Academic literature on the topic 'Reactive distillation'

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Journal articles on the topic "Reactive distillation"

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Kalakuntala, Raju, R. Navya, T. Sisira, V. V. Basava Rao, and Srinath Surnani. "Experimental studies on reactive distillation of propionic acid using n-butanol as entrained." International Journal of Engineering & Technology 7, no. 3.29 (2018): 46. http://dx.doi.org/10.14419/ijet.v7i3.29.18459.

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Reactive distillation is a cost effective chemical engineering process intensification method which involves the reaction and separation simultaneously in a single unit. In the present work the system selected was Propionic acid and n-butanol which undergoes esterification reaction to form butyl propionate. Propionic acid is an important raw material from a biodegradable polymer. The experiments were done in both conventional batch distillation and reactive distillation. In conventional batch distillation no catalyst were used were as in reactive distillation amberlite catalyst used with vario
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Malone, Michael F., and Michael F. Doherty. "Reactive Distillation." Industrial & Engineering Chemistry Research 39, no. 11 (2000): 3953–57. http://dx.doi.org/10.1021/ie000633m.

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Zhang, Xin, Ping He, and Hao Li. "Research progress in reactive distillation." Advanced Separation Technology 1, no. 1 (2023): 1–7. http://dx.doi.org/10.61187/ast.v1i1.3.

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As a special distillation process, reactive distillation technology has been widely used in the petrochemical field due to its outstanding advantages such as high efficiency and energy saving. It has been paid more and more attention from researchers in the field of chemical process enhancement since the 1920s. With the progress of social development level, resource conservation and environmental friendliness have become the general trend. In order to pursue the maximization of energy utilization and higher economic benefits, scientific researchers have developed a variety of new reactive dist
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Sudibyo, Sudibyo, Muhamad Nazri Murat, and Norashid Aziz. "Neural Wiener Based Model Predictive Control (NWMPC) for MTBE Catalytic Distillation Using Reduced Sequential Quadratic Programming (RSQP)." Advanced Materials Research 1113 (July 2015): 733–38. http://dx.doi.org/10.4028/www.scientific.net/amr.1113.733.

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Reactive distillation is a process that combines both reactor and distillation column in one unit process. The reactive distillation is normally applied in MTBE production in order to achieve high reaction conversion and purity of the MTBE. Controlling such reactive distillation is a challenging task due to its highly nonlinear behavior and the existence of strong interactions among control variables. In this work, a Neural Wiener based model predictive control (NWMPC) is designed and implemented to control the tray temperature of MTBE reactive distillation. The Reduced SQP (RSQP) has been emb
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Šulgan, Branislav, Juraj Labovský, and Zuzana Labovská. "Multi-Aspect Comparison of Ethyl Acetate Production Pathways: Reactive Distillation Process Integration and Intensification via Mechanical and Chemical Approach." Processes 8, no. 12 (2020): 1618. http://dx.doi.org/10.3390/pr8121618.

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This paper provides a multi-aspect comparison of selected methods of ethyl acetate production and shows the possibility of further reactive distillation process integration and sophisticated intensification including process stream regeneration. The production pathways were selected with respect to their practical applicability and sufficient experimental and feasibility studies already published. A total of four case studies were designed and compared: conventional process set-up (ethyl acetate is produced in a chemical reactor) is designed as a base case study; reactive distillation with a s
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Dr., Dipak K. Chandre, Sushant S. Kurhe Mr., Shradha V. Nikam Dr., and Ganesh B. Shinde Dr. "Design parameter for Reactive Distillation Column using etherification reaction with ion exchange resin." International Journal of Scientific Development and Research 9, no. 2 (2024): 552–59. https://doi.org/10.5281/zenodo.11240429.

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Nowadays Reactive Distillation is widely used as alternative for conventional distillation. In this work we have to suggest a new technique in Distillation technology rather than ordinary distillation process. Reactive Distillation technology sounds azeotrope system such as synthesis of ETBE, MTBE, and Methyl Acetate where more than one azeotropes are formed. In this work we have concentrate on all theoretical and basic experimental data which will be useful for some rigorous experimentation and process simulation work.
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Muthia, Rahma. "Structured Data Management for Investigating an Optimum Reactive Distillation Design." ADI Journal on Recent Innovation (AJRI) 5, no. 1 (2023): 34–42. http://dx.doi.org/10.34306/ajri.v5i1.899.

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Reaction and separation are the two most important processes in the chemical industry that significantly affect the overall energy and cost requirements. Therefore, the operation of integrated reactive separation in a single equipment, such as reactive distillation, potentially increases the chemical process efficiency remarkably. To achieve that advantage, it is vital to design an optimum reactive distillation configuration in the preliminary evaluation. This paper proposes structured data management that can be used to encounter an optimum reactive distillation design. The approach simplifie
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Taylor, R., and R. Krishna. "Modelling reactive distillation." Chemical Engineering Science 55, no. 22 (2000): 5183–229. http://dx.doi.org/10.1016/s0009-2509(00)00120-2.

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Stichlmair, Johann, and Thomas Frey. "Reactive Distillation Processes." Chemical Engineering & Technology 22, no. 2 (1999): 95–103. http://dx.doi.org/10.1002/(sici)1521-4125(199902)22:2<95::aid-ceat95>3.0.co;2-#.

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Wang, Liang, Xiaoyan Sun, Li Xia, Jianping Wang, and Shuguang Xiang. "Inside–Out Method for Simulating a Reactive Distillation Process." Processes 8, no. 5 (2020): 604. http://dx.doi.org/10.3390/pr8050604.

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Reactive distillation is a technical procedure that promotes material strengthening and its simulation plays an important role in the design, research, and optimization of reactive distillation. The solution to the equilibrium mathematical model of the reactive distillation process involves the calculation of a set of nonlinear equations. In view of the mutual influence between reaction and distillation, the nonlinear enhancement of the mathematical model and the iterative calculation process are prone to fluctuations. In this study, an improved Inside–Out method was proposed to solve the reac
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Dissertations / Theses on the topic "Reactive distillation"

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Spatschek, Raymond. "Investigations into reactive distillation systems." Thesis, University of Newcastle Upon Tyne, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.283075.

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Wierschem, Matthias [Verfasser]. "Enzymatic Reactive Distillation / Matthias Wierschem." München : Verlag Dr. Hut, 2018. http://d-nb.info/1168534941/34.

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Sneesby, Martin G. "Simulation and control of reactive distillation." Thesis, Curtin University, 1998. http://hdl.handle.net/20.500.11937/2555.

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Reactive distillation has enormous potential for the economical synthesis of tertiary ethers. Methyl tert-butyl ether (MTBE) has been commercially produced with this technology since the early 1980s and it appears that the process also has application for Ethyl tert-butyl ether (ETBE) and other ethers. However, the combination of reaction and distillation in a single unit operation produces a process complexity that inhibits expeditious design and tight control, and presents a technology risk for potential developers. This particularly applies to hybrid reactive distillation where both reactiv
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Sneesby, Martin G. "Simulation and control of reactive distillation." Curtin University of Technology, School of Chemical Engineering, 1998. http://espace.library.curtin.edu.au:80/R/?func=dbin-jump-full&object_id=10629.

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Reactive distillation has enormous potential for the economical synthesis of tertiary ethers. Methyl tert-butyl ether (MTBE) has been commercially produced with this technology since the early 1980s and it appears that the process also has application for Ethyl tert-butyl ether (ETBE) and other ethers. However, the combination of reaction and distillation in a single unit operation produces a process complexity that inhibits expeditious design and tight control, and presents a technology risk for potential developers. This particularly applies to hybrid reactive distillation where both reactiv
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Schenk, Myrian Andrea. "Design of operable reactive distillation columns." Thesis, University College London (University of London), 1999. http://discovery.ucl.ac.uk/1382008/.

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Reactive distillation is an integrated process which considers simultaneous physical and chemical transformations. It is increasingly receiving attention both from industry and academia. Significant advances have been made in the area of modelling and simulation as well as the implementation of such units industrially. However, the area of control and optimisation of such units has not been explored thoroughly. The thesis presents a general framework for simulation and design, which can handle reactive and non-reactive systems. Various different aspects of the modelling and simulation of disti
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Daniel, Guido. "Conceptual design of reactive distillation processes." Thesis, University of Manchester, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.503083.

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Integrated processes such as reactive distillation offer the potential for reduced capital and operating costs compared to conventional flowsheets. In this work new tools for the identification of the optimal reactive distillation process with the optimal degree of integration are developed. A conceptual design method based on the boundary value method is used for a set of reactive distillation processes. The combination of a reactive distillation column with a pre-reactor is a valuable alternative to standalone reactive distillation columns. This thesis presents an approach to identify promis
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Hidalgo-Vivas, Angelica. "Reactive distillation for middle distillates hydrotreatment." Thesis, University of Manchester, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.680181.

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Kühn, Steffen [Verfasser], and Andreas [Akademischer Betreuer] Liese. "Reaction engineering in biocatalytic reactive distillation / Steffen Kühn ; Betreuer: Andreas Liese." Hamburg : Universitätsbibliothek der Technischen Universität Hamburg-Harburg, 2018. http://d-nb.info/1173788824/34.

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Todd, Heather Elizabeth. "Investigating catalyst performance in batch reactive distillation." Thesis, University of Newcastle Upon Tyne, 2011. http://hdl.handle.net/10443/1244.

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Reactive distillation (RD) combines chemical synthesis with separation by distillation, but this leads to a non-trivial system: the hardware selection, the system components, the mode of operation and the operating conditions all affect the performance of the RD process. A key process development issue is the identification of suitable catalysts that perform well under reactive distillation conditions, as catalysts are crucial for increasing reaction rate when operating temperature range is limited by evaporation. The main goal of this research is to develop a method, utilizing high throughput
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Murat, Muhamad Nazri. "Novel catalytic structures for reactive distillation processes." Thesis, University of Manchester, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.527418.

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Books on the topic "Reactive distillation"

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1956-, Yu Cheng-Ching, ed. Reactive distillation design and control. John Wiley, 2008.

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Luyben, William L. Reactive distillation design and control. John Wiley, 2008.

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name, No. Reactive distillation: Status and future directions. Wiley-VCH, 2003.

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Max-Planck-Institut. Reactive distillation: Status and future directions. Wiley-VCH, 2003.

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Almeida-Rivera, Cristhian Pau l. Designing reactive distillation processes with improved efficiency: Economy, exergy loss and responsiveness. s.n.], 2005.

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Sakhre, Vandana, and Uday Pratap Singh. Reactive Distillation. De Gruyter, 2022. http://dx.doi.org/10.1515/9783110656268.

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Sundmacher, Kai, and Achim Kienle, eds. Reactive Distillation. Wiley, 2002. http://dx.doi.org/10.1002/3527600523.

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Luyben, William L., and Cheng-Ching Yu. Reactive Distillation Design and Control. American Institute of Chemical Engineers, 2009.

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Luyben, William L., and Cheng-Ching Yu. Reactive Distillation Design and Control. Wiley & Sons, Incorporated, John, 2009.

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Reactive Distillation Design and Control. Wiley & Sons, Incorporated, John, 2008.

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Book chapters on the topic "Reactive distillation"

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Kiss, Anton A. "Reactive Distillation Technology." In Process Intensification for Green Chemistry. John Wiley & Sons, Ltd, 2013. http://dx.doi.org/10.1002/9781118498521.ch9.

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Kiss, Anton Alexandru. "Reactive Distillation Technology." In Process Intensification Technologies for Biodiesel Production. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03554-3_5.

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Kolah, Aspi K., Carl T. Lira, and Dennis J. Miller. "Reactive Distillation for the Biorefinery." In Separation and Purification Technologies in Biorefineries. John Wiley & Sons, Ltd, 2013. http://dx.doi.org/10.1002/9781118493441.ch16.

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Orjuela, Alvaro, Miguel A. Santaella, and Paola A. Molano. "Process Intensification by Reactive Distillation." In Process Intensification in Chemical Engineering. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-28392-0_6.

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Huang, Hsiao-Ping, I.-Lung Chien, and Hao-Yeh Lee. "Plantwide Control of a Reactive Distillation Process." In Plantwide Control. John Wiley & Sons, Ltd, 2012. http://dx.doi.org/10.1002/9781119968962.ch15.

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Wierschem, Matthias, Mathias Leimbrink, Mirko Skiborowski, Rene Heils, Irina Smirnova, and Andrzej Górak. "CHAPTER 10. Enzymatic Reactive Absorption and Distillation." In Intensification of Biobased Processes. Royal Society of Chemistry, 2018. http://dx.doi.org/10.1039/9781788010320-00210.

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Stinn, Caspar, Spencer Toll, and Antoine Allanore. "Aluminothermic Reduction of Sulfides via Reactive Vacuum Distillation." In Light Metals 2022. Springer International Publishing, 2022. http://dx.doi.org/10.1007/978-3-030-92529-1_89.

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Keller, Tobias. "Reactive Distillation." In Distillation. Elsevier, 2014. http://dx.doi.org/10.1016/b978-0-12-386878-7.00008-5.

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"Chapter 1 Introduction." In Reactive Distillation. De Gruyter, 2022. http://dx.doi.org/10.1515/9783110656268-001.

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"Contents." In Reactive Distillation. De Gruyter, 2022. http://dx.doi.org/10.1515/9783110656268-toc.

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Conference papers on the topic "Reactive distillation"

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Huerta-Rosas, Brenda, Melanie Coronel-Mu�oz, Juan Jos� Quiroz-Ram�rez, et al. "Intensified Alternative for Sustainable Gamma-Valerolactone Production from Levulinic Acid." In The 35th European Symposium on Computer Aided Process Engineering. PSE Press, 2025. https://doi.org/10.69997/sct.167219.

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An intensified approach to ?-valerolactone (GVL) production is achieved using a reactive distillation column. Conventional methods require multiple units, leading to high energy consumption, costs, and limited scalability. The proposed technology integrates reaction and separation into a single unit, enhancing process efficiency for biomass-derived chemicals. A multiobjective optimization framework balances economic, environmental, and operational goals, reducing total annual cost (TAC) by 43% and environmental impact (EI99) by 45% compared to conventional processes. Additionally, energy consu
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Fioravante, Igor F., Riann de Q. N�brega, Rubens Maciel Filho, and Jean F. Leal Silva. "Design and Cost Analysis of a Reactive Distillation Column to Produce Ethyl Levulinate Using Excess Levulinic Acid." In The 35th European Symposium on Computer Aided Process Engineering. PSE Press, 2025. https://doi.org/10.69997/sct.198461.

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Despite the potential of electrification in transportation, diesel will remain one of the main fuels for decades. The replacement of diesel with biodiesel is one of the solutions to decrease the net emissions of diesel engines. However, biodiesel has limited performance in cold weather and requires fuel additives. In this context, choosing additives from non-edible, inexpensive, renewable sources is important. Ethyl levulinate, an ester derived from levulinic acid that can be produced from sugarcane, is a promising option because it improves the cold-flow properties of fuels and reduces soot e
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Vel�zquez, Josu� J. Herrera, J. Rafael Alc�ntara Avila, Salvador Hern�ndez, and Juli�n Cabrera Ruiz. "Evaluation of the Controllability of Distillation with Multiple Reactive Stages." In The 35th European Symposium on Computer Aided Process Engineering. PSE Press, 2025. https://doi.org/10.69997/sct.120398.

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Intensified schemes, such as reactive distillation, have been proposed to produce silane (SiH4). Several studies have been carried out around this intensified scheme focusing directly on its improvement in energy or economic criteria. However, these mentioned criteria do not ensure that the scheme is also optimal from the control point of view. There is a direct compromise between the economic criterion and the control criterion. Thus, the best controllable scheme is not necessarily the most economical and vice versa. Analyses have been proposed to evaluate the controllability of steady-state
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Yoon, Yuhchae, Hui Li, and Kwei Meng Yap. "Naphthenic Acid Corrosion and Sulfidic Corrosion in Crude Oil Fractions." In CONFERENCE 2022. AMPP, 2022. https://doi.org/10.5006/c2022-17533.

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ABSTRACT Crude Corrosivity issues manifest themselves at locations where fluid flow rates and velocities are relatively high in atmospheric distillation units, vacuum distillation units, transfer lines, valves, baffles, heat exchangers, and side cut piping in refinery systems. The heavy vacuum gas oil fraction of the vacuum distillation plant is the crude fraction which usually has the highest total acid number (TAN) due to high concentration of naphthenic acids close to their boiling points. This mechanism of non-aqueous corrosion in the presence of crude oil or oil fractions with high quanti
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Vel�zquez, Josu� J. Herrera, Erik L. Pi��n Hern�ndez, Luis A. Vega, Dana E. Carrillo Espinoza, J. Rafael Alc�ntara Avila, and Juli�n Cabrera Ruiz. "Comparative and Statistical Study on Aspen Plus Interfaces Used for Stochastic Optimization." In The 35th European Symposium on Computer Aided Process Engineering. PSE Press, 2025. https://doi.org/10.69997/sct.102858.

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New research on complex intensified distillation schemes has popularized the use of several commercial process simulation software. The interfaces between process simulation and optimization-oriented software have allowed the use of rigorous and robust models. This type of optimization is mentioned in the literature as "Black Box Optimization", since successive evaluations exploits the information from the simulator without altering the model that represents the given process. Among process simulation software, Aspen Plus� has become popular due to their rigorous calculations, model customizat
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Toba, Kazuhiro, Satoshi Tokuoka, and Shinji Miyamoto. "A New Prediction Tool for Sulfidation Corrosion in Crude Units." In CORROSION 2021. AMPP, 2021. https://doi.org/10.5006/c2021-16762.

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Abstract A new prediction tool was developed for sulfidation corrosion applied in crude units. The corrosion rate of sulfidation is predicted using the total sulfur concentration and temperature by the modified McConomy curves. However, the corrosion behavior in crudes even with the same total sulfur concentration is sometimes different. This is because the corrosion rate might be affected by reactive sulfur compounds in particular crudes. This study was conducted to enhance prediction technique using a new factor replaced with the total sulfur concentration. For the target crude oils, diesel,
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Yoon, Yuhchae, and Sridhar Srinivasan. "A Review of Naphthenic Acid Corrosion and Sulfidic Corrosion in Crude Oil Refining Applications." In CORROSION 2019. NACE International, 2019. https://doi.org/10.5006/c2019-13443.

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Abstract Corrosion problems related to crude refining became a dominant concern as crude oil refining expanded to serve global energy demands with concomitant economic benefits in the petroleum industry, and more so with the availability of ‘opportunity crudes'. Reducing oil production costs have continuously forced refineries to look for so-called “opportunity” or “alternate” crudes, which are usually lower quality, higher corrosivity crude oils with higher levels of naphthenic acids and sulfur compounds. Processing of these high acid, high sulfur crudes has engendered significant corrosion c
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Patel, Amit, Jesse Contreras, John Green, and John Wodarcyk. "Physical Fouling inside a Crude Unit Overhead from a Reaction Byproduct of Hexahydro-1,3,5-Tris(2-Hydroxyethyl)-S-triazine Hydrogen Sulfide Scavenger." In CORROSION 2015. NACE International, 2015. https://doi.org/10.5006/c2015-06054.

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Abstract Monoethanolamine (MEA) hydrochloride salts, which are formed from the use of hexahydro-1,3,5-tris(2-hydroxyethyl)-s-triazine (commonly referred to as MEA triazine), a hydrogen sulfide scavenger, can create major corrosion issues inside an atmospheric crude oil distillation unit. Recently, deposit formation has been observed in a crude unit processing significant quantities of tight oil; these deposits result from polymerization of dithiazines (a reaction byproduct of MEA triazine) in the presence of hydrogen sulfide. Such fouling has been reported in upstream applications. This paper
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Bota, Gheorghe, Peng Jin, Fernando Farelas, and Winston Robbins. "Phosphate Esters Inhibitors in Naphthenic Acid Corrosion – an Experimental Evaluation." In CORROSION 2019. NACE International, 2019. https://doi.org/10.5006/c2019-13491.

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Abstract Crude oils with a total acid number (TAN) higher than 0.5 are highly corrosive at temperatures between 400 and 700°F found in atmospheric and vacuum distillations of oil refineries. The destructive effects of naphthenic acids (NAP) occur in the same temperature range as sulfidation corrosion due to reactive sulfur compounds also contained in crude oils. Efforts of mitigating NAP corrosion of existing equipment by a high TAN oil include blending with crudes of lower acids content, neutralization or removal of naphthenic acids, and the use of corrosion inhibitors. Phosphate esters are c
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Morach, R., and M. Büchler. "Analysis of Welded Stainless Steels and Nickel Base Alloys Using a Locally Resolving Electrochemical Sensor." In CORROSION 2004. NACE International, 2004. https://doi.org/10.5006/c2004-04232.

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Abstract The patented electrochemical cell built into a pen permits the non-destructive examination of individual surface areas. The small tip of the pen of approx. 1.5mm2 allows positioning the sensor on any surface geometry and thus achieving locally resolved measurements. So far, the examination of welded pieces was restricted to special fabricated specimens or the analysis of the complete weld and the adjacent surface. The pen-type cell was used to examine welded plates made from standard stainless steel grades. The examination of the weld metal, the heat affected zone and the base materia
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Reports on the topic "Reactive distillation"

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Fields, Nathan, Dennis J. Miller, Navinchandra S. Asthana, Aspi K. Kolah, Dung Vu, and Carl T. Lira. Reactive Distillation for Esterification of Bio-based Organic Acids. Office of Scientific and Technical Information (OSTI), 2008. http://dx.doi.org/10.2172/937553.

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