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Dissertations / Theses on the topic 'Reaction of aniline'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

Soper, Jake D. "Reactions at nitrogenous ligands on oxidizing group 8 metal centers /." Thesis, Connect to this title online; UW restricted, 2003. http://hdl.handle.net/1773/8589.

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2

Rannou, Patrice. "Poly(aniline) : synthèse, mise en oeuvre et vieillissement." Université Joseph Fourier (Grenoble ; 1971-2015), 1998. http://www.theses.fr/1998GRE10080.

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Ce travail est consacré à la synthèse, la mise en œuvre et le vieillissement d'un polymère conducteur (pc) : la polyaniline (pani). Deux morphologies ont été étudiées : des poudres divisées de pani dopee par l'acide chlorhydrique (pani-hci) et des films de pani dopee par l'acide camphre sulfonique (csa) obtenus par l'évaporation de solutions dans le m-cresol. Dans une première partie, nous présentons la synthèse chimique basse température par voie oxydante de la pani. Le contrôle des paramètres de synthèse a permis de préciser le mécanisme de polymérisation et d'obtenir des polymères de masse

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3

Doridot, Gabriel. "Etude de la transformation d'aminocyclopropanes élaborés dans le cadre d'une stratégie de synthèse de 14-azastéroïdes." Phd thesis, Université Paris Sud - Paris XI, 2011. http://tel.archives-ouvertes.fr/tel-00937934.

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Au cours de ces travaux de thèse, une voie de synthèse de différentes cyclopropylamines a été développée. Leur fonctionnalisation a ensuite été mise en œuvre à l'aide de réactions de métallation ou de couplages croisés catalysés au palladium. Les cyclopropylamines ainsi fonctionnalisées furent alors soumises à des conditions de cyclisation dans le but d'obtenir tout ou partie d'une structure 14-azastéroïde. Si notre modèle, dont la synthèse s'est construite autour d'une aniline, nous a permis d'obtenir la structure des cycles B, C et D d'un 14-azastéroïde, nous n'avons pas été en mesure d'obte

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4

Rabbitt, Lynsey C. "Some kinetic and equilibrium studies of the reactions of nitrobenzofurazan derivatives with nucleophiles." Thesis, Durham University, 2000. http://etheses.dur.ac.uk/4623/.

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The reactions of 4,6-dinitrobenzofuroxan, (DNBF) with aniline and six of its N- and ring- substituted derivatives have been studied. It is known that aniline usually reacts as a nitrogen nucleophile, forming nitrogen-bonded σ-adducts with trinitrobenzene, (TNB) in the presence of a strong base. However, in acidic solutions, a-adducts are formed with bonding between a ring carbon atom of the anilines and the 7-position of DNBF. A value of 2.0 for k(_H)/k(_D), the kinetic isotope effect, indicates that bond formation is largely rate determining in the substitution pathway. Estimates were made fo

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5

RAMADAN, DOAA REDA MOHAMED. "PALLADIUM CATALYZED REACTIONS: REDUCTIVE CYCLIZATION OF NITROARENES, AND OXIDATIVE CARBONYLATION OF ANILINE." Doctoral thesis, Università degli Studi di Milano, 2021. http://hdl.handle.net/2434/819652.

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Palladium Catalyzed Reactions: Reductive Cyclization of Nitroarenes, and Oxidative Carbonylation of Aniline Abstract: The thesis is divided into two main chapters: reductive cyclization of nitroarenes, and oxidative carbonylation of aniline. The first chapter involves developing a catalytic system for carbazoles synthesis through reductive cyclization of 2-nitrobiphenyls employing phenyl formate as an in-situ source of CO. Thus, the synthetic chemist can avoid handling pressurized CO lines and perform the reaction in a pressure tube, a cheap and readily available tool for any laborat

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6

Radianingtyas, Helia. "Development of a biofilm reactor process for the treatment of 4-chloroaniline." Thesis, University of Kent, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.314266.

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7

Mendiratta, Arjun. "Reductive coupling and related reactions with Mo and Ti tris- anilides." Thesis, Massachusetts Institute of Technology, 2005. http://hdl.handle.net/1721.1/32483.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2005.<br>Vita.<br>Includes bibliographical references.<br>Chapter 1: The capability of Mo(N[t-BulAr)₃ to act as a powerful one, two, and three electron reductant have been previously demonstrated. In this work, we show that Mo(NIt-BulAr)₃ forms a metastable adduct with the moderate [pi] acid PhCN; coordination of PhCN activates the nitrile carbon towards reaction with a variety of one-electron reagents such as dichalcogenides, nitric oxide, hydrogen atom donors, cobaltocene, and elemental phosphorus. Evidence is presen

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8

ELKACEMI, KACEM. "Etude electrochimique de divers conducteurs organiques." Paris 6, 1986. http://www.theses.fr/1986PA066399.

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Etude electrochimique des sels de radicaux ioniques organiques, des complexes par transfert de charge et des radicaux ioniques. Donnees sur les composes conducteurs, formes par oxydation du tetrathiofulvalene (ttf) en presence de differents anions (scn**(-), no::(3)**(-) et mncl::(3)**(-)), par oxydation de tmttf dans l'acetonitrile en presence de scn**(-) et par reduction de tcnq en presence de differents cations. Donnees, aussi, sur les proprietes optiques et electrochimiques des films conducteurs de polyaniline

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9

HADDAD-FAHED, OMAIMA. "Catalyse micellaire de reactions de substitution nucleophile aromatique comportant des reactifs electriquement charges." Paris 6, 1987. http://www.theses.fr/1987PA066419.

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10

Liu, Kun. "Catalytic Asymmetric Synthesis of Chiral Cyclic Amines and Axially Chiral Anilides by Phase-Transfer Catalyzed Reactions." 京都大学 (Kyoto University), 2012. http://hdl.handle.net/2433/158098.

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11

Naturale, Guillaume. "Approches radicalaires pour la fonctionnalisation directe de quinones à visée anticancereuse." Thesis, Bordeaux 1, 2012. http://www.theses.fr/2012BOR14635/document.

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Dans le cadre d’un programme de recherche dédié à la découverte de petites molécules à visée anticancéreuse, nous avons envisagé de concevoir des composés originaux dérivés de quinones. Notre premier objectif a été d’élaborer des mimes non-peptidiques de la protéine Smac, susceptibles de participer à relancer le phénomène d’apoptose, dont la structure est rigidifiée par des contraintes conformationnelles. Par ailleurs, les kinases et les phosphatases, jouant des rôles complémentaires de phosphorylation / déphosphorylation dans le cadre du contrôle du cycle cellulaire notamment, apparaissent au

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12

RAZAFINDRALAMBO, ROMUALD. "Mecanisme et cinetique des deux stades de la reaction de transimination des n-benzylidene-anilines par des amines aliphatiques, la formation et la coupure des gem-diamines." Paris 7, 1989. http://www.theses.fr/1989PA077105.

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Le mecanisme des deux stades de la reaction est examine: la gem-diamine est formee suivant deux voies competitives, l'addition de l'amine sur l'imine protonee ou sur l'imine neutre; la gem-diamine se coupe selon un mecanisme concerte, le transfert de proton sur l'azote, et la coupure de la liaison c-n s'effectuant simultanement pour conduire au nouvel ion iminium

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13

Rinard, Chauncey J. "I. An Unusual Hydride Transfer in the Thermolysis of a Lithium Alkoxide ; II. Carbon-Carbon Bond Forming Reactions of Oxidized Anilide Intermediates. A New Route to Dihydroindoles /." The Ohio State University, 1996. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487935125878439.

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14

Petrov, Ravil Rashitovich. "Part I. Application of 2-Hydroxymethylacrylic Acid, a Product of Baylis-Hillman Reaction, for the Synthesis of Novel N-backbone-to-Side-Chain Cyclic Peptide Analogs: Strategies and Side Reactions Part II. Synthesis and Biological Activities of Chimeric Bioactive Peptides Featuring Amino Acids Coupled to 4-Anilino-N-Phenethyl-Piperidine." Diss., The University of Arizona, 2007. http://hdl.handle.net/10150/194330.

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During my research career in Prof. V.J.Hruby's laboratory I worked on two different projects. The first project, which was initiated by the author, was planned to serve the need of our laboratory for a novel method of peptide cyclization. This method was planned to use recent advances in Pd0-catalyzed asymmetric synthesis combined with the structural richness offered by the Baylis-Hillman chemistry which could open new ways to diverse areas of drug design, molecular immunology and chemotherapy. This approach would provide cyclic peptides featuring N-alkylated amino acids that would confer high

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15

Chou, Chun-Tzer. "Part I, reaction of quinone imine monoketals with organolithium reagents. ; Part II, preparation of quinone imide monoketals by anodic oxidation of anilides. ; Part III, construction of the erythrina alkaloids skeleton /." The Ohio State University, 1987. http://rave.ohiolink.edu/etdc/view?acc_num=osu14875846121632.

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16

Felipe-Blanco, Diego. "Salicylic Acid-Catalyzed Radical Arylations from In-situ Formed Arenediazonium Salts." Doctoral thesis, Universidad de Alicante, 2020. http://hdl.handle.net/10045/112757.

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In this thesis, it has been studied the deamination of aromatic amines, through in situ formed diazonium salts as reaction intermediates, catalyzed by salicylic acid, a nontoxic, eco-friendly and economic catalyst. In the early part of the thesis (Chapter I) it has studied the deamination process using THF as solvent as hydrogen donor and anilines as radical source, to carry the hydrodeamination reaction, as well as the process in its deuterodeamination manner using deuterated solvent. Following with this study in Chapter II and Chapter III, it has been studied the addition of the aromatic rad

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17

Brown, Carole E. Stiegman Albert E. "Charaterization [sic] of the reaction of silica bound chromium(VI) sites with aniline." 2004. http://etd.lib.fsu.edu/theses/available/etd-04122004-145720.

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Thesis (M.S.)--Florida State University, 2004.<br>Advisor: Dr. Albert E. Stiegman, Florida State University, College of Arts and Sciences, Dept. of Chemistry and Biochemistry. Title and description from dissertation home page (viewed June 17, 2004). Includes bibliographical references.

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18

Chou, Hsiu Yen, and 周秀燕. "Study on the condensation reaction of quinaldine cyanine compoumds and the synthesis of aniline polymer." Thesis, 2001. http://ndltd.ncl.edu.tw/handle/07540762219588383005.

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碩士<br>國立中央大學<br>化學工程研究所<br>89<br>The condensation of 2-methylquinaldinemethiodide and 2,3,3-trimethyl-benzo indole methiodide and 4-(Dimethylamino) benzaldehyde in isopropanol catalyzed by piperidine was a good method. It is also good method,if it applies to condensation benzaldehyde salicylaldehyde.., etc . It is better to use condensation different carbon , example triethyl orthoformate and 1,1,3,3-tetramethoxypropane to cyanine dye .It will make wavelength extends more than 600nm.Then changing solvent to increase boiling point and to reduce reaction time is also one of this experimental obj

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19

Roy, Suman Kumar. "C-N BOND FORMING REACTIVITY IN ANILINE AND THEIR CO-ORDINATION CHEMISTRY." Thesis, 2019. http://hdl.handle.net/10821/8200.

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The research has been originated from an attempt to explore direct and selective transformation of c-h bonds that are mediated either by metal coordination or by protonation of anilido substrate oxidative dimerization and polymerization reactions<br>The research guide was Prof. Sreebrata Goswami of Inorganic Chemistry division under SCS [School of Chemical Science]<br>Research was conducted under CSIR fellowship in IACS

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20

Luo, Yue-Gui, and 羅月貴. "Palladium-Catalyzed Cyclization and Oxidative Cross-Coupling Reaction of N,N-Dimethyl-2-(phenylethynyl)aniline with Aryl Pinacol Boronates." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/tx9zu4.

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碩士<br>國立中興大學<br>化學系所<br>106<br>This thesis is about synthesis of indole derivatives, which has found in many bioactive natural products, medicinal chemistry, materials chemistry, and agrochemicals. The synthesis and functionalization of indoles have attracted chemists and remain an active research area. At first, we developed the palladium-catalyzed that aryl pinacol boronates chosen as boronic sources and underwent cross-coupling with C-C bond in EtOH is reported. We synthesize the 2,3-substituted indoles through the coupling reaction of arylpinacol boronates and cyclization with N,N-dimeth

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21

Chang, Yuan-Ho, and 張元和. "A competitive study of fluorenone and aniline deriveatives underway Friedel-Crafts reaction and Imindation reaction at acid condition : synthesis of a conductive 2,7-bis(methylstyryl)-fluorenone materials." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/21493098735221623432.

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碩士<br>正修科技大學<br>化工與材料工程研究所<br>99<br>Under acid conditions，9-fluorenone and benzene derivatives take place Fridel-Crafts alkylation, another is imindation reaction by used Dean-Stark. In this experiment, 9-fluorenone was used as starting material reacted with benzene derivatives by acid-catalysts to give conductive material, which is electron-rich. At the same time, we will analyze the UV-Vis characteristics of material and the characteristic curves of I-V、EL analyzing the optoelectronic characteristics of white organic light-emitting device. First, 9-fluorenone was brominated to give 2,7-Dibro

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22

Zhuang, Xin-Yi, and 莊新毅. "Synthesis of Benzo[4,5]imidazo[1,2-a]pyridine and its derivatives by intermolecular carbon-nitrogen bond coupling reaction between aniline and pyridine induced by different aromatic substituted hypervalent iodine reagents." Thesis, 2019. http://ndltd.ncl.edu.tw/handle/ncwgwy.

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碩士<br>國立中山大學<br>化學系研究所<br>107<br>In this thesis, we have successfully found two types of highpervalent iodine reagents with different substituent groups: (4-methoxyphenyl)- λ3-iodanediyl diacetate and (4-methoxyphenyl)- λ3-iodanediyl diacetate, increasing the yield of the production of benzo[4,5]imidazo[1,2-a]pyridines with aniline derivatives and pyridine derivatives as starting materials. 　　In this thesis, we have successfully found two types of highpervalent iodine reagents with different substituent groups: (4-methoxyphenyl)- λ3-iodanediyl diacetate and (4-methoxyphenyl)- λ3-iodanediyl dia

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23

Hung, Chia-Ju, and 洪嘉嬬. "Adsorption and Reactions of Aniline on Copper and Titania Single Crystal Surfaces." Thesis, 2013. http://ndltd.ncl.edu.tw/handle/za8fv5.

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碩士<br>國立中山大學<br>化學系研究所<br>101<br>The applications of azo dye are extremely versatile; therefore, searching for more efficient and environmentally friendly catalysts to synthesize azo dye molecule has become a very important issue. Aniline can be used to synthesize azobenzene in the presence of a copper catalyst. Titanium dioxide can also catalyze the conversion from aniline to azobenzene, and the reaction intermediate is believed to be surface-bound phenyl imide species. In this study, we selected aniline and phenyl isocyanate as precursors to investigate their thermal chemistry on copper and

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24

廖庭宇. "Combined toxic effects of reactive toxicants and polar narcotic toxicants - halogen - anilines." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/44605156953656029192.

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碩士<br>國立交通大學<br>環境工程系所<br>98<br>The combined toxic effects of reactive organic toxicants (aldehydes or nitriles) and polar narcotic halogenated anilines were evaluated using the Microtox test. The effects of the mixtures of the above compounds, which contain different mechanisms of toxicity, were investigated using equit-toxic-ratio tests and isobologram analyses. Both less-than-additive and additive effects were observed from the above mixtures. According to Non-interactive multiple toxicity theory (Christensen ＆ Chen, 1989), greater- than-additive (synergistic) effects will perform when

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25

Chen, Wun-Yu, and 陳玟妤. "Hypervalent Iodine-Mediated Reaction of Anilines with Pyridines to Benzo[4,5]imidazo[1,2-a]pyridine Derivatives." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/d548ct.

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碩士<br>國立中山大學<br>化學系研究所<br>105<br>It was found that hypervalent iodine, such as (diacetoxyiodo)benzene and [bis(trifluoroacetoxy)iodo]benzene could mediate reaction of anilines with pyridines in mild reaction to give benzo[4,5]imidazo[1,2-a]pyridine derivatives. In this thesis, the effect of solvent and substituents group on reactivity are investigated. The optimized reaction conditions is the reaction of anilines with pyridines in the ratio of 1 to 77 without any additional solvent for 15 minutes at room temperature. The benzo[4,5]imidazo[1,2-a]pyridine was obtained in yield. It was also foun

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26

Chan, Chi-Yu, and 詹啟裕. "Synthesis and characterization of Anilido-oxazoline Zinccomplexes and their application in ring opening polymerization reaction." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/52432673490938258227.

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27

Huang, Guo-Cyuan, and 黃國銓. "Synthesis, Characterization and Application in Hydrogen Transfer Reaction of Ruthenium Complexes Containing Anilido-Pyridinyl-(Imidazole/Benzimidazole) Ligands." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/32592020599066392173.

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碩士<br>國立中興大學<br>化學系所<br>104<br>A series of the anilido-pyridinyl-(imidazole/benzimidazole) ligands L7–L12 was synthesized by Pd-catalyzed amination. Treatment of ligands L7–L12 with 0.5 equiv. of dichloro(p-cymene) ruthenium(II) dimer in dichloromethane affords ruthenium complexes 52–57. Ligands and ruthenium complexes were characterized by NMR spectroscopy, elemental analysis and liquid chromatograph tandem mass spectrometer. Crystal structure of ruthenium complexes 52 and 57 were further determined by single crystal X-ray diffraction technique. The catalytic activities of ruthenium compl

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28

Wang, Wei-Lin, and 王薇琳. "Carbon - Carbon Bond Forming Reactions of Nitrenium Ions Generated from Aceton - Anile." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/52501039354178880910.

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29

Liu, Shui-Te, and 劉水德. "PART(I):Halogenation of 2-Anilino-1,4-Naphthoquinoes With Copper(II) Halids PART(II):5-Phenylpentenes In Free Radical Reactions." Thesis, 1998. http://ndltd.ncl.edu.tw/handle/60077039871725641018.

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30

Liu, Shui-De, and 劉水德. "PART(I):Halogenation of 2-Anilino-1,4-Naphthoquinoes With Copper(II) Halids PART(II):5-Phenylpentenes In Free Radical Reactions." Thesis, 1998. http://ndltd.ncl.edu.tw/handle/06112566658534312231.

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