Academic literature on the topic 'Rehm-Weller equation'

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Journal articles on the topic "Rehm-Weller equation"

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Huang, Heyong, Jiahong Zhou, Yan Zhou, Yanhuai Zhou, and Yuying Feng. "Studies on the Photoinduced Interaction between Zn(II) Porphyrin and Colloidal TiO2." International Journal of Photoenergy 2010 (2010): 1–5. http://dx.doi.org/10.1155/2010/547135.

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The interaction of Zn(II) porphyrin (ZnPP) with colloidal TiO2was studied by absorption and fluorescence spectroscopy. The fluorescence emission of ZnPP was quenched by colloidal TiO2upon excitation of its absorption band. The quenching rate constant (kq) is1.24×1011 M−1 s−1. These data indicate that there is an interaction between ZnPP and colloidal TiO2nanoparticle surface. The quenching mechanism is discussed on the basis of the quenching rate constant as well as the reduction potential of the colloidal TiO2. And the mechanism of electron transfer has been confirmed by the calculation of fr
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Nagarajan, N., G. Paramaguru, G. Vanitha, and R. Renganathan. "Photosensitization of Colloidal SnO2Semiconductor Nanoparticles with Xanthene Dyes." Journal of Chemistry 2013 (2013): 1–7. http://dx.doi.org/10.1155/2013/585920.

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The photochemical behavior of xanthene dyes (fluorescein, erythrosine, and eosin) with colloidal SnO2nanoparticles was probed by UV-visible, steady state, and time resolved fluorescence measurements. The prepared SnO2nanoparticles were characterized by using UV-visible and powder XRD measurements. The xanthene dyes were adsorbed on the surface of colloidal SnO2nanoparticles through electrostatic interaction. Apparent association constant (Kapp) was calculated from the relevant fluorescence data. The larger value of apparent association constant indicates a strong association between xanthene d
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OSAKI, Toshihiko, Yutaka TAI, Masato TAZAWA, Sakae TANEMURA, Katsuya ISHIGURO, and Yasuhiko SAWAKI. "Electron Transfer Reaction to Triplet Excited State of Fullerenes in Solution. Comparison with the Rehm-Weller Equation." Journal of the Spectroscopical Society of Japan 42, no. 6 (1993): 379–84. http://dx.doi.org/10.5111/bunkou.42.379.

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Dufresne, Stéphane, Thomas Skalski, and W. G. Skene. "Insights into the effect of ketylimine, aldimine, and vinylene group attachment and regiosubstitution on the fluorescence deactivation of fluorene." Canadian Journal of Chemistry 89, no. 2 (2011): 173–80. http://dx.doi.org/10.1139/v10-089.

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The spectroscopic and electrochemical properties of a 9-substituted fluorene ketylimine (3) were investigated and compared with those of its vinylene analogue (4) to determine the origins of the quenched fluorescence of these compounds. The predominate mode of singlet excited state deactivation of the heteroatomic fluorene was found to be internal conversion involving bond rotation. Meanwhile, its carbon counterpart was found to undergo deactivation preferentially by intersystem crossing to form its triplet, which was confirmed by laser flash photolysis. Both 3 and 4 quenched the fluorescence
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Caronna, Tullio, Sergio Morrocchi, and Bruno M. Vittimberga. "Importance of acidity on the energetically unfavorable electron-transfer reaction. An extension of the Rehm-Weller equation. Photoreaction of triplet 2,4-pyridinedicarbonitrile with 2-propanol." Journal of the American Chemical Society 108, no. 9 (1986): 2205–8. http://dx.doi.org/10.1021/ja00269a013.

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CARONNA, T., S. MORROCCHI, and B. M. VITTIMBERGA. "ChemInform Abstract: Importance of Acidity on an Energetically Unfavorable Electron-Transfer Reaction - an Extension of the Rehm-Weller Equation. Photoreaction of Triplet 2,4-Pyridinedicarbonitrile with 2-Propanol." Chemischer Informationsdienst 17, no. 34 (1986). http://dx.doi.org/10.1002/chin.198634048.

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Dissertations / Theses on the topic "Rehm-Weller equation"

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Narayanan, Madhavan. "Study of photoinduced electron transfer in fluorescent nucleobase analogues (FBAs) and DNA photolyase." Diss., Temple University Libraries, 2011. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/119151.

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Chemistry<br>Ph.D.<br>Photoinduced electron transfer (PET) plays a crucial role in a wide array of biological pathways. These electron transfer reactions happen from or to the excited state of a chromophore upon absorption of light. Hence understanding the properties of excited states is necessary in elucidating the details of such pathways. The work presented in this thesis deals with PET in two systems: Fluorescent Nucleobase Analogues (FBAs) and DNA photolyase. The introductory chapter (Chapter 1) presents some background information about the two systems and sets up the stage for the reaso
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Bourque, Alex N. "Photophysical Investigations of Thiophene Azomethine Derivatives." Thèse, 2009. http://hdl.handle.net/1866/3565.

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Une série de dimères composés de thiophène-aniline encombrée stériquement a été synthétisée. Les différents processus de désactivation de l’état singulet excité ont été étudiés par UV-visible, fluorescence, phosphorescence, photolyse par impulsion laser et calculs théoriques. Les graphiques de Stern-Volmer obtenus à partir des expériences de désactivation des états singulet et triplet ont démontré l’efficacité de l’azométhine à désactiver les fluorophores. Les calculs semi-empiriques AM1 examinant l’effet des substituants encombrés ont démontrés que les groupements tert-butyls sur l’aniline o
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