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1

Spatschek, Raymond. "Investigations into reactive distillation systems." Thesis, University of Newcastle Upon Tyne, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.283075.

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2

Wierschem, Matthias [Verfasser]. "Enzymatic Reactive Distillation / Matthias Wierschem." München : Verlag Dr. Hut, 2018. http://d-nb.info/1168534941/34.

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3

Sneesby, Martin G. "Simulation and control of reactive distillation." Thesis, Curtin University, 1998. http://hdl.handle.net/20.500.11937/2555.

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Reactive distillation has enormous potential for the economical synthesis of tertiary ethers. Methyl tert-butyl ether (MTBE) has been commercially produced with this technology since the early 1980s and it appears that the process also has application for Ethyl tert-butyl ether (ETBE) and other ethers. However, the combination of reaction and distillation in a single unit operation produces a process complexity that inhibits expeditious design and tight control, and presents a technology risk for potential developers. This particularly applies to hybrid reactive distillation where both reactiv
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4

Sneesby, Martin G. "Simulation and control of reactive distillation." Curtin University of Technology, School of Chemical Engineering, 1998. http://espace.library.curtin.edu.au:80/R/?func=dbin-jump-full&object_id=10629.

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Reactive distillation has enormous potential for the economical synthesis of tertiary ethers. Methyl tert-butyl ether (MTBE) has been commercially produced with this technology since the early 1980s and it appears that the process also has application for Ethyl tert-butyl ether (ETBE) and other ethers. However, the combination of reaction and distillation in a single unit operation produces a process complexity that inhibits expeditious design and tight control, and presents a technology risk for potential developers. This particularly applies to hybrid reactive distillation where both reactiv
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5

Schenk, Myrian Andrea. "Design of operable reactive distillation columns." Thesis, University College London (University of London), 1999. http://discovery.ucl.ac.uk/1382008/.

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Reactive distillation is an integrated process which considers simultaneous physical and chemical transformations. It is increasingly receiving attention both from industry and academia. Significant advances have been made in the area of modelling and simulation as well as the implementation of such units industrially. However, the area of control and optimisation of such units has not been explored thoroughly. The thesis presents a general framework for simulation and design, which can handle reactive and non-reactive systems. Various different aspects of the modelling and simulation of disti
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6

Daniel, Guido. "Conceptual design of reactive distillation processes." Thesis, University of Manchester, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.503083.

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Integrated processes such as reactive distillation offer the potential for reduced capital and operating costs compared to conventional flowsheets. In this work new tools for the identification of the optimal reactive distillation process with the optimal degree of integration are developed. A conceptual design method based on the boundary value method is used for a set of reactive distillation processes. The combination of a reactive distillation column with a pre-reactor is a valuable alternative to standalone reactive distillation columns. This thesis presents an approach to identify promis
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7

Hidalgo-Vivas, Angelica. "Reactive distillation for middle distillates hydrotreatment." Thesis, University of Manchester, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.680181.

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8

Kühn, Steffen [Verfasser], and Andreas [Akademischer Betreuer] Liese. "Reaction engineering in biocatalytic reactive distillation / Steffen Kühn ; Betreuer: Andreas Liese." Hamburg : Universitätsbibliothek der Technischen Universität Hamburg-Harburg, 2018. http://d-nb.info/1173788824/34.

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9

Todd, Heather Elizabeth. "Investigating catalyst performance in batch reactive distillation." Thesis, University of Newcastle Upon Tyne, 2011. http://hdl.handle.net/10443/1244.

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Reactive distillation (RD) combines chemical synthesis with separation by distillation, but this leads to a non-trivial system: the hardware selection, the system components, the mode of operation and the operating conditions all affect the performance of the RD process. A key process development issue is the identification of suitable catalysts that perform well under reactive distillation conditions, as catalysts are crucial for increasing reaction rate when operating temperature range is limited by evaporation. The main goal of this research is to develop a method, utilizing high throughput
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10

Murat, Muhamad Nazri. "Novel catalytic structures for reactive distillation processes." Thesis, University of Manchester, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.527418.

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11

Stein, Erik [Verfasser]. "Synthesis of Reactive Distillation Processes / Erik Stein." Aachen : Shaker, 2003. http://d-nb.info/1181602440/34.

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12

Biller, Nicholas Charles Trinder. "Modelling and control of reactive distillation processes." Thesis, University College London (University of London), 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.405850.

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13

Dragomir, Ramona Manuela. "Synthesis and design of reactive distillation columns." Thesis, University of Manchester, 2004. http://www.manchester.ac.uk/escholar/uk-ac-man-scw:230198.

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During the past decades, reactive distillation has received intensive attention due to the well known benefits of integrating distillation with reaction in a single unit. Significant capital savings, improved conversion and selectivity, avoidance of azeotropes, together with heat integration are some of the main advantages of using reactive distillation. Many applications have proven to be economically advantageous by using reactive distillation (e.g. MTBE and TAME synthesis, production of methyl-acetate, manufacture of di-isopropyl-ether, oligomerisation of linear butenes and others). Whereas
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14

MIAO, PEIZHI. "MODELING, STABILITY AND DYNAMICS OF REACTIVE DISTILLATION." University of Cincinnati / OhioLINK, 2000. http://rave.ohiolink.edu/etdc/view?acc_num=ucin974208955.

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15

Yalcin, Ozgen. "Production Of Lactic Acid Esters By Reactive Distillation." Master's thesis, METU, 2011. http://etd.lib.metu.edu.tr/upload/12613618/index.pdf.

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The esterification of lactic acid with ethanol over Lewatit S 100, strong cation ion exchange resin catalyst, was studied in counter current vapor-liquid contactor type differential reactor by feeding ethanol and lactic acid solution as vapor and liquid phases, respectively. The ethanol vapor phase was diluted by dry air and the water removal was achieved by the mass transfer of water from liquid to vapor phase. Effect of ethanol to lactic acid feed molar ratio and vapor flow rate on fractional conversion and water removal efficiency were tested at 40-70&deg<br>C of column temperature range.
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16

Houge, Emilie Oritsland. "Reactive Distillation of Biodiesel: Modelling and Optimal Operation." Thesis, Norges teknisk-naturvitenskapelige universitet, Institutt for kjemisk prosessteknologi, 2013. http://urn.kb.se/resolve?urn=urn:nbn:no:ntnu:diva-23368.

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This thesis modifies an already existing dynamic Matlab Simulink model to correlate with a Hysys model from a similar research. The models are concerned with the reactive distillation for production of biodiesel from linoleic esters of soybean oil through transesterification reactions. The Matlab model was constructed using molar balances, Francis? weir equation for the liquid dynamics, no vapour dynamics, kinetics according to the rate law and temperature estimations according to the UNIQUAC method. Very similar results were presented for the two models besides the Matlab being of simpler ori
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17

Giessler, Sabine. "Synthesis and Dynamic Optimization of Reactive Distillation Processes." Kyoto University, 2000. http://hdl.handle.net/2433/180939.

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18

Ait, Aissa Belaid. "Contribution to the synthesis of reactive distillation processes." Clausthal-Zellerfeld Papierflieger, 2008. http://d-nb.info/992300991/04.

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19

Wang, Hongqi. "Bio-oil Upgrading via High-Pressure Reactive Distillation." Thesis, Curtin University, 2020. http://hdl.handle.net/20.500.11937/82786.

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This study aims to investigate the roles of process parameters especially pressure and the major components in the high-pressure reactive distillation of bio-oil. The bio-oil distillation fraction yields and properties were evaluated to demonstrate the advantages of the distillation at elevated pressures over distillation at atmospheric pressure. The results indicate that high-pressure distillation can achieve high distillate yields with reduced polymerisation because high pressure can retain water and other light components in the liquid phase.
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Keller, Tobias [Verfasser]. "Reactive Distillation for Multiple-reaction Systems: Experimental Investigation, Modelling and Optimisation / Tobias Keller." München : Verlag Dr. Hut, 2013. http://d-nb.info/103728948X/34.

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21

Bahar, Almila. "Modeling And Control Studies For A Reactive Batch Distillation Column." Phd thesis, METU, 2007. http://etd.lib.metu.edu.tr/upload/12608344/index.pdf.

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Modeling and inferential control studies are carried out on a reactive batch distillation system for the esterification reaction of ethanol with acetic acid to produce ethyl acetate. A dynamic model is developed based on a previous study done on a batch distillation column. The column is modified for a reactive system where Artificial Neural Network Estimator is used instead of Extended Kalman Filter for the estimation of compositions of polar compounds for control purposes. The results of the developed dynamic model of the column is verified theoretically with the results of a similar study.
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Tanskanen, J. P. (Juha P. ). "Phenomenon driven process design:focus on multicomponent reactive and ordinary distillation." Doctoral thesis, Oulun yliopisto, 1999. http://urn.fi/urn:isbn:9514251458.

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Abstract This thesis describes part of the work that has been done in the Chemical Process Engineering Laboratory of the University of Oulu to systematize conceptual process design. The aim has been to develop a design methodology, i.e. how process design is done, based on a carefully elaborated concept analysis. The starting point has been that all the knowledge related to process design, i.e. not only the procedural knowledge related to the design activity itself, but also the declarative knowledge related to the design target (process) and the environment (project) in which the design is do
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23

Estrada-Villagrana, Alma Delia. "On the modeling of dynamics and operation of reactive distillation." Thesis, University College London (University of London), 2002. http://discovery.ucl.ac.uk/1317706/.

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The aim of the present project was to study the factors that affect gross scale reactive distillation behaviour and to set a useful framework for control system design of reactive distillation. A modification of an equilibrium model based on using elementary quantities instead of molar quantities was used for different steady state and dynamic simulations of reactive distillation. Furthermore, a control system design method for reactive distillation was proposed and tested. In the first part of the present study, the role of operating conditions in reactive distillation behaviour was investiga
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24

Niesbach, Alexander [Verfasser]. "Design of Reactive Distillation Processes Using Bio-based Raw Materials / Alexander Niesbach." München : Verlag Dr. Hut, 2014. http://d-nb.info/1063221722/34.

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25

Bennun, Serrano Sandra Viviana. "COMPUTER SIMULATION STUDIES FOR THE PRODUCTION OF 7-TETRADECENE BY REACTIVE DISTILLATION." MSSTATE, 2003. http://sun.library.msstate.edu/ETD-db/theses/available/etd-07222003-155936/.

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The production of 7-tetradecene was examined. Properties for this compound were estimated using group contribution methods and compared to experimental data. Process simulation was used as a tool to identify competitive processing strategies. For reactive distillation, three different models were compared to determine the model complexity needed to describe the process: Model A, with the assumption of physical and chemical equilibrium; Model B, with kinetics described by a second order reaction and physical equilibrium; and Model C, a non-equilibrium stage model that accounts for mass transfer
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Eleftheriades, Nicolas M. "A novel approach to FAME biodiesel production by means of reactive distillation." Master's thesis, University of Cape Town, 2010. http://hdl.handle.net/11427/10460.

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Includes bibliographical references (leaves 109-111).<br>A novel concept of reactive distillation is examined in this dissertation. The design and construction of a rig to test the novel set-up were executed. The design of the rig was based on residence times selected for the rig's three main sections; the pre-reactor, the column and the reboiler. The rig was designed as a continuous process, provided feed could be supplied constantly even in the case of small scale users. The reactor was designed to perform around a flowrate of 5l/hr. The main aim of the design was to produce biodiesel by usi
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27

Teo, Hue Tat Ronnie. "Recovery of dilute acetic acid through esterification in a reactive distillation column." Thesis, Loughborough University, 2005. https://dspace.lboro.ac.uk/2134/24561.

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With ever-growing environmental concerns, petrochemical and fine chemical industries face an omnipresent issue in recovering acetic acid from its aqueous solutions. The recovery of acetic acid through the esterification process is a very viable option. However, esterification reactions are typically restricted by equilibrium limitations, and face challenges with product purification. Reactive distillation is an emerging technology that has an extremely attractive potential as a process alternative for carrying out equilibrium limited chemical reactions. Although the reactive distillation proce
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BARBOSA, DOMINGOS AZEVEDO GONEALVES. "DISTILLATION OF REACTIVE MIXTURES." 1987. https://scholarworks.umass.edu/dissertations/AAI8727018.

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In this dissertation, the influence of equilibrium chemical reactions on vapor-liquid equilibrium and distillation processes is studied. The theory of reactive-phase diagrams for two-phase systems, in which the components undergo one equilibrium chemical reaction, is developed, and the conditions for reactive-azeotropy are derived. It is shown that reactive-azeotropes do not necessarily correspond to stationary points in the chemical equilibrium surfaces. Reactive-phase diagrams, which illustrate the influence of chemical reactions on phase equilibria, are computed for some typical systems. Th
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Chen, Chin-Shin, and 陳晉仕. "Feasibility of Ternary Reactive Distillation Systems: Decomposition Reaction." Thesis, 2007. http://ndltd.ncl.edu.tw/handle/24913219760483127384.

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碩士<br>國立臺灣大學<br>化學工程學研究所<br>95<br>Abstract The reactive distillation offers significant economic advantages in some systems, especially when reactions are reversible and/or when azeotropes are presented. The feasibility analysis helps us to check whether a process is feasible or not. It is crucial and important because there are fewer methods for shortcut designs and the iterative design is always time-consuming in reactive distillation column. A lot of time would be saved for the design procedures of reactive distillation by getting rid of infeasible cases and focusing on the feasible ones.
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Al-Arfaj, Muhammad A. "Control of reactive distillation systems /." Diss., 2002. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3048943.

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31

Gulati, Ketan, and Varun Bharti. "Optimization of reactive distillation column." Thesis, 2007. http://ethesis.nitrkl.ac.in/4265/1/%E2%80%9COPTIMIZATION__OF_REACTIVE.pdf.

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The reactive distillation combines both chemical reaction and multi component separation into a single unit. It is a unit operation in which chemical reaction and distillative separation are carried out simultaneously within a fractional distillation apparatus. Reactive distillation (RD), the combination of chemical reaction and distillation in a single unit operation, has proven to be advantageous over conventional process systems consisting of separate reactor and distillation units. A simulation model based on an extension of conventional distillation is proposed for the simulation step of
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Yu, Sheng Jin, and 游生金. "Optimal Experimental Design of Reactive Distillation." Thesis, 1996. http://ndltd.ncl.edu.tw/handle/06820955909356348431.

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33

Chadda, Nitin. "Feasibility of kinetically controlled reactive distillation." 2001. https://scholarworks.umass.edu/dissertations/AAI3012120.

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For some time, there has been an interest in reactive distillation as an alternative to conventional reactor-separator processes because it has the potential for lower capital and energy costs as well as improved conversions and selectivities. However, it is not true that all processes using reactor-separators can be given up in favor of reactive distillation. This is due to the constraints that develop because of the complex interaction between distillation and reaction in the same device. It is very important then to determine when reactive distillation is a good process concept. We have dev
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Venimadhavan, Ganesh. "Effects of kinetics on reactive distillation." 1998. https://scholarworks.umass.edu/dissertations/AAI9909230.

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In the last decade, there has been growing success at developing commercial processes which combine reaction and separation. This technology offers the potential of significantly improved economics, reduced emissions and direct energy integration between the reaction and separation processes in the system. In this dissertation, we develop tools to analyze and design reactive distillation systems with multiple kinetically controlled chemical reactions. Residue curve maps are a useful tool in the conceptual design of distillation systems. They are the trajectories on a phase plane of the composi
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王勝田. "Thermodynamic analysis of reactive distillation column." Thesis, 2008. http://ndltd.ncl.edu.tw/handle/61992946158453200799.

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碩士<br>明新科技大學<br>化學工程研究所<br>96<br>The reactive distillation combines the chemical reaction and separation in one column. This research uses two kinds of thermodynamics analysis methods to reflect the discussion of the reactive distillation column, The column grand composite curve (CGCC) is similar to the grand composite curve used in pinch technology, provides a convenient tool for energy analysis and process integration for distillation column. The exergy loss profile shows the irresibility and energy inefficiency within the distillation column. Synthesizing MTBE by reactive distillation from
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黃士哲. "Reactive distillation system for butyl propionate." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/02139596852867711506.

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碩士<br>國立臺灣科技大學<br>化學工程系<br>90<br>Abstract Reactive distillation offers an attractive alternative for process intensification, especially for reaction/separation systems. In this work, we continue the effort to explore a specific class of reactive distillations: heterogeneous reactive distillation (or three-phase reactive distillation). By heterogeneous reactive distillation, we mean two-liquid phase exists in the reflux drum and a decanter is employed to separate the aqueous product from the organic reflux. For esterification reactions, propyl acetate, butyl acetate, butyl propionat
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Peng, Jianjun. "Modeling and control of packed reactive distillation columns." 2003. http://wwwlib.umi.com/cr/utexas/fullcit?p3116136.

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Chen, Wun-Yu, and 陳玟羽. "Design of Reactive Distillation and Azeotropic Distillation Systems by Dividing-Wall Columns." Thesis, 2013. http://ndltd.ncl.edu.tw/handle/17314249712596195614.

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碩士<br>東海大學<br>化學工程與材料工程學系<br>101<br>Due to shortage of energy resources and fluctuating oil prices in recent years, the development of energy-saving processes has become an important issue. In view of energy-efficient features of newly developed dividing-wall columns (DWC), this study looks into the design of a reactive distillation system and a heterogeneous azeotropic system by incorporating DWCs using ChemCad. The first system involves the esterification of mixed acids (acetic acid and propionic acid) with methanol to yield methyl acetate, methyl propionate, and water. Simulation and optima
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Edreder, E. A., Iqbal M. Mujtaba, and M. Emtir. "Optimal Operation of Batch Reactive Distillation Process Involving Esterification Reaction System." 2015. http://hdl.handle.net/10454/9141.

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No<br>The performance of batch reactive distillation process involving the esterification of acetic acid with methanol to produce methyl acetate and water is considered in this work. Two cases studies with varying amount of the reactants are considered. The reflux ratio (single time interval) is selected as the control variable to be optimised (treated as piecewise constant) for different but fixed batch time ranging from 5 to 15 h, so as to maximise the conversion of methanol subject to product purity of methyl acetate. The dynamic optimisation problem is converted to a nonlinear programming
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Cheng, Jian-Kai, and 程建凱. "Understanding Nonlinear Dynamic Behavior of Reactive Distillation." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/67988950020794478054.

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碩士<br>國立臺灣大學<br>化學工程學研究所<br>94<br>Reactive distillation combines reaction and separation in a single unit, which provides substantial economic incentives for some chemical reaction systems. However, the multifunctional nature of the reactive distillation complicates already very nonlinear nature of either reaction or separation. Thus, the dynamics and control of reactive distillation are less obvious as compared to its single functional unit counterparts. The objective of this work is to explore the nonlinear dynamics of reactive distillation. The interaction between reaction and separation le
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曾欽義. "Simulate of Ethyl Acetate by Reactive Distillation." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/25223535588691894876.

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碩士<br>明新科技大學<br>化學工程研究所<br>94<br>This work studies the feasibility of using equilibrium model for the preliminary design of the production of ethyl acetate by reactive distillation (RD) process. The commercial simulator ChemCad is used for the analysis of the single reactive distillation column and the whole process. The effects of design variables include: (1) the feed ratio of RD column (2) the rectifying section in RD column (3) the stripping section in RD column (4) the recycle rate of the bottom product of RD column (5) the organic reflux of RD column (6) the water added in the decanter
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Rokhmah, Anisatur, and 羅安妮. "Design of Diethyl Carbonate Reactive Distillation Process." Thesis, 2009. http://ndltd.ncl.edu.tw/handle/34477877187128151800.

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碩士<br>國立臺灣科技大學<br>化學工程系<br>97<br>optimal condition is reached by 8:1 feed ratio of EtOH : DMC, 39 total trays of distillation column, feed location of dimethyl carbonate (DMC) at 29th stage and feed location of ethanol (EtOH) at 9th stage. Since the distillate of the reactive distillation column is a mixture of ethanol and methanol, further study to separate this mixture is required in order to recover the EtOH for reaction. Comparison between simple distillation and extractive distillation to separate EtOH/MeOH mixture was made. Simple distillation was found to have smaller TAC than the extra
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Chen, Chieh-Ming, and 陳界名. "Reactive Distillation Design for Ethyl Acetate Production." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/32039348703059968360.

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碩士<br>東海大學<br>化學工程學系<br>94<br>Ethyl acetate is one of the most important organic solvents in the industry. The main purpose of this study is using reactive distillation technique on the production of ethyl acetate. The industrial grade raw materials, i.e. 88 mole% of ethanol and 99.5 mole% of acetate acid, are used. A commercial simulation software package Aspen Plus has been employed. First, six heuristic-design strategies on the reactive section are proposed. Based on the maximum conversion, the minimization of energy consumption, and the smaller equipment sizing, the ‘best’ design is chosen
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Yuan, Chang Chia, and 張家原. "Dynamic Simulation and Optimization of Reactive Distillation." Thesis, 1996. http://ndltd.ncl.edu.tw/handle/93038893078519733026.

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Buzad, George. "Design of kinetically controlled reactive distillation columns." 1994. https://scholarworks.umass.edu/dissertations/AAI9510449.

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Reactive distillation is an emerging technology that has great potential as a process alternative for carrying out liquid-phase chemical reactions. Systematic design methods for reactive distillation systems have only recently begun to appear, and so far these have been restricted to systems at chemical equilibrium. It is not always desirable, however, to operate reactive distillation columns close to reaction equilibrium conditions. In this dissertation we present a design procedure for kinetically controlled reactive distillation columns. We show that the amount of liquid holdup per stage ha
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Zhu, Wei-Song, and 朱維崧. "Production of Ethyl Butyrate by Reactive Distillation." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/00388640749506516664.

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碩士<br>明新科技大學<br>化學工程與材料科技系碩士班<br>103<br>The purpose of this work is to study the process of synthesizing ethyl butyrate 3000 ton annually, by continuous reactive distillation. The commercial simulation software Aspen Plus® is used in this study. Two processes are proposed. The first process (Process 1) is utilizing one single reactive distillation column, where two feeds are fed into the middle reaction section of the column and two products are withdrawn from the top and bottom of the column. The second process (Process 2) consists of two columns, where one is the main reactive distillation c
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Lin, Owens, and 林宏信. "Artifical intelligence Identification of Reactive Distillation Dynamics." Thesis, 1997. http://ndltd.ncl.edu.tw/handle/36505992809009855387.

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48

Morrison, Ryan Frederick. "Olefin production via reactive distillation based Olefin metathesis." Thesis, 2010. http://hdl.handle.net/2152/ETD-UT-2010-12-2202.

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Reactive distillation is a combination of a traditional multi-stage distillation column with a chemical reaction. The primary benefits of a reactive distillation process are reduced capital costs for equipment and energy in addition to enhanced conversion for equilibrium-limited reactions. One such equilibrium-limited reaction is an olefin metathesis. Olefin metathesis is a catalyzed reaction that breaks the double bond in olefins and rearranges the alkene fragments into new olefinic products. A comprehensive investigation of a reactive distillation based olefin metathesis and supporting e
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Lin, Zin-Xian, and 林誌賢. "Windows Programming of Ethylene Glycol Reactive Distillation Column." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/2m48da.

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碩士<br>國立臺北科技大學<br>化學工程研究所<br>98<br>The research expects to develop an ethylene glycol reactive distillation simulation provides for training and learning use. Ethylene glycol is an important industrial chemical, it produced from ethylene oxide hydration process. In recent years, reactive distillation is a new technology for ethylene glycol production. Reactive distillation is the process of simultaneous reaction and distillation in a single unit, offers numerous advantages over conventional configurations of reactors followed by separators. When reactions are equilibrium limited, reactive dist
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Shen, Xiu-Gong, and 沈修功. "Scale-up of an ideal reactive distillation process." Thesis, 2005. http://ndltd.ncl.edu.tw/handle/58063543260881885786.

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