Relevant bibliographies by topics / Redox non-innocent ligand

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  2. Dissertations / Theses
  3. Book chapters

Academic literature on the topic 'Redox non-innocent ligand'

Author: Grafiati
Published: 4 June 2025
Last updated: 1 August 2025

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Journal articles on the topic "Redox non-innocent ligand"

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Braun, Jason D., Paul A. Gray, Baldeep K. Sidhu, Dion B. Nemez, and David E. Herbert. "Zn-Templated synthesis of substituted (2,6-diimine)pyridine proligands and evaluation of their iron complexes as anolytes for flow battery applications." Dalton Transactions 49, no. 45 (2020): 16175–83. http://dx.doi.org/10.1039/d0dt00543f.

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Zn<sup>2+</sup> templating enables synthesis of redox ‘non-innocent’ diimine pyridine ligands with strong electron-withdrawing groups, allowing construction of iron complexes with multiple ligand-based reductions for application in redox flow batteries.
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Lehtonen, Ari. "Metal Complexes of Redox Non-Innocent Ligand N,N′-Bis(3,5-di-tertbutyl-2-hydroxy-phenyl)-1,2-phenylenediamine." Molecules 29, no. 5 (2024): 1088. http://dx.doi.org/10.3390/molecules29051088.

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Redox non-innocent ligands react with metal precursors to form complexes where the oxidation states of the ligand and thus the metal atom cannot be easily defined. A well-known example of such ligands is bis(o-aminophenol) N,N′-bis(3,5-di-tertbutyl-2-hydroxy-phenyl)-1,2-phenylenediamine, previously developed by the Wieghardt group, which has a potentially tetradentate coordination mode and four distinct protonation states, whereas its electrochemical behavior allows for five distinct oxidation states. This rich redox chemistry, as well as the ability to coordinate to various transition metals,
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Simler, Thomas, Andreas A. Danopoulos, and Pierre Braunstein. "Non-symmetrical, potentially redox non-innocent imino NHC pyridine ‘pincers’ via a zinc ion template-assisted synthesis." Dalton Transactions 46, no. 18 (2017): 5955–64. http://dx.doi.org/10.1039/c7dt01014a.

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A Zn<sup>II</sup>-promoted modular synthesis allows access to new non-symmetrical, redox-active imino NHC pyridine pincer ligands. Radical anionic and dianionic redox states of the ligand are involved in its Fe<sup>II</sup> complexes obtained from FeBr<sub>2</sub>/KC<sub>8</sub>.
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Dutta, Debarpan, Suvendu Maity, Suman Kundu, and Prasanta Ghosh. "Mixed-valence di-ruthenium(ii,iii) complexes of redox non-innocent N-aryl-o-phenylenediamine derivatives." Dalton Transactions 50, no. 22 (2021): 7791–803. http://dx.doi.org/10.1039/d1dt00779c.

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Hazari, Arijit Singha, Alexa Paretzki, Jan Fiedler, Stanislav Zalis, Wolfgang Kaim та Goutam Kumar Lahiri. "Different manifestations of enhanced π-acceptor ligation at every redox level of [Os(9-OP)L2]n, n = 2+, +, 0, − (9-OP− = 9-oxidophenalenone and L = bpy or pap)". Dalton Transactions 45, № 45 (2016): 18241–51. http://dx.doi.org/10.1039/c6dt03764j.

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Wang, Yichen, Jing Li, Li Zhang, et al. "Magnetic on–off switching in redox non-innocent ligand bridged binuclear cobalt complexes." Dalton Transactions 47, no. 48 (2018): 17211–15. http://dx.doi.org/10.1039/c8dt04157a.

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Vijaykumar, Gonela, Anand Pariyar, Jasimuddin Ahmed, Bikash Kumar Shaw, Debashis Adhikari, and Swadhin K. Mandal. "Tuning the redox non-innocence of a phenalenyl ligand toward efficient nickel-assisted catalytic hydrosilylation." Chemical Science 9, no. 10 (2018): 2817–25. http://dx.doi.org/10.1039/c7sc04687a.

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Chakraborty, Soumi, Arpan Das, Jasimuddin Ahmed, Sayani Barman, and Swadhin K. Mandal. "Designing a Cr-catalyst bearing redox non-innocent phenalenyl-based ligand towards hydrosilylative CO2 functionalization." Chemical Communications 56, no. 89 (2020): 13788–91. http://dx.doi.org/10.1039/d0cc05348a.

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Benson, Christopher R., Alice K. Hui, Kumar Parimal, et al. "Multiplying the electron storage capacity of a bis-tetrazine pincer ligand." Dalton Trans. 43, no. 17 (2014): 6513–24. http://dx.doi.org/10.1039/c4dt00341a.

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Kim, Jee Eon, Patrick J. Carroll, and Eric J. Schelter. "Bidentate nitroxide ligands stable toward oxidative redox cycling and their complexes with cerium and lanthanum." Chemical Communications 51, no. 81 (2015): 15047–50. http://dx.doi.org/10.1039/c5cc06052d.

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Dissertations / Theses on the topic "Redox non-innocent ligand"

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Colin, Aristide. "Design and magnetic behavior of redox-switchable polynuclear complexes." Electronic Thesis or Diss., université Paris-Saclay, 2024. http://www.theses.fr/2024UPASF093.

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Parmi la vaste classe des complexes de coordination moléculaire, certains composés présentent des propriétés magnétiques, pour un environnement de coordination approprié. Par exemple, ces propriétés incluent le comportement de molécule aimant, lorsque qu'il y a une barrière d'énergie à l'inversion de l'aimantation, ou des propriétés de bit quantique lorsque la dégénérescence de l'état fondamental est complètement levée. Combiner ces propriétés magnétiques avec d'autres, comme la luminescence ou la commutabilité magnétique dans des matériaux multifonctionnels est particulièrement intéressant. E
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MUSTIELES, MARÍN Irene. "Oxidation of phosphasalen complexes." Thesis, Université Paris-Saclay (ComUE), 2017. http://www.theses.fr/2017SACLX078/document.

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Les ligands phosphasalen développés au sein du laboratoire peuvent être considérés comme les analogues phosphorés des ligands salen dont ils diffèrent par la présence de groupements iminophosphorane à la place des imines. L’introduction de ces fonctions a d’importantes conséquences sur les propriétés de ces ligands, qui sont plus électrodonneurs et plus flexibles que les dérivés salen correspondants, capables de stabiliser des métaux à haut degré d’oxydation. Ces ligands ont également un caractère redox non-innocent, une propriété très étudiée de nos jours tant en chimie de coordination qu’en
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Salanouve, Elise. "Complexes de métaux non-nobles de fer et de nickel portant des ligands redox non-innocents et leurs applications en catalyse : de l'activation C-H aux réactions de couplages croisés." Thesis, Paris 6, 2014. http://www.theses.fr/2014PA066620/document.

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Ce travail de thèse s’est intéressé au développement de complexes de métaux non-nobles portant des ligands non-innocents et leurs applications en catalyse comme alternatives efficaces aux complexes de métaux nobles dans un contexte de fortes préoccupations économiques et environnementales. Ainsi, nous avons synthétisé et caractérisé des complexes de fer et de nickel portant des ligands non-innocents, à l’aide de différentes techniques spectroscopiques. Ces ligands pourraient moduler la réactivité du métal et étendre ainsi le champ d’applications de ces métaux de transition. Dans le but de déve
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Mele, Andrea. "Preparation and study of diiron complexes, featuring redox ligands, inspired by the active site of [FeFe]-Hydrogenases." Thesis, Brest, 2019. http://www.theses.fr/2019BRES0100.

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L’hydrogénase [FeFe] est une enzyme capable de catalyser efficacement la réduction des protons en hydrogène moléculaire. La structure du site actif, appelé le cluster-H a été élucidée à la fin des années 90. Depuis, plusieurs systèmes modèles ont été synthétisés en essayant de reproduire ses caractéristiques uniques. Le cluster {4Fe4S}, présent dans le site actif joue un rôle crucial en tant que cofacteur redox, lié de manière covalente à un système difer qui est le site de la conversion H+/H2. Il se comporte comme un réservoir d'électrons capable d'accepter et de partager des électrons avec l
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Das, Hari Sankar [Verfasser], and Biprajit [Akademischer Betreuer] Sarkar. "Ruthenium complexes with non-innocent quinonoid, quinoline-5,8-dione and iminoquinone ligands : synthesis, structure, redox properties and electron distribution / Hari Sankar Das. Betreuer: Biprajit Sarkar." Stuttgart : Universitätsbibliothek der Universität Stuttgart, 2012. http://d-nb.info/102604331X/34.

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"Synthesis and Reactivity of Group 9 Complexes Featuring Redox Non-Innocent Ligands." Master's thesis, 2016. http://hdl.handle.net/2286/R.I.38406.

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abstract: The addition of aminoalkyl-substituted 2,6-bis(imino)pyridine (or pyridine diimine, PDI) ligands to [(COD)RhCl]2 (COD = 1,5-cyclooctadiene) resulted in the formation of rhodium monochloride complexes with the general formula (NPDI)RhCl (NPDI = iPr2NEtPDI or Me2NPrPDI). The investigation of (iPr2NEtPDI)RhCl and (Me2NPrPDI)RhCl by single crystal X-ray diffraction verified the absence of amine arm coordination and a pseudo square planar geometry about rhodium. Replacement of the chloride ligand with an outer-sphere anion was achieved by adding AgBF4 directly to (iPr2NEtPDI)RhCl to form
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"Biomimetic Models of [FeFe]-hydrogenase: Utilization of peptides and redox non-innocent ligands in synthetic catalysts." Doctoral diss., 2013. http://hdl.handle.net/2286/R.I.18826.

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abstract: [FeFe]-hydrogenases are enzymes for the reduction of protons to hydrogen. They rely on only the earth abundant first-row transition metal iron at their active site (H cluster). In recent years, a multitude of diiron mimics of hydrogenases have been synthesized, but none of them catalyzes hydrogen production with the same exquisite combination of high turnover frequency and low activation energy as the enzymes. Generally, model complexes fail to include one or both of two features essential to the natural enzyme: an intricate array of outer coordination sphere contacts that constrain
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"Development of Homogeneous Manganese and Iron Catalysts for Organic Transformations and Renewable Fuel Production." Doctoral diss., 2016. http://hdl.handle.net/2286/R.I.39403.

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abstract: The late first row transition metals, being inexpensive and environmentally benign, have become very attractive for sustainable catalyst development. However, to overcome the detrimental one electron redox processes exhibited by these metals, the employment of redox non-innocent chelates turned out to be very useful. The Trovitch group has designed a series of pentadentate bis(imino)pyridine ligands (pyridine diimine, PDI) that are capable of binding the metal center beyond their 3-N,N,N core and also possess coordination flexibility. My research is focused on developing PDI-support
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Das, Atanu Kumar [Verfasser]. "Structural, electron transfer and spectroscopic studies of transition metal complexes with redox-active non-innocent ligands / vorgelegt von Atanu Kumar Das." 2009. http://d-nb.info/995067260/34.

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Book chapters on the topic "Redox non-innocent ligand"

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de Bruin, Bas, Pauline Gualco, and Nanda D. Paul. "Redox Non-innocent Ligands." In Ligand Design in Metal Chemistry. John Wiley & Sons, Ltd, 2016. http://dx.doi.org/10.1002/9781118839621.ch7.

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Varela-Alvarez, Adrian, and Djamaladdin G. Musaev. "Fundamental Aspects of the Metal-Catalyzed C-H Bond Functionalization by Diazocarbenes: Guiding Principles for Design of Catalyst with Non-redox-Active Metal (Such as Ca) and Non-Innocent Ligand." In Understanding Organometallic Reaction Mechanisms and Catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527678211.ch2.

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Itoh, Shinobu, та Yuma Morimoto. "β-Diketiminates as Redox Non-innocent Supporting Ligands in Coordination Chemistry". У Chemical Science of π-Electron Systems. Springer Japan, 2015. http://dx.doi.org/10.1007/978-4-431-55357-1_42.

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Heims, Florian, and Kallol Ray. "Multiple Spin Scenarios in Transition-Metal Complexes Involving Redox Non-Innocent Ligands." In Spin States in Biochemistry and Inorganic Chemistry. John Wiley & Sons, Ltd, 2015. http://dx.doi.org/10.1002/9781118898277.ch11.

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Breitwieser, Kevin, and Dominik Munz. "Cyclic (alkyl)(amino)carbene (CAAC) ligands: Electronic structure and application as chemically- and redox-non-innocent ligands and chromophores." In Advances in Organometallic Chemistry. Elsevier, 2022. http://dx.doi.org/10.1016/bs.adomc.2022.03.003.

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You might also be interested in the extended bibliographies on the topic 'Redox non-innocent ligand' for particular source types:
Journal articles
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