Academic literature on the topic 'Reductive reactions'

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Journal articles on the topic "Reductive reactions"

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Koóš, Peter, Martin Markovič, Pavol Lopatka, and Tibor Gracza. "Recent Applications of Continuous Flow in Homogeneous Palladium Catalysis." Synthesis 52, no. 23 (2020): 3511–29. http://dx.doi.org/10.1055/s-0040-1707212.

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Considerable advances have been made using continuous flow chemistry as an enabling tool in organic synthesis. Consequently, the number of articles reporting continuous flow methods has increased significantly in recent years. This review covers the progress achieved in homogeneous palladium catalysis using continuous flow conditions over the last five years, including C–C/C–N cross-coupling reactions, carbonylations and reductive/oxidative transformations.1 Introduction2 C–C Cross-Coupling Reactions3 C–N Coupling Reactions4 Carbonylation Reactions5 Miscellaneous Reactions6 Key to Schematic Sy
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Nicholas, Kenneth M., and Chandrasekhar Bandari. "Deoxygenative Transition-Metal-Promoted Reductive Coupling and Cross-Coupling of Alcohols and Epoxides." Synthesis 53, no. 02 (2020): 267–78. http://dx.doi.org/10.1055/s-0040-1707269.

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AbstractThe prospective utilization of abundant, CO2-neutral, renewable feedstocks is driving the discovery and development of new reactions that refunctionalize oxygen-rich substrates such as alcohols and polyols through C–O bond activation. In this review, we highlight the development of transition-metal-promoted reactions of renewable alcohols and epoxides that result in carbon–carbon bond-formation. These include reductive self-coupling reactions and cross-coupling reactions of alcohols with alkenes and arene derivatives. Early approaches to reductive couplings employed stoichiometric amou
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R., G. BHATTACHARYYA. "Systematisation of Synthetic Inorganic Reactions. Part-l. Electron-transfer Reactions : Possibility of introducing Name Reactions in Inorganic Chemistry." Journal Of India Chemical Society Vol.66, Aug-Oct 1989 (1989): 579–83. https://doi.org/10.5281/zenodo.5996445.

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Department of Chemistry, Jadavpur University, Calcutta- 700 032 Synthetic reactions in inorganic and coordination chemistry have not grown systematically. Since inorganic chemistry encompasses a variety of elements it is difficult to systematise those synthetic reactions. An attention has herein been focussed on the reductive reaction of higher valent metal ions with a view to generalising some synthetic routes. The concerned area is reductive nitrosylation and reductive carbonylation. It has been suggested that perhaps the introduction of name reactions, par
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Dutta, Lona, Atanu Mondal, and S. S. V. Ramasastry. "Metal‐Free Reductive Aldol Reactions." Asian Journal of Organic Chemistry 10, no. 4 (2021): 680–91. http://dx.doi.org/10.1002/ajoc.202000693.

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Pal, Sudipta, You-Yun Zhou, and Christopher Uyeda. "Catalytic Reductive Vinylidene Transfer Reactions." Journal of the American Chemical Society 139, no. 34 (2017): 11686–89. http://dx.doi.org/10.1021/jacs.7b05901.

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Lin, Ivan J. B., Hayder A. Zahalka, and Howard Alper. "Rhodium catalyzed reductive esterification reactions." Tetrahedron Letters 29, no. 15 (1988): 1759–62. http://dx.doi.org/10.1016/s0040-4039(00)82035-3.

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Anderson, James C., Alexander J. Blake, Paul J. Koovits, and Gregory J. Stepney. "Diastereoselective Reductive Nitro-Mannich Reactions." Journal of Organic Chemistry 77, no. 10 (2012): 4711–24. http://dx.doi.org/10.1021/jo300535h.

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Werth, Jacob, Kristen Berger, and Christopher Uyeda. "Cobalt Catalyzed Reductive Spirocyclopropanation Reactions." Advanced Synthesis & Catalysis 362, no. 2 (2019): 348–52. http://dx.doi.org/10.1002/adsc.201901293.

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Wang, Zhipeng A., Yan-Yu Liang, and Ji-Shen Zheng. "Reductive Amination/Alkylation Reactions: The Recent Developments, Progresses, and Applications in Protein Chemical Biology Studies." Current Organic Synthesis 15, no. 6 (2018): 755–61. http://dx.doi.org/10.2174/1570179415666180522093905.

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The chemical modifications of proteins or protein complexes have been a challenging but fruitful task in the post-genomic era. Bioorthogonal reactions play an important role for the purpose of selective functionalization, localization, and labeling of proteins with natural or non-natural structures. Among these reactions, reductive amination stands out as one of the typical bioorthogonal reactions with high efficiency, good biocompatibility, and versatile applications. However, not many specific reviews exist to discuss the mechanism, kinetics, and their applications in a detailed manner. In t
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Beeler, Joshua A., and Henry S. White. "Reductive Electrosynthesis Initiated By Mediated Oxalate Oxidation." ECS Meeting Abstracts MA2024-02, no. 53 (2024): 3639. https://doi.org/10.1149/ma2024-02533639mtgabs.

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Reductive electrosynthesis often requires large negative potentials, air-sensitive electrocatalysts, precious metal electrode surfaces, dry solvent, and/or a sacrificial anode. As a result, electroorganic reduction reactions remain relatively underdeveloped compared to oxidative electroorganic methods. This work introduces a novel reductive electrosynthetic method, wherein the mediated oxidation of oxalate (C2O4 2–) at a carbon electrode facilitates the homogeneous reduction of aryl halides. Specifically, the homogeneous oxidation of C2O4 2– in mixed organic/aqueous solutions by electrochemica
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Dissertations / Theses on the topic "Reductive reactions"

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Rodrigo, Sanjeewa K. "Nickel Catalyzed Regioselective Reductive Coupling Reactions." University of Cincinnati / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1396532622.

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Börjesson, Carazo Marino Rolando. "Ni-Catalyzed Reductive Carboxylation Reactions with Carbon Dioxide." Doctoral thesis, Universitat Rovira i Virgili, 2020. http://hdl.handle.net/10803/670249.

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El gas hivernacle principal emès a causa del desenvolupament industrial de la nostra societat és el diòxid de carboni. Com a conseqüència, els darrers anys han estat testimonis del desenvolupament de processos per a la fixació de CO2 en molècules orgàniques. Tot i que l’ús químic del CO2 probablement no reduirà dràsticament la seva concentració a l’atmosfera, el seu baix cost i alta disponibilitat podria ajudar a substituir alguns dels processos industrials establerts que contribueixen al canvi climàtic. En particular, el grup carboxil està present en una gran quantitat de productes farmacèuti
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Serrano, Robledo Eloísa Sofía. "Amide Formation via Ni-Catalyzed Reductive Coupling Reactions with Isocyanates." Doctoral thesis, Universitat Rovira i Virgili, 2018. http://hdl.handle.net/10803/586084.

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Recentment, les reaccions d’acoblament creuat entre electròfils s’han posicionat com a potents alternatives a les reaccions clàssiques d’acoblament creuat entre electròfils orgànics i nucleòfils organometàl•lics. Aquests acoblaments reductius presenten nombrosos avantatges degut a que utilitzen compostos de partida simples i fàcilment assequibles que eviten la necessitat de sintetitzar espècies organometàl•liques sensibles a la humitat i a l’oxigen. Com a conseqüència, els protocols experimentals són pràctics i les condicions de reacció són suaus. A causa de la ubiqüitat de les amides en molèc
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Joensuu, Pekka Matias. "Development of catalytic stereoselective reductive aldol reactions." Thesis, University of Edinburgh, 2008. http://hdl.handle.net/1842/2576.

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The chemistry of enolates can be considered one of the cornerstone areas in organic chemistry. Regioselective generation of an enolate in the presence of several enolisable sites can often prove to be a difficult task. Discoveries in recent years have led to new areas of enolate formation in the presence of other carbonyl groups. These include reductive aldol chemistry where direct reductive aldol coupling of an alpha,beta - unsaturated carbonyl group in presence of a carbonyl electrophile enables often perfectly regioselective reactions to occur. This tandem conjugate reductionelectrophilic t
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Gallagher, P. "The reductive decomposition of bis-diazo-alkanes." Thesis, University of Liverpool, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.381343.

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Mc, Geehin Peter Kevin Mark. "Hydrogenation, hydrogenolysis and reductive fission reactions of cis dihydrodiols." Thesis, Queen's University Belfast, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.252284.

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Chakraborty, Satyajit. "Studies on oxidative and reductive reactions of carbocyclic compounds." Thesis, University of North Bengal, 1988. http://hdl.handle.net/123456789/709.

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Fung, Chi-ming Kelvin. "Synthesis and applications of copper hydride complexes in reductive reactions." Click to view the E-thesis via HKUTO, 2005. http://sunzi.lib.hku.hk/hkuto/record/B36388208.

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Fung, Chi-ming Kelvin, and 馮志明. "Synthesis and applications of copper hydride complexes in reductive reactions." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2005. http://hub.hku.hk/bib/B36388208.

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Mendiratta, Arjun. "Reductive coupling and related reactions with Mo and Ti tris- anilides." Thesis, Massachusetts Institute of Technology, 2005. http://hdl.handle.net/1721.1/32483.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2005.<br>Vita.<br>Includes bibliographical references.<br>Chapter 1: The capability of Mo(N[t-BulAr)₃ to act as a powerful one, two, and three electron reductant have been previously demonstrated. In this work, we show that Mo(NIt-BulAr)₃ forms a metastable adduct with the moderate [pi] acid PhCN; coordination of PhCN activates the nitrile carbon towards reaction with a variety of one-electron reagents such as dichalcogenides, nitric oxide, hydrogen atom donors, cobaltocene, and elemental phosphorus. Evidence is presen
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Books on the topic "Reductive reactions"

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Henderson, Richard A. The mechanisms of reactions at transition metal sites. Oxford University Press, 1997.

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United States. National Aeronautics and Space Administration., ed. Final report...for heterogeneous photocatalytic oxidation of atmospheric trace contaminants. National Aeronautics and Space Administration, 1994.

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United States. National Aeronautics and Space Administration., ed. Final report...for heterogeneous photocatalytic oxidation of atmospheric trace contaminants. National Aeronautics and Space Administration, 1994.

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1946-, Isied Stephan S., ed. Electron transfer reactions: Inorganic, organometallic, and biological applications. American Chemical Society, 1997.

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Prousek, Josef. Reakce iniciované přenosem elektronu. Academia, 1988.

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Humiston, T. J. Production-scale direct oxide reduction demonstration. Edited by Santi D. J, Long J. L, Rockwell International. Rocky Flats Plant, and United States. Dept. of Energy. Albuquerque Operations Office. Rockwell International, Aerospace Operations, Rocky Flats Plant, 1989.

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Geoghegan, Susan M. Modulating the redox propertoes of a flavoprotein; cloning, expression and site-directed mutagenesis of flavodoxin from M. elsdenii. University College Dublin, 1997.

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J, Mattay, and Khaĭrutdinov R. F, eds. Photoinduced electron transfer IV. Springer-Verlag, 1992.

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Lutz, Bernd. Experimente und Behandlungsvorschläge zum Unterrichtsthema "Redox-Reaktionen": Eine Synopse. Institut für die Pädagogik der Naturwissenschaften, 1986.

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Martinovich, G. G. Okislitelʹno-vosstanovitelʹnye prot︠s︡essy v kletkakh. BGU, 2008.

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Book chapters on the topic "Reductive reactions"

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Li, Jie Jack. "Borch reductive amination." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_32.

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Li, Jie Jack. "Borch reductive amination." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_28.

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Balch, A. L. "Reductive Procedures." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145296.ch82.

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Gras, J. L. "Reductive Hydrolysis." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch65.

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Atwood, David A. "Reductive Elimination Reactions." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145296.ch179.

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Li, Jie Jack. "Eschweiler–Clarke Reductive Amination." In Name Reactions. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-50865-4_48.

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Beller, Matthias, and Xiao Feng Wu. "Reductive Carbonylations." In Transition Metal Catalyzed Carbonylation Reactions. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-39016-6_3.

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Dräger, M., and N. Kleiner. "By Reductive Processes." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145234.ch74.

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Balch, A. L. "Binuclear Reductive Elimination." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145296.ch76.

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Li, Jie Jack. "Clarke-Eschweiler reductive alkylation of amines." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_62.

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Conference papers on the topic "Reductive reactions"

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Cullimore and Johnston. "Inter-Relationship between Sulfate Reducing Bacteria Associated with Microbiologically Influenced Corrosion and Other Bacterial Communities in Wells." In CORROSION 2004. NACE International, 2004. https://doi.org/10.5006/c2004-04588.

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Abstract Sulfate reducing bacteria have long been recognized as principal inducers of corrosion within water, oil and gas systems. This study evaluates the potential to utilize the tester system to detect SRB in water wells as a possible bioprospecting tool. Here the findings reveal that water wells associated with ground waters overlaying oil and gas deposits may be more prone to very aggressive populations of SRB that generate a BT (blackening at the top of the tester in the oxidative zone). Comparable studies on water wells not known to be associated with oil and gas reserves generally had
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Rocchini, Gabriele. "Some Aspects of the Acid Cleaning of Steam Generators." In CORROSION 1987. NACE International, 1987. https://doi.org/10.5006/c1987-87396.

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Abstract Some problems connected with the acid cleaning of steam generators are discussed. They concern the kinetics of magnetic dissolution, electrochemical controls and the use of a pilot plant for developing this technology. In the first part dealing with magnetite dissolution the chemical and electrochemical mechanisms are examined on the basis of experimental results and it is demonstrated that, though in principle they coexist as parallel reactions, the electrochemical path is kinetically favoured. The phenomenon of reductive magnetite dissolution is very valid in determining the quantit
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Wang, F., and J. Postlethwaite. "Modelling of Aqueous CO2 Corrosion of Iron in Turbulent Pipe Flow." In CORROSION 2001. NACE International, 2001. https://doi.org/10.5006/c2001-01041.

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Abstract Aqueous CO2 corrosion of iron in turbulent pipe flow is modelled with a two-dimensional low Reynolds number k-ε turbulence model by simultaneously solving the conservation equations for mass, momentum, kinetic energy of turbulence and turbulent energy dissipation rate, along with the concentrations of various dissolved species. The effect of slow homogeneous chemical reaction of CO2 hydration is incorporated into the model by including an extra source term in the transport equation for H2CO3. Other homogeneous chemical reactions are assumed to be in equilibrium with the equilibrium ad
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Royer, Richard A., and Richard F. Unz. "Iron-Microbe Interactions in Corrosion and Solid Phase Mineral Dissolution." In CORROSION 2002. NACE International, 2002. https://doi.org/10.5006/c2002-02473.

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Abstract The role of microorganisms in the reduction of solid phase iron minerals and corrosion of ferrous metals entails fundamental mechanisms which have common grounds for both processes. In each case, organisms influence surface/liquid interfacial reactions and are responsible for accelerating oxidation- or reduction-coupled mineral/metal dissolution. Hydrogen is a widely used microbial energy source which can serve as an electron donor to drive microbial iron reduction or accelerate the rate of the cathodic reaction during anaerobic corrosion. In the former, bacteria act as a biocatalyst
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Zheng, Yougui, Jing Ning, Bruce Brown, and Srdjan Nesic. "Investigation of Cathodic Reaction Mechanisms of H2S Corrosion Using a Passive SS304 Rotating Cylinder Electrode." In CORROSION 2016. NACE International, 2016. https://doi.org/10.5006/c2016-07340.

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Abstract The internal corrosion of pipeline steel in the presence of hydrogen sulfide (H2S) represents a significant problem in oil and gas industry. Its prediction and control pose a challenge for the corrosion engineers. In previously published research by the same authors, an electrochemical model of H2S corrosion was developed in both pure H2S and H2S/CO2 aqueous systems. An additional electrochemical cathodic reaction, direct H2S reduction, was uncovered based upon the carbon steel corrosion experimental results. However, in the carbon steel corrosion experiments, the cathodic sweeps expe
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Gray, Linda G. S., Bruce G. Anderson, Michael J. Danysh, and Peter R. Tremaine. "Mechanisms of Carbon Steel Corrosion in Brines Containing Dissolved Carbon Dioxide at pH 4." In CORROSION 1989. NACE International, 1989. https://doi.org/10.5006/c1989-89464.

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Abstract Electrochemical polarization measurements have been used to examine the corrosion of carbon steel by aqueous CO2 at partial pressures from 0 to 1.4 MPa in rotating disk and static electrode cells at 25°C. A detailed corrosion mechanism was derived which consisted of four redox reactions under varying types of kinetic control: diffusion controlled reduction of H+ (aq) to H2 (g), chemically controlled reduction of H2CO3° (aq) to H2 (g), charge transfer controlled reduction of H2O to H2 (g), and charge transfer controlled oxidation of Fe to Fe++. The rate of H2CO3° (aq) reduction was con
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Choi, Yoon-Seok, Srdjan Nešić, Deli Duan, and Shengli Jiang. "Mechanistic Modeling of Carbon Steel Corrosion in a MDEA-Based CO2 Capture Process." In CORROSION 2012. NACE International, 2012. https://doi.org/10.5006/c2012-01321.

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Abstract A predictive model was developed for corrosion of carbon steel in CO2-loaded aqueous methyldiethanolamine (MDEA) systems, based on modeling of thermodynamic equilibria and electrochemical reactions. The concentrations of aqueous carbonic and amine species (CO2, HCO3-, CO32-, MDEA and MDEAH+) as well as pH values in the MDEA solution were calculated. The water chemistry model showed a good agreement with experimental data for pH and CO2 loading, with an improved correlation upon use of activity coefficients. The electrochemical corrosion model was developed by modeling polarization cur
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Kim, Young-Jin. "Development and Validation of ECP Model for BWR Application." In CORROSION 2000. NACE International, 2000. https://doi.org/10.5006/c2000-00207.

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Abstract This paper describes the theoretical understanding and development of the electrochemical corrosion potential (ECP) predictive model to calculate the ECP of structural materials in BWRs and evaluates the effects of the various model parameters, which were experimentally produced in high temperature, high purity water. The electrochemical kinetic parameters for the O2 reduction and H2 oxidation reactions were measured experimentally in 288°C water. To develop the ECP model in the presence of H2O2, the electrochemical kinetic constants for the H2O reduction reaction were assumed to be t
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Kvarekvål, Jon. "A Kinetic Model for Calculating Concentration Profiles and Fluxes of Correlated Species across the Nernst Diffusion Layer." In CORROSION 1997. NACE International, 1997. https://doi.org/10.5006/c1997-97005.

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Abstract The aggressive behavior of carbonic acid solutions upon various steels has been widely investigated, but is yet not fully understood. In order to achieve more knowledge of the mechanisms of CO2 corrosion, simultaneous diffusion and homogenous chemical reactions have been simulated close to a corroding iron electrode, using kinetic data for the reactions involving CO2-related species and water. Many CO2 corrosion models predict mass transfer across the stagnant diffusion layer without considering contributions from homogenous chemical reactions.1-3 However, such reactions play a signif
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Kahyarian, Aria, Bruce Brown, and Srdjan Nesic. "Fundamental Mechanisms of Mild Steel Corrosion in H2S Containing Environments." In CORROSION 2019. NACE International, 2019. https://doi.org/10.5006/c2019-12875.

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Abstract The current understanding of the corrosion mechanisms in H2S containing environments is based on the direct electrochemical reduction of H2S as the main contribution of this species to the corrosion process. Such an argument has been developed based on the distinctive behavior of cathodic polarization curves in H2S containing solutions, as compared to the behavior observed in the solutions of strong acids or those in presence of other weak acids such as carboxylic acids and carbonic acid. The direct reduction of H2S is generally associated with the observation of a “double wave” in a
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Reports on the topic "Reductive reactions"

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Leeladee, Pannee. Cooperative small-molecule activation toward sustainable catalysis. Faculty of Science, Chulalongkorn University, 2018. https://doi.org/10.58837/chula.res.2018.47.

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In this research, a series of copper complexes containing polypyridyl ligands were designed to study the influence from ligands, nuclearity, solvents and secondary coordination on reactivity toward small-molecule activation. This structure-reactivity relationship was used in investigation for oxygen reduction reactions (ORR), and applied in detection of ascorbic acid (AsH₂). Firstly, copper (II) complexes containing polypyridyl derivatives ligands (i.e., Cu(dpa), Cu(adpa) and Cu₂ (addpa)) were synthesized and fully characterized by elemental analysis, mass spectrometry and X-ray crystallograph
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Berry, John. Novel Homogeneous Electrocatalysts for the Nitrogen Reduction Reaction. Office of Scientific and Technical Information (OSTI), 2020. http://dx.doi.org/10.2172/1670696.

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Schlautman, Mark A. Optimizing Metalloporphyrin-Catalyzed Reduction Reactions for In Situ Remediation of DOE Contaminants. Office of Scientific and Technical Information (OSTI), 2013. http://dx.doi.org/10.2172/1087345.

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Stoerzinger, Kelsey. Electrocatalytic nitrate reduction: controlling adsorbate affinity to tailor reaction products. Office of Scientific and Technical Information (OSTI), 2024. http://dx.doi.org/10.2172/2461619.

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Scott C. Brooks, Wenming Dong, Sue Carroll, Jim Fredrickson, Ken Kemner, and Shelly Kelly. Aqueous Complexation Reactions Governing the Rate and Extent of Biogeochemical U(VI) Reduction. Office of Scientific and Technical Information (OSTI), 2006. http://dx.doi.org/10.2172/895942.

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Scott C. Brooks, Wenming Dong, Sue Carroll, James K. Fredrickson, Kenneth M. Kemner, and Shelly D. Kelly. Aqueous Complexation Reactions Governing the Rate and Extent of Biogeochemical U(VI) Reduction. Office of Scientific and Technical Information (OSTI), 2006. http://dx.doi.org/10.2172/896202.

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Kemner, K. M., S. D. Kelly, Scott C. Brooks, Wenming Dong, Sue Carroll, and James K. Fredrickson. Aqueous complexation reactions governing the rate and extent of biogeochemical U(VI) reduction. Office of Scientific and Technical Information (OSTI), 2006. http://dx.doi.org/10.2172/896239.

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Neta, P. Redox Reactions of Metalloporphyrins and their Role in Catalyzed Reduction of Carbon Dioxide. Office of Scientific and Technical Information (OSTI), 2002. http://dx.doi.org/10.2172/836561.

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Burgos, William D., Eric E. Roden, and Gour-Tsyh Yeh. Reaction-Based Reactive Transport Modeling of Fe(III) and U(V) Reduction. Office of Scientific and Technical Information (OSTI), 2005. http://dx.doi.org/10.2172/893413.

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Gkatis, G., C. Paradela, G. Alaerts, et al. Results of time-of-flight transmission measurements for natFe at a 50 m station of GELINA. IAEA Nuclear Data Section, 2024. http://dx.doi.org/10.61092/iaea.twc4-dgh7.

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Transmission measurements on natural iron samples have been performed at the time-of-flight facility GELINA to validate neutron resonance parameters for Fe isotopes. The measurements were carried out at the 50 m transmission station using a Li-glass scintillator with the accelerator operating at 800 Hz. This report provides the experimental details required to deliver the data to the EXFOR data library which is maintained by the International Network of Nuclear Reaction Data Centres (NRDC). The experimental conditions and data reduction procedures are described. In addition, the full covarianc
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