Academic literature on the topic 'Pyrimidinyl'

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Journal articles on the topic "Pyrimidinyl"

1

Jiang, Duo Hua, and Gang Liu. "Synthesis and Properties Study of 1-(2,4-Dimethoxyl-5-Pyrimidinyl)-2-[2-Methyl-5-(3-Cyano)-3-Thienyl]Perfluorocyclopentene." Applied Mechanics and Materials 662 (October 2014): 91–94. http://dx.doi.org/10.4028/www.scientific.net/amm.662.91.

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A novel photochromic diarylethene bearing a pyrimidine moiety, 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(3-cyano)-3-thieny-l] perfluorocyclopentene has been synthesized. Its properties, including photochromic behavior and fluorescent properties, have been investigated. The compound exhibited remarkable photochromism, changing from colorless to blue after irradiation with UV light. The results indicated that the pyrimidine moiety played a very important role during the process of photoisomerization reactions.
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2

Kurth, Mark, Wonken Choung, Beth Lorsbach, Thomas Sparks, and James Ruiz. "4-(Isoxazol-3-yl)pyrimidines from Pyrimidinyl Nitrile Oxides." Synlett 2008, no. 19 (2008): 3036–40. http://dx.doi.org/10.1055/s-0028-1087346.

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3

Hurst, DT, AD Stacey, M. Nethercleft, A. Rahim, and MR Harnden. "The Synthesis of Some Pyrimidinyl and Thiazolyl Ureas and Thioureas and Some Related Compounds." Australian Journal of Chemistry 41, no. 8 (1988): 1221. http://dx.doi.org/10.1071/ch9881221.

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Some pyrimidin-2- and pyrimidin-4-amines were treated with isocyanates and isothiocyanates to give the corresponding disubstituted ureas or thioureas . A pyrimidin-2-amine is more reactive than a pyrimidin-4- amine in these reactions. 2-Aminothiazoles and thiazolinones also react to give the disubstituted ureas or thioureas . The use of ethoxycarbonyl or benzoyl isothiocyanate or isocyanate gives products which are readily hydrolysed to the pyrimidinyl or thiazolyureas or thioureas but with concomitant hydrolysis and decarboxylation of an ethoxycarbonyl substituent . The use of chlorosulfonyl
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4

Sharma, Vijay Kumar, Anup Barde, and Sunita Rattan. "Design, Synthesis and Characterization of Pyrimidine based Thiazolidinedione Derivatives." Asian Journal of Chemistry 32, no. 5 (2020): 1101–8. http://dx.doi.org/10.14233/ajchem.2020.22565.

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Novel thiazolidine-2,4-dione (TZD) based pyrimidine derivatives have been synthesized by Knoevenagel condensation reaction between thiazolidine-2,4-dione and amino pyrimidinyl aliphatic aldehydes followed by heterogeneous metal reduction. Synthetic strategy involved nucleophillic substitution of hydroxyl protected six membered aliphatic chain on 4,6-dichloropyrimidine followed by Suzuki coupling. This approach is regioselective, efficient and versatile for synthesis of such analogs
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5

Liu, Jing Jing, Hong Jing Jia, and Shou Zhi Pu. "Synthesis and Properties Study of 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(9-phenanthrene)-3-thienyl] perfluorocyclopentene." Advanced Materials Research 1003 (July 2014): 31–34. http://dx.doi.org/10.4028/www.scientific.net/amr.1003.31.

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A novel photochromic diarylethene bearing a pyrimidine moiety, 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(9-phenanthrene)-3-thienyl] perfluorocyclopentene has been synthesized. Its properties, including photochromic behavior and fluorescent properties, have been investigated. The compound exhibited remarkable photochromism, changing from colorless to red after irradiation with UV light in solution. The fluorescence had a remarkable initial increase with subsequent dramatic decrease with increasing concentration. The results indicated that the pyrimidine moiety played a very important role
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6

Liu, Jing Jing, Hong Jing Jia, and Shou Zhi Pu. "Synthesis and Properties Study of 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(4-n-pentylbenzene)-3-thienyl] Perfluorocyclopentene." Advanced Materials Research 952 (May 2014): 75–78. http://dx.doi.org/10.4028/www.scientific.net/amr.952.75.

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A novel photochromic diarylethene based on a six-membered pyrimidine moiety 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(4-n-pentylbenzene)-3-thienyl] perfluorocyclopent-ene has been synthesized. Its properties, including photochromic behavior and fluorescent properties, have been investigated. The compounds exhibited remarkable photochromism, changing from colorless to red after irradiation with UV light both in solution and in PMMA film. The fluorescence had a remarkable initial increase with subsequent dramatic decrease with increasing concentration. The results indicated that the pyrimi
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7

Brough, Peter, Jacques Pécaut, André Rassat, and Paul Rey. "Pyrimidinyl Nitronyl Nitroxides." Chemistry - A European Journal 12, no. 19 (2006): 5134–41. http://dx.doi.org/10.1002/chem.200600061.

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8

Wang, Hsiao-Fen, Kuang-Hway Yih та Gene-Hsiang Lee. "Syntheses, Reactivities, Characterization, and Crystal Structures of Dipalladium Complexes Containing the 1,3-pyrimidinyl Ligand: Structures of [Pd(PPh3)(Br)]2(μ,η2-C4H3N2)2, [Pd(Br)]2(μ,η2-Hdppa)2, and [{Pd(PPh3)(CH3CN)}2(μ,η2-C4H3N2)2][BF4]2". Molecules 25, № 9 (2020): 2035. http://dx.doi.org/10.3390/molecules25092035.

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In a refluxing chloroform solution, the η1-pyrimidinyl {pyrimidinyl = C4H3N2} palladium complex [Pd(PPh3)2(η1-C4H3N2)(Br)], 1 exhibited intermolecular displacement of two triphenylphosphine ligands to form the doubly bridged η2-pyrimidinyl Dipalladium complex [Pd(PPh3)(Br)]2(μ,η2-C4H3N2)2, 3. The treatment of 1 with Hdppa {Hdppa = N,N-bisdiphenyl phosphinoamine} in refluxing dichloromethane yielded the doubly bridged Hdppa dipalladium complex [Pd(Br)]2(μ,η2-Hdppa)2, 4. Complex 1 reacted with the bidentate ligand, NH4S2CNC4H8 and, NaS2COEt, and the tridentate ligand, KTp {Tp = tris(pyrazoyl-1-y
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9

Voigt, Harry, Dietrich Heydenhauß, Frank Hofmann, and Günter Jaenecke. "Gemischte Pyrimidinyl-azolyl-thioäther." Zeitschrift für Chemie 14, no. 12 (2010): 472. http://dx.doi.org/10.1002/zfch.19740141208.

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10

Smicius, Romualdas, Virginija Jakubkiene, Milda M. Burbuliene, Aiste Mikalainyte, and Povilas Vainilavicius. "Synthesis of 1-(6-Methyl-2,4-Dioxo-1,2,3,4-Tetrahydro-3-Pyrimidinyl)Acetyl-4-Alkyl(Aryl)Thiosemicarbazides and their Heterocyclisation to 1,2,4-Triazoles and 1,3,4-Thiadiazoles." Journal of Chemical Research 2002, no. 4 (2002): 170–72. http://dx.doi.org/10.3184/030823402103171555.

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5-(6-Methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)methyl-1,3,4-oxadiazole-2-thione reacts with amines to give 1-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)acetyl-4-alkyl(aryl)thiosemicarbazides, which on treatment with base or acid undergo cyclisation to 4-alkyl-1,2,4-triazole-2-thiones or 4-amino-1,3,4-thiadiazoles, respectively.
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