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Dissertations / Theses on the topic 'Quinoline Complexes'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Stringer, Tameryn. "Development of quinoline and non-quinoline based organometallic complexes and their ligands conjugated to polyamine scaffolds as pharmacological agents." Doctoral thesis, University of Cape Town, 2014. http://hdl.handle.net/11427/9542.

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Includes bibliographical references.<br>Malaria remains a major global health problem and to date, hundreds of thousands of people die as a result of this disease every year. Malaria has been able to adapt and rebound despite various efforts made to combat the disease. The decrease in efficacy of many front-line drugs against malaria, due to increased resistance, prompts investigation into obtaining effective compounds that are able to overcome this resistance. This study investigated the synthesis, characterisation and biological evaluation of new quinoline as well as non-quinoline based comp

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2

Parkes, Louise Francesca. "Luminescent transition metal complexes of terdentate quinoline-based ligands for light-emitting devices." Thesis, Durham University, 2012. http://etheses.dur.ac.uk/3461/.

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Luminescent transition metal complexes are of interest due to their applications in areas such as organic light-emitting devices (OLEDs), solar cells and biological probes and sensors. The use of heavy transition metals promotes phosphorescent emission from the triplet state. In OLEDs, this enables the quantum efficiency of devices to reach a theoretical maximum of 100 % through harvesting photons from both singlet and triplet excited states. The synthesis of cyclometallated N^C^N-coordinated iridium(III) complexes and two representative rhodium(III) analogues, based upon a series of isomeric

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3

Melis, Diana. "Quinoline-triazole half-sandwich iridium(III) complexes: Synthesis, antiplasmodial activity and preliminary transfer hydrogenation studies." Master's thesis, Faculty of Science, 2020. http://hdl.handle.net/11427/32414.

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Malaria is a devastating and pervasive infectious disease and continues to be a major global health issue, with over half the world's population being at risk of transmission. In the absence of a suitable vaccine, efforts to eradicate the disease rely heavily on clinically available drugs. Plasmodium falciparum, the deadliest species of malaria, has however become resistant to most conventional antimalarial treatments, resulting in the worldwide search for new, effective drugs. Amongst other requirements, these drugs should target resistant parasitic strains in an attempt to curb the escalatio

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4

Knight, Cheryl Lynn. "Application of IR and NMR spectroscopy to certain complexes of 8-hydroxyquinoline and 8-aminoquinoline." Master's thesis, University of Cape Town, 1987. http://hdl.handle.net/11427/22001.

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The IR spectra of twenty-one transition metal complexes of 8-hydroxyquinoline over the range 700 - 50 cm⁻¹ are discussed in relation to their known or inferred structures. The complexes are of three types: (a) the bis(aquo) complexes of the first row transition metal(II) ions, [M(ox)₂(H₂O)₂] (M =Mn, Fe, Co, Ni, Cu, Zn); (b) the corresponding anhydrous complexes, [M(ox)₂]n (M=Mn, Co, Ni, Cu, Zn) and (c) the complexes of the metal(III) ions, [M(ox)₃] (M = Sc, V, Cr, Mn, Fe, Co, Ga, Rh and In). Deuterated 8-hydroxyquinoline was. synthesized by the Skraup synthesis and has been used to assist in t

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5

Abdel-Rahman, Obadah S. [Verfasser]. "Biphenyl- and Carbazole-Bridged Di- and Trinuclear Alkenyl-Ruthenium Complexes and Mononuclear Alkenyl Complexes with Pyridine- and Quinoline-Derived Bidentate Coligands / Obadah S. Abdel-Rahman." Konstanz : Bibliothek der Universität Konstanz, 2015. http://d-nb.info/1148942327/34.

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6

Mannsperger, Johannes [Verfasser], and Sonja [Akademischer Betreuer] Herres-Pawlis. "New hybrid guanidine-quinoline copper complexes and their use in atom transfer radical polymerization / Johannes Mannsperger ; Betreuer: Sonja Herres-Pawlis." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2018. http://d-nb.info/1210861674/34.

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7

Das, Hari Sankar [Verfasser], and Biprajit [Akademischer Betreuer] Sarkar. "Ruthenium complexes with non-innocent quinonoid, quinoline-5,8-dione and iminoquinone ligands : synthesis, structure, redox properties and electron distribution / Hari Sankar Das. Betreuer: Biprajit Sarkar." Stuttgart : Universitätsbibliothek der Universität Stuttgart, 2012. http://d-nb.info/102604331X/34.

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8

Benaissa, Tahar. "Synthèse de ligands contenant un atome de fluor et pouvant donner des complexes à applications médicales : étude de la complexation de la 5-fluoro-8-hydroxyquinoline avec des cations métalliques, par RMN du fluor." Université Joseph Fourier (Grenoble), 1996. http://www.theses.fr/1996GRE10100.

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Ce travail se place a la convergence de deux grands themes etudies au laboratoire: le marquage de molecules par un atome de fluor et l'etude de la complexation de cations metalliques par des ligands. La premiere partie concerne la preparation de deux series de ligands contenant du fluor: des biphenols et des composes contenant des groupements 2-fluoropyridines. Les biphenols substitues par deux ou quatre atomes de fluor (en position 4,4' ; 5,5' ; 4,4 ;,5,5') ont ete obtenus a partir de bromophenols par une reaction de type ullman. Leurs derives sulfones ont egalement ete prepares pour augmente

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9

Marty-Tommasi, Laurence. "Modélisation du centre actif de métalloprotéines à fer non hème. Complexes du fer avec des analogues de PQQ et des ligands à donneurs soufre et N-imidazole." Toulouse 3, 1995. http://www.theses.fr/1995TOU30022.

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La premiere partie de ce travail concerne la synthese et l'etude des proprietes de quatre complexes du fer. Ils sont constitues d'analogues de synthese du pqq (pyrroloquinoleine quinone), dont deux sont sous forme reduite et un sous forme orthoquinonique. Les etudes par spectroscopie infrarouge, mossbauer et susceptibilite magnetique des quatre complexes, ont mis en evidence differentes nuclearites dependant de la stoechiometrie fe/l et du ph de la reaction. Trois sont caracterises par un rapport fe/2l (deux mononucleaires et un polynucleaire). Le quatrieme complexe dont la determination de la

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10

Junior, Evanildo Gomes Lacerda. "Estudos Teóricos de Misturas Álcool-Água e Seus Efeitos em Propriedades Eletrônicas em um Derivado de Quinolina." Universidade de São Paulo, 2013. http://www.teses.usp.br/teses/disponiveis/43/43134/tde-26112013-185523/.

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Neste trabalho usamos simulações computacionais para estudar inicialmente a estrutura das redes de ligação de hidrogênio (HB) formadas pelas misturas de metanol--água e 1-propanol--água e em seguida como essas misturas afetam as propriedades eletrônicas da sonda solvatocrômica 1-metilquinolin-8-olato (QB). Para a primeira parte fizemos uso do formalismo de redes complexas na análise das redes de HB formadas nas misturas. Com essa abordagem foi possível verificar o comportamento do sistema como um todo em diferentes concentrações de água nas misturas por meio do cálculo de diversas propriedad

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11

Luci, Luisa. "Synthesis of heteroleptic Cu(I) complexes based on quinolin-yl-1H-1,2,3-triazole." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2018. http://amslaurea.unibo.it/16659/.

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In this work, three mononuclear and five binuclear heteroleptic copper(I) complexes based on quinolin-yl-1H-1,2,3-triazole as diimine chelating ligand and DPEPhos as chelating diphosphine were successful synthesised, these compounds may be good alternative to more expensive photosensitizer based on ruthenium complexes. They show good absorption in visible region and good luminescence in solution at room temperature with long-lived excited states. The most promising complexes, which show adequate photophysical characteristics, such as high PLQY and long-lived luminescence lifetimes will be used

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12

Tokoro, Yuichiro. "Synthesis of Boron and Sillicon Complexes Coordinated with Quinolate-Type Ligands." 京都大学 (Kyoto University), 2013. http://hdl.handle.net/2433/174962.

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13

ARTIZZU, FLAVIA. "Near-Infrared Luminescent Lanthanide Complexes of Quinolinol Ligands: Structure/Properties Relationship." Doctoral thesis, Università degli Studi di Cagliari, 2008. http://hdl.handle.net/11584/265938.

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The synthesis and the characterisation of lanthanide complexes with quinolinolato ligands, a class of complexes proposed as near-infrared emitters for several optical applications, with a full investigation of the structure/property relationship, valuable for a reliable interpretation of their photo-physical properties, are described in this thesis. This work has been addressed to a detailed investigation of the proper synthetic procedures useful to prepare pure products suitable for structural, spectroscopic and photo-physical studies. Several types of lanthanide quinolinolates have been ide

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14

Primault, Gaëlle. "Substitution nucléophile benzylique d'esters hétéroaromatiques catalysée par des complexes de palladium(0) : synthèse des substrats et étude de leur réactivité." Paris 11, 2002. http://www.theses.fr/2002PA112126.

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Cette thèse concerne la substitution nucléophile benzylique d'esters hétéroaromatiques catalysée par des complexes de palladium(0). La première partie est consacrée à l'étude de la réactivité de substrats appauvris en électrons que sont les acétates de 1-(quinolyl)éthyle et les acétates de 1-isoquinolyl)éthyle. Ces acétates secondaires ont été préparés par réduction puis acétylation des cétones correspondantes. Ces dernières sont obtenues à partir des dérivés halogénés ou des triflates par des réactions catalysées par le palladium : couplage de Stille, couplage de Negishi, couplage avec le tri

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15

Barchi, Tobia. "Synthesis and characterization of heteroleptic Cu(I) complexes based on quinolin-yl-1,2,3-triazole and pyridin-yl-1,2,3 triazole." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2020. http://amslaurea.unibo.it/20680/.

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The present work is part of a research project that involves the study of new copper based complexes to be employed as photosensitizer in carbon dioxide photoreduction reaction. My research project is focused on the synthesis and characterization of 1,2,3 triazoles with a quinoline or pyridine in the lateral chain, which have been successively utilized to synthesize heteroleptic Cu(I) complexes. Redox potential and photophysic properties have been studied.

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16

Fochesatto, Cíntia. "Caracterização química e avaliação in vitro da atividade antimicrobiana de complexos de 99m Tc-ciprofloxacino e 99m Tc-pefloxacino." reponame:Biblioteca Digital de Teses e Dissertações da UFRGS, 2008. http://hdl.handle.net/10183/13156.

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A diferenciação entre processos infecciosos e inflamatórios representa um grande desafio na área de diagnóstico. A complexação do antimicrobiano ciprofloxacino (CIP) com o tecnécio (99mTc-CIP) vem sendo estudada com objetivo de desenvolver um radiofármaco com alta especificidade no diagnóstico de infecções, baseado em seu amplo espectro de atividade antibacteriana. O mecanismo de ação do fármaco consiste na ligação deste com a enzima ADN-girase da bactéria, permitindo sua ligação à bactéria ativa e a obtenção de imagens devido a fótons emitidos pelo 99mTc. Tendo em vista que o local de formaçã

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17

Thomas, Fabrice. "Complexation du fer par des ligands tripodes originaux et la calcéine : étude thermodynamique, cinétique et biologique." Université Joseph Fourier (Grenoble), 1999. http://www.theses.fr/1999GRE10108.

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L'etude thermodynamique, cinetique et biologique des ligands du fer est primordiale pour concevoir de nouveaux medicaments, des outils agronomiques ou des outils physiologiques. La premiere partie concerne l'etude de ligands tripodes possedant des sous unites catechol (trencams), 8-hydroxyquinoleine + catechol (trensoxcams 2) et pyridinophenol (trenpypols). La caracterisation des ligands et complexes ferriques a permis de mettre en evidence que le trencams est un fort complexant de fe i i i a ph 7,4 (pfe i i i = 29,6) mais tres labile ; il ne complexe pas fe i i. Le ligand mixte trensoxcams2 e

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18

Boukhalfa, Hakim. "Complexation du fer par des ligands tripodes à base de sous-unités 8-hydroxyquinoléine et 2,2'dihydroxybiphényle : aspects thermodynamiques et cinétiques." Université Joseph Fourier (Grenoble), 1996. http://www.theses.fr/1996GRE10250.

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Ce travail concerne des etudes thermodynamiques et cinetiques de la complexation du fer(iii) par des ligands possedant des sites de coordination de type 8-hydroxyquinoleine et 2,2'-dihydroxybiphenyle. La premiere partie a concerne l'etude des complexes ferriques des ligands 8-hq (oxine), 5-so#3#, 8-hq (sulfoxine) et 5-f-8-hq (fluorooxine). Les resultats mettent en evidence l'influence des proprietes electroniques des sites de coordination sur la stabilite des complexes. Quand la coordination du fer par le ligand n'est pas complete, des hydroxo complexes sont formes. Les etudes cinetiques de fo

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19

Benelhadj, Karima. "Synthèse et propriétés optiques de fluorophores à squelette iminophénol : transfert de proton à l'état excité et complexes de bore (III)." Thesis, Strasbourg, 2015. http://www.theses.fr/2015STRAF060/document.

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Les travaux de cette thèse portent sur l'élaboration et l'étude de sondes fluorescentes construites autour d'un squelette iminophénol, permettant ainsi d'accéder à un panel de composés absorbants et émettant sur une large gamme spectrale {UV, visible, proche infrarouge) et présentant des propriétés optiques remarquables : des coefficients d'absorption importants,des rendements quantiques élevés et de grands déplacements de Stockes. Des voies synthétiques simples et efficaces ont permis la constitution d'un catalogue de fluorophores modulables sur une large gamme du spectre électromagnétique. E

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20

Zheve, Georgina Teurai. "Neuroprotective mechanisms of nevirapine and efavirenz in a model of neurodegeneration." Thesis, Rhodes University, 2008. http://hdl.handle.net/10962/d1003285.

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AIDS Dementia Complex (ADC) is a neurodegenerative disorder implicated in HIV-1 infection that is associated with elevated levels of the neurotoxin, quinolinic acid (QA) which causes a cascade of events to occur, leading to the production of reactive oxygen species (ROS), these being ultimately responsible for oxidative neurotoxicity. In clinical studies, Non-nucleoside reverse transcriptase inhibitors (NNRTIs), efavirenz (EFV) and nevirapine (NVP) have been shown to potentially delay the progressive degeneration of neurons, thus reducing the frequency and neurological deficits associated with

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21

Imbert, Daniel. "Nouveaux ligands à charpente tripodale carbonée en vue de la complexation du fer en milieu hydrophile ou lipophile." Université Joseph Fourier (Grenoble), 2000. http://www.theses.fr/2000GRE10112.

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De nouveaux ligands tripodaux possedant deux types de sous-unites chelatantes (8-hydroxyquinoleine et catechol) ont ete prepares. Pour ce faire, un nouvel espaceur tripodal comportant un motif tris (aminopropyl)methane diversement fonctionnalise a ete developpe, permettant le greffage de ces sous-unites par des liaisons de type amide. Les complexes de fer correspondants ont ete prepares et caracterises par spectrometrie de masse et spectrophotometrie uv-visible. Des etudes physico-chimiques ont permis de determiner les caracteristiques thermodynamiques en solution aqueuse (constantes d'acidite

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22

Wu, Cai-Ling, and 吳采伶. "Synthesis of Transition Metal Complexes Containing a Pyrazolyl Quinoline Ligand and Catalytic Activity Study." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/73346488041133236954.

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碩士<br>國立臺灣大學<br>化學研究所<br>104<br>Complexation of 2‐pyrazolyl‐8‐hydroxyquinoline(4) with PdCl2 and PtCl2 afforded pincer complexes [(4)PdCl](5) and [(4)PtCl](7). The obtained complexes are stabilized through the chelation of the pincer ligand. The solubility of both complexes is poor. Replacement of chloride by acetonitrile through anion exchange gave complexes in ionic forms [(4)Pd(MeCN)]PF6(6) and [(4)Pt(MeCN)]PF6(8). The solubility of 6 and 8 improves quite a lot. Reaction of 4 with Ru(CO)3Cl2(THF) provided [(4)Ru(CO)2Cl](9). Complexes [(4)Ru(CO)2(MeCN)]PF6 (10) and [(4)Ru(CO)2(DMSO)]PF6(11)

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23

Pan, Sheng-Ming, and 潘勝明. "The Synthesis and Characterization of Quinoline-Metallic Complexes and Study Material for Military Sensor." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/16855261054407127097.

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博士<br>國防大學理工學院<br>國防科學研究所<br>99<br>ABSTRACT In this study, 8-hydroxyquinoline and three metals (such as Al3+, Fe3+ and Mg2+) is applied to prepare fluorescent organic metal complex, tris (8-hydroxyquinoline) aluminum, tris (8-hydroxyquinoline) iron and bis (8-hydroxyquinoline) magnesium. The structure characteristics of these complexes were analyzed by Ultra-Violet Visible Spectroscopy (UV-Vis), Photoluminescent (PL) Fluorescent Spectrum, Fourier Transform Infrared Spectroscopy (FTIR) and Mass Spectroscopy. The measurement of fluorescence properties and thermal stability for three fluorescent

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24

"Metallation of 8-methylquinoline." Chinese University of Hong Kong, 1993. http://library.cuhk.edu.hk/record=b5887206.

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by Lawrence Tin-chi Law.<br>Thesis (M.Phil.)--Chinese University of Hong Kong, 1993.<br>Includes bibliographical references (leaves 96).<br>acknowledgements --- p.iii<br>ABSTRACT --- p.iv<br>CONTENTS --- p.v<br>ABBREVIATION --- p.vii<br>Chapter CHAPTER I --- METALLATION OF 8-METHYLQUINOLINE<br>Chapter 1.1 --- INTRODUCTION --- p.1<br>Chapter 1.1.1 --- A Brief Review of Metal-Alkyl Chemistry --- p.1<br>Chapter 1.1.2 --- General Considerations --- p.2<br>Chapter 1.1.3 --- 8-Methylquinoline as Ligand Precursor --- p.8<br>Chapter 1.1.4 --- Metallations by Organolithium Compounds --- p.9<b

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25

Padilla, Esther M. "Synthesis, characterization, and structure-bonding relationships of palladium mu-thiolato and 2-quinoline thione complexes." Thesis, 1991. http://hdl.handle.net/10125/9501.

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26

Palardy, Marc. "Complexes mono-oxo de rhénium(V) avec des ligands dérivés de la quinoline et de la cystéine." Thèse, 2007. http://hdl.handle.net/1866/17990.

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27

Wu, Jian-Lin, and 吳建霖. "Quinoline and Isoquinoline Derivatives as Red and Green Phosphorescent Iridium Complexes and Their Application in Organic Electroluminescent Devices." Thesis, 2009. http://ndltd.ncl.edu.tw/handle/92436570960687309743.

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博士<br>國立清華大學<br>化學系<br>97<br>Abstract The thesis includes three parts that focuses on synthesizing various red and green phosphorescent iridium complexes. In the first part, the alkenylquinoline and alkenylisoquinoline derivatives were prepared by two different procedures. The iridium(III) complex cyclometalated with alkenylquinoline or alkenylisoquinoline ligangs as red-light emitters for OLED application. Those complexes show deep red phosphorescent emissions. The optimed device structure is NPB(10nm)/TCTA(20nm)/Dopants(5%):CBP(or o-CzOXD)(30nm)/BCP (10nm)/Alq(50nm)/LiF(1nm)/Al(100nm). When

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Horta, Pedro Filipe Castela. "Design and synthesis of novel quinolones directed to the Plasmodium falciparum bc1 protein complex." Doctoral thesis, 2016. http://hdl.handle.net/10400.1/8685.

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Tese de Doutoramento, Química, Especialização em Química Orgânica, Faculdade de Ciências e Tecnologia, Universidade do Algarve, 2016<br>Apesar dos intensos esforços para controlo da malária, esta doença parasítica milenar permanece como uma das doenças infeciosas conducentes a maiores taxas de mortalidade no mundo. É transmitida pela picada de um mosquito infectado do género Anopheles (apenas a fémea transmite a doença) e causada por um parasita do género Plasmodium. P. falciparum é a mais prevalente de entre as cinco estirpes de Plasmodium que afectam o homem e é também a mais mortal, sendo r

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Henderson, Morgan. "DNA-Protein Complexes Created by Mutant EcoRII Methyltransferase and Quinolone Antibiotics in Escherichia coli." Diss., 2014. http://hdl.handle.net/10161/8713.

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<p>Expression of mutant M.EcoRII protein (M.EcoRII-C186A) in Escherichia coli leads to tightly bound DNA-protein complexes (TBCs), located sporadically on the chromosome rather than in tandem arrays. The mechanisms behind the lethality induced by such sporadic TBCs are not well studied, nor is it clear whether very tight binding but non-covalent complexes are processed in the same way as covalent DNA-protein crosslinks (DPCs). Using 2D gel electrophoresis, we found that TBCs induced by M.EcoRII-C186A block replication forks in vivo. Specific bubble molecules were detected as spots on the 2D ge

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Jhong, Hong-Ming, and 鐘宏明. "Synthesis and Catalytic Application of Palladium Complexes with a Pyridinyl- Quinolinone Ligand." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/32700655572675277846.

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碩士<br>國立臺灣大學<br>化學研究所<br>104<br>The main work of this thesis involves the synthesis and application of palladium complexes with a pyridinyl-quinolinone ligand. Nucleophilic substitution of 2-(bromo-methyl)pyridine with 2-chloroquinolin-8-ol under basic conditions provided 2-chloro-8-(pyridin-2-ylmethoxy)quinoline, which was further hydrolyzed in acetic acid to yield the desired ligand, 8-(pyridin-2-ylmethoxy)quinolin-2(1H)-one (6). Complexation of 6 with (CH3CN)2PdCl2 gave the corresponding complex 7. The structure of 7 was characterized by 1H /13C NMR and mass spectroscopic methods, and furt

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Correia, Raquel Cristina Barão. "Complexos de cobre dirigidos a G-quadruplex para teranóstica de cancro." Master's thesis, 2016. http://hdl.handle.net/10451/27682.

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Tese de mestrado, Química Farmacêutica e Terapêutica, Universidade de Lisboa, Faculdade de Farmácia, 2016<br>Atualmente, é bem reconhecido que a inibição da telomerase pode impedir a proliferação celular, sendo por isso um alvo relevante para novas terapias anticancerígenas. Uma das possíveis estratégias para inibir a actividade da telomerase baseia-se no uso de compostos que se ligam selectivamente a estruturas de ADN do tipo G-quadruplexo (G4 de ADN). As indolo[3,2-c]quinolinas (IQc) são uma de entre muitas classes de compostos que têm vindo a ser estudadas como potenciais estabilizadores de

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Zheve, Georgina Teurai. "Neuroprotective mechanisms of nevirapine and efavirenz in a model of neurodegeneration /." 2007. http://eprints.ru.ac.za/1350/.

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