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Dissertations / Theses on the topic 'Rate constanta'

Author: Grafiati
Published: 4 June 2021
Last updated: 5 February 2022

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1

Mahon, Peter John, and mikewood@deakin edu au. "The determination of rate constants using microelectrodes." Deakin University. School of Science, 1992. http://tux.lib.deakin.edu.au./adt-VDU/public/adt-VDU20050728.090033.

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An understanding of the rate and the mechanism of reaction is of fundamental importance in the many facets of chemistry. Electrochemical systems are further complicated by the heterogeneous boundary, between the solution and the electrode, that the electron passes through before any electrochemical reaction can take place. This thesis concerns the development of methods for analysing electrode kinetics. One part involves the further development of the Global Analysis procedure to include electrodes with a spherical geometry which are traditionally the most popular form of electrodes. Simulated
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2

Saw, Yoo-Sok. "Nonlinear rate control techniques for constant bit rate MPEG video coders." Thesis, University of Edinburgh, 1997. http://hdl.handle.net/1842/1381.

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Digital visual communication has been increasingly adopted as an efficient new medium in a variety of different fields; multi-media computers, digital televisions, telecommunications, etc. Exchange of visual information between remote sites requires that digital video is encoded by compressing the amount of data and transmitting it through specified network connections. The compression and transmission of digital video is an amalgamation of statistical data coding processes, which aims at efficient exchange of visual information without technical barriers due to different standards, services,
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3

Howell, Leonard L. "An experimental analysis of rate constancy." Diss., Georgia Institute of Technology, 1985. http://hdl.handle.net/1853/29865.

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4

Bensaci, Abderrahmane. "Etude par RMN du sélénium 77 et du tellure 125 de la cinétique d'échange de dichalcogénures aromatiques." Rouen, 1987. http://www.theses.fr/1987ROUES008.

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5

Bijlsma, Sabina. "Estimating rate constants of chemical reactions using spectroscopy." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2000. http://dare.uva.nl/document/81947.

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6

SUPO, KATHIA CECILIA LOPEZ. "DEVELOPMENT OF A CONSTANT RATE OF FLOW FIELD PERMEAMETER." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2008. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=13449@1.

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PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO<br>COORDENAÇÃO DE APERFEIÇOAMENTO DO PESSOAL DE ENSINO SUPERIOR<br>presente dissertação descreve o desenvolvimento de um equipamento destinado a determinar a condutividade hidráulica de meios porosos saturados in situ. O permeâmetro consiste em uma sonda que emprega o método da vazão constante. Após sua inserção pelo modo de cravação. Uma bomba de seringa instalada na superfície do terreno é utilizada para aplicar uma vazão constante enquanto que a carga hidráulica induzida no meio é medida através de um transdutor de pressão piezoresistivo in
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7

Lee, Yew Choong Patrick 1975. "Numerical modeling of constant rate of strain consolidation tests." Thesis, Massachusetts Institute of Technology, 2003. http://hdl.handle.net/1721.1/29564.

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Thesis (M.Eng.)--Massachusetts Institute of Technology, Dept. of Civil and Environmental Engineering, 2003.<br>Includes bibliographical references (leaves 95-96).<br>Constant Rate of Strain Consolidation Testing (CRSC) is an effective testing method to determine cohesive soil properties including stress history, compressibility, hydraulic conductivity and coefficient of consolidation. However, testing at varying strain rates have resulted in inconsistent results with respect to expected soil behavior. This theoretical study develops at numerical model to simulate the important details of a CRS
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8

Tao, Jianping. "PULSE SHAPED CONSTANT ENVELOPE 8-PSK MODULATION STUDY." International Foundation for Telemetering, 1997. http://hdl.handle.net/10150/609753.

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International Telemetering Conference Proceedings / October 27-30, 1997 / Riviera Hotel and Convention Center, Las Vegas, Nevada<br>The most bandwidth-efficient communication methods are imperative to cope with the congested frequency bands. Pulse Shaping methods have excellent effects on narrowing bandwidth and increasing band utilization. The position of the baseband filters for the pulse shaping is crucial. Filters after the modulator will have non-constant envelope and before the modulator will have constant envelope. These two types have different effects on narrowing the bandwidth and pr
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9

McIntyre, Dennis O. "The effect of temperature on uptake rate constants, depuration rate constants, and bioconcentration factors (BCF) for six organochlorines in the aquatic insect, Chironomus riparius /." The Ohio State University, 1988. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487596807823978.

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10

Hariharakumar, Pradeep. "Constant displacement rate experiments and constitutive modeling of asphalt mixtures." Texas A&M University, 2004. http://hdl.handle.net/1969.1/3066.

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The focus of this dissertation is on constant displacment rate experiments on asphalt concrete and on developing continuum models in a general thermo-mechanical setting which will corroborate with the experimental results. Modeling asphalt concrete and predicting its response is of great importance to the pavement industry. More than 90 percent of the US Highways uses asphalt concrete as a pavement material. Asphalt concrete exhibits nonlinear response even at small strains and the response of asphalt concrete to different types of loading is quite different. The properties of asphalt concret
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11

González, Jorge H. (Jorge Hugo) 1971. "Experimental and theoretical investigation of constant rate of strain consolidation." Thesis, Massachusetts Institute of Technology, 2000. http://hdl.handle.net/1721.1/8985.

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Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Civil and Environmental Engineering, 2000.<br>Includes bibliographical references (leaves 212-216).<br>The Constant Rate of Strain (CRS) test provides an efficient and a relatively rapid method to determine properties (stress history, compressibility, hydraulic conductivity, and rate of consolidation) of a cohesive soil and possess many advantages over the incremental oedometer test. Ease of operation and the ability to take frequent readings provides tremendous labor savings and a better definition of the compression curve. Howeve
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12

Nakamura, Hisao. "Quantum Dynamics Study on State Resolved Rate Constants in Unimolecular Reactions." 京都大学 (Kyoto University), 2000. http://hdl.handle.net/2433/181456.

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13

McCoy, Tammy Michelle. "Extension of the master sintering curve for constant heating rate modeling." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/22532.

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Thesis (Ph. D.)--Materials Science and Engineering, Georgia Institute of Technology, 2008.<br>Committee Chair: Dr. Joe K. Cochran; Committee Co-Chair: Dr. Thomas H. Sanders; Committee Member: Dr. John Elton; Committee Member: Dr. Meilin Liu; Committee Member: Dr. Robert F. Speyer.
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Berutti, Neto Renato. "Investiga??o Te?rica de Rea??es Unimoleculares da Formamida em Fase Gasosa." Universidade Federal Rural do Rio de Janeiro, 2012. https://tede.ufrrj.br/jspui/handle/jspui/2221.

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Submitted by Sandra Pereira (srpereira@ufrrj.br) on 2018-03-15T14:04:44Z No. of bitstreams: 1 2012 - Renato Berutti Neto.pdf: 4059567 bytes, checksum: 6f8cfef981af15e4298a546d0c7563dc (MD5)<br>Made available in DSpace on 2018-03-15T14:04:44Z (GMT). No. of bitstreams: 1 2012 - Renato Berutti Neto.pdf: 4059567 bytes, checksum: 6f8cfef981af15e4298a546d0c7563dc (MD5) Previous issue date: 2012-03-14<br>Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior, CAPES, Brasil.<br>This work has been performed at the Laboratory of Chemical Kinetics, located in the Chemistry Department of Universid
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Turnidge, Martin Laurence. "Vibrational energy transfer at low temperatures and the use of infrared laser excitation for trace detection." Thesis, University of Oxford, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.337427.

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16

Li, Vincent Yiu Fai. "An artificial intelligence approach to the processing of radar return signals for target detection." Thesis, University of Plymouth, 1999. http://hdl.handle.net/10026.1/2814.

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Most of the operating vessel traffic management systems experience problems, such as track loss and track swap, which may cause confusion to the traffic regulators and lead to potential hazards in the harbour operation. The reason is mainly due to the limited adaptive capabilities of the algorithms used in the detection process. The decision on whether a target is present is usually based on the magnitude of the returning echoes. Such a method has a low efficiency in discriminating between the target and clutter, especially when the signal to noise ratio is low. The performance of radar target
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17

Jönsson, Daniel. "Evaluation of Rate Constants from Protein-Ligand Interactions with Weak Affinity Chromatography." Thesis, Linnéuniversitetet, Institutionen för naturvetenskap, NV, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:lnu:diva-19974.

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The paradigm of drug discovery have been to find the strongest possible binder to the target by high-throughput screening (HTS) but high affinity interactions are related to low kinetic off rates and thus result in severe side-effects and non-approved drugs. Lead molecules working in a transient manner (KD &gt; µM) will allow for rapid off rates and possibly less side-effects. In this study the peak profile method applied to weak affinity chromatography (WAC) was evaluated as a simple way to provide the kinetics of the interaction and thereby allowing for high-throughput determinations. In the
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18

Bird, Nicholas James. "Use of the terminal rate constant in the assessment of glomerular filtration rate by clearance of injected tracers." Thesis, University of Surrey, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.436077.

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19

Boyd, Laura E. "Heterogeneous electron transfer rate constants of ferrocene/ ferrocenium in room-temperature ionic liquids /." Full text available from ProQuest UM Digital Dissertations, 2009. http://0-proquest.umi.com.umiss.lib.olemiss.edu/pqdweb?index=0&did=1913291371&SrchMode=1&sid=2&Fmt=2&VInst=PROD&VType=PQD&RQT=309&VName=PQD&TS=1278437152&clientId=22256.

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20

Short, Hayden B. "Chemically Accurate Calculations of Rate Constants of Spin Trap-Hydroxyl Radical Addition Reactions." Digital Commons @ East Tennessee State University, 2015. https://dc.etsu.edu/honors/252.

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The DMPO type spin trap 5,5-Dimethyl-1-pyrroline N-oxide (DMPO) and the exceptionally similar spin trap 2-ethoxycarbonyl-2-methyl-3,4-dihydro-2H-pyrrole-l-oxide (EMPO) are widely studied in computational and theoretical works. This particular study examines the addition reactions that both these molecules undergo with the carcinogenic hydroxyl radical. This work used a relatively new approximation method, called the correlation consistent composite approach or ccCA, for carrying out quantum mechanical calculations to give the free energies of the products and reactants of the reactions. The fr
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21

Lai, Yeh-Hung. "The constrained blister - a nearly constant strain energy release rate test for adhesives." Thesis, Virginia Tech, 1988. http://hdl.handle.net/10919/44077.

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<p>This study developed and analyzed a modification of the blister test permitting nearly constant strain energy release rate testing of adhesive bonds. The work consisted of three parts; (1) development of the testing technique to evaluate strain energy release rate and to record the time dependent nature of the fracture process, (2) numerical analysis of the constrained blister test to determine the applicability of an approximate solution for several materials, and (3) development of an. analytical technique to evaluate the strain energy release rate for relatively stiff specimens.<
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22

Yandek, Lindsay E. "MULTIPLE SUBSTRATE KINETICS OF RIBONUCLEASE P: RELATIVE RATE CONSTANT DETERMINATION THROUGH INTERNAL COMPETITION." Case Western Reserve University School of Graduate Studies / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=case1371041699.

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23

Adams, Amy Lynn. "Laboratory evaluation of the constant rate of strain and constant head techniques for measurement of the hydraulic conductivity of fine grained soils." Thesis, Massachusetts Institute of Technology, 2011. http://hdl.handle.net/1721.1/66859.

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Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Civil and Environmental Engineering, 2011.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references (p. 185-187).<br>This thesis evaluates the constant rate of strain and constant head techniques for measurement of the hydraulic conductivity of fine grained soils. A laboratory program compares hydraulic conductivity measurements made using both measurement techniques on a total of 12 specimens. Both resedimented and intact materials covering a wide range of plasticity are investigated. Specific material types
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24

Minakata, Daisuke. "Development of aqueous phase hydroxyl radical reaction rate constants predictors for advanced oxidation processes." Diss., Georgia Institute of Technology, 2010. http://hdl.handle.net/1853/37127.

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Emerging contaminants are defined as synthetic or naturally occurring chemicals or microorganisms that are not currently regulated but have the potential to enter the environment and cause adverse ecological and/or human health effects. With recent development in analytical techniques, emerging contaminants have been detected in wastewater, source water, and finished drinking water. These environmental occurrence data have raised public concern about the fate and ecological impacts of such compounds. Concerns regarding emerging contaminants and the many chemicals that are in use or producti
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Buras, Zachary J. (Zachary James). "Measuring rate constants and product branching for reactions relevant to combustion and atmospheric chemistry." Thesis, Massachusetts Institute of Technology, 2018. http://hdl.handle.net/1721.1/117862.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemical Engineering, 2018.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references (pages [383]-406).<br>Over the last century there have been countless experimental measurements of the overall reaction kinetics of gas-phase radicals, often with the aid of lasers. In more recent decades, ab initio predictions of product branching using quantum chemical calculations combined with modem rate theories have become common. However, there are few experimental measurements against which to validate predicted
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Casey, Lee S. "Kinetic rate constants for the formation of trihalomethanes in chlorinated ammonia containing ground water." FIU Digital Commons, 1985. http://digitalcommons.fiu.edu/etd/2026.

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It is well established that trihalomethanes, in drinking water are byproducts of chlorine disinfection. A method to predict the distribution and concentration of trihalornethanes is important because of health risks associated with chronic exposure to these compounds. A literature review has provided information on the chemistry of water chlorination and a data base developed in the laboratory has provided data on trihalomethane formation under various conditions. These data were used to generate rate constants for the formation of trihalomethanes. Trihalornethane formation kinetics appeared t
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27

Clarke, Jo Aine. "A Constant Struggle: Renegotiating Identity in the Aftermath of Rape." [Tampa, Fla] : University of South Florida, 2008. http://purl.fcla.edu/usf/dc/et/SFE0002371.

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28

Saghaian, Nejad Esfahani Sayed Mahdi. "STATISTICAL MODELS FOR CONSTANT FALSE-ALARM RATE THRESHOLD ESTIMATION IN SOUND SOURCE DETECTION SYSTEMS." UKnowledge, 2010. http://uknowledge.uky.edu/gradschool_theses/46.

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Constant False Alarm Rate (CFAR) Processors are important for applications where thousands of detection tests are made per second, such as in radar. This thesis introduces a new method for CFAR threshold estimation that is particularly applicable to sound source detection with distributed microphone systems. The novel CFAR Processor exploits the near symmetry about 0 for the acoustic pixel values created by steered-response coherent power in conjunction with a partial whitening preprocessor to estimate thresholds for positive values, which represent potential targets. To remove the low frequen
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Karaca, Ümit Özen Serdar. "Constant False Alarm Rate (cfar) Detection Based Estimators With Applications to Sparse Wireless Channels/." [s.l.]: [s.n.], 2006. http://library.iyte.edu.tr/tezler/master/elektrikveelektronikmuh/T000586.pdf.

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30

Liang, Y., C. Zeng, J. J. Wang, M. W. Liu, Yeh T. C. Jim, and Y. Y. Zha. "Constant Gradient Erosion Apparatus for Appraisal of Piping Behavior in Upward Seepage Flow." AMER SOC TESTING MATERIALS, 2017. http://hdl.handle.net/10150/625214.

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Seepage direction is crucial for understanding the critical state and development of piping erosion. A stress-controlled apparatus was designed to investigate the piping behavior of cohesionless soil under upward flow condition. The components of the new apparatus included a loading chamber, a vertical and confining loading system, an upstream water supply device, a soil-water separating system, and a water collecting system. The loading chamber provides space for a soil specimen setting and loading. The combination of a vertical and a confining loading system was designed to apply complex str
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31

Pradie, Noriberto Araujo. "Mecanismo da decomposição e reações com radicais em acetatos." Universidade de São Paulo, 2011. http://www.teses.usp.br/teses/disponiveis/46/46136/tde-18082011-104220/.

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Estudos do mecanismo de reações unimoleculares, das moléculas de acetato de metila e etila, induzidas por absorção multifotônica e de reações bimoleculares com os radicais OH e Cl, usando cálculos ab initio e de funcional de densidade foram realizados neste trabalho. A análise dos cálculos das barreiras de energia e das constantes de velocidade microcanônicas das reações unimoleculares com o formalismo da teoria RRKM, permitiu prever algumas reações cujos produtos não foram determinados experimentalmente. Além disso, semelhanças das geometrias e dos valores de energia de algumas estruturas ent
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32

Pezacki, John Paul. "Rate constants and mechanisms for reactions of carbenes and cations from oxadiazolines and other precursors." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape7/PQDD_0028/NQ51008.pdf.

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Pezacki, John Paul. "Rate constants and mechanisms for reactions of carbenes and cations from oxadiazolines and other precursors /." *McMaster only, 1998.

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34

Betts, Nicholas B. "Laboratory studies of gas phase ion-neutral reaction rate constants relevant to the interstellar medium." Diss., Connect to online resource, 2006. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:1439438.

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35

Holm, Daniélle. "Influence of strain rate in CRS tests : A laboratory study of three Swedish clays." Thesis, KTH, Jord- och bergmekanik, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-192212.

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The Constant Rate of Strain (CRS) test is currently the most widely used method for determination of consolidation parameters in Sweden. These parameters are used to calculate the probable settlements and behavior of soils. With the Swedish standard strain rate, the duration of a single the test is about 24h, but a higher strain rate would allow for more tests to be performed in the same amount of time. For all clays in Sweden, the Swedish standard for the CRS test suggests a fixed rate of strain that is independent of soil properties, while the North American standard proposes a strain rate t
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Karlsson, Mikael. "Determination of antibody affinity and kinetic binding constants in Gyrolab Bioaffy microfluidic CD." Thesis, Linköping University, The Department of Physics, Chemistry and Biology, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-11616.

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<p>Studies of binding reactions are of highest importance in a vast number of areas of biomedicine and biotechnology. A demand for fast and accurate small-volume measurements grows stronger, partly due to the development of therapeutic antibodies. In this report, a novel method for studies of binding reactions of antibodies is described. The use of a microfluidic platform shows promising results in determination of affinity binding constants.</p><p>Affinities between 1E-09 and 1E-11 M have been determined for four TSH antibodies. Reproducibility tests give a CV below 10%, using different Gyrol
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37

Chun, Geumju 1965. "Critical strain for dynamic recrystallization during the constant strain rate hot deformation of Nb steels." Thesis, McGill University, 2004. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=81532.

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The presence of peak points in constant strain rate flow curves is generally considered to indicate the onset of dynamic recrystallization (DRX). However, not all materials display clear peaks when tested under these conditions. It has been suggested that DRX is initiated when the strain reaches a critical value epsilonc that is related to the peak strain epsilonp and that this critical strain can be detected from the inflection point in plots of the strain hardening rate theta against stress sigma, regardless of the presence or absence of peaks. This is of importance because many works
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Cai, Wei. "Discrete element modelling of constant strain rate and creep tests on a graded asphalt mixture." Thesis, University of Nottingham, 2013. http://eprints.nottingham.ac.uk/29249/.

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This thesis investigates the use of Discrete Element Modelling (DEM) to simulate the elastic and viscoelastic deformation behaviour of an asphalt mixture. A numerical specimen preparation procedure has been developed to produce specimens with an isotropic stress and correct volumetrics. Stone mastic asphalt has been chosen in this project because of its high content of coarse aggregate and binder-rich mortar. A range of uniaxial compression tests have been undertaken in the laboratory under various loading speeds and stresses. The axial stress, axial strain and radial strain were recorded duri
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Wang, Xipeng. "CONSTANT FALSE ALARM RATE PERFORMANCE OF SOUND SOURCE DETECTION WITH TIME DELAY OF ARRIVAL ALGORITHM." UKnowledge, 2017. http://uknowledge.uky.edu/ece_etds/105.

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Time Delay of Arrival (TDOA) based algorithms and Steered Response Power (SRP) based algorithms are two most commonly used methods for sound source detection and localization. SRP is more robust under high reverberation and multi-target conditions, while TDOA is less computationally intensive. This thesis introduces a modified TDOA algorithm, TDOA delay table search (TDOA-DTS), that has more stable performance than the original TDOA, and requires only 4% of the SRP computation load for a 3-dimensional space of a typical room. A 2-step adaptive thresholding procedure based on a Weibull noise pe
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Quillon, Aurélia Leroux Caroline Piau Didier. "Prédiction markovienne in silico des régions constantes et variables des lentivirus." [s.l.] : [s.n.], 2006. http://hal.archives-ouvertes.fr/docs/00/12/41/42/PDF/these_BoissinQuillon.pdf.

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Dawson, Casey A. "Children's Use of Race in Drawing Inferences Based on Their Understanding of Race Constancy." TopSCHOLAR®, 2007. http://digitalcommons.wku.edu/theses/10.

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Children’s understanding of race constancy and their subsequent use of race as a means of drawing inductive inferences were investigated. Race constancy was determined by children’s tendency to say that people could change category membership by changing their outside appearance. A second phase of the study measured how many race-based inferences children made relative to other social categories such as age or sex. The results indicated that children who had a better understanding of race constancy were also more likely to use race as a means of drawing inductive inferences. These findings sup
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Cochran, Kellie. "Prediction of the Degradation of Emerging Contaminants During Oxidative Treatment via Analysis of Reaction Rate Constants." DigitalCommons@CalPoly, 2018. https://digitalcommons.calpoly.edu/theses/1890.

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Globally, water supplies are diminishing in quality while demand is continually increasing. The municipal water and wastewater sector has been paying increased attention to unregulated emerging organic contaminants. Advanced oxidation processes (AOPs), which produce hydroxyl radicles (•OH), have been developed and implemented to remove recalcitrant emerging contaminants left by conventional treatment processes. The current understanding of the removal efficacy of AOPs for emerging contaminants is limited. This study analyzes the ability of an AOP involving ozone and multi-walled carbon nanotub
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Alves, Tiago Vinicius. "Estudo teórico da reação do radical metila com nitrogênio atômico (4S): aspectos estruturais, energéticos, espectroscópicos e cinéticos." Universidade de São Paulo, 2008. http://www.teses.usp.br/teses/disponiveis/46/46132/tde-19052008-134755/.

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A busca de uma melhor compreensão dos ciclos químicos que ocorrem na atmosfera de Titan, um dos satélites naturais de Saturno, tem posto em relevância a importância de reações químicas envolvendo nitrogênio atômico e hidrocarbonetos, principalmente o radical metila. Além desta ênfase astroquìmica, essa reação tem também um papel importante no estudo da decomposição de metano em plasma pós-descarga de nitrogênio e no entendimento de processos de combustão. Neste trabalho, dando continuidade a estudos teóricos envolvendo reações de espécies atômicas com hidrocarbonetos realizados por este grupo
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Fritsch, LeaAnn Thompson. "Effects of chronic suboptimal energy intake on constant-load exercise in young women." Thesis, This resource online, 1996. http://scholar.lib.vt.edu/theses/available/etd-09182008-063227/.

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45

Dean, Valarie Nichole. "Time Constant Analysis of Initial 'Jump' in Firing Rate of Human Motor Units During Isometic Contraction." Thesis, The University of Arizona, 2010. http://hdl.handle.net/10150/146201.

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Ongoing research studying the underlying mechanism and prevalence of Persistent Inward Currents (PICs) has posed a challenge to the conventional view that the firing rate of a motor unit is proportional to the amount of synaptic input it receives. Near the time of human motor unit recruitment during isometric muscle contraction, a sudden steep rise in firing rate is observed, which is suggested to result from rapid triggering of PICs, an intrinsic property of motor neurons. In evaluating the time constants associated with these steep rises in firing rate across different contractile speeds, it
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Phan, Anthony. "Development of a rate of injection bench and constant volume combustion chamber for diesel spray diagnostics." [Ames, Iowa : Iowa State University], 2009.

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47

Green, Dale. "A probabilistic approach to reaction coordinate and rate constant modeling applied to epoxide ring-opening reactions." Kansas State University, 2012. http://hdl.handle.net/2097/15085.

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Master of Science<br>Department of Chemical Engineering<br>Keith Hohn<br>The study will utilize a probabilistic reaction modeling method for ring-opening reactions of epoxide. In particular, to elucidate the reaction mechanism by the methods presented, focus will be placed on the nucleophillic attack of ethylene oxide by ammonia and its anion. This focus was chosen because of the potential to gain significant advantage in computational intensity required to model the epoxy-amino macromolecular curing reactions and resulting thermochemical and physical properties of the cured resin. The method
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48

Shao, Kejun. "Kinetic Study of the Reactions of Chlorine Atoms with Fluoromethane and Fluoromethane-d3 in the Gas Phase." Thesis, University of North Texas, 2017. https://digital.library.unt.edu/ark:/67531/metadc1011808/.

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The kinetics of the gas-phase reactions of chlorine atoms with fluoromethane (CH3F) and fluoromethane-d3(CD3F) were tested experimentally. The relative rate method was applied by using CH4 as the reference compound for fluoromethane (CH3F) and CH4 and CH3F as the reference compound for fluoromethane-d3(CD3F). The rate constants for H-abstraction from CH3F and D-abstraction from CD3F were measured at room temperature and a total pressure of 920 Torr using Ar as a diluent. The rate constants are described by the expressions: kH= (3.50±0.52) x 10-13 cm3 molecule-1 s-1 and kD=(5.0±0.51) x 10-14 cm
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49

Sherrell, Ian M. "Development of a Flotation Rate Equation from First Principles under Turbulent Flow Conditions." Diss., Virginia Tech, 2004. http://hdl.handle.net/10919/29943.

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A flotation model has been proposed that is applicable in a turbulent environment. It is the first turbulent model that takes into account hydrodynamics of the flotation cell as well as all relevant surface forces (van der Waals, electrostatic, and hydrophobic) by use of the Extended DLVO theory. The model includes probabilities for attachment, detachment, and froth recovery as well as a collision frequency. A review of the effects fluids have on the flotation process has also been given. This includes collision frequencies, attachment and detachment energies, and how the energies of the turbu
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50

Jani, Parth K. "Experimental Investigation of Influence of Liquid Physicochemical Properties on Adiabatic Bubble Growth from Submerged Capillary Orifice under Constant Flow Rate Conditions." University of Cincinnati / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1623169715636338.

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