Academic literature on the topic 'Reductive dehydroxylation'

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Journal articles on the topic "Reductive dehydroxylation"

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Gräwert, Tobias, Ingrid Span, Adelbert Bacher, and Michael Groll. "Reductive Dehydroxylation of Allyl Alcohols by IspH Protein." Angewandte Chemie International Edition 49, no. 47 (2010): 8802–9. http://dx.doi.org/10.1002/anie.201000833.

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Mostinski, Yelena, David Lankri, Yana Konovalov, Riva Nataf та Dmitry Tsvelikhovsky. "Proline-promoted dehydroxylation of α-ketols". Chemical Science 10, № 40 (2019): 9345–50. http://dx.doi.org/10.1039/c9sc02543j.

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A new single-step proline-potassium acetate promoted reductive dehydroxylation of α-ketols is reported. We introduce the unexplored reactivity of proline and, for the first time, reveal its ability to function as a reducing agent.
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Abdel-Azeim, Safwat, Abdesslem Jedidi, Jorg Eppinger, and Luigi Cavallo. "Mechanistic insights into the reductive dehydroxylation pathway for the biosynthesis of isoprenoids promoted by the IspH enzyme." Chemical Science 6, no. 10 (2015): 5643–51. http://dx.doi.org/10.1039/c5sc01693b.

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Kim, Sunggak, Li Chan, and Jazreel Lim. "Iron-Catalyzed Reductive Dehydroxylation of Benzylic Alcohols Using Polymethylhydrosiloxane (PMHS)." Synlett 2011, no. 19 (2011): 2862–66. http://dx.doi.org/10.1055/s-0031-1289857.

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Graewert, Tobias, Ingrid Span, Adelbert Bacher, and Michael Groll. "ChemInform Abstract: Reductive Dehydroxylation of Allyl Alcohols by IspH Protein." ChemInform 42, no. 6 (2011): no. http://dx.doi.org/10.1002/chin.201106274.

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Boll, Matthias, and Georg Fuchs. "Unusual reactions involved in anaerobic metabolism of phenolic compounds." Biological Chemistry 386, no. 10 (2005): 989–97. http://dx.doi.org/10.1515/bc.2005.115.

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AbstractAerobic bacteria use molecular oxygen as a common co-substrate for key enzymes of aromatic metabolism. In contrast, in anaerobes all oxygen-dependent reactions are replaced by a set of alternative enzymatic processes. The anaerobic degradation of phenol to a non-aromatic product involves enzymatic processes that are uniquely found in the aromatic metabolism of anaerobic bacteria: (i) ATP-dependent phenol carboxylation to 4-hydroxybenzoate via a phenylphosphate intermediate (biological Kolbe-Schmitt carboxylation); (ii) reductive dehydroxylation of 4-hydroxybenzoyl-CoA to benzoyl-CoA; a
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Szewzyk, Ulrich, Regine Szewzyk, and Bernhard Schink. "Methanogenic degradation of hydroquinone and catechol via reductive dehydroxylation to phenol." FEMS Microbiology Letters 31, no. 2 (1985): 79–87. http://dx.doi.org/10.1111/j.1574-6968.1985.tb01134.x.

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Zhang, Jie, Hong-Kui Zhang, and Pei-Qiang Huang. "Towards stereochemical control: A short formal enantioselective total synthesis of pumiliotoxins 251D and 237A." Beilstein Journal of Organic Chemistry 9 (November 5, 2013): 2358–66. http://dx.doi.org/10.3762/bjoc.9.271.

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A concise enantioselective synthesis of the advanced intermediate 5 for the synthesis of pumiliotoxins (Gallagher’s intermediate) is described. The synthesis started from the regio- and trans-diastereoselective (dr = 98:2) reductive 3-butenylation of (R)-3-(tert-butyldimethylsilyloxy)glutarimide 14. After O-desilylation and Dess–Martin oxidation, the resulting keto-lactam 10 was subjected to a highly trans-stereoselective addition of the methylmagnesium iodide to give carbinol 11 as sole diastereomer. An efficient ring closure procedure consisting of ozonolysis and reductive dehydroxylation pr
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Chan, Li Yan, Jazreel Seh Kai Lim, and Sunggak Kim. "ChemInform Abstract: Iron-Catalyzed Reductive Dehydroxylation of Benzylic Alcohols Using Polymethylhydrosiloxane (PMHS)." ChemInform 43, no. 15 (2012): no. http://dx.doi.org/10.1002/chin.201215029.

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Boll, Matthias, Bernhard Schink, Albrecht Messerschmidt, and Peter M. H. Kroneck. "Novel bacterial molybdenum and tungsten enzymes: three-dimensional structure, spectroscopy, and reaction mechanism." Biological Chemistry 386, no. 10 (2005): 999–1006. http://dx.doi.org/10.1515/bc.2005.116.

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Abstract The molybdenum enzymes 4-hydroxybenzoyl-CoA reductase and pyrogallol-phloroglucinol transhydroxylase and the tungsten enzyme acetylene hydratase catalyze reductive dehydroxylation reactions, i.e., transhydroxylation between phenolic residues and the addition of water to a triple bond. Such activities are unusual for this class of enzymes, which carry either a mononuclear Mo or W center. Crystallization and subsequent structural analysis by high-resolution X-ray crystallography has helped to resolve the reaction centers of these enzymes to a degree that allows us to understand the inte
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Dissertations / Theses on the topic "Reductive dehydroxylation"

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Jobelius, Hannah. "Etude de la métalloenzyme IspH, une cible pour le développement de nouveaux agents antibactériens." Electronic Thesis or Diss., Strasbourg, 2024. http://www.theses.fr/2024STRAF004.

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IspH est la dernière enzyme de la voie du méthylérythritol phosphate qui produit les deux précurseurs nécessaires à la biosynthèse de tous les isoprénoïdes. Cette métalloenzyme est essentielle à la survie de nombreux microorganismes dont des bactéries pathogènes et le parasite responsable du paludisme. Etant absente chez l’humain, IspH est une cible de choix pour le développement de nouveaux agents antimicrobiens. En utilisant une approche pluridisciplinaire combinant biologie moléculaire, enzymologie, spectroscopies Raman, Mössbauer et cristallographie, l’objectif de cette thèse était d’étudi
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Qian, Jiang. "Studies of Sulfur Reduction of Taurine and Taurine-Conjugated Bile Acids by Bile acid 7α-Dehydroxylating Bacteria". TopSCHOLAR®, 2000. http://digitalcommons.wku.edu/theses/694.

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Bile acids are C24 steroids that are derived in the liver from cholesterol and secreted into the intestinal lumen to aid in emulsification of dietary lipids and lipid-soluble vitamins. The indigenous intestinal microflora modify bile acids, producing up to 20 unique bile acid metabolites. The 7α-dehydroxylation of the bile acids is the most physiologically important bile acid biotransformation. All known intestinal bacteria capable of bile acid 7α-dehydroxylation are anaerobic, gram-positive rods of the genera Clostridium and Eubcicterium. Bile acid 7α-dehydroxylating bacteria often contain bi
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Book chapters on the topic "Reductive dehydroxylation"

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Iyoda, M. "1,4-Dehalogenation, Reductive Dehydroxylation, and Retro-Diels–Alder Reaction." In Monocyclic Arenes, Quasiarenes, and Annulenes. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-045-00495.

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