Academic literature on the topic 'Pyridinium compounds. Chemical reactions'

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Journal articles on the topic "Pyridinium compounds. Chemical reactions"

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Wenska, Grazyna, Bohdan Skalski, Stefan Paszyc, and Zofia Gdaniec. "Photochemistry of N-(pyrimidin-2-one-4-yl)pyridinium derivatives. The ring contraction of pyrimidinone into imidazolinone." Canadian Journal of Chemistry 73, no. 12 (1995): 2178–84. http://dx.doi.org/10.1139/v95-270.

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Photochemical reactions (λ > 300 nm) of N-(1-methylpyrimidin-2-one)-and N-(1,5-dimethyl-pyrimidin-2-one)pyridinium chlorides were studied in deoxygenated aqueous solution at various pH's. Only the former compound was found to be reactive under these conditions to give pyrimidine ring contraction photoproducts 1-methyl-4-imidazolin-2-one and 1-methyl-4-imidazolin-2-one-5-carboxyaldehyde, with pH-dependent chemical yields. The photochemical pyrimidine ring contraction reaction does not occur for other photochemically reactive pyrimidin-2-ones bearing 3-methylimidazolium-1,1,2,4-triazol-1-yl,
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El Kharrat, Salem, Philippe Laurent, Laurent Boiteau, and Hubert Blancou. "Novel Synthesis of Substituted 2-Trifluoromethyl and 2-Perfluoroalkyl N-Arylpyridinium Compounds—Mechanistic Insights." Molecules 24, no. 12 (2019): 2328. http://dx.doi.org/10.3390/molecules24122328.

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We report a new one-pot synthesis of 2-trifluoromethylated/2-perfluoroalkylated N-aryl-substituted pyridiniums, 5,6,7,8-tetrahydroquinoliniums and 6,7,8,9-tetrahydro-5H-cyclohepta[b]-pyridinium compounds starting from an activated β-dicarbonyl analogue (here a perfluoro-alkylated gem-iodoacetoxy derivative), an aromatic amine and a (cyclic or acyclic) ketone. The key step of this multicomponent reaction, involves the formation of a 3-perfluoroalkyl-N,N’-diaryl-1,5-diazapentadiene intermediate, various examples of which were isolated and characterized for the first time, together with investiga
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Adamcsik, Bernadett, Enikő Nagy, Béla Urbán, Péter Szabó, Péter Pekker, and Rita Skoda-Földes. "Palladium nanoparticles on a pyridinium supported ionic liquid phase: a recyclable and low-leaching palladium catalyst for aminocarbonylation reactions." RSC Advances 10, no. 40 (2020): 23988–98. http://dx.doi.org/10.1039/d0ra03406a.

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SILP catalyst with grafted pyridinium ions was used for either mono- or double carbonylation depending on the reaction conditions. Good recyclability and low palladium loss were observed during the synthesis of pharmaceutically active compounds.
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Neue, Benedikt, Roland Fröhlich, and Ernst-Ulrich Würthwein. "A Novel Pathway to Imidazo[1,2-a]pyridines. Access through Imino Pyridinium Salts." Zeitschrift für Naturforschung B 67, no. 4 (2012): 295–304. http://dx.doi.org/10.1515/znb-2012-0403.

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A new synthetic strategy for the preparation of imidazo[1,2-a]pyridines 10 is reported, which is based on the electrocyclization reaction of imino pyridinium salts 7 upon treatment with a strong base. The starting materials are easily prepared from 2-aminopyridine (3) by imine condensation and subsequent alkylation at the pyridine nitrogen atom. The ring closure reaction of the zwitterionic intermediate 8 to give a five-membered ring proceeds in low yield forming first the dihydro compound 9, which under the reaction conditions is transformed into the corresponding aromatic compounds 10 and 11
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Wzgarda-Raj, Kinga, Martyna Nawrot, Agnieszka J. Rybarczyk-Pirek, and Marcin Palusiak. "Ionic cocrystals of dithiobispyridines: the role of I...I halogen bonds in the building of iodine frameworks and the stabilization of crystal structures." Acta Crystallographica Section C Structural Chemistry 77, no. 8 (2021): 458–66. http://dx.doi.org/10.1107/s2053229621006306.

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It has been confirmed that mercaptopyridines undergo spontaneous condensation in redox reaction with iodine-forming dithiopyridines. In the solid state, these compounds are protonated at the N atoms and cocrystallize with iodine forming salt structures, namely, 2-[(pyridin-2-yl)disulfanyl]pyridinium triiodide sesquiiodine, C10H9N2S2 +·I3 −·1.5I2, and 4,4′-(disulfanediyl)dipyridinium pentaiodide triiodide, C10H10N2S2 2+·I5 −·I3 −. Dithiopyridine cations are packed among three-dimensional frameworks built from iodide anions and neutral iodine molecules, and are linked by hydrogen, halogen and ch
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Freitas, Emanuelle Dantas, Celso Fidelis Moura Jr., Jonas Kerwald, and Marisa Masumi Beppu. "An Overview of Current Knowledge on the Properties, Synthesis and Applications of Quaternary Chitosan Derivatives." Polymers 12, no. 12 (2020): 2878. http://dx.doi.org/10.3390/polym12122878.

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Chitosan, a chitin-derivative polysaccharide, known for its non-toxicity, biocompatibility and biodegradability, presents limited applications due to its low solubility in neutral or basic pH medium. Quaternization stands out as an alternative to modify this natural polymer, aiming to improve its solubility over a wide pH range and, consequently, expand its range of applications. Quaternization occurs by introducing a quaternary ammonium moiety onto or outside the chitosan backbone, via chemical reactions with primary amino and hydroxyl groups, under vast experimental conditions. The oldest an
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Agbodan, Kokou Agbékonyi, Oudjaniyobi Simalou, Gneiny Whad Tchani, and Koffi Jondo. "Etude de l’influence de la basicité sur l’enthalpie de réaction des sels N-méthoxycarbonyl-(oxy)-pyridiniums." International Journal of Biological and Chemical Sciences 14, no. 4 (2020): 1489–98. http://dx.doi.org/10.4314/ijbcs.v14i4.26.

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Les hétérocycles sont importants, aussi bien dans les domaines biologique, médicinal et thérapeutique (vitamines, hormones, antibiotiques, etc), que dans le secteur industriel et technologique (inhibiteurs de corrosion, colorants, agents stabilisants, pesticides, herbicides. Les chloroformiates ou chlorocarbonates sont les esters dérivés de l’acide chloroformique. La chimie des N-oxydes hétérocycliques (pyridine et N-oxydes) a connu un important développement au cours des dernières années. L’objectif principal du présent travail est l’étude de l’action du métoxycarbonylchloride sur la pyridine
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Goto, Hiromasa. "Preparation of Lyotropic Liquid Crystals and Optical Characterisation." International Letters of Chemistry, Physics and Astronomy 64 (February 2016): 171–77. http://dx.doi.org/10.18052/www.scipress.com/ilcpa.64.171.

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Synthesis of an ionic liquid crystal (1-(6-(4-(4-trans-pentyl-cyclohexyl)-phenoxy)-hexyl)pyridinium chloride) showing lyotropic smectic phase was carried out. A simple reaction between phenylcyclohexane-type liquid crystal having halogen atom in the terminal and pyridine allows production of the ionic liquid crystal. The NMR measurements confirm chemical structure of the compound. Observation with polarsing optical microscopy evaluated that the compound shows fine multi-domains having fluidity. The lyotropic LC thus prepared displays smectic phase with layer structure.
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Günther, Andrzej, and Robert Pelech. "Bio-Active Pyridinium Salts: A Mini-Review on Properties and Selected Reactions." Mini-Reviews in Organic Chemistry 16, no. 7 (2019): 610–16. http://dx.doi.org/10.2174/1570193x16666181228102304.

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Pyridium salts are very valuable compounds with various activities, especially biological, and therefore their preparation can be very useful in the synthesis of various compounds, such as drugs, dyes or surfactants. In this mini-review authors focused mostly on bioactive properties of pyridinium salts, and main preparations of these compounds such, synthesis pyridinium salts from pyrylium salts via nucleophilic substitution SN(ANRORC), obtaining pyridinium salts via directs arylation, and via Addition at Nitrogen atom, and the last method is synthesis of pyridinium salts via ring opening and
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Subramaniam, G., K. Balasubramanian, and P. Sridhar. "1,1′-Alkylene bis-pyridinium compounds as pickling inhibitors." Corrosion Science 30, no. 10 (1990): 1019–23. http://dx.doi.org/10.1016/0010-938x(90)90209-n.

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Dissertations / Theses on the topic "Pyridinium compounds. Chemical reactions"

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Bennett, Christopher James. "A study of the photochemistry of pyridinium salts." Thesis, University of Sussex, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.341061.

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Arnaout, Abdulkarim al. "Synthese regioselective de dihydropyridines et de pyridines 2- ou 4-fonctionnalisees : applications." Poitiers, 1987. http://www.theses.fr/1987POIT2254.

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Jo, Kyo Dong. "Synthesis and reactions of poly(ethynyldialkylsilanes)." Thesis, University of North Texas, 1990. https://digital.library.unt.edu/ark:/67531/metadc332501/.

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A nucleophilic cleavage reaction of 2,2,5,5,8,8-hexamethyl-2,5,8-trisilanona-3,6-diyne, I, with several bases, occurs rapidly at room temperature in both polar and non-polar solvents. An attack occurs exclusively at the central silicon regardless of the steric requirements of the bases (alkyllithium). The major products from the reaction of I with tert-butyllithium followed by hydrolysis were 2,2,5,5,6,6-hexamethyl-2,5-disilahepta-3-yne, II, and 2,2,5,5-tetramethyl-2,5-disilahexa-3-yne, VI.
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DiCesare, John C. "Carbohydrates as chiral auxiliaries in organometallic reactions." Diss., Georgia Institute of Technology, 1992. http://hdl.handle.net/1853/27389.

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Zheng, Sipeng. "The reactions of ruthenium (ii) polypyridyl complexes." Thesis, Nelson Mandela Metropolitan University, 2009. http://hdl.handle.net/10948/1089.

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Ruthenium (II) polypyridine complexes in general have been extensively studied because of their unique redox and photochemical properties. A typical example of such complexes is tris(2,2’-bipyridyl) ruthenium (II). In this study, this complex was synthesized and then characterized using electronic spectroscopy and cyclic voltammetry. It was also shown that the ruthenium concentration could be accurately determined using ICP-MS. It was found that the complex is very stable in various chemical environments. It was observed from spectrophotometric investigations that persulphate and lead dioxide
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Lachance, Russell Philip. "Oxidation and hydrolysis reactions in supercritical water : chlorinated hydrocarbons and organosulfur compounds." Thesis, Massachusetts Institute of Technology, 1995. http://hdl.handle.net/1721.1/33533.

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Majeed, Zulfiqar. "The reactions of directly related tellurium and selenium heterocyclic compounds with triiron dodecacarbonyl." Thesis, Aston University, 1999. http://publications.aston.ac.uk/9622/.

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The reactions of directly related tellurium and selenium heterocyclic compounds with triiron dodecacarbonyl are described. The reaction of 2-telluraphthalide, C8H8OTe with [Fe3(CO)12 gave [Fe{C6H4(CH2)Te}(CO)3]2, (1). An iron atom has inserted into the telluracyclic ring, and it is probable that one co-ordinated CO ligand arises from the initially organic carbonyl group. X-ray analysis of compound (1) showed that the compound has a Fe2Te2 core, which is achieved by dimerisation. The reaction of telluraphthalic anhydride, C8H402Te with [Fe3(CO)12] gave a known, but unexpected, organic phthalide
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McCarten, Paul. "Synthesis and reactivity of alpha-heteroaton substituted organoiron compounds." Diss., Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/30503.

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Sen, Subhabrata. "Sythesis of diaryl ethers and diaryl amines via Dötz benzannulation /." free to MU campus, to others for purchase, 2001. http://wwwlib.umi.com/cr/mo/fullcit?p3030540.

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Laird, Darin Wiley. "Theoretical and experimental investigations of norbornyne and cyclohexyne /." Full text (PDF) from UMI/Dissertation Abstracts International, 2001. http://wwwlib.umi.com/cr/utexas/fullcit?p3008374.

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Books on the topic "Pyridinium compounds. Chemical reactions"

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Science of synthesis: Multicomponent reactions. Georg Thieme Verlag KG, 2014.

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Inventing reactions. Springer, 2013.

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Luis, S. V. Chemical reactions and processes under flow conditions. RSC Publishing, 2010.

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Russell, M. J. The inorganic-organic interface: Geological, chemical and biological potential. University of Glasgow, Dept. of Geology & Applied Geology, 1991.

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Otrzymywanie i niektóre reakcje chemiczne tetraalkilodiboroksanów. Wydawnictwa Politechniki Warszawskiej, 1989.

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Sporzyński, Andrzej. Właściwości i niektóre reakcje chemiczne trialkilo- i triaryloboroksynów. Wydawnictwa Politechniki Warszawskiej, 1993.

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1923-, Setton R., and North Atlantic Treaty Organization. Scientific Affairs Division., eds. Chemical reactions in organic and inorganic constrained systems. D. Reidel, 1986.

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G, Ellerd Michael, ed. Name reactions and reagents in organic synthesis. Wiley, 1988.

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I͡A︡, Simkin B., and Mini͡a︡ev R. M, eds. Quantum chemistry of organic compounds: Mechanisms of reactions. Springer-Verlag, 1990.

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Synthesis, structure and reactivity of oligometallic complexes. Hartung-Gorre, 1985.

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Book chapters on the topic "Pyridinium compounds. Chemical reactions"

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Minkin, Vladimir I., Boris Ya Simkin, and Ruslan M. Minyaev. "Potential Energy Surfaces of Chemical Reactions." In Quantum Chemistry of Organic Compounds. Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-75679-5_1.

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Martell, Arthur E. "Metal-Catalyzed Reactions of Organic Compounds." In Chemical Changes in Food during Processing. Springer US, 1985. http://dx.doi.org/10.1007/978-1-4613-2265-8_3.

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Martell, Arthur E. "Metal-Catalyzed Reactions of Organic Compounds." In Chemical Changes in Food During Processing. Springer Netherlands, 1985. http://dx.doi.org/10.1007/978-94-017-1016-9_3.

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Beard, James M., and Ruth Ann Murphy. "Types of Chemical Compounds and Their Reactions." In Environmental Chemistry in Society, 3rd ed. CRC Press, 2021. http://dx.doi.org/10.1201/9780429316548-4.

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Mineshos, G., S. Glavas, and U. Schurath. "Reactions of Peroxyacetyl Radicals with Sulfur Compounds." In Physico-Chemical Behaviour of Atmospheric Pollutants. Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-009-0567-2_28.

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Williams, J. O., R. Hoare, N. Hunt, and M. J. Parrott. "Monitoring Chemical Reactions in Metal-Organic Chemical Vapour Deposition (MOCVD)." In Mechanisms of Reactions of Organometallic Compounds with Surfaces. Springer US, 1989. http://dx.doi.org/10.1007/978-1-4899-2522-0_17.

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Barnes, I., V. Bastian, and K. H. Becker. "Reactions of IO Radicals with Sulphur Containing Compounds." In Physico-Chemical Behaviour of Atmospheric Pollutants. Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-009-0567-2_25.

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Sidebottom, Howard, Jack Tracy, and Ole John Nielsen. "Reactions of OH Radicals with Organic Nitrogen-Containing Compounds." In Chemical Processes in Atmospheric Oxidation. Springer Berlin Heidelberg, 1997. http://dx.doi.org/10.1007/978-3-642-59216-4_22.

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Voronkov, M. G., N. S. Vyazankin, E. N. Deryagina, A. S. Nakhmanovich, and V. A. Usov. "Methods of Preparation and Chemical Properties of Different Modifications of Sulfur." In Reactions of Sulfur with Organic Compounds. Springer US, 1987. http://dx.doi.org/10.1007/978-1-4684-0679-5_2.

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Boehm, H. P., Y. Sh Ko, B. Ruisinger, and R. Schlögl. "Order-Disorder Phenomena in Graphite Intercalation Compounds and Reduction Reactions in Alkali Metal-Intercalated Compounds of Graphite." In Chemical Reactions in Organic and Inorganic Constrained Systems. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4582-1_32.

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Conference papers on the topic "Pyridinium compounds. Chemical reactions"

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Choudhary, R. B. "An Investigation on Tribo-Chemical Reactions of AF/AW Additive Compounds of Alkyl ThioOctadecenoate Origin." In Annual International Conference on Chemistry, Chemical Engineering and Chemical Process. Global Science & Technology Forum (GSTF), 2013. http://dx.doi.org/10.5176/2301-3761_ccecp.04.

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Plehovich, Sergey, Sergey Zelentsov, and Alexandre Plehovich. "Quantum-chemical Study of Mechanism of the Photochemical Reactions of Nitro Compounds with Sulfur - and Nitroso Containing Compounds." In The 16th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2012. http://dx.doi.org/10.3390/ecsoc-16-01048.

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Ewinger, Angela, Guenter Rinke, Sigrid Kerschbaum, Monika Rinke, and Klaus Schubert. "Raman-Spectroscopy for Measuring Chemical Reactions in Micro Reactors." In ASME 2008 6th International Conference on Nanochannels, Microchannels, and Minichannels. ASMEDC, 2008. http://dx.doi.org/10.1115/icnmm2008-62089.

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Micro heat exchangers, micro mixers and micro reactors have gained importance in chemical, pharmaceutical and life sciences applications. Due to the large surface to volume ratio these devices provide efficient mass and heat transfer. This results in greater selectivity and higher yield for chemical reactions. The Institute for Micro Process Engineering is working on the development, manufacturing, and testing of micro channel devices mainly manufactured of stainless steel, where channel widths and depths lie in the range of 0.2 mm. In order to obtain a better understanding of the physical and
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Perangin-angin, Sabarmin, and Sri Wahyuni Barus. "Synthesis of Quatenary Ammonium Compounds from Eugenol through Mannich and Methylation Reactions and Its Antibacterial Activity." In International Conference on Chemical Science and Technology Innovation. SCITEPRESS - Science and Technology Publications, 2019. http://dx.doi.org/10.5220/0008879202230228.

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Daimon, Emiko, Kousuke Inada, Takuya Nomoto, Kenjiro Otsuka, Keiji Kitada, and John O'Doherty. "Chemical Effects of Titanate Compounds on the Thermal Reactions of Phenolic Resins in Friction Materials - Part 2." In SAE 2012 Brake Colloquium & Exhibition - 30th Annual. SAE International, 2012. http://dx.doi.org/10.4271/2012-01-1790.

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Daimon, Emiko, Takuya Nomoto, Kousuke Inada, Hidetoshi Ogawa, Keiji Kitada, and John O'Doherty. "Chemical Effects of Titanate Compounds on the Thermal Reactions of Phenolic Resins in Friction Materials -Part 3." In SAE 2013 Brake Colloquium & Exhibition - 31st Annual. SAE International, 2013. http://dx.doi.org/10.4271/2013-01-2025.

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Plehovitch, Sergey, Sergei Zelentsov, Dmitry Fomichev, Sergey Zelentsov, and Dmitry Ovsyannikov. "Quantum-chemical calculations of the possible formation of nitroso oxides in the course of the photooxidation reactions by nitro compounds." In The 17th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2013. http://dx.doi.org/10.3390/ecsoc-17-e004.

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Villinger, J., W. Federer, and S. Praun. "Continuous Pre- and Post- Catalyst Hydrocarbon and Nitrogen Compounds-Monitoring of Various DeNOx Reactions by Twin Chemical Ionization Mass Spectrometry." In Spring Fuels & Lubricants Meeting & Exhibition. SAE International, 2002. http://dx.doi.org/10.4271/2002-01-1679.

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Tannous, J., M. I. De Barros Bouchet, T. Le Mogne, J. M. Martin, and P. Charles. "Experimental Modelisation of Organosulphurs Tribochemistry by Gas Phase Lubrication." In ASME/STLE 2007 International Joint Tribology Conference. ASMEDC, 2007. http://dx.doi.org/10.1115/ijtc2007-44030.

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Organosulphurs compounds have been used for many years as Extreme Pressure (EP) and Anti Wear (AW) additives in a wide range of metal working applications. These additives act in severe conditions by building up a reaction film (tribofilm) on the metallic surfaces. Several interpretations have been proposed to explain the (EP) and the (AW) properties of these compounds, but the detailed mechanisms and surface reactions products are still largely unknown. To better understand the tribochemistry of these compounds, we developed a new device in our laboratory called “Environmentally Controlled Tr
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Roy, Shrabanti, and Omid Askari. "Chemical Kinetic Study on Reaction Pathway of Anisole Oxidation at Various Operating Condition." In ASME 2020 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/imece2020-24233.

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Abstract Biofuels are considered as an alternative source of energy which can decrease the growing consumption of fossil fuel, hence decreasing pollution. Anisole (methoxybenzene) is a potential source of biofuel produced from cellulose base compounds. It is mostly available as a surrogate of phenolic rich compound. Because of the attractive properties of this fuel in combustion, it is important to do detail kinetic study on oxidation of anisole. In this study a detail chemical mechanism is developed to capture the chemical kinetics of anisole oxidation. The mechanism is developed using an aut
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