Toutes structures sont analysees par rmn **(1)h, **(31)p et 1**(3)c. L'analogue phosphore de l'intermediaire a aussi ete prepare. L'extention de la reaction de bischler aux aryloxycetones permet d'atteindre de
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38

Davic, Andrew Paul. "Development of a Microfluidic Platform for Trace Lipid Analysis." 2016. http://digital.library.duq.edu/u?/etd,197236.

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The field of lipidomics encompasses the study of pathways, networks, and functionality of cellular lipids in biological systems. The lipid subclass, primary fatty acid amides, are crucial to nervous system signaling, receptor function, and numerous other physiological roles. Chapter 1 details these bioactive properties of several well-studied primary fatty acid amides as well as their biosynthesis, degradation, and most common analysis techniques. As these bioactive lipids are endogenously present in trace and ultra-trace abundancies, the field of microfluidics presents an attractive altern
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Ashley, Melissa Ann. "Photoredox-Catalyzed Site-Selective Functionalization of Primary Amine Derivatives." Thesis, 2021. https://doi.org/10.7916/d8-nz4d-fj65.

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Given the prevalence of primary amines in biologically active molecules, an important area of research is devoted to creating methods to site-selectively functionalize their C(sp³)-H bonds. For simple aliphatic primary amines, many of these C-H bonds are chemically indistinguishable due to their similar electronics and sometimes, steric environments. Through strategic choice of activating group, site-selective functionalization at both α- and ẟ- positions is achieved. Exploiting inductive effect allows for a photoredox-catalyzed α-C(sp³)-H alkylation of trifluoromethanesulfonamides. In the cas
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Taleb, Sereshki Farzaneh. "Rh-catalyzed asymmetric C-H bond activation by chiral primary amine." 2017. http://hdl.handle.net/1993/32091.

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Developing asymmetric C-H bond activation methods in order to achieve enantiopure products is crucial for the advancement of the field and for the production of novel chiral compounds. Therefore, we tried to develop this area of organic chemistry by presenting metal catalyzed stereoselective C-H bond activation utilizing chelation-assisted tools. The first section of this study involves Rh(I) catalyzed asymmetric C-H bond activation of a series of ketones via an intermolecular procedure. By this method, we examine ortho-alkylation of aromatic ketones and β-functionalization of α-β unsaturated
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41

Dai, Jia-Wei, and 戴嘉瑋. "Quantitation of Relative and Absolute Phosphorylation Stoichiometry Using Primary Amine Isotopic Labeling." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/16139431044791064427.

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碩士<br>國立臺灣海洋大學<br>生物科技研究所<br>94<br>Cellular processes such as proliferation, differentiation, and adaptation to environmental changes are regulated by protein phosphorylation. Qualitative and quantitative analysis of protein phosphorylation is important to elucidate the “molecular switch” in cellular processes. Increasing numbers of human diseases such as neurodegenerative diseases were discovered to involve mutations, overexpression, or malfunction of protein kinases and phosphatases as well as their regulators and effectors. In this study, we developed a new quantitation strategy to deter
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Wei, Chen Cheng, and 陳政偉. "Azobenzene-Derivative From the Coupling Reaction of Primary Amine Through Dicobalt Cataltic Reaction." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/38296579224688973964.

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碩士<br>國立中興大學<br>化學系<br>90<br>Reaction of Co2(CO)8 with HC≡CC6H4NH2 in THF at 55°C for 3 hours affords an unusual complex {[Co2(CO)6(μ-HC≡C-)]-C6H4N=}2 1 in reasonable yield. The crystal structure of 1 reveals that it can be regarded as two alkyne-bridged dicobalt fragments being united by a diazene-based ligand. Two hydrogen atoms from the amine site of the 4-ethynylaniline were detached and an N=N bond was formed during the reaction. Organic moiety of 1 was obtained in good yield by treatment of it with oxidant, Ce(IV). A mechanism of forming 1 was proposed. It has been shown previ
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Ko, Chi-Ting, and 柯紀廷. "Enantioselective synthesis of spiro cyclohexanone derivatives using cinchona alkaloid derived primary amine as organocatalyst." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/g98f9r.

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Yeh, Yu-Hui, and 葉愉惠. "Development of Carbohydrate-based Primary Amine Organocatalysts and Application to Asymmetric Aldol Reaction of Cyclohexanone with Isatines." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/67294870744746691483.

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碩士<br>中原大學<br>化學研究所<br>104<br>In this work, six novel carbohydrate-based primary amine organo-catalysts bearing multiple hydrogen bonding donors were designed and sythesized for aldol reaction of cyclohexanone with isatines. Catalyst cat-5 catalyzed the asymmetric aldol reactions between isatin dervativers and cyclic ketons with good yields ( up to 89% ) and enantoselectivity ( up to 96% ).
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Wang, Meng-Wei, and 汪孟緯. "Steric hindrance-control synthesis of primary amine-containing benzoxazines, and properties of the resulting poly(benzoxazine imide) thermosets." Thesis, 2013. http://ndltd.ncl.edu.tw/handle/04074774186164210367.

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Sultana, Tamanna. "Primary fatty acid amides in mammalian tissues isolation and analysis by HPTLC and SPE in conjunction with GC/MS /." 2005. http://etd1.library.duq.edu/theses/available/etd-05022005-132324/.

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Cox-Nowak, K., Ohood Al-Yamani, Colin A. Grant, N. H. Green, and Stephen Rimmer. "Poly(n-butyl Methacrylate) with Primary Amine End Groups for Supporting Cell Adhesion and Proliferation of Renal Epithelial Cells." 2017. http://hdl.handle.net/10454/11542.

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Yes<br>Polymer coatings that support epithelial cell culture have been developed. Ozonolysis and subsequent work up of poly(butyl methacrylate-co-butadiene) copolymers is used to form oligomers with carboxylic acid end groups, which are then further reacted with diamines to provide poly(butyl methacrylate)s with primary amine end groups. The polymers are cast as films and used as cell culture substrates for human dermal fibroblasts and human renal epithelial cells. Fibroblast and epithelial cells adhere and proliferate on acid functional materials but on amine functional films epithelial cells
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Küpke, Jochen. "Untersuchungen zur Zirkonium-katalysierten Oxidation von Alkoholen, primären Aminen und anderen Stickstoffverbindungen mit tert-Butylhydroperoxid /." 1999. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=009684270&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.

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Chang, Yu-Chang, and 張裕昌. "Design, Synthesis, Catalytic Application of a Novel Dicobalt Carbonyl-Containing Phosphine Family and Density Functional Studies on Dicobalt-Octacarbonyl Mediated Urea Formation from Primary Amine." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/28782829944019621053.

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博士<br>國立中興大學<br>化學系<br>92<br>This Ph. D thesis comprises two distinct parts which are Experiment (PART I: Design, Synthesis, Catalytic Application of a Novel Dicobalt Carbonyl-Containing Phosphine Family) and Computation (PART II: Density Functional Studies on Dicobalt- Octacarbonyl Mediated Urea Formation from Primary Amine) studies in the field of Chemistry. In Part I, several dicoblat-containing di-phosphine Ligand [{μ-P,P-PPh2CH2PPh2}Co2(CO)4{μ-PPh2CCPPh2}] (3-1)-chelated metal complexes were prepared and their fluxional behavior of the bridging DPPM on complexes were examined b
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Schade, Matthias Alexander [Verfasser]. "Cross-coupling of benzylic zinc reagents, preparation and applications of alkenyl zinc reagents, preparation of primary amides and synthesis of functionalized allenes / von Matthias Alexander Schade." 2011. http://d-nb.info/1013232666/34.

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