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Dissertations / Theses on the topic 'Reduction-oxidation reactions'

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Published: 4 June 2025

Last updated: 1 August 2025

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1

Duff, Jack Lawrence. "Single electron transfer in nucleophilic reactions of substituted norbornanes." Thesis, Georgia Institute of Technology, 1989. http://hdl.handle.net/1853/27444.

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2

Holder, Grant Newton. "Redox reactivity of mononuclear and binuclear rhenium complexes." Diss., Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/30392.

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3

Zweni, Pumza P. "Dendrimer-transition metal catalyzed oxidation and reduction reactions." Thesis, University of Ottawa (Canada), 2005. http://hdl.handle.net/10393/10529.

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This project was launched with the aim of developing dendrimer catalysts for oxidation and reduction reactions. Poly(amidoamine) (PAMAM) and poly(propyleneimine) (PPI) dendrimers were of interest because of their well-established synthesis. Chapter 1 describes the fundamentals of dendrimers and provides a brief insight of their application in catalysis. In particular, examples of dendritic catalysts that have been previously employed as oxidation and reduction catalysts are presented. Chapter 2 presents the synthesis and characterization of silica-supported PAMAM dendrimers, their phosphomethy

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4

羅政藩 and Chang-fan Lo. "Substitution and redox reactions of some binuclear platinum (II) and platinum (III) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31231901.

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5

Lo, Chang-fan. "Substitution and redox reactions of some binuclear platinum (II) and platinum (III) complexes /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12505304.

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6

Lippert, Cameron A. "Redox-active ligand-mediated radical coupling reactions at high-valent oxorhenium complexes: reactions relevant to water oxidation for artificial photosynthesis." Diss., Georgia Institute of Technology, 2011. http://hdl.handle.net/1853/41199.

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The making and breaking of O-O bonds has implications ranging from artificial photosynthesis and water oxidation to the use of O₂ as a selective, green oxidant for transformations of small molecules. Oxidative generation of O₂ from coupling of two H₂O molecules remains challenging, and well defined systems that catalytically evolve O₂ are exceedingly rare. Recent theoretical studies have invoked metal oxyl radicals (L[subscript n]M=O*) containing a singly occupied M-O π-type orbital as precursors to O-O bond forming events in both biological and synthetic water oxidation catalysts. However, th

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7

Moritz, Paul Stuart. "Substitution and redox chemistry of ruthenium complexes /." Title page, contents and summary only, 1987. http://web4.library.adelaide.edu.au/theses/09PH/09phm862.pdf.

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8

Sun, Xiao-Jing. "The extent and importance of single electron transfers in organic reactions." Diss., Georgia Institute of Technology, 1993. http://hdl.handle.net/1853/27981.

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9

Saleh, Nail Asad. "Dynamical solvent effect in 1-(9-anthryl)-3-(4-dimethylaniline) propane charge transfer reactions /." free to MU campus, to others for purchase, 2002. http://wwwlib.umi.com/cr/mo/fullcit?p3060138.

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10

Haffenden, Luke John William. "Investigation into the role of redox reactions in Maillard model systems : generation of aroma, colour and other non-volatiles." Thesis, McGill University, 2007. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=111850.

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The role of redox reactions in the formation of aroma volatiles, colour and other non-volatiles in the Maillard Reaction was investigated. The electrochemical properties of individual reactants and Maillard model mixtures were monitored via ORP (oxidation-reduction potential) and oxygen electrodes. All models exhibited unique electrochemical activities represented by their corresponding ORP profiles. Investigation into the redox potentials of several model systems demonstrated that the increased negative value of a redox potential is not necessarily correlated with its browning potential. An o

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11

Pham, Long Vo. "Oxidation and reduction reactions of the water-oxidizing complex in photosystem II." Doctoral thesis, Umeå universitet, Kemiska institutionen, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-111862.

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The oxygen that we breathe and food that we eat are products of the natural photosynthesis. Molecular oxygen is crucial for life on Earth owing to its role in the glycolysis and citric acid pathways that yield in aerobic organisms the energy-rich ATP molecules. Photosynthetic water oxidation, which produces molecular oxygen from water and sunlight, is performed by higher plants, algae and cyanobacteria. Within the molecular structure of a plant cell, photosynthesis is performed by a specific intracellular organelle – the chloroplast. Chloroplasts contain a membrane system, the thylakoid membra

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12

Dehestani, Ahmad. "Exploring reactivities of oxo and nitrido ligands on high valent osmium with electrophiles, nucleophiles, alkenes, hydrogen, and methane. /." Thesis, Connect to this title online; UW restricted, 2004. http://hdl.handle.net/1773/8626.

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13

劉強 and Keung Lau. "Kinetics and mechanisms of redox reactions of some macrocyclic tertiary anine complexes of ruthenium." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1988. http://hub.hku.hk/bib/B31231226.

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14

Lau, Keung. "Kinetics and mechanisms of redox reactions of some macrocyclic tertiary anine complexes of ruthenium /." [Hong Kong] : University of Hong Kong, 1988. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12358770.

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15

Addam, Billey Bright. "Probing learners' conceptual understanding of oxidation and reduction (redox) reactions : a case study." Thesis, Rhodes University, 2004. http://hdl.handle.net/10962/d1002950.

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The new political dispensation in South Africa has seen a lot of changes taking place. The democratic wind, which has been blowing in all spheres of the political arena, could not leave out Education. This has led to the transformation in education and the revision of the curriculum guided by the Outcomes-Based Education philosophy (OBE). Thus, require education authorities as well as educators to look at education more comprehensively. The challenge posed to educators now is to develop tools and strategies that will make learning accessible to as many learners as possible and to teach for und

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16

Gunawardhana, Kihanduwage N. Gipson Stephen L. "Chemistry, electrochemistry and electron transfer induced reactions of cobalt complexes with fluorinated ligands." Waco, Tex. : Baylor University, 2007. http://hdl.handle.net/2104/5114.

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Thesis (Ph.D.)--Baylor University, 2007.<br>In the abstract "CF3COCo(CO)3PPh3, CF3, Bu3SnH, CF3H, [Co(CO)4]-, [Co(CO)3(PPh3)]-, C2F4, C6F5Co(CO)3PPh3, C6F5, C6F5H, C6F5D, CF3COCo(CO)3PPh3, and Co-C(acyl)" are subscript. Includes bibliographical references (p. 205-213).

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17

Cooper, Ian Blake. "Photosynthetic water oxidation and proton-coupled electron transfer." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/26707.

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Thesis (Ph. D.)--Chemistry and Biochemistry, Georgia Institute of Technology, 2009.<br>Committee Chair: Bridgette Barry; Committee Member: El-Sayed, Mostafa; Committee Member: Fahrni, Christoph; Committee Member: Kröger, Nils; Committee Member: McCarty, Nael. Part of the SMARTech Electronic Thesis and Dissertation Collection.

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18

Jensen, Stephen C. "The Role of Interstitials and Surface Defects on Oxidation and Reduction Reactions on Titania." Thesis, Harvard University, 2013. http://dissertations.umi.com/gsas.harvard:10768.

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This thesis focuses on understanding the influence of defect sites in titanium dioxide that drive many types of thermal and photochemical reactions. Two of the most common defects in vacuum are titanium interstitials and oxygen vacancies. Molecular oxygen fills oxygen vacancies and creates oxygen adatoms. We broadly investigate reduction and oxidation reactions of oxygenates driven by titanium interstitials and oxygen adatoms. First, we focus on the thermal chemistry of oxygen adatoms with butyrophenone and find that it reacts with the adatoms to form a strongly bound complex. The large differ

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19

Mullen, Lisa Maureen. "Bacterial influence on uranium oxidation reduction reactions : implications for environmental remediation and isotopic composition." Thesis, Massachusetts Institute of Technology, 2007. http://hdl.handle.net/1721.1/41293.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Nuclear Science and Engineering, 2007.<br>Includes bibliographical references (p. 239-247).<br>The bacterial influence on the chemistry and speciation of uranium has some important impacts on the environment, and can be exploited usefully for the purposes of environmental remediation of uranium waste contamination. It is important to understand both from a scientific and environmental perspective how different types of bacteria can affect the chemistry and speciation of uranium. Analysis of the kinetics of uranium reduction, to d

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20

Vyas, R. "Application of chiral ligands in transition metal catalyzed aziridination, reduction, oxidation and cyclopropanation reactions." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2001. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2345.

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21

Wesselmark, Maria. "Electrochemical Reactions in Polymer Electrolyte Fuel Cells." Doctoral thesis, KTH, Tillämpad elektrokemi, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-25267.

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The polymer electrolyte fuel cell converts the chemical energy in a fuel, e.g. hydrogen or methanol, and oxygen into electrical energy. The high efficiency and the possibility to use fuel from renewable sources make them attractive as energy converters in future sustainable energy systems. Great progress has been made in the development of the PEFC during the last decade, but still improved lifetime as well as lowered cost is needed before a broad commercialization can be considered. The electrodes play an important role in this since the cost of platinum used as catalyst constitutes a large p

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22

Jenson, David L. Jenson. "Proton-coupled electron transfer and tyrosine D of phototsystem II." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/29667.

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Thesis (Ph. D.)--Chemistry and Biochemistry, Georgia Institute of Technology, 2010.<br>Committee Chair: Bridgette Barry; Committee Member: Ingeborg Schmidt-Krey; Committee Member: Jake Soper; Committee Member: Nils Kroger; Committee Member: Wendy Kelly. Part of the SMARTech Electronic Thesis and Dissertation Collection.

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23

Karle, Ida-Maja. "On redox reactions and transport processes of solutes in coastal marine sediments /." [Göteborg] : Analystical and Marine Chemistry, Dept. of Chemistry, Göteborg University, 2006. http://www.loc.gov/catdir/toc/fy0706/2006455268.html.

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24

Soper, Jake D. "Reactions at nitrogenous ligands on oxidizing group 8 metal centers /." Thesis, Connect to this title online; UW restricted, 2003. http://hdl.handle.net/1773/8589.

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25

Motsoeneng, Rapelang Gloria. "Advanced oxygen reduction reaction catalysts/material for direct methanol fuel cell (dmfc) application." University of the Western Cape, 2014. http://hdl.handle.net/11394/4365.

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>Magister Scientiae - MSc<br>Fuel cells are widely considered to be efficient and non-polluting power source offering much higher energy density. This study is aimed at developing oxygen reduction reactions (ORR) catalysts with reduced platinum (Pt) loading. In order to achieve this aim, monometallic Pd and Pt nanostructured catalysts were electrodeposited on a substrate (carbon paper) by surface limited redox replacement using electrochemical atomic layer deposition (ECALD) technique. Pd:Pt bimetallic nanocatalysts were also deposited on carbon paper. Pd:Pt ratios were (1:1, 2.1 and 3:1). The

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26

Polshakov, Dmitrii Arkadyevich. "Ultrafast spectroscopy and dynamics of nitrenes and carbenes." Columbus, Ohio : Ohio State University, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1130968887.

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27

Pérez, Inés Monte. "Bioinspired oxidation reactions involving mono- and poly-nuclear transition metal complexes." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät, 2017. http://dx.doi.org/10.18452/17741.

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Hochvalente Metal-oxo-, -peroxo- und -nitrenzentren später Übergangsmetalle werden als reaktive Intermediate vieler technologisch interessanter und biologischer Transformationsreaktionen wie die Oxidation von Kohlenwasserstoffen, Hydroxylierung, Aminierung, Aziridierung und Sauerstoffreduktion angenommen. Die Isolierung und Charakterisierung solcher Intermediate, wenngleich sie sich schwierig gestaltet, kann wichtige Informationen zum Mechanismus solcher Reaktionen liefern und kann somit zu einer gezielten Optimierung und Herstellung von verbesserten Katalysatoren genutzt werden. In dieser A

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28

Ángeles-Boza, Alfredo M. "The importance of heavy atom isotope effects in the elucidation of mechanistic details in small molecule activation reactions." Revista de Química, 2017. http://repositorio.pucp.edu.pe/index/handle/123456789/123963.

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La medición de efectos isotópicos es una herramienta importante en el estudio de las transformaciones químicas. El uso de efectos isotópicos de átomos ligeros como el deuterio es muy común e incluso aparece en muchos textos básicos de química. Lamentablemente, el uso de efectos isotópicos de átomos pesados no ha recibido la misma atención a pesar de su gran utilidad. Este manuscrito sirve como introducción a este tema importante.<br>The determination of isotope effects is an important tool in the study of chemical transformations. Very common in the literature is the use of deuterium isoto

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29

Crowell, Brendan William. "Biological sulfur reactions and the influence on fluid flow at mid-ocean ridge hydrothermal systems." Thesis, Available online, Georgia Institute of Technology, 2007, 2007. http://etd.gatech.edu/theses/available/etd-07092007-085654/.

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30

Siriwardane, Upali. "Systematic syntheses of iron-triad (Fe,Ru,Os) tetranuclear clusters by redox condensation reactions of [Ru(3);CO(11)) and [Os(3);CO(11)] trinuclear carbonylates; co-crystallization of ruthenium-osmium clusters /." The Ohio State University, 1985. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487264603216477.

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31

Offenbacher, Adam R. "Protein structural changes and tyrosyl radical-mediated electron transfer reactions in ribonucleotide reductase and model compounds." Diss., Georgia Institute of Technology, 2011. http://hdl.handle.net/1853/39473.

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Tyrosyl radicals can facilitate proton-coupled electron transfer (PCET) reactions that are linked to catalysis in many biological systems. One such protein system is ribonucleotide reductase (RNR). This enzyme is responsible for the conversion of ribonucleotides to deoxyribonucleotides. The beta2 subunit of class Ia RNRs contains a diiron cluster and a stable tyrosyl radical (Y122*). Reduction of ribonucleotides is dependent on reversible, long-distance PCET reactions involving Y122* located 35 Å from the active site. Protein conformational dynamics are postulated to precede diiron cluster ass

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32

Ampurdanés, Vilanova Jordi. "Novel Catalytic Materials and Strategies for Hydrogen Production and Hydrogenation Reactions based on PEM Electrolysis." Doctoral thesis, Universitat Rovira i Virgili, 2014. http://hdl.handle.net/10803/319946.

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La producció d’hidrogen, a gran escala, a partir d’aigua ha esdevingut un repte des de fa uns quants any enrere. Així, una via ecològica i eficient per a la generació d’hidrogen ha de ser establerta. Entre totes les possibilitats, la electròlisis mitjançant la tecnologia de membranes bescanviadores de protons (PEM) és la tècnica més prometedora per a aconseguir tal propòsit. A més a més, aquesta aproximació també pot ser considerada per a dur a terme reaccions electroquímiques per altres propòsits més enllà de la generació d’hidrogen, com per exemple, la reducció de contaminants d’origen quím

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33

Клочко, А. Д. "Вплив ОВП харчових продуктів на їхні седативні властивості". Thesis, Сумський державний університет, 2018. http://essuir.sumdu.edu.ua/handle/123456789/66782.

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34

Kisukuri, Camila de Menezes. "Nanopartículas bimetálicas e biocatalisadores: um estudo sobre sua interação e atividade catalítica." Universidade de São Paulo, 2018. http://www.teses.usp.br/teses/disponiveis/46/46136/tde-19072018-110201/.

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Apostando na versatilidade de nanopartículas bimetálicas como catalisadores em reações orgânicas, nós desenvolvemos um estudo onde nanopartículas bimetálicas de AgAu, AgPd e AgPt, foram utilizadas como catalisadores em reações de oxidação de compostos de silício (1a-j) ao respectivo silanol (2a-j). Empregando a água como agente oxidante, para estas reações, conversões de 43->99% foram alcançadas. Visando formar catalisadores metalo-enzimáticos (CME), nanopartículas bimetálicas de AgAu, AgPd e AgPt foram utilizadas como suporte da CAL-B (CMEs: CALB-AgAu; CALB-AgPd; CALB-AdPt). Esses catalisador

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35

Hayes, Elizabeth Jane. "Macrocyclic complexes as redox-active receptors /." St. Lucia, Qld, 2001. http://www.library.uq.edu.au/pdfserve.php?image=thesisabs/absthe16372.pdf.

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36

Hong, William Sungil. "Oxidation-reduction kinetics of porous titanium dioxide /." The Ohio State University, 1987. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487331541711442.

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37

Davies, Arthur John. "The development and teaching of redox concepts /." Title page, table of contents and abstract only, 1992. http://web4.library.adelaide.edu.au/theses/09EDM/09edmd255.pdf.

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38

Miedzinska, K. M. E. (Katarzyna Malgorzata Ewa) Carleton University Dissertation Chemistry. "A study of the redox mechanism of exchanged zeolites." Ottawa, 1985.

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39

SILVA, SIRLANE G. da. "Estudo da oxidação eletroquímica do etanol em meio alcalino utilizando eletrocatalisadores PtAuIr/C e PdAuIr/C preparados via redução por borohidreto de sódio." reponame:Repositório Institucional do IPEN, 2017. http://repositorio.ipen.br:8080/xmlui/handle/123456789/28037.

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Submitted by Pedro Silva Filho (pfsilva@ipen.br) on 2017-11-22T16:50:49Z No. of bitstreams: 0<br>Made available in DSpace on 2017-11-22T16:50:49Z (GMT). No. of bitstreams: 0<br>Eletrocatalisadores Pt/C, Pd/C, PtAu/C, PtIr/C, PdAu/C, PdIr/C, PtAuIr/C e PdAuIr/C foram preparados via redução por borohidreto de sódio em diferentes proporções atômicas, com 20% em massa de metal e suportados em carbono Vulcan XC72 de alta área superficial. Os materiais foram caracterizados pelas técnicas de espectroscopia de energia dispersiva de raios-X (EDX), análise de difração de raios-X (DRX) e microscopia ele

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40

Ayub, Ibrar. "Oxidation and reduction properties of iron-containing oxides." Thesis, n.p, 2001. http://ethos.bl.uk/.

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41

Lee, Lester Y. C. "Transmembrane electron transfer in artificial bilayers /." Full text open access at:, 1985. http://content.ohsu.edu/u?/etd,86.

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42

Kaighobadi, Joni N. "Transition state studies on protocatechuate 3,4-dioxygenase." Thesis, Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/27285.

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43

Sanii, Laurie Shireen. "The effect of terminal base identity on radical cation injection into the DNA duplex." Thesis, Georgia Institute of Technology, 1999. http://hdl.handle.net/1853/29377.

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44

Hsu, Songman. "Oxidation and reduction studies of polyphenylene suldide and its model compounds." Thesis, Georgia Institute of Technology, 1992. http://hdl.handle.net/1853/30006.

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45

Beard, Collen Alana. "Rubredoxin cobalt substitution and crystallization attempts." Thesis, Georgia Institute of Technology, 1989. http://hdl.handle.net/1853/29863.

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46

Qi, Hongyi, and 齐红艺. "Molecular characterization of Chinese medicines for the regulation of the intracellular redox signaling." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2011. http://hub.hku.hk/bib/B46921801.

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47

PETSOM, AMORN. "SYNTHETIC AND MECHANISTIC STUDIES ON THE ELECTROOXIDATION OF ORGANIC THIOETHERS." Diss., The University of Arizona, 1987. http://hdl.handle.net/10150/184178.

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This research has been directed at the study of neighboring group participation in electrooxidation of thioethers. Controlled potential oxidation of substituted 1,3-dithiane in wet acetonitrile provides substituted 1,2-dithiolane 1-oxide in good yield. Thioethers appended with neighboring alcohols and carboxylate are catalytically oxidized in a redox cycle by bromide ion. The formation of the alkoxysulfonium salt intermediates in such reactions is confirmed by product study. On the other hand, the acyloxysulfonium salt intermediates in the electrooxidation of endo -6-methylthio-bicyclo [2.2.1]

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48

Liu, Pei. "Development of redox proteomics methods and the identification of redox-sensitive proteins in arabidopsis." HKBU Institutional Repository, 2015. https://repository.hkbu.edu.hk/etd_oa/184.

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Cellular redox homeostasis mediates a wide range of physiological and developmental processes. Various stresses trigger over-production of reactive oxygen/nitrogen species which leads to oxidative modifications of redox-sensitive proteins. Identification and characterization of redox-sensitive proteins are important steps toward understanding molecular mechanisms of stress responses. In the study, a high-throughput quantitative proteomic approach termed OxiTRAQ was developed for identifying proteins whose thiols undergo reversible oxidative modifications in Arabidopsis cells subjected to oxida

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49

Crevier, Thomas J. "Oxidation and reduction of small molecules by tungsten and osmium compounds /." Thesis, Connect to this title online; UW restricted, 1998. http://hdl.handle.net/1773/11581.

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50

Yang, Kun-Yun. "The effects of the N(5) hydrogen bond and the re-face positive charge on the redox properties of flavin in the methylotrophic bacterium W3A1 electron transfer flavoprotein." Columbus, Ohio : Ohio State University, 2006. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1150407209.

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