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1

Yilmaz, S., R. Gerhard-Multhaupt, W. A. Bonner, D. M. Hwang, A. Inam, J. A. Martinez, T. S. Ravi, et al. "Electro-optic potassium-tantalate-niobate films prepared by pulsed laser deposition from segmented pellets." Journal of Materials Research 9, no. 5 (May 1994): 1272–79. http://dx.doi.org/10.1557/jmr.1994.1272.

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Thin films of potassium tantalate niobate (KTN) were prepared by means of pulsed excimer-laser deposition and investigated with a number of analytical techniques, including electrical and electro-optical measurements. For applications in longitudinal electro-optic modulators, a transparent electrode is required between substrate and electro-optic layers. Suitable electrode materials, which at the same time permit epitaxial growth of KTN, were identified and prepared. The resulting layered samples were not only of good epitaxial and optical quality, but also exhibited the expected maximum of the longitudinal electro-optic effect at temperatures between the phase transitions from cubic to tetragonal and from tetragonal to orthorhombic. However, the maximum achievable electro-optic phase shift was found to be limited to roughly τ/100 for KTN films in the thickness range around 1 μm. Therefore, much thicker films are probably necessary for most practical applications, which requires significant improvements in the long-term stability and homogeneity of the deposition process.
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2

Wang, Yan, Wen Ge, Qian Yang, and Wen Cheng. "Corrosion Resistance of Reverse Pulsed Electrodeposition Nano-Nickel Coating." Applied Mechanics and Materials 105-107 (September 2011): 1666–70. http://dx.doi.org/10.4028/www.scientific.net/amm.105-107.1666.

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With the purpose of decorative bright nickel plating process, nano-nickel and ordinary bright nickel coatings were prepared by applying the electro-deposition method with DC and PRC respectively. The grain sizes, organizational structures and surface morphologies of samples were characterizated by X-ray diffraction(XRD) and scanning electron microscopy (SEM) analysis. The corrosion resistance of the samples were determined by immersion corrosion test, salt spray corrosion test and electrochemical methods. The results showed that the corrosion resistance of reverse pulsed electrodeposition nano-nickel coating is superior to the DC electrodeposition nickel coating.
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3

Schubert, J., M. Siegert, M. Fardmanesh, W. Zander, M. Prömpers, Ch Buchal, Judit Lisoni, and C. H. Lei. "Superconducting and electro-optical thin films prepared by pulsed laser deposition technique." Applied Surface Science 168, no. 1-4 (December 2000): 208–14. http://dx.doi.org/10.1016/s0169-4332(00)00599-7.

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4

Yılmaz, M. S., E. Atar, O. Şahin, and E. S. Kayalı. "Improving the Surface Properties of Cp-Ti by Pulsed Electro-Spark Deposition." Acta Physica Polonica A 125, no. 2 (January 2014): 593–96. http://dx.doi.org/10.12693/aphyspola.125.593.

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5

Schubert, M., N. Ashkenov, T. Hofmann, M. Lorenz, H. Hochmuth, H. v. Wenckstern, M. Grundmann, and G. Wagner. "Electro-optical properties of ZnO-BaTiO3-ZnO heterostructures grown by pulsed laser deposition." Annalen der Physik 13, no. 12 (January 29, 2004): 61–62. http://dx.doi.org/10.1002/andp.200310047.

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6

Tian, H. Y., D. Y. Wang, X. Y. Zhou, Y. Wang, H. L. W. Chan, and C. L. Choy. "Large quasi-linear electro-optical response of BaZr0.75Hf0.25O3thin films by pulsed laser deposition." physica status solidi (a) 202, no. 6 (May 2005): R63—R65. http://dx.doi.org/10.1002/pssa.200510017.

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7

Gupta, Surbhi, Ayushi Paliwal, Vinay Gupta, and Monika Tomar. "Dynamically tuneable PLD grown SBN75 thin film based Electro optic modulator." MRS Advances 4, no. 41-42 (2019): 2265–69. http://dx.doi.org/10.1557/adv.2019.271.

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Abstract:Present work reports the growth of Strontium Barium Niobate (Sr0.75 Ba0.25 Nb2 O6, SBN 75)thin films using Pulsed laser deposition (PLD) technique for possible realization of electrically tunable modulators. Structural and optical properties of grown SBN75 thin film were investigated indicating the growth of high quality polycrystalline and optically transparent. Prism coupling technique was further utilized for coupling the incident laser light λ = 633 nm with the grown SBN75 thin film. The guided EM radiation could be further coupled with the electric field for the realization of EO modulator.
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8

Kilburger, S., R. Chety, E. Millon, Ph Di Bin, C. Di Bin, A. Boulle, and R. Guinebretière. "Growth of LiNbO3 thin films on sapphire by pulsed-laser deposition for electro-optic modulators." Applied Surface Science 253, no. 19 (July 2007): 8263–67. http://dx.doi.org/10.1016/j.apsusc.2007.02.112.

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9

Venkatesh, C., N. Sundara Moorthy, R. Venkatesan, and V. Aswinprasad. "Optimization of Process Parameters of Pulsed Electro Deposition Technique for Nanocrystalline Nickel Coating Using Gray Relational Analysis (GRA)." International Journal of Nanoscience 17, no. 01n02 (October 12, 2017): 1760007. http://dx.doi.org/10.1142/s0219581x17600079.

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The moving parts of any mechanism and machine parts are always subjected to a significant wear due to the development of friction. It is an utmost important aspect to address the wear problems in present environment. But the complexity goes on increasing to replace the worn out parts if they are very precise. Technology advancement in surface engineering ensures the minimum surface wear with the introduction of polycrystalline nano nickel coating. The enhanced tribological property of the nano nickel coating was achieved by the development of grain size and hardness of the surface. In this study, it has been decided to focus on the optimized parameters of the pulsed electro deposition to develop such a coating. Taguchi’s method coupled gray relational analysis was employed by considering the pulse frequency, average current density and duty cycle as the chief process parameters. The grain size and hardness were considered as responses. Totally, nine experiments were conducted as per L9 design of experiment. Additionally, response graph method has been applied to determine the most significant parameter to influence both the responses. In order to improve the degree of validation, confirmation test and predicted gray grade were carried out with the optimized parameters. It has been observed that there was significant improvement in gray grade for the optimal parameters.
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10

Todoran, Daniela, Radu Todoran, Zsolt Szakács, and Eugen Anitas. "Electrical Conductivity and Optical Properties of Pulsed Laser Deposited LaNi5 Nanoscale Films." Materials 11, no. 8 (August 19, 2018): 1475. http://dx.doi.org/10.3390/ma11081475.

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This work presents pulsed laser deposition as a method to obtain unoxidized LaNi5 nanoscale films and describes their temperature and thickness dependent electrical conductivity and the spectral dispersions of some optical properties. AB5-type rare earth element (REE)-nickel compounds are currently studied from both theoretical and practical points of view. Special challenges are posed during the preparation of these nanomaterials, which can be overcome using finely tuned parameters in a preparation process that always involves the use of high energies. Film deposition was made by laser—induced vaporization, with short and modulated impulses and electro–optical tuning of the quality factor, mainly on glass and one SiO2 substrate. Deposition geometry dependent linear thickness increase, between 1.5–2.5 nm per laser burst, was achieved. Film structures and phase compositions were determined using XRD and discussed in comparison with films obtained by similar deposition procedures. Temperature and scale dependent properties were determined by studying electrical conductivity and optical properties. Electrical conductivity was measured using the four-probe method. The observed semiconductor-like conductivity for film thicknesses up to 110 nm can be explained by thermal activation of electrons followed by inter-insular hopping or quantum tunneling, which, on the other hand, modulates the material’s native metallic conductance. Films with thicknesses above this value can be considered essentially metallic and bulk-like. The spectral behaviors of the refractive index and absorption coefficient were deduced from differential reflectance spectroscopy data acquired on a broad ultraviolet, visible, near- and mid-infrared (UV-VIS-NIR-MIR) domain, processed using the Kramers-Krönig formalism. Their study led to the identification of the allowed interband transitions. Electronic behavior in the energy bands near the Fermi level and in the surface and interface-states was described, discussing the differences between experimental data and the classical free-electron theoretical model applied for the bulk intermetallic alloy, in correlation with theoretical optical properties or experimental X-ray photoelectron spectroscopy (XPS) results from references. However, the dielectric-like shape of the reflectance of the thinnest film was in accordance with the Lorentz–Drude model.
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11

Li, Wencan, Jiao Cui, Dahuai Zheng, Weiwei Wang, Shuolin Wang, Shaoqing Song, Hongde Liu, Yongfa Kong, and Jingjun Xu. "Fabrication and Characteristics of Heavily Fe-Doped LiNbO3/Si Heterojunction." Materials 12, no. 17 (August 21, 2019): 2659. http://dx.doi.org/10.3390/ma12172659.

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A series of heavily Fe-doped LiNbO3 (LN:Fe) crystals were grown via the Czochralski method. The dark- and photo-conductivity of the 5.0 wt.% Fe-doped LiNbO3 crystal reached 3.30 × 10−8 Ω−1 cm−1 and 1.46 × 10−7 Ω−1 cm−1 at 473 nm, which are about 7 and 5 orders of magnitude higher than that of congruent LiNbO3, respectively. Then, a p-n heterojunction was fabricated by depositing the heavily Fe-doped LiNbO3 on a p-type Si substrate using the pulsed laser deposition. The current–voltage curve of the LN:Fe/Si heterojunction presents a well-defined behavior with a turn-on voltage of 2.9 V. This LN:Fe/Si heterojunction gives an excellent prototype device for integrated optics and electro-photonics.
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12

Tayebati, Parviz, Dhrupad Trivedi, and Martin Tabat. "Pulsed laser deposition of SBN:75 thin films with electro‐optic coefficient of 844 pm/V." Applied Physics Letters 69, no. 8 (August 19, 1996): 1023–25. http://dx.doi.org/10.1063/1.116919.

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13

Kiryukhantsev-Korneev, Philipp, Alina Sytchenko, Alexander Sheveyko, Dmitry Moskovskikh, and Stepan Vorotylo. "Two-Layer Nanocomposite TiC-Based Coatings Produced by a Combination of Pulsed Cathodic Arc Evaporation and Vacuum Electro-Spark Alloying." Materials 13, no. 3 (January 23, 2020): 547. http://dx.doi.org/10.3390/ma13030547.

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A novel two-stage technology combining vacuum electro-spark alloying (VESA) and pulsed cathodic arc evaporation (PCAE) was approbated for the deposition of TiC-based coatings in inert (Ar) and reactive (C2H4) atmospheres. The deposition was carried out using a TiC-NiCr-Eu2O3 electrode and 5140 steel substrates. Structural, elemental, and phase compositions of the deposited coatings were investigated by scanning electron microscopy, energy-dispersive spectrometry, and X-ray diffraction. The mechanical properties of the coatings were measured by nanoindentation using a 4 mN load. The tribological properties of the coatings were measured using the pin-on-disc setup in air and in distilled water at a 5 N load. The experimental data suggest that VESA coatings are characterized by surface defects, a hardness of 12.2 GPa, and a friction coefficient of 0.4. To ensure good adhesion between the VESA coating and the upper layer containing diamond-like carbon (DLC), an intermediate layer was deposited by PCAE in the Ar atmosphere. The intermediate layer had a hardness of up to 31 GPa. The upper layer of the coating ensured a low and stable friction coefficient of 0.2 and high wear resistance due to the formation of an sp2–sp3 bound carbon phase. Multilayer TiC-based coating with the upper DLC layer, in addition to high tribological properties, was characterized by the lowest corrosion current density (12 μA/cm2).
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14

ZHOU, Xiaowei, Yifu SHEN, and Dongdong GU. "MICROSTRUCTURE AND HIGH TEMPERATURE OXIDATION RESISTANCE OF NANOCRYSTALLINE Ni-CeO2COMPOSITE COATINGS DEPOSITED BY DOUBLE-PULSED ELECTRO DEPOSITION." Acta Metallurgica Sinica 48, no. 8 (2012): 957. http://dx.doi.org/10.3724/sp.j.1037.2012.00298.

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15

Scarisoreanu, N. D., F. Craciun, A. Andrei, V. Ion, R. Birjega, A. Moldovan, M. Dinescu, and C. Galassi. "Electro-optic and dielectric properties of epitaxial Pb1−3x/2LaxZr0.2Ti0.8O3 thin films obtained by pulsed laser deposition." Thin Solid Films 541 (August 2013): 127–30. http://dx.doi.org/10.1016/j.tsf.2012.11.119.

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16

Wang, D. Y., J. Wang, H. L. W. Chan, and C. L. Choy. "Structural and electro-optic properties of Ba0.7Sr0.3TiO3 thin films grown on various substrates using pulsed laser deposition." Journal of Applied Physics 101, no. 4 (February 15, 2007): 043515. http://dx.doi.org/10.1063/1.2646014.

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17

Liu, Yanwei, Zhenghao Chen, Chunling Li, Dafu Cui, Yueliang Zhou, Guozhen Yang, and Yong Zhu. "Electrical and electro-optical properties of Ce-doped barium titanate thin films prepared by pulsed laser deposition." Journal of Applied Physics 81, no. 9 (May 1997): 6328–31. http://dx.doi.org/10.1063/1.364367.

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18

Daryakenari, Ahmad Ahmadi, Davood Hosseini, Mohammad Hassan Mirfasih, Aleksandra Apostoluk, Christoph R. Müller, and Jean-Jacques Delaunay. "Formation of NiO nanoparticle-attached nanographitic flake layers deposited by pulsed electrophoretic deposition for ethanol electro-oxidation." Journal of Alloys and Compounds 698 (March 2017): 571–76. http://dx.doi.org/10.1016/j.jallcom.2016.12.136.

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19

Iriarte, G. F., F. Engelmark, and I. V. Katardjiev. "Reactive Sputter Deposition of Highly Oriented AlN Films at Room Temperature." Journal of Materials Research 17, no. 6 (June 2002): 1469–75. http://dx.doi.org/10.1557/jmr.2002.0218.

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Textured as well as epitaxial thin AlN films are of great interest for a wide range of electro-acoustic and optoelectronic applications. Reduction of the deposition temperature is of vital importance in a number of applications due to thermal budget limitations. In this work we systematically studied the influence of the process parameters on the film properties and identified the factors leading to improved film quality as well as reduced deposition temperature with pulsed direct current sputtering in an Ar/N2 atmosphere. We demonstrated that fully textured (0002) films can be grown under a wide range of conditions. At the same time the full width at half-maximum (FWHM) of the rocking curve of the (0002) XRD peak was found to vary systematically with process conditions—depostion rate, process pressure, gas composition, and substrate temperature. The best films showed a FWHM of 1.2°. We found that by far the most important factor is the arrival energy of the sputtered Al atoms, which is primarily controlled by the process pressure. We report for the first time that fully textured AlN films with a FWHM of under 2° can be grown at room temperature. Other important factors are the ion and electron bombardment of the films and substrate temperature as well as gas composition, although their influence is not as dramatic. Generally, the film quality increases with temperature. Bias and electron bombardment within a certain range also lead to better films.
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20

Adurodija, F. O., H. Izumi, T. Ishihara, H. Yoshioka, and M. Motoyama. "The electro-optical properties of amorphous indium tin oxide films prepared at room temperature by pulsed laser deposition." Solar Energy Materials and Solar Cells 71, no. 1 (January 2002): 1–8. http://dx.doi.org/10.1016/s0927-0248(01)00037-x.

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21

Mbenkum, B. N., N. Ashkenov, M. Schubert, M. Lorenz, H. Hochmuth, D. Michel, M. Grundmann, and G. Wagner. "Temperature-dependent dielectric and electro-optic properties of a ZnO-BaTiO3-ZnO heterostructure grown by pulsed-laser deposition." Applied Physics Letters 86, no. 9 (February 28, 2005): 091904. http://dx.doi.org/10.1063/1.1862778.

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22

Karthikeyan, Sreejith, Kushagra Nagaich, Arthur E. Hill, Richard D. Pilkington, and Stephen A. Campbell. "A low temperature, single step, pulsed d.c magnetron sputtering technique for copper indium gallium diselenide photovoltaic absorber layers." MRS Proceedings 1538 (2013): 45–50. http://dx.doi.org/10.1557/opl.2013.1008.

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ABSTRACTPulsed d.c Magnetron Sputtering (PdcMS) has been investigated for the first time to study the deposition of copper indium gallium diselenide (CIGS) thin films for photovoltaic applications. Pulsing the d.c. in the mid frequency region enhances the ion intensity and enables long term arc-free operation for the deposition of high resistivity materials such as CIGS. It has the potential to produce films with good crystallinity, even at low substrate temperatures. However, the technique has not generally been applied to the absorber layers for photovoltaic applications. The growth of stoichiometric p-type CIGS with the desired electro-optical properties has always been a challenge, particularly over large areas, and has involved multiple steps often including a dangerous selenization process to compensate for selenium vacancies. The films deposited by PdcMS had a nearly ideal composition (Cu0.75In0.88Ga0.12Se2) as deposited at substrate temperatures ranging from no intentional heating to 400 °C. The films were found to be very dense and pin-hole free. The stoichiometry was independent of heating during the deposition, but the grain size increased with substrate temperature, reaching about ∼ 150 nm at 400 °C. Hot probe analysis showed that the layers were p-type. The physical, structural and optical properties of these films were analyzed using SEM, EDX, XRD, and UV-VIS-NIR spectroscopy. The material characteristics suggest that these films can be used for solar cell applications. This novel ion enhanced single step low temperature deposition technique may have a critical role in flexible and tandem solar cell applications compared to other conventional techniques which require higher temperatures.
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23

Doğan, Fatih, Mehmet Uysal, Hasan Algül, Erhan Duru, Hatem Akbulut, and Serdar Aslan. "Optimization of pulsed electro co-deposition for Ni-B-TiN composites and the variation of tribological and corrosion behaviors." Surface and Coatings Technology 400 (October 2020): 126209. http://dx.doi.org/10.1016/j.surfcoat.2020.126209.

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24

Chen, Lu Sheng, Yan Yan Liu, Yan Ping Ban, and Huai Xiang Li. "Porous Silicon Modification with ZnO Films Electro-Deposited from Zinc Nitrate Aqueous Solution by Pulsed Current of Rectangular Wave." Advanced Materials Research 239-242 (May 2011): 150–55. http://dx.doi.org/10.4028/www.scientific.net/amr.239-242.150.

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The pulsed current of rectangular wave was used to electrolyzing zinc nitrate aqueous solution for the purpose of preparation of a transparent zinc oxide (ZnO) film by cathodic deposition. The current density of rectangular wave was 0.2 and 1.0 mA/cm2, respectively. The former plays a role to deposit homogenous ZnO particles on the substrate surface and the latter plays the role to promote further growth of the particles and film formation. The structural and optical characterizations of the deposited films were performed with x-ray diffraction, scanning electron microscope, and measurements of optical absorption in UV-vis range. Similar technique has been used to modify as prepared porous silicon, resulting a green photoluminescence after 1 h annealing at 1273 K under oxygen atomsphere.
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25

Zhang, Jing, Xiu Hua Fu, Li Jun Guo, Jian Hong Zhou, Dong Mei Liu, and Deg Gui Sun. "Design and Fabrication of BaTiO3 Crystal Thin-Film Waveguides." Key Engineering Materials 609-610 (April 2014): 201–7. http://dx.doi.org/10.4028/www.scientific.net/kem.609-610.201.

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BaTiO3 crystal film has the very high electro-optic effect, so it has important research value for thin film waveguide electro-optic modulators. In this work, BPM software is used to simulate the single-mode condition of ridge waveguide at first, then BaTiO3 film waveguide structure is designed with suitable film thickness.BaTiO3 waveguide thin films are grown by pulsed laser deposition on single crystal MgO substrate. The BaTiO3 thin-film crystalline structures grown at different temperature sand different laser powers were analyzed by using X ray diffraction , which showed the BaTiO3 films have a priority crystallization direction and good crystallization quality at 750°C grown temperature. For the optimally-designed waveguide structures, the PECVD technique and ICP plasma etching method are employed to coat and etch Si3N4 films, respectively. Through the optimization of main process parameters, 60 sccm reaction gas flow and 150 nm/min etching speed are finally selected to create the ridge waveguides, and consequently, the surface roughness of Si3N4 film waveguide reaches 2.3 nm.
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26

Ma, Youcao, Jian Song, Xubo Wang, Yue Liu, and Jia Zhou. "Synthesis, Microstructure and Properties of Magnetron Sputtered Lead Zirconate Titanate (PZT) Thin Film Coatings." Coatings 11, no. 8 (August 7, 2021): 944. http://dx.doi.org/10.3390/coatings11080944.

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Compared to aluminum nitride (AlN) with simple stoichiometry, lead zirconate titanate thin films (PZT) are the other promising candidate in advanced micro-electro-mechanical system (MEMS) devices due to their excellent piezoelectric and dielectric properties. The fabrication of PZT thin films with a large area is challenging but in urgent demand. Therefore, it is necessary to establish the relationships between synthesis parameters and specific properties. Compared to sol-gel and pulsed laser deposition techniques, this review highlights a magnetron sputtering technique owing to its high feasibility and controllability. In this review, we survey the microstructural characteristics of PZT thin films, as well as synthesis parameters (such as substrate, deposition temperature, gas atmosphere, and annealing temperature, etc.) and functional proper-ties (such as dielectric, piezoelectric, and ferroelectric, etc). The dependence of these influential factors is particularly emphasized in this review, which could provide experimental guidance for researchers to acquire PZT thin films with expected properties by a magnetron sputtering technique.
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27

Li, A.-D., C. L. Mak, K. H. Wong, D. Wu, and Naiben Ming. "Novel route for the epitaxial growth of (SrBa)Nb2O6 thick films by the sol-gel method using a self-template layer." Journal of Materials Research 16, no. 11 (November 2001): 3179–83. http://dx.doi.org/10.1557/jmr.2001.0438.

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A novel sol-gel processing method has been developed to fabricate epitaxial (SrBa)Nb2O6 (SBN) thin films on MgO substrates. It involves the introduction of a SBN self-template layer on MgO by pulsed laser deposition (PLD). Effects of the SBN self-template layer on the structural and morphological properties of the sol-gel-derived SBN films were investigated. Compared to the sol-gel-derived SBN films without a self-template layer, our new technique produces SBN films of excellent epitaxy and more dense grains with uniform distribution. This can be explained by the self-template-layer-induced homoepitaxial growth. The innovative processing method with combination of PLD and sol-gel is a promising technique in preparing high-quality, thick epitaxial SBN films for electro-optics device applications.
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28

Kuptsov, K. A., A. N. Sheveyko, E. I. Zamulaeva, D. A. Sidorenko, and D. V. Shtansky. "Two-layer nanocomposite WC/a-C coatings produced by a combination of pulsed arc evaporation and electro-spark deposition in vacuum." Materials & Design 167 (April 2019): 107645. http://dx.doi.org/10.1016/j.matdes.2019.107645.

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29

Krishnan, Rajagopalan, and Jagannathan Thirumalai. "Synthesis and up/down conversion luminescence properties of Na0.5R0.5MoO4:Ln3+ (R3+ = La, Gd), (Ln3+ = Eu, Tb, Dy, Yb/Er) thin phosphor films grown by pulsed laser deposition technique." RSC Adv. 4, no. 109 (2014): 64258–66. http://dx.doi.org/10.1039/c4ra11274a.

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30

Chakraborty, Rajib, Monalisa Mandal, and Partha Saha. "Electrochemical stability and bio-mineralization capability of zinc substituted and elemental zinc reinforced calcium phosphate composite coatings synthesized through pulsed electro-deposition." Ceramics International 45, no. 17 (December 2019): 22899–911. http://dx.doi.org/10.1016/j.ceramint.2019.07.333.

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31

Jankowski, Alan F. "Diffusion Mechanisms in Nanocrystalline and Nanolaminated Au-Cu." Defect and Diffusion Forum 266 (September 2007): 13–28. http://dx.doi.org/10.4028/www.scientific.net/ddf.266.13.

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Thermal anneal treatments are used to identify the temperature range of the two dominant diffusion mechanisms – bulk and grain boundary. To assess the transition between mechanisms, the low temperature range for bulk diffusion is established utilizing the decay of static concentration waves in composition-modulated nanolaminates. These multilayered structures are synthesized using vapor deposition methods as thermal evaporation and magnetron sputtering. However, at low temperature the kinetics of grain-boundary diffusion are much faster than bulk diffusion. The synthesis of Au-Cu alloys (0-20 wt.% Cu) with grain sizes as small as 5 nm is accomplished using pulsed electro-deposition. Since the nanocrystalline grain structure is thermally unstable, these structures are ideal for measuring the kinetics of grain boundary diffusion as measured by coarsening of grain size with low temperature anneal treatments. A transition in the dominant mechanism for grain growth from grain boundary to bulk diffusion is found with an increase in temperature. The activation energy for bulk diffusion is found to be 1.8 eV·atom-1 whereas that for grain growth at low temperatures is only 0.2 eV·atom-1. The temperature for transitioning from the dominant mechanism of grain boundary to bulk diffusion is found to be 57% of the alloy melt temperature and is dependent on composition.
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32

Chakraborty, Rajib, Jhimli Sarkar Manna, and Partha Saha. "Development and relative comparison of polypyrrole-calcium phosphate composite coatings with differential concentration of chlorophyll functionalized polymer particle achieved through pulsed electro deposition." Surface and Coatings Technology 363 (April 2019): 221–35. http://dx.doi.org/10.1016/j.surfcoat.2019.02.025.

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33

González-Quijano, D., W. J. Pech-Rodríguez, L. E. Verduzco, J. I. Escalante-García, G. Vargas-Gutiérrez, and F. J. Rodríguez-Varela. "Application of the Electrophoretic Deposition Technique for the Development of Electrodes Containing a Catalyst Layer of Nanostructured Pt-Sn/C for DAFCs." MRS Advances 5, no. 57-58 (2020): 2991–3002. http://dx.doi.org/10.1557/adv.2020.379.

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AbstractA catalyst layer of Pt-Sn/C (Pt:Sn 1:1 atomic ratio) was deposited on commercial carbon cloth electrodes by electrophoretic deposition (EPD). The Pt-Sn/C nanocatalyst was synthesized by the polyol method. Three current signals were applied: i) continuous direct current (CDC); ii) positive pulsed current (PPC); and iii) asymmetric alternating current (AAC). The chemical composition analysis showed the effect of the applied signal on species transferred onto the carbon cloth to form the catalyst layers. Evaluation by SEM confirmed the effect of deposition-signal on the morphology of the catalyst layer. The CDC signal formed spherical agglomerates with irregular distribution along with carbon fibers over the electrode, showing some cracks. A cross-cut view of the electrode showed that the catalyst penetrated the carbon cloth. Meanwhile, the PPC signal promoted a better deposition of the catalyst layer over the carbon cloth surface, with a thicker and more homogeneous rough layer than CDC. In contrast, the layer developed by the AAC signal showed a morphology similar to that by CDC, suggesting the formation of a layer with low metal loading. The cross-cut view of the AAC electrode showed the formation of a highly rough layer having large areas with limited contact with the carbon cloth fibers. The electro-catalytic activity of the electrodes for the Ethanol Oxidation Reaction (EOR) was studied in acid media. The CDC electrode showed an enhanced performance for the EOR by delivering the highest current density (272 mA mg-1Pt) with the more negative onset potential (341 mV) relative to the PPC and AAC electrodes.
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34

Kumar, Mohan E., P. Sathyabalan, P. Thamilarasi, and Saravana P. Kumar. "An Investigation on the Mechanical Properties of Ni-Nano-Mg Composite Coatings on ASTM A284 Grade-A by Pulsed Electro-Deposition using Taguchi Method." Asian Journal of Research in Social Sciences and Humanities 6, no. 6special (2016): 21. http://dx.doi.org/10.5958/2249-7315.2016.00376.2.

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35

Darwish, Abdalla M., Shaelynn Moore, Aziz Mohammad, Deonte' Alexander, Tyler Bastian, Wydglif Dorlus, Sergey Sarkisov, et al. "Polymer nano-composite films with inorganic upconversion phosphor and electro-optic additives made by concurrent triple-beam matrix assisted and direct pulsed laser deposition." Composites Part B: Engineering 109 (January 2017): 82–90. http://dx.doi.org/10.1016/j.compositesb.2016.10.053.

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36

Zong, Haohua, Matteo Chiatto, Marios Kotsonis, and Luigi de Luca. "Plasma Synthetic Jet Actuators for Active Flow Control." Actuators 7, no. 4 (November 1, 2018): 77. http://dx.doi.org/10.3390/act7040077.

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The plasma synthetic jet actuator (PSJA), also named as sparkjet actuator, is a special type of zero-net mass flux actuator, driven thermodynamically by pulsed arc/spark discharge. Compared to widely investigated mechanical synthetic jet actuators driven by vibrating diaphragms or oscillating pistons, PSJAs exhibit the unique capability of producing high-velocity (>300 m/s) pulsed jets at high frequency (>5 kHz), thus tailored for high-Reynolds-number high-speed flow control in aerospace engineering. This paper reviews the development of PSJA in the last 15 years, covering the major achievements in the actuator working physics (i.e., characterization in quiescent air) as well as flow control applications (i.e., interaction with external crossflow). Based on the extensive non-dimensional laws obtained in characterization studies, it becomes feasible to design an actuator under several performance constraints, based on first-principles. The peak jet velocity produced by this type of actuator scales approximately with the cubic root of the non-dimensional energy deposition, and the scaling factor is determined by the electro-mechanical efficiency of the actuator (O(0.1%–1%)). To boost the electro-mechanical efficiency, the energy losses in the gas heating phase and thermodynamic cycle process should be minimized by careful design of the discharge circuitry as well as the actuator geometry. Moreover, the limit working frequency of the actuator is set by the Helmholtz natural resonance frequency of the actuator cavity, which can be tuned by the cavity volume, exit orifice area and exit nozzle length. In contrast to the fruitful characterization studies, the application studies of PSJAs have progressed relatively slower, not only due to the inherent difficulties of performing advanced numerical simulations/measurements in high-Reynolds-number high-speed flow, but also related to the complexity of designing a reliable discharge circuit that can feed multiple actuators at high repetition rate. Notwithstanding these limitations, results from existing investigations are already sufficient to demonstrate the authority of plasma synthetic jets in shock wave boundary layer interaction control, jet noise mitigation and airfoil trailing-edge flow separation.
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37

Polischuk, S. D., Yu A. Stekolnikov, D. G. Churilov, N. V. Byshov, S. N. Borychev, N. Yu Stekolnikova, and V. K. Astanin. "Corrective Maintenance and Hardening of Agricultural Machinery Parts." Key Engineering Materials 836 (March 2020): 158–67. http://dx.doi.org/10.4028/www.scientific.net/kem.836.158.

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The article presents information on the technological characteristics and industrial use of chroming electrolytes. The modern electrochemical technologies of repairing worn-out parts of agricultural machinery are considered. Particular attention is paid to the use of chrome plating methods making possible to increase the durability and reliability of the parts recovered in electrolytes of different composition, allowing to obtain coatings with high physical-mechanical properties that determine their suitability for the operation in the process of use for their intended purpose. The use of self-regulating dilute chroming electrolytes makes possible to increase the productivity of the deposition process of chromium coatings significantly, to obtain high-quality coatings of chromium and iron, and high adhesion to the base material - carbon, alloyed steels, and cast iron. The deposition of metals using reverse, pulsed currents with adjustable anodic-cathodic ratio of amplitude values and its duration allows to influence electro crystallization, control the structure, texture and roughness of the formed precipitate, which makes possible to get with predetermined functional physical and mechanical properties for specific repair conditions and subsequent operation in agricultural machinery. The following modes are recommended for brilliant coatings: when reverse current τ (cat) / τ (an) = 50-70, τ (cat) = 4-7 min, D(cat) = 40-100 А / dm2, D(cat) / D(an) = 3-4, Т = 60-65 ° С; when impulse current D(cat) = 40-100 А / dm2, Т = 60-65 ° С, τ (imp) = 1.5-2.5 min, τ (pauses) = 5-10 sec., impulse ratio 1.07-1.15.
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38

Cieniek, Łukasz. "Effect of the Electron Energy on the Structural Evolution of Functional Perovskite La0.6Ca0.4CoO3 Thin Films Produced by the Pulsed Electron Deposition (PED) Technique." Solid State Phenomena 231 (June 2015): 25–32. http://dx.doi.org/10.4028/www.scientific.net/ssp.231.25.

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Functional nonstoichiometric La0.6Ca0.4CoO3perovskite thin films were deposited on theepi-polished [001] MgO substrates by the electron ablation process (PED - pulsed electron deposition) in low oxygene pressure conditions (~7 x 10-3Torr). Deposition process was performed for about 4 hours with the repetition rate of 5 Hz that gave about 72 000 pulses for each sample. By adjusting both the target-substrate distance in the working chamber (70 - 80 mm) as well as the electron energy (10 - 14 kV) it is possible to affect the microstructure and quality of obtained thin films. This paperrelates to the influence of the single pulse electron energy (discharge) on the structure of La0.6Ca0.4CoO3thin films investigated by means of scanning electron microscopy, transmission electron microscopy and atomic force microscopy. The chemical compositions were also examined using energy dispersive spectroscopy. Multiple linear scratch tests allowed to determine the thin films adhesion to the substrates.
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39

Fan, Hui. "Improvement of Deposition Uniformity in Laminated Templates Electro-Deposition." Key Engineering Materials 426-427 (January 2010): 5–8. http://dx.doi.org/10.4028/www.scientific.net/kem.426-427.5.

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Laminated templates electro-deposition (LTE) is a small-sized metallic-structure fabrication technique based on template-patterned depositing. Avoiding locally excessive electroplating at the template edge area has been proved crucial to this method. To improve deposition uniformity, auxiliary cathode and modulated double-pulse current were tried individually and assessed on their effects and efficiencies. By applying assisting cathode the deposition uniformity in plannar pattern depositing was significantly improved with an increased thickness ratio of edge to center for the plating sample. Pulse application, especially double-pulse was studied mainly on the proportion between anodic duty circle and cathodic duty circle. Through a group of optimized parameters, including current density ranging 8-10A/dm2, anodic and cathodic duty circle of respectively 80% and 30%, frequency 300HZ, a bulk of copper parts, section size 20×20mm and 4-7mm thick were produced with a well depositing quality.
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40

Qin, Ying, Wei Qu, Xian Xiu Mei, Sheng Zhi Hao, Ji Jun Zhao, Wen Lu, and Chuang Dong. "Numerical Simulation for Surface Modification of Thermal Barrier Coatings by High-Current Pulse Electron Beam." Materials Science Forum 654-656 (June 2010): 1807–10. http://dx.doi.org/10.4028/www.scientific.net/msf.654-656.1807.

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High current pulsed electron beam is an effective technique for surface sealing of ceramic thermal barrier coatings prepared by electron beam physical vapor deposition. Due to the rapid remelting and solidification, the outer layers of ceramic coatings become smooth and dense, and the protective performance for turbine blades is effectively improved. Because of the complex multi-layered structures in the coatings, a high-current pulsed electron beam treatment requires specific parameter inputs which are related to the temperature field induced by electron energy deposition in the coatings. In this paper, a two-dimensional temperature simulation was performed to demonstrate the melting depth and temperature evolution in ceramic coatings treated by high-current pulsed electron beam. Different energy densities and pulses were studied and discussed for obtaining optimized parameters.
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41

Chakraborty, Rajib, V. S. Seesala, Srijan Sengupta, Santanu Dhara, Partha Saha, Karabi Das, and Siddhartha Das. "Comparison of Osteoconduction, cytocompatibility and corrosion protection performance of hydroxyapatite-calcium hydrogen phosphate composite coating synthesized in-situ through pulsed electro-deposition with varying amount of phase and crystallinity." Surfaces and Interfaces 10 (March 2018): 1–10. http://dx.doi.org/10.1016/j.surfin.2017.11.002.

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42

Niemczyk, Moszyński, Jędrzejewski, Kwiatkowski, Piwowarczyk, and Baranowska. "Chemical Structure of EVA Films Obtained by Pulsed Electron Beam and Pulse Laser Ablation." Polymers 11, no. 9 (August 29, 2019): 1419. http://dx.doi.org/10.3390/polym11091419.

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Poly(ethylene-co-vinyl acetate) (EVA) films were deposited for the first time using physical methods. The chemical structure of the films obtained using two techniques, pulsed electron beam deposition (PED) and pulsed laser deposition (PLD), was studied by attenuated total reflection Fourier infrared spectroscopy (ATR-FTIR) and X-ray photoelectron spectroscopy (XPS). Whilst significant molecular degradation of the EVA films was observed for the PLD method, the original macromolecular structure was only partially degraded when the PED technique was used, emphasizing the superiority of the PED method over PLD for structurally complex polymers such as EVA. Optical and scanning electron microscopic observations revealed compact and smooth EVA films deposited by pulsed electron beam ablation as opposed to heterogeneous films with many different sized particulates obtained by PLD.
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43

Kamarulzaman, Norlida, and Nurhanna Badar. "Pulsed LASER Deposition of MgO Thin Films." Advanced Materials Research 545 (July 2012): 38–42. http://dx.doi.org/10.4028/www.scientific.net/amr.545.38.

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MgO thin films were deposited by Pulsed Laser deposition using different process parameter. The characteristics were investigated via X-Ray diffraction (XRD), Scanning Electron Microscope (SEM) and Digital Holographic Microscope (DHM). It is found that the thin film surface morphology and thickness are different. It was found that the different process parameters such as chamber gas pressure, substrate temperature, LASER energy and number of pulses greatly influence the characteristics of the thin films obtained. The thin films have very low thicknesses of 97, 187 and 193 nm.
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44

Kund, Julian, Sven Daboss, Tommaso Marchesi D’Alvise, Sean Harvey, Christopher V. Synatschke, Tanja Weil, and Christine Kranz. "Physicochemical and Electrochemical Characterization of Electropolymerized Polydopamine Films: Influence of the Deposition Process." Nanomaterials 11, no. 8 (July 30, 2021): 1964. http://dx.doi.org/10.3390/nano11081964.

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Polydopamine (PDA) is a synthetic eumelanin polymer which is, to date, mostly obtained by dip coating processes. In this contribution, we evaluate the physical and electrochemical properties of electrochemically deposited PDA films obtained by cyclic voltammetry or pulsed deposition. The obtained PDA thin films are investigated with respect to their electrochemical properties, i.e., electron transfer (ET) kinetics and charge transfer resistance using scanning electrochemical microscopy and electrochemical impedance spectroscopy, and their nanomechanical properties, i.e., Young’s modulus and adhesion forces at varying experimental conditions, such as applied potential or pH value of the medium using atomic force microscopy. In particular, the ET behavior at different pH values has not to date been investigated in detail for electrodeposited PDA thin films, which is of particular interest for a multitude of applications. Adhesion forces strongly depend on applied potential and surrounding pH value. Moreover, force spectroscopic measurements reveal a significantly higher percentage of polymeric character compared to films obtained by dip coating. Additionally, distinct differences between the two depositions methods are observed, which indicate that the pulse deposition process leads to denser, more cross-linked films.
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45

Hamed, Esraa K. "Laser energy effect on the properties of ZnS thin films prepared by PLD technique." Iraqi Journal of Physics (IJP) 11, no. 21 (February 24, 2019): 84–90. http://dx.doi.org/10.30723/ijp.v11i21.371.

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Zinc sulfide (ZnS) thin films were deposited on glass substrates using pulsed laser deposition technique. The laser used is the Q-switched Nd: YAG laser with 1064nm wavelength and 1Hz pulse repetition rate and varying laser energy 700mJ-1000mJ with 25 pulse. The substrate temperature was kept constant at 100°C. The structural, morphological and optical properties of ZnS thin films were characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscope (AFM) and UV-VIS spectrophotometer.
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46

Anikeev, Sergey G., Anastasiia V. Shabalina, Sergei A. Kulinich, Nadezhda V. Artyukhova, Daria R. Korsakova, Evgeny V. Yakovlev, Vitaly A. Vlasov, Oleg V. Kokorev, and Valentina N. Hodorenko. "Preparation and Electron-Beam Surface Modification of Novel TiNi Material for Medical Applications." Applied Sciences 11, no. 10 (May 12, 2021): 4372. http://dx.doi.org/10.3390/app11104372.

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A new approach to fabricate TiNi surfaces combining the advantages of both monolithic and porous materials for implants is used in this work. New materials were obtained by depositing a porous TiNi powder onto monolithic TiNi plates followed by sintering at 1200 °C. Then, further modification of the material surface with a high-current-pulsed electron beam (HCPEB) was carried out. Three materials obtained (one after sintering and two after subsequent beam treatment by 30 pulses with different pulse energy) were studied by XRD, SEM, EDX, surface profilometry, and by means of electrochemical measurements, including OCP and EIS. Structural and compositional changes caused by HCPEB treatment were investigated. Surface properties of the samples during their storage in saline for 10 days were studied and a model experiment with cell growth (MCF-7) was carried out for the unmodified sample with an electron beam to detect cell appearance on different surface locations.
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47

BERNARDINELLO, A., D. BATANI, V. MASELLA, T. A. HALL, S. ELLWI, M. KOENIG, A. BENUZZI, et al. "Fast electron propagation and energy deposition in laser shock compressed plasmas." Laser and Particle Beams 17, no. 3 (July 1999): 519–28. http://dx.doi.org/10.1017/s0263034699173208.

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The first experimental study of the propagation of electrons created by an intense laser in shock-compressed matter has been performed with the VULCAN laser facility at the Rutherford Appleton Laboratory, to investigate one of the fundamental phases of the fast ignitor concept for inertial confinement fusion. Plastic plane targets were irradiated on one side with two pulsed laser beams, each with I ≈ 1014 W/cm2, t ≈ 2 ns, E ≈ 80 J per pulse, to generate a planar shock wave; on the opposite side of the target, a chirped pulse amplification (CPA) laser beam (I ≈ 1016 W/cm2, t ≈ 3 ps, E ≈ 10 J) was focused to generate the fast electrons. The results show an increase of hot electron penetration in compressed matter with respect to an ordinary one. Experimental results have been analyzed with computer simulations.
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48

Xu, Dafeng, Shengmin Cai, Xizun Wu, and Wenzhi Zhang. "Galvanostatic study of the kinetics of lithium deposition on platinum electrode in dimethylformamide." Collection of Czechoslovak Chemical Communications 56, no. 1 (1991): 241–45. http://dx.doi.org/10.1135/cccc19910241.

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The deposition of lithium in dimethylformamide (DMF) has been studied by means of galvanostatic measurements. The overpotential was recorded during constant current pulses of so short a duration that only a few monolayers per pulse were deposited. The experiments were carried out under conditions of minimum contamination of the metal surface. The deposition process of Li in DMF is irreversible, the electron transfer being the rate-determining step. A mechanism of Li electrodeposition in DMF was proposed.
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49

ESCAMILLA, CONETT HUERTA, FABIO CHALE LARA, and MUFEI XIAO. "PHOTONIC GAPS OF ALUMINIUM–NITRIDE FILM RELATED WITH STRUCTURE AND DEPOSITION." International Journal of Modern Physics B 25, no. 04 (February 10, 2011): 487–97. http://dx.doi.org/10.1142/s0217979211058183.

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Work is reported on the characterizations of pulsed laser deposited aluminum–nitride thin films. The films were deposited on silicon substrate with a KrF 248 nm pulse laser operating in a Riber LDM-22 system. Optical reflection spectroscopy (400–900 nm) was carried out, which revealed that, under certain deposition conditions, the films could show strong periodic spectra with reflection gaps of about 50–100 nm in width. The microscopic structures, such as crystalline status and element composition, were also investigated with Auger electron spectroscopy, X-ray photoelectron spectroscopy, atomic force microscopy, scanning electron microscopy, and profilometry etc. Relations between the optical responses and the microscopic structures were established. The foundations underlying the relations were studied and discussed.
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50

Veljković, Dj, D. Tanaskovic, R. Petrović, Dj Janaćković, M. Mitrić, C. Cojanu, C. Ristoscu, and Ion N. Mihailescu. "Double-Layer Bioactive Glass Coatings Obtained by Pulsed Laser Deposition." Key Engineering Materials 361-363 (November 2007): 277–80. http://dx.doi.org/10.4028/www.scientific.net/kem.361-363.277.

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Pulsed laser deposition was used to obtain functionally graded bioactive glass coatings on titanium substrates. An UV KrF* (λ=248 nm, τ>7 ns) excimer laser was used for the multi-pulse irradiation of the targets. The depositions were performed in oxygen while keeping substrate temperature at 400°C. We used sintered glass targets in the system SiO2-Na2O-K2O-CaO-MgOP2O5 that differed in SiO2 content, which was either 57 wt.% (6P57) or 61 wt.% (6P61). A glass 6P61 was used as the first layer in direct contact with the metallic substrate, while the outer bioactive layer was made of glass 6P57. Both the bioactive coatings and the bulk glasses were analyzed by Fourier transform infrared spectrometry (FTIR), grazing incidence X-ray diffraction (GIXRD), and scanning electron microscopy (SEM). The FTIR spectra of the glass powders and glass coatings showed the main vibration modes of the Si-O-Si groups. GIXRD analysis confirmed that the glass coatings had an amorphous structure. The SEM micrographs of the glass coatings showed the films to consist of droplets with diameters ranging from 0.2 to 5 μm. SEM was used to determine the rate of apatite formation on the coating when exposed to simulated body fluid (SBF) solution for 7 days. We demonstrated that pulsed laser deposition leads to good glass-metal adhesion on the substrate and well attached bioactive particles on the surface. We consider therefore this method appropriate for forming implants that can develop an apatite layer after immersion in SBF.
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