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Journal articles on the topic 'Reimer-Tiemann reaction'

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Published: 5 June 2025
Last updated: 1 August 2025

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1

Bhunia, Sankar C., Gopal C. Patra, and Sudhir C. Pal. "Reimer–Tiemann Reaction of Coumarins." Synthetic Communications 41, no. 24 (2011): 3678–82. http://dx.doi.org/10.1080/00397911.2010.519847.

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2

Cochran, John C., and Margaret G. Melville. "The Reimer-Tiemann Reaction, Enhanced by Ultrasound." Synthetic Communications 20, no. 4 (1990): 609–16. http://dx.doi.org/10.1080/00397919008244911.

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3

Bhunia, Sankar C., Gopal C. Patra, and Sudhir C. Pal. "ChemInform Abstract: Reimer-Tiemann Reaction of Coumarins." ChemInform 43, no. 18 (2012): no. http://dx.doi.org/10.1002/chin.201218159.

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4

Bird, C. W., A. L. Bronw, and C. C. Chan. "A new type of abnormal reimer-tiemann reaction." Tetrahedron 41, no. 20 (1985): 4685–90. http://dx.doi.org/10.1016/s0040-4020(01)82364-4.

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5

GAONKAR, A. V., and J. K. KIRTANY. "ChemInform Abstract: Reimer-Tiemann Reaction Using Carbon Tetrachloride." ChemInform 22, no. 41 (2010): no. http://dx.doi.org/10.1002/chin.199141092.

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6

Castillo, R., V. Moliner, J. Andr�s, M. Oliva, V. S. Safont, and S. Bohm. "Theoretical investigation of the abnormal Reimer-Tiemann reaction." Journal of Physical Organic Chemistry 11, no. 8-9 (1998): 670–77. http://dx.doi.org/10.1002/(sici)1099-1395(199808/09)11:8/9<670::aid-poc56>3.0.co;2-u.

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7

Ravichandran, Ramaswamy. "β-Cyclodextrin mediated regioselective photo-Reimer–Tiemann reaction of phenols". Journal of Molecular Catalysis A: Chemical 130, № 3 (1998): L205—L207. http://dx.doi.org/10.1016/s1381-1169(97)00223-9.

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8

Yamabe, Shinichi, and Takeshi Fukuda. "A significant role of alkaline cations on the Reimer–Tiemann reaction." Organic & Biomolecular Chemistry 9, no. 14 (2011): 5109. http://dx.doi.org/10.1039/c1ob05405h.

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9

Wantulok, Jakub, Marcin Szala, Andrea Quinto, et al. "Synthesis, Electrochemical and Spectroscopic Characterization of Selected Quinolinecarbaldehydes and Their Schiff Base Derivatives." Molecules 25, no. 9 (2020): 2053. http://dx.doi.org/10.3390/molecules25092053.

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A new approach to the synthesis of selected quinolinecarbaldehydes with carbonyl groups located at C5 and/or in C7 positions is presented in this paper in conjunction with spectroscopic characterization of the products. The classical Reimer-Tiemann, Vilsmeier-Haack and Duff aldehyde synthesis methods were compared due to their importance. Computational studies were carried out to explain the preferred selectivity of the presented formylation transformations. A carbene insertion reaction based on Reimer-Tiemann methodology is presented for making 7-bromo-8-hydroxyquinoline-5-carbaldehyde. Addit
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10

Langlois, Bernard R. "Anomalous reimer-tiemann reaction from phenol, chloroform and potassium fluoride in sulfolane." Tetrahedron Letters 32, no. 30 (1991): 3691–94. http://dx.doi.org/10.1016/s0040-4039(00)79769-3.

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11

NISHIOKA, Hiroshi, Tetsu KUMAGAI, Tohru NAGAHIRO, and Katsuya UESUGI. "Flow injection analysis of chloroform in water by using Reimer-Tiemann reaction." Journal of Environmental Conservation Engineering 22, no. 10 (1993): 599–603. http://dx.doi.org/10.5956/jriet.22.599.

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12

Vibhute, Yeshwant B., Subhash M. Lonkar, Mudassar A. Sayyed, and Mohammad A. Baseer. "Synthesis of substituted 2-hydroxyaryl aldehydes by the microwave-induced Reimer-Tiemann reaction." Mendeleev Communications 17, no. 1 (2007): 51. http://dx.doi.org/10.1016/j.mencom.2007.01.020.

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13

Castillo, R., V. Moliner, and J. Andrés. "A theoretical study on the molecular mechanism for the normal Reimer–Tiemann reaction." Chemical Physics Letters 318, no. 1-3 (2000): 270–75. http://dx.doi.org/10.1016/s0009-2614(00)00005-1.

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14

Neumann, Ronny, and Yoel Sasson. "IncreasedparaSelectivity in the Reimer-Tiemann Reaction by Use of Polyethylene Glycol as Complexing Agent." Synthesis 1986, no. 07 (1986): 569–70. http://dx.doi.org/10.1055/s-1986-31708.

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15

Shastri, Lokesh A., Samundeeswari L. Shastri, Chinna D. Bathula, Mahantesha Basanagouda, and Manohar V. Kulkarni. "Mild, Simple, and Efficient Method forN-Formylation of Secondary Amines via Reimer–Tiemann Reaction." Synthetic Communications 41, no. 4 (2011): 476–84. http://dx.doi.org/10.1080/00397910903576644.

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16

NOMURA, Eisaku, and Hisaji TANIGUCHI. "The catalytic effects of polyethylene glycols and their ethers on the reimer-tiemann reaction." NIPPON KAGAKU KAISHI, no. 6 (1989): 977–82. http://dx.doi.org/10.1246/nikkashi.1989.977.

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17

LANGLOIS, B. R. "ChemInform Abstract: Anomalous Reimer-Tiemann Reaction from Phenol, Chloroform, and Potassium Fluoride in Sulfolane." ChemInform 23, no. 17 (2010): no. http://dx.doi.org/10.1002/chin.199217115.

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18

Li, Kai, Huijie Lu, Yuanyuan Li, Shuangquan Zang, and Benzhong Tang. "A Comprehensive Experiment on Synthesis of Aggregation-Induced Emitting Salicylaldehyde Azine Using Reimer-Tiemann Reaction." University Chemistry 35, no. 1 (2020): 53–58. http://dx.doi.org/10.3866/pku.dxhx201904010.

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19

Iles, Alexander, Robin Fortt, and Andrew J. de Mello. "Thermal optimisation of the Reimer–Tiemann reaction using thermochromic liquid crystals on a microfluidic reactor." Lab on a Chip 5, no. 5 (2005): 540. http://dx.doi.org/10.1039/b419081e.

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20

Hapsari, M., T. Windarti, Purbowatiningrum, Ngadiwiyana, and Ismiyarto. "Synthesis of 4-hydroxy-3-methylchalcone from Reimer-Tiemann reaction product and its antibacterial activity test." IOP Conference Series: Materials Science and Engineering 349 (April 2018): 012036. http://dx.doi.org/10.1088/1757-899x/349/1/012036.

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21

Consuelo Jiménez, M., Miguel A. Miranda, and Rosa Tormos. "Formation of dichloromethyl phenyl ethers as major products in the photo-Reimer-Tiemann reaction without base." Tetrahedron 51, no. 20 (1995): 5825–30. http://dx.doi.org/10.1016/0040-4020(95)00235-z.

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22

Ismiyarto, Ismiyarto, Suyanti Suyanti, Ngadiwiyana Ngadiwiyana, Purbowatiningrum Ria Sarjono, and Nor Basid Adiwibawa Prasetya. "Synthesis of 4-Hydroxy-2-Methylchalcone from meta-Cresol Formilation Product and Its Activities as an Antibacteria." Jurnal Kimia Sains dan Aplikasi 21, no. 4 (2018): 193–97. http://dx.doi.org/10.14710/jksa.21.4.193-197.

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Research on the synthesis of 4-hydroxy-2-methylchalcone from 4-hidroksi-2-metilbenzaldehida as formilated meta-cresol product and its antibacterial activity test has been conducted. As the first step, synthesis of 4-hydroxy-2-methylbenzaldehyde was carried out by treatment meta-cresol with chloroform through the Reimer-Tiemann formylation. Product is a brown solid with 23.94% yields. Furthermore, the 4-hydroxy-2-methylchalcone was synthesized using the 4-hydroxy-2-methylbenzaldehyde and acetophenone through the Claisen-Schmidt reaction. The product is a brownish yellow solid with 29.74% yields
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23

Shastri, Lokesh A., Samundeeswari L. Shastri, Chinna D. Bathula, Mahantesha Basanagouda, and Manohar V. Kulkarni. "ChemInform Abstract: Mild, Simple, and Efficient Method for N-Formylation of Secondary Amines via Reimer-Tiemann Reaction." ChemInform 42, no. 29 (2011): no. http://dx.doi.org/10.1002/chin.201129042.

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24

Ren, Shenyong, Zhenhua Wu, Qiaoxia Guo, and Baojian Shen. "Zeolites as Shape-Selective Catalysts: Highly Selective Synthesis of Vanillin from Reimer–Tiemann Reaction of Guaiacol and Chloroform." Catalysis Letters 145, no. 2 (2014): 712–14. http://dx.doi.org/10.1007/s10562-014-1456-5.

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25

Thoer, A., G. Denis, M. Delmas, and A. Gaset. "The Reimer-Tiemann Reaction in Slightly Hydrated Solid-liquid Medium: A New Method for the Synthesis of Formyl and Diformyl Phenols." Synthetic Communications 18, no. 16-17 (1988): 2095–101. http://dx.doi.org/10.1080/00397918808068278.

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26

Sankar, P. Dey, and K. Dey Dilip. "Acid-catalysed rearrangements of allyl 4-hydroxybenzoate and 3-methylbut-2- enyl-4-hydroxybenzoate." Journal of Indian Chemical Society Vol. 86, May 2009 (2009): 485–87. https://doi.org/10.5281/zenodo.5810153.

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Department of Chemistry, Srikrishna College, Bagula-741 507, Nadia, West Bengal, India <em>E-mail</em> : deysp2002@yahoo.co.in Department of Chemistry, Chandidas Mahavidyalaya, Khujutipara-731 215, Birbhum, West Bengal, India <em>E-mail </em>: deydk@yahoo.com <em>Manuscript received 27 June 2008, revised 31 December 2008, accepted 1 January 2009</em> On treatment with 75% polyphosphoric acid or TFA-H<sub>2</sub>SO<sub>4</sub> (50%) allyl 4-hydroxybenzoate and 3-methylbut-2-enyl-4-hydroxybenzoate afforded 4-hydroxy-3-(2<em>&#39;</em> -hydroxypropyl)benzoic acid and 4-hydroxy-3-(3<em>&#39;</em>
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27

Barbera, Vincenzina, Luigi Brambilla, Alessandro Porta, et al. "Selective edge functionalization of graphene layers with oxygenated groups by means of Reimer–Tiemann and domino Reimer–Tiemann/Cannizzaro reactions." Journal of Materials Chemistry A 6, no. 17 (2018): 7749–61. http://dx.doi.org/10.1039/c8ta01606b.

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28

Smith, Kevin M., Frank W. Bobe, Ohannes M. Minnetian, Hakon Hope, and Michael D. Yanuck. "Novel substituent orientation in Reimer-Tiemann reactions of pyrrole-2-carboxylates." Journal of Organic Chemistry 50, no. 6 (1985): 790–92. http://dx.doi.org/10.1021/jo00206a012.

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29

Pert, DJ, and DD Ridley. "Formylation of Estrogens." Australian Journal of Chemistry 42, no. 3 (1989): 405. http://dx.doi.org/10.1071/ch9890405.

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Reimer-Tiemann formylations of oestradiol and oestrone were investigated and, whilst substitution was effected under certain conditions to give mixtures of 2- and 4-formyloestrogens, yields were very low and the method was unsuitable for preparative purposes. Regioselective methods were developed and 2-formyloestradiol was conveniently prepared from oestradiol by formylation of the lithio derivative of the bis(methoxymethyl) ether and removal of the rotecting groups with hydrochloric acid. 4-Formyloestradiol was prepared by a sequence of reactions starting with the methoxyethyl ether of 4-brom
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30

Cambie, C., William A. Denny, Michael P. Hay, Lorna H. Mitchell, Peter S. Rutledge, and Paul D. Woodgate. "Modifications of Rings B and C of Podocarpic Acid: Towards the Synthesis of Quassinoids Richard." Australian Journal of Chemistry 52, no. 1 (1999): 7. http://dx.doi.org/10.1071/c98015.

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Attempts to alkylate products from Birch reductions of derivatives of podocarpic acid are reported. Attempted reductive silylation of ring C of methyl 12-methoxypodocarpa-8,11,13-trien-19-oate (5) gives products of C4 ester reduction only. The enantiopure form of the bis(ethylene acetal) (15) of 19-norpodocarp-8-ene-3,12-dione, a potentially useful intermediate for quassinoid synthesis, has been prepared from the ketone (34). Functionality at C8 on the β-face has been successfully introduced by abnormal Reimer–Tiemann reactions of podocarpic acid (2) and its 13-methyl derivative (10). The satu
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31

Jung, Michael E., and Tsvetelina I. Lazarova. "Efficient Synthesis of Selectively Protectedl-Dopa Derivatives froml-Tyrosine via Reimer−Tiemann and Dakin Reactions." Journal of Organic Chemistry 62, no. 5 (1997): 1553–55. http://dx.doi.org/10.1021/jo962099r.

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32

JUNG, M. E., and T. I. LAZAROVA. "ChemInform Abstract: Efficient Synthesis of Selectively Protected L-Dopa Derivatives from L- Tyrosine via Reimer-Tiemann and Dakin Reactions." ChemInform 28, no. 27 (2010): no. http://dx.doi.org/10.1002/chin.199727222.

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33

Shade, Joyce E., Wayne H. Pearson, James E. Brown, and Thomas E. Bitterwolf. "Photochemical Reimer-Tiemann Reactions of (.eta.5-C5H5)2Fe2(.mu.-CO)2(.mu.-Ph2PCH2PPh2) and (.eta.5-C5H5)2Fe2(.mu.-CO)2(.mu.-Ph2PCH2CH2PPh2). The Molecular structures of (.eta.5-C5H5)2Fe2(.mu.-CO)2(.mu.-Ph2PCH2CH2PPh2) and (.eta.5-CHOC5H4)(.eta.5-C5H5)Fe2(.mu.-CO)2(.mu.-Ph2PCH2CH2PPh2)." Organometallics 14, no. 1 (1995): 157–61. http://dx.doi.org/10.1021/om00001a025.

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34

Bhatt, Sakshi, Ranjita S. Das, Anupama Kumar, Aishwarya Soni, Anil Malik, and Suman L. Jain. "Light Assisted Coupling of Phenols with CO2 to 2-Hydroxy-benzaldehydes Catalyzed by g-C3N4 /NH2-MIL-101(Fe) composite." Catalysis Science & Technology, 2022. http://dx.doi.org/10.1039/d2cy01430k.

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Salicylaldehyde is a key precursor to a variety of medicinal compounds synthesised by heating phenol and chloroform in the presence of alkali using the Reimer-Tiemann reaction. Owing to the growing...
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35

COCHRAN, J. C., and M. G. MELVILLE. "ChemInform Abstract: The Reimer-Tiemann Reaction, Enhanced by Ultrasound." ChemInform 21, no. 35 (1990). http://dx.doi.org/10.1002/chin.199035115.

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36

"An Efficient Synthesis of Nitrogen Heterocarbaldehydes Synthon by Remodel Reimer-Tiemann Reaction." International Journal of ChemTech Research, 2018. http://dx.doi.org/10.20902/ijctr.2018.110518.

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37

Vibhute, Yeshwant B., Subhash M. Lonkar, Mudassar A. Sayyed, and Mohammad A. Baseer. "Synthesis of Substituted 2-Hydroxyaryl Aldehydes by the Microwave-Induced Reimer—Tiemann Reaction." ChemInform 38, no. 34 (2007). http://dx.doi.org/10.1002/chin.200734077.

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38

NEUMANN, R., and Y. SASSON. "ChemInform Abstract: Increased para Selectivity in the Reimer-Tiemann Reaction by Use of Polyethylene Glycol as Complexing Agent." Chemischer Informationsdienst 17, no. 51 (1986). http://dx.doi.org/10.1002/chin.198651145.

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39

THOER, A., G. DENIS, M. DELMAS, and A. GASET. "ChemInform Abstract: The Reimer-Tiemann Reaction in Slightly Hydrated Solid-Liquid Medium: A New Method for the Synthesis of Formyl and Diformylphenols." ChemInform 20, no. 21 (1989). http://dx.doi.org/10.1002/chin.198921135.

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40

SMITH, K. M., F. W. BOBE, O. M. MINNETIAN, H. HOPE, and M. D. YANUCK. "ChemInform Abstract: NOVEL SUBSTITUENT ORIENTATION IN REIMER-TIEMANN REACTIONS OF PYRROLE-2-CARBOXYLATES." Chemischer Informationsdienst 16, no. 32 (1985). http://dx.doi.org/10.1002/chin.198532152.

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