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1
Hand, R. J. "Impact and fracture properties of infra-red and optical transmitting materials." Thesis, University of Cambridge, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.233087.
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The liquid impact properties of a range of infra-red and optical transmitting materials have been investigated using the liquid jet impact technique. In particular the effects of temperature and pre-existing stress fields on the liquid impact performance of certain materials have been examined. Consideration of these aspects of liquid impact has been supplemented by measurements of related fracture properties. The correlation between liquid jet impact and liquid drop impact has been re-examined for normal impact by comparing impacts on perspex. This correlation has been extended to consider angled impact. Components that are subjected to liquid impact may simultaneously be subjected to elevated temperatures. A system has been developed to allow experimental investigation of the liquid impact performance of materials at elevated temperatures. Preliminary results were obtained on a polymer (PEEK). The amount of damage resulting from liquid impact increased with temperature. Subsequently two brittle materials (glass and zinc sulphide) were investigated. Thermal shock has been shown to be the dominant failure mechanism for these materials at temperatures of 300oC and greater. Pre-existing stresses in a material can affect not only its static but also its dynamic loading response. The liquid impact performance and some associated fracture properties of toughened glass systems have been investigated. Chemically and thermally toughened systems were compared. There is a small increase in the threshold velocity for the toughened glasses considered compared to soda-lime glass. The toughening stresses distributions led to differences in the behaviour under single and multiple impact. A novel computer simulation of liquid impact onto pre-stressed substrates has been developed. It is based on the interaction of a model Rayleigh surface wave with a flaw distribution. Good agreement with experiment was obtained for a thermal toughening stress distribution.
2
Martins, Ana Margarida Ferreira. "Phycobiliproteins extraction from the red macroalga Gracilaria vermiculophylla." Master's thesis, Universidade de Aveiro, 2015. http://hdl.handle.net/10773/19031.
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Mestrado em BiotecnologiaRecentemente, o interesse pelos produtos obtidos de fontes naturais tem crescido em relação aos produtos sintéticos. Assim sendo, produtos extraídos de fontes naturais têm sido alvo de especial atenção pela indústria e pelo meio académico. Alguns desses compostos interessantes podem ser encontrados nas macroalgas vermelhas, nomeadamente a R-ficoeritrina, uma das ficobiliproteínas mais valiosas presentes na macroalga. Contudo, a maior dificuldade encontrada na extração e purificação desta proteína fotossintética está associada à necessidade de metodologias de extração e purificação mais eficazes, de mais baixo impacto económico e ambiental, capaz de remover as proteínas da biomassa, mantendo a sua estrutura conformacional e principais atividades. Neste trabalho, um conjunto de parâmetros experimentais de extração foram otimizados, nomeadamente o solvente em causa. Várias soluções aquosas de líquidos iónicos foram testadas na extração de ficobiliproteínas a partir da macroalga vermelha Gracilaria vermiculophylla. Depois de otimizado o tempo de extração, a razão sólido-líquido, o solvente, pH e concentração de solvente, foi possível chegar a uma metodologia capaz de extrair mais 30% de ficobiliproteínas quando comparado com o método convencional reportado na literatura.
In the past few years, there has been an increased demand for natural compounds over the synthetic ones. Thus, products extracted from natural sources have gained significant interest among industries and academia. Several of these interesting compounds are present in red macroalgae namely R-phycoerythrin, a phycobiliprotein. However, the major drawback is associated with the demand for more effective, with low economic and environmental impact extraction and purification methodology capable to remove the protein from the biomass, while maintaining its structure conformation and main activities. Therefore, the search for efficient extraction technologies is of utmost importance. In this work, a set of different parameters of extraction was optimized, such as the solvent used. Aqueous solutions of ionic liquids were screened for the phycobiliproteins extraction from the Gracilaria vermiculophylla. Once optimized the time of extraction, the solid-liquid ratio, the solvent, the solvent concentration, and the pH, it was possible to design an efficient methodology capable to enhance the phycobiliproteins extraction in 30% when compared with the conventional extraction methodology.
3
Raptodimos, T. "Visualising the radiated infra-red patterns from stationary and rotating components using liquid crystal and image derotation techniques." Thesis, University of Strathclyde, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.382529.
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4
Niles, Summer Nicole. "Extraction and Determination of a Selected Polyphenol from Selected Red and Black Grapes By High Performance Liquid Chromatography." Digital Commons @ East Tennessee State University, 2010. https://dc.etsu.edu/honors/3.
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Polyphenols are a group of compounds found naturally in plants and they provide much of the flavor, color, and taste to fruits, vegetables, seeds, and other parts of the plants They also act as antioxidants which provide numerous health benefits by protecting cells against damage caused by free radicals. Their antibacterial, anti-inflammatory and anti-allergenic properties have also contributed to the prevention of degenerative diseases, such as cardiovascular diseases and cancers by slowing the rate of oxidative stress on cells. This study was aimed at the identification and quantitation of a specific polyphenol, quercetin, found in grapes commonly purchased at grocery stores to show their benefits toward human health. Samples of red and black grapes were collected and their polyphenolic compounds were extracted from the pulp using an organic solvent extraction method. High pressure liquid chromatography (hplc) was then used for the determination and quantitation of quercetin in each of samples. Quercetin was identified in both the red and black grape samples at retention times around five minutes. Due to technical problems with the HPLC instrument, only estimates of the amount of quercetin in each of the analyzed samples could be calculated with the highest estimated yield being 8.29 mg/mL of quercetin in black grape extract #4.
5
Song, Qiong. "FAST RESPONSE DUAL FREQUENCY LIQUID CRYSTAL MATERIALS." Doctoral diss., University of Central Florida, 2010. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/3112.
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Dual frequency liquid crystal (DFLC) exhibits a positive dielectric anisotropy at low frequencies and negative dielectric anisotropy at high frequencies. The frequency where dielectric anisotropy is zero is called crossover frequency. DFLC can achieve fast rise time and fast decay time with the assistance of applied voltage. However, one drawback of DFLC is that it has dielectric heating effect when driven at a high frequency. Thus, the first part of this dissertation is to develop low crossover frequency DFLC materials. The dielectric relaxation and physical properties of some single- and double-ester compounds were investigated. Experimental results indicate that the double-ester compound exhibits a ~ 3 X lower dielectric relaxation frequencies and larger dielectric anisotropy than the single ester, but its viscosity is also higher. More generally, ten groups of dual frequency liquid crystals were compared in terms of dielectric relaxation frequency and dielectric anisotropy. The dielectric relaxation theory was discussed at last. To realize fast response time, high birefringence and low viscosity LC are required. From these two aspects, firstly four new high birefringence laterally difluoro phenyl tolane liquid crystals with a negative dielectric anisotropy were studied. These materials are used to enhance the birefringence of DFLC. They have a fairly small heat fusion enthalpy (~3000 cal/mol) which improves their solubility in a host. We dope 10 wt% of each compound into a commercial negative mixture N1 and measured their birefringence, viscoelastic constant and figure of merit. Birefringence varies very little among homologues while viscoelastic constant increases as alkyl chain length increases. Secondly, we studied the effects of six diluters for lowering the viscosity while stabilizing the vertical alignment (VA) of the laterally difluoro terphenyl host mixture at elevated temperatures. The pros and cons of each diluter are analyzed. These lateral difluoro terphenyls exhibit a high birefringence, fairly low viscosity, and modest dielectric anisotropy, but their molecular alignment in a VA cell is gradually deteriorated at elevated temperatures as their concentration increases. As a result, the device contrast ratio is decreased noticeably due to the light leakage through the crossed polarizers. Finally, liquid crystal doped with metallic nanoparticles, such as Pd, Ag, or Ag-Pd, which are protected with ligand molecules, such as nematic liquid crystal were studied. The metal nanoparticles doped LC exhibit a frequency modulation (FM) electro-optical (EO) response in the millisecond to submillisecond range together with the ordinary root-mean-square voltage response.Ph.D.
Optics and Photonics
Optics and Photonics
Optics PhD
6
Wu, Yung-Hsun. "FAST RESPONSE LIQUID CRYSTAL DEVICES." Doctoral diss., University of Central Florida, 2006. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/3111.
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Liquid crystal (LC) has been widely used for displays, spatial light modulators, variable optical attenuators (VOAs) and other tunable photonic devices. The response time of these devices is mainly determined by the employed liquid crystal material. How to obtain fast response for the LC devices is a fundamentally important and technically challenging task. In this dissertation, we investigate several methods to improve liquid crystal response time, for examples, using dual-frequency liquid crystals, polymer stabilized liquid crystals, and sheared polymer network liquid crystals. We discover a new class of material, denoted as sheared polymer network liquid crystal (SPNLC) which exhibits a submillisecond response time. First, dual-frequency liquid crystals and polymer network methods are demonstrated as examples for the variable optical attenuators. Variable optical attenuator (VOA) is a key component in optical communications. Especially, the sheared PNLC VOA shows the best result; its dynamic range reaches 43 dB while the response time is in the submillisecond range at 1550 nm wavelength, which is 50 times faster than the commercial LC-based VOA. Second, we report a new device called axially-symmetric sheared polymer network liquid crystals (AS-SPNLC) and use it as LC devices. An axially-symmetric sheared polymer network liquid crystal has several attractive features: 1) it is polarization independent, 2) it has gradient phase change, and 3) its response time is fast. It can be used for polarization converter and divergent LC lens. In addition, a new method for simultaneously measuring the phase retardation and optic axis of a compensation film is demonstrated using an axially-symmetric sheared polymer network liquid crystal. This simple technique can be used for simultaneously measuring the optic axis and phase retardations of both A- and C-plates. These compensation films have been used extensively in wide-view LCD industry. Therefore, this method will make an important impact to the LCD industry.Ph.D.
Optics and Photonics
Optics
7
Fan, Yun-Hsing. "TUNABLE LIQUID CRYSTAL PHOTONIC DEVICES." Doctoral diss., University of Central Florida, 2005. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/3926.
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Liquid crystal (LC)-based adaptive optics are important for information processing, optical interconnections, photonics, integrated optics, and optical communications due to their tunable optical properties. In this dissertation, we describe novel liquid crystal photonic devices and their fabrication methods. The devices presented include inhomogeneous polymer-dispersed liquid crystal (PDLC), polymer network liquid crystals (PNLC) and phase-separated composite film (PSCOF). Liquid crystal/polymer composites could exist in different forms depending on the fabrication conditions. In Chap. 3, we demonstrate a novel nanoscale PDLC device that has inhomogeneous droplet size distribution. In such a PDLC, the inhomogeneous droplet size distribution is obtained by exposing the LC/monomer with a non-uniform ultraviolet (UV) light. An electrically tunable-efficiency Fresnel lens is devised for the first time using nanoscale PDLC. The tunable Fresnel lens is very desirable to eliminate the need of external spatial light modulator. Different gradient profiles are obtained by using different photomasks. The nanoscale LC droplets are randomly distributed within the polymer matrix, so that the devices are polarization independent and exhibit a fast response time. Because of the small droplet sizes, the operating voltage is higher than 100 Vrms. To lower the driving voltage, in Chap. 2 and Chap. 3, we have investigated a polymer-network liquid crystal (PNLC) using a rod-like monomer structure. Since the monomer concentration is only about 5%, the operating voltage is below 10 Vrms. The PNLC devices are polarization dependent. To overcome this shortcoming, stacking two cells with orthogonal alignment directions is a possibility. In Chap. 3, another approach to lower the operating voltage is to use phase-separated composite film (PSCOF) where the LC and polymer are separated completely to form two layers. Without multi-domain formed in the LC cell, PSCOF is free from light scattering. Using PNLC and PSCOF, we also demonstrated LC blazed grating and Fresnel lens. The diffraction efficiency of these devices is continuously controlled by the electric field. Besides Fresnel lens, another critical need for imaging and display is to develop a system with continuously tunable focal length. A conventional zooming system controls the lens distance by mechanical motion along the optical axis. This mechanical zooming system is bulky and power hungry. To overcome the bulkiness, in Chap. 4 we developed an electrically tunable-focus flat LC spherical lens which consists of a spherical electrode imbedded in the top flat substrates while a planar electrode on the bottom substrate. The electric field from the spherical and planar electrodes induces a centrosymmetric gradient refractive index distribution within the LC layer which, in turn, causes the focusing effect. The focal length is tunable by the applied voltage. A tunable range from 0.6 m to infinity is achieved. Microlens array is an attractive device for optical communications and projection displays. In Chap. 5, we describe a LC microlens array whose focal length can be switched from positive to negative or vise versa by the applied voltage. The top spherical electrode glass substrate is flattened with a polymer layer. The top convex substrate and LC layer work together like a zoom lens. By tuning the refractive index profile of the LC layer, the focal length of the microlens array can be switched from positive to negative or vise versa. The tunable LC microlens array would be a great replacement of a conventional microlens array which can be moved by mechanical elements. The fast response time feature of our LC microlens array will be very helpful in developing 3-D animated images. A special feature for LC/polymer composites is light scattering. The concept is analogous to the light scattering of clouds which consist of water droplets. In Chap. 6, we demonstrate polymer network liquid crystals for switchable polarizers and optical shutters. The PNLC can present anisotropic or isotropic light scattering behavior depending on the fabrication methods. The use of dual-frequency liquid crystal and special driving scheme leads to a sub-millisecond response time. The applications for display, light shutters, and switchable windows are emphasized. Although polymer networks help to reduce liquid crystal response time, they tend to scatter light. In Chap. 7, for the first time, we demonstrate a fast-response and scattering-free homogeneously-aligned PNLC light modulator. Light scattering in the near-infrared region is suppressed by optimizing the polymer concentration such that the network domain sizes are smaller than the wavelength. As a result, the PNLC response time is ~300X faster than that of a pure LC mixture except that the threshold voltage is increased by ~25X. The PNLC cell also holds promise for mid and long infrared applications where response time is a critical issue.Ph.D.
Other
Optics and Photonics
Optics
8
Lin, Yi-Hsin. "POLARIZATION-INDEPENDENT LIQUID CRYSTAL DEVICES." Doctoral diss., University of Central Florida, 2006. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/4199.
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Liquid crystal (LC) devices can be operated as amplitude modulators and phase modulators. LC amplitude modulation is commonly used in liquid crystal display (LCD) while phase-only modulation is useful for laser beam steering, tunable grating, prism, lens, and other photonic devices. Most LC devices are polarization dependent and require at least one polarizer. As a result, the optical efficiency is low. To enhance display brightness, a power hungry backlight has to be used leading to a high power consumption and short battery life. In a LC phase modulator, the polarization dependent property complicates the laser beam steering system. It is highly desirable to develop new operating mechanisms that are independent of the incident light polarization. In this dissertation, we have developed eight polarization-independent liquid crystal operation principles: three of them are aimed for displays and the other five are for phase modulators. For amplitude modulations, a new polymer-dispersed liquid crystal (PDLC) and two new dye-doped LC gels are polarizer-free by combining light scattering with dye-absorption effects. In phase modulation, we explore five device concepts: PDLC and Polymer-Stabilized Cholesteric Texture (PSCT), homeotropic LC gels, thin polymer film separated double-layered structure, and double-layered LC gels. In the low voltage regime, both PDLC and PSCT have a strong light scattering. However, as the voltage exceeds a certain level, the phase modulation is scattering-free and is independent of polarization. The homeotropic LC gels do not require any biased voltage and the response time is still fast. Although the remaining phase in these devices is small, they are still useful for micro-photonic device applications. To increase the phase change, thin polymer film separated double-layered structure is a solution. The orthogonal arrangement of top and bottom LC directors results in polarization independence. However, the response time is slow. Similarly, double-layered LC gels are not only polarization independent but also fast response due to the established polymer network.Ph.D.
Optics and Photonics
Optics
9
Jiao, Meizi. "Fast-response liquid crystal displays." Doctoral diss., University of Central Florida, 2010. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/4580.
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After about five decades of extensive material research and device development, followed by massive investment in manufacturing technology, thin-film-transistor liquid-crystal-display (TFT-LCD) has finally become the dominant flat panel display technology. Nowadays, LCD performances, such as viewing angle, contrast ratio, and resolution, have reached acceptable levels. The remaining major technical challenges are response time, light efficiency, and sunlight readability. Fast response time is desired to reduce motion blur and to enable field sequential color displays using red (R), green (G), and blue (B) LEDs (light emitting diodes) without noticeable color breakup. Sequential RGB colors would eliminate the commonly used spatial color filters which in turn enhances light efficiency and resolution density by ~ 3X. In this dissertation, several new approaches for achieving fast-response LCDs are explored. From material viewpoint, the most straightforward approach for achieving fast response time is to employ a thin cell gap with high birefringence and low viscosity liquid crystal (LC). We investigated the thin cell approach theoretically and experimentally. Voltage shielding effect and anchoring energy effect of alignment layers are found to play important roles on operating voltage and response time. Simulations are carried out to understand the underlying physics and confirm the experimental results quantitatively. Another approach to realize fast response time is to explore novel device configuration. Here, we proposed a dual fringing-field switching (DFFS) mode in which small LC domains are formed following the distribution of fringing fields. Therefore, it exhibits submillisecond response time without using thin cell or overdrive/undershoot voltage method. The response time of the DFFS mode is ~20X faster than a conventional vertical aligned LCD.; In addition, high optical efficiency is achieved from the complementary top and bottom active LC domains. Two transmissive and one transflective LCDs using DFFS mode are conceived and their electro-optical properties investigated. A shortcoming of DFFS LCDs is their fabrication complexity. To keep the advantages of this fast-response mode while avoiding the requirement of double-TFTs and pixel registration, we modified the device structure to transflective LCD which uses a single TFT in each pixel and vertical aligned positive dielectric anisotropy LC. Two types of electrodes are considered: fringing-field switching (FFS) and in-plane switching (IPS). Besides fast response time and high transmittance, such a transflective LCD shows good sunlight readability. As nematic LC is gradually approaching to its limit in term of response time, polymer-stabilized blue phase (PSBP) LCD is emerging. It has potential to become next-generation display because of following revolutionary features: submillisecond response time, no need for alignment layer, good dark state and symmetric viewing angle, and cell gap insensitivity if IPS electrode is employed. In this dissertation, we studied the material-property correlation of Kerr effect-induced birefringence in nano-structured PSBP LC composites. Furthermore, a new device configuration of BP LCD with corrugated electrodes is proposed to solve two critical technical issues: high driving voltage and relatively low transmittance. The on-state voltage can be reduced from ~35 Vsubscript rms] to ~10 Vsubscript rms] which will enable TFT addressing, and the transmittance is improved from ~65% to ~85%. This new device configuration will accelerate the emergence of PSBP LCD. Wide view is another important requirement for a high-end display. Several new LCD configurations with negative A-plate and biaxial plate as phase compensation films are proposed to achieve wide view and broadband operation.; The underlying working principles are studied and detailed display performances are included in this dissertation.ID: 030422960; System requirements: World Wide Web browser and PDF reader.; Mode of access: World Wide Web.; Thesis (Ph.D.)--University of Central Florida, 2010.; Includes bibliographical references (p. 114-122).
Ph.D.
Doctorate
Optics and Photonics
10
Hollingworth, Robert James. "Development of read-out systems for liquid xenon based dark matter detectors." Thesis, University of Sheffield, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.425577.
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11
Hong, Qi. "WIDE VIEWING ANGLE LIQUID CRYSTAL DISPLAYS." Doctoral diss., University of Central Florida, 2006. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/4042.
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In this dissertation, novel phase compensation technologies are applied to the designs of wide viewing angle and high transmittance liquid crystal displays. First, a design of wide viewing angle liquid crystal displays utilizing crossed linear polarizers is proposed. The designed multi-domain vertical-alignment liquid crystal display predicts superb contrast ratio over wide viewing angles. Next, to increase the bright state transmittance while maintain the high contrast. Finally, to reduce the cost and improve the applicability of the broadband and wide-view circular polarizer, the device configuration of the broadband and wide-view circular polarizer is significantly simplified by the application of biaxial compensation films. The produced states of polarization remain close to the ideal circular polarization over a wide range of incident angles within the visual spectrum. With this circular polarizer, the presented wide-view liquid crystal display predicts high contrast ratio as well as high and uniform transmittance over wide viewing angles within the visual spectrum. ratio, wide viewing angle circular polarizers are developed. The produced states of polarization are very close to the ideal circular state of polarization over a wide range of incident angles within the visual spectrum. This guarantees not only high contrast ratio but also high and uniform transmittance.Ph.D.
School of Electrical Engineering and Computer Science
Engineering and Computer Science
Electrical Engineering
12
Wang, Haiying. "STUDIES OF LIQUID CRYSTAL RESPONSE TIME." Doctoral diss., University of Central Florida, 2005. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/3541.
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In this dissertation, the response time issue of the liquid crystal (LC) devices is investigated in meeting the challenges for display and photonic applications. The correlation between the LC director response time and the optical response time is derived theoretically and confirmed experimentally. A major contribution of this thesis is that, based on the small angle approximation, we derive rigorous analytical solutions for correlating the LC director response time to its consequent optical response times (both rise and decay) of a vertical-aligned nematic LC cell. This work successfully fills the gap in the literature of LCD switching dynamics. An important effect related to response time, backflow is analyzed using a homogeneous LC cell in an infrared wavelength. The Leslie viscosity coefficients can hardly be found in the literature. A new effective approach to estimate the Leslie coefficients of LC mixtures based on MBBA data is proposed in this dissertation. Using this method, the Leslie coefficients of the LC material under study can be extracted based on its order parameters. The simulation results agree with the experimental data very well. This method provides a useful tool for analyzing the dynamic response including backflow. Cell gap is an important factor affecting the LC response time. Usually a thinner cell gap is chosen to achieve faster response time, since normally both rise and decay times are known to be proportional to d2. However, they are valid only in the region. In the large voltage region where , the optical decay time is independent of d. In this thesis, we find that between these two extremes the response time is basically linearly proportional to d. Our analytical derivation is validated by experimental results. Therefore, in the whole voltage region, the physical picture of the optical response time as a function of the cell gap is completed. This analysis is useful for understanding the grayscale switching behaviors of the LC phase modulators. In conclusion, this dissertation has solved some important issues related to LC optical response time and supplied valuable tools for scientists and engineers to numerically analyze the LC dynamics.Ph.D.
Department of Electrical and Computer Engineering
Engineering and Computer Science
Electrical Engineering
13
Parish, Amanda Jane. "High Birefringence Liquid Crystals for Optical Communications." Master's thesis, University of Central Florida, 2007. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/3199.
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High birefringence ([delta]n>0.4) nematic liquid crystals are particularly attractive for infrared applications because they enable a thinner cell gap to be used for achieving fast response time and improved diffraction efficiency. In this thesis, the mesomorphic and electro-optic properties of several new fluorinated isothiocyanate (NCS) terphenyl and phenyl tolane single compounds and mixtures are reported. The single compounds demonstrated [delta]n~0.35-0.52 in the visible spectral region at room temperature and exhibit relatively low viscosity. It was found that lateral fluorine substitutions and short alkyl chains eliminate smectic phase and lower the melting temperature of the single compounds. However, the consequence of using highly conjugated compounds to improve electro-optic properties is that the nematic phase is exhibited at high temperatures, over 100[degrees]C, and therefore single compounds cannot be used for device applications. Therefore, several mixtures based on the terphenyl and phenyl-tolane compounds were formulated and evaluated. The purpose of mixtures is to find the optimum balance between electro-optic performance and the mesomorphic properties that determine the operating temperature range. It was found that mixture formulations greatly improved mesomorphic properties to produce nematic phase at or near room temperature and suppressed smectic phase to below 0[degrees]C or eliminating completely. The analysis presented evaluates the benefits of lowering the operating temperature versus the consequence of degrading the electro-optic properties.M.S.
Optics and Photonics
Optics and Photonics
Optics MS
14
Zhou, Ying. "CHOLESTERIC LIQUID CRYSTAL PHOTONIC CRYSTAL LASERS AND PHOTONIC DEVICES." Doctoral diss., University of Central Florida, 2008. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/2706.
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This dissertation discusses cholesteric liquid crystals (CLCs) and polymers based photonic devices including one-dimensional (1D) photonic crystal lasers and broadband circular polarizers. CLCs showing unique self-organized chiral structures have been widely used in bistable displays, flexible displays, and reflectors. However, the photonic band gap they exhibit opens a new way for generating laser light at the photonic band edge (PBE) or inside the band gap. When doped with an emissive laser dye, cholesteric liquid crystals provide distributed feedback so that mirrorless lasing is hence possible. Due to the limited surface anchoring, the thickness of gain medium and feedback length is tens of micrometers. Therefore lasing efficiency is quite limited and laser beam is highly divergent. To meet the challenges, we demonstrated several new methods to enhance the laser emission while reducing the beam divergence from a cholesteric liquid crystal laser. Enhanced laser emission is demonstrated by incorporating a single external CLC reflector as a polarization conserved reflector. Because the distributed feedback from the active layer is polarization selective, a CLC reflector preserves the original polarization of the reflected light and a further stimulated amplification ensues. As a result of virtually doubled feedback length, the output is dramatically enhanced in the same circular polarization state. Meanwhile, the laser beam divergence is dramatically reduced due to the increased cavity length from micrometer to millimeter scale. Enhanced laser emission is also demonstrated by the in-cell metallic reflector because the active layer is pumped twice. Unlike a CLC reflector, the output from a mirror-reflected CLC laser is linearly polarized as a result of coherent superposition of two orthogonal circular polarization states. The output linear polarization direction can be well controlled and fine tuned by varying the operating temperature and cell gap. Enhanced laser emission is further demonstrated in a hybrid photonic band edge - Fabry-Perot (FP) type structure by sandwiching the CLC active layer within a circular polarized resonator consisting of two CLC reflectors. The resonator generates multiple FP modes while preserving the PBE mode from the active layer. More importantly this band edge mode can be greatly enhanced by the external resonator under some conditions. Theoretical analysis is conducted based on 4×4 transfer matrix and scattering matrix and the results are consistent with our experimental observations. To make the CLC laser more compact and miniaturized, we have developed a flexible polymer laser using dye-doped cholesteric polymeric films. By stacking the mirror reflecting layer, the active layer and the CLC reflecting layer, enhanced laser emission was observed in opposite-handed circular polarization state, because of the light recycling effect. On the other hand, we use the stacked cholesteric liquid crystal films, or the cholesteric liquid crystals and polymer composite films to demonstrate the single film broadband circular polarizers, which are helpful for converting a randomly polarized light into linear polarization. New fabrication methods are proposed and the circular polarizers cover ~280 nm in the visible spectral range. Both theoretical simulation and experimental results are presented with a good match.Ph.D.
Optics and Photonics
Optics and Photonics
Optics PhD
15
Khan, Sajjad. "Liquid Crystal Optics for Communications, Signal Processing and 3-D Microscopic Imaging." Doctoral diss., University of Central Florida, 2005. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/3389.
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This dissertation proposes, studies and experimentally demonstrates novel liquid crystal (LC) optics to solve challenging problems in RF and photonic signal processing, freespace and fiber optic communications and microscopic imaging. These include free-space optical scanners for military and optical wireless applications, variable fiber-optic attenuators for optical communications, photonic control techniques for phased array antennas and radar, and 3-D microscopic imaging. At the heart of the applications demonstrated in this thesis are LC devices that are non-pixelated and can be controlled either electrically or optically. Instead of the typical pixel-by-pixel control as is custom in LC devices, the phase profile across the aperture of these novel LC devices is varied through the use of high impedance layers. Due to the presence of the high impedance layer, there forms a voltage gradient across the aperture of such a device which results in a phase gradient across the LC layer which in turn is accumulated by the optical beam traversing through this LC device. The geometry of the electrical contacts that are used to apply the external voltage will define the nature of the phase gradient present across the optical beam. In order to steer a laser beam in one angular dimension, straight line electrical contacts are used to form a one dimensional phase gradient while an annular electrical contact results in a circularly symmetric phase profile across the optical beam making it suitable for focusing the optical beam. The geometry of the electrical contacts alone is not sufficient to form the linear and the quadratic phase profiles that are required to either deflect or focus an optical beam. Clever use of the phase response of a typical nematic liquid crystal (NLC) is made such that the linear response region is used for the angular beam deflection while the high voltage quadratic response region is used for focusing the beam. Employing an NLC deflector, a device that uses the linear angular deflection, laser beam steering is demonstrated in two orthogonal dimensions whereas an NLC lens is used to address the third dimension to complete a three dimensional (3-D) scanner. Such an NLC deflector was then used in a variable optical attenuator (VOA), whereby a laser beam coupled between two identical single mode fibers (SMF) was mis-aligned away from the output fiber causing the intensity of the output coupled light to decrease as a function of the angular deflection. Since the angular deflection is electrically controlled, hence the VOA operation is fairly simple and repeatable. An extension of this VOA for wavelength tunable operation is also shown in this dissertation. A LC spatial light modulator (SLM) that uses a photo-sensitive high impedance electrode whose impedance can be varied by controlling the light intensity incident on it, is used in a control system for a phased array antenna. Phase is controlled on the Write side of the SLM by controlling the intensity of the Write laser beam which then is accessed by the Read beam from the opposite side of this reflective SLM. Thus the phase of the Read beam is varied by controlling the intensity of the Write beam. A variable fiber-optic delay line is demonstrated in the thesis which uses wavelength sensitive and wavelength insensitive optics to get both analog as well as digital delays. It uses a chirped fiber Bragg grating (FBG), and a 1xN optical switch to achieve multiple time delays. The switch can be implemented using the 3-D optical scanner mentioned earlier. A technique is presented for ultra-low loss laser communication that uses a combination of strong and weak thin lens optics. As opposed to conventional laser communication systems, the Gaussian laser beam is prevented from diverging at the receiving station by using a weak thin lens that places the transmitted beam waist mid-way between a symmetrical transmitter-receiver link design thus saving prime optical power. LC device technology forms an excellent basis to realize such a large aperture weak lens. Using a 1-D array of LC deflectors, a broadband optical add-drop filter (OADF) is proposed for dense wavelength division multiplexing (DWDM) applications. By binary control of the drive signal to the individual LC deflectors in the array, any optical channel can be selectively dropped and added. For demonstration purposes, microelectromechanical systems (MEMS) digital micromirrors have been used to implement the OADF. Several key systems issues such as insertion loss, polarization dependent loss, wavelength resolution and response time are analyzed in detail for comparison with the LC deflector approach. A no-moving-parts axial scanning confocal microscope (ASCM) system is designed and demonstrated using a combination of a large diameter LC lens and a classical microscope objective lens. By electrically controlling the 5 mm diameter LC lens, the 633 nm wavelength focal spot is moved continuously over a 48 [micro]m range with measured 3-dB axial resolution of 3.1 [micro]m using a 0.65 numerical aperture (NA) micro-objective lens. The ASCM is successfully used to image an Indium Phosphide twin square optical waveguide sample with a 10.2 [micro]m waveguide pitch and 2.3 [micro]m height and width. Using fine analog electrical control of the LC lens, a super-fine sub-wavelength axial resolution of 270 nm is demonstrated. The proposed ASCM can be useful in various precision three dimensional imaging and profiling applications.Ph.D.
Optics and Photonics
Optics
16
Wen, Chien-Hui. "High Birefringence and Low Viscosity Liquid Crystals." Doctoral diss., University of Central Florida, 2006. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/3206.
Full textAbstract:
In this dissertation, liquid crystal (LC) materials and devices are investigated in order to meet the challenges for photonics and displays applications. We have studied three kinds of liquid crystal materials: positive dielectric anisotropic LCs, negative dielectric anisotropic LCs, and dual- frequency LCs. For the positive dielectric anisotropic LCs, we have developed some high birefringence isothiocyanato tolane LC compounds with birefringence ~0.4, and super high birefringence isothiocyanato biphenyl-bistolane LC compounds with birefringence as high as ~0.7. Moreover, we have studied the photostability of several high birefringence LC compounds, mixtures, and LC alignment layers in order to determine the failure mechanism concerning the lifetime of LC devices. Although cyano and isothiocyanato LC compounds have similar absorption peaks, the isothiocyanato compounds are more stable than their cyano counterparts under the same illumination conditions. This ultraviolet-durable performance of isothiocyanato compounds originates from its molecular structure and the delocalized electron distribution. We have investigated the alignment performance of negative dielectric anisotropic LCs in homeotropic (vertical aligned, VA) LC cell. Some (2,3) laterally difluorinated biphenyls, terphenyls and tolanes are selected for this study. Due to the strong repulsive force between LCs and alignment layer, (2,3) laterally difluorinated terphenyls and tolanes do not align well in a VA cell resulting in a poor contrast ratio for the LC panel. We have developed a novel method to suppress the light leakage at dark state. By doping positive [Delta][epsilon] or non-polar LC compounds/mixtures into the host negative LC mixtures, the repulsive force is reduced and the cell exhibits an excellent dark state. In addition, these dopants increase the birefringence and reduce the viscosity of the host LCs which leads to a faster response time. Dual-frequency liquid crystal exhibits a unique feature that its dielectric anisotropy changes from positive to negative when we increase the operating frequency. Submillisecond response time can be achieved by switching the frequency of a biased voltage, rather than switching the voltage at a given frequency. In this dissertation, we investigate the dielectric heating effect of dual-frequency LCs. Because the absorption peak of imaginary dielectric constant occurs at high frequency region (~ MHz), there is a heat generated when the LC cell is operated at a high frequency voltage. To measure the transient temperature change of the LC inside the cell, we have developed a non-contact method by utilizing the temperature-dependent birefringence property of the LC. Most importantly, we have formulated a new dual-frequency LC mixture which greatly reduces the dielectric heating effect while maintaining good physical properties. Another achievement in this thesis is that we have developed a polarization independent phase modulator by using a negative dielectric anisotropic LC gel. With ~20 % of polymer mixed in the LC host, the LC forms polymer network which, in turn, exerts a strong anchoring force to the neighboring LC molecules. As a result, the operating voltage increases but the response time is significantly decreased. On the phase shift point of view, our homeotropic LC gel has ~0.08 [pi] phase shift, which is 2X larger than the previous nano-sized polymer-dispersed liquid crystal droplets. Moreover, it is free from light scattering and requires a lower operating voltage. In conclusion, this dissertation provides solutions to improve the performance of LC devices both in photonics and displays applications. These will have great impacts in defense and display systems such as optical phased array, LCD TVs, projectors, and LCD monitors.Ph.D.
Other
Optics and Photonics
Optics
17
Li, Yan. "High-efficiency Blue Phase Liquid Crystal Displays." Doctoral diss., University of Central Florida, 2012. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/5399.
Full textAbstract:
Blue phase liquid crystals (BPLCs) have a delicate lattice structure existing between chiral nematic and isotropic phases, with a stable temperature range of about 2 K. But due to short coherent length, these self-assembled nano-structured BPLCs have a fast response time. In the past three decades, the application of BPLC has been rather limited because of its narrow temperature range. In 2002, Kikuchi et al. developed a polymer stabilization method to extend the blue-phase temperature range to more than 60 K. This opens a new gateway for display and photonic applications. In this dissertation, I investigate the material properties of polymer-stabilized BPLCs. According the Gerber's model, the Kerr constant of a BPLC is linearly proportional to the dielectric anisotropy of the LC host. Therefore, in the frequency domain, the relaxation of the Kerr constant follows the same trend as the dielectric relaxation of the host LC. I have carried out experiments to validate the theoretical predictions, and proposed a model called extended Cole-Cole model to describe the relaxation of the Kerr constant. On the other hand, because of the linear relationship, the Kerr constant should have the same sign as the dielectric anisotropy of the LC host; that is, a positive or negative Kerr constant results from positive or negative host LCs, respectively. BPLCs with a positive Kerr constant have been studied extensively, but there has been no study on negative polymer-stabilized BPLCs. Therefore, I have prepared a BPLC mixture using a negative dielectric anisotropy LC host and investigated its electro-optic properties. I have demonstrated that indeed the induced birefringence and Kerr constant are of negative sign. Due to the fast response time of BPLCs, color sequential display is made possible without color breakup. By removing the spatial color filters, the optical efficiency and resolution density are both tripled. With other advantages such as alignment free and wide viewing angle, polymer-stabilized BPLC is emerging as a promising candidate for next-generation displays. However, the optical efficiency of the BPLC cell is relatively low and the operating voltage is quite high using conventional in-plane-switching electrodes. I have proposed several device structures for improving the optical efficiency of transmissive BPLC cells. Significant improvement in transmittance is achieved by using enhanced protrusion electrodes, and a 100% transmittance is achievable using complementary enhanced protrusion electrode structure. For a conventional transmissive blue phase LCD, although it has superb performances indoor, when exposed to strong sunlight the displayed images could be washed out, leading to a degraded contrast ratio and readability. To overcome the sunlight readability problem, a common approach is to adaptively boost the backlight intensity, but the tradeoff is in the increased power consumption. Here, I have proposed a transflective blue phase LCD where the backlight is turned on in dark surroundings while ambient light is used to illuminate the displayed images in bright surroundings. Therefore, a good contrast ratio is preserved even for a strong ambient. I have proposed two transflective blue phase LCD structures, both of which have single cell gap, single gamma driving, reasonably wide view angle, low power consumption, and high optical efficiency. Among all the 3D technologies, integral imaging is an attractive approach due to its high efficiency and real image depth. However, the optimum observation distance should be adjusted as the displayed image depth changes. This requires a fast focal length change of an adaptive lens array. BPLC adaptive lenses are a good candidate because of their intrinsic fast response time. I have proposed several BPLC lens structures which are polarization independent and exhibit a parabolic phase profile in addition to fast response time. To meet the low power consumption requirement set by Energy Star, high optical efficiency is among the top lists of next-generation LCDs. In this dissertation, I have demonstrated some new device structures for improving the optical efficiency of a polymer-stabilized BPLC transmissive display and proposed sunlight readable transflective blue-phase LCDs by utilizing ambient light to reduce the power consumption. Moreover, we have proposed several blue-phase LC adaptive lenses for high efficiency 3D displays.Ph.D.
Doctorate
Optics and Photonics
Optics and Photonics
Optics
18
Rao, Linghui. "Low Voltage Blue Phase Liquid Crystal Displays." Doctoral diss., University of Central Florida, 2012. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/5448.
Full textAbstract:
From cell phones, laptops, desktops, TVs, to projectors, high reliability LCDs have become indispensable in our daily life. Tremendous progress in liquid crystal displays (LCDs) has been made after decades of extensive research and development in materials, device configurations and manufacturing technology. Nowadays, the most critical issue on viewing angle has been solved using multidomain structures and optical film compensation. Slow response time has been improved to 2-5 ms with low viscosity LC material, overdrive and undershoot voltage, and thin cell gap approach. Moving image blur has been significantly reduced by impulse driving and frame insertion. Contrast ratio in excess of one million-to-1 has been achieved through local dimming of the segmented LED backlight. The color gamut would exceed 100% of the NTSC (National Television System Committee), if RGB LEDs are used. Besides these technological advances, the cost has been reduced dramatically by investing in advanced manufacturing technologies. Polymer-stabilized blue phase liquid crystal displays (BPLCDs) based on Kerr effect is emerging as a potential next-generation display technology. In comparison to conventional nematic devices, the polymer-stabilized BPLCDs exhibit following attractive features: (1) submillisecond response time, (2) no need for molecular alignment layers, (3) optically isotropic dark state when sandwiched between crossed polarizers, and (4) transmittance is insensitive to cell gap when the in-plane electrodes are employed. However, aside from these great potentials, there are still some tough technical issues remain to be addressed. The major challenges are: 1) the operating voltage is still too high (~50 Volts vs. 5 Volts for conventional nematic LCDs), and the transmittance is relatively low (~65% vs. 85% for nematic LCDs), 2) the hysteresis effect and residual birefringence effect are still noticeable, 3) the mesogenic temperature range is still not wide enough for practical applications (?40 oC to 80 oC), and 4) the ionic impurities in these polymer-stabilized nano-structured LC composites could degrade the voltage holding ratio, which causes image sticking. In this dissertation, the BPLC materials are studied and the new BPLC device structures are designed to optimize display performances. From material aspect, the electro-optical properties of blue phase liquid crystals are studied based on Kerr effect. Temperature effects on polymer-stabilized blue phase or optically isotropic liquid crystal displays are investigated through the measurement of voltage dependent transmittance under different temperatures. The physical models for the temperature dependency of Kerr constant, induced birefringence and response time in BPLCs are first proposed and experimentally validated. In addition, we have demonstrated a polymer-stabilized BPLC mixture with a large Kerr constant K~13.7 nm/V2 at 20 oC at 633 nm. These models would set useful guidelines for optimizing material performances. From devices side, the basic operation principle of blue phase LCD is introduced. A numerical model is developed to simulate the electro-optic properties of blue phase LCDs based on in-plane-switching (IPS) structure. Detailed electrode dimension effect, distribution of induced birefringence, cell gap effect, correlation between operation voltage and Kerr constant, and wavelength dispersion are investigated. Viewing angle is another important parameter. We have optimized the device configurations according to the device physics studied. With proper new device designs, the operating voltage is decreased dramatically from around 50 Volts to below 10 Volts with a reasonably high transmittance (~70%) which enables the BPLCDs to be addressed by amorphous silicon thin-film transistors (TFTs). Moreover, weak wavelength dispersion, samll color shift, and low hysteresis BPLCDs are achieved after their root causes being unveiled. Optimization of device configurations plays a critical role to the widespread applications of BPLCDs. In addition to displays, blue phase liquid crystals can also be used for photonic applications, such as light modulator, phase grating, adaptive lens and photonic crystals. We will introduce the application of blue phase liquid crystal as a modulator to realize a viewing angle controllable display. The viewing angle can be tuned continuously and precisely with a fast response time. The detailed design and performance are also presented in this dissertation.Ph.D.
Doctorate
Optics and Photonics
Optics and Photonics
Optics
19
Serrano, Ana Filipa Albano. "Cochineal, a precious source of red: cochineal dyes characterization by high performance liquid chromatography with diode array detection and principal component analysis." Master's thesis, Faculdade de Ciências e Tecnologia, 2010. http://hdl.handle.net/10362/5786.
Full textAbstract:
Presented at Faculdade de Ciências e Tecnologias, Universidade de Lisboa, to obtain the Master Degree in Conservation and Restoration of TextilesThe identification of precise cochineal species used to dye historical textiles can provide important information about the provenance and date of these objects. The most widely used method to identify cochineal species in textiles involves quantification of specific minor compounds, after High-performance Liquid Chromatography with Diode Array Detection (HPLC/DAD) analysis. However, there are several factors which are not presently taken in account when characterizing cochineal species on historical textiles. Not only all the species of cochineal are not well studied, but also the current studies, based on a limited number of species, frequently face difficulties with the identification of these on historical textiles, especially due to the analysis conditions and the results treatment. Therefore, a new approach on the study of cochineal species present in historical textiles was developed. Different parameters for the analysis conditions were undertaken to optimize the results for both insect species and textiles samples. Afterwards, with Principal Components Analysis (PCA), results from textiles samples exhibited a satisfactory correlation when compared with a cochineal reference database. Moreover, High-performance Liquid Chromatography with Diode Array Detector coupled with Mass Spectrometry (HPLC/DAD/MSn) analysis could offer accurate information on cochineal species and textiles samples. The characterization of six species of cochineal allowed, through PCA and HPLC/DAD/MSn analysis, the identification of unidentified cochineal insect samples and a group of Islamic and Italian historical dyed-cochineal textiles, dated from 15th to 17th centuries. This identification contributes to connect the textiles’ history, and the trade and dyeing technologies on possible different species of cochineal. This fact regards especially textiles produced in the main textile centres, where, after the 16th century, the traded American cochineal was swiftly adopted, as many historical publications assert. Although this study identified American cochineal in a 17th-century Indian textile for the first time, the results for the other analyzed textiles did not reveal the presence of this species. In this way, the possibility of the prompt spread of the American specie in European and Asian textiles dyeing seems to be more complex than what is emphasized by present publications.
20
Vatsavai, Keerthika. "ANALYTICAL EVALUATION OF THE FLUORESCENCE CHARACTERISTICS OF METABOLITES OF POLYCYCLIC AROMATIC HYDROCARBONS AT ROOM, LIQUID NITROGEN AND LIQUID HELIUM TEMPERATURES." Master's thesis, University of Central Florida, 2007. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/2586.
Full textAbstract:
Although environmental monitoring of polycyclic aromatic hydrocarbons (PAH) is an essential step to prevent human exposure to contaminated sites, it provides little information on the actual human uptake and subsequent risks. To this end, urine analysis of short-term biomarkers such as PAH metabolites fill an important niche. The general approach follows the sequence of urine hydrolysis, sample clean-up and pre-concentration, chromatographic separation and determination. Whereas chromatographic methods are based on well established laboratory techniques, the development of easy-to-use, cost-effective and large sample throughput techniques is becoming increasingly relevant to investigate adverse PAH effects on large human populations. This thesis compares the room-temperature, 77K and 4.2K fluorescence properties of 1-naphthol, 2-naphthol, 1-hydroxypyrene, 2-hydroxyfluorene, 3-hydroxybenzopyrene and 9-hydroxyphenanthrene. These metabolites are used as model biomarkers to investigate the analytical potential of a simple method of analysis based on Solid-Phase Extraction and Room-Temperature Fluorimetry. Metabolites are directly determined in the eluting solvent (methanol) without the need of previous separation via multidimensional formats. Metabolite recoveries varied between 87 ± 1.51% (9-hydroxyphenanthrene) and 99 ± 1.05% (3-hydroxybenzopyrene). For 10mL of urine samples, limits of detection varied between 0.01ng.mL-1 (3-hydroxybenzopyrene) and 0.6ng.mL-1 (2-hydroxynaphthalene). These figures of merit demonstrate the potential of this approach for screening purposesM.S.
Department of Chemistry
Sciences
Industrial Chemistry MS
21
Ge, Zhibing. "MODELING OF LIQUID CRYSTAL DISPLAY AND PHOTONIC DEVICES." Doctoral diss., University of Central Florida, 2007. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/3867.
Full textAbstract:
Liquid crystal (LC) materials have been widely applied in electro-optical devices, among which display is the most successful playground and numerous new applications in photonic areas (such as laser beam steering devices) are also emerging. To well guide the device design for optimum performance, accurate modeling is of prior and practical importance. Generally, the modeling of LC devices includes two parts in sequence: accurate LC molecule deformation extraction under external electric fields and optical calculation thereafter for the corresponding electro-optical behaviors. In this dissertation, first, hybrid finite element method and finite difference method are developed to minimize the free energy of the LC systems. In this part of study, with computer-aided derivation, the full forms of the LC free energy equations without any simplification can be obtained. Besides, Galerkin's method and weak form technique are further introduced to successfully degrade the high order nonlinear derivative terms associated with the free energy equations into ones that can be treated by first order interpolation functions for high accuracy. The developed modeling methods for LC deformation are further employed to study display structures, such as 2D and 3D in-plane switching LC cells, and provides accurate results. Followed is the optical modeling using extended Jones matrix and beam propagation method to calculate the electro-optical performances of different devices, according to their amplitude modulation property or diffractive one. The developed methods are further taken to assist the understanding, development, and optimization of the display and photonic devices. For their application in the display area, sunlight readable transflective LCDs for mobile devices and the related optical films for wide viewing angle are developed and studied. New cell structure using vertically aligned liquid crystal mode is developed and studied to obtain a single cell gap, high light efficiency transflective LCD that can be driven by one gray scale control circuit for both transmissive and reflective modes. And employing an internal wire grid polarizer into a fringe field switching cell produces a single cell gap and wide viewing angle display with workable reflective mode under merely two linear polarizers. To solve the limited viewing angle of conventional circular polarizers, Poincaré sphere as an effective tool is taken to trace and understand the polarization change of the incident light throughout the whole LC system. This study further guides the design of high performance circular polarizers that can consist of purely uniaxial plates or a combination of uniaxial and biaxial plates. The developed circular polarizers greatly enhance the viewing angle of transflective LCDs. Especially, the circular polarizer design using a biaxial film can even provide comparable wide viewing angle performance for the same vertically aligned cell as it is used between merely two linear polarizers, while using circular polarizers can greatly boost the display brightness. As for the beam steering device modeling, the developed LC deformation method is taken to accurately calculate the associated LC director distribution in the spatial light modulator, while beam propagation method and Fourier transformation technique are combined to calculate the near and far fields from such devices. The modeling helps to better understand the origins and formations of the disclinations associated with the fringe fields, which further result in reduced steering efficiency and output asymmetric polarizations between positive and negative diffractions. Optimization in both voltage profile and driving methods is conducted to well tune the LC deformation under strong fringe fields and improve the light efficiency.Ph.D.
School of Electrical Engineering and Computer Science
Engineering and Computer Science
Electrical Engineering PhD
22
Watzková, Jarmila. "Extrakce, separace a identifikace anthokyanů ve slupkách bobulí červených odrůd Vitis vinifera." Master's thesis, Vysoké učení technické v Brně. Fakulta chemická, 2008. http://www.nusl.cz/ntk/nusl-216438.
Full textAbstract:
This diploma thesis deals with application of pressurized liquid extraction (PFE) on grape skins of Vitis vinifera cultivars Alibernet and Svatovavřinecké to gain extraction of anthocyanin pigments in the form of 3-monoglucosides. This thesis deals with comparison efficiency pressurized liquid extraction (PFE) for the range temperatures 40–120 °C and the Soxhlet extraction with four extraction solvents. The identification of the anthocyanin pigments by high-performance liquid chromatography with diode array detection (HPLC/DAD) based on Synergi C12 column separation (Phenomenex) was performed. The anthocyanin pigments were identified at wavelength 520 nm. The complete amount of anthocyanin pigments grape skins was depended on the extraction solvent and temperature in range 0,38–244,06 mg/g for cultivar Alibernet and 0,28–105,01 mg/g for cultivar Svatovavřinecké. The contents of anthocyanin pigments was determined in the samples of wine both cultivars in the range 3,83–2836,84 mg/l too. PFE followed by HPLC/DAD employing Synergi C12 column provides relatively fast, quantitative and reproducible determination of anthocyanins in grape skins and wines.
23
Du, Fang. "LIQUID CRYSTAL MATERIALS AND TUNABLE DEVICES FOR OPTICAL COMMUNICATIONS." Doctoral diss., University of Central Florida, 2005. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/3375.
Full textAbstract:
In this dissertation, liquid crystal materials and devices are investigated in meeting the challenges for photonics and communications applications. The first part deals with polymer-stabilized liquid crystal (PSLC) materials and devices. Three polymer-stabilized liquid crystal systems are developed for optical communications. The second part reports the experimental investigation of a novel liquid-crystal-infiltrated photonic crystal fiber (PCF) and explores its applications in fiber-optic communications. The curing temperature is found to have significant effects on the PSLC performance. The electro-optic properties of nematic polymer network liquid crystal (PNLC) at different curing temperatures are investigated experimentally. At high curing temperature, a high contrast, low drive voltage, and small hysteresis PNLC is obtained as a result of the formed large LC micro-domains. With the help of curing temperature effect, it is able to develop PNLC based optical devices with highly desirable performances for optical communications. Such high performance is generally considered difficult to realize for a PNLC. In fact, the poor performance of PNLC, especially at long wavelengths, has hindered it from practical applications for optical communications for a long time. Therefore, the optimal curing temperature effect discovered in this thesis would enable PSLCs for practical industrial applications. Further more, high birefringence LCs play an important role for near infrared photonic devices. The isothiocyanato tolane liquid crystals exhibit a high birefringence and low viscosity. The high birefringence LC dramatically improves the PSLC contrast ratio while keeping a low drive voltage and fast response time. A free-space optical device by PNLC is experimentally demonstrated and its properties characterized. Most LC devices are polarization sensitive. To overcome this drawback, we have investigated the polymer-stabilized cholesteric LC (PSCLC). Combining the curing temperature effect and high birefringence LC, a polarization independent fiber-optical device is realized with over 30 dB attenuation, ~12 Vrms drive voltage and 11/28 milliseconds (rise/decay) response times. A polymer-stabilized twisted nematic LC (PS TNLC) is also proposed as a variable optical attenuator for optical communications. By using the polarization control system, the device is polarization independent. The polymer network in a PS TNLC not only results in a fast response time (0.9/9 milliseconds for rise/decay respectively), but also removes the backflow effect of TNLC which occurs in the high voltage regime.Ph.D.
Other
Optics and Photonics
Optics
24
Partridge, Jonathan Koert. "Experimental studies of liquefaction and densification of liquid oxygen." Master's thesis, University of Central Florida, 2010. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/4574.
Full textAbstract:
Rocketry employs cryogenic refrigeration to increase the density of propellants, such as oxygen, and stores the propellant as a liquid. In addition to propellant liquefaction, cryogenic refrigeration can also conserve propellant and provide propellant subcooling and densification. Previous studies analyzed vapor conditioning of a cryogenic propellant, which occurred by either a heat exchanger positioned in the vapor or by using the vapor as the working fluid in a refrigeration cycle. This study analyzes the refrigeration effects of a heat exchanger located beneath the vapor-liquid interface of liquid oxygen. This study predicts the mass liquefaction rate and heat transfer coefficient for liquid oxygen using two different models, a Kinetic Theory Model and a Cold Plate Model, and compares both models to experimental data. The Kinetic Theory Model overestimated the liquefaction rate and heat transfer coefficient by five to six orders of magnitude, while the Cold Plate Model underestimated the liquefaction rate and heat transfer coefficient by one to two orders of magnitude. This study also suggested a model to predict the densification rate of liquid oxygen, while the system is maintained at constant pressure. The densification rate model is based on transient heat conduction analysis and provides reasonable results when compared to experimental data.ID: 029049996; System requirements: World Wide Web browser and PDF reader.; Mode of access: World Wide Web.; Thesis (M.S.M.E.)--University of Central Florida, 2010.; Includes bibliographical references (p. 127-129).
M.S.M.E.
Masters
Department of Mechanical, Materials and Aerospace Engineering
Engineering and Computer Science
Mechanical Engineering
25
Bera, Tanmay. "Developing surface engineered liquid crystal droplets for sensing applications." Doctoral diss., University of Central Florida, 2012. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/5125.
Full textAbstract:
Diagnosis plays a very crucial role in medicine and health care, which makes biosensors extremely important in modern technological context. Till date, various types of biosensors have been developed that are capable of detecting a wide range of biologically important species with great sensitivity and selectivity. However, most of these sensing units require highly sophisticated instrumentation and often lack the desired portability. Liquid crystal (LC) droplets, on the other hand, are a new type of functional material that are finding increasing research attention as a new sensing unit due to their tunable optical property, high surface area, portability and cost-effectiveness. In this dissertation, functionalized LC droplets for biosensing at aqueous-LC interface are highlighted. Chemically functionalized LC droplets dispersed in aqueous solution were prepared by the self-assembly of amphiphilic molecules at the aqueous/LC interface. These functionalized LC droplets showed a well-defined director of configuration and a specific optical pattern when observed with a polarizing light microscope. It was discovered that the interaction of chemically functionalized LC droplets with an analyte triggers transition of the director of configuration of the LC within the droplets, providing a simple and unique optical sign for the detection of the analyte. Moreover, the director of configuration transition happened in a concentration dependent manner, allowing both qualitative and quantitative detection of the analyte. The sensitivity of chemically functionalized LC droplets depends not only on the nature of amphiphilic molecules but also the size and number of the droplets. The dissertation essentially deals with the application of these chemically functionalized LC droplets in detecting several biologically important species. It was observed that the adsorption of charged macromolecules (dendrimers, proteins, and viruses) on polyelectrolyte functionalized LC droplets triggered a bipolar-to-radial configuration transition based on the polar verses non-polar interaction. By using a simple optical microscope, microgram per milliliter concentrations of bovine serum albumin, cowpea mosaic virus, and tobacco mosaic virus could be detected in aqueous solution. The detection limit of Mastoparan X polypeptide decorated LC droplets in detecting E. coli could reach to approximately 10 bacteria per milliliter. In this case, the high affinity of the polypeptide towards the bacterial causes the former to detach from the LC droplets, triggering the director of configuration transition of the LC inside the droplets. Finally, surfactant decorated LC droplets were used to detect lithocholic acid (LCA), a toxic bile acid used as a specific biomarker for colon cancers. In this case, the director of configuration transition of the LC inside the droplets is a result of the replacement of the surfactant from the aqueous/LC interface by LCA. The microgram per milliliter concentration of LCA, a clinically significant concentration, could be easily detected by changing the length of surfactants. These studies highlight the novel use of surface functionalized LC droplets to detect biologically important species. Due to their tunable optical property, coupled with high surface area and portability, surface functionalized LC droplets have great potentials in the design of next generation biosensors.ID: 031001378; System requirements: World Wide Web browser and PDF reader.; Mode of access: World Wide Web.; Adviser: .; Title from PDF title page (viewed May 21, 2013).; Thesis (Ph.D.)--University of Central Florida, 2012.; Includes bibliographical references (p. 119-134).
Ph.D.
Doctorate
Materials Science Engineering
Engineering and Computer Science
Materials Science and Engineering
26
Chen, Kuan Ming. "Submillisecond-response blue phase liquid crystals for display applications." Doctoral diss., University of Central Florida, 2012. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/5158.
Full textAbstract:
With exploding growth of information exchanges between people, display has become indispensable in our daily lives. After decades of intensive research and development in materials and devices, and massive investment in manufacturing technologies, liquid crystal display (LCD) has overcome various obstacles and achieved the performance we need, such as wide viewing angle, high contrast ratio, and high resolution, etc. These excellent performances make LCD prevailed in every perspective. Recently, with the demands of energy conservation, a greener LCD with lower power consumption is desired. In order to achieve this goal, new energy-effective driving methods, such as field sequential color display, have been proposed. However, in order to suppress color breakup the LC response time should be faster than 1 ms. To overcome this challenge, various fast-response liquid crystal modes, such as thin cell gap, low viscosity materials, overdrive and undershoot voltages, polymer stabilization, and ferroelectric liquid crystal, are under active investigations. Among these approaches, blue phase liquid crystal (BPLC) shows a greater potential with less fabrication limitations. In this dissertation, the feasibility of polymer-stabilized blue phase liquid crystal for display applications is explored starting from the building blocks of the material system, polymer-stabilization processes, test cell preparations, electro-optical (EO) properties, to suggested approaches for further improvements. Because of the nature of blue phase liquid crystals, delicate balance among system components is critically important. Besides the properties of each composition, the preparation process also dictates the EO performance of the self-assembled nano-structured BPLC composite. After the preparation of test cells, EO properties for display applications are investigated and results described. Approaches for further improvements of the EO properties are also suggested in the final part of this dissertation.ID: 031001409; System requirements: World Wide Web browser and PDF reader.; Mode of access: World Wide Web.; Title from PDF title page (viewed June 12, 2013).; Thesis (Ph.D.)--University of Central Florida, 2012.; Includes bibliographical references (p. 82-89).
Ph.D.
Doctorate
Optics and Photonics
Optics and Photonics
Optics
27
Sun, Jie. "Fast-Response Liquid Crystals for Photonic and Display Applications." Doctoral diss., University of Central Florida, 2013. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/6025.
Full textAbstract:
Liquid crystals (LCs) are attractive for many applications such as information displays, spatial light modulators, and adaptive optics because the optical properties of these devices are electrically tunable. For most display and photonic applications, response time is a critical parameter especially for spatial light modulators that requires at least 2? phase change. This problem gets more severe as the wavelength increases because a thicker LC layer is needed, which results in a slower response time. A typical E7 nematic liquid crystal cell with 2? phase change shows a response time longer than 100 ms at room temperature, which is too slow. Therefore, solutions for achieving fast response time are in high demand.
In this dissertation, several approaches for achieving submillisecond response time are investigated. In Chapter 2, we begin by introducing dual frequency liquid crystals (DFLCs) which provide possibility to achieve submillisecond rise time and decay time. We developed a DFLC mixture with a record-high birefringence (?n=0.39 at ?=633nm) based on phenyl-tolane compounds, which exhibit a positive dielectric anisotropy (??) and modest dielectric relaxation frequency.
In Chapter 3, a phase modulator with 4? phase change and 400 &"181;s average gray-to-gray response time is demonstrated using a sheared polymer network liquid crystal (SPNLC). This device exhibits a low scattering at ?=532 nm due to the employed material set and shearing technique. We also discuss the application of SPNLCs for 3D displays.
In Chapter 4, we studied the temperature effect on the splay elastic constant of polymer network liquid crystal (PNLC). Due to the existence of polymer network, the temperature dependent splay elastic constant of the LC cell deviates from the model for nematic LCs.
In Chapter 5, we focus on PNLC light modulators. This technology is attractive because it can achieve submillisecond response time while maintaining a large phase change. However, the light scattering loss caused by grain boundaries of liquid crystal multi-domains at voltage-on state hinders the widespread application of PNLCs. By optimizing liquid crystal host, polymer, and proper curing process, we successfully eliminate light scattering from short wave infrared region (1.55 ?m) to visible range.
In Chapter 6, we introduce a reconfigurable fabrication technique of tunable liquid crystal devices. Based on this technique and our scattering-free PNLCs, we developed a series of fast switching LC devices such as LC prism, grating and lens. The application of this technology in 3D lenticular lens development is also discussed. This technique provides a great flexibility for designing and fabricating LC photonic devices with desired refractive index profile.Ph.D.
Doctorate
Optics and Photonics
Optics and Photonics
Optics
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Chen, Yuan. "Advanced liquid crystal materials for display and photonic applications." Doctoral diss., University of Central Florida, 2014. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/6261.
Full textAbstract:
Thin-film-transistor (TFT) liquid crystal display (LCD) has been widely used in smartphones, pads, laptops, computer monitors, and large screen televisions, just to name a few. A great deal of effort has been delved into wide viewing angle, high resolution, low power consumption, and vivid color. However, relatively slow response time and low transmittance remain as technical challenges. To improve response time, several approaches have been developed, such as low viscosity liquid crystals, overdrive and undershoot voltage schemes, thin cell gap with a high birefringence liquid crystal, and elevated temperature operation. The state-of-the-art gray-to-gray response time of a nematic LC device is about 5 ms, which is still not fast enough to suppress the motion picture image blur. On the other hand, the LCD panel's transmittance is determined by the backlight, polarizers, TFT aperture ratio, LC transmittance, and color filters. Recently, a fringe-field-switching mode using a negative dielectric anisotropy (??) LC (n-FFS) has been demonstrated, showing high transmittance (98%), single gamma curve, and cell gap insensitivity. It has potential to replace the commonly used p-FFS (FFS using positive ?? LC) for mobile displays.
With the urgent need of submillisecond response time for enabling color sequential displays, polymer-stabilized blue phase liquid crystal (PS-BPLC) has become an increasingly important technology trend for information display and photonic applications. BPLCs exhibit several attractive features, such as reasonably wide temperature range, submillisecond gray-to-gray response time, no need for alignment layer, optically isotropic voltage-off state, and large cell gap tolerance. However, some bottlenecks such as high operation voltage, hysteresis, residual birefringence, and slow charging issue due to the large capacitance, remain to be overcome before their widespread applications can be realized. The material system of PS-BPLC, including nematic LC host, chiral dopant, and polymer network, are discussed in detail. Each component plays an essential role affecting the electro-optic properties and the stability of PS-BPLC.
In a PS-BPLC system, in order to lower the operation voltage the host LC usually has a very large dielectric anisotropy (??>100), which is one order of magnitude larger than that of a nematic LC. Such a large ?? not only leads to high viscosity but also results in a large capacitance. High viscosity slows down the device fabrication process and increases device response time. On the other hand, large capacitance causes slow charging time to each pixel and limits the frame rate. To reduce viscosity, we discovered that by adding a small amount (~6%) of diluters, the response time of the PS-BPLC is reduced by 2X-3X while keeping the Kerr constant more or less unchanged. Besides, several advanced PS-BPLC materials and devices have been demonstrated. By using a large ?? BPLC, we have successfully reduced the voltage to <10V while maintaining submillisecond response time. Finally we demonstrated an electric field-indeced monodomain PS-BPLC, which enables video-rate reflective display with vivid colors. The highly selective reflection in polarization makes it promising for photonics application.
Besides displays in the visible spectral region, LC materials are also very useful electro-optic media for near infrared and mid-wavelength infrared (MWIR) devices. However, large absorption has impeded the widespread application in the MWIR region. With delicate molecular design strategy, we balanced the absorption and liquid crystal phase stability, and proposed a fluoro-terphenyl compound with low absorption in both MWIR and near IR regions. This compound serves as an important first example for future development of low-loss MWIR liquid crystals, which would further expand the application of LCs for amplitude and/or phase modulation in MWIR region.Ph.D.
Doctorate
Optics and Photonics
Optics and Photonics
Optics and Photonics
29
Tawhid-Al-Islam, Kazi M. "Electromagnetic Effect on the Rheology of Liquid Suspension." Diss., Temple University Libraries, 2018. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/513297.
Full textAbstract:
PhysicsPh.D.
Innovative methods to control the viscosity and turbulence in the flow of liquid suspension can be engineered by way of incorporating the concepts of electric and magnetic field into the rheology of complex fluids. Rheology of liquid Chocolate is a very crucial factor in determining the cost of manufacturing process as well as formulating varieties of end consumer products, for example, containing less fat. We have invented a method to lower the viscosity of liquid chocolate flow with the application of electric field. In the lab, we have found that viscosity of chocolate samples is reduced by 40~50% with our method. Thus, fat content in those samples can be reduced by 10% or more. Therefore, we expect to see much healthier and tastier chocolate product in the market once this technology gets implemented in commercial manufacturing. High viscosity and turbulence in blood flow greatly increase the risk of cardiac diseases. Hence, discovering new method to address turbulence suppression and viscosity reduction is critically important. In our study, we have found that in the in-vitro experiment, if blood is subjected to flow through a channel placed inside a strong magnetic field, its viscosity reduces by 10~20%. Based on these findings, a Megneto-Rheology (MR) therapeutic device has been developed to examine the effect on the blood pressure in human subjects. Preliminary clinical trials show that application of this MR therapy reduces blood pressure by 10% or more. In this thesis, above mentioned inventions for the flow of Blood and liquid Chocolate will be thoroughly discussed.
Temple University--Theses
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Cucchiara, Jason. "PUBS, PUNTERS, AND PINTS: ANTHROPOLOGICAL REFLECTIONS ON PUB LIFE IN IRELAND." Master's thesis, University of Central Florida, 2009. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/4278.
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Ireland is a country with a rich and unique cultural heritage. It is difficult to imagine that certain facets of Irish culture (e.g. Saint Patrick's Day, the Blarney Stone, or the Ring of Kerry) can ever be taken for granted since they are so widely recognized internationally. One common feature of Irish life that possibly warrants more scholarly attention is the public house or pub. Much has been written about pubs as quaint institutions in popular literature and fiction. Curiously, they remain largely overlooked as vital aspects of Irish culture by anthropologists and others in the social sciences. In many ways, socio-cultural research on pub life in Ireland is woefully under examined. In an effort to better evaluate the significance of traditional pub life to Irish culture, my thesis seeks to integrate and critically assess the existing socio-cultural literature on Irish pub life. Such work will not only help highlight both the commonalities and discrepancies within this area of study, it will more significantly identify those areas of Irish pub life that can benefit from further academic investigation. Two recent trips to Ireland in September 2004 and May 2006, allowed me to observe important aspects of pub life first hand. It became apparent from these encounters that, like the history of Ireland itself, local pubs have a rich historical foundation. Many of the pubs that I visited have been in existence or operational since the Middle Ages. Based on this longevity, one can reasonably argue that pubs in Ireland function largely as locales of social significance and cultural reproduction, not just centers of recreational drinking. Using my travel experience as a starting point for the critical analysis phase of this thesis project, I have developed three general research questions that I will explore to varying degrees in the context of this work. These are: (1) what are the origins of pubs in Ireland?; (2) what explicit and implicit functions do pubs serve in Irish communities?; and (3) what possible developments are likely to affect Irish pubs in the near and distant future?M.A.
Department of Anthropology
Sciences
Anthropology MA
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Sarkissian, Hakob. "APPLICATIONS OF LINEAR AND NONLINEAR OPTICAL EFFECTS IN LIQUID CRYSTALS." Doctoral diss., University of Central Florida, 2006. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/2603.
Full textAbstract:
Liquid crystals have been a major subject of research for the past decades. Aside from the variety of structures they can form, they exhibit a vast range of optical phenomena. Many of these phenomena found applications in technology and became an essential part of it. In this dissertation thesis we continue the line to propose a number of new applications of optical effects in liquid crystals and develop their theoretical framework. One such application is the possibility of beam combining using Orientational Stimulated Scattering in a nematic liquid crystal cell. Our numerical study of the OSS process shows that normally this possibility does not exist. However, we found that if a number of special conditions is satisfied efficient beam combining with OSS can be done. These conditions require a combination of special geometric arrangement of incident beams, their profiles, nematic material, and more. When these conditions are fulfilled, power of the beamlets can be coherently combined into a single beam, with high conversion efficiency while the shape and wave-front of the output beam are still of good quality. We also studied the dynamics of the OSS process itself and observed (in a numerical model) a number of notorious instabilities caused by effects of back-conversion iv process. Additionally, there was found a numerical solitary-wave solution associated with this back-conversion process. As a liquid crystal display application, we consider a nematic liquid crystal layer with the anisotropy axis modulated at a fixed rate in the transverse direction with respect to light propagation direction. If the layer locally constitutes a half-wave plate, then the thinscreen approximation predicts 100% -efficient diffraction of normal incident wave. If this diffracted light is blocked by an aperture only transmitting the zero-th order, the cell is in dark state. If now the periodic structure is washed out by applying voltage across the cell and light passes through the cell undiffracted, the light will pass through the aperture as well and the cell will be in its bright state. Such properties of this periodically aligned nematic layer suggest it as a candidate element in projection display cells. We studied the possibility to implement such layer through anchoring at both surfaces of the cell. It was found that each cell has a thickness threshold for which the periodic structure can exist. The anchored periodic structure cannot exist if thickness of the cell exceeds this threshold. For the case when the periodic structure exists, we found the structure distortion in comparison with the preferable ideal sinusoidal profile. To complete description of the electromechanical properties of the periodic cell, we studied its behavior at Freedericksz transition. Optical performance was successfully described with the coupled-mode theory. While influence of director distortion is shown to be negligibly small, the walk-off effects appear to be larger. In summary, there are good prospects for use of this periodically v aligned cell as a pixel in projection displays but experimental study and optimization need to be performed. In the next part we discuss another modulated liquid crystal structure in which the director periodically swings in the direction of light propagation. The main characteristic of such structure is the presence of bandgap. Cholesteric liquid crystals are known to possess bandgap for one of two circular polarizations of light. However, unlike the cholesterics the bandgap of the proposed structure is independent of polarization of normally incident light. This means that no preparation of light is needed in order for the structure to work in, for example, liquid crystal displays. The polarization universality comes at the cost of bandgap size, whose maximum possible value ∆ωPTN compared to that of cholesterics ∆ωCh is approximately twice smaller: ∆ωPTN ≈ 0.58∆ωCh if modulation profile is sinusoidal, and ∆ωPTN ≈ 0.64∆ωCh if it is rectangular. This structure has not yet been experimentally demonstrated, and we discuss possible ways to make it.Ph.D.
Other
Optics and Photonics
Optics
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Wehking, Jonathan. "Electrohydrodynamic Manipulation of Liquid Droplet Emulsions in a Microfluidic Channel." Doctoral diss., University of Central Florida, 2013. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/6034.
Full textAbstract:
This work specifically aims to provide a fundamental framework, with some experimental validation, for understanding droplet emulsion dynamics in a microfluidic channel with an applied electric field. Electrification of fluids can result in several different modes of electrohydrodynamics (EHD). Several studies to date have provided theoretical, experimental, and numerical results for stationary droplet deformations and some flowing droplet configurations, but none have reported a method by which droplets of different diameters can be separated, binned and routed through the use of electric fields. It is therefore the goal of this work to fill that void and report a comprehensive understanding of how the electric field can affect flowing droplet dynamics.
This work deals with two primary models used in electrohydrodynamics: the leaky dielectric model and the perfect dielectric model. The perfect dielectric model assumes that fluids with low conductivities do not react to any effects from the small amount of free charge they contain, and can be assumed as dielectrics, or electrical insulators. The leaky dielectric model suggests that even though the free charge is minimal in fluids with low conductivities, it is still is enough to affect droplet deformations. Finite element numerical results of stationary droplet deformations, implemented using the level set method, compare well both qualitatively (prolate/oblate and vortex directions), and quantitatively with results published by other researchers. Errors of less than 7.5% are found when comparing three-dimensional (3D) numerical results of this study to results predicted by the 3D leaky dielectric model, for a stationary high conductivity drop suspended in a slightly lower conductivity suspending medium. Droplet formations in a T-junction with no applied electric field are adequately predicted numerically using the level set finite element technique, as demonstrated by other researchers and verified in this study. For 3D models, droplet size is within 6%, and droplet production frequency is within 2.4% of experimental values found in the microfluidic T-junction device. In order to reduce computational complexity, a larger scale model was solved first to obtain electrical potential distributions localized at the channel walls for the electrode placement configurations.
Droplet deceleration and pinning is demonstrated, both experimentally and numerically, by applying steep gradients of electrical potential to the microchannel walls. As droplets flow over these electrical potential ``steps," they are pinned to the channel walls if the resulting electric forces are large enough to overcome the hydrodynamic forces. A balance between four dimensionless force ratios, the electric Euler number (Eu_e - ratio of inertial to electric forces), Mason number (Ma - ratio of viscous to electric forces), electric pressure (Ps - ratio of upstream pressure forces to electric forces), and the electric capillary number (Ca_e - ratio of electric to capillary forces) are used to quantify the magnitudes of each of these forces required to pin a droplet, and is consistent with a cubic dependency on the drop diameter. For larger drop diameters, effects of hydrodynamic forces become more prominent, and for smaller droplets, a greater electric forces is required due to the proximity of the droplet boundary with reference to the electrified channel wall. Droplet deceleration and pinning can be exploited to route droplets into different branches of a microfluidic T-junction. In addition, using steep electrical potential gradients placed strategically along a microchannel, droplets can even be passively binned by size into separate branches of the microfluidic device. These characteristics have been identified and demonstrated in this work.Ph.D.
Doctorate
Mechanical and Aerospace Engineering
Engineering and Computer Science
Mechanical Engineering
33
Richardson, Lyle. "Liquid yield option notes (LYONS) : corporate objectives, valuation and pricing." Honors in the Major Thesis, University of Central Florida, 2001. http://digital.library.ucf.edu/cdm/ref/collection/ETH/id/299.
Full textAbstract:
This item is only available in print in the UCF Libraries. If this is your Honors Thesis, you can help us make it available online for use by researchers around the world by following the instructions on the distribution consent form at http://library.ucf.edu/Systems/DigitalInitiatives/DigitalCollections/InternetDistributionConsentAgreementForm.pdf You may also contact the project coordinator, Kerri Bottorff, at kerri.bottorff@ucf.edu for more information.Bachelors
Business Administration
Finance
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Keller, Scott. "Stress Intensity Factor Dependence of HG-AL Liquid Metal Embrittlement." Master's thesis, University of Central Florida, 2009. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/2220.
Full textAbstract:
When high strength aluminum alloys are subjected to liquid metals, physical and chemical reactions ensue resulting in what is known as liquid metal embrittlement (LME). A subset of environmentally-assisted cracking, LME is exhibited when a liquid metal, e.g. Hg or Ga, comes into intimate contact with a solid metal having significant susceptibility. As mechanical loads are applied, the interaction between the two metals results in a reduction in the flow properties of the solid metal. Several theories have been proposed to identify the underlying microstructural failure mechanism; however, none have been widely accepted, as failures can typically incorporate features common to several failure theories. In an effort to confirm, extend or replace the physically-based theories, fracture mechanics experiments on Al 7075-T651 in liquid mercury have been conducted. Experiments were conducted in a custom environmental chamber capable of exposing specimens to liquid environments while applying a mechanical load. Through both plane-strain fracture and stress intensity factor-dependent (SIF) tests, fracture toughness values along with incubation periods were analyzed and provided data for a load-based theory of LME. These mechanical test data, along with metallographic analysis, show that the phenomena of LME is both strongly time- and SIF-dependent.M.S.M.E.
Department of Mechanical, Materials and Aerospace Engineering;
Engineering and Computer Science
Mechanical Engineering MSME
35
Fisher, Brian. "Surface Acoustic Wave (SAW) Cryogenic Liquid and Hydrogen Gas Sensors." Doctoral diss., University of Central Florida, 2012. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/5208.
Full textAbstract:
This research was born from NASA Kennedy Space Center's (KSC) need for passive, wireless and individually distinguishable cryogenic liquid and H2 gas sensors in various facilities. The risks of catastrophic accidents, associated with the storage and use of cryogenic fluids may be minimized by constant monitoring. Accidents involving the release of H2 gas or LH2 were responsible for 81% of total accidents in the aerospace industry. These problems may be mitigated by the implementation of a passive (or low-power), wireless, gas detection system, which continuously monitors multiple nodes and reports temperature and H2 gas presence. Passive, wireless, cryogenic liquid level and hydrogen (H2) gas sensors were developed on a platform technology called Orthogonal Frequency Coded (OFC) surface acoustic wave (SAW) radio frequency identification (RFID) tag sensors. The OFC-SAW was shown to be mechanically resistant to failure due to thermal shock from repeated cycles between room to liquid nitrogen temperature. This suggests that these tags are ideal for integration into cryogenic Dewar environments for the purposes of cryogenic liquid level detection. Three OFC-SAW H2 gas sensors were simultaneously wirelessly interrogated while being exposed to various flow rates of H2 gas. Rapid H2 detection was achieved for flow rates as low as 1ccm of a 2% H2, 98% N2 mixture. A novel method and theory to extract the electrical and mechanical properties of a semiconducting and high conductivity thin-film using SAW amplitude and velocity dispersion measurements were also developed. The SAW device was shown to be a useful tool in analysis and characterization of ultrathin and thin films and physical phenomena such as gas adsorption and desorption mechanisms.?Ph.D.
Doctorate
Electrical Engineering and Computer Science
Engineering and Computer Science
Electrical Engineering
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Heller, David Francis. "Pass The Flow: The Subcultural Practice of Liquid Dance." Diss., Temple University Libraries, 2018. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/539612.
Full textAbstract:
DancePh.D.
This dissertation explores how the subcultural practice of liquid dance emerged from US rave culture and continues to sustain itself and evolve in today’s era of social media and EDM festival culture. I draw upon the concept of flow as a lens to trace the historical, aesthetic, digital, social and subcultural trajectory of liquid dance. I analyze how this subculture continues to evolve through individual practice, as well as how dance is shared through online and live dance exchange. My dissertation consists of seven chapters that provide both academic and practitioner perspectives of liquid dance. My research methods combine a multidisciplinary approach to implementing semi-structured interviews, participant observation, and digital archival research. My fieldwork consists of interviewing fourteen liquid practitioners, as well as conducting ethnographic research at an EDM festival where liquid dancers annually attend and participate. The purpose of this project is twofold. One, to contribute new knowledge to the field of dance studies on the specific dance genre of liquid, which up until now has not been documented in this field. Two, to provide a space for practitioners to openly share their perspectives in a collaborative effort to produce new knowledge. From the beginning, it has been my intention to produce a dissertation that provides the foundation for a continuing series of academic discussions from which to draw upon for further, future research and critical engagement with liquid dance. This document may also be used as a template for scholars across disciplines to deploy as a lens to analyze and critique other subcultural dance practices within the continuum of rave, club and dance music festivals.
Temple University--Theses
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Steele, Valerie J. "Organic residue analysis of Red Lustrous Wheelmade Ware vessels traded across the eastern Mediterranean during the Late Bronze Age." Thesis, University of Bradford, 2008. http://hdl.handle.net/10454/5519.
Full textAbstract:
Red Lustrous Wheelmade Ware (RLWm ware) transport and storage vessels have been excavated from Late Bronze Age (LBA) sites across the eastern Mediterranean. These distinctive vessels were traded for the valuable commodity they contained so far unidentified. Seventy-three sherds (61 RLWm ware, 12 in local fabrics) and two visible residues were analysed for organic residues using standard lipid extraction techniques. Seven residues from a previous study were re-examined. Gas chromatography-mass spectrometry identified four materials - beeswax, bitumen, fat/oil and resin. Beeswax, found only in vessels from Hittite sites in Turkey, was probably used as a post-firing treatment. Fat/oil, present in some sherds from every site, represents the contents of the vessels and showed many of the characteristics of degraded plant oil. Two examples contained a plant sterol and three yielded ricinoleic acid, a biomarker for castor oil. Gas-chromatography compound-specific isotope ratio mass spectrometry of selected residues excluded dairy products, ruminant animal fats and fish oils as source materials for the fats/oils, while comparison with a small database of modern oils created during this study does not exclude plant oils. Selected samples analysed by high performance liquid chromatography-tandem mass spectrometry did not reveal wine residues. Data on the elemental composition of the fabric collected during another study was re-analysed and compared with data from a further published study, confirming the remarkable consistency of RLWm ware fabric. Volume calculations were also attempted to give an estimate of the capacity of the main vessel forms.
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Gracia-Gonzalez, Gerardo. "Metabolite Profiling of Hard Red Spring Wheat (Triticum Aestivum) Inoculated with Fusarium Graminearum Utilizing Ultra High Pressure Liquid Chromatography-Quadrupole Time of Flight / Mass Spectrometry." Diss., North Dakota State University, 2015. http://hdl.handle.net/10365/24874.
Full textAbstract:
Fusarium Head Blight (FHB) of wheat is a fungal disease caused mainly by Fusarium graminearum. It has been a persistent worldwide problem for years causing substantial economic losses. Efforts to breed resistance in wheat cultivars represent a practical way to manage this disease. However, there is still much to contribute on how the infection develops and what events make a cultivar resistant to the infection at a molecular level. A metabolite profiling time course strategy was applied to a wheat near isogenic lines (NIL), with contrasting resistant alleles, and three hard red spring wheat cultivars with various degrees of resistance. The analytical time window where no significant difference occurs from sample extraction to sample analysis was also determined adding robustness to this study. Results indicate a maximum analytical window time of 7:45 hours for a wheat extraction queued in an UHPLC auto-sampler at 25 ??C. Combining UHPLC-QTOF/MS technology with statistical analyses resulted in 61 significant metabolites (p < 0.05; fold change ?? 2). The NIL and wheat cultivars had profiles with common and unique molecules. Tentative identification was performed by using accurate mass search, tandem MS fragmentation data with internal and online databases. Taking into account the restriction of database identifications, results confirm the presence of hydroxycinnamic acid amides (HCAA) which have been shown to induce thickening of cell walls. These compounds were seen in the resistant and susceptible genotypes with no difference in their intensities but can appear as early or late occurring between 0 and 48 hours after inoculation. Compounds classified as resistant related induced and resistant related constitutive were found in the NIL resistant pair at 48hrs. ??Susceptibility indicator?? molecules were also observed in the susceptible NIL pair. This suggest that for the NIL pair, HCAA were a normal part of host reaction, while potentially important metabolites for the host resistance may develop later than 48 hours after inoculation. It was possible to establish an analytical and data mining methodology to perform metabolite profiling in wheat florets utilizing a UPLC-QTOF/MS.
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Semyonov, Alexander N. "Design, Synthesis and Characterization of Fluorescent Dyes and Liquid Crystal Semiconductors." Kent State University / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=kent1153556141.
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Nie, Xiangyi. "ANCHORING ENERGY AND PRETILT ANGLE EFFECTS ON LIQUID CRYSTAL RESPONSE TIME." Doctoral diss., University of Central Florida, 2007. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/2591.
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This dissertation covers some important topics on the liquid crystal-substrate surface effects, including theoretical derivations and confirming experimental results. The research work is expected to make important impacts on liquid crystal device designs and to open new doors for further research along these topics. In this dissertation, a novel high-electric-field technique is developed to characterize the anchoring energy of vertically-aligned liquid crystal cells. Both theoretical analyses and confirming experimental results are presented. Vertically-aligned liquid crystal cells with buffed polyimide alignment layers are used to validate the measurement techniques. Based on the voltage-dependent transmittance of the liquid crystal cells, a linear fitting can be obtained, which leads to a precise determination of the anchoring energy. If some specific liquid crystal material parameters are known, then the traditional cell capacitance measurements can be avoided. Anchoring energy and cell gap effects on liquid crystal response time is theoretically analyzed and experimentally investigated. A novel theory on the liquid crystal dynamics is developed. In this part, two different theoretical approaches are discussed: one is surface dynamic equation method and the other is effective cell gap method. These two different approaches lead to consistent results, which are also confirmed by our experimental results. This work opens a new door for LCD industry to optimize liquid crystal response time, and it is especially critical for liquid crystal cells with thin cell gap, which is a promising approach for fast response time liquid crystal display. Pretilt angle effects on liquid crystal dynamics are analyzed theoretically and validated experimentally. Analytical expressions are derived to describe liquid crystal response time under nonzero pretilt angle conditions. The theoretical analysis is confirmed experimentally using vertically-aligned liquid crystal cells. These results quantitatively correlate pretilt angles with liquid crystal response time, which is important for optimizing liquid crystal response time.Ph.D.
School of Electrical Engineering and Computer Science
Engineering and Computer Science
Electrical Engineering PhD
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Talari, Kiran. "LIQUID CRYSTAL THERMOGRAPHY STUDIES IN WATER POOL BOILING AT SUBATMOSPHERIC PRESSURES." Master's thesis, University of Central Florida, 2007. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/3388.
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A pool boiling experimental facility has been designed and built to investigate nucleate pool boiling in water under sub atmospheric pressure. Liquid crystal thermography, a non intrusive technique, is used for the determination of surface temperature distributions. This technique uses encapsulated liquid crystals that reflect definite colors at specific temperatures and viewing angle. Design of the test section is important in this experimental study. Since a new TLC is required for every new set of test conditions, a permanently sealed test section is not an option. The real challenge is to design a leak proof test section which is flexible so that it can be taken apart easily. A plexiglass test section, including a top chamber with an internal volume of 60.9 x 60.9 x 66.4 mm and a bottom plate of 5.5mm thickness is designed and assembled together using quick grips. In the test section, water is boiled using 85.0mm x 16.0mm and 0.050mm thick Fecralloy® as the heating element. The TLC sheet is attached to the bottom plate and the heating element is placed on top of TLC so that the temperature distribution of the heating element during boiling can be interpreted from TLC. A camera system fast enough to capture the thermal response of the TLC and an arrangement to capture both hue of the TLC and growth of the bubble on the same frame has been designed and successfully used. This system allowed recording of position, size and shape of the bubble with synchronized surface temperature. In order to get hue vs. temperature relation, in-situ calibration of the TLC is performed for each test condition with the present experimental setup and lighting conditions. It is found that the calibration curve of the TLC at atmospheric pressure is different from the calibration curve of the same TLC at subatmospheric pressures. The maximum temperature difference between the two curves for the same hue is found to be only 0.6°C. The experiment is run at four different test conditions of subatmospheric pressure and low heat flux. It is run at system pressures of 6.2kPa (0.89Psi) and 8.0kPa (1.16Psi) with a constant heat flux of 1.88kW/m2 and 2.70kW/m2, and a constant heat flux of 2.70kW/m2, 3.662kW/m2 and 4.50 kW/m2 respectively. Analysis of nucleating surface temperatures using thermochromic liquid crystal technique is performed for these test conditions and the bubble dynamics is studied. The temperature distribution is quite varied in each case and the temperature is at its maximum value at the center of the bubble and it decreases radially from the center. The dry spot observed during the experiments indicates that the process of evaporation of the microlayer is dominant at subatmospheric pressures. It is observed that at very low pressure and heat flux the bubble growth is accompanied by the neck formation. Boiling parameters such as bubble frequency, bubble size and contact are also analyzed and a summary of these results for four different test conditions is presented and the relevant differences between the cases are discussed and the effect of increase in pressure and heat flux is noted.M.S.
Department of Mechanical, Materials and Aerospace Engineering;
Engineering and Computer Science
Mechanical Engineering
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kumar, Amit. "TEMPERATURE INSIDE THE LANDFILL: EFFECTS OF LIQUID INJECTION AND AMBIENT TEMPERATURE." Master's thesis, University of Central Florida, 2007. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/2231.
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This study represents an analysis of comprehensive temperature and moisture content data collected from the anaerobic portion of a bioreactor landfill at the New River Regional Landfill, Florida, USA. The main focus of the study was the analysis of effects of the liquid injection on the temperature inside the landfill. When the leachate or groundwater at lower temperature than the landfilled waste is injected into the landfill, it has an initial cooling effect on the waste until the biological activity, enhanced by the additional moisture, releases heat. This cooling effect was tested in the study to determine whether it could be used to track moisture arrival as an alternative to moisture sensors. First of all, this hypothesis of cooling effect was tested at the injection wells by correlating temperature drops at the injection wells with known injection events. Then the temperature drop events were identified at monitoring locations where temperature and moisture sensors were co-located. The identification step at the monitoring wells was more difficult than in the case of the injection wells because the cooling effect at the injection well is more pronounced than at the monitoring sites, located 7.62 m away from the point of injection. From the analysis it was found out that, overall, the temperature drop at monitoring locations brought about by the injected liquid is a good criterion for tracking the moisture arrival, however only at the first arrival of moisture. Of all of the cases studied, temperature was able to indicate the moisture arrival for 85% of the times at the first injection as opposed to 36% overall. The difference was attributed to the stimulation of biological activity and subsequent heating of the injected liquid as it moves through the waste. Another focus of the research was the estimation of the waste quantity (volume) wetted from the injection. It was assumed that complete mixing takes places between injected liquid and the moisture already present in the waste and that the temperature of the injected liquid is the ambient temperature. According to the results, there was a significant gap between the expected and the actual wetted volume. The waste volume actually wetted was < 1% to 9% of the total waste volume expected to be wetted. Also studied was the effect of ambient temperature on the waste temperature. It was observed that the ambient temperature has no effect on the global temperature inside a bioreactor landfill even at a shallow depth of 4.6 m. While analyzing the trend of waste temperature inside the landfill, liquid injection was found to lead to an increase in temperature.M.S.Env.E.
Department of Civil and Environmental Engineering
Engineering and Computer Science
Environmental Engr MSEnvE
43
Tamhane, Karan. "Formation of Lyotropic Liquid Crystals Through the Self-Assembly of Bile Acid Building Blocks." Master's thesis, University of Central Florida, 2009. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/2169.
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Liquid crystalline materials (LCMs) have gained much popularity over the past century. The thermotropic forms of these materials have been extensively studied and employed in a range of innovative applications. The lyotropic liquid crystal systems that have been studied in the past have often been formed by the organization of natural and synthetic small molecules in solutions. In this study, we use self-assembled supramolecular structures as building blocks to fabricate lyotropic liquid crystals. We investigate the self-assembly of a naturally occurring bile acid called lithocholic acid (LCA), to form supramolecular fibrous and tubular structures in basic aqueous solutions. We control the morphology of the self-assembled structures by manipulating experimental parameters in order to gain comprehensive knowledge regarding the self-assembly process. We characterize these structures with respect to their morphology i.e. their length, diameter, flexibility and shape using atomic force microscopy, optical microscopy and infrared spectroscopy. We produce lyotropic liquid crystal phases using self-assembled LCA structures through modification of physical parameters such as concentration, temperature, shear and pH. The nature of the lyotropic liquid crystal phases depends upon the morphology of the fibers and tubes. We observe that the short, rigid fibers and tubes form nematic phases while long, flexible fibers and tubes form cholesteric phases. We also study the phase transitions of the liquid crystal (LC) phases by observing their patterns using a polarizing microscope. Observations show that LC phases form in samples with LCA concentration above 0.75%w/w. Since the process of self-assembly is time-dependent, so is the formation of liquid crystal phases. We note that the optimum LCA concentration for LC phase formation is 2%-4%w/w and that the liquid crystal transition temperature is about 70[degrees]C.M.S.
Department of Mechanical, Materials and Aerospace Engineering
Engineering and Computer Science
Materials Science & Engr MSMSE
44
Tsai, Chang-Ching. "Propagation Effect in Inhomogeneous Media, Including Media with Light-Induced and Fixed Gratings." Doctoral diss., University of Central Florida, 2006. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/4255.
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Optical waves propagation in various types of volume gratings, materials with constant impendence and optical fibers are studied. Instability of cross–phase modulation and of Energy transfer via GRON-type (Grating-type Orientational Nonlinearity in Liquid Crystal) Stimulated Scattering is numerically observed. Two diffractive optical elements made of volume gratings are suggested and analyzed. A transmission hologram based on the analogy with Stimulated Raman Adiabatic Passage (STIRAP) in nonlinear optics is proposed. This transmission hologram demonstrates high diffraction efficiency and low sensitivity to polarization and hologram strength. The other is a reflection hologram with two crossed-gratings. It features good angular selectivity in comparison with the poor angular selectivity of conventional Bragg grating mirror. This defense also contains the approximation of Maxwell equations for the description of depolarized light sources and polarization-insensitive detectors. A scalar wave equation, Z-Helmholtz equation, is proposed and discussed in the approximation of constant impedance media. As examples, this equation successfully describes a) Fresnel transmission coefficient, and b) Goose-Hanschen shift in total internal reflection, for depolarized incident light and, at the same time, polarization-insensitive detectors. Evolution of polarization during light propagation in an inhomogeneous locally isotropic medium, and also in a single-mode fiber is described by Rytov's non-rotation equation. With arbitrary chosen real unit vector, the complete description of polarization change can be described in a single rotation angle obtained from the integral of rotation rate. Based on introduction of this reference frame, a device is suggested as rigid body's rotation sensor due to polarization change in a twisted fiber.Ph.D.
Other
Optics and Photonics
Optics
45
Cheng, Hui-Chuan. "Vertical Field Switching Blue Phase Liquid Crystals for Field Sequential Color Displays." Doctoral diss., University of Central Florida, 2012. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/5161.
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Low power consumption is a critical requirement for all liquid crystal display (LCD) devices. A field sequential color (FSC) LCD was proposed by using red (R), green (G) and blue (B) LEDs and removing the lossy component of color filters which only transmits ~30% of the incoming white light. Without color filters, FSC LCDs exhibit a ~3X higher optical efficiency and 3X higher resolution density as compared to the conventional color filters-based LCDs. However, color breakup (CBU) is a most disturbing defect that degrades the image quality in FSC displays. CBU can be observed in stationary or moving images. It manifests in FSC LCDs when there is a relative speed between the images and observers* eyes, and the observer will see the color splitting patterns or rainbow effect at the boundary between two different colors. In Chapter 2, we introduce a five-primary display by adding additional yellow(Y) and cyan(C) colors. From the analysis and simulations, five primaries can provide wide color gamut and meanwhile the white brightness is increased, as compared to the three-primary. Based on the five-primary theorem, we propose a method to reduce CBU of FSC LCDs by using RGBYC LEDs instead of RGB LEDs in the second section. Without increasing the sub-frame rate as three-primary LCDs, we can reduce the CBU by utilizing proper color sequence and weighting ratios. In addition, the color gamut achieves 140% NTSC and the white brightness increases by more than 13%, as compared to the three-primary FSC LCDs. Another strategy to suppress CBU is using higher field frequency, such as 540 Hz or even up to 1000 Hz. However, this approach needs liquid crystals with a very fast response time (<1 ms). Recently, the polymer-stabilized blue-phase liquid crystal (PS-BPLC) draws great attentions because of improved temperature range which enables the applications for photonic devices and displays. PS-BPLC is a good candidate for FSC LCDs because of its submillisecond gray-to-gray response time, no need for alignment layer, and isotropic dark state. So far, almost all the BPLC devices utilize planar or protruded in-plane switching (IPS) electrode configuration. The structure of planar IPS is relatively simple, but the operating voltage is too high for thin-film transistor (TFT) addressing. Moreover, high voltage causes deformation of polymer network and induces a noticeable hysteresis. Protruded IPS is helpful for lowering the operating voltage, but the manufacturing process becomes more sophisticated. In Chapter 3, we propose a vertical field switching (VFS) mode for blue phase LCDs. The simple structure of VFS cell generates uniform vertical fields on the BPLC materials. From our experimental results, the operation voltage can be reduced to ~10Vrms while eliminating the hysteresis. We also defined a critical field below which hysteresis does not occur. Above critical field, lattice distortion and other irreversible phase transition processes would occur. As a result, the associated response time would be slower. Therefore, VFS mode also shows faster response time than IPS mode. The operating voltage can be further reduced by choosing an optimized cell gap and a larger oblique incident angle in VFS blue phase LCDs. In Chapter 4, we propose several compensation mechanisms to improve the viewing angle of VFS blue-phase LCDs. The compensation principles are analyzed and simulation results evaluated. Because VFS blue-phase LCD processes several advantages over IPS blue-phase LCD and conventional LCDs, it could become a strong contender for next-generation display technology.Ph.D.
Doctorate
Optics and Photonics
Optics and Photonics
Optics
46
Li, Jun. "REFRACTIVE INDICES OF LIQUID CRYSTALS AND THEIR APPLICATIONS IN DISPLAY AND PHOTONIC DEVICES." Doctoral diss., University of Central Florida, 2005. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/2200.
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Liquid crystals (LCs) are important materials for flat panel display and photonic devices. Most LC devices use electrical field-, magnetic field-, or temperature-induced refractive index change to modulate the incident light. Molecular constituents, wavelength, and temperature are the three primary factors determining the liquid crystal refractive indices: ne and no for the extraordinary and ordinary rays, respectively. In this dissertation, we derive several physical models for describing the wavelength and temperature effects on liquid crystal refractive indices, average refractive index, and birefringence. Based on these models, we develop some high temperature gradient refractive index LC mixtures for photonic applications, such as thermal tunable liquid crystal photonic crystal fibers and thermal solitons. Liquid crystal refractive indices decrease as the wavelength increase. Both ne and no saturate in the infrared region. Wavelength effect on LC refractive indices is important for the design of direct-view displays. In Chapter 2, we derive the extended Cauchy models for describing the wavelength effect on liquid crystal refractive indices in the visible and infrared spectral regions based on the three-band model. The three-coefficient Cauchy model could be used for describing the refractive indices of liquid crystals with low, medium, and high birefringence, whereas the two-coefficient Cauchy model is more suitable for low birefringence liquid crystals. The critical value of the birefringence is deltan~0.12. Temperature is another important factor affecting the LC refractive indices. The thermal effect originated from the lamp of projection display would affect the performance of the employed liquid crystal. In Chapter 3, we derive the four-parameter and three-parameter parabolic models for describing the temperature effect on the LC refractive indices based on Vuks model and Haller equation. We validate the empirical Haller equation quantitatively. We also validate that the average refractive index of liquid crystal decreases linearly as the temperature increases. Liquid crystals exhibit a large thermal nonlinearity which is attractive for new photonic applications using photonic crystal fibers. We derive the physical models for describing the temperature gradient of the LC refractive indices, ne and no, based on the four-parameter model. We find that LC exhibits a crossover temperature To at which dno/dT is equal to zero. The physical models of the temperature gradient indicate that ne, the extraordinary refractive index, always decreases as the temperature increases since dne/dT is always negative, whereas no, the ordinary refractive index, decreases as the temperature increases when the temperature is lower than the crossover temperature (dno/dT<0 when the temperature is lower than To) and increases as the temperature increases when the temperature is higher than the crossover temperature (dno/dT>0 when the temperature is higher than To ). Measurements of LC refractive indices play an important role for validating the physical models and the device design. Liquid crystal is anisotropic and the incident linearly polarized light encounters two different refractive indices when the polarization is parallel or perpendicular to the optic axis. The measurement is more complicated than that for an isotropic medium. In Chapter 4, we use a multi-wavelength Abbe refractometer to measure the LC refractive indices in the visible light region. We measured the LC refractive indices at six wavelengths, lamda=450, 486, 546, 589, 633 and 656 nm by changing the filters. We use a circulating constant temperature bath to control the temperature of the sample. The temperature range is from 10 to 55 oC. The refractive index data measured include five low-birefringence liquid crystals, MLC-9200-000, MLC-9200-100, MLC-6608 (delta_epsilon=-4.2), MLC-6241-000, and UCF-280 (delta_epsilon=-4); four middle-birefringence liquid crystals, 5CB, 5PCH, E7, E48 and BL003; four high-birefringence liquid crystals, BL006, BL038, E44 and UCF-35, and two liquid crystals with high dno/dT at room temperature, UCF-1 and UCF-2. The refractive indices of E7 at two infrared wavelengths lamda=1.55 and 10.6 um are measured by the wedged-cell refractometer method. The UV absorption spectra of several liquid crystals, MLC-9200-000, MLC-9200-100, MLC-6608 and TL-216 are measured, too. In section 6.5, we also measure the refractive index of cured optical films of NOA65 and NOA81 using the multi-wavelength Abbe refractometer. In Chapter 5, we use the experimental data measured in Chapter 4 to validate the physical models we derived, the extended three-coefficient and two-coefficient Cauchy models, the four-parameter and three-parameter parabolic models. For the first time, we validate the Vuks model using the experimental data of liquid crystals directly. We also validate the empirical Haller equation for the LC birefringence delta_n and the linear equation for the LC average refractive index Ph.D.
Optics and Photonics
Optics
47
Arlt, Jean M. "An Examination of Timing Variables in Liquid Taste Administration fMRI Paradigms." Diss., Temple University Libraries, 2019. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/595305.
Full textAbstract:
Psychology;Ph.D.;
Use of liquid administration paradigms in functional magnetic resonance imaging (fMRI) research has rapidly increased and expanded. Despite rapid expansion, there are no studies examining the methods setup of this paradigm. The present study aims to address basic questions about the methodology of liquid administration paradigms using a series of three experiments. These questions include whether using timing files generated by the study computer accurately represent the time of taste receipt, whether variation in methods setup meaningfully impacts time of taste receipt, and whether inaccurate receipt time impacts first-level analysis of fMRI data. Experiment 1 used an equipment setup simulating the running of an fMRI study with three taste stimuli; tasteless solution, chocolate milkshake, and chocolate milk. For each taste stimulus, we captured and compared the times of administration recorded by the study computer and the time of receipt captured using two measurement systems. Experiment 2 used a similar setup with only one taste stimulus: chocolate milkshake. Using high-definition video, we captured the time elapsed as the taste stimulus passed through the tubing at three infusion speeds and varying temperatures. In Experiment 3, we used the fMRI data from a previous study, in which five participants were administered chocolate milkshake to demonstrate how the lag times captured in Experiment 1 affect first-level fMRI data analyses. There were significant differences in time of administration recorded by the computer and time of receipt, demonstrating the existence of a lag time. This lag time was greatest for chocolate milkshake. Semiautomatic pump speed also was significantly associated with lag time. Temperature and length of tubing were not significantly related to lag time. Additionally, our fMRI analyses show that the variation in the methods setup have a meaningful impact on first-level fMRI analyses. When using the computer-generated time that was not corrected for lag time, increased neural activity in response to the chocolate milkshake taste was shown in three out of the five participants. When correcting using the lag time, increased neural activity in response to chocolate milkshake taste was found in all five participants. Overall, this study demonstrates a “proof of concept” that the practice of estimating liquid administration times from computer-generated files may not be accurate, that variation in methods setup may affect the timing in this paradigm, and that these differences in timing introduce variation in the fMRI data of individual participants.
Temple University--Theses
48
Wehking, Jonathan. "PRESSURE LOSSES EXPERIENCED BY LIQUID FLOW THROUGH PDMS MICROCHANNELS WITH ABRUPT AREA CHANGES." Master's thesis, University of Central Florida, 2008. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/4231.
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Given the surmounting disagreement amongst researchers in the area of liquid flow behavior at the microscale for the past thirty years, this work presents a fundamental approach to analyzing the pressure losses experienced by the laminar flow of water (Re = 7 to Re = 130) through both rectangular straight duct microchannels (of widths ranging from 50 to 130 micrometers), and microchannels with sudden expansions and contractions (with area ratios ranging from 0.4 to 1.0) all with a constant depth of 104 micrometers. The simplified Bernoulli equations for uniform, steady, incompressible, internal duct flow were used to compare flow through these microchannels to macroscale theory predictions for pressure drop. One major advantage of the channel design (and subsequent experimental set-up) was that pressure measurements could be taken locally, directly before and after the test section of interest, instead of globally which requires extensive corrections to the pressure measurements before an accurate result can be obtained. Bernoulli's equation adjusted for major head loses (using Darcy friction factors) and minor head losses (using appropriate K values) was found to predict the flow behavior within the calculated theoretical uncertainty (~12%) for all 150+ microchannels tested, except for sizes that pushed the aspect ratio limits of the manufacturing process capabilities (microchannels fabricated via soft lithography using PDMS). The analysis produced conclusive evidence that liquid flow through microchannels at these relative channel sizes and Reynolds numbers follow macroscale predictions without experiencing any of the reported anomalies expressed in other microfluidics research. This work also perfected the delicate technique required to pierce through the PDMS material and into the microchannel inlets, exit and pressure ports without damaging the microchannel. Finally, two verified explanations for why prior researchers have obtained poor agreement between macroscale theory predictions and tests at the microscale were due to the presence of bubbles in the microchannel test section (producing higher than expected pressure drops), and the occurrence of localized separation between the PDMS slabs and thus, the microchannel itself (producing lower than expected pressure drops).M.S.M.E.
Department of Mechanical, Materials and Aerospace Engineering;
Engineering and Computer Science
Mechanical Engineering MSME
49
Wright, Darrel W. "Pressure losses experienced by liquid flow through straight PDMS microchannels of varying diameters." Honors in the Major Thesis, University of Central Florida, 2010. http://digital.library.ucf.edu/cdm/ref/collection/ETH/id/1527.
Full textAbstract:
This item is only available in print in the UCF Libraries. If this is your Honors Thesis, you can help us make it available online for use by researchers around the world by following the instructions on the distribution consent form at http://library.ucf.edu/Systems/DigitalInitiatives/DigitalCollections/InternetDistributionConsentAgreementForm.pdf You may also contact the project coordinator, Kerri Bottorff, at kerri.bottorff@ucf.edu for more information.Bachelors
Engineering and Computer Science
Mechanical Engineering
50
Liu, Yifan. "High Performance Three-Dimensional Display Based on Polymer-Stabilized Blue Phase Liquid Crystal." Doctoral diss., University of Central Florida, 2014. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/6309.
Full textAbstract:
Autostereoscopic 2D/3D (two-dimension/three-dimension) switchable display has been attracting great interest in research and practical applications for several years. Among different autostereoscopic solutions, direction-multiplexed 3D displays based on microlens array or parallax barrier are viewed as the most promising candidates, due to their compatibility with conventional 2D display technologies. These 2D/3D switchable display system designs rely on fast switching display panels and photonics devices, including adaptive focus microlens array and switchable slit array. Polymer-stabilized blue phase liquid crystal (PS-BPLC) material provides a possible solution to meet the aforementioned fast response time requirement. However, present display and photonic devices based on blue phase liquid crystals suffer from several drawbacks, such as low contrast ratio, relatively large hysteresis and short lifetime.
In this dissertation, we investigate the material properties of PS-BPLC so as to improve the performance of PS-BPLC devices. Then we propose several PS-BPLC devices for the autostereoscopic 2D/3D switchable display system designs.
In the first part we evaluate the optical rotatory power (ORP) of blue phase liquid crystal, which is proven to be the primary reason for causing the low contrast ratio of PS-BPLC display systems. Those material parameters affecting the ORP of PS-BPLC are investigated and an empirical equation is proposed to calculate the polarization rotation angle in a PS-BPLC cell. Then several optical compensation methods are proposed to compensate the impact of ORP and to improve the contrast ratio of a display system. The pros and cons of each solution are discussed accordingly.
In the second part, we propose two adaptive focus microlens array structures and a high efficiency switchable slit array based on the PS-BPLC materials. By optimizing the design parameters, these devices can be applied to the 2D/3D switchable display systems.
In the last section, we focus on another factor that affects the performance and lifetime of PS-BPLC devices and systems: the UV exposure condition. The impact of UV exposure wavelength, dosage, uniformity, and photo-initiator are investigated. We demonstrate that by optimizing the UV exposure condition, we can reduce the hysteresis of PS-BPLC and improve its long term stability.Ph.D.
Doctorate
Optics and Photonics
Optics and Photonics
Optics and Photonics