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Journal articles on the topic 'Propanal'

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1

Lepore, Giuseppe P., Bhuvan C. Pant, and Cooper H. Langford. "Limiting quantum yield measurements for the disappearance of 1-propanol and propanal: an oxidative reaction study employing a TiO2 based photoreactor." Canadian Journal of Chemistry 71, no. 12 (1993): 2051–59. http://dx.doi.org/10.1139/v93-255.

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Relative initial quantum yields [Formula: see text] for the disappearance of 1-propanol and propanal were estimated based on total light intensity entering the reaction vessels. Two types of photocatalytic reactor geometries were compared, a commercial prototype flow reactor with immobilized TiO2 and a conventional reactor with TiO2 dispersion. A maximum relative quantum yield, [Formula: see text], was extrapolated for pure propanol and propanal in both geometries. The high quantum yields were attributed to efficient competition of substrate oxidation with electron–hole recombination, at high
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2

Qasim, D., G. Fedoseev, K. J. Chuang, et al. "Synthesis of solid-state complex organic molecules through accretion of simple species at low temperatures." Proceedings of the International Astronomical Union 15, S350 (2019): 46–50. http://dx.doi.org/10.1017/s174392131900975x.

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AbstractComplex organic molecules (COMs) have been detected in the gas-phase in cold and lightless molecular cores. Recent solid-state laboratory experiments have provided strong evidence that COMs can be formed on icy grains through ‘non-energetic’ processes. In this contribution, we show that propanal and 1-propanol can be formed in this way at the low temperature of 10 K. Propanal has already been detected in space. 1-propanol is an astrobiologically relevant molecule, as it is a primary alcohol, and has not been astronomically detected. Propanal is the major product formed in the C2H2 + CO
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3

Truong Duc, Duc, Huy Nguyen Trung, and Thang Le Minh. "Improving the catalytic activity of Au/SiO2 catalyst in the directly conversion of CO2, C2H4 and H2 using a new dual-reactor concept." Vietnam Journal of Catalysis and Adsorption 9, no. 1 (2020): 81–87. http://dx.doi.org/10.51316/jca.2020.013.

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Directly conversion of CO2 to propanol using C2H4 and H2 had succeeded over Au/SiO2 catalyst in one reactor mode. However, application of new dual-reactor concept enhaned the catalytic activity strongly by using two saparated reactors. To this details, a first reactor is used to convert CO2 to CO through the reverse water gas shift (RWGS) reaction, consecutive hydroformylation of C2H4 with resulting CO and H2 to propanal and finally the hydrogenation of propanal to propanol takes place in a second reactor at a different temperature. The selectivity to oxo products (propanol and propanal) incre
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4

Ngadiwiyana, Ngadiwiyana, Ismiyarto Ismiyarto, Jumina Jumina, and Chairil Anwar. "Sintesis 3-(3,4-Dimetoksifenil)-Propanal sebagai Senyawa Antara dalam Pembuatan Turunan Antiboitik C-9154 dari Minyak Daun Cengkeh." Jurnal Kimia Sains dan Aplikasi 11, no. 2 (2008): 38–42. http://dx.doi.org/10.14710/jksa.11.2.38-42.

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Telah dilakukan sintesis senyawa antara 3-(3,4-dimetoksifenil) propanal dalam pembuatan turunan antibiotik C-9154 sebagai upaya perluasan poemanfaatan minyak kayu cengkeh. Eugenol merupakan komponen utama minyak daun cengkeh yang dapat diisolasi menggunakan pelarut natrium hidroksida. Pemanfaatan senyawa ini masih sangat terbatas, sehingga perlu dilakukan upaya pengubahan eugenol menjadi senyawa turunannya yang lebih berdaya guna. Salah satunya, eugenol dapat diubah menjadi senyawa 3-(3,4-dimetoksifenil)-propanal, senyawa tersebut digunakan sebagai bahan untuk mensintesis senyawa turunan antib
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5

Qasim, D., G. Fedoseev, K. J. Chuang, et al. "Formation of interstellar propanal and 1-propanol ice: a pathway involving solid-state CO hydrogenation." Astronomy & Astrophysics 627 (June 25, 2019): A1. http://dx.doi.org/10.1051/0004-6361/201935217.

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Context. 1-propanol (CH3CH2CH2OH) is a three carbon-bearing representative of the primary linear alcohols that may have its origin in the cold dark cores in interstellar space. To test this, we investigated in the laboratory whether 1-propanol ice can be formed along pathways possibly relevant to the prestellar core phase. Aims. We aim to show in a two-step approach that 1-propanol can be formed through reaction steps that are expected to take place during the heavy CO freeze-out stage by adding C2H2 into the CO + H hydrogenation network via the formation of propanal (CH3CH2CHO) as an intermed
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6

Neurock, Matthew, Zhiyuan Tao, Ashwin Chemburkar, David D. Hibbitts, and Enrique Iglesia. "Theoretical insights into the sites and mechanisms for base catalyzed esterification and aldol condensation reactions over Cu." Faraday Discussions 197 (2017): 59–86. http://dx.doi.org/10.1039/c6fd00226a.

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Condensation and esterification are important catalytic routes in the conversion of polyols and oxygenates derived from biomass to fuels and chemical intermediates. Previous experimental studies show that alkanal, alkanol and hydrogen mixtures equilibrate over Cu/SiO<sub>2</sub> and form surface alkoxides and alkanals that subsequently promote condensation and esterification reactions. First-principle density functional theory (DFT) calculations were carried out herein to elucidate the elementary paths and the corresponding energetics for the interconversion of propanal + H<sub>2</sub> to prop
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7

O’Toole, Timothy E., Xiaohong Li, Daniel W. Riggs, David J. Hoetker, Shahid P. Baba, and Aruni Bhatnagar. "Urinary Levels of the Acrolein Conjugates of Carnosine Are Associated with Cardiovascular Disease Risk." International Journal of Molecular Sciences 22, no. 3 (2021): 1383. http://dx.doi.org/10.3390/ijms22031383.

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Carnosine is a naturally occurring dipeptide (β-alanine-L-histidine) which supports physiological homeostasis by buffering intracellular pH, chelating metals, and conjugating with and neutralizing toxic aldehydes such as acrolein. However, it is not clear if carnosine can support cardiovascular function or modify cardiovascular disease (CVD) risk. To examine this, we measured urinary levels of nonconjugated carnosine and its acrolein conjugates (carnosine-propanal and carnosine-propanol) in participants of the Louisville Healthy Heart Study and examined associations with indices of CVD risk. W
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8

Esan, Dominic A., and Michael Trenary. "Surface chemistry of propanal, 2-propenol, and 1-propanol on Ru(001)." Physical Chemistry Chemical Physics 19, no. 17 (2017): 10870–77. http://dx.doi.org/10.1039/c6cp08893g.

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9

Muir, Mark, David L. Molina, Arephin Islam, Mohammed K. Abdel-Rahman, and Michael Trenary. "Adsorption properties of acrolein, propanal, 2-propenol, and 1-propanol on Ag(111)." Physical Chemistry Chemical Physics 22, no. 43 (2020): 25011–20. http://dx.doi.org/10.1039/d0cp04634e.

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10

Mezyk, Stephen P. "Rate constant and activation energy determination for reaction of e−(aq) and •OH with 2-butanone and propanal." Canadian Journal of Chemistry 72, no. 4 (1994): 1116–19. http://dx.doi.org/10.1139/v94-142.

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The techniques of pulse radiolysis and absorption spectroscopy have been used to determine kinetic parameters for e−(aq) and •OH reaction with 2-butanone and propanal. The temperature dependent rate constants for hydrated electron reaction are given by ln k(T) = (28.96 ± 0.06) − (1970 ± 20)/T' (2-butanone, 275–343 K), and ln k(T) = (29.2 ± 0.2) − (2160 ± 50)/T (propanal, 275–310 K), where the given uncertainties are 1σ and only represent precision, and the rate constants are in units of M−1 s−1. For hydroxyl radical reaction over the same temperature ranges. ln k(T) = 25.32 ± 0.02) − (1460 ± 4
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11

Yang, Ke, Cheng Zhan, Xingjia Man, Li Guan, Zuohua Huang, and Chenglong Tang. "Shock Tube Study on Propanal Ignition and the Comparison to Propane, n-Propanol, and i-Propanol." Energy & Fuels 30, no. 1 (2016): 717–24. http://dx.doi.org/10.1021/acs.energyfuels.5b02739.

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12

Van Wyngarden, A. L., S. Pérez-Montaño, J. V. H. Bui, et al. "Complex chemical composition of colored surface films formed from reactions of propanal in sulfuric acid at upper troposphere/lower stratosphere aerosol acidities." Atmospheric Chemistry and Physics Discussions 14, no. 21 (2014): 28571–608. http://dx.doi.org/10.5194/acpd-14-28571-2014.

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Abstract. Particles in the upper troposphere and lower stratosphere (UT/LS) consist mostly of concentrated sulfuric acid (40–80 wt %) in water. However, airborne measurements have shown that these particles also contain a significant fraction of organic compounds of unknown chemical composition. Acid-catalyzed reactions of carbonyl species are believed to be responsible for significant transfer of gas phase organic species into tropospheric aerosols and are potentially more important at the high acidities characteristic of UT/LS particles. In this study, experiments combining sulfuric acid (H2
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13

Van Wyngarden, A. L., S. Pérez-Montaño, J. V. H. Bui, et al. "Complex chemical composition of colored surface films formed from reactions of propanal in sulfuric acid at upper troposphere/lower stratosphere aerosol acidities." Atmospheric Chemistry and Physics 15, no. 8 (2015): 4225–39. http://dx.doi.org/10.5194/acp-15-4225-2015.

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Abstract. Particles in the upper troposphere and lower stratosphere (UT/LS) consist mostly of concentrated sulfuric acid (40–80 wt%) in water. However, airborne measurements have shown that these particles also contain a significant fraction of organic compounds of unknown chemical composition. Acid-catalyzed reactions of carbonyl species are believed to be responsible for significant transfer of gas phase organic species into tropospheric aerosols and are potentially more important at the high acidities characteristic of UT/LS particles. In this study, experiments combining sulfuric acid (H2S
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14

Ngadiwiyana, Ngadiwiyana, Ismiyarto Ismiyarto, and Ayu Ratri Kartika Iriany. "Oksidasi 3-(3,4-dimetoksifenil)-propanol dengan Menggunakan Oksidator Piridinium Klorokromat (PCC)." Jurnal Kimia Sains dan Aplikasi 10, no. 3 (2007): 68–71. http://dx.doi.org/10.14710/jksa.10.3.68-71.

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3-(3,4-dimetoksfenil)-propanol mudah dioksidasi menjadi bentuk aldehida-nya menggunakan piridinium klorokromat (PCC) tanpa menimbulkan oksidasi lebih lanjut membentuk asam karboksilat. PCC telah disintesis dengan mereaksikan reacting HCl dan CrO3, diikuti dengan penambahan piridin dalam larutan pada suhu 0oC dan hasilnya 85%. Sedangkan, reaksi oksidasi dari 3-(3,4-dimetoksfenil)-propanol dengan PCC sebagai oksidator dilakukan dalam diklorometan selama 3 jam dan direfluks pada suhu 30oC dan rasio mol alkohol:PCC adalah 1:2. Produk oksidasi diekstraksi menggunakan dietileter dan diuapkan, mengha
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15

Ngadiwiyana, Ngadiwiyana, Ismiyarto Ismiyarto, and Ayu Ratri Kartika Iriany. "Oksidasi 3-(3,4-dimetoksifenil)-propanol dengan Menggunakan Oksidator Piridinium Klorokromat (PCC)." Jurnal Kimia Sains dan Aplikasi 10, no. 3 (2007): 72–77. http://dx.doi.org/10.14710/jksa.10.3.72-77.

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3-(3,4-dimetoksfenil)-propanol mudah dioksidasi menjadi bentuk aldehida-nya menggunakan piridinium klorokromat (PCC) tanpa menimbulkan oksidasi lebih lanjut membentuk asam karboksilat. PCC telah disintesis dengan mereaksikan reacting HCl dan CrO3, diikuti dengan penambahan piridin dalam larutan pada suhu 0oC dan hasilnya 85%. Sedangkan, reaksi oksidasi dari 3-(3,4-dimetoksfenil)-propanol dengan PCC sebagai oksidator dilakukan dalam diklorometan selama 3 jam dan direfluks pada suhu 30oC dan rasio mol alkohol:PCC adalah 1:2. Produk oksidasi diekstraksi menggunakan dietileter dan diuapkan, mengha
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16

Jakoubková, Marie, and Josef Pola. "CO2 laser induced decomposition of propylene oxide." Collection of Czechoslovak Chemical Communications 55, no. 10 (1990): 2455–59. http://dx.doi.org/10.1135/cccc19902455.

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The continuous-wave (cw) CO2 laser induced decomposition of propylene oxide yields propanal, propanone and methyl vinyl ether as primary isomerization products. The absence of allylol and great amounts of ethene among products of ensuing fragmentation of primary products make the reaction different from conventional thermal decomposition of propylene oxide. CW CO2 laser induced decomposition of methyl vinyl ether affords propanal as isomerization product and shows thermal interconvertibility of propylene oxide and methyl vinyl ether.
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17

Martsinkevich, E. M., A. A. Afaunov, V. R. Flid, and L. G. Bruk. "Heterogeneous catalytic condensation of propanal." Russian Chemical Bulletin 70, no. 10 (2021): 2031–33. http://dx.doi.org/10.1007/s11172-021-3313-1.

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18

Mondal, Suman Kumar, Prasanta Gorai, Milan Sil, et al. "Is There Any Linkage between Interstellar Aldehyde and Alcohol?" Astrophysical Journal 922, no. 2 (2021): 194. http://dx.doi.org/10.3847/1538-4357/ac1f31.

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Abstract It is speculated that there might be some linkage between interstellar aldehydes and their corresponding alcohols. Here an observational study and astrochemical modeling are coupled together to illustrate the connection between them. The ALMA cycle 4 data of a hot molecular core, G10.47+0.03, are utilized for this study. Various aldehydes (acetaldehyde, propanal, and glycolaldehyde), alcohols (methanol and ethylene glycol), and a ketone (acetone) are identified in this source. The excitation temperatures and column densities of these species were derived via the rotation diagram metho
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19

Gong, Jing, Shuang Zhang, Yu Cheng, Zuohua Huang, Chenglong Tang, and Jiaxiang Zhang. "A comparative study of n -propanol, propanal, acetone, and propane combustion in laminar flames." Proceedings of the Combustion Institute 35, no. 1 (2015): 795–801. http://dx.doi.org/10.1016/j.proci.2014.05.066.

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20

Godunov, I. A., N. N. Yakovlev, R. V. Terentiev, D. V. Maslov, and A. V. Abramenkov. "The S1 ← S0 fluorescence excitation spectrum and structure of propanal in the S1 excited electronic state." Physical Chemistry Chemical Physics 18, no. 22 (2016): 15244–50. http://dx.doi.org/10.1039/c6cp02138g.

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21

Singh, Santosh K., N. Fabian Kleimeier, André K. Eckhardt, and Ralf I. Kaiser. "A Mechanistic Study on the Formation of Acetone (CH3COCH3), Propanal (CH3CH2CHO), Propylene Oxide (c-CH3CHOCH2) along with Their Propenol Enols (CH3CHCHOH/CH3C(OH)CH2) in Interstellar Analog Ices." Astrophysical Journal 941, no. 2 (2022): 103. http://dx.doi.org/10.3847/1538-4357/ac8c92.

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Abstract Carbonyl-bearing complex organic molecules (COMs) in the interstellar medium (ISM) are of significant importance due to their role as potential precursors to biomolecules. Simple aldehydes and ketones like acetaldehyde, acetone, and propanal have been recognized as fundamental molecular building blocks and tracers of chemical processes involved in the formation of distinct COMs in molecular clouds and star-forming regions. Although previous laboratory simulation experiments and modeling established the potential formation pathways of interstellar acetaldehyde and propanal, the underly
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22

Magdalinova, N. A., T. G. Volkova, M. V. Klyuev, and M. S. Gruzdev. "Propanal hydroamination with p-aminobenzoic acid." Russian Journal of Organic Chemistry 46, no. 5 (2010): 634–36. http://dx.doi.org/10.1134/s1070428010050052.

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23

HAGGIN, JOSEPH. "New routes lead to benzene, propanal." Chemical & Engineering News 71, no. 19 (1993): 22–23. http://dx.doi.org/10.1021/cen-v071n019.p022.

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24

Gao, Daming, Dechun Zhu, Linyun Zhang, et al. "Isobaric Vapor−Liquid Equilibria for Binary and Ternary Mixtures of Propanal, Propanol, and Propanoic Acid." Journal of Chemical & Engineering Data 55, no. 12 (2010): 5887–95. http://dx.doi.org/10.1021/je100912t.

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25

Rodrigues, E. G., T. C. Keller, S. Mitchell, and J. Pérez-Ramírez. "Hydroxyapatite, an exceptional catalyst for the gas-phase deoxygenation of bio-oil by aldol condensation." Green Chem. 16, no. 12 (2014): 4870–74. http://dx.doi.org/10.1039/c4gc01432d.

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Hydroxyapatites displaying high surface concentrations of calcium exhibit exceptional performance in the gas-phase condensation of propanal, a model substrate for the intermediate deoxygenation of biocrude.
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Tian, Xiao-Qing, Lin Liu, Xiang-Rong Wang, et al. "Engineering of the interactions of volatile organic compounds with MoS2." Journal of Materials Chemistry C 5, no. 6 (2017): 1463–70. http://dx.doi.org/10.1039/c6tc04673h.

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We investigate the interactions between volatile organic compounds (VOCs, including ethanol, acetone and propanal) and pristine, defective and transition metal-functionalized MoS<sub>2</sub>using the first-principles method.
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27

An, Wei. "The role of synergic interaction in transition state formation for the aldol reaction on a metal oxide catalyst: a DFT investigation." Physical Chemistry Chemical Physics 17, no. 35 (2015): 22529–32. http://dx.doi.org/10.1039/c5cp03478g.

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28

Dostert, Karl-Heinz, Casey P. O'Brien, Francesca Mirabella, Francisco Ivars-Barceló, and Swetlana Schauermann. "Adsorption of acrolein, propanal, and allyl alcohol on Pd(111): a combined infrared reflection–absorption spectroscopy and temperature programmed desorption study." Physical Chemistry Chemical Physics 18, no. 20 (2016): 13960–73. http://dx.doi.org/10.1039/c6cp00877a.

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We present a mechanistic study on adsorption of acrolein and its partial hydrogenation products propanal and allyl alcohol over Pd(111) to understand the factors governing the selectivity in acrolein hydrogenation.
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29

Zhao, Jinbo, Dinghua Yu, Wengui Zhang, et al. "Catalytic dehydration of 2,3-butanediol over P/HZSM-5: effect of catalyst, reaction temperature and reactant configuration on rearrangement products." RSC Advances 6, no. 21 (2016): 16988–95. http://dx.doi.org/10.1039/c5ra23251a.

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As a type of important bio-based vicinal diol, 2,3-butanediol could be transformed into methyl ethyl ketone and 2-methyl propanal through a pinacol rearrangement mechanism under acid catalysis conditions.
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30

Murillo, Luis E., and Jingguang G. Chen. "Adsorption and reaction of propanal, 2-propenol and 1-propanol on Ni/Pt(111) bimetallic surfaces." Surface Science 602, no. 14 (2008): 2412–20. http://dx.doi.org/10.1016/j.susc.2008.05.026.

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31

Zingsheim, Oliver, Holger S. P. Müller, Luis Bonah, Frank Lewen, Sven Thorwirth, and Stephan Schlemmer. "(Sub-)millimeter-wave spectroscopy of gauche-propanal." Journal of Molecular Spectroscopy 384 (February 2022): 111565. http://dx.doi.org/10.1016/j.jms.2021.111565.

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32

Randeil, Jeremy, A. Peter Cox, and H. Dreizier. "Gauche Propanal: Microwave Spectrum and Methyl Barrier." Zeitschrift für Naturforschung A 42, no. 9 (1987): 957–62. http://dx.doi.org/10.1515/zna-1987-0908.

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The barrier hindering internal rotation of the methyl group was determined by analysing ground-state A, E splittings of rotational lines in the 0+ and 0- torsional states of gauche propanal. The value V3 = 886 (10)cm-1 obtained can be compared with that obtained earlier for the cis rotamer.The A rotational constant has also been determined, its value averaged over the two lowest states being 26248.41 (5) MHz.
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33

Tao, Hongli, Lei Shen, Myung Hwa Kim, Arthur G. Suits, and Todd J. Martinez. "Conformationally selective photodissociation dynamics of propanal cation." Journal of Chemical Physics 134, no. 5 (2011): 054313. http://dx.doi.org/10.1063/1.3540659.

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34

Guirgis, Gamil A., B. R. Drew, T. K. Gounev, and J. R. Durig. "Conformational stability and vibrational assignment of propanal." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 54, no. 1 (1998): 123–43. http://dx.doi.org/10.1016/s1386-1425(97)00200-x.

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35

Zingsheim, Oliver, Holger S. P. Müller, Frank Lewen, Jes K. Jørgensen, and Stephan Schlemmer. "Millimeter and submillimeter wave spectroscopy of propanal." Journal of Molecular Spectroscopy 342 (December 2017): 125–31. http://dx.doi.org/10.1016/j.jms.2017.07.008.

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36

Mori, Keitaro, Yasuhiro Yamada, and Satoshi Sato. "Catalytic dehydration of 1,2-propanediol into propanal." Applied Catalysis A: General 366, no. 2 (2009): 304–8. http://dx.doi.org/10.1016/j.apcata.2009.07.018.

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37

Wu, Tao, Dandan Feng, Bing Xie, and Xuebing Ma. "A solution to achieve good reusability of MNPs Fe3O4-supported (S)-diphenylprolinoltrimethylsilyl ether catalysts in asymmetric Michael reactions." RSC Advances 6, no. 30 (2016): 25246–54. http://dx.doi.org/10.1039/c6ra01051b.

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A PVP-modified MNPs Fe<sub>3</sub>O<sub>4</sub>-supported Jøgensen–Hayashi catalyst to achieved good reusability with high yields and unchangeable excellent stereoselectivities in the asymmetric Michael addition of propanal to nitroalkenes.
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38

Caprio, Vittorio, Michael Jones, and Margaret Brimble. "1-(2-Vinyl-pyridin-3-yl)propanal O-methyloxime and 1-(6-Vinyl-pyridin-3-yl)propanal O-methyloxime." Molecules 6, no. 3 (2001): M201. http://dx.doi.org/10.3390/m201.

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39

Randell, Jeremy, A. Peter Cox, Kurt W. ii Hillig, Misako Imachi, Marabeth S. LaBarge, and Robert L. Kuczkowski. "Cis and Gauche Propanal: Microwave Spectra and Molecular Structures." Zeitschrift für Naturforschung A 43, no. 3 (1988): 271–76. http://dx.doi.org/10.1515/zna-1988-0314.

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The microwave spectra of twelve isotopic species of cis propanal (CH3CH2CHO) and six isotopic forms of the less stable gauche rotamer have been studied to determine accurate structural parameters for both conformers. The following bond lengths (Å) and angles (°) were derived:
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40

Varelis, P., and BL Johnson. "Preparation of Optically Active (S)-2-(Benzyloxy)propanal." Australian Journal of Chemistry 48, no. 10 (1995): 1775. http://dx.doi.org/10.1071/ch9951775.

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A convenient and large scale amenable preparation of optically active ethyl (S)-2-( benzyloxy )propionate (5) from ethyl (S)-lactate (4), and the conversion of the ester (5) by two alternative methods into (S)-2-( benzyloxy ) propanal (1) are described.
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41

Myint, MyatNoeZin, Yushan Yan, and Jingguang G. Chen. "Reaction Pathways of Propanal and 1-Propanol on Fe/Ni(111) and Cu/Ni(111) Bimetallic Surfaces." Journal of Physical Chemistry C 118, no. 21 (2014): 11340–49. http://dx.doi.org/10.1021/jp501208q.

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42

Cavender, A. E., T. A. Biesenthal, J. W. Bottenheim, and P. B. Shepson. "Volatile organic compound ratios as probes of halogen atom chemistry in the Arctic." Atmospheric Chemistry and Physics Discussions 7, no. 4 (2007): 11647–83. http://dx.doi.org/10.5194/acpd-7-11647-2007.

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Abstract. Volatile organic compound concentration ratios can be used as indicators of halogen chemistry that occurs during ozone depletion events in the Arctic during spring. Here we use a combination of modeling and measurements of [acetone]/[propanal] as an indicator of bromine chemistry, and [isobutane]/[n-butane] and [methyl ethyl ketone]/[n-butane] are used to study the extent of chlorine chemistry during four ozone depletion events during the Polar Sunrise Experiment of 1995. Using a 0-D photochemistry model in which the input of halogen atoms is controlled and varied, the approximate ra
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43

Cavender, A. E., T. A. Biesenthal, J. W. Bottenheim, and P. B. Shepson. "Volatile organic compound ratios as probes of halogen atom chemistry in the Arctic." Atmospheric Chemistry and Physics 8, no. 6 (2008): 1737–50. http://dx.doi.org/10.5194/acp-8-1737-2008.

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Abstract. Volatile organic compound concentration ratios can be used as indicators of halogen chemistry that occurs during ozone depletion events in the Arctic during spring. Here we use a combination of modeling and measurements of [acetone]/[propanal] as an indicator of bromine chemistry, and [isobutane]/[n-butane] and [methyl ethyl ketone]/[n-butane] are used to study the extent of chlorine chemistry during four ozone depletion events during the Polar Sunrise Experiment of 1995. Using a 0-D photochemistry model in which the input of halogen atoms is controlled and varied, the approximate ra
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Yarnall, Yuki Y., Perry A. Gerakines, and Reggie L. Hudson. "Propanal, an interstellar aldehyde – first infrared band strengths and other properties of the amorphous and crystalline forms." Monthly Notices of the Royal Astronomical Society 494, no. 4 (2020): 4606–15. http://dx.doi.org/10.1093/mnras/staa1028.

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ABSTRACT Chemical evolution in molecular clouds in the interstellar medium is well established, with the identification of over 200 molecules and molecular ions. Among the classes of interstellar organic compounds found are the aldehydes. However, laboratory work on the aldehydes has scarcely kept pace with astronomical discoveries as little quantitative solid-phase infrared (IR) data have been published on any of the aldehydes, and the same is true for important properties such as density, refractive indices, and vapour pressures. In this paper, we examine the IR spectra of solid propanal (HC
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Marchois, J., C. Fressigné, B. Lecachey, and J. Maddaluno. "Base or nucleophile? DFT finally elucidates the origin of the selectivity between the competitive reactions triggered by MeLi or LDA on propanal." Chemical Communications 51, no. 48 (2015): 9801–4. http://dx.doi.org/10.1039/c5cc01549a.

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Why is LDA such a good base while MeLi is mainly a nucleophile? This communication presents a DFT theoretical study comparing side by side the mechanistic pathways followed during the deprotonation and nucleophilic addition of these two reagents, solvated by THF, onto propanal.
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Machek, Jaroslav, Karel Handlíř, Jiří Švachula, and Josef Tichý. "Sorption of Acetic and Propionic Acids and Propanal on a Molybdenum-Vanadium Oxide Catalyst." Collection of Czechoslovak Chemical Communications 57, no. 7 (1992): 1381–84. http://dx.doi.org/10.1135/cccc19921381.

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It has been found by gas chromatography that the equilibrium adsorption of propanal, propionic and acetic acids on molybdenum-vanadium oxide catalyst can be described by the Langmuir adsorption isotherm. The existence of carboxylates on the catalyst surface has been proved by IR spectroscopy.
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Təranə Xalıqova, Adıgözəl Hüseynov, Təranə Xalıqova, Adıgözəl Hüseynov. "MO-P TƏRKİBLİ KATALİZATORLARIN İŞTİRAKI İLƏ METİLAKROLEİNİN OKSİDLƏŞMƏ PROSESİNİN TƏDQİQİ." PAHTEI-Procedings of Azerbaijan High Technical Educational Institutions 31, no. 08 (2023): 226–33. http://dx.doi.org/10.36962/pahtei31082023-226.

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Metakrolinin metakril turşusuna selektiv oksidləşməsini kataliz etmək üçün müxtəlif x qiymətləri olan bir sıra KxH1.1-xCu0.2Cs1(NH4)1.5PVMo11O40 (KxCuCsNH4PVA) katalizatorları sintez edilmişdir. Kalium (K) ionlarının həm struktura, həm də katalitik aktivliyə təsiri ətraflı öyrənilmişdir. Optimal K0.6CuCsNH4PVA Keggin strukturunun ikincil strukturunda geniş səth sahəsi, daha çox turşu sahələri və bol aktiv növlər (V4+/VO2+) nümayiş etdirdi və nəticədə yaxşı katalitik performans təklif etdi. Bundan əlavə, K ionları karbon monoksit və karbon dioksid (birlikdə COX kimi müəyyən edilir) hesabına MAA
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Barluenga, José, Covadonga Rubiera, José R. Fernández, and Miguel Yus. "3,3-Diethoxypropyl-lithium: a masked lithium propanal homoenolate." J. Chem. Soc., Chem. Commun., no. 6 (1987): 425–26. http://dx.doi.org/10.1039/c39870000425.

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Coto, Baudilio, Concepción Pando, Ramón G. Rubio, and Juan A. R. Renuncio. "Vapour-liquid equilibrium of the ethanol–propanal system." J. Chem. Soc., Faraday Trans. 91, no. 2 (1995): 273–78. http://dx.doi.org/10.1039/ft9959100273.

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Green, Malcolm L. H., Shik Chi Tsang, Patrick D. F. Vernon, and Andrew P. E. York. "Conversion of methane to propanal at ambient pressure." Industrial & Engineering Chemistry Research 32, no. 6 (1993): 1030–34. http://dx.doi.org/10.1021/ie00018a006.

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