Relevant bibliographies by topics / Redlich-Kister expression

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Academic literature on the topic 'Redlich-Kister expression'

Author: Grafiati
Published: 4 June 2021
Last updated: 6 February 2022

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Journal articles on the topic "Redlich-Kister expression"

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Ohshima, H., A. Tanaka, and T. Sukegawa. "Calculation of the GaAlSb phase diagram using the Redlich-Kister expression." physica status solidi (a) 87, no. 2 (February 16, 1985): K131—K134. http://dx.doi.org/10.1002/pssa.2210870245.

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Ahluwalia, R., Ritu Gupta, J. L. Vashisht, and R. K. Wanchoo. "Thermophysical Properties of Binary Liquid Systems of Ethanoic Acid, Propanoic Acid, and Butanoic Acid with Benzene or Acetophenone." ISRN Physical Chemistry 2013 (August 27, 2013): 1–13. http://dx.doi.org/10.1155/2013/612837.

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The density (), viscosity (), and surface tension () of binary mixtures of carboxylic acids (CAs) (ethanoic acid (EA), propanoic acid (PA), butanoic acid (BA)) + benzene (BEN) or acetophenone (ACT) have been measured at 298.15, 308.15, and 318.15 K. From the experimental results, excess values of molar volume (), viscosity (), Gibb's free energy for the activation of low (), and surface tension () were evaluated and fitted to a Redlich-Kister type of equation. The parameter “” of Grunberg and Nissan expression has also been calculated. From the sign and magnitude of , , , , and “” values, it is concluded that specific interactions are present in CA+ACT system and these interactions are absent in CA + BEN mixtures. Various viscosity and surface tension models have been used to test the consistency of the data.
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Li, Yandong, Tongsheng Zhang, Yefeng Feng, Chengjun Liu, and Maofa Jiang. "Liquid Regions of Lanthanum-Bearing Aluminosilicates." Materials 13, no. 2 (January 17, 2020): 450. http://dx.doi.org/10.3390/ma13020450.

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The Al2O3-SiO2, La2O3-Al2O3, and La2O3-SiO2 binary phase diagrams were estimated by Redlich–Kister expression. La4.67Si3O13 (=La4.67(SiO4)3O) was introduced to improve the existing phase diagrams. The Al2O3-SiO2-La2O3 ternary phase diagram extrapolated by Kohler method was optimized. Then, the liquidus of Al2O3-SiO2-La2O3 system at 1600 °C was compared with Al2O3-SiO2-RE2O3 (RE = Rare Earth Elements) systems and experimental results in other literature. The high temperature experiments were conducted in the tube furnace at 1500 °C. Then the field emission scanning electron microscope (FE-SEM), energy dispersive spectrometer (EDS), and X-ray diffraction (XRD) were employed to verify the calculated liquid region and precipitates phase at 1500 °C. Moreover, the liquidus of binary systems were compared with FactSage results and experiments. The optimized ternary phase diagram shows the relatively reliable region of liquid phase, and it is significant to the seal glass of solid oxide fuel cells and other fields being related to RE containing silicates.
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Cao, Zhan Min, Kun Peng Wang, Guang Wei Du, and Zhi Yu Qiao. "Thermodynamic Evaluation and Assessment of the Ti-U Binary System." Applied Mechanics and Materials 187 (June 2012): 272–77. http://dx.doi.org/10.4028/www.scientific.net/amm.187.272.

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The thermodynamic description of the Ti-U binary system is obtained by the CALPHAD method using Thermo-Calc software and based on the estimated thermodynamic properties using ion-bonding model and Miedema model as well as the experimental phase diagram information. The liquid, αU, βU, δTi, and γ phases are assumed to be substitutional solutions with Redlich-Kister formula for the expressions of their excess Gibbs energy. The intermetallic compound TiU2 is treated as a stoichiometric compound. The calculated phase equlibria are in good agreement with the estimated and available experimental phase diagram data.
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5

Hossain, Md Kamrul, M. Abdur Rahaman, and Shamim Akhtar. "Molar Interactions of Some Aromatic Hydrocarbons in n-Heptane by Viscometric Measurements at 298.15K." Chittagong University Journal of Science 40, no. 1 (June 28, 2018): 97–110. http://dx.doi.org/10.3329/cujs.v40i1.47918.

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The viscosities, η , of pure n-heptane, toluene, o-xylene, mesitylene, and some of their binary mixtures covering the whole composition range have been measured at 298.15K. Deviations in viscosity, ∆η , was calculated using experimental results. The concentration dependencies of η were correlated to polynomial expressions, whereas, ∆η were fitted to the Redlich–Kister equation. Moreover, the values of the excess Gibbs free energy of activation, ∆G#E, of these mixtures were determined. Viscosity measurements of the binary systems were correlated with Grunberg and Nissan the three-body and four-body McAllister expressions. In all systems, ∆η were found to be negative in the whole range of composition with a single lobe having minimum at 0.6 mple fraction of aromatic hydrocarbon. While dispersive forces are suggested to dominate in n-heptane + toluene, for the other two systems ‘favourable geometric fitting’ overpowers them due to the increasing number of – CH3 groups in the relevant aromatic hydrocarbons. The Chittagong Univ. J. Sci. 40 : 97-110, 2018
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Dissertations / Theses on the topic "Redlich-Kister expression"

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Teng, I.-Lih. "Thermochemical Investigation of Ternary Nonelectrolyte Mixtures." Thesis, University of North Texas, 1992. https://digital.library.unt.edu/ark:/67531/metadc500889/.

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Excess molar volumes have been determined for four ternary chlorobenzene + dibutyl ether + alkane mixtures at 25°C. Results of these measurements are used to test the applications and limitations of BAB, Redlich-Kister, Kohler and Hwang et al. cubic models. For the systems studied, Redlich- Kister, Kohler and Cubic models were found to provide reasonable predictions. Differences between experimental and predicted ΔV^ex_123 values were about ±0.020 cm^3mol^-1 or less at most ternary compositions. Solubilities are reported for anthracene in binary mixtures containing propanol and butanol with alkanes at 25°C. Results of these measurements are used to test the NIBS/Redlich-Kister expression. The three-parameter form of this expression is found to provide reasonable mathematical representation with deviations between experimental and back-calculated values being less than ±1%.
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