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Dissertations / Theses on the topic 'Quinoline N -oxide complexes'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Chu, Tsun-tung. "Biomimetic reactions of nitric oxide synthase study of the reactions of n-substituted-N'-hydroxyguanidines with metalloporphyrin and non-heme complexes /." Click to view the E-thesis via HKUTO, 2007. http://sunzi.lib.hku.hk/hkuto/record/B39634097.

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Chu, Tsun-tung, and 朱俊東. "Biomimetic reactions of nitric oxide synthase: study of the reactions of n-substituted-N'-hydroxyguanidines with metalloporphyrin and non-heme complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2007. http://hub.hku.hk/bib/B39634097.

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3

Lima, Renata Galvão de. "Reatividade química e fotoquímica de complexos nitrosilos de rutênio do tipo [Ru(terpy)(L)NO]n+." Universidade de São Paulo, 2006. http://www.teses.usp.br/teses/disponiveis/59/59138/tde-26052009-170459/.

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O óxido nítrico (NO) é um mensageiro biológico que tem vital importância em muitos processos fisiológicos, tais como o controle cardiovascular, a sinalização neural e a defesa contra microorganismos e tumores. Sua natureza radicalar lhe confere grande reatividade e versatilidade e torna um desafio o entendimento de sua bioquímica. A molécula de NO reage rapidamente com alguns metais de transição e forma compostos estáveis denominados complexos nitrosilos, os quais podem ser utilizados como fonte geradora de óxido nítrico. Neste caso, faz-se necessário o entendimento do comportamento físico-quí

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4

Fantin, Creusa Aparecida. "Síntese e caracterização dos compostos de adição entre os mono e dicloroacetatos de lantanídeos (III) e a quinolina-N-óxido (QNO)." Universidade de São Paulo, 2003. http://www.teses.usp.br/teses/disponiveis/46/46134/tde-14032018-115520/.

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Este trabalho descreve a síntese e caracterização dos compostos de adição obtidos pela reação entre os monocloroacetatos (CA) e dicloroacetatos (DCA) de lantanídeos (III) com a quinolina-N-óxido (QNO), na presença de etanol e ortoformiato de trietila. Os compostos foram obtidos na forma sólida e caracterizados por análise elementar, testes de solubilidade, medidas de condutância eletrolítica, difração de raios X (método do pó), espectros de absorção na região do infravermelho, espectros de absorção na região do visível dos compostos de Nd, espectros de emissão dos compostos de Eu e análise tér

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Kupper, Claudia Gisela. "Electronic Structure and Reactivity of Bioinspired Organometallic Iron Complexes Relevant to Small Molecule Activation." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2017. http://hdl.handle.net/11858/00-1735-0000-0023-3E79-1.

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6

Shen, Jingyi. "Density functional theory study on the interstitial chemical shifts of main-group-element centered hexazirconium halide clusters; synthetic control of speciation in [(Zr6ZCl12)] (Z = B, C)-based mixed ligand complexes." Diss., Texas A&M University, 2003. http://hdl.handle.net/1969.1/2444.

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The correlation between NMR chemical shifts of interstitial atoms and electronic structures of boron- and carbon-centered hexazirconium halide clusters was investigated by density functional theory (DFT) calculation. The influences of bridging halide and terminal ligand variations on electronic structure were examined respectively. Inverse proportionality was found between the chemical shifts and the calculated energy gaps between two Kohn-Sham orbitals of t1u symmetry, which arose from the bonding and antibonding interaction between the zirconium cage bonding orbitals and the interstitial 2

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7

周彥甫. "Synthesis, Characterization and Nitric Oxide Reactivity of N/O–polydentate Nickel Complexes." Thesis, 2013. http://ndltd.ncl.edu.tw/handle/66893448070339325494.

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8

Rong, Dawen, Victoria A. Phillips, R. S. Rubio, Castro M. Angeles, and Richard T. Wheelhouse. "A safe, convenient and efficient method for the preparation of heterocyclic N-oxides using urea-hydrogen peroxide." 2008. http://hdl.handle.net/10454/6160.

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A novel, convenient, and high-yielding method has been developed for the preparation of heterocyclic N-oxides. The reaction uses the urea·hydrogen peroxide addition complex as a peroxide source for the in situ generation of trifluoroperacetic acid. The advantages of this method are easy handling of a stable, solid oxidant; high yields and simple removal of excess reagents and by-products.

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9

Hess, Jennifer. "Bioinspired Synthesis and Reactivity Studies of Nitric Oxide Iron Complexes." Thesis, 2011. http://hdl.handle.net/1969.1/ETD-TAMU-2011-12-10258.

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The significant role that nitric oxide plays in human physiology is linked to the ability of NO to bind to iron forming mono-nitrosyl iron complexes. Protein-bound and low-molecular-weight dinitrosyl iron complexes (DNICs) are known to form in excess NO. Studies of such biological DNICs have relied on their paramagnetism and characteristic EPR signal of g value of 2.03. It has been suggested that DNICs act in vivo as NO storage (when protein-bound) and transfer agents (when released by, for example, free cysteine). Biological DNICs, mainly resulting from iron-sulfur cluster degradation, ar

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10

沈奕伶. "Six-coordinated, Nitric oxide Cobalt N-confused Porphyrin Complexes and Cocrystallization of Cobalt N-confused Porphyrin with [60]Fullerene." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/30839166322692584025.

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碩士<br>國立彰化師範大學<br>化學系<br>94<br>Abstract In the derivatives of the porphyrin system, N-confused porphyrin(NCP) has attracted extensive attention in recent years. In this thesis, we prepared a series of cobalt complexes of N-confused porphyrin and devided the results into four parts including synthesis and oxidation reaction of four coordinated N-confused porphyrin cobalt complex, preparation of six-coordinated cobalt complexes, preparation of nitrosylated cobalt NCP complexes and cocrystallization of cobalt NCP complex with fullerene. We confirmed that four coordinated and planar starting Co(HC

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11

Lin, Wen-Chain, and 林文茜. "Metal Complexes of 2-N substituted N-confused Porphyrin: PartⅠ:Comparism of iminiun ion pairs type between 2-NCH2CH2CH2OC6H5NCTPPH and Ni(2-NCH2CH2CH2OC6H5NCTPP)PartⅡ: Molecular structures of Cu(Ⅱ), Rh(Ⅲ) complexes of 2-N substituted N-confused porphyrin inner C-oxide." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/94z2w3.

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碩士<br>國立中興大學<br>化學系所<br>100<br>We use 3-phenoxypropyl bromide as alkylation reagent to react with N-confused porphyrin to get 2-aza-2-(3’-phenoxypropyl)-5,10,15,20- tetraphenyl N-confused porphyrin，2-NCH2CH2CH2-O-C6H5NCTPPH (2)。And we use Ni(OAc)2、Cu(OAc)2 to react separately with 2-NCH2CH2CH2-O-C6H5NCTPPH (2) to get two different complexes，Ni(2-NCH2CH2CH2OC6H5NCTPP) (3) and Cu(2-NCH2CH2CH2OC6H5NCTPPO)(4). Then we use X-ray Single-Crystal Diffeactometer、NMR spectroscopy and EPR spectroscopy，etc.，to determine the crtstal structure of complexes and to compare and analyze the molecular characteri

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12

Wu, Cheng-En, and 吳承恩. "Investigation of Heck Reaction by Employing Palladium Complexes Having Metal-Containing P-N Ligands and Phosphine Oxide Ligand." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/49436707384534273528.

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13

Feng, Li-Ting, and 馮立婷. "Exploring the transforming mechanism of nitric oxide donors in vitro cell cultures and Toward understanding the nitric oxide reaction on methylated iron N-confused porphyrin complexes." Thesis, 2007. http://ndltd.ncl.edu.tw/handle/vc3bnz.

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碩士<br>國立彰化師範大學<br>化學系<br>95<br>Nitric oxide, NO, has been recognized as an important biological molecule. Dinitrosyl Iron Complex (DNIC) and nitrite are suggested to behave as NO storage and transporting molecules in biological system. Several well-known iron-sulfur cluster nitrosyl complex, such as Roussin’s black salt (RBS), Roussin’s red salt (RRS) and Roussin’s red ester (RRE), have been chemically synthesized in vitro. In this thesis we use two chemically synthesized, water-soluble Roussin’s red ester [(NO)2Fe(µ-SCH2COOH)2Fe(NO)2] and {Fe(NO)2}10 DNIC [(NO)2Fe(P(C6H5)2(C6H4SO3Na))2] to st

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14

"Part 1, Arene oxidation with 2,6-dichloropyridine N-oxide catalyzed by ruthenium porphyrins: Part 2, Imine complexes of ruthenium and manganese with acyclic tetradentate N₂O₂-donors as oxidation catalysts for styrene oxidation." 1998. http://library.cuhk.edu.hk/record=b5889841.

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by Lo Tim Lun.<br>Thesis (M.Phil.)--Chinese University of Hong Kong, 1998.<br>Includes bibliographical references (leaves 68-71).<br>Abstract also in Chinese.<br>Acknowledgments --- p.i<br>Abstract --- p.ii<br>Abbreviations --- p.iii<br>Table of Contents --- p.iv<br>Chapter Part 1. --- "Arene Oxidation with 2,6-Dichloropyridine- N-oxide Catalyzed by Ruthenium Porphyrins" --- p.1<br>Chapter 1. --- Introduction --- p.1<br>Chapter 1.1 --- Natural Occurrence of Cytochrome P-450 --- p.1<br>Chapter 1.2 --- Biomimetic Models of Cytochromes of P-450 --- p.4<br>Chapter 1.3 --- Homogenous Metal

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15

Yang, Meng-Hua, and 楊孟樺. "Synthesis and Characterization of Transition Metal(Ni, Co, Cu) Complexes Supported by S,N,O-Schiff Base Ligands for Reaction of Cyclohexene Oxide with Carbon Dioxide." Thesis, 2019. http://ndltd.ncl.edu.tw/handle/355eu8.

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碩士<br>國立中興大學<br>化學系所<br>107<br>A series of novel transition metal (Ni, Co, Cu) complexes bearing S,N,O-tridentate Schiff–base ligands have been synthesized with respect to various electronic and steric effect. The results of one-pot CHO/CO2 reaction carried out with ligand precusors and transition metals infer the active species in the reaction. The composition of complexes has been characterized by elemental analysis, FT-IR and EPR spectroscopy. Their physical properties were investigated using the melting point analyzer and UV/Vis spectroscopy. X-ray diffraction studies of the complex (1

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16

Cibian, Mihaela. "Des complexes métalliques avec des ligands hydroxyamidines/ amidines oxydes (AMOXs) : synthèse, caractérisation et investigation de leurs applications." Thèse, 2015. http://hdl.handle.net/1866/18431.

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The English translation of the chapters written in French is available in Appendix.<br>La motivation initiale de ce travail provient de l'importance que les composés de coordination ont dans notre vie quotidienne. Leurs propriétés les rendent attrayants pour un large éventail d'applications, dans des domaines allant de la catalyse et de la conversion et stockage de l'énergie solaire jusqu’au domaine des matériaux et des sciences de la vie. Poussée par l'évolution et le progrès général de notre société, la recherche en chimie de coordination moderne évolue vers la complexité au niveau moléculai

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