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Dissertations / Theses on the topic 'Reaction systems'

Author: Grafiati

Published: 4 June 2021

Last updated: 10 March 2023

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1

Fromell, Karin. "Nanoscale Reaction Systems." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-8249.

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2

Steele, Aaron J. "Collective behavior in chemical systems." Morgantown, W. Va. : [West Virginia University Libraries], 2007. https://eidr.wvu.edu/etd/documentdata.eTD?documentid=5386.

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Thesis (Ph. D.)--West Virginia University, 2007.<br>Title from document title page. Document formatted into pages; contains vii, 126 p. : ill. (some col.) + video files. Includes supplementary video files in a zip file. Includes abstract. Includes bibliographical references.

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3

He, Taiping. "Reaction-Diffusion Systems with Discontinuous Reaction Functions." NCSU, 2005. http://www.lib.ncsu.edu/theses/available/etd-03192005-101102/.

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This dissertation studies coupled reaction diffusion systems with discontinuous reaction functions. It includes three parts: The first part is concerned with the existence of solutions for a coupled system of two parabolic equations and the second part is devoted to the monotone iterative methods for monotone and mixed quasimonotone functions. Various monotone iterative schemes are presented and each of these schemes leads to an existence-comparison theorem and the monotone convergence of the maximal and minimal sequences. In the third part, the monotone iterative schemes are applied to comput

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4

Newton, Elizabeth Lynn. "Sustainable Reaction and Separation Systems." Thesis, Georgia Institute of Technology, 2005. http://hdl.handle.net/1853/7463.

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With increasing environmental awareness and natural resource limitations, researchers must begin to incorporate sustainability into their process and product designs. One target for green engineering is in reaction and separation design. This is typically done in a wasteful and often toxic manner with organic solvents and lack of recycle. The following thesis discusses alternatives to these costly separations by means of ionic liquids, benign extraction, separation with carbon dioxide, and near critical water. Ionic liquids are combined with carbon dioxide to induce melting point depressio

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5

Hemming, Christopher John. "Resonantly forced inhomogeneous reaction-diffusion systems." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0022/MQ50344.pdf.

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6

Brendel, Marc Levin. "Incremental identification of complex reaction systems /." Düsseldorf : VDI-Verl, 2006. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=015009980&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.

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7

Smith, Mark. "Spatial reaction systems on parallel supercomputers." Thesis, University of Edinburgh, 1994. http://hdl.handle.net/1842/12985.

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A wide variety of physical, chemical and biological systems can be represented as a collection of discrete spatial locations within which some interaction proceeds, and between which reactants diffuse or migrate. Many such real-world spatial reaction systems are known to be both non-linear and stochastic in nature, and thus studies of these systems have generally relied upon analytic approximation and computer simulation. However, this later approach can become impractical for large, complex systems which require massive computational resources. In this work we analyse a general spatial reacti

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8

Vaughan, Asa Dee Byrne Mark E. "Reaction analysis of templated polymer systems." Auburn, Ala., 2008. http://hdl.handle.net/10415/1538.

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9

Memon, Muhammad Hanif. "Microemulsions as analytical reaction media." Thesis, University of Hull, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.235839.

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10

Nagaiah, Chamakuri. "Adaptive numerical simulation of reaction-diffusion systems." [S.l.] : [s.n.], 2007. http://deposit.ddb.de/cgi-bin/dokserv?idn=985277882.

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11

Smith, Mathew D. "Reaction of hydroxyl radical with aromatic systems." Virtual Press, 2008. http://liblink.bsu.edu/uhtbin/catkey/1399191.

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The regioselectivity of the reaction of hydroxyl radical addition to toluene and naphthalene are examined in this study over the temperature range of 25°C-45°C. Also, the relative rates of reactivity as compared to benzene are determined for toluene, naphthalene, mesitylene, and p-xylene over the same temperature range. 2-(t-Butylazo)prop-2-yl hydroperoxide was used as the hydroxyl radical source and 1,1,3,3-tetramethylisoindolin-2-yloxyl was used as radical trap. For toluene the relative rates of addition were found to be 4 times greater for the ortho position versus the meta postion and 2 ti

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12

Davidson, Fordyce A. "Bifurcation in systems of reaction-diffusion equations." Thesis, Heriot-Watt University, 1993. http://hdl.handle.net/10399/1444.

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13

Howard, Martin. "Non-equilibrium dynamics of reaction-diffusion systems." Thesis, University of Oxford, 1996. http://ora.ox.ac.uk/objects/uuid:4485a178-6262-4487-b40f-7c7ec790d687.

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Fluctuations are known to radically alter the behaviour of reaction-diffusion systems. Below a certain upper critical dimension d<sub>c</sub> , this effect results in the breakdown of traditional approaches, such as mean field rate equations. In this thesis we tackle this fluctuation problem by employing systematic field theoretic/renormalisation group methods, which enable perturbative calculations to be made below d<sub>c</sub>. We first consider a steady state reaction front formed in the two species irreversible reaction A + B → Ø. In one dimension we demonstrate that there are two compone

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14

Turpin, Kevin. "Patterns and fronts in reaction-diffusion systems." Thesis, University of Nottingham, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.287233.

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15

Aldurayhim, Abdullah Mohammed. "Propagating waves in reaction cross-diffusion systems." Thesis, University of Exeter, 2017. http://hdl.handle.net/10871/31129.

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This research focuses on the reaction diffusion systems where the matrix of diffusion co- efficients is not diagonal. We call these systems reaction cross-diffusion systems. These systems possess interesting solutions that do not appear in the reaction self-diffusion systems that have a diagonal diffusion matrix. Compared to research conducted on re- action self-diffusion systems, the reaction cross-diffusion systems have received little attentions. The aim of this research is to extend existing literature on these systems. In this thesis we considered two-components reaction cross-diffusion s

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16

Fernandez, Fonseca Andrea. "Sharp interface models from homogeneous reaction systems." Thesis, University of Bath, 2013. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.607473.

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This thesis investigates the fast-reaction limit for a one dimensional reaction-diffusion system describing the penetration of the carbonation reaction in concrete. Three conceptually different scaling regimes of the effective diffusivities of the driving chemical species are explored using matched asymptotics. The limiting models include one-phase and two-phase generalised Stefan moving boundary problems as well as a nonstandard two-scale (micro-macro) moving boundary problem. These sharp interface models are studied to uncover the mechanisms at the free boundary. A power law for the concentr

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17

Kammogne, Kamgaing Rodrigue. "Domain decomposition methods for reaction-diffusion systems." Thesis, University of Birmingham, 2014. http://etheses.bham.ac.uk//id/eprint/4599/.

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Domain Decomposition (DD) methods have been successfully used to solve elliptic problems, as they deal with them in a more elegant and efficient way than other existing numerical methods. This is achieved through the division of the domain into subdomains, followed by the solving of smaller problems within these subdomains which leads to the solution. Furthermore DD-techniques can incorporate in their implementation not only the physics of the different phenomena associated with the modeling, but also the enhancement of parallel computing. They can be divided into two major categories: with an

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18

Zhang, Wenling. "Model building methodology for complex reaction systems." Thesis, University of Manchester, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.503069.

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The complexity of chemical reaction processes and the short market window of some chemical products mean that detailed model building can often not be justified. With little knowledge of chemistry, this work aims to provide a new methodology for model building of chemical reaction systems with minimum experimental measurements, for the purpose of reactor design and optimisation. Most often reactor designs are scaled from experimental measurements, especially for the manufacture of fine and speciality chemicals. Yet, without a model of the reaction system, major opportunities can be missed in t

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19

Hiwale, Rameshwar. "Model Building Methodology for Multiphase Reaction Systems." Thesis, University of Manchester, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.521567.

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20

Alves, Jessica. "Advanced photochemical reaction systems for molecular design." Thesis, Queensland University of Technology, 2022. https://eprints.qut.edu.au/227734/1/Jessica_Alves_Thesis.pdf.

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Direct laser writing is a technique for printing complex 3D structures with high resolution by irradiating a photoresist in a two-photon process. Improved resolution and dynamic material properties of the printed structures is critical. Herein, advanced photochemical systems were investigated, potentially enabling dual-wavelength direct laser writing. Such systems consisting of organic photoswitches enable the formation of a single product only when irradiated with two wavelengths. A well-known class of photoswitches was investigated for this purpose and its chemistry was carefully explored. F

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21

Keller, Tobias [Verfasser]. "Reactive Distillation for Multiple-reaction Systems: Experimental Investigation, Modelling and Optimisation / Tobias Keller." München : Verlag Dr. Hut, 2013. http://d-nb.info/103728948X/34.

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22

Rolland, Guillaume. "Global existence and fast-reaction limit in reaction-diffusion systems with cross effects." Phd thesis, École normale supérieure de Cachan - ENS Cachan, 2012. http://tel.archives-ouvertes.fr/tel-00785757.

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This thesis is devoted to the study of parabolic systems of partial differential equations arising in mass action kinetics chemistry, population dynamics and electromigration theory. We are interested in the existence of global solutions, uniqueness of weak solutions, and in the fast-reaction limit in a reaction-diffusion system. In the first chapter, we study two cross-diffusion systems. We are first interested in a population dynamics model, where cross effects in the interactions between the different species are modeled by non-local operators. We prove the well-posedness of the correspondi

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23

Balding, D. J. "Some annihilating particle systems." Thesis, University of Oxford, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.236110.

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24

Sinclair, E. C. "Geometric reaction forces in billiards." Thesis, University of Bristol, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.294868.

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25

Picciani, Massimiliano. "Rare events in many-body systems : reactive paths and reaction constants for structural transitions." Phd thesis, Université Pierre et Marie Curie - Paris VI, 2012. http://tel.archives-ouvertes.fr/tel-00706510.

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Cette thèse aborde l'étude de phénomènes physiques fondamentaux, avec des applications aux matériaux d'intérêt nucléaire. Nous avons développé des méthodes pour l'étude d'évènements rares concernant des transitions structurales thermiquement activées dans des systèmes à N-corps. La première méthode consiste en la simulation numérique du courant de probabilité associé aux chemins réactifs. Après avoir dérivé les équations d'évolution du courant de probabilité, on échantillonne ce courant grâce à un algorithme de type Monte Carlo Diffusif. Cette technique, dénommée Transition Current Sampling, a

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26

Barkat, Omar. "Rheology of flowing, reacting systems the crosslinking reaction of hydroxypropyl guar with titanium chelates /." Access abstract and link to full text, 1987. http://0-wwwlib.umi.com.library.utulsa.edu/dissertations/fullcit/8712850.

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27

Howarth, J. N. "Microelectrode studies of Electroplating systems." Thesis, University of Southampton, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.380601.

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28

Büger, Matthias. "Systems of reaction-diffusion equations and their attractors." Giessen : Selbstverlag des Mathematischen Instituts, 2005. http://catalog.hathitrust.org/api/volumes/oclc/62216537.html.

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29

Stich, Michael. "Target patterns and pacemakers in reaction-diffusion systems." [S.l.] : [s.n.], 2003. http://deposit.ddb.de/cgi-bin/dokserv?idn=967163943.

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30

Filho, Sergio Muniz Oliva. "Reaction-diffusion systems on domains with thin channels." Diss., Georgia Institute of Technology, 1993. http://hdl.handle.net/1853/28837.

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31

Lamb, David R. "New reaction systems for environmentally conscious chemical processes." Diss., Georgia Institute of Technology, 1998. http://hdl.handle.net/1853/30075.

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32

Provatas, Nikolas. "Kinetic roughening and bifurcations in reaction-diffusion systems." Thesis, McGill University, 1994. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=28886.

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We study the dynamics of two reaction-diffusion phenomena driven by chemical activation and thermal dissipation and evolving, respectively, on a randomly distributed or continuous medium. The first system describes the process of slow combustion of a randomly distributed reactant. It is studied by a phase-field model built up from first principles and describes the evolution of thermal and reactant concentration fields. Our combustion model incorporates thermal diffusion, activation and dissipation. We examine it in a manner which makes a connection between the propagation of combustion fronts

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33

Lesutis, Heather Patrick. "Reaction kinetics in environmentally benign novel solvent systems." Diss., Georgia Institute of Technology, 2000. http://hdl.handle.net/1853/11865.

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34

Menon, Shakti Narayana. "Bifurcation problems in chaotically stirred reaction-diffusion systems." Thesis, The University of Sydney, 2008. http://hdl.handle.net/2123/3685.

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A detailed theoretical and numerical investigation of the behaviour of reactive systems under the influence of chaotic stirring is presented. These systems exhibit stationary solutions arising from the balance between chaotic advection and diffusion. Excessive stirring of such systems results in the termination of the reaction via a saddle-node bifurcation. The solution behaviour of these systems is analytically described using a recently developed nonperturbative, non-asymptotic variational method. This method involves fitting appropriate parameterised test functions to the solution, and also

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35

Menon, Shakti Narayana. "Bifurcation problems in chaotically stirred reaction-diffusion systems." University of Sydney, 2008. http://hdl.handle.net/2123/3685.

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Doctor of Philosophy<br>A detailed theoretical and numerical investigation of the behaviour of reactive systems under the influence of chaotic stirring is presented. These systems exhibit stationary solutions arising from the balance between chaotic advection and diffusion. Excessive stirring of such systems results in the termination of the reaction via a saddle-node bifurcation. The solution behaviour of these systems is analytically described using a recently developed nonperturbative, non-asymptotic variational method. This method involves fitting appropriate parameterised test functions t

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36

Kamm, Philipp Willi. "Understanding of lambda-orthogonal photo-induced reaction systems." Thesis, Queensland University of Technology, 2022. https://eprints.qut.edu.au/234293/1/Philipp%20Willi_Kamm_Thesis.pdf.

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Using light as an energy source allows chemical reactions to be carried out with high precision in time and space. In time, because light can be switched on and off, in space, because light can be highly focussed. Further, different colours of light can be used to activate different reactants individually, even when they are present in the same reaction mixture. Herein, a system of two light-sensitive molecules was developed, which react completely sequence-independently with UV or visible light. The wavelength-dependence as well as the influence of chemical-physical parameters on such reactio

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37

Asar, Isik. "Model Predictive Control (mpc) Performance For Controlling Reaction Systems." Master's thesis, METU, 2004. http://etd.lib.metu.edu.tr/upload/12605001/index.pdf.

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In this study, the performance of the Model Predictive Controller (MPC) algorithm is investigated in two different reaction systems. The first case is a saponification reaction system where ethyl acetate reacts with sodium hydroxide to produce sodium acetate and ethanol in a CSTR. In the reactor, temperature and sodium acetate concentration are controlled by manipulating the flow rates of ethyl acetate and cooling water. The model of the reactor is developed considering first principal models. The experiments are done to obtain steady state data from the reaction system and these are compared

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38

Joglekar, Saurabh Gajanan. "Numerical Study of Reaction-Diffusion Systems using Front Tracking." Thesis, State University of New York at Stony Brook, 2018. http://pqdtopen.proquest.com/#viewpdf?dispub=10622549.

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<p> We study the three component Reaction-Diffusion systems with and without precipitation and crystal growth. Focus is on the generic chemical reaction represented by <i>nA</i> + <i>mB</i> → <i> C,</i> where <i>n,m</i> are the stoichiometric coefficients. In case of the reaction-diffusion system without precipitation, we investigate the movement of the center of reaction zone in for equal and unequal diffusivities. We compare the analytical and numerical solutions for equal diffusivities to establish the accuracy of the numerical method. Then we apply the numerical method to provide nume

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39

Geffen, Dara. "Parameter identifiability of biochemical reaction networks in systems biology." Thesis, Kingston, Ont. : [s.n.], 2008. http://hdl.handle.net/1974/1347.

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40

Crews, Steven R. II. "Increasing slew performance of reaction wheel attitude control systems." Thesis, Monterey, California: Naval Postgraduate School, 2013. http://hdl.handle.net/10945/37606.

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Approved for public release; distribution is unlimited<br>This thesis explores the physical and mathematical limitations of two common attitude control systems: one based on reaction wheels and another based on control moment gyroscopes (CMGs). The dynamics are derived from first principles and control algorithms for achieving maximum reaction wheel potential are discussed. The shaped eigenaxis input is utilized to establish baseline maneuver performance. A time-optimal shaped input is introduced and implemented in a feedback setting, subject to the limitations of the Moore-Penrose pseudo-inve

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41

Parker, Duncan J. "Uncovering features of chemical reaction networks in complex systems." Thesis, University of Southampton, 2018. https://eprints.soton.ac.uk/422229/.

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This thesis introduces a comprehensive atlas of behaviour in the iron-catalysed Belousov-Zhabotinsky reaction across a wide parameter space, under both stirred and unstirred conditions, encompassing variations in the concentrations of sulfuric acid, malonic acid and sodium bromate. All stirred reactions were monitored by UV-vis spectroscopy enabling the definition of concentration-dependent transitions in behaviour including those to chaotic oscillation. A programme was generated to quantify spirals observed in the unstirred reaction. This expanded on the work of Müller et al. by increasing t

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42

Taylor, Benjamin Luke. "Reaction systems and phase development for investment casting ceramics." Thesis, University of Birmingham, 2015. http://etheses.bham.ac.uk//id/eprint/5932/.

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Aero engine turbine blades are commonly produced via investment casting methods utilising sacrificial ceramic cores during casting to provide internal features such as cooling channels. During the firing process the conversion of the main ingredient (amorphous silica) to β-cristobalite plays a significant role, as it directly affects the dimensional stability, shrinkage, and leachability of the core after casting. Dilatometry, X-ray diffraction (XRD) and scanning electron microscopy (SEM) were utilised to evaluate common additives such as zirconium silicate and aluminosilicate. Zircon was foun

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43

Losey, Matthew W. "Novel multiphase chemical reaction systems enabled by microfabrication technology." Thesis, Massachusetts Institute of Technology, 2001. http://hdl.handle.net/1721.1/8634.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering, 2001.<br>Includes bibliographical references (p. 237-251).<br>Advances in MEMS (micro-electromechanical systems) have enabled some of the "Lab-on-a-Chip" technologies and microfluidics that are pervasive in many of the current developments in analytical chemistry and molecular biology. Coinciding with this effort in micro-analytics has been research in chemical process miniaturization -- reducing the characteristic length scale of the unit operation to improve heat and mass transfer, and ultimately process p

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44

Li, Fei. "Stochastic Modeling and Simulation of Reaction-Diffusion Biochemical Systems." Diss., Virginia Tech, 2016. http://hdl.handle.net/10919/64913.

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Reaction Diffusion Master Equation (RDME) framework, characterized by the discretization of the spatial domain, is one of the most widely used methods in the stochastic simulation of reaction-diffusion systems. Discretization sizes for RDME have to be appropriately chosen such that each discrete compartment is "well-stirred" and the computational cost is not too expensive. An efficient discretization size based on the reaction-diffusion dynamics of each species is derived in this dissertation. Usually, the species with larger diffusion rate yields a larger discretization size. Partitioning wi

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45

Tu, Junyi. "Global Attractors and Random Attractors of Reaction-Diffusion Systems." Scholar Commons, 2016. http://scholarcommons.usf.edu/etd/6418.

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The dissertation studies about the existence of three different types of attractors of three multi-component reaction-diffusion systems. These reaction-diffusion systems play important role in both chemical kinetics and biological pattern formation in the fast-growing area of mathematical biology. In Chapter 2, we prove the existence of a global attractor and an exponential attractor for the solution semiflow of a reaction-diffusion system called Boissonade equations in the L2 phase space. We show that the global attractor is an (H, E) global attractor with the L∞ and H2 regularity and that th

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46

Crooks, Elaine Craig Mackay. "Travelling-wave solutions for parabolic systems." Thesis, University of Bath, 1996. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.319218.

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47

Ma, Jinyu, and 马金余. "Phloretin and phloridzin as modulators in maillard reaction model systems." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2011. http://hub.hku.hk/bib/B47146977.

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48

Haffenden, Luke John William. "Investigation into the role of redox reactions in Maillard model systems : generation of aroma, colour and other non-volatiles." Thesis, McGill University, 2007. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=111850.

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The role of redox reactions in the formation of aroma volatiles, colour and other non-volatiles in the Maillard Reaction was investigated. The electrochemical properties of individual reactants and Maillard model mixtures were monitored via ORP (oxidation-reduction potential) and oxygen electrodes. All models exhibited unique electrochemical activities represented by their corresponding ORP profiles. Investigation into the redox potentials of several model systems demonstrated that the increased negative value of a redox potential is not necessarily correlated with its browning potential. An o

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49

Thul, Rüdiger. "Analysis of intracellular reaction diffusion systems the stochastic medium Calcium /." [S.l.] : [s.n.], 2004. http://www.diss.fu-berlin.de/2005/97/index.html.

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50

Gerisch, Alf. "Numerical methods for the simulation of taxis-diffusion-reaction-systems." [S.l. : s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=963208098.

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