Academic literature on the topic 'Reactions of fluorinated'

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Journal articles on the topic "Reactions of fluorinated"

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Fustero, Santos, María Sánchez-Roselló, and Carlos del Pozo. "Asymmetric tandem reactions: New synthetic strategies." Pure and Applied Chemistry 82, no. 3 (2010): 669–77. http://dx.doi.org/10.1351/pac-con-09-09-07.

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The use of domino and multicomponent reactions in asymmetric synthesis is constantly increasing nowadays. This allows for the synthesis of complex molecules in a single synthetic sequence, usually with high atom economy. Herein, we report three examples of new asymmetric tandem reactions recently developed in our laboratories, giving rise to new families of enantiomerically enriched fluorinated and nonfluorinated heterocycles. Thus, 1,4-dihydropyridines (1,4-DHPs) bearing fluorinated substituents at C6 were assembled by means of a Hantzsch-type reaction; cyclic β-amino carbonyl derivatives wer
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Yin, Xuemei, Xihong Wang, Lei Song, Junxiong Zhang, and Xiaoling Wang. "Recent Progress in Synthesis of Alkyl Fluorinated Compounds with Multiple Contiguous Stereogenic Centers." Molecules 29, no. 15 (2024): 3677. http://dx.doi.org/10.3390/molecules29153677.

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Organic fluorides are widely used in pharmaceuticals, agrochemicals, material sciences, and other fields due to the special physical and chemical properties of fluorine atoms. The synthesis of alkyl fluorinated compounds bearing multiple contiguous stereogenic centers is the most challenging research area in synthetic chemistry and has received extensive attention from chemists. This review summarized the important research progress in the field over the past decade, including asymmetric electrophilic fluorination and the asymmetric elaboration of fluorinated substrates (such as allylic alkyla
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Mlostoń, Grzegorz, Yuriy Shermolovich, and Heinz Heimgartner. "Synthesis of Fluorinated and Fluoroalkylated Heterocycles Containing at Least One Sulfur Atom via Cycloaddition Reactions." Materials 15, no. 20 (2022): 7244. http://dx.doi.org/10.3390/ma15207244.

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Fluorinated heterocycles constitute an important group of organic compounds with a rapidly growing number of applications in such areas as medicinal chemistry, agrochemicals production, polymer chemistry, as well as chemistry of advanced materials. In the latter case, fluorinated thiophenes are considered as a lead class of compounds with numerous spectacular applications. On the other hand, cycloaddition reactions offer a superior methodology for stereo-chemically controlled synthesis of heterocycles with a diverse ring size and a variable number of heteroatoms. A comprehensive review of meth
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Haas, Alois, and Hans-Udo Krächter. "Reactions of fluorinated ethynes." Journal of Fluorine Chemistry 29, no. 1-2 (1985): 103. http://dx.doi.org/10.1016/s0022-1139(00)83339-4.

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Bendada, Abdallah, David S. Boyle, Laurence McGhee, Geoffrey Webb, and John M. Winfield. "Reactions on fluorinated surfaces." Journal of Fluorine Chemistry 71, no. 2 (1995): 175. http://dx.doi.org/10.1016/0022-1139(94)06011-a.

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Haydar, Lolwa, Wassim El Malti, Vincent Ladmiral, Ali Alaaeddine, and Bruno Ameduri. "Original Fluorinated Non-Isocyanate Polyhydroxyurethanes." Molecules 28, no. 4 (2023): 1795. http://dx.doi.org/10.3390/molecules28041795.

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New fluorinated polyhydroxyurethanes (FPHUs) with various molar weights were synthesized via the polyaddition reaction of a fluorinated telechelic bis(cyclocarbonate) (bis-CC) with a diamine. The fluorinated bis-CC was initially synthesized by carbonylation of a fluorinated diepoxide, 1,4-bis(2′,3′-epoxypropyl)perfluorobutane, in the presence of LiBr catalyst, in high yield. Then, several reaction conditions were optimized through the model reactions of the fluorinated bis-CC with hexylamine. Subsequently, fluorinated polymers bearing hydroxyurethane moieties (FPHUs) were prepared by reacting
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Manoj, Kumar Singh, Kumar Manoj, and Bandyopadhyay Debkumar. "The study of [4+2] cycloaddition reactions of some unactivated aldehydes with a simple diene : Role of various iron(III) porphyrins as catalysts." Journal of Indian Chemical Society Vol. 92, Dec 2015 (2015): 1799–803. https://doi.org/10.5281/zenodo.5599361.

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Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi-110 016, India <em>E-mail</em> : dkbp@chemistry.iitd.ac.in The [4+2] hetero Diels-Alder reaction of some benzaldehyde derivatives with 2,3-dimethylbutadiene has been investigated in presence of catalytic quantities of TPPFe<sup>III</sup>.X and its fluorinated analogues. It was observed that in case of fluorinated catalysts the reaction was indeed facilitated and the Fe<sup>III</sup>-bound axial anionic ligands play a very important role. The reactions of various substituted benzaldehydes with 2,3-dimethyl butad
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Joshi, KrishnaC, VijaiN Pathak, R. K. Chaturvedi, and Ragini Gupta. "Synthesis reactions of fluorinated indoles." Journal of Fluorine Chemistry 35, no. 1 (1987): 69. http://dx.doi.org/10.1016/0022-1139(87)95054-8.

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Orsi, Douglas L., and Ryan A. Altman. "Exploiting the unusual effects of fluorine in methodology." Chemical Communications 53, no. 53 (2017): 7168–81. http://dx.doi.org/10.1039/c7cc02341c.

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Kotun, Stefan P., and Darryl D. DesMarteau. "Superacid-induced ring-opening reactions of fluorinated heterocycles." Canadian Journal of Chemistry 67, no. 11 (1989): 1724–28. http://dx.doi.org/10.1139/v89-265.

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HF/AsF5 and HF/SbF5 superacid mixtures react with fluorinated small-ring heterocycles such as 1,2-oxazetidines and oxetanes with consequent addition of HF to give alcohol and amine ring-opened products in high yield. Excess HF serves as solvent and reactant. Ring compounds containing both nitrogen and oxygen as heteroatoms protonate predominantly on nitrogen; a case with competing O-protonation arises in the case of a chloro-substituted oxazetidine. In general, rings containing two heteroatoms retain the heteroatom–heteroatom bond and it is a carbon–heteroatom bond that opens. The resulting OH
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Dissertations / Theses on the topic "Reactions of fluorinated"

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Lateef, Juma. "The reactions of fluorinated ketones." Thesis, Brunel University, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.286819.

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Goto, Masashi. "Kinetics of atmospheric chemical reactions of fluorinated hydrocarbons." 京都大学 (Kyoto University), 2005. http://hdl.handle.net/2433/145179.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(地球環境学)<br>甲第11759号<br>地環博第1号<br>新制||地環||1(附属図書館)<br>23402<br>UT51-2005-D508<br>京都大学大学院地球環境学舎地球環境学専攻<br>(主査)教授 川崎 昌博, 教授 田村 類, 助教授 川崎 三津夫<br>学位規則第4条第1項該当
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Sergis, Andreas Neophytos. "Reactions of sulphone stabilised carbanions with fluorinated aromatic compounds." Thesis, University of Greenwich, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.280469.

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Li, Yuqi. "Synthesis of fluorinated drug scaffolds using SNAr substitution reactions." Thesis, Loughborough University, 2017. https://dspace.lboro.ac.uk/2134/27541.

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Fluorinated arenes are considered valuable in organic chemistry. They display different types of reactivity and physicochemical properties compared to their hydrogen analogues. In this project, our medicinal chemistry programme focused on developing rapidly accessible and modifiable heterocyclic scaffolds. Different classes of fluorinated heteroatom-containing organic compounds including benzothiophenes, (aza)phenoxazines and benzaldehyde phenylhydrazones were synthesised from highly fluorinated aromatic compounds with a diverse range of functional groups appropriate for medicinal chemistry de
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Xu, Conghui. "Rhodium-mediated Activation and Borylation Reactions of Fluorinated Olefins." Doctoral thesis, Humboldt-Universität zu Berlin, 2020. http://dx.doi.org/10.18452/22174.

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Die Dissertation beinhaltet Studien zur Reaktivität von Rhodiumkomplexen gegenüber unterschiedlichen ungesättigten fluorierten Olefinen mit einem Fokus auf C–F Aktivierungs- und Borylierungsreaktionen. Der Rhodium(I)hydridokomplex [Rh(H)(PEt3)3] (1) wurde als Katalysator in den Reaktionen von HFO-1234yf, HFO-1234ze, HFO-1225zc bzw. HFO-1225ye (Z) mit HBpin verwendet. Dabei wurden Produktgemische bestehend aus Borylierungsprodukten erhalten. Die selektive Mono- und Dihydroborierung von 3,3,3-Trifluorpropin konnte durch Verwendung von Komplex 1 als Katalysator erreicht werden. Trifluorethylen
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Bridge, Colin Francis. "The influence of fluorine substitution on some enzyme mediated reactions." Thesis, Durham University, 1997. http://etheses.dur.ac.uk/4715/.

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The replacement of a hydrogen or hydroxy group with a fluorine atom is a popular strategy to alter the activity of biologically important molecules, as their similar sizes mean that such a replacement has little steric impact. The effect of fluorine substitution in a number of enzyme mediated processes has been investigated. 3-Fluorocyclohex-l-enylcarbonyl-CoA has been synthesised and the reaction with cyclohexenylcarbonyl-CoA reductase investigated. The fluorinated substrate has a comparable K(_m) value to that of the natural substrate but a V(_max) that is five times greater. A change in the
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Xu, Conghui [Verfasser]. "Rhodium-mediated Activation and Borylation Reactions of Fluorinated Olefins / Conghui Xu." Berlin : Humboldt-Universität zu Berlin, 2020. http://d-nb.info/1222973480/34.

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Gunawardhana, Kihanduwage N. Gipson Stephen L. "Chemistry, electrochemistry and electron transfer induced reactions of cobalt complexes with fluorinated ligands." Waco, Tex. : Baylor University, 2007. http://hdl.handle.net/2104/5114.

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Thesis (Ph.D.)--Baylor University, 2007.<br>In the abstract "CF3COCo(CO)3PPh3, CF3, Bu3SnH, CF3H, [Co(CO)4]-, [Co(CO)3(PPh3)]-, C2F4, C6F5Co(CO)3PPh3, C6F5, C6F5H, C6F5D, CF3COCo(CO)3PPh3, and Co-C(acyl)" are subscript. Includes bibliographical references (p. 205-213).
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Mazumder, Shrila. "Laser flash photolysis studies of chlorine atom reactions with fluorinated propenes and methyl amines." Thesis, Georgia Institute of Technology, 2014. http://hdl.handle.net/1853/52308.

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The research addresses two groups of reactions: chlorine atom reactions with fluorinated propenes and methyl amines. Most of the reactions were studied over a range of temperature and pressure with the goals of (i) assessing the potential importance of the reactions in atmospheric chemistry and (ii) obtaining kinetic and thermochemical information of fundamental physical–chemical interest. In the studies reported herein, laser flash photolysis (LFP) was coupled with time resolved atomic resonance fluorescence (RF) spectroscopic detection of chlorine atoms to investigate chlorine atom kinetic
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Seeley, A. J. "New studies of reactions of metal atoms with fluorinated arenes and, in part, with carbenoid species." Thesis, University of Bristol, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.357892.

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Books on the topic "Reactions of fluorinated"

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Callan, Alison Marion. The synthesis and reactions of fluorinated aromatics. University of Birmingham, 1996.

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Yarwood, Thomas David. The synthesis and reactions of lightly fluorinated benzenes. University of Birmingham, 1992.

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Rees, Anthony John. The synthesis and reactions of some fluorinated nitrogen-containing heterocycles. University of Birmingham, 1996.

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Stansfield, Kevin. Diels-alder reactions of fluoroalkenes: New strategy and tactics in the synthesis of fluorinated carbocycles. University of Birmingham, 1996.

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B, DeMore William, and United States. National Aeronautics and Space Administration., eds. Temperature-dependent rate constants and substituent effects for the reactions of hydroxyl radicals with three partially fluorinated ethers. 2nd ed. National Aeronautics and Space Administration, 1995.

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B, DeMore William, and United States. National Aeronautics and Space Administration., eds. Temperature-dependent rate constants and substituent effects for the reactions of hydroxyl radicals with three partially fluorinated ethers. 2nd ed. National Aeronautics and Space Administration, 1995.

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Temperature-dependent rate constants and substituent effects for the reactions of hydroxyl radicals with three partially fluorinated ethers. 2nd ed. National Aeronautics and Space Administration, 1995.

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Temperature-dependent rate constants and substituent effects for the reactions of hydroxyl radicals with three partially fluorinated ethers. 2nd ed. National Aeronautics and Space Administration, 1995.

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Book chapters on the topic "Reactions of fluorinated"

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Shinde, Sandip S., S. N. Thore, Rajendra P. Pawar, K. L. Ameta, and Sunil N. Patil. "Synthesis of Fluorinated Heterocycles via Multicomponent Reactions." In Multicomponent Reactions. CRC Press, 2017. http://dx.doi.org/10.1201/9781315369754-7.

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Hiyama, Tamejiro, and Hisashi Yamamoto. "Organic Reactions with Fluorinated Reagents." In Organofluorine Compounds. Springer Berlin Heidelberg, 2000. http://dx.doi.org/10.1007/978-3-662-04164-2_8.

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Mikami, Koichi, Yoshimitsu Itoh, and Masahiro Yamanaka. "Fluorinated Synthon: Asymmetric Catalytic Reactions." In ACS Symposium Series. American Chemical Society, 2005. http://dx.doi.org/10.1021/bk-2005-0911.ch020.

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Chambers, R. D., and J. F. S. Vaughan. "Nucleophilic reactions of fluorinated alkenes." In Organofluorine Chemistry. Springer Berlin Heidelberg, 1997. http://dx.doi.org/10.1007/bfb0119264.

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Améduri, Bruno, and Bernard Boutevin. "Telomerisation Reactions of fluorinated alkenes." In Organofluorine Chemistry. Springer Berlin Heidelberg, 1997. http://dx.doi.org/10.1007/bfb0119267.

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Hack, Walter, Markus Hold, Karlheinz Hoyermann, Igor I. Morozov, and Evgenii S. Vasiliev. "Fluorinated Radical Reactions of Atmospheric Importance." In Global Atmospheric Change and its Impact on Regional Air Quality. Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-0082-6_16.

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Shestopalov, Anatoliy M., Lyudmila A. Rodinovskaya, Alexander A. Shestopalov, Anna V. Gromova, Aleksander E. Fedorov, and Andrei A. Gakh. "Synthesis and Reactions of Fluorinated Nicotinonitriles." In ACS Symposium Series. American Chemical Society, 2009. http://dx.doi.org/10.1021/bk-2009-1003.ch012.

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Burgess, D. R. F., M. R. Zachariah, Wing Tsang, and P. R. Westmoreland. "Key Species and Important Reactions in Fluorinated Hydrocarbon Flame Chemistry." In ACS Symposium Series. American Chemical Society, 1997. http://dx.doi.org/10.1021/bk-1995-0611.ch025.

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Harvey, Jonelle. "Photodissociation Dynamics of Four Fluorinated Ethenes: Fast, Slow, Statistical and Non-statistical Reactions." In Springer Theses. Springer International Publishing, 2013. http://dx.doi.org/10.1007/978-3-319-02976-4_5.

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Phillips, Robert S., Robert L. Von Tersch, Joel G. Fletcher, and Ah H. Lai. "Enzymatic synthesis and biochemical reactions of fluorinated analogues of L-tyrosine and L-dopa." In Amino Acids. Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-011-2262-7_20.

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Conference papers on the topic "Reactions of fluorinated"

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Mehta, Narinder K., Vinod S. Agarwala, Airan Perez, and K. S. Rajan. "Fluorinated Schiff Base Compound as Corrosion Inhibitor for Steel." In CORROSION 1995. NACE International, 1995. https://doi.org/10.5006/c1995-95491.

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A study to evaluate wear and corrosion inhibition, and the mode of molecular bonding of a fluorinated schiff base compound (imine compounds), a condensation reaction product of 4-fluorobenzaldehyde and 4,4'-benzidine, onto AISI 1010 steel surface was undertaken to develop a new lubricant additive for greases. Physical vapor adsorption and chemisorption techniques were used for the deposition of schiff base on the metal surface. The schiff base was found to adhere best with the physical adsorption technique. It involved heating of freshly cleaned specimens suspended over schiff base in an all-g
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Soejima, Takao, Katsuyuki Okubo, Ken’ichi Hiratsuka, and Yukihiro Sakamoto. "Tribochemical Polishing of Aluminum Oxide in the Atmosphere of CHF3." In World Tribology Congress III. ASMEDC, 2005. http://dx.doi.org/10.1115/wtc2005-64041.

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Fluorinated hydrocarbon has been used as lubricants on the surface of magnetic hard disk drive. This is because this compound is thermally stable. However it has been found that fluorinated hydrocarbon was degraded on the surface during friction to generate radicals1,2). Therefore we considered that hard ceramics will be worn out in the gaseous atmosphere of fluorinated hydrocarbon by radical reactions. If the interaction of gas to ceramics is strong, we can expect that the surface will be polished through tribochemical processes. In the present paper, we investigated the characteristic of tri
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Hudgens, Jeffrey W., Jeffrey L. Brum, Russell D. Johnson, and David V. Dearden. "Structure Matters: Detection of Difluoromethyl and Difluoroethyl Radicals by Resonance Enhanced Multiphoton Ionization Spectroscopy." In Laser Applications to Chemical Analysis. Optica Publishing Group, 1994. http://dx.doi.org/10.1364/laca.1994.fa.4.

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The link between anthropogenic chlorofluorocarbon (CFC) release and stratospheric ozone depletion now appears well established. Several fluorinated methanes and ethanes are among the hydrofluorocarbons (HFCs) currently being investigated as replacements for the chlorine containing congeners that have traditionally found use as refrigerants, fire extinguishers, and in more specialized applications. In recent years significant effort has focused on the tropospheric degradation pathways available to HFCs initiated by H atom abstraction by a hydroxyl radical. For alternate CFC's the generic initia
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Thiemann, Thies, Christian Burmester, Kodai Shiine, and Shuntaro Mataka. "From Suzuki-Miyaura cross coupling reactions of 2-bromo- and 4-bromoestranes to fluorinated benzofuranoestranes." In The 17th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2013. http://dx.doi.org/10.3390/ecsoc-17-a028.

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Gelhausen, Marius G., Safa Kutup Kurt, and Norbert Kockmann. "Mixing and Heat Transfer in Helical Capillary Flow Reactors With Alternating Bends." In ASME 2014 12th International Conference on Nanochannels, Microchannels, and Minichannels collocated with the ASME 2014 4th Joint US-European Fluids Engineering Division Summer Meeting. American Society of Mechanical Engineers, 2014. http://dx.doi.org/10.1115/icnmm2014-21779.

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Capillary flow is often occurring in natural and technical systems. Due to small diameter channels, laminar flow is established, while heat transfer is high from large specific surface area. For chemical reactions, good mixing and a narrow residence time distribution are important for high selectivity and yield. To improve mixing and residence time distribution, several measures of bend flow, helical arrangements and curved capillaries are proposed in literature. This contribution describes the flow, residence time distribution, and its influence on chemical reactions in short helical, alterna
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Morishima, Naohiko, and Yuji Takahashi. "PREPARATION AND REACTION OF FLUORINATED GLUCOFURANOSYL FLUORIDES." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.628.

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Mayer, Kevin, Channing West, Reilly Sonstrom, Martin Holdren, Haley Scolati, and Brooks Pate. "REACTION CHEMISTRY OF EPOXIDES WITH FLUORINATED CARBOXYLIC ACIDS." In 2020 International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2020. http://dx.doi.org/10.15278/isms.2020.wk06.

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Mayer, Kevin, Channing West, Reilly Sonstrom, Martin Holdren, Haley Scolati, and Brooks Pate. "REACTION CHEMISTRY OF EPOXIDES WITH FLUORINATED CARBOXYLIC ACIDS." In 2021 International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2021. http://dx.doi.org/10.15278/isms.2021.fm04.

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Kumar, A., H. Bakhru, A. W. Haberl, R. A. Carpio, and A. Ricci. "Characterization of fluorinated silicon dioxide films by nuclear reaction analysis and optical techniques." In The fourteenth international conference on the application of accelerators in research and industry. AIP, 1997. http://dx.doi.org/10.1063/1.52543.

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Liu, Shuyan, Yabin Zhang, Congcong Zhai, et al. "Synthesis and Properties of a Novel Fluorinated Surfactant via “Thiol-ene” Click Reaction." In The Second International Conference on Materials Chemistry and Environmental Protection. SCITEPRESS - Science and Technology Publications, 2018. http://dx.doi.org/10.5220/0008185400550058.

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