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1

Vlcek, Antonin. "Dithiolenes and non-innocent redox-active ligands." Coordination Chemistry Reviews 254, no. 13-14 (2010): 1357. http://dx.doi.org/10.1016/j.ccr.2010.01.015.

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2

Matelková, Kristína, Katrin Ossberger, Juraj Hudák, Jaroslav Vatrál, Roman Boča, and Wolfgang Linert. "Redox activity of some non-innocent amino acids." Monatshefte für Chemie - Chemical Monthly 144, no. 7 (2013): 937–49. http://dx.doi.org/10.1007/s00706-013-0972-0.

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3

Dutta, Debarpan, Suvendu Maity, Suman Kundu, and Prasanta Ghosh. "Mixed-valence di-ruthenium(ii,iii) complexes of redox non-innocent N-aryl-o-phenylenediamine derivatives." Dalton Transactions 50, no. 22 (2021): 7791–803. http://dx.doi.org/10.1039/d1dt00779c.

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4

Singh, Baghendra, and Arindam Indra. "Role of redox active and redox non-innocent ligands in water splitting." Inorganica Chimica Acta 506 (June 2020): 119440. http://dx.doi.org/10.1016/j.ica.2020.119440.

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5

Kaim, Wolfgang. "Chelate rings of different sizes with non-innocent ligands." Dalton Transactions 48, no. 24 (2019): 8521–29. http://dx.doi.org/10.1039/c9dt01411j.

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6

Wang, Yichen, Jing Li, Li Zhang, et al. "Magnetic on–off switching in redox non-innocent ligand bridged binuclear cobalt complexes." Dalton Transactions 47, no. 48 (2018): 17211–15. http://dx.doi.org/10.1039/c8dt04157a.

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7

Chakraborty, Soumi, Arpan Das, Jasimuddin Ahmed, Sayani Barman, and Swadhin K. Mandal. "Designing a Cr-catalyst bearing redox non-innocent phenalenyl-based ligand towards hydrosilylative CO2 functionalization." Chemical Communications 56, no. 89 (2020): 13788–91. http://dx.doi.org/10.1039/d0cc05348a.

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8

Vijaykumar, Gonela, Anand Pariyar, Jasimuddin Ahmed, Bikash Kumar Shaw, Debashis Adhikari, and Swadhin K. Mandal. "Tuning the redox non-innocence of a phenalenyl ligand toward efficient nickel-assisted catalytic hydrosilylation." Chemical Science 9, no. 10 (2018): 2817–25. http://dx.doi.org/10.1039/c7sc04687a.

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9

Braun, Jason D., Paul A. Gray, Baldeep K. Sidhu, Dion B. Nemez, and David E. Herbert. "Zn-Templated synthesis of substituted (2,6-diimine)pyridine proligands and evaluation of their iron complexes as anolytes for flow battery applications." Dalton Transactions 49, no. 45 (2020): 16175–83. http://dx.doi.org/10.1039/d0dt00543f.

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Zn<sup>2+</sup> templating enables synthesis of redox ‘non-innocent’ diimine pyridine ligands with strong electron-withdrawing groups, allowing construction of iron complexes with multiple ligand-based reductions for application in redox flow batteries.
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10

Cappillino, Patrick J., Harry D. Pratt, Nicholas S. Hudak, Neil C. Tomson, Travis M. Anderson, and Mitchell R. Anstey. "Application of Redox Non-Innocent Ligands to Non-Aqueous Flow Battery Electrolytes." Advanced Energy Materials 4, no. 1 (2013): 1300566. http://dx.doi.org/10.1002/aenm.201300566.

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11

Ringenberg, Mark R., Swarna Latha Kokatam, Zachariah M. Heiden, and Thomas B. Rauchfuss. "Redox-Switched Oxidation of Dihydrogen Using a Non-Innocent Ligand." Journal of the American Chemical Society 130, no. 3 (2008): 788–89. http://dx.doi.org/10.1021/ja076801k.

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12

Duarte, Gabriel M., Jason D. Braun, Patrick K. Giesbrecht, and David E. Herbert. "Redox non-innocent bis(2,6-diimine-pyridine) ligand–iron complexes as anolytes for flow battery applications." Dalton Transactions 46, no. 47 (2017): 16439–45. http://dx.doi.org/10.1039/c7dt03915h.

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13

Simler, Thomas, Andreas A. Danopoulos, and Pierre Braunstein. "Non-symmetrical, potentially redox non-innocent imino NHC pyridine ‘pincers’ via a zinc ion template-assisted synthesis." Dalton Transactions 46, no. 18 (2017): 5955–64. http://dx.doi.org/10.1039/c7dt01014a.

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A Zn<sup>II</sup>-promoted modular synthesis allows access to new non-symmetrical, redox-active imino NHC pyridine pincer ligands. Radical anionic and dianionic redox states of the ligand are involved in its Fe<sup>II</sup> complexes obtained from FeBr<sub>2</sub>/KC<sub>8</sub>.
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14

Saini, Anu, Cecilia R. Smith, Francis S. Wekesa, Amanda K. Helms, and Michael Findlater. "Conversion of aldimines to secondary amines using iron-catalysed hydrosilylation." Organic & Biomolecular Chemistry 16, no. 48 (2018): 9368–72. http://dx.doi.org/10.1039/c8ob01262h.

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15

Patra, Sarat Chandra, Amit Saha Roy, Saswati Banerjee, et al. "Palladium(ii) and platinum(ii) complexes of glyoxalbis(N-aryl)osazone: molecular and electronic structures, anti-microbial activities and DNA-binding study." New Journal of Chemistry 43, no. 25 (2019): 9891–901. http://dx.doi.org/10.1039/c9nj00223e.

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16

Nelson, Nicholas C., Zhuoran Wang, Pranjali Naik, J. Sebastián Manzano, Marek Pruski, and Igor I. Slowing. "Phosphate modified ceria as a Brønsted acidic/redox multifunctional catalyst." Journal of Materials Chemistry A 5, no. 9 (2017): 4455–66. http://dx.doi.org/10.1039/c6ta08703e.

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17

Benson, Christopher R., Alice K. Hui, Kumar Parimal, et al. "Multiplying the electron storage capacity of a bis-tetrazine pincer ligand." Dalton Trans. 43, no. 17 (2014): 6513–24. http://dx.doi.org/10.1039/c4dt00341a.

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18

Kim, Jee Eon, Patrick J. Carroll, and Eric J. Schelter. "Bidentate nitroxide ligands stable toward oxidative redox cycling and their complexes with cerium and lanthanum." Chemical Communications 51, no. 81 (2015): 15047–50. http://dx.doi.org/10.1039/c5cc06052d.

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19

Lyaskovskyy, Volodymyr, and Bas de Bruin. "Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions." ACS Catalysis 2, no. 2 (2012): 270–79. http://dx.doi.org/10.1021/cs200660v.

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20

Jones, J. Stuart, and François P. Gabbaï. "Coordination and Redox Non-innocent Behavior of Hybrid Ligands Containing Tellurium." Chemistry Letters 45, no. 4 (2016): 376–84. http://dx.doi.org/10.1246/cl.160103.

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21

Tewary, Subrata, Ian A. Gass, Keith S. Murray, and Gopalan Rajaraman. "Theoretical Perspectives on Redox “Non-Innocent” OxazolidineN-Oxide Iron Nitroxide Complexes." European Journal of Inorganic Chemistry 2013, no. 5-6 (2013): 1024–32. http://dx.doi.org/10.1002/ejic.201201077.

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22

Khairul, Wan M., Mark A. Fox, Phil A. Schauer, et al. "Ligand redox non-innocent behaviour in ruthenium complexes of ethynyl tolans." Inorganica Chimica Acta 374, no. 1 (2011): 461–71. http://dx.doi.org/10.1016/j.ica.2011.02.043.

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23

Boyer, Julie L., Thomas R. Cundari, Nathan J. DeYonker, Thomas B. Rauchfuss, and Scott R. Wilson. "Redox Activation of Alkene Ligands in Platinum Complexes with Non-innocent Ligands." Inorganic Chemistry 48, no. 2 (2009): 638–45. http://dx.doi.org/10.1021/ic8017248.

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24

Ehret, Fabian, Martina Bubrin, Stanislav Záliš, and Wolfgang Kaim. "Non-innocent Redox Behavior of Amidinato Ligands: Spectroscopic Evidence for Amidinyl Complexes." Zeitschrift für anorganische und allgemeine Chemie 640, no. 14 (2014): 2781–87. http://dx.doi.org/10.1002/zaac.201400306.

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25

Pearce, Adam J., Alyssa A. Cassabaum, Grace E. Gast, Renee R. Frontiera, and Ian A. Tonks. "Redox Non-Innocent Behavior of a Terminal Iridium Hydrazido(2−) Triple Bond." Angewandte Chemie 128, no. 42 (2016): 13363–67. http://dx.doi.org/10.1002/ange.201607648.

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26

Kaim, Wolfgang. "The Shrinking World of Innocent Ligands: Conventionaland Non-Conventional Redox-Active Ligands." European Journal of Inorganic Chemistry 2012, no. 3 (2012): 343–48. http://dx.doi.org/10.1002/ejic.201101359.

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27

Pearce, Adam J., Alyssa A. Cassabaum, Grace E. Gast, Renee R. Frontiera, and Ian A. Tonks. "Redox Non-Innocent Behavior of a Terminal Iridium Hydrazido(2−) Triple Bond." Angewandte Chemie International Edition 55, no. 42 (2016): 13169–73. http://dx.doi.org/10.1002/anie.201607648.

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28

Orchanian, Nicholas M., Lorena E. Hong, David A. Velazquez, and Smaranda C. Marinescu. "Electrocatalytic syngas generation with a redox non-innocent cobalt 2-phosphinobenzenethiolate complex." Dalton Transactions 50, no. 31 (2021): 10779–88. http://dx.doi.org/10.1039/d0dt03270k.

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29

Lima, Lidiane M. A., Heide Murakami, D. Jackson Gaebler, et al. "Acute Toxicity Evaluation of Non-Innocent Oxidovanadium(V) Schiff Base Complex." Inorganics 9, no. 6 (2021): 42. http://dx.doi.org/10.3390/inorganics9060042.

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The vanadium(V) complexes have been investigated as potential anticancer agents which makes it essential to evaluate their toxicity for safe use in the clinic. The large-scale synthesis and the acute oral toxicity in mice of the oxidovanadium(V) Schiff base catecholate complex, abbreviated as [VO(HSHED)dtb] containing a redox-active ligand with tridentate Schiff base (HSHED = N-(salicylideneaminato)-N’-(2-hydroxyethyl)-1,2-ethylenediamine) and dtb = 3,5-di-(t-butyl)catechol ligands were carried out. The body weight, food consumption, water intake as well biomarkers of liver and kidney toxicity
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30

Liu, Yu-Chiao, Tao-Hung Yen, Kai-Ti Chu, and Ming-Hsi Chiang. "Utilization of Non-Innocent Redox Ligands in [FeFe] Hydrogenase Modeling for Hydrogen Production." Comments on Inorganic Chemistry 36, no. 3 (2015): 141–81. http://dx.doi.org/10.1080/02603594.2015.1115397.

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31

Lyaskovskyy, Volodymyr, and Bas de Bruin. "ChemInform Abstract: Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions." ChemInform 43, no. 15 (2012): no. http://dx.doi.org/10.1002/chin.201215261.

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32

Paul, Nanda D., Tobias Krämer, John E. McGrady, and Sreebrata Goswami. "Dioxygen activation by mixed-valent dirhodium complexes of redox non-innocent azoaromatic ligands." Chemical Communications 46, no. 38 (2010): 7124. http://dx.doi.org/10.1039/c0cc01880e.

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33

Lu, Connie C, Serena DeBeer George, Thomas Weyhermüller, Eckhard Bill, Eberhard Bothe, and Karl Wieghardt. "An Electron-Transfer Series of High-Valent Chromium Complexes with Redox Non-Innocent, Non-Heme Ligands." Angewandte Chemie 120, no. 34 (2008): 6484–87. http://dx.doi.org/10.1002/ange.200800669.

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34

Lu, Connie C, Serena DeBeer George, Thomas Weyhermüller, Eckhard Bill, Eberhard Bothe, and Karl Wieghardt. "An Electron-Transfer Series of High-Valent Chromium Complexes with Redox Non-Innocent, Non-Heme Ligands." Angewandte Chemie International Edition 47, no. 34 (2008): 6384–87. http://dx.doi.org/10.1002/anie.200800669.

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35

Chuang, Yu-Chun, Chou-Fu Sheu, Gene-Hsiang Lee, Yu-Sheng Chen, and Yu Wang. "Charge density studies of 3dmetal (Ni/Cu) complexes with a non-innocent ligand." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 73, no. 4 (2017): 634–42. http://dx.doi.org/10.1107/s2052520617007119.

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High-resolution X-ray diffraction experiments and atom-specific X-ray absorption experiments are applied to investigate a series of square planar complexes with the non-innocent ligand of maleonitriledithiolate (mnt), [S2C2(CN)2]z−, containingM—S bonds. Four complexes of (PyH)z[M(mnt)2]z−, whereM= Ni or Cu,z= 2 or 1 and PyH+= C5NH6+, were studied in order to clarify whether such one-electron oxidation–reduction, [M(mnt)2]2−/[M(mnt)2]1−, is taking place at the metal or the ligand site. Combining the techniques of metalK-,L-edge and SK-edge X-ray absorption spectroscopy with high-resolution X-ra
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36

Mouchel Dit Leguerrier, D., R. Barré, J. K. Molloy, and F. Thomas. "Lanthanide complexes as redox and ROS/RNS probes: A new paradigm that makes use of redox-reactive and redox non-innocent ligands." Coordination Chemistry Reviews 446 (November 2021): 214133. http://dx.doi.org/10.1016/j.ccr.2021.214133.

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37

Jacobsen, Heiko, and James P. Donahue. "Computational Study of Iron Bis(dithiolene) Complexes: Redox Non-Innocent Ligands and Antiferromagnetic Coupling." Inorganic Chemistry 47, no. 21 (2008): 10037–45. http://dx.doi.org/10.1021/ic801277r.

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38

Zhou, Wen, Brian O. Patrick, and Kevin M. Smith. "Influence of redox non-innocent phenylenediamido ligands on chromium imido hydrogen-atom abstraction reactivity." Chem. Commun. 50, no. 69 (2014): 9958–60. http://dx.doi.org/10.1039/c4cc04545a.

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39

Heinze, Katja, and Sven Reinhardt. "Platinum(II) Complexes with Non-Innocent Ligands: Solid-Phase Synthesis, Redox Chemistry and Luminescence." Chemistry - A European Journal 14, no. 31 (2008): 9482–86. http://dx.doi.org/10.1002/chem.200801288.

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40

Gluyas, Josef B. G., Andrew J. Boden, Samantha G. Eaves, Herrick Yu, and Paul J. Low. "Long range charge transfer in trimetallic mixed-valence iron complexes mediated by redox non-innocent cyanoacetylide ligands." Dalton Trans. 43, no. 17 (2014): 6291–94. http://dx.doi.org/10.1039/c4dt00614c.

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41

Hazari, Arijit Singha, Alexa Paretzki, Jan Fiedler, Stanislav Zalis, Wolfgang Kaim та Goutam Kumar Lahiri. "Different manifestations of enhanced π-acceptor ligation at every redox level of [Os(9-OP)L2]n, n = 2+, +, 0, − (9-OP− = 9-oxidophenalenone and L = bpy or pap)". Dalton Transactions 45, № 45 (2016): 18241–51. http://dx.doi.org/10.1039/c6dt03764j.

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42

Berry, John F., Eckhard Bill, Eberhard Bothe, Thomas Weyhermüller, and Karl Wieghardt. "Octahedral Non-Heme Non-Oxo Fe(IV) Species Stabilized by a Redox-Innocent N-Methylated Cyclam−Acetate Ligand." Journal of the American Chemical Society 127, no. 33 (2005): 11550–51. http://dx.doi.org/10.1021/ja052673t.

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43

Hou, Pengxin, Jianbo Fang, and Guangqun Zhai. "Catalytic aerobic radical polymerization in typical redox-non-innocent solvents as potential low-efficiency initiators." Journal of Macromolecular Science, Part A 56, no. 12 (2019): 1121–31. http://dx.doi.org/10.1080/10601325.2019.1659104.

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44

Ward, Michael D., and Jon A. McCleverty. "Non-innocent behaviour in mononuclear and polynuclear complexes: consequences for redox and electronic spectroscopic properties." Journal of the Chemical Society, Dalton Transactions, no. 3 (January 10, 2002): 275–88. http://dx.doi.org/10.1039/b110131p.

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45

Gandara, Catherine, Christian Philouze, Olivier Jarjayes, and Fabrice Thomas. "Coordination chemistry of a redox non-innocent NHC bis(phenolate) pincer ligand with nickel(II)." Inorganica Chimica Acta 482 (October 2018): 561–66. http://dx.doi.org/10.1016/j.ica.2018.06.046.

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46

Butschke, Burkhard, Kathlyn L. Fillman, Tatyana Bendikov, et al. "How Innocent are Potentially Redox Non-Innocent Ligands? Electronic Structure and Metal Oxidation States in Iron-PNN Complexes as a Representative Case Study." Inorganic Chemistry 54, no. 10 (2015): 4909–26. http://dx.doi.org/10.1021/acs.inorgchem.5b00509.

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47

Boyle, Jenna, Catherine Breakfield, Leah Buck, Catherine McMahon, and Dominic C. Babbini. "Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-diyl)bis[N-(2,3,4,5,6-pentafluorophenyl)ethan-1-imine]." Acta Crystallographica Section E Crystallographic Communications 73, no. 7 (2017): 954–56. http://dx.doi.org/10.1107/s2056989017008040.

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The title compound, C21H9F10N3, represents a potential redox non-innocent pyridine diimine ligand system. It consists of a central pyridine ring with two pentafluorophenyl substituted imine groups in positions 2 and 6. The whole molecule is generated by mirror symmetry, the mirror bisecting the N andpara-C atom of the pyridine ring. The perfluorophenyl ring is inclined to the pyridine ring by 73.67 (8)°. In the crystal, molecules stack along theaaxis, but there are no significant intermolecular interactions present.
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48

Freeman, Lucas A., Jacob E. Walley, Akachukwu D. Obi та ін. "Stepwise Reduction at Magnesium and Beryllium: Cooperative Effects of Carbenes with Redox Non-Innocent α-Diimines". Inorganic Chemistry 58, № 16 (2019): 10554–68. http://dx.doi.org/10.1021/acs.inorgchem.9b01058.

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49

Shen, Jingmei, Glenn P. A. Yap, William E. Barker IV, William E. Geiger та Klaus H. Theopold. "An electron transfer series of octahedral chromium complexes containing a redox non-innocent α-diimine ligand". Chem. Commun. 50, № 73 (2014): 10626–29. http://dx.doi.org/10.1039/c4cc03332a.

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50

Jurca, Titel, Wen-Ching Chen, Sheila Michel, Ilia Korobkov, Tiow-Gan Ong, and Darrin S. Richeson. "Solid-State Thermolysis of afac-Rhenium(I) Carbonyl Complex with a Redox Non-Innocent Pincer Ligand." Chemistry - A European Journal 19, no. 13 (2013): 4278–86. http://dx.doi.org/10.1002/chem.201203045.

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