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1

Luceri, Francesca, Giuseppe Pieraccini, Gloriano Moneti, and Piero Dolara. "Primary Aromatic Amines from Side-Stream Cigarette Smoke are Common Contaminants of Indoor Air." Toxicology and Industrial Health 9, no. 3 (1993): 405–13. http://dx.doi.org/10.1177/074823379300900302.

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A very sensitive mass-spectrometry method has been developed for the analysis of aromatic amines in tobacco smoke and in indoor air. Cigarettes were smoked with a smoking machine; the anwies from the smoke were trapped in a 5% HCl water solution containing internal standards and detected by gas chromatography/mass spectrometry in the selected-ion-monitoring (SIM) mode. The amines measured were the following: aniline. 2-toluidine, 3-toluidine, 4-toluidine, 2-ethylaniline, 3-ethylaniline, 4-ethylaniline, 2,3-dimethylaniline, 2,4-dimethylaniline, 2,5-dimethylaniline, 2,6-dimethylaniline, 1-naphth
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2

Arora, Revika, Satya Paul, and Rajive Gupta. "A mild and efficient procedure for the conversion of aromatic carboxylic esters to secondary amides." Canadian Journal of Chemistry 83, no. 8 (2005): 1137–40. http://dx.doi.org/10.1139/v05-134.

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A mild and efficient procedure has been developed for the conversion of aromatic carboxylic esters to secondary amides using reusable Zn dust with microwave heating in the presence of N,N-dimethylformamide or conventional heating by stirring in an oil bath using THF as solvent. Zn dust can be reused several times after simple washing with dil. HCl and distilled water.Key words: aromatic carboxylic esters, aromatic primary amines, secondary amides, Zn dust, microwave activation.
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3

Bittner, Nataly, Andy Boon, Evert H. Delbanco, Christof Walter, and Angela Mally. "Assessment of aromatic amides in printed food contact materials: analysis of potential cleavage to primary aromatic amines during simulated passage through the gastrointestinal tract." Archives of Toxicology 96, no. 5 (2022): 1423–35. http://dx.doi.org/10.1007/s00204-022-03254-w.

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AbstractRecent analyses conducted by German official food control reported detection of the aromatic amides N-(2,4-dimethylphenyl)acetamide (NDPA), N-acetoacetyl-m-xylidine (NAAX) and 3-hydroxy-2-naphthanilide (Naphthol AS) in cold water extracts from certain food contact materials made from paper or cardboard, including paper straws, paper napkins, and cupcake liners. Because aromatic amides may be cleaved to potentially genotoxic primary amines upon oral intake, these findings raise concern that transfer of NDPA, NAAX and Naphthol AS from food contact materials into food may present a risk t
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4

Gu, Jiajia, Zheng Fang, Yuhang Yang, et al. "Copper-catalyzed one-pot oxidative amidation of alcohol to amide via C–H activation." RSC Advances 6, no. 92 (2016): 89413–16. http://dx.doi.org/10.1039/c6ra20732d.

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Copper-catalyzed one-pot oxidative amidation of both aliphatic and aromatic alcohols with N-chloramines, prepared in situ from many types of primary and secondary amines, to form amides under mild conditions.
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5

Amster, Regin Lawrence R. Iniya Udhaya C. John Peter Paul J.*. "PHYTOCHEMICAL ANALYSIS OF CHLOROFORM EXTRACT OF SARGASSUM LINEARIFOLIUM (TURNER) C.AG. (BROWN SEAWEED) USING UV-VIS, FTIR AND HPLC." INDO AMERICAN JOURNAL OF PHARMACEUTICAL RESEARCH 07, no. 09 (2017): 390–95. https://doi.org/10.5281/zenodo.1036435.

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The present investigation was carried to determine the phytochemicals of Sargassum linearifolium (Turner) C.Ag using UV-Visible spectroscopy, FTIR spectroscopy and HPLC. The UV-Visible spectrum of chloroform extract of Sargassum linearifolium (Turner) C.Ag. showed the peaks at the nm of 325, 412, 537, 610, 668, 882, 962, 1015 and 1059 with the absorption 1.573, 2.783, 0.593, 0.502, 1.150, 0.181, 0.108, 0.099 and 0.030 respectively. The FTIR spectrum was revealed the presence of amides, aliphatic nitro compounds, organo phosphorus compounds, ether, amines, aromatic nitro compounds, benzene ring
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6

Hlavica, P., I. Golly, M. Lehnerer, and J. Schulze. "Primary aromatic amines: their N-oxidative bioactivation." Human & Experimental Toxicology 16, no. 8 (1997): 441–48. http://dx.doi.org/10.1177/096032719701600805.

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There exists a diversity of pathways in mammalian cells serving to activate primary aromatic amines. 1 N-Oxidative mixed-function turnover usually involves participation of the cytochrome P450 superfamily, while catalysis by the flavin-containing monooxy genases is restricted to a few amines capable of forming imine tautomers. Surprisingly, haemoglobin metabo lizes cytotoxic and carcinogenic arylamines via a monooxygenase-like mechanism, but peroxygenase activity is also operative. 2 In extrahepatic tissues that exhibit only a low level of monooxygenases, peroxidative transformations, as are b
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7

Kong, Xianqiang, Huizi Zhang, Yunqing Xiao, Changsheng Cao, Yanhui Shi, and Guangsheng Pang. "Effective, transition metal free and selective C–F activation under mild conditions." RSC Advances 5, no. 10 (2015): 7035–48. http://dx.doi.org/10.1039/c4ra13753a.

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A simple and effective aromatic nucleophilic monosubstitution reaction for the synthesis of aromatic amines via selective C–F bond cleavage of various fluoroarenes with primary and secondary aromatic amines is demonstrated.
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8

Verardo, Giancarlo, Angelo G. Giumanini, Paolo Strazzolini, and Marco Poiana. "ReductiveN-Monoalkylation of Primary Aromatic Amines." Synthesis 1993, no. 01 (1993): 121–25. http://dx.doi.org/10.1055/s-1993-25813.

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9

Pasricha, Sharda, and T. M. Rangarajan. "Green Acetylation of Primary Aromatic Amines." Resonance 28, no. 2 (2023): 325–31. http://dx.doi.org/10.1007/s12045-023-1551-2.

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10

Chen, Xiao Yun, Luming Zhang, Yaonan Tang, et al. "Green H2O-Promoted Solvent-Free Synthesis of Enaminocarbonyl Compounds with High Stereoselectivity from Electron-Deficient Terminal Alkynes." Synlett 31, no. 09 (2020): 878–82. http://dx.doi.org/10.1055/s-0040-1707968.

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A green H2O-promoted solvent-free hydroamination of electron-deficient terminal alkynes with amines has been developed. All secondary amines, including aliphatic and aromatic amines, gave the corresponding (E)-enamines in good to excellent yields, whereas primary aromatic amines afforded Z-configured products in moderate yields. Propiolates, propyn-1-ones, propynamides, and 1-(ethynylsulfonyl)-4-methylbenzene were explored in this Michael addition.
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11

Hozien, Zeinab A., Abd El-Wareth A. O. Sarhan, Hassan A. H. El-Sherief, and Abdalla M. Mahmoud. "A Convenient One-Pot Synthesis of Pyrazolo[3,4-d]pyrimidines and s-Triazolo[3,4-b][1,3,5]thiadiazines." Zeitschrift für Naturforschung B 52, no. 11 (1997): 1401–12. http://dx.doi.org/10.1515/znb-1997-1119.

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Abstract The reaction of 5-amino-3-aryl-1-phenylpyrazoles (1a-d) with formaldehyde and secondary amines in boiling ethanol gave the corresponding 4-alkylaminomethyl derivatives (2a-f) and bis-(4-pyrazolyl)methane (4a,b) as byproduct. Such reaction with primary aliphatic and aro­ matic amines at room temperature afforded 1,3,5-trisubstituted (5a-h) and 1,3.5,7-tetrasubstituted tetrahydropyrazolo[3,4-d]pyrimidines (8a-k) respectively in good yield. Similarily, the Mannich reaction of 5-mercapto-3-phenyl-1,2,4-triazole (9) with secondary amines, in boiling ethanol, and primary aromatic amines, at
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12

Lupea, Xenia, and Mirabela Padure. "Synthesis and characterization of some N-substituted amides of salicylic acid." Zbornik Matice srpske za prirodne nauke, no. 104 (2003): 5–10. http://dx.doi.org/10.2298/zmspn0304005l.

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The synthesis of some N-substituted aromatic amides in the salicylic acid series was achieved, by direct reaction between primary amines and salicylic acid in inert organic solvent, in the presence of PCl3. The compounds that were obtained, partially not described in literature, were characterized by chemical-physical methods.
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13

C., S. P. SASTRY, G. RAO B., and SASTRY B.S. "Spectrophotometric Determination of Primary Aromatic Amines using Syringaldehyde." Journal of Indian Chemical Society Vol. 63, Nov 1986 (1986): 1006–7. https://doi.org/10.5281/zenodo.6298751.

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Lasminarayan Institute of Technology, Nagpnr University,&nbsp;Nagpur-440 010 <em>Manuscript received 18 October 1982, revised 8 October 1986,&nbsp;accepted 13 November 1986</em> Spectrophotometric Determination of Primary Aromatic Amines using Syringaldehyde.
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14

Tian, Qingqiang, Zongjie Gan, Xuetong Wang, et al. "Imidazolium Chloride: An Efficient Catalyst for Transamidation of Primary Amines." Molecules 23, no. 9 (2018): 2234. http://dx.doi.org/10.3390/molecules23092234.

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A highly efficient and convenient protocol of imidazolium chloride (30 mol %) catalyzed amidation of amines with moderate to excellent yields was reported. The protocol shows broad substrate scope for aromatic, aliphatic, and heterocyclic primary amines.
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15

Chuang, Gary, Hua-Hsuan Huang, Yu-Feng Chen, and Guang-Hao Niu. "Photoinduced Reduction of Nitrobenzenes to Primary Aromatic Amines." Synlett 28, no. 10 (2017): 1191–94. http://dx.doi.org/10.1055/s-0036-1588953.

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Primary aromatic amines were synthesized from the corresponding nitrobenzenes via photoinduced reduction. The reaction was found to be effective when nitrobenzenes with electron-withdrawing substituents were irradiated with a broad band of UV light centered at 306 nm. When reactions are completed, products could be isolated by acid–base extraction or by column chromatography. This presenting photoreaction procedure for the synthesis of primary aromatic amines from the corresponding nitrobenzenes proceeds without the need of a sensitizer in isopropanol or THF. Without the usage of catalysts, or
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16

Kahovec, J. "Simple synthesis of polymeric primary aromatic amines." Polymer Bulletin 19, no. 5 (1988): 423–26. http://dx.doi.org/10.1007/bf00263909.

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17

Panarina, A. E., A. V. Aleksandrova, A. V. Dogadina, and B. I. Ionin. "Reaction of Aminoethynylphosphonates with Primary Aromatic Amines." Russian Journal of General Chemistry 75, no. 1 (2005): 3–8. http://dx.doi.org/10.1007/s11176-005-0162-9.

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18

Frank, H. G. "Mechanisms and products of azo coupling in histochemical protease procedures based on primary aromatic amines as unspecific moieties." Journal of Histochemistry & Cytochemistry 38, no. 9 (1990): 1295–300. http://dx.doi.org/10.1177/38.9.2201736.

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It is presumed that the azo dyes generated by histochemical protease reactions are formed by substitution of a reactive aromatic carbon. They are referred to as dyes of the C-azo series. To confirm this assumption, the absorption spectra between 330 and 630 nm of azo dyes resulting from coupling between various aromatic amines of the aniline and naphthylamine series and the diazonium salts Fast Blue B and Fast Garnet GBC were studied in test tube experiments. Some of the amines were blocked by methylation to prevent coupling either at the amino group (N-methylated) or at the aromatic nucleus (
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19

Bonar-Law, R. P., A. P. Davis, and B. J. Dorgan. "The “benzostabase” protecting group for primary amines; application to aromatic amines." Tetrahedron Letters 31, no. 46 (1990): 6721–24. http://dx.doi.org/10.1016/s0040-4039(00)97157-0.

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20

Hung, Tran Quang, Tuan Thanh Dang, Peter Langer, et al. "Efficient Copper-Catalysed Synthesis of Carbazoles by Double N-Arylation of Primary Amines with 2,2′-Dibromobiphenyl in the Presence of Air." Synlett 32, no. 06 (2021): 611–15. http://dx.doi.org/10.1055/s-0040-1706641.

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AbstractAn efficient Cu-catalyzed synthesis of carbazole derivatives is reported, which proceeds by double C–N coupling reactions of 2,2′-dibromobiphenyl and amines in the presence of air. The reaction is robust, proceeds in high yields, and tolerates a series of amines including neutral, electron-rich, electron-deficient aromatic amines and aliphatic amines.
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21

Zhao, Ziming, Yu Long, Sha Luo, Wei Wu, and Jiantai Ma. "Preparation of a magnetic mesoporous Fe3O4–Pd@TiO2 photocatalyst for the efficient selective reduction of aromatic cyanides." New Journal of Chemistry 43, no. 16 (2019): 6294–302. http://dx.doi.org/10.1039/c8nj06508j.

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22

Bei, M. P., and A. P. Yuvchenko. "Synthesis of new imides and imidoamides of citraconopimaric acid." Proceedings of the National Academy of Sciences of Belarus, Chemical Series 59, no. 1 (2023): 35–41. http://dx.doi.org/10.29235/1561-8331-2023-59-1-35-41.

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For the first time, a method has been developed for the synthesis of aromatic imides of citraconopimaric acid by the interaction of primary aromatic amines (aniline, p-toluidine) and citraconopimaric acid in p-xylene at reflux. New aliphatic imides have been synthesized by the reaction of citraconopimaric acid and primary aliphatic amines (octyl-, octadecylamine) in a melt at 125–150°C. For the first time, the synthesis of citraconopimaric acid imidoamides was developed by treating citraconopimaric acid N-octylimide with thionyl chloride and subsequent reaction of the resulting acid chloride w
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23

MUTSUGA, Motoh, Youn-Kyu LEE, Yoko KAWAMURA, and Kenichi TANAMOTO. "Analysis of Primary Aromatic Amines in Paper Products." Journal of the Food Hygienic Society of Japan (Shokuhin Eiseigaku Zasshi) 50, no. 4 (2009): 160–68. http://dx.doi.org/10.3358/shokueishi.50.160.

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24

Chinthakindi, Sridhar, and Kurunthachalam Kannan. "Variability in urinary concentrations of primary aromatic amines." Science of The Total Environment 831 (July 2022): 154768. http://dx.doi.org/10.1016/j.scitotenv.2022.154768.

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25

Mařı́k, Jan, Aimin Song, and Kit S. Lam. "Detection of primary aromatic amines on solid phase." Tetrahedron Letters 44, no. 23 (2003): 4319–20. http://dx.doi.org/10.1016/s0040-4039(03)00984-5.

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26

Le Pera, Adolfo, Antonella Leggio, and Angelo Liguori. "Highly specific N-monomethylation of primary aromatic amines." Tetrahedron 62, no. 25 (2006): 6100–6106. http://dx.doi.org/10.1016/j.tet.2006.03.104.

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27

Perharic, L., V. Golja, A. Zoric, and M. Luci. "Primary aromatic amines in kitchen utensils in Slovenia." Toxicology Letters 164 (September 2006): S278—S279. http://dx.doi.org/10.1016/j.toxlet.2006.07.238.

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28

Al-Sabha, Theia'a N., and Najwa M. Al-Karemy. "The Use of 7,7′,8,8′-Tetracyanoquinodimethane for the Spectrophotometric Determination of Some Primary Amines Application to Real Water Samples." Journal of Analytical Methods in Chemistry 2013 (2013): 1–8. http://dx.doi.org/10.1155/2013/803767.

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A sensitive, simple, and accurate spectrophotometric method was developed for the quantitative determination of some primary aliphatic and aromatic amines, that is, ethylamine, 1,2-diaminopropane, aniline, p-aminophenol, and benzidine. The method is based on the interaction of these amines in aqueous medium with 7,7′,8,8′-tetracyanoquinodimethane (TCNQ) reagent in the presence of a buffer solution and surfactant (in the case of aromatic amines) to form charge-transfer complexes measurable at maximum wavelengths ranging between 323 and 511 nm. Beer’s law is obeyed over the concentration ranges
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29

Young, Michael, Mohit Kapoor, Pratibha Chand-Thakuri, Justin Maxwell, Daniel Liu, and Hanyang Zhou. "Carbon Dioxide-Driven Palladium-Catalyzed C–H Activation of Amines: A Unified Approach for the Arylation of Aliphatic and Aromatic Primary and Secondary Amines." Synlett 30, no. 05 (2019): 519–24. http://dx.doi.org/10.1055/s-0037-1611381.

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Amines are an important class of compounds in organic chemistry and serve as an important motif in various industries, including pharmaceuticals, agrochemicals, and biotechnology. Several methods have been developed for the C–H functionalization of amines using various directing groups, but functionalization of free amines remains a challenge. Here, we discuss our recently developed carbon dioxide driven highly site-selective γ-arylation of alkyl- and benzylic amines via a palladium-catalyzed C–H bond-activation process. By using carbon dioxide as an inexpensive, sustainable, and transient dir
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30

Verkade, P. E., H. Nijon, F. D. Tollenaar, J. H. van Rij, and M. van Leeuwen. "Trityl derivatives of amines: I. N-trityl derivatives of aromatic primary amines." Recueil des Travaux Chimiques des Pays-Bas 71, no. 10 (2010): 1007–11. http://dx.doi.org/10.1002/recl.19520711008.

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31

Ojeda-Porras, Andrea, Alejandra Hernández-Santana, and Diego Gamba-Sánchez. "Direct amidation of carboxylic acids with amines under microwave irradiation using silica gel as a solid support." Green Chemistry 17, no. 5 (2015): 3157–63. http://dx.doi.org/10.1039/c5gc00189g.

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A highly improved methodology for the direct amidation of carboxylic acids with amines using silica gel as a solid support and catalyst is described. Several examples using aliphatic, aromatic, unsaturated and fatty acids combined with primary and secondary amines are shown.
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32

Fujita, Ken-ichi, Genki Toyooka, and Akiko Tuji. "Efficient and Versatile Catalytic Systems for the N-Methylation of Primary Amines with Methanol Catalyzed by N-Heterocyclic Carbene Complexes of Iridium." Synthesis 50, no. 23 (2018): 4617–26. http://dx.doi.org/10.1055/s-0037-1610252.

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Efficient and versatile catalytic systems were developed for the N-methylation of both aliphatic and aromatic primary amines using methanol as the methylating agent. Iridium complexes bearing an N-heterocyclic carbene (NHC) ligand exhibited high catalytic performance for this type of transformation. For aliphatic amines, selective N,N-dimethylation was achieved at low temperatures (50–90 °C). For aromatic amines, selective N-monomethylation and selective N,N-dimethylation were accomplished by simply changing the reaction conditions (presence or absence of a base with an appropriate catalyst).
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33

Largeron, Martine, and Khac Nguyen. "Recent Advances in the Synthesis of Benzimidazole Derivatives from the Oxidative Coupling of Primary Amines." Synthesis 50, no. 02 (2017): 241–53. http://dx.doi.org/10.1055/s-0036-1590915.

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Benzimidazole belongs to the top five most commonly used five-membered aromatic nitrogen heterocycles among U.S. FDA approved pharmaceuticals. Over the last few years, a large number of improved synthetic strategies have been developed to construct the benz­imidazole molecular framework under environmentally benign conditions. This review focuses on the use of primary amines as readily available substrates for the synthesis of benzimidazole derivatives through different types of oxidative cross-coupling reactions.1 Introduction2 Catalyst-Free Oxidative Coupling of Primary Amines3 Catalytic Oxi
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34

Agamaliyeva, M. M., A. M. Pashajanov, T. M. Ismailov, N. I. Ismailov, and G. O. Hasanova. "AMINOMETHYLATION OF DIHYDROXYACETOPHENONES." Azerbaijan Chemical Journal, no. 3 (September 22, 2022): 81–86. http://dx.doi.org/10.32737/0005-2531-2022-3-81-86.

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Aminomethylation of trifunctional 2.5-dihydroxyacetophenone (2.5-DHA) and 2.4-dihydro¬xy¬aceto-phenone (2.4-DHA) by free primary and secondary amines in the presence of formaldehyde has been conducted for the first time. It has been established that 2.5-DHA is aminomethylated with secondary heterocyclic amines - piperidine and morpholine and with aqueous formaldehyde solution in alcohol medium at 500C. The reaction proceeds simultaneously via all three functions forming stable C,O-substitution products − β-amino-2-aminomethoxy-4-aminomethyl-5-hydroxypropiophenones. The aminomethylation reactio
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35

Hossain, M. M., M. A. Foysal, M. Mahabub, and Al Amin. "Microwave-assisted Efficient Synthesis of Isatins and spiro-Thiadiazolines under Green Chemistry Protocol." Journal of Scientific Research 2, no. 2 (2010): 322–29. http://dx.doi.org/10.3329/jsr.v2i2.3731.

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MW-assisted treatment of oximinoacetanilides obtained from substituted primary aromatic amines was carried out in conc. H2SO4 medium for 5-10 sec to give cyclic amides (isatins) through intramolecular cyclization by means of electrophilic aromatic substitution. Isatins reacted with thiosemicarbazide under MW-condition gave the corresponding Schiff-bases. The Schiff-bases undergo cyclization in presence of minimal Ac2O under MW-irradiation for 3-4 min to give the spiro-thiadiazoline acetyl derivatives in excellent yield. Keywords: Microwave-synthesis; Isatins; Schiff-base; spiro-Thiadiazoline;
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36

Filatov, Vadim Evgenievich, Dmitrii Aleksandrovich Iuzabchuk, Dmitry Alexandrovich Guk, Dmitrii Anatol'evich Lemenovskii, and Elena Kimovna Beloglazkina. "Facile, efficient and green phthalimide synthesis in supercritical carbon dioxide." Mendeleev Communications 35, no. 3 (2025): 341–43. https://doi.org/10.71267/mencom.7646.

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The reactions between phthalic anhydrides and primary amines in supercritical CO&lt;sub&gt;2&lt;/sub&gt; (80-110 bar) to afford the corresponding phthalimides proceed at temperatures of 120-130 °C (aliphatic amines) or 260-275 °C (aromatic amines). The developed procedure fully complies with the principles of green chemistry and allows one to obtain target phthalimides in 65-85
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37

Ohtsuka, Naoya, Moriaki Okuno, Yujiro Hoshino, and Kiyoshi Honda. "A base-mediated self-propagative Lossen rearrangement of hydroxamic acids for the efficient and facile synthesis of aromatic and aliphatic primary amines." Organic & Biomolecular Chemistry 14, no. 38 (2016): 9046–54. http://dx.doi.org/10.1039/c6ob01178k.

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38

Dubey, Rahul, Vinay K. Singh, Laxmi Kant Sharma, Abhishek Upadhyay, Narendra Kumar, and Rana Krishna Pal Singh. "A convenient electro-catalyzed multicomponent synthesis of 4H-thiopyran derivatives." New Journal of Chemistry 41, no. 16 (2017): 7836–39. http://dx.doi.org/10.1039/c7nj01211j.

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39

Punrattanasin, Nattaya. "Investigation of Ultraviolet Protection Properties of Cotton Fabric via Azoic Dyeing with Green Tea Extract." Advanced Materials Research 331 (September 2011): 279–82. http://dx.doi.org/10.4028/www.scientific.net/amr.331.279.

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Green tea dyeing of cotton fabric via azoic combination method was investigated in order to improve ultraviolet protection properties without the application of polutting metal mordants. Three types of diazonium salts were prepared from three different primary aromatic amines (aniline, p-nitroaniline and 2,4 dichoroaniline) and subsequently, reacted with pretreated cotton fabric with coupling component or polyphenolic compounds found in green tea extract to form an azo dye inside the cellulose matrix. The result showed that as the strength of electron withdrawing groups of the substituents in
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40

Nabar, Kasturi U., Bhalchandra M. Bhanage, and Sudam G. Dawande. "Copper-catalyzed N-arylation of amines with aryliodonium ylides in water." Beilstein Journal of Organic Chemistry 19 (July 4, 2023): 1008–14. http://dx.doi.org/10.3762/bjoc.19.76.

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Copper sulfate catalyzed an efficient, inexpensive, and environment-friendly protocol that has been developed for N-arylation of amines with 1,3-cyclohexadione-derived aryliodonium ylides in water as a green solvent. Aromatic primary amines substituted with electron-donating as well as electron-withdrawing groups on the aryl ring reacted smoothly with iodonium ylides to give the corresponding diarylamines with good to excellent yields. Also, secondary amines underwent N-arylation to deliver tertiary amines with moderate yields.
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41

Chakraborty, Subrata, Gregory Leitus, and David Milstein. "Selective hydrogenation of nitriles to primary amines catalyzed by a novel iron complex." Chemical Communications 52, no. 9 (2016): 1812–15. http://dx.doi.org/10.1039/c5cc08204h.

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A novel complex based on earth-abundant iron, and its application in the catalytic homogeneous hydrogenation of (hetero)aromatic, benzylic, and aliphatic nitriles to selectively form primary amines is discovered.
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42

BONAR-LAW, R. P., A. P. DAVIS, and B. J. DORGAN. "ChemInform Abstract: The “Benzostabase” Protecting Group for Primary Amines. Application to Aromatic Amines." ChemInform 23, no. 15 (2010): no. http://dx.doi.org/10.1002/chin.199215108.

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43

Jiang, Zhaoqiong, Zhiqing Wu, Lixia Wang, Di Wu, and Xiangge Zhou. "Preparation of aromatic amines by copper-catalyzed coupling of boronic acids with aqueous ammonia." Canadian Journal of Chemistry 88, no. 9 (2010): 964–68. http://dx.doi.org/10.1139/v10-105.

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A simple, highly efficient, and environmentally friendly protocol for the synthesis of primary aromatic amines by catalytic coupling of aromatic boronic acids with aqueous ammonia has been developed by using commercial and inexpensive CuSO4·5H2O as catalyst without addition of other solvents under mild reaction conditions.
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44

Lu, Wenchao, and Chanjuan Xi. "CuCl-catalyzed aerobic oxidative reaction of primary aromatic amines." Tetrahedron Letters 49, no. 25 (2008): 4011–15. http://dx.doi.org/10.1016/j.tetlet.2008.04.089.

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45

VERARDO, G., A. G. GIUMANINI, P. STRAZZOLINI, and M. POIANA. "ChemInform Abstract: Reductive N-Monoalkylation of Primary Aromatic Amines." ChemInform 24, no. 38 (2010): no. http://dx.doi.org/10.1002/chin.199338135.

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46

Kalyuzhnyi, S., V. Sklyar, T. Mosolova, I. Kucherenko, J. a. Russkova, and N. Degtyaryova. "Methanogenic biodegradation of aromatic amines." Water Science and Technology 42, no. 5-6 (2000): 363–70. http://dx.doi.org/10.2166/wst.2000.0536.

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Batch methanogenic toxicity and biodegradability of 2-, 3- and 4-aminobenzoic acids (ABA) as well as 4- and 5-aminosalicylic acids (ASA) have been studied in the presence of two mesophilic (Shell and cattle) and one thermophilic sludges. The aminoaromatics tested practically did not inhibit methanogenesis up to concentrations of 3–7 g/l; moreover, some of them (2-ABA, 4-ABA and 5-ASA) even exert a stimulating effect on aceticlastic activity of the sludges. Concerning biodegradability, 5-ASA was completely mineralised by all the sludges tested; however, 4-ASA was not degraded at all by any of t
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47

Orestes, Ednilsom, Célia Machado Ronconi, and José Walkimar de Mesquita Carneiro. "Insights into the interactions of CO2 with amines: a DFT benchmark study." Phys. Chem. Chem. Phys. 16, no. 32 (2014): 17213–19. http://dx.doi.org/10.1039/c4cp02254h.

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48

Huang, Haizhou, Zitong Wu, Guorui Gao, Le Zhou, and Mingxin Chang. "Iridium-catalyzed direct asymmetric reductive amination of aromatic ketones." Organic Chemistry Frontiers 4, no. 10 (2017): 1976–80. http://dx.doi.org/10.1039/c7qo00400a.

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49

Chandrashekhar, Vishwas G., Wolfgang Baumann, Matthias Beller, and Rajenahally V. Jagadeesh. "Nickel-catalyzed hydrogenative coupling of nitriles and amines for general amine synthesis." Science 376, no. 6600 (2022): 1433–41. http://dx.doi.org/10.1126/science.abn7565.

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Efficient and general methods for the synthesis of amines remain in high demand in the chemical industry. Among the many known processes, catalytic hydrogenation is a cost-effective and industrially proven reaction and currently used to produce a wide array of such compounds. We report a homogeneous nickel catalyst for hydrogenative cross coupling of a range of aromatic, heteroaromatic, and aliphatic nitriles with primary and secondary amines or ammonia. This general hydrogenation protocol is showcased by straightforward and highly selective synthesis of &gt;230 functionalized and structurally
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50

Khullar, Anju. "Studies and Synthesis of Substituted 4-Biphenyl Acetamide Derivatives." Asian Journal of Chemistry 31, no. 3 (2019): 510–14. http://dx.doi.org/10.14233/ajchem.2019.21579.

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A new series of substituted 4-biphenylamides have been synthesized by condensation of 4-biphenyl acetic acid with different primary amines (aromatic and aliphatic). 4-Biphenyl acetic acid was first treated with thionyl chloride in dry benzene to prepare substituted 4-biphenyl acetyl chloride, which is then treated with different aliphatic or aromatic amines to synthesize various substituted 4-biphenyl acid-amide derivatives. The structure of newly synthesized compounds has been established by analytical and spectral methods. These synthesized compounds have shown antifungal properties against
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