Academic literature on the topic 'Reformatsky's reaction'

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Journal articles on the topic "Reformatsky's reaction"

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Cozzi, Pier Giorgio, Alessandro Mignogna, and Luca Zoli. "Catalytic enantioselective Reformatsky reactions." Pure and Applied Chemistry 80, no. 5 (2008): 891–901. http://dx.doi.org/10.1351/pac200880050891.

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The Reformatsky reaction is a venerable named reaction that was introduced more than 120 years ago. Diastereoselective variants based on the use of chiral auxiliary and enantioselective protocols, based on the employment of stoichiometric amount of chiral ligands, have been successfully applied in organic synthesis during the years. However, a facile and general catalytic enantioselective variant was still a difficult task. Recently, we have established a new general and straightforward methodology for catalytic enantioselective Reformatsky reaction based on different concepts. In this paper,
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Cozzi, Pier Giorgio, and Eleonora Rivalta. "First enantioselective one-pot, three-component imino Reformatsky reaction." Pure and Applied Chemistry 78, no. 2 (2006): 287–91. http://dx.doi.org/10.1351/pac200678020287.

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The Reformatsky reaction is the well-recognized carbon-carbon bond-forming reaction of α-halo esters with aldehydes or ketones in the presence of Zn metal to give β-hydroxy esters. Recently, it has been reported that Rh- and Ni-catalyzed Reformatsky reaction, in which R2Zn (R = Me, Et) acts as the Zn source, reacted smoothly with carbonyl compounds and imines. Taking advantage of N-methylephedrine as a cheap and recoverable chiral ligand, we have discovered the first homogeneous enantioselective Ni-catalyzed imino Reformatsky reaction. The process is a one-pot, three-component reaction, in whi
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De Munck, Lode, Verena Sukowski, Carlos Vila, M. Carmen Muñoz, and José R. Pedro. "Catalytic enantioselective aza-Reformatsky reaction with seven-membered cyclic imines dibenzo[b,f][1,4]oxazepines." Organic Chemistry Frontiers 4, no. 8 (2017): 1624–28. http://dx.doi.org/10.1039/c7qo00329c.

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Pellissier, Hélène. "Recent developments in the asymmetric Reformatsky-type reaction." Beilstein Journal of Organic Chemistry 14 (February 2, 2018): 325–44. http://dx.doi.org/10.3762/bjoc.14.21.

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This review collects the most important developments in asymmetric Reformatsky-type reactions published since the beginning of 2013, including both diastereoselective methodologies based on the use of chiral substrates and enantioselective catalytic procedures.
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Mylari, Banavara L., and William J. Zembrowski. "Reformatsky reaction: carboxymethylenation of cyclic anhydrides and reactions of products thereof." Journal of Organic Chemistry 56, no. 7 (1991): 2587–89. http://dx.doi.org/10.1021/jo00007a061.

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Tarui, Atsushi, Takeshi Ikebata, Kazuyuki Sato, Masaaki Omote та Akira Ando. "Enantioselective synthesis of α,α-difluoro-β-lactams using amino alcohol ligands". Org. Biomol. Chem. 12, № 33 (2014): 6484–89. http://dx.doi.org/10.1039/c4ob01184h.

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Park, Doo-Han, Ho-Jin Choi, and Sang-Gi Lee. "Enantioselective Reformatsky Reaction Using Cinchona Alkaloids as Chiral Ligands." Journal of the Korean Chemical Society 47, no. 6 (2003): 597–600. http://dx.doi.org/10.5012/jkcs.2003.47.6.597.

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Chen, Zhiwei, Hao Chen, Xiaofeng Yang, and Xiangqing Chang. "Novel One-Pot Cyclization of the Blaise Reaction Intermediate and Arylglyoxals: The Synthesis of Substituted NH-Pyrroles." Synlett 28, no. 12 (2017): 1463–66. http://dx.doi.org/10.1055/s-0036-1588168.

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A novel tandem Blaise reaction for the one-pot synthesis of substituted NH-pyrroles was described. The Blaise reaction intermediate, generated in situ from Reformatsky reagent and nitrile, reacted with arylglyoxals chemoselectively to afford a wide variety of substituted NH-pyrroles in good yields.
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Chaudhari, Tohasib Yusub, Urvashi Urvashi, Sandeep K. Ginotra, Pooja Yadav, Gulshan Kumar, and Vibha Tandon. "Regioselective synthesis of functionalized dihydroisoquinolines from o-alkynylarylaldimines via the Reformatsky reaction." Organic & Biomolecular Chemistry 14, no. 41 (2016): 9896–906. http://dx.doi.org/10.1039/c6ob01790h.

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Sgreccia, Laura, Marco Bandini, Stefano Morganti, Arianna Quintavalla, Achille Umani-Ronchi, and Pier Giorgio Cozzi. "Titanium-catalyzed Reformatsky-type reaction." Journal of Organometallic Chemistry 692, no. 15 (2007): 3191–97. http://dx.doi.org/10.1016/j.jorganchem.2007.02.037.

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Dissertations / Theses on the topic "Reformatsky's reaction"

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Pezzotta, Justine. "Synthèse de C-sialosides par samariation réductrice : approches inter- et intramoléculaires." Thesis, Paris 11, 2014. http://www.theses.fr/2014PA112094/document.

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Les acides ulosoniques constituent une famille de monosaccharides complexes dont les glycoconjugués présentent des propriétés biologiques importantes. L’acide sialique ou acide N-acétylneuraminique (Neu5Ac), membre le plus couramment rencontré de cette famille joue notamment un rôle dans l’infection par le virus Influenza. La liaison α-O-glycosylée des résidus naturels de Neu5Ac est cependant sensible à l’hydrolyse chimique et enzymatique. La synthèse d’analogues C-glycosylés qui présentent l’avantage d’être non-hydroysables, constituent alors un axe de recherche de grand intérêt. Les dérivés
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Fornalczyk, Michal. "The fluorinated asymmetric Reformatsky reaction with aromatic ketones and imines." Thesis, University of Leicester, 2011. http://hdl.handle.net/2381/10264.

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One of the most challenging topics in organofluorine chemistry is the asymmetric introduction of fluorine atoms, difluoromethylene and trifluoromethyl groups. Outstanding progress has been made in recent years, but further developments are necessary for chiral fluorinated molecules to be increasingly used in medicinal, agricultural and material chemistry. The enantioselective addition of the fluorinated Reformatsky reagent to aromatic aldehydes in the presence of chiral aminoalcohols to give α,α-difluoro-β-hydroxy esters in good enantiomeric excess is well established. However, the two step pr
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Chavant, Pierre Yves. "Reaction de type barbier ou reformatsky effectuees a l'aide de manganese." Paris 6, 1988. http://www.theses.fr/1988PA066138.

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Etude de la reactivite du manganese metallique vis-a-vis d'halogenures allyliques et d'halogeno-2 esters. Une etude de l'influence du solvant et de la presence de divers sels metalliques, a debouche sur la mise au point d'une nouvelle voie d'acces a des alcools homoallyliques
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Soares-Sello, Anna Mampe. "Biosynthetic studies of strobilurins." Thesis, University of Bristol, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.389145.

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Liébert, Clémence. "Neodymium(III)-mediated Reformatsky-type reactions of alpha-halo ketones with carbonyl compounds & synthetic studies directed toward a de novo synthesis of cyperane class sesquiterpenoids /." München : Verl. Dr. Hut, 2009. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=017732553&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.

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Frutos, Höner Annabelle P. "Methodology studies on in situ generated Fischer carbene complexes of group VI transition metals, on the chromium-Reformatsky reaction of nitrogen based compounds, and analytical studies of the Vogel collection /." Diss., Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2000. http://wwwlib.umi.com/cr/ucsd/fullcit?p9956454.

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EL, ALAMI NAJAT. "Isolement et reactivite du derive zincique de (bromomethyl-2) acrylate d'ethyle : synthese de methylene-3 pyrrolidinone-3 potentiellement antineoplasique." Nantes, 1987. http://www.theses.fr/1987NANT2016.

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Reaction de l'organozinicique allylique prepare, avec divers electrophiles conduisant a des methylene-3 perhydrofurannones-2 et -pyrrolidones-2. Etude de l'activite de ces composes sur la leucamie p388
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詹淑怡. "Asymmetric Reformatsky Reaction Catalyzed by Camphor-derives β-Amino Alcohols as Chiral Ligands". Thesis, 2012. http://ndltd.ncl.edu.tw/handle/72168733135956251457.

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day, danny, та 戴森地. "A study of Asymmetric Reformatsky Reaction of α-iodoester using chiral amino alcohols derivated form amino acids". Thesis, 2005. http://ndltd.ncl.edu.tw/handle/88507915134795521234.

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碩士<br>國立中興大學<br>化學系<br>93<br>The use of a series of chiral amino-alcohols as ligand to control the stereoselectivity of Reformatsky reaction has been examined. We found that, the β-hydroxy esters were prepared from asymmetric Reformatsky reactions with good enatioselectivity up to 90% e.e..
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何孟宗. "The application of asymmetric reformatsky-type reaction in preparing of chiral B-hydroxyamide for the intermediate of new triazole antifungal agents." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/47580184868957857448.

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碩士<br>國立中興大學<br>化學系<br>92<br>The asymmetric Reformatsky reaction is a versatile and straight forward approach to obtaining chiral alcohols ( -hydroxy esters), a motif found in biologically active compounds and synthetic intermediates. Although a variety of asymmetric Reformatsky reactions have been developed. In our study the compound 3 with  -hydroxycarboxylic acid was reported as an important intermediate of triazole antifungal agent. We found the Reformatsky reaction with acetophenone (Ketone) was carried out under the metal-halogen exchange reaction of the α-Bromo oxazolidinones with d
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Books on the topic "Reformatsky's reaction"

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Armitage, Mark Alan. Studies in asymmetric synthesis: Attempted asymmetric reformatsky reactions & approaches towards the alkaloid fastigiatine. University of East Anglia, 1993.

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Book chapters on the topic "Reformatsky's reaction"

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Li, Jie Jack. "Reformatsky reaction." In Name Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04835-1_235.

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Li, Jie Jack. "Reformatsky reaction." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_212.

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Li, Jie Jack. "Reformatsky reaction." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_227.

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Li, Jie Jack. "Reformatsky reaction." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_246.

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Li, Jie Jack. "Reformatsky Reaction." In Name Reactions. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-50865-4_129.

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Vidal, Agnès, Adel Nefzi, and Richard A. Houghten. "Solid-Phase Synthesis of α-Difluoro-β-amino Acids by a Reformatsky Reaction." In Peptides: The Wave of the Future. Springer Netherlands, 2001. http://dx.doi.org/10.1007/978-94-010-0464-0_118.

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"82. Reformatsky Reaction." In Organic Chemistry: 100 Must-Know Mechanisms. De Gruyter, 2020. http://dx.doi.org/10.1515/9783110608373-082.

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Araki, S., and T. Hirashita. "Reformatsky-Type Reactions." In Science of Synthesis Knowledge Updates KU 2011/1. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-107-00115.

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Mahrwald, R., and B. Schetter. "Reactions of Aldehydes/Ketones with α-Halo Ketones (Reformatsky Reaction)." In Alcohols. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-036-00696.

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Malacria, M., C. Aubert, and J. L. Renaud. "Reformatsky- and Aldol-Type Reactions." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00378.

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