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1

Adeboye, B. S., S. O. Obayopo, A. A. Asere, and I. K. Okediran. "Production of Pyrolytic Oil from Cassava Peel Wastes." Journal of Solid Waste Technology and Management 47, no. 4 (2021): 726–31. http://dx.doi.org/10.5276/jswtm/2021.726.

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This study investigated the production of pyrolytic oil from cassava peel wastes. Pyrolysis is a very important thermochemical method for converting biomass into biofuel. In recent times, the production of biofuel has taken center stage due to concerns over the sustainability of conventional energy sources. Pyrolysis has received much attention by researchers because it can be used to optimize the production of high calorific value pyrolytic oil. A fixed bed pyrolysing unit was constructed for the production of liquid fuel in this study. Cassava peels were pyrolysed in the reactor. The tempera
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2

ASSUMPÇÃO, Luiz Carlos Fonte Nova de, Mônica Regina da Costa MARQUES, and Montserrat Motas CARBONELL. "CO-PYROLYSIS OF POLYPROPYLENE WITH PETROLEUM OF BACIA DE CAMPOS." Periódico Tchê Química 06, no. 11 (2009): 23–30. http://dx.doi.org/10.52571/ptq.v6.n11.2009.24_periodico11_pgs_23_30.pdf.

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In this study, the process of co-pyrolysis of polypropylene (PP) residues with gas-oil was evaluated, varying the temperature and the amount of polypropylene fed to the reactor. The polypropylene samples and gas-oil were submitted to the thermal co-pyrolysis in an inert atmosphere, varying the temperature and the amount of PP. The influence of the gas-oil was evaluated carrying the co-pyrolysis in the absence of PP. The pyrolysed liquids produced by this thermal treatment were characterized by modified gaseous chromatography in order to evaluate the yield in the range of distillation of diesel
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3

Urbanovičs, Igors, Gaļina Dobele, Vilhelmīne Jurkjane, Valdis Kampars, and Ēriks Samulis. "PYROLYTIC OIL - A PRODUCT OF FAST PYROLYSIS OF WOOD RESIDUES FOR ENERGY RESOURCES." Environment. Technology. Resources. Proceedings of the International Scientific and Practical Conference 1 (June 23, 2007): 16. http://dx.doi.org/10.17770/etr2007vol1.1742.

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The application of renewable energy resources for energy production becomes increasingly urgent worldwide. Fast pyrolysis is one of the trends of obtaining liquid fuel from solid biomass.The aim of the present study was to investigate the yield, chemical composition, physical properties and water amount of hardwood pyrolytic oil (PO) depending on the pyrolysis and pre-treatment conditions in an ablative type reactor.The results of the analysis of the heat capacity of pyrolytic oil show an increase in this parameter from 12 MJ/kg (without drying) to 15-16 MJ/kg, drying the wood, and then pyroly
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4

Usino, David O., Päivi Ylitervo, and Tobias Richards. "Primary Products from Fast Co-Pyrolysis of Palm Kernel Shell and Sawdust." Molecules 28, no. 19 (2023): 6809. http://dx.doi.org/10.3390/molecules28196809.

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Co-pyrolysis is one possible method to handle different biomass leftovers. The success of the implementation depends on several factors, of which the quality of the produced bio-oil is of the highest importance, together with the throughput and constraints of the feedstock. In this study, the fast co-pyrolysis of palm kernel shell (PKS) and woody biomass was conducted in a micro-pyrolyser connected to a Gas Chromatograph–Mass Spectrometer/Flame Ionisation Detector (GC–MS/FID) at 600 °C and 5 s. Different blend ratios were studied to reveal interactions on the primary products formed from the c
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5

Mercl, Filip, Zdeněk Košnář, Lorenzo Pierdonà, Leidy Marcela Ulloa-Murillo, Jiřina Száková, and Pavel Tlustoš. "Changes in availability of Ca, K, Mg, P and S in sewage sludge as affected by pyrolysis temperature." Plant, Soil and Environment 66, No. 4 (2020): 143–48. http://dx.doi.org/10.17221/605/2019-pse.

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Pyrolysis is a promising technology for sewage sludge (SS) treatment providing several improvements of SS properties for soil application. However, information on the influence of pyrolytic temperature on the availability of nutrients in resulting biochar (BC) is limited. In this study, anaerobically stabilised SS was pyrolysed in a laboratory fixed-bed reactor at 220, 320, 420, 520, and 620 °C for 30 min in the N<sub>2</sub> atmosphere. Pyrolysis resulted in a higher total content of all studied nutrients in BCs. Aromaticity and hydrophobicity of BCs increased with increasing temp
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6

Alagu, R. M., and E. Ganapathy Sundaram. "Experimental Studies on Thermal and Catalytic Slow Pyrolysis of Groundnut Shell to Pyrolytic Oil." Applied Mechanics and Materials 787 (August 2015): 67–71. http://dx.doi.org/10.4028/www.scientific.net/amm.787.67.

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Pyrolysis process in a fixed bed reactor was performed to derive pyrolytic oil from groundnut shell. Experiments were conducted with different operating parameters to establish optimum conditions with respect to maximum pyrolytic oil yield. Pyrolysis process was carried out without catalyst (thermal pyrolysis) and with catalyst (catalytic pyrolysis). The Kaolin is used as a catalyst for this study. The maximum pyrolytic oil yield (39%wt) was obtained at 450°C temperature for 1.18- 2.36 mm of particle size and heating rate of 60°C/min. The properties of pyrolytic oil obtained by thermal and cat
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7

Lee, Nahyeon, Junghee Joo, Kun-Yi Andrew Lin, and Jechan Lee. "Waste-to-Fuels: Pyrolysis of Low-Density Polyethylene Waste in the Presence of H-ZSM-11." Polymers 13, no. 8 (2021): 1198. http://dx.doi.org/10.3390/polym13081198.

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Herein, the pyrolysis of low-density polyethylene (LDPE) scrap in the presence of a H-ZSM-11 zeolite was conducted as an effort to valorize plastic waste to fuel-range chemicals. The LDPE-derived pyrolytic gas was composed of low-molecular-weight aliphatic hydrocarbons (e.g., methane, ethane, propane, ethylene, and propylene) and hydrogen. An increase in pyrolysis temperature led to increasing the gaseous hydrocarbon yields for the pyrolysis of LDPE. Using the H-ZSM-11 catalyst in the pyrolysis of LDPE greatly enhanced the content of propylene in the pyrolytic gas because of promoted dehydroge
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8

Lu, Tao, Hao Ran Yuan, Shun Gui Zhou, Hong Yu Huang, Kobayashi Noriyuki, and Yong Chen. "On the Pyrolysis of Sewage Sludge: The Influence of Pyrolysis Temperature on Biochar, Liquid and Gas Fractions." Advanced Materials Research 518-523 (May 2012): 3412–20. http://dx.doi.org/10.4028/www.scientific.net/amr.518-523.3412.

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Pyrolytic conversion of sewage sludge to biochar, oil and gas is an environmentally and economically acceptable way comparable to conventional options for sewage sludge disposal. The aim of this paper is to investigate the influence of pyrolysis temperature on production of biochar fraction for agronomic application, oil and gas fractions for energy utilization. Sewage sludge samples collected from an urban sewage treatment plant were pyrolysed in a bench–scale quartz tubular furnace over the temperature range of 300-700°C.The results indicated that the biochar fraction yield decreased, the yi
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9

CARNEIRO, Débora da Silva, and Mônica Regina da Costa MARQUES. "CO-PYROLYSIS OF POLYETHYLENE S WASTE WITH BACIA DE CAMPOS'S GASOIL." Periódico Tchê Química 07, no. 13 (2010): 16–21. http://dx.doi.org/10.52571/ptq.v7.n13.2010.17_periodico13_pgs_16_21.pdf.

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In this work the process of co-pyrolysis of polyethylene plastic residue was carried through with petroleum, in a temperature of 550°C. First, the polyethylene samples and petroleum had been submitted the thermal co-pyrolysis in inert atmosphere. Later they had been evaluated the efficiency of the process with variation of the amount of polyethylene residue added to the petroleum. The generated pyrolytic liquids had been characterized by modified gaseous chromatography, with the objective to evaluate the generation of fractions in the band of the distillation of diesel. It can be observed that
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10

Kumar, Sachin, and R. K. Singh. "Thermolysis of High-Density Polyethylene to Petroleum Products." Journal of Petroleum Engineering 2013 (May 30, 2013): 1–7. http://dx.doi.org/10.1155/2013/987568.

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Thermal degradation of plastic polymers is becoming an increasingly important method for the conversion of plastic materials into valuable chemicals and oil products. In this work, virgin high-density polyethylene (HDPE) was chosen as a material for pyrolysis. A simple pyrolysis reactor system has been used to pyrolyse virgin HDPE with an objective to optimize the liquid product yield at a temperature range of 400°C to 550°C. The chemical analysis of the HDPE pyrolytic oil showed the presence of functional groups such as alkanes, alkenes, alcohols, ethers, carboxylic acids, esters, and phenyl
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11

Ramani, Balan, Arqam Anjum, Eddy Bramer, Wilma Dierkes, Anke Blume, and Gerrit Brem. "Flash Pyrolysis of Waste Tires in an Entrained Flow Reactor—An Experimental Study." Polymers 16, no. 12 (2024): 1746. http://dx.doi.org/10.3390/polym16121746.

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In this study, a flash pyrolysis process is developed using an entrained flow reactor for recycling of waste tires. The flash pyrolysis system is tested for process stability and reproducibility of the products under similar operating conditions when operated continuously. The study is performed with two different feedstock materials, i.e., passenger car (PCT) and truck tire (TT) granulates, to understand the influence of feedstock on the yield and properties of the pyrolysis products. The different pyrolytic products i.e., pyrolytic carbon black (pCB), oil, and pyro-gas, are analyzed, and the
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12

Yang, Bin, and Ming Chen. "Influence of Interactions among Polymeric Components of Automobile Shredder Residue on the Pyrolysis Temperature and Characterization of Pyrolytic Products." Polymers 12, no. 8 (2020): 1682. http://dx.doi.org/10.3390/polym12081682.

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Pyrolysis and gasification have gradually become the main means to dispose of automobile shredder residue (ASR), since these methods can reduce the volume and quality of landfill with lower cost and energy recovery can be conducted simultaneously. As the ASR pyrolysis process is integrated, the results of pyrolysis reactions of organic components and the interaction among polymeric components can be clarified by co-pyrolysis thermogravimetric experiments. The results show that the decomposition mechanisms of textiles and foam are markedly changed by plastic in the co-pyrolysis process, but the
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13

Sarkar, Aparna, Sudip De Sarkar, Michael Langanki, and Ranjana Chowdhury. "Studies on Pyrolysis Kinetic of Newspaper Wastes in a Packed Bed Reactor: Experiments, Modeling, and Product Characterization." Journal of Energy 2015 (2015): 1–8. http://dx.doi.org/10.1155/2015/618940.

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Newspaper waste was pyrolysed in a 50 mm diameter and 640 mm long reactor placed in a packed bed pyrolyser from 573 K to 1173 K in nitrogen atmosphere to obtain char and pyro-oil. The newspaper sample was also pyrolysed in a thermogravimetric analyser (TGA) under the same experimental conditions. The pyrolysis rate of newspaper was observed to decelerate above 673 K. A deactivation model has been attempted to explain this behaviour. The parameters of kinetic model of the reactions have been determined in the temperature range under study. The kinetic rate constants of volatile and char have be
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14

Wang, Xian-Hua, Han-Ping Chen, Xue-Jun Ding, Hai-Ping Yang, Shi-Hong Zhang, and Ying-Qiang Shen. "Properties of gas and char from microwave pyrolysis of pine sawdust." BioResources 4, no. 3 (2009): 946–59. http://dx.doi.org/10.15376/biores.4.3.946-959.

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Pine sawdust pyrolysis was carried out respectively using microwave and conventional electrical heating at different temperatures in order to understand the properties of pyrolytic products from microwave pyrolysis of biomass. Less char material was obtained by microwave pyrolysis compared to conventional heating at the same temperature. While comparing the components of the pyrolytic gases, it was revealed that the microwave pyrolysis gas usually had higher H2 and CO contents and lower CH4 and CO2 contents than those obtained by conventional pyrolysis at the same temperature. The texture anal
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15

Acosta, Rolando, Claudia Tavera, Paola Gauthier-Maradei, and Debora Nabarlatz. "Production of Oil and Char by Intermediate Pyrolysis of Scrap Tyres: Influence on Yield and Product Characteristics." International Journal of Chemical Reactor Engineering 13, no. 2 (2015): 189–200. http://dx.doi.org/10.1515/ijcre-2014-0137.

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Abstract Scrap tyres represent a severe environmental problem that must be solved by developing technologies allowing the processing of high quantities of this residue. This work presents the results of pyrolysis oil and pyrolytic char production by intermediate pyrolysis of rubber recovered from scrap tyres. The influence of process variables such as particle size, temperature and reaction time on the characteristics of the products obtained was analysed. Maximal yields of 52.56 and 39.50 wt% of pyrolysis oil and pyrolytic char, respectively, were obtained, under operational conditions that f
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16

Elkhalifa, Samar, Sabah Mariyam, Hamish R. Mackey, Tareq Al-Ansari, Gordon McKay, and Prakash Parthasarathy. "Pyrolysis Valorization of Vegetable Wastes: Thermal, Kinetic, Thermodynamics, and Pyrogas Analyses." Energies 15, no. 17 (2022): 6277. http://dx.doi.org/10.3390/en15176277.

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In comparison to other methods, valorising food waste through pyrolysis appears to be the most promising because it is environmentally friendly, fast, and has a low infrastructure footprint. On the other hand, understanding the pyrolytic kinetic behaviour of feedstocks is critical to the design of pyrolysers. As a result, the pyrolytic degradation of some common kitchen vegetable waste, such as tomato, cucumber, carrot, and their blend, has been investigated in this study using a thermogravimetric analyser. The most prevalent model fitting method, Coats–Redfern, was used for the kinetic analys
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17

Joo, Junghee, Seonho Lee, Heeyoung Choi, Kun-Yi Andrew Lin, and Jechan Lee. "Single-Use Disposable Waste Upcycling via Thermochemical Conversion Pathway." Polymers 13, no. 16 (2021): 2617. http://dx.doi.org/10.3390/polym13162617.

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Herein, the pyrolysis of two types of single-use disposable waste (single-use food containers and corrugated fiberboard) was investigated as an approach to cleanly dispose of municipal solid waste, including plastic waste. For the pyrolysis of single-use food containers or corrugated fiberboard, an increase in temperature tended to increase the yield of pyrolytic gas (i.e., non-condensable gases) and decrease the yield of pyrolytic liquid (i.e., a mixture of condensable compounds) and solid residue. The single-use food container-derived pyrolytic product was largely composed of hydrocarbons wi
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18

Li, Chao, Zhaoying Yang, Xinge Wu, Shuai Shao, Xiangying Meng, and Gaowu Qin. "Reactive Molecular Dynamics Simulations of Polystyrene Pyrolysis." International Journal of Molecular Sciences 24, no. 22 (2023): 16403. http://dx.doi.org/10.3390/ijms242216403.

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Polymers’ controlled pyrolysis is an economical and environmentally friendly solution to prepare activated carbon. However, due to the experimental difficulty in measuring the dependence between microstructure and pyrolysis parameters at high temperatures, the unknown pyrolysis mechanism hinders access to the target products with desirable morphologies and performances. In this study, we investigate the pyrolysis process of polystyrene (PS) under different heating rates and temperatures employing reactive molecular dynamics (ReaxFF-MD) simulations. A clear profile of the generation of pyrolysi
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19

Djuric, Slavko, Sasa Brankov, Tijana Kosanic, Mirjana Ceranic, and Branka Nakomcic-Smaragdakis. "The composition of gaseous products from corn stalk pyrolysis process." Thermal Science 18, no. 2 (2014): 533–42. http://dx.doi.org/10.2298/tsci120711021d.

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This paper describes experimental investigation of corn stalk pyrolysis. The mass of the sample (corn stalk) inside a pyrolytic reactor was 10 g with particle diameter of 5-10 mm. The sample in the reactor was heated in the temperature range of 24-650?C and the gas components generated during corn stalk pyrolysis were measured using gas analyzer G750 POLYTECTOR II. The sample mass before, during and after pyrolysis process was determined by using METTLER P1000 digital scale. Experimental results of the corn stalk pyrolysis indicate that as the temperature in the reactor increases from 300-650?
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20

Lucas, E. B., O. E. Itabiyi, and O. O. Ogunleye. "Optimization of Products Yields from the Pyrolysis of Palm Kernel Shells Using Response Surface Methodology." Applied Mechanics and Materials 575 (June 2014): 13–16. http://dx.doi.org/10.4028/www.scientific.net/amm.575.13.

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This work focussed on the optimisation of product yields from the pyrolysis of palm kernel shells (PKS). 479g of dried PKS were loaded into the retort and then placed inside the furnace chamber and this was pyrolysed at 300, 400, 500, 600 and 700°C. The pyrolysis products obtained are char, tar (pyro oil and pyroligneous acid) and gas. A full factorial design (FFD) consisting two factors (Temperature and duration of pyrolysis) at three level was used to study the pattern of product yields from the pyrolysis of PKS. Char, tar and gas were evaluated as the responses. Thirteen experimental runs r
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21

Mazlan, Mohammad Amir Firdaus, Yoshimitsu Uemura, Norridah Osman, and Suzana Yusup. "Review on Pyrolysis of Hardwood Residue to Biofuel." Applied Mechanics and Materials 625 (September 2014): 714–17. http://dx.doi.org/10.4028/www.scientific.net/amm.625.714.

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In Malaysia, approximately 7 million tonne/year of rubber wood waste and 5 million tonne/year of acacia wood waste were generated in 2011. These hardwood residues could be utilized to produce biofuel through pyrolysis process. The aims of the paper are to study the fluidized bed pyrolysis system, determine the properties of pyrolytic bio-oil, and highlight the effect of biomass type, size and pyrolysis temperature on pyrolytic products distribution.
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22

Fonseca, Noyala, Roger Fréty, and Emerson Andrade Sales. "Biogasoline Obtained Using Catalytic Pyrolysis of Desmodesmus sp. Microalgae: Comparison between Dry Biomass and n-Hexane Extract." Catalysts 12, no. 12 (2022): 1517. http://dx.doi.org/10.3390/catal12121517.

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The present work deals with the production of hydrocarbons in the C5–C12 range obtained from the fast micropyrolysis of a laboratory-grown Desmodesmus sp. microalgae. It compares the properties of this specific fraction of hydrocarbons using or not using transition alumina catalysts during pyrolysis in experiments with both pure dried microalgae and its n-hexane extract. The microalgae were characterised using thermogravimetry (TG) and CHN analysis; the n-hexane extract was analysed through Fourier transform infrared spectroscopy (FTIR). The pyrolysis experiments were performed in a multi-shot
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23

Banciu, MD, RFC Brown, KJ Coulston, et al. "Formation of Cyclopent[hi]acephenanthrylene From 1,2-, 1,3-, 1,4- and 2,3-Triphenylenedicarboxylic Acid Derivatives on Flash Vacuum Pyrolysis at >900°C." Australian Journal of Chemistry 49, no. 9 (1996): 965. http://dx.doi.org/10.1071/ch9960965.

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The processes involved in the conversion of triphenylene , C18H12, into cyclopent [hi] acephenanthrylene, C18H10, under flash vacuum pyrolytic conditions at 900-1100°C have been investigated by pyrolysing triphenylene-1,2- and -2,3-dicarboxylic anhydrides and diallyl triphenylene-1,3- and -1,4-dicarboxylates to give the corresponding didehydrotriphenylenes in the gas phase. These didehydro intermediates are converted into mixtures of cyclopent [hi] acephenanthrylene and triphenylene in different yields and proportions. Pyrolysis of 9,10-diethynylphenanthrene. C18H10, yields cyclopent [hi] acep
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24

Liao, Hang Tao, Yang Zhang, Qiang Lu, and Chang Qing Dong. "Analytical Fast Pyrolysis of Glucose, Cellubiose and Cellulose: Comparison of the Pyrolytic Product Distribution." Advanced Materials Research 805-806 (September 2013): 186–90. http://dx.doi.org/10.4028/www.scientific.net/amr.805-806.186.

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Analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) was employed for the fast pyrolysis of glucose, cellubiose and cellulose in this study. The pyrolytic products from the three glucose-based materials were determined and compared to reveal the distribution differences. The results indicated that fast pyrolysis of the three materials obtained similar pyrolytic products, including the anhydrosugars, furans, linear carbonyls and cyclopentanones, but the distribution of the pyrolytic products differed from each other. The cellulose formed more anhydrosugars, but less carbonyls an
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25

Wu, Zhi, Pengcheng Jiang, Hongxing Pang, et al. "Improving the Oxidation Resistance of Phenolic Resin Pyrolytic Carbons by In Situ Catalytic Formation of Carbon Nanofibers via Copper Nitrate." Materials 17, no. 15 (2024): 3770. http://dx.doi.org/10.3390/ma17153770.

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Phenolic resin pyrolytic carbons were obtained by catalytic pyrolysis of phenolic resin at 500 °C, 600 °C, 700 °C, and 800 °C for 3 h in an argon atmosphere using copper nitrate as a catalyst precursor. The effects of copper salts on the pyrolysis process of phenolic resin as well as the structural evolution and oxidation resistance of phenolic resin pyrolytic carbons were studied. The results showed that copper oxide (CuO) generated from the thermal decomposition of copper nitrate was reduced to copper (Cu) by the gas generated from the thermal decomposition of the phenolic resin. Carbon nano
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26

Kim, Soosan, Nahyeon Lee, and Jechan Lee. "Pyrolysis for Nylon 6 Monomer Recovery from Teabag Waste." Polymers 12, no. 11 (2020): 2695. http://dx.doi.org/10.3390/polym12112695.

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In this work, we used pyrolysis to treat teabag waste (TBW). Changes in the pyrolysis temperature affected the composition and yield of the products. For example, more non-condensable gases and less char were produced with an increase in the pyrolysis temperature. Pyrolysis conducted under a nitrogen environment yielded caprolactam at temperatures between 400 and 700 °C. An increase in the pyrolysis temperature from 400 to 500 °C increased the caprolactam yield from 3.1 to 6.2 wt.%. At 700 °C, the yield decreased to 4.6 wt.%. The highest caprolactam yield (i.e., 6.2 wt.% at 500 °C) was equival
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27

Halasová, Martina, Martin Černý, Adam Strachota, and Zdeněk Chlup. "Effect of Pyrolysis Temperature on the Mechanical Response in Partially Pyrolysed Polysiloxanes." Key Engineering Materials 784 (October 2018): 55–60. http://dx.doi.org/10.4028/www.scientific.net/kem.784.55.

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The pyrolysis process of polysiloxane resin conducted in the temperature range 400 – 700 °C results in hybrid materials owning some polymeric (thermosetting) behaviour. A certain level of elastic recovery and/or viscoelastic flow showed at various steps of pyrolytic transformation was monitored using the instrumented Vickers hardness method. Determined indentation force-indentation depth curves reflect the mechanical response and the level of the transformation; however, the relaxation behaviour is not covered by this method fully. An extensive indentation relaxation was revealed in the materi
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28

Zhao, Rongwen, Zhongyang Liu, Tongjun Liu, and Liping Tan. "Pyrolysis behaviors, kinetics, and byproducts of enzymatic hydrolysis residues for lignocellulosic biorefining." BioResources 16, no. 2 (2021): 2626–43. http://dx.doi.org/10.15376/biores.16.2.2626-2643.

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Enzymatic hydrolysis residues (EHR) are the solid wastes from enzymatic hydrolysis and/or fermentation of the cellulosic bioethanol industry. These byproducts have not been effectively used. Thermogravimetric analysis with infrared spectroscopy (TG-IR) and pyrolysis-gas chromatography/ mass spectrometry (Py-GC/MS) were used to quantify the pyrolytic bioenergy potential of EHR with alkaline hydrogen peroxide (AHP) and bisulfite (BSF) pretreatment through assessing their pyrolysis behaviors, kinetics, and byproducts. The TG-IR analysis showed that the EHR pyrolysis temperature range was 180 °C t
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29

Purevsuren, Barnasan, Otgonchuluun Dashzeveg, Ariunaa Alyeksandr, Narangerel Janchig, and Jargalmaa Soninkhuu. "Pyrolysis of pine wood and characterisation of solid and liquid products." Mongolian Journal of Chemistry 19, no. 45 (2018): 24–31. http://dx.doi.org/10.5564/mjc.v19i45.1086.

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Pyrolysis of pine wood was carried out at different temperatures and the yields of solid (biochar), liquid (tar and pyrolysed water) and gas products were determined. Temperature around 500 ºC was determined as an optimal heating temperature of pyrolysis and approximately 27.1% hard residue (biochar), 21.46% tar, 20.04% pyrolysed water and 31.30% gas were obtained by pyrolysis. The thermal stability indices of pine wood are relatively low, which are indications of its low thermal stability and high yield of volatile matter (Vdaf = 90.3%). The thermal stability indices of pyrolysis of solid res
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30

Shi, Kai Qi, Tao Wu, Hai Tao Zhao, Edward Lester, Philip Hall, and Yao Dong Wang. "Microwave Induced Pyrolysis of Biomass." Applied Mechanics and Materials 319 (May 2013): 127–33. http://dx.doi.org/10.4028/www.scientific.net/amm.319.127.

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Microwave heating has attracted much attention recently due to its nature of volumetric heating and instant heating. In this study, microwave heating was adopted not only as a heating method but also an approach to enhance the pyrolysis of biomass. Microwave induced pyrolysis was carried out at 500°C with silicon carbide as a microwave energy absorber. Conventional pyrolysis of gumwood was also conducted under the same operating temperature as microwave-enhanced pyrolysis. The yields of pyrolytic bio-oil and bio-gas under microwave heating are 8.52 wt% and 73.26 wt% respectively, which are hig
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31

Kushch, S. D., V. E. Muradyan, and N. S. Kuyunko. "Methane Conversion over Vacuum Carbon Black: Influence of Hydrogen." Eurasian Chemico-Technological Journal 3, no. 3 (2017): 163. http://dx.doi.org/10.18321/ectj560.

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<p>Methane pyrolysis over vacuum carbon black has been studied in the temperature range 550–1000 °C. The methane conversion degree and selectivity with respect to ethene and propene do not depend on the initial concentration of methane <em>i.e. </em>the process order with respect to methane is first. The selectivity with respect to pyrolytic carbon is antibate to the methane initial concentration. Hydrogen introduced to methane inhibits formation of pyrolytic carbon and aromatics especially in methane pyrolysis. The methane conversion degree in pyrolysis of methane/hydrogen m
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32

Elnour, Ahmed Y., Abdulaziz A. Alghyamah, Hamid M. Shaikh, et al. "Effect of Pyrolysis Temperature on Biochar Microstructural Evolution, Physicochemical Characteristics, and Its Influence on Biochar/Polypropylene Composites." Applied Sciences 9, no. 6 (2019): 1149. http://dx.doi.org/10.3390/app9061149.

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Environmental management through effective utilization of biowastes has been a topic of intensive research in recent years. This study examines the effect of pyrolysis temperature on the physical and morphological characteristic of biochar (BC) derived from lignocellulosic wastes. The biochar was prepared by pyrolysing date palm biomass at various temperatures, i.e., 300, 400, 500, 600, and 700 °C. These pyrolysed biochars were then characterized for their carbon content, mineral compositions, chemical functionalities, and morphological structures, for understanding their physicochemical chara
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Półtorak, Andrzej, Anna Onopiuk, Jan Kielar, et al. "Polycyclic Aromatic Hydrocarbons (PAHs) in Wheat Straw Pyrolysis Products Produced for Energy Purposes." Sustainability 16, no. 22 (2024): 9639. http://dx.doi.org/10.3390/su16229639.

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Using agricultural waste biomass pyrolysis to produce energy sources and biochar may support local economies in rural areas and enhance sustainability in the agricultural sector, reducing dependence on traditional energy sources and fertilisers. To obtain liquid and gaseous forms of biomass fuel, wheat straw pellets were pyrolysed in a screw reactor at temperatures of 300, 400, 500, 600, and 700 °C. An analysis was conducted to assess the influence of process temperature on the physicochemical composition of the raw material and the resulting biochar, pyrolysis liquid, and synthesis gas. The p
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Jasminská, Natália, Tomáš Brestovič, and Mária Čarnogurská. "THE EFFECT OF TEMPERATURE PYROLYSIS PROCESS OF USED TIRES ON THE QUALITY OF OUTPUT PRODUCTS." Acta Mechanica et Automatica 7, no. 1 (2013): 20–25. http://dx.doi.org/10.2478/ama-2013-0004.

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Abstract Pyrolysis together with gasification and combustion create a group of so called thermic processes. Unlike the combustion it is based on thermic decomposition of organic materials without any access of oxidative media. Within the pyrolytic process, three main fractions are created: solid residue, pyrolytic gas and organic liquid product - pyrolytic oil. The presented article examines the effects of pyrolysis operational conditions (above all, temperature) on gas products, solid residues and liquid fractions.
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Pola, Josef, and Václav Chvalovský. "Laser driven pyrolysis of n-alkanes." Collection of Czechoslovak Chemical Communications 50, no. 1 (1985): 223–27. http://dx.doi.org/10.1135/cccc19850223.

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CW CO2 laser photosensitized (SF6) homogeneous pyrolysis of n-alkanes (C5-C7) affords almost twice higher yield of important ethylene compared to conventional pyrolysis in tubular reactors. No production of heavy pyrolytic oils, resins or coke and very small alteration of the pyrolytic distribution with the conversion are other advantages of the laser process that can be ascribed to the absence of in conventional reactors important surface reactions.
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Aljbour, Salah H., Muhamad O. Al-Limoun, Ahmad Alamro, Malek Ma’moun, and Pilar Nasser. "Extraction of Bio Oil from Jordanian Biomass Resources via Pyrolysis and its Antibacterial Effect." Research Journal of Chemistry and Environment 28, no. 11 (2024): 60–65. http://dx.doi.org/10.25303/2811rjce060065.

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This study explores the potential of pyrolytic oil extracted from Jordanian biomass resources as an antibacterial agent. Pyrolysis, a transformative thermal decomposition process, offers a promising avenue for converting biomass into valuable products. Pyrolytic oil, derived from biomass via pyrolysis, presents a complex composition and inherent antibacterial properties, making it a candidate for addressing antibiotic resistance and promoting sustainable solutions. Five biomass feed stocks were subjected to pyrolysis and their product distributions were analyzed. Pyrolytic oil yields were inve
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Ramesh, B. T., Javed Sayyad, Arunkumar Bongale, and Anupkumar Bongale. "Extraction and Performance Analysis of Hydrocarbons from Waste Plastic Using the Pyrolysis Process." Energies 15, no. 24 (2022): 9381. http://dx.doi.org/10.3390/en15249381.

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Ecosystem destruction is one of today’s significant challenges due to fast industrialisation and an increasing population. It takes several years for solid trash, such as plastic bottles and super-market bags, to decompose in nature. In addition, plastic disposal techniques such as landfilling, reuse, and incineration pose significant threats to human health and the environment. In this paper, we investigated whether the impact of mixing biodiesel with waste oil from recycled plastic on the resulting fuel mixture’s yields better physical and chemical properties. Consequently, pyrolysis is one
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Raclavská, Helena, Hana Škrobánková, Petr Pavlík, and Veronika Sassmanová. "The Properties of Material from Recovered TetraPak Beverage Cartons." Applied Mechanics and Materials 832 (April 2016): 3–9. http://dx.doi.org/10.4028/www.scientific.net/amm.832.3.

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Energy utilization (pyrolysis) of residue from fibre recycling of used beverage cartons is very important. Identification the optimal technology for separation of aluminium from pyrolytic carbon and assessment of its quality in relationship to the pyrolysis conditions is necessary for recycling of Al. The particles of pyrolytic carbon are not pure carbon, they contain only from 65 to 83 % of carbon, the rest in ash coming from sorting and collection of waste (glass, porcelain). Process of pyrolysis and/or utilization of charge reactor influenced the chemical composition of Al particles by carb
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Cao, Junrui, and Yuhui Ma. "Pyrolysis and gasification of macroalgae Enteromorpha prolifera under a CO2 atmosphere using the thermogravimetry–Fourier transform infrared spectroscopy technique." Progress in Reaction Kinetics and Mechanism 44, no. 2 (2019): 132–42. http://dx.doi.org/10.1177/1468678319825735.

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Non-isothermal pyrolysis and gasification of Enteromorpha prolifera (also known as Ulva prolifera) under a CO2 atmosphere were investigated by thermogravimetry analysis. The gaseous products were measured online with Fourier transform infrared spectroscopy coupled with thermogravimetry. The kinetic parameters of pyrolysis and gasification reactions were obtained using the Coats–Redfern method. The experimental results showed that Enteromorpha prolifera had two derivative thermogravimetry peaks centered at 240 and 800°C, indicating the pyrolysis of organics and gasification of char, respectivel
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Sundaramurthy, Suresh, Suresh Arisutha, Katti Sanjeev, and Verma Jyoti. "Photocatalytic assisted microwave-based plasma pyrolyser: A solution for COVID-19 related wastes." Journal of Indian Chemical Society Vol. 97, No. 12a, Dec 2020 (2020): 2623–32. https://doi.org/10.5281/zenodo.5656061.

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Department of Chemical Engineering, Maulana Azad National Institute of Technology, Bhopal-462 003, Madhya Pradesh, India Eco-Science and Technology, Bhopal-462 003, Madhya Pradesh, India ONGC Energy Centre, 8th Floor, Core-3&amp;4, SCOPE Minar, Laxmi Nagar, Delhi-110 092, India <em>E-mail:</em> sanjeev_katti@ongc.co.in Manuscript received online 17 November 2020, revised and accepted 27 December 2020 The aim of this mini-review is to explore the potential of indigenous photocatalytic assisted microwave plasma based pyrolyser for COVID-19 related wastes (gloves, masks, bottles, personal protect
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He, Xuan Ming, Jia Qi Fang, Ye Pan, Wei Li, and Xiao Juan Wang. "Study on Mechanism of Low Temperature Co-Pyrolysis of Duckweed and Flame Coal." Advanced Materials Research 724-725 (August 2013): 300–305. http://dx.doi.org/10.4028/www.scientific.net/amr.724-725.300.

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Co-pyrolysis characteristics of long flame coal mixed with duckweed in different proportions were studied by using TG. And the kinetic parameters was also figured out by using the method of Coats-Redfern. It was exhibited significant synergistic effect created more the light component between duckweed and coal during co-pyrolysis, The pyrolysis rate of flame coal is much smaller than biomass, and the starting pyrolysis temperature of flame coal is higher than biomass. The kinetic analysis indicated that the pyrolytic processes can be described as first order reactions model. The average activa
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Amanat, A., Z. Hussain, M. Imran Din, et al. "Catalytic pyrolysis of Sweet Sorghum plant by using fixed-bed reactor; Effect of different temperatures on the pyrolytic bio-oil yield and FT-IR characterization." Journal of Optoelectronic and Biomedical Materials 13, no. 4 (2021): 137–44. http://dx.doi.org/10.15251/jobm.2021.134.137.

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Pyrolysis of sweet sorghum, lignocellulosic graminaceous plant has been conceded using the fixed bed tubular reactor. Temperature plus catalyst are the important factors which effect the pyrolysis process. Here catalytic pyrolysis has been done by the catalyst ZnO-Fe2O3/Al2O3 at different temperatures. We have done our pyrolysis reactions on3changed temperatures i.e. 250̊ C, 350 ̊C, 450 ̊C. By using catalyst, we obtain the pyrolytic products at a very low temperature and it is proved very efficient method for biofuel production. From different temperature experimentation, we concluded that the
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Moško, Jaroslav, Michael Pohořelý, Siarhei Skoblia, Zdeněk Beňo, and Michal Jeremiáš. "Detailed Analysis of Sewage Sludge Pyrolysis Gas: Effect of Pyrolysis Temperature." Energies 13, no. 16 (2020): 4087. http://dx.doi.org/10.3390/en13164087.

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Conventional methods of sewage sludge disposal are often limited by their environmental impact and economic demands. Pyrolysis has been studied as a viable method for sewage sludge disposal and transformation into usable products. Pyrolytic products may have various uses, and their complex characteristics shall be described to assess their potential for safe utilization. Here, we studied slow pyrolysis of stabilized sewage sludge in a fixed bed reactor at 400–800 °C to describe the composition of the pyrolysis gas and the condensate fraction. We found that condensate elemental composition was
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Ścierski, Waldemar. "Migration of Sulfur and Nitrogen in the Pyrolysis Products of Waste and Contaminated Plastics." Applied Sciences 11, no. 10 (2021): 4374. http://dx.doi.org/10.3390/app11104374.

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The most advantageous way of managing plastics, according to circular economy assumptions, is recycling, i.e., reusing them. There are three types of plastics recycling: mechanical, chemical and energy recycling. The products of the pyrolysis process can be used for both chemical and energy recycling. Possibilities of further use of pyrolysis products depend on their physicochemical parameters. Getting to know these parameters was the aim of the research, some of which are presented in this article. The paper presents the research position for conducting the pyrolysis process and discusses the
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Lu, Qiang, Xu-Ming Zhang, Zhi-Bo Zhang, Ying Zhang, Xi-Feng Zhu, and Chang-Qing Dong. "Catalytic fast pyrolysis of cellulose mixed with sulfated titania to produce levoglucosenone: Analytical Py-GC/MS study." BioResources 7, no. 3 (2012): 2820–34. http://dx.doi.org/10.15376/biores.7.3.2820-2834.

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Sulfated titania (SO42-/TiO2) was prepared and used for catalytic fast pyrolysis of cellulose to produce levoglucosenone (LGO), a valuable anhydrosugar product. Analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) technique was employed in this study to achieve the catalytic fast pyrolysis of cellulose and on-line analysis of the pyrolysis vapors. Experiments were performed to investigate the effects of several factors on the LGO production, i.e. pyrolysis temperature, cellulose/catalyst ratio, TiO2 crystal type, and pyrolysis time. The results indicated that the SO42-/TiO2 cat
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Pourjafar, Mohammad, Amir Khosravani, and Rabi Behrooz. "Formation mechanism of aromatics during co-pyrolysis of coal and cotton stalk." BioResources 15, no. 2 (2020): 4449–63. http://dx.doi.org/10.15376/biores.15.2.4449-4463.

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Pyrolysis experiments were conducted in a tubular furnace from room temperature to 600 °C at 5 °C /min, and kept for 15 min. The light tar was then derived from the liquid products of pyrolysis by n-hexane supersonic extraction. Gas chromatography–mass spectrometry was employed to analyze the light tars from cotton stalk (CS) pyrolysis, Shenmu coal (SM) pyrolysis, and co-pyrolysis of CS/SM. Microcrystalline cellulose (MCC) was selected as a model compound, and the light tar from co-pyrolysis tar of MCC/SM was investigated for comparison. The results indicated that CS improved the yields and qu
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Saringat, Muhammad Ilmam B., Ayub M. Som, Norhayati Talib, and Mohammad Asadullah. "Kinetic Parameters of Biomass Pyrolysis – Comparison between Thermally Thick and Fine Particles of Biomass." Advanced Materials Research 1113 (July 2015): 340–45. http://dx.doi.org/10.4028/www.scientific.net/amr.1113.340.

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In this study, kinetic parameters of fast and slow pyrolysis is compared. For fast pyrolysis, cylindrical wood pieces of 20 mm diameter and 50 mm length is pyrolysed in a tube furnace at temperatures ranging from 300°C to 500°C. Solid, liquid and gas products are collected and the yields are calculated. For slow pyrolysis, thermogravimetric analysis (TGA) is used using sawdust from the same biomass. Using the experimental data from two different methods the kinetic parameters are calculated such as activation energy and pre-exponential factor for the two different pyrolysis methods. For fast p
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48

Julius Gbenga Akinbomi, Olawale Theophilus Ogunwumi, Rosemary Ojone Daniel, et al. "Influence of waste sorting on the effectiveness of polymeric waste pyrolysis." Global Journal of Engineering and Technology Advances 10, no. 3 (2022): 079–84. http://dx.doi.org/10.30574/gjeta.2022.10.3.0042.

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Pyrolysis of polymeric wastes, including waste plastic bottles, discarded rubber tyres and pure water sachets, is one of the environmental-friendly processes for waste valorization. However, continuous effort must be made to reduce the cost implication of the pyrolysis process in terms of time, money and energy requirement. Based on this premise, this study examined the justification regarding heat absorption rate and product yield, for sorting polymeric waste mixture before the pyrolysis process. The objective was achieved by carrying out pyrolysis of the separated and mixed plastic bottle, r
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Julius, Gbenga Akinbomi, Theophilus Ogunwumi Olawale, Ojone Daniel Rosemary, et al. "Influence of waste sorting on the effectiveness of polymeric waste pyrolysis." Global Journal of Engineering and Technology Advances 10, no. 3 (2022): 079–84. https://doi.org/10.5281/zenodo.6402405.

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Pyrolysis of polymeric wastes, including waste plastic bottles, discarded rubber tyres and pure water sachets, is one of the environmental-friendly processes for waste valorization. However, continuous effort must be made to reduce the cost implication of the pyrolysis process in terms of time, money and energy requirement. Based on this premise, this study examined the justification regarding heat absorption rate and product yield, for sorting polymeric waste mixture before the pyrolysis process. The objective was achieved by carrying out pyrolysis of the separated and mixed plastic bottle, r
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50

Lou, Brandon, Mallory Parker, and Eleftheria Roumeli. "Effects of pyrolysis temperature of macroalgal biomass on the structure and mechanical properties of produced biochar." BioResources 20, no. 2 (2025): 4152–73. https://doi.org/10.15376/biores.20.2.4152-4173.

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Biochars, produced via pyrolysis, are gaining attention in applications ranging from soil amendments to energy storage and environmental remediation. While lignocellulosic biochars from woody biomass are well studied, algal biochars remain comparatively overlooked despite offering diverse organic and inorganic content that may broaden their applications. This study investigates how pyrolysis temperature and oxidative pretreatment affect the structure and properties of biochars derived from two macroalgae, Ulva expansa and Sargassum sp., under various pyrolysis conditions (500 to 900 °C). Using
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